WJ_1992_05_s195

Embed Size (px)

Citation preview

  • 8/10/2019 WJ_1992_05_s195

    1/6

    Effect of Welding Variables on Cracking inCobal t -Based SMA Hardfacing Deposi ts

    Investigation focuses on establishing guidelines for depositingcrack-free hardfacing weld metal

    B Y R. V. S H A R PL E S A N D T. G . G O O C H

    n t r o d u c t i o n

    Weld deposit ion of hardfacing al loyss co m mo nly em ploy ed to increase theerv ice l i fe of components subjec t tobras ive wear. A number of a l loys a re

    ommerc ia l ly ava i lab le , based la rge lyn i r o n , n icke l or cobal t mat r ices , andffering various properties in the depositRefs. 1, 2). In general, greater life is oba ined for many appl ica t ions by us ingeposits of higher hardness, this beingbtained via the presence of hard secnd-phase part icles, especially ca rbides,n the matrix. However, at high hardnessevels, the tensi le ducti l i ty of the hard-acing is reduced and crack ing can oc curs a result of we ldin g co ntrac tion strain.uch cracking does not necessari ly s ig

    nificantly reduce the service wear life ofhe com pon ent, and indeed is sometimeseen as an advantage in reducing resid

    ual stress levels (rel ief checking).Nonetheless, in many instances, crackng i s undes i rab le , whether to obta in aealing surface or to avoid fat igue f a i l

    ure, for example, and a requirement exs ts for depos i t ion of c rack-f ree , h igh-

    hardness surfacing.Cracking can arise ei ther in the solid

    tate because of low tensile ducti l i ty orur ing so l id i f ica t ion . The la t te r mecha

    nism of c racking can normal ly be overome by reducing travel speed, with aten t ion to a rc ex t inc t ion procedure tovoid c ra te r c racking , bu t the formerrack type represents a rather more inrac tab le problem in hardfac ing a l loys .

    Essentially, the incidence of cracking cane related to the tensi le ducti l i ty of the

    depos i t , and hence , to it s com pos i t ionnd hardness . Whi le c racking can bevoided by se lec t ion of an a l te rna t ive

    R. V. SHARPLES and T G. GOOCH are withThe W elding Institute, Abington Hall, Abingon, Cambridge, U.K.

    Paper presented at the 72nd Annual AWSMeeting, held April 14-19, 1991, in Detroit,Mich.

    consumable composi t ion , th i s wil l genera l ly invo lve a redu ct ion in depos i thardness , wh ich m ay be unacc eptab lein te rms of serv ice proper t ies . Wheresuch a mate rial change is inap plica ble ,the most common preventat ive measure

    is to apply preheat (Refs. 1, 2) , on thebasis that the cooling rate after weldingcan be reduced wi th a concom itant reduc t ion in the d i ffe ren t ia l co nt ra c t ionstrain between the clad ding and the substrate. Howeve r, f ew quan t i t a t i ve da t ahave been, published on the effects ofweld ing condi t ions on the c racking (orserv ice) behavior of weld-depos i tedha rdf ac ing (Ref. 3); thus , unless pr iorpractical experience exists , substantialp roce du re deve lopmen t i s commo n lynecessary to achieve crack-free hardfacing.

    The present program was ini t iated toexamine the e ffec ts of vary ing weld ingcondit ions on the cracking sensit ivi ty ofweld-dep os i ted hardfac ing . A par t icu larobjec t ive was to explore the feas ib i l i tyof producing nomograms afford ing general guidance on welding procedures toavoid cracking with different hardfacingal loys so tha t proce dura l d eve lopm enttr ials can be minimized. Shielded metalarc (SMA) welding was chosen to makedepos i t s on s tee l us ing consumablesmeet ing AWS A5.1 3 ECoCr-B specif icat i o n , an exc e l len t hardfac ing a l loy but

    K E Y W O R D S

    ECoCr-BHardfac ing A l loysWelding Var iab lesCrackingTensile Ducti l i tyNomogramsS M AWCo-Based Consumable

    Wear ResistanceAbrasive Wear

    one known for i ts tendency to crack onc o o l i n g . This combina t ion of processand material is wi de ly used in hardfacing applications, especially on site.

    A p p r o a c h

    In essence, the risk of cracking in thehard fac ing is govern ed by the tens i leduct i l i ty of the depos i t and by the applied shrinkage strain (Refs. 2, 3) . Theforme r is depe nde nt on the mater ia lcomposit ion and microstructure, and thela t te r on composi t ion and weld ing c o ndit ions, especial ly, from practical exper ience, on the preheat level (Ref. 3). Testswere therefore car r ied out vary ing depos i t d i lu t ion and prehea t tempera ture ,changes i n d i l u t i on a nd c ompos i t i onbeing achieved by a l te r ing the weld ingcurrent with single- and double-layer deposit ion.

    Test welds were deposited circumferential onto a steel bar of 1 00- mm (4-in.)d i a me te r and 30 0 -mm (1 2-in.) len gth .This geometry was selected as constituting a semi-infinite heat sink of fairly highrestraint . Prel iminary tests showed thatd i ffe rent ia t ion could be made be tweenthe incidence of cracking in the ECoCr-B deposits produ ced w ith varyin g w e l ding current .

    Ex pe r i men t a l P rocedu r e

    Materials

    The hardfacing material used was inthe form of SMA elec t rodes of 4-mm(0.1 6-in.) diameter, obtaine d to the AW SA5.13 ECoCrB spec i f ica t ion . The substrate bar ma terial was 0.4 % ca rbon steel080 A42 (Ref. 4) (Table 1), as representa t ive of components for which suchhardfac ing might be em ployed in practice.

    Deposition and Welding Conditions

    Depos i t s were made manual ly bywelding in the f lat posit ion onto the bar

    W E L D I N G R E S E AR C H S U P P L E M E N T I 195-s

  • 8/10/2019 WJ_1992_05_s195

    2/6

    Ta b l e 1Mater ia l Analys is

    M a t e r i a l Fe C S

    ECoCr-B< a > 2 . 38 1 .70 - ( c >080A42< b > Ba l 0 . 41 0 . 021

    P

    (c)

    0 . 0 1 2

    E lemen t (w t - )

    Si M n N i

    1.02 -< c > 2 . 4 70 . 1 9 0 . 8 2 0 .2 2

    Cr

    31 . 50 . 2 3

    M o

    0 . 2 00 . 0 7

    Cu

    (c)

    0 . 2 4

    Co

    Bal0 .0 2

    W

    8 . 7 0(c)

    (a) Manufacturer's analysis.(b) TWI Ref. No. S/85/205.(c) Not determined.

    Table 2 Summary of Effects of WeldingConditions on Incidence of Cracking in theDeposited Hardfacing

    P r e h e a t C u r r e n t

    Q

    20

    40

    70

    100

    150

    200

    250

    100250300200

    (a) Cracked

    (A)

    100120150100150120150100120150100120150100150120150100100160100

    (b) Not cracked.(c) No t d ete rmrned.

    NominalHeatInput

    (k ) /mm

    11.21.611.61.21.611.21.611.21.611.61.21.6111.81

    1st

    C ,

    N CN CCN CNCN CNC,N CN CNCN CNCNCN CN CN CC(c)

    NC_ ( c )

    C r a c k i n g

    L a y e r 2 n d t a y e r

    NC< b>

    C

    C, CCC

    ccccc, ccccccC N C

    cNCNC (c)

    C(c)

    NC

    rotat ing at a surface {i.e., t ravel) speedof 130 mm/min (5 in. /min). Single-layerdepos i t s cons is ted of three beads wi tha p p r o x i m a t e l y 2 5 % ove r l a p be tweene a c h , and for dou ble- la yer sa mples , afurther two beads were dep osited on theoriginal three beads.

    Welds were made a t prehea ts ranging fro m 20 to 30 0C (68 to 572 F) fo rcurrents between 100 and 160 A at voltages between 21 and 24 V, as summarized in Table 2. W eld ing was p erformedusing DC, electrode posit ive condit ions.In most cases, the same nominal conditions were used for both layers. The preheat was applied by placing the test barin a furnace at the required temperature,and i t was m ain tain ed as an interpasstempera ture for depos i t ion of ad jacentbeads . On comple t i on o f we l d ing o feach layer, the tes t p iece was a l lowedto cool in air to room tem perature. Sometests under specif ic condit ions were repeated to clarify behavior as necessary.

    Thermocouples were harpooned in tothe 3rd and 5th bead weld pools duringdepos i t ion , and the cool ing cyc le downto about 1 00C (21 2F) wa s r ec o rded .Co olin g rates from 80 0 to 500C (1472to 932F) we re de t e rmined . Th i s c o o ling parameter was taken as corresponding to a temperature range close to thata t wh ich c r a c k ing comm enc e s d u r ingcooling (Ref. 2), and because data exist(Refs. 5, 6) to pred ict the effect of cha nging weld ing condi t ions , jo in t hea t s ink ,etc. , on the deposit cooling cycle.

    Examination

    Cracks were detected both aurally asthey occurred during ini t ial cooling andby dye penetrant testing carried out afterdepos i t ion of the 3rd bead and aga inafter the f inal run. Sections were takenf rom depos i t s , moun te d , g round andpolished to a 1 pm finish. They were examined under an opt ica l microscope to

    assess de pos it mic ros truc ture and as afurther check on the incidence of cracking.

    To de termine the ex tent of d i lu t ion ,the amount of iron present in the depositwas measured by using energy dispersive x-ray analysis in conjunction with ascanning electron microscope. Analyseswere taken in each of beads 3 and 5.

    Hardness measurements on t ransverse sections were made using a Vickers pyra mida l d iam ond indentor unde ra load of 5 kg.

    Results

    Material Microstructure andCracking Behavior

    Figures 1 and 2 show represen tat ivedeposits and cracking. Both the first andsecond layers showed pr imary so l id i f icat ion to the metall ic a-phase, with subsequent formation of interdendri t ic carbides, as in Fig. 3. The carbide contentin the second layer was, however, verymuch higher than in the first beads.

    The cracking observed was v i r tua l lyall t ransverse to the weld bead, roughlyperpendicular to the substrate, and hadformed apparent ly randomly a long thedepo s i t (F igs . 1 , 4 ) . The cra cking occurred wi th negl ig ib le p las t ic s t ra in inthe matrix, and developed along the carb ide phase . No so l id i f ica t ion crackingwas observed.

    In addi t ion to c racking in the depos i ted bead , fus ion l ine and hea t -a ffec ted zone (HAZ) , hydrogen cracking

    Fig. 1 View of test weld: 1 kj/mm and 10CPC preheat.

    Fig. 2 Transverse section through test weld: 1.2 kj/mm and 150Cpreheat.

    1 9 6 - s I M A Y 1992

  • 8/10/2019 WJ_1992_05_s195

    3/6

    ig. 3 Microstructure of test weld in Fig. 1, 320X. A Third run; B fifth run.

    a s o b s e r v e d . F i g u re 5 s h o w s c r a c k i n gn i t i a t e d at t h e d e p o s i t t o e i n a s a m p l er o d u c e d a t 1 k j / m m (25 k j / i n . ) a nd 40C

    104F) p r e h e a t . T h e H A Z c r a c k s w e r ef t h e t o e a n d u n d e r b e a d t y p e l y i n g

    o u g h l y p a r a l l e l t o t h e w e l d i n g d i r e co n , t h e f o r m e r s o m e t i m e s b e i n g a s s o

    i a t e d w i t h c r a c k i n g i n t h e c l a d d i n g m ae r i a l . C r a c k i n g a p pe a r e d p r e d o m i n a n t l yn t e r g r a n u l a r , a n d w a s l a r g e l y c o n f i n e do t h e t r a n s f o r m e d H A Z . T h e H A Z m ir o s t r u c t u r e p r o d u c e d b y t h e f i rs t l a y e ra r i e d f r o m f u l l y m a r t e n s i t i c i n t h e d eo s i t s w i t h th e m o s t r a p i d c o o l i n g t o

    m i x e d h i g h e r t e m p e r a t u r e t r a n s f o r m ao n p r o d u c t s at t h e l o n g e r c o o l i n g t i m e s .h e H A Z c r a c k s w e r e o b s e r v e d o n l y i n

    h e m a r t e n s i t i c m i c r o s t r u c t u r e s .

    ffect of Welding Conditions

    A s u m m a r y o f t h e e f f e c t s o f c u r r e n tn d p r e h e a t o n d e p o s i t c r a c k i n g i s g i v e nn Ta b l e 2 . F o r b o t h l a y e r s , c r a c k i n g i nh e h a r d f a c i n g w a s r e d u c e d b y i n c r e a sn g c u r r e n t o r p r e h e a t t e m p e r a t u r e , a n dr a c k i n g o c c u r r e d m a i n l y i n t h e s e c o n da ye r, r equ i r i n g a subs t an t i a l i nc r ea s e i nr e h e a t l e v e l f o r i ts a v o i d a n c e . A s i l l u s

    r a t e d i n F i g . 6 , c o o l i n g t i m e s f r o m 8 0 0 o 500C (At a _ 5) i n c r e a s e d a t h i g h e r p r e

    h e a t t e m p e r a t u r e s , e s p e c i a l l y w i t h p r eh e a t t o a b o v e 2 0 0 C ( 3 9 2 F ) . N o p a r t i cu l a r d i f f i c u l t i e s w e r e e x p e r i e n c e d w i t hs l a g r e m o v a l , a n d t h e re w e r e n o i n d i c at i o n s t h a t r e s i d u a l s l a g c o n t r i b u t e d t o

    c r a c k i n g i n t h e s e c o n d l a y e r.T h e H A Z c r a c k i n g o c c u r r e d o n l y i n

    d e p o s i t s p r o d u c e d w i t h p r e h e a t l e v e l su p t o 1 0 0 C . R e s u l t s o f h a r d n e s s m e as u r e m e n t s o n t y p i c a l c r a c k e d a n d u nc r a c k e d H A Z s a r e g i v e n i n Ta b l e 3 . T h eh i g h e s t h a r d n e s s w a s f o u n d w i t h 2 0 Cp r e h e a t , b u t , e s p e c i a l l y i n t h e o t h e rw e l d s , i t m u s t b e p r e s u m e d t h a t s o m et e m p e r i n g a n d s o f t e n i n g f r o m t h e as -w e l d e d h a r d n e s s h a d o c c u r r e d d u r i n gs u b s e q u e n t p r e h e a t i n g a n d d e p o s i t i o no f t he s ec ond l aye r.

    Dilution

    D i l u t i o n a s a s s es s e d b y t h e i r o n c o nt e n t o f t h e d e p o s i t i n c r e a s e d w i t h i nc r e a s i n g c u r r e n t a n d , t o a le s s e r e x t e n t ,p r e h e a t F i g . 7 . T h e d e p o s i t h a r d n e s sm e a s u r e m e n t s a r e p l o t t e d a g a i n s t d i l ut i o n i n F ig . 8 . Ha rdn es s f e l l a t h ig he r d il u t i o n l e v e l s . N o e v i d e n c e o f d e p o s i tc r a c k i n g a r o u n d h a r d ne s s i n d e n t a t i o n sw a s s e e n .

    D i s c u s s i o n

    Effect o f Welding Conditions

    C r a c k i n g o c c u r s i n a d e p o s i t as a re

    su l t o f t he s t r a i n s s e t up n o t on ly by u ne q u a l c o o l i n g r a te s w i t h i n t h e d e p o s i t ,b u t a l s o b y a n y e x p a n s i o n m i s m a t c h b et w e e n d e p o s i t a n d s u b s t r a t e . In t h e c a s eo f h a r d f a c i n g , t h e p r o b l e m i s e x a c e rb a t e d b y t h e h i g h m a t e r i a l s t r e n g t h o v e ra r a n g e o f t e m p e r a t u r e s t h a t r es i s ts a cc o m m o d a t i o n o f s h r i n k a g e s tr a i n . I t f o ll o w s t h a t a n y d e g r e e o f d i l u t i o n o f aE C o C r - B o r s i m i l a r a l l o y b y a s t e e l s u b -

    Table 3Representative Results of HAZHardness Measurements

    Nominal MaximumHeat HAZ

    Preheat Cu rrent Input HA Z Hardness(C) (A) (kj/mm) Cracking HV5

    20 100 1100 100 1150 100 1300 160 1.8

    C 473C 349N C 289NC 317

    (a) Vickers hardness wi th 5 kg indent ing load.(b) C ra ck ed .(c) Not cracked.

    ig. 4 Typical deposit cracking, 100X. Fig. 5 - HAZ cracking from deposit toe, 50X.

    W E L D I N G R E S E A R C H S U P P L E M E N T I 1 9 7 - s

  • 8/10/2019 WJ_1992_05_s195

    4/6

    25

    20 -

    S 15

    1 h

    cncoo 5 =

    1

    D = 1.6kJ/mm

    D aa

    ^n Q a ^ . ^B .

    9

    1

    ^- - _ ' ,,

    i

    ^ ^

    i

    / // /

    a S /' //

    y Y

    ^

    i

    100 200P r e h e a t t e m p e r a t u r e , C

    300

    40

    30

    20

    10

    n

    i iP r e h e a t = 20Co = 100*Ca = 250T

    // D

    //

    y

    ^ - ^ s

    i i

    i

    /y

    First -l a y e r ,

    yy

    Second jjLayer , '

    i

    100 120 140C u r r e n t , A

    160

    Fig. 6 Effect of preheat temperature on deposit cooling times, 800-500C, for 1 Fig. 7 Effect of current on dilution, measu red as ironand 1.6 kj/mm, with bounding lines. content of the deposit.

    0

    Fig. 8 -

    20Iron c o n t e n t , %

    Effect of deposit dilution, measu red as iron content, on hardness.

    25 -

    20 -

    n

    cu

    eC

    oo

    15

    10 -

    5 -

    1

    - o = F i r s t

    1

    l aye rQ = Second lay erSol id symb

    D

    ,

    **~ __ n __

    V. #

    i

    ol s = c rac k ing

    *1\

    .4 *0 0: \ o

    \\

    0

    o

    8 o

    o

    o

    -

    -

    10 20 30% iron in deposi t

    40

    Fig. 9 Effect of cooling time from 800 - 500 C ondeposit cracking.

    198-s I MA Y 1992

  • 8/10/2019 WJ_1992_05_s195

    5/6

    ra te w i l l be par t ic u lar ly imp or tan t invoiding cracking because dilut ion botheduces composi t iona l (and to a la rgextent expans ion) mismatch and a lsoakes a softe r and more a ccom mo dat

    ng depos i t by decreas ing the carb ideontent . In pr inc ip le , the overa l l s i tuaon is made more complex when a secnd layer of deposit is added becauseomposi t iona l d i ffe rences be tween the

    ew layer and its substrate be com emuch less, but so does the degree of acom mod at ion requi red . In addi t ion , misatch strains generated in the first layeri l l , to some extent , be t ransmi t ted to

    he second layer, but the concept of to lrance to shrinkage strains being deter

    mined by dilut ion should remain val id.I t was further argued above that the

    ffective applied strain and hence crackng risk is influenced by preheat levelnd subsequent cool ing ra te . Cer ta in lyhis is indicated by practical experiencei th the proviso that a genera l prehe at

    applied to the substrate so that severemperature gradients do not exist.On this basis , the present data were

    lotted as in Fig. 9, considering dilu t ionnd cool ing condi t ions . I t can be seenhat a bounding curve can be identif ied,i v id ing c r a c k e d a n d unc rac ke d d eos i t s . There would seem to be a d isnc t ion be tween the f i r s t and second

    ayer results, as discussed further be low ,ut it is considered that a diagram of thisype could well form the basis for aomogram sy s t em t o de f i ne we ld ingondit ions giving crack-free deposits .

    Such a no m ogr am s hou ld b e ap p l iab le to hardfac ing sys tems genera l ly,nd not only to the ECoCr-B consumbles ut i l ized in the present work. Howver, the practical usage of data in theorm of Fig. 9 wil l require con siderat ionf a number of aspects of behavior. Inhe f irst instance, the control of di lut ion par t icu lar ly impo r tan t in hardfa c ing

    s it markedly affects the wear and corosion resistance of the deposit (Refs. 3, 7). Low levels of iron dilution may be

    cc ep table (as is the case w ith ECoCr-), but in general , the greater the per

    entage of iron in a hardfacing layer, theoorer i ts proper t ies wi l l be . The t enency for increased dilution to decreasehe l ike l ihood of c racking may lead tohe use of we ld i ng cond i t ions caus ingigher d i lu t ions than are compat ib lei th the serv ice condi t ions of the comonen t , wh en m a x i m u m p e r fo rm a nc e

    will not be given by the hardfacing deosit . Hence , wh en e mp loy ing Fig. 9, aec ision must be taken as to the perm isible di lut ion level . If , for example, deosit hardness can be taken as a usefuluide to the resistance of a surface unergoing low- load abras ive wear (Ref .), data as in Fig. 8 may be applicable,ut will need to be generated for partic-

    300 200 100P r e h e a t t e m p e r a t u r e , C

    10 20 30 40% iron in deposit

    Fig. 10 Proposed nomogram for derivation of SMA welding conditions giving a specified

    iron content in the deposit, with no brittle hardfacing cracking.

    ular hardfacing/substrate combina t ions .It will be necessary also to define the

    c oo l i n g r a te a nd d i l u t i on ex pe r i en cedin any par t icu lar hardfac ing opera t ion .Some guidance on the lat ter is given inFig. 7 , bu t c lear ly more informat ion i sneeded. In regard to coo ling rate, a number of nomograms exist (Refs. 5, 6) forp r ed i c t i on o f A t8 . 5 . For infini te heatsinks, and using the bounding l ines fromFigs. 6 and 9, i t is possible to develo p anomogram cons t ruc t ion as in F ig . 10,

    whereby the cool ing ra te necessary toavoid c rack ing a t the requi red d i lu t ionis directly related to we ldin g co ndit ions .

    At present, the nomogram must be regarded as on ly a tentat ive pro posal , andsubs tantially mo re testing is essential todef ine i t s prac t ica l v iab i l i ty. In dee d , anumber of reservations must be expressed. First , Fig. 9 was obtained for aspec i f ic mater ia l /weld ing process combina t ion and for only one consumableb a t c h ; whereas, other hardfacing al loysmust be expec ted to show a d i ffe rentcracking response with changes in d i l ut i o n , depending on the composi t ion inv o l v e d . Further, the use of dilution as aninput presupposes tha t process andwe l d ing c ond i t i ons i n f l uence c r ack ingo n ly by de t e rmin ing t he de p th o f subs t ra te penet ra t ion . For prac t ica l purposes, this may be true but appropriatestudy of such welding variables is requi red . Moreover, it is assumed that thecracking test piece geometry used is relevant to service. Even if this is the case,Fig. 10 is limited to substrate geometrieswh ich ac t as a sem i- inf in i te hea t s inkand a l low no accommodat ion of res idual stresses by distortion. In this last respect , the nom ogram wi ll err on the c o nservative side.

    Hardfacing Cracking Behavior

    The very high strength and low ducti l i ty of the deposit from ECoCr-B electrodes, and i ts great sensit ivi ty to d i l ut ion , dominate the behavior of a depositalmost to the exclusion of other factorsand are respons ib le for the somewhatdifferent response of the f irst and secon d layers. It was diff icu lt to generatecracks in the first layer, but the c rack/no-crack boundary appears to approach a

    near-ver t ica l l ine . This impl ies tha t d ilu t ion was the main fac tor inf luencingcrack format ion in the f i r s t l ayer, p resum ably via its effect on the carbid e cont en t , and tha t about 20% was the c r i t ical leve l , irrespective of coolin g rate insofar as this was an inde pen de nt v a r ia b l e . Thus, from Fig. 8, any f irst layerdeposit with a hardness below say 450HV would be expected to be crack-freea lmost wi thout regard to i t s condi t ionsof deposit ion, noting that only one c o nsumable was tested and given that thepresent level of restraint was sufficient

    to represent a wor st case. In prin cip le,depos i t c r ack in g cou ld b e i n f l uencedalso by the volume expans ion assoc ia ted wi th t ransform at ion to m ar tens i tein the subs t ra te . However, s ince c o o ling rate had l i t t le effect on f irst layercracking (Fig. 9) , such an effect is unlikely to be of particular significance.

    On the other hand, di lut io n of the second layer was restr icted to low levels.H e r e , t he c r ack /no - c r ac k bounda rywould appear to be near ly hor izonta l ,that is , cooling rate was the controll ingfactor with dilut ion having much less effect . I t is dif f icu lt or im pos sible toachieve such low di lu t ion in a s inglelayer with the SMA process, but this is

    W E L D I N G R E SE A RC H S U P P L E M E N T I 199-s

  • 8/10/2019 WJ_1992_05_s195

    6/6

    QJC L

    QJc_

    Q _

    200

    150

    100

    50

    i I

    Increasing parent metalhardenabil i ty or weldmeta l hydrogen leve l '

    v /

    \ '\ /

    //

    /(b) / 1

    /i i

    l

    N7

    a) /

    i

    1 1oo

    /

    / Reducing parent metalhardenabil i ty or weldmetal hydrogen level

    M

    0 0 1 0.5.2 0.3 0.4Carbon conten t , %

    Fig. 11 Guide to preheat temperatures using austenitic SMA electrodes at about 1 to 2 kj/mmto avoid HAZ hydrogen cracking when welding ferritic steels Ref. 10 . A tovv restraint; B high restraint. The present results are indicated as: = not cracked, = cracked.

    readi ly obta ined wi th a l te rna t ive deposit ion methods, for example, by plasmatransferred arc surfacing (Ref. 8), and as tudy of low-di lu t ion f i r s t l ayers produced by other processes is necessaryto indicate the general applicabil i ty (orotherwise) of Figs. 9 and 10.

    I t should also be noted that the present inves t iga t ion has conce nt ra ted onbr i t t le , so l id-s ta te c racking . Sol id i f icat ion cracking was not found to be a part icular problem, but may require furtherat tention in ECoCr-B deposits at veryhigh d i lu t ion leve ls or in a l te rna t ivehardfacing materials .

    Heat-Affected Zone Cracking

    The loca t ion and morphology of theHAZ cracking observed indica te th i ss tems f r om h yd ro g e n em br i t t l emen t .Clear ly, th i s problem must be recognized in any scheme in tended to g iveguidance on weld ing procedures for production of crack-free hardfaced compo

    nents. Vi r tua l ly no da ta ex is t on w eldmeta l hydrogen leve ls assoc ia ted wi thcobalt-based consumables, but in termsof hydrogen solu bil i ty and diffusion rate,a c lose para l le l can be dra wn wi thaustenitic stainless steel and nickel alloyelectro des (Ref. 9). The risk of HA Z h ydrogen cracking us ing s ta in less s tee lconsumables was d iscussed by Gooch(Ref. 10) in terms of base metal transforma t ion beh av io r a nd consumab le hydrogen level , and i t is considered probable that the guidelines proposed wouldbe generally applicable to cobalt-basedSMA electrodes as presently employed.

    The maximum HAZ hardness in Table3 of over 470 HV is high enough to en

    gender s igni f icant sens i t iv i ty to hydrogen cracking. In plain carbon steels suchas 080 A4 2, some cont ro l over H AZ m icros t ruc ture and hardness can beachieved by vary ing we ld ing condi t ions .However, in SMA hardfac ing , the hea tinput emp loyed may be restr icted by theneed for pos i t iona l weld ing . In suchcases, rel iance must be placed on theuse of prehea t , espec ia l ly to a l low hy

    drogen diffusion away from the depositwh ile the material is at sufficien tly hightemperature for hydrogen embrit t lementto be negligible. In this regard, referencecan be made to Fig. 1 1 , d e r i v ed f r omwelds in t ransformable fe r r i t ic s tee lsm ad e u s ing au s t en i t i c SMA consumables. The present HAZ cracking resultsare shown, and i t can be seen that theobserved beh avior is pred icted we ll bythe diagram.

    S umm ary an d Conc lu s ions

    Study has been carried o ut on the sensi t ivi ty of weld deposited hardfacing tocracking stemming from low tensi le ducti l i ty of the deposit . Cobalt-based al loyto AWS A5.1 3 Grade ECoCr-B was depos i ted o nto a 0 .4% C s tee l by theshie lded m eta l a rc process , wi th v arying current and preheat levels . The fo llowing conclusions were reached.

    1) Cracking in the hardfacing was reduced by increasing current and preheattempera ture for both s ingle- and two-layer deposits.

    2) Sensit ivi ty to deposit cracking wassubstantial ly higher in the second layerthan the f irst , as a result of lower d i l ution and higher deposit hardness.

    3 ) B ound ing cond i t i o ns fo r depos i tc racking were def ined in te rms of depos i t d i lu t io n and coo l ing ra te . The approa ch is proposed as a basis for a no m ogram system to predict the risk of cracking in d i ffe rent hardfacing/substratecombinat ions .

    4) For the par t icu lar e lec t rodes andsubstrate steel s tudied, cracking of f irstlayers was avoided by selection of w e l ding condi t ions g iv ing over 20% d i lu t ion :prevent ion of c racking in the secondlayer required a we ldin g proced ure suchthat a co olin g t ime from 800 to 500Cabove 20 s was obtain ed.

    5) Heat -affec ted zone hydrogencracking was observed . I t i s p robabletha t ex is t ing guide l ines for the avoidance of such cracking us ing aus ten i t icstainless steel electrodes are applicablealso to cobalt-based consumables.

    AcknowledgmentsThe authors thank their colleagues at

    The W el d in g Inst i tute for assistance in

    the course of the pro gram . Part icular a ckno wled gm ent is made to D. N. N oblefor in i t ia t ing the pro jec t , to Dr. I. A .Bucklow for advice, to C. S. Hunt for directing the welding, and to N.) . Tebbit ,G. H . D ixo n and J. E. Clark for carry ingou t t he ex pe r i men t a l w o rk . The workwas jointly funded by research membersof The Welding Inst i tute and the Minerals and Metals Division of the U.K. Department of Trade and Industry.

    References

    1. Gregory, E. N. 1980. Surfacing by welding alloys, processes, coatings and materials se lection. Met C on 12(12): 685-6 90.

    2. Mathew, M. D., Mannan, S. L, andGupta, S. K. 1980. Influence of preheat temperature on stellite deposits. Welding journa l 59(7): 213-s to 216-s.

    3. Noble, D. N. 1 985. Abrasive wear resistance of hardfacing we ld d eposits. Met Con17(9): 605-611.

    4. British Standard 970, Part 1: 1 983.5. Defourny, J., and Bragard, A. 1975.

    Characterization of the thermal cycles in thesubmerged arc butt welding of steel plate bymeans of two parameters of the thermal field.Rev de la Soud/Lastijdscht 31 (3): 124-1 32.

    6. Berkhout, C. F., and van Lent, P. H.1968. The use of maximum temperature-cooling time diagrams (STAZ) in the w eldingof high-strength steels. Schw eis und Schneid20(6): 256-260.

    7. Noble, D. N. 1987. The role of fluxcored arc welding conditions on wear resistance of iron-based hardfacing alloys. Second International Conference on Surface Engineering, Stratford upon Avo n, England.

    8. Harris, P., and Smith, B. 1983. Factorial techniques for weld quality prediction.Met Con 15(11): 661-66 6.

    9. Smithells Metals Reference Book. 1983.E. A. B randes, ed., 6th Ed ition, B utterworth& Co. (publishers) Ltd., Londo n, England.

    1 0. Gooch , T. G. 1 980. Repair w eldingwith austenitic stainless steel MMA electrodes. Met Con 12(11): 622-631.

    2 0 0 - s I M A Y 1 99 2