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Seas = environmental services Food, Health, Commerce Tourism Biodiversity Environment, protected areas But…

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Slide 2 Slide 3 Seas = environmental services Food, Health, Commerce Tourism Biodiversity Environment, protected areas But Slide 4 we are about 7 billion (7.000.000.000) people, and many living in coastal urban centers Slide 5 Global Change Physical alteration Seawage Nutrients Sediment mobilisation POPs Hydrocarbons Heavy metals Litter Radionuclides Climate Change... Slide 6 IAEA Marine Environment Laboratories Slide 7 Marine Isotopic Records and Models to Assess Climate Change Slide 8 Sanchez-Cabeza, J.A. Dunbar, R. Druffel, E. Al-Rousan, S. Fink, D. Gutierrez, D. Morgenstern, U. Reynaud, S. Sifeddine, A. Skilbeck, G. Slide 9 Objective Apply the latest knowledge and analytical techniques to study the history of ENSO (El Nio Southern Oscillation) and its teleconnections extending from the Pacific basin into the Indian Ocean and back in time beyond the instrumental era. (NOAA) Slide 10 Strategy Galpagos and Peru Republic of Palau Palmyra Atoll Slide 11 Light filters Temperature controller Tank After 2 months Skeleton used for measurements (Acropora) Corals as paleo- thermometers Slide 12 The vital effect on 18 O Calcification 18 O Slide 13 Element ratios (Acropora) Mg/Ca Reynaud S, Pags C, Meibom A, Mortlock R, Fairbanks R, Allemand D. Geochimica Cosmochimica Acta 71 (2007) 354-362 Sr/Ca Mainly controlled by water temperature Slide 14 Field calibration: Gulf of Aqaba (Jordan), Porites Slide 15 Consistent and reliable record of SST Slide 16 Anthropogenic record Slide 17 Bomb Radiocarbon as a chronometer and as a ventilation tracer Simulated Surface Ocean Response 1951 1971 1991 Atmospheric Forcing 14 C Slide 18 Slide 19 14 C as a tracer of equatorial wind- induced upwelling Wind induced upwelling Radiocarbon signal Rodgers et al. 2003 -73 to -80 14 C of Sub-Antarctic Mode Water (SAMW) 80N 40N 20N 20S 40S 80S EQ 150E150W90W Equatorial UnderCurrrent (EUC) Slide 20 Galapagos EUC Normal 14 C Normal entrainment of SAMW Slide 21 Palmyra atoll ( 6N 162W ) Slide 22 Palmyra P10 TOPBOTTOM Slide 23 Slide 24 CO 2 graphite H 2 on Fe @ 560 o C Isotopic fractionation normalized to a 13 C = -25 14 C = - 1 1000 () ( 14 C/ 12 C)sample ( 14 C/ 12 C)standard [ ] Coral CaCO 3 Acidification AMS 14 C by Accelerator Mass Spectrometry (AMS) Slide 25 14 C in Pacific corals Druffel (1987); Druffel et al (2001); Druffel-Rodriguez et al (2011) 14 C Slide 26 14 C in Palmyra coral show Suess effect of -7 14 C There is no apparent correlation between 14 C and 18 O values. So 14 C values at Palmyra are invariant with climatic parameters, such as ENSO, during the 20 th century. Druffel-Rodriguez et al (2011) Slide 27 14 C in Pacific corals - Suess Effect 2 sigma High upwelling Low upwelling Druffel-Rodriguez et al (2011) Slide 28 Galapagos: Urvina Bay (0- 91W) Slide 29 Stuiver and Quay 1980 Robertson et al 2001 Druffel et al. 2007 | 2 sigma Seasonal time-series Co-occurrence of low 14 C water and Volcanic Activity Slide 30 Seasonal 14 C - Galapagos Pure SAMW? | 2 sigma El Nios Slide 31 Galapagos Sub-Antarctic Mode Water (SAMW) Equatorial Undercurrent Slide 32 Galapagos EUC Normal 14 C Normal entrainment of SAMW Slide 33 Galapagos EUC Lowest 14 C Increased entrainment of SAMW (early 1600s and 1800s) Slide 34 Republic of Palau Slide 35 Grottoli, 2006 Slide 36 Ulong Channel (>200 years!) Cold/saline Warm/fresh Cold/saline Slide 37 W longitude 6090 120 0 30 60 * Lima 020406080100120 N Dissolved oxygen (% saturation) 100 m depth Chlorophyll-a concentration (mg m -3 ) Peruvian continental margin characteristics Sediments without bioturbation Slide 38 Laminated cores Cores with laminated sequences were collected south of 8S, within the OMZ (