CHEMICAL SAFETY
DATA SHEETS
For staff & subscribers of:
EMPIRIBOX LTD
Dated: March 2018
Review Date: August 2018
Contents
Ethanoic Acid ............................................................................................................................................... 1
Sodium Hydrogen Carbonate ....................................................................................................................... 2
Copper Sulphate .......................................................................................................................................... 3
Ethanol ........................................................................................................................................................ 4
Hydrochloric Acid......................................................................................................................................... 5
Hydrogen Peroxide ...................................................................................................................................... 6
Nitric Acid .................................................................................................................................................... 7
Potassium Iodide ......................................................................................................................................... 8
Potassium Permanganate ............................................................................................................................ 9
Propanone ..................................................................................................................................................10
Sodium Hydroxide ......................................................................................................................................11
Sulphuric Acid .............................................................................................................................................12
Calcium Hydroxide ......................................................................................................................................13
Boric Acid ...................................................................................................................................................14
Calcium Carbide ..........................................................................................................................................15
Calcium Chloride .........................................................................................................................................16
Calcium Oxide .............................................................................................................................................17
Copper Sulphate .........................................................................................................................................18
Ethanol .......................................................................................................................................................19
Methanol ....................................................................................................................................................20
Methylene Blue ..........................................................................................................................................21
Potassium Hydroxide ..................................................................................................................................22
Propan-2-ol.................................................................................................................................................23
Sodium Polyacrylate ...................................................................................................................................24
Ammonium Chloride ...................................................................................................................................25
Ammonium Dichromate .............................................................................................................................26
Barium Hydroxide .......................................................................................................................................27
Ammonia Solution ......................................................................................................................................28
Zinc Nitrate .................................................................................................................................................29
Phosphoric Acid ..........................................................................................................................................30
Magnesium Hydroxide ................................................................................................................................31
Lithium Hydroxide ......................................................................................................................................32
Zinc Hydroxide ............................................................................................................................................33
Copper Carbonate ......................................................................................................................................34
P a g e | 1
Chemical Safety Data Sheet Date Created: 27/02/2018
Ethanoic Acid
Other names: Acetic acid, Vinegar
Formula: CH3COOH
Quantity Provided: 500mls
Storage: Store in a dry place.
Use: Approx. 500mls of ethanoic acid is reacted with 300g of sodium bicarbonate to produce carbon
dioxide gas.
Hazards: Ethanoic acid can irritate the eyes, skin and respiratory tract.
Mitigation: Gloves must be worn as well as safety goggles/glasses.
Unit: Forces Lesson: 7: Air and Water Resistance
Unit: Particle Theory Lesson: 5: Chemical Reactions
Unit: Chemical Change Lesson: 12: Rusting Iron Wool
Spill process: If spilled, the liquid can be mopped up with dry paper towels and disposed of in the waste
paper basket.
Disposal: Any unused ethanoic acid can be disposed of into the waste stream.
In the event of contact with:
Eye Contact: Check for and remove any contact lenses. In case of contact, immediately flush eyes with
plenty of water for at least 15 minutes. Cold water may be used. Get medical attention immediately.
Skin Contact: In case of contact, immediately flush skin with plenty of water while removing contaminated
clothing and shoes. Cover the irritated skin with an emollient. Cold water may be used. Wash clothing
before reuse. Thoroughly clean shoes before reuse.
Inhalation: If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult,
give oxygen. Get medical attention immediately.
Ingestion: Do NOT induce vomiting unless directed to do so by medical personnel. Never give anything by
mouth to an unconscious person. Loosen tight clothing such as a collar, tie, belt or waistband. Get medical
attention if symptoms appear.
Hazard Symbols:
P a g e | 2
Chemical Safety Data Sheet Date Created: 27/02/18
Sodium Hydrogen Carbonate
Other names: Sodium Bicarbonate, Bicarbonate of Soda
Formula: NaHCO3
Quantity Provided: 500g of white powder
Storage: Store in a dry place.
Use: Approx. 300g of sodium bicarbonate is added to about ½ litre of vinegar to produce carbon dioxide
gas
Hazards: Slightly hazardous in case of skin contact (irritant), of eye contact (irritant), of ingestion, of
inhalation
Unit: Forces Lesson: Lesson 7&8: Air and Water Resistance
Unit: Particle Theory Lesson: 5: Chemical Reactions
Unit: Particle Theory: Lesson: 7: Exothermic and Endothermic Reaction
Spill process: Simply brush the powder directly into the waste bin. Ensure the area is completely clean as
the powder can slightly irritate the skin.
Disposal: Can be disposed either directly into the waste bin or into the waste stream.
In the event of contact with:
Skin Contact: Wash with soap and water. Cover the irritated skin with an emollient. Get medical attention if irritation
develops. Cold water may be used.
Inhalation: If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give
oxygen. Get medical attention.
Ingestion: Do NOT induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an
unconscious person. Loosen tight clothing such as a collar, tie, belt or waistband. Get medical attention if symptoms
appear.
Hazard Symbols:
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Chemical Safety Data Sheet Date Created: 27/02/18
Copper Sulphate
Other names: Copper Sulfate, Copper (II) Sulphate
Formula: CuSO4.5H2O
Quantity Provided: 500g
Storage: Keep in a dry place. Children should only have access under adult supervision
Use: A small portion of iron wool is added to 100mls of copper sulphate solution, and the temperature of
the resultant reaction is taken.
Hazards: Harmful if swallowed. Irritating to eyes and skin. Very toxic to aquatic organisms, may cause long-
term adverse effects in the aquatic environment.
Unit: Particle Theory Lesson: 7&8 Exothermic and Endothermic Reactions
Unit: Chemical Change Lesson: 4: Electroplating
Spill process: Use a dry tissue to wipe the area until completely dry. The tissue can be disposed of in the
waste paper bin.
Disposal: Unused or ‘reacted’ copper sulphate solute can be poured into the waste stream.
In the event of:
INHALATION Remove victim immediately from source of exposure. Provide rest, warmth and fresh air. Get medical
attention if any discomfort continues.
INGESTION Immediately rinse mouth and drink plenty of water. Get medical attention immediately!
SKIN CONTACT Immediately remove contaminated clothing. Wash the skin immediately with soap and water. Get
medical attention if irritation persists after washing.
EYE CONTACT Promptly wash eyes with plenty of water or eye wash solution while lifting the eyelids. If possible
remove any contact lenses and continue to wash. Get medical attention if any discomfort continues.
Hazard Symbols:
P a g e | 4
Chemical Safety Data Sheet Date Created: 27/02/2018
Ethanol
Other names: Alcohol, Methylated Spirit
Formula: CH3CH2OH
Quantity Provided: 500mls
Storage: Store in a cool dry place. Should not be placed in direct sunlight or near a source of heat or naked
flames.
Use: 50mls of alcohol is poured into a water-cooler bottle, which is shaken for one minute and the excess
alcohol poured out. The evaporated alcohol vapour is then ignited to produce a characteristic ‘whoosh’
sound and flame.
Hazards: Alcohol is extremely flammable and should be kept away from naked flames except in
recommended use.
Unit: Particle Theory Lesson: 1&2 – Introduction to Particle Theory
Unit: Particle Theory Lesson: 9: Rates of Chemical Reaction
Unit: Chemical Change Lesson: 1: Green Fire
Unit: Chemical Change Lesson: 3: Money to Burn
Spill process: Dry area with a dry tissue until completely dry. Place the tissue into a sealable bag. This can
then be disposed of in the waste paper basket.
Disposal: Unused alcohol can be poured back into the bottle.
In the event of contact with:
Inhalation Remove victim immediately from source of exposure. Provide rest, warmth and fresh air. Get medical
attention if any discomfort continues.
Ingestion Do not induce vomiting. Rinse mouth thoroughly with water Get medical attention.
Skin contact Remove contaminated clothing and wash before re - use. Flush skin thoroughly with water. If irritation or
discomfort occurs obtain medical attention
Eye contact Promptly wash eyes with plenty of water or eye wash solution while lifting the eyelids.If possible remove
any contact lenses and continue to wash. Get medical attention if any discomfort continues.
Hazard Symbols:
P a g e | 5
Chemical Safety Data Sheet Date Created: 27/02/2018
Hydrochloric Acid
Other names: Hydrogen Chloride solution
Formula: HCl
Quantity Provided: 2 litres
Storage: Keep away from children except under adult supervision.
Use: 5mls of HCl is reacted with small pieces of metal and the reactions observed.
Hazards: Corrosive and an irritant to the skin and eyes.
Unit: Particle Theory Lesson: 5&6 – Introduction to Chemical Reactions
Unit: Water, Acids and Alkalis Lesson: Indicators
Spill process: The area must be dried completely with dry tissue and disposed in the waste paper basket.
Disposal: Can be poured into the waste stream.
In the event of:
Inhalation Remove victim immediately from source of exposure. Provide rest, warmth and fresh air. Get
medical attention if any discomfort continues.
Ingestion Do not induce vomiting. Rinse mouth thoroughly with water In case of ingestion of large amounts
or if any discomfort continues obtain medical attention.
Skin contact As a general precaution remove contaminated clothing and wash the skin with plenty of water.
If irritation or discomfort occurs obtain medical attention
Eye contact Promptly wash eyes with plenty of water or eye wash solution while lifting the eyelids.If
possible remove any contact lenses and continue to wash. Get medical attention if any discomfort
continues.
Hazard Symbols:
P a g e | 6
Chemical Safety Data Sheet Date Created: 27/02/2018
Hydrogen Peroxide
Other names: none
Formula: H2O2
Quantity Provided: 250mls
Storage: Should be stored in a refrigerator. Children should not have access at any time. Ensure the lid is
screwed on tightly after use.
Use: 50mls of hydrogen peroxide is reacted with potassium iodide and detergent to produce a foam.
Hazards: Can cause severe irritation to the skin and damage the eyes.
Unit: Particle Theory
Lesson: 3&4 – Solids, Liquids and Gases
Spill process: Gloves should be used at all times. The area must be dried with dry tissue. If possible, put the
tissue in a sealable bag and then can be disposed of in the waste paper basket.
Disposal: Can be poured into the normal waste stream
In the event of contact with:
Inhalation Remove victim immediately from source of exposure. Provide rest, warmth and fresh air. In
case of severe exposure or if any discomfort continues get medical attention.
Ingestion Do not induce vomiting. Rinse mouth thoroughly with plenty of water. Get medical attention
immediately!
Skin contact Remove footwear if contaminated. Immediately remove contaminated clothing and wash
before re-use. Rinse the skin immediately with lots of water. After contact with small amounts get medical
attention if any discomfort continues. For large amounts, obtain medical attention.
Eye contact Promptly wash eyes with plenty of water or eye wash solution while lifting the eyelids. If
possible remove any contact lenses and continue to wash. Get medical attention immediately.
Hazard Symbols:
P a g e | 7
Chemical Safety Data Sheet Date Created: 27/02/2018
Nitric Acid
Other names: none
Formula: HNO3
Quantity Provided: 1 litre
Storage: Store in the tray provided by Empiribox and in a dry cool place.
Use: 5mls of nitric acid is reacted with 4 different metals and the reaction observed.
Hazards: Corrosive and an irritant to the skin, eyes and respiratory tract
Unit: Particle Theory
Lesson: 5&6 – Introduction to Chemical Reactions
Spill process: Dry the area with a dry tissue, and then dispose into the waste paper basket
Disposal: Can be poured down the waste stream
In the event of contact with:
INHALATION Remove victim immediately from source of exposure. Provide rest, warmth and fresh air. Get
medical attention if any discomfort continues.
INGESTION Do not induce vomiting. Immediately rinse mouth and drink plenty of water (200-300 ml). Get
medical attention immediately!
SKIN CONTACT Immediately remove contaminated clothing. Wash the skin immediately with soap and
water. Get medical attention if irritation persists after washing.
EYE CONTACT Make sure to remove any contact lenses from the eyes before rinsing. Promptly wash eyes
with plenty of water while lifting the eye lids. Continue to rinse for at least 15 minutes. Get medical
attention if any discomfort continues.
Hazard Symbols:
P a g e | 8
Chemical Safety Data Sheet Date Created: 27/02/2018
Potassium Iodide
Other names: none
Formula: KI
Quantity Provided: 100g
Storage: Store in the black tray provided by Empiribox. Should be dry.
Use: Approx 5g of potassium iodide is added to 50mls of hydrogen peroxide and detergent to produce a
foam
Hazards: Can irritate the skin and eyes and slight hazard in the case of ingestion or inhalation
Unit: Particle Theory
Lesson: 5&6 – Introduction to Chemical Reactions
Spill process: Area can be cleared with wet tissue which can then be thrown into the waste paper basket.
Disposal: Can be thrown into the waste paper basket
In the event of:
Eye Contact: Check for and remove any contact lenses. In case of contact, immediately flush eyes with plenty of water
for at least 15 minutes. Cold water may be used. Get medical attention if irritation occurs.
Skin Contact: Wash with soap and water. Cover the irritated skin with an emollient. Get medical attention if irritation
develops. Cold water may be used.
Inhalation: If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give
oxygen. Get medical attention.
Ingestion: Do NOT induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an
unconscious person. If large quantities of this material are swallowed, call a physician immediately. Loosen tight
clothing such as a collar, tie, belt or waistband.
Hazard Symbols:
P a g e | 9
Chemical Safety Data Sheet Date Created: 27/02/2018
Potassium Permanganate
Other names: none
Formula: KMnO4
Quantity Provided: 500mls
Storage: Store away from direct sunlight in the black tray provided by Empiribox. Children should not have
access without adult supervision.
Use: 80mls of potassium permanganate is reacted with pieces of rhubarb to produce a ‘dirty green’
solution
Hazards: Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
Unit: Particle Theory
Lesson: 9 & 10 – Speed of Chemical Reactions
Spill process: Wipe the area with a dry tissue until completely dry. There should be no ‘purple’ remaining.
Disposal: The reacted solution can be poured down the drain. Unreacted permanganate should not be
poured down the drain.
In the event of contact with:
INHALATION Remove victim immediately from source of exposure. Provide rest, warmth and fresh air. In case of severe exposure
or if any discomfort continues get medical attention.
INGESTION Do not induce vomiting. Immediately rinse mouth and drink plenty of water. Get medical attention.
SKIN CONTACT Remove contaminated clothing and wash before re - use. Wash the skin immediately with soap and water. In
serious cases or if discomfort continues obtain medical attention.
EYE CONTACT Make sure to remove any contact lenses from the eyes before rinsing. Promptly wash eyes with plenty of water
while lifting the eye lids. Continue to rinse for at least 15 minutes. Get medical attention if any discomfort continues
Hazard Symbols:
P a g e | 10
Chemical Safety Data Sheet Date Created: 27/02/2018
Propanone
Other names: Acetone
Formula: (CH3)2CO
Quantity Provided: 1 litre
Storage: Store away from heat, direct sunlight or naked flame. Children should have access at no time.
Use: Approx. 25mls of acetone is placed in a drinking mug and then expanded polystyrene is introduced.
Hazards: Extremely flammable
Unit: Particle Theory Lesson: 11 & 12. Mass changes in chemical reactions
Unit: Geology, Mixtures and Separation Lesson: 4: Solvents
Spill process: The area should be wiped with a dry tissue until the area is dry. Place the tissue in a sealable
bag and dispose into the waste paper basket.
Disposal: Can be poured into the waste stream
In the event of:
Inhalation Remove victim immediately from source of exposure. Provide rest, warmth and fresh air. In
case of severe exposure or if any discomfort continues get medical attention.
Ingestion Rinse mouth thoroughly with water Do not induce vomiting. Get medical attention.
Skin contact Immediately remove contaminated clothing. Wash the skin immediately with soap and water.
If irritation or discomfort occurs after washing obtain medical attention.
Eye contact Promptly wash eyes with plenty of water or eye wash solution while lifting the eyelids. If
possible remove any contact lenses and continue to wash. Get medical attention.
Hazard Symbols:
P a g e | 11
Chemical Safety Data Sheet Date Created: 27/02/2018
Sodium Hydroxide
Other names: Caustic soda
Formula: NaOH
Quantity Provided: 1 litre
Storage: Store in the tray provided by Empiribox. Children should not have access except under adult
supervision
Use: 10mls of sodium hydroxide is reacted with 10mls of hydrochloric acid and the temperature of the
reaction is taken.
Hazards: Is corrosive and can cause burns to the skin.
Unit: Particle Theory Lesson: 7&8 Exothermic and Endothermic Reactions
Unit: Water, Acids and Alkalis Lesson: 3: Indicators
Spill process: Wipe the area with a dry tissue and then dispose into the waste paper basket.
Disposal: Can be poured into the normal waste stream.
In the event of:
Inhalation Remove victim immediately from source of exposure. Provide rest, warmth and fresh air. In
case of severe exposure or if casualty feels unwell, obtain medical attention.
Ingestion Do not induce vomiting. Rinse mouth thoroughly with water Get medical attention immediately!
Skin contact Remove contaminated clothing and wash before re - use. Wash the skin with copious amounts
of water. If clothing is difficult to remove or stuck to the skin then leave in place and flush affected area
with water. Get medical attention immediately!
Eye contact May cause permanent damage if eye is not immediately irrigated. Promptly wash eyes with
plenty of water or eye wash solution while lifting the eyelids. If possible remove any contact lenses and
continue to wash. Get medical attention immediately. Continue to rinse.
Hazard Symbols:
P a g e | 12
Chemical Safety Data Sheet Date Created: 27/02/2018
Sulphuric Acid
Other names: none
Formula: H2SO4
Quantity Provided: 2 litres
Storage: Store in the tray provided by Empiribox. Children should not have access except under adult
supervision.
Use: Sulphuric acid is reacted with small pieces of magnesium ribbon and the temperature of the reaction
is taken.
Hazards: Corrosive and can cause skin burns
Unit: Particle Theory
Lesson: 7&8 – Exothermic and Endothermic Reactions
Spill process: Wipe the area until completely dry with a dry tissue which can then be disposed in the waste
paper basket
Disposal: Can be poured into the normal waste stream
In the event of:
Inhalation Remove victim immediately from source of exposure. Provide rest, warmth and fresh air. Get
medical attention if any discomfort continues.
Ingestion Rinse mouth thoroughly with water DO NOT induce vomiting. Get medical attention immediately.
Skin contact Immediately remove contaminated clothing and wash before re-use. Flush skin thoroughly
with water. Get medical attention if any discomfort continues.
Eye contact Promptly wash eyes with plenty of water or eye wash solution while lifting the eyelids. If
possible remove any contact lenses and continue to wash. Get medical attention immediately.
Hazard Symbols:
P a g e | 13
Chemical Safety Data Sheet Date Created: 27/02/2018
Calcium Hydroxide
Other names: Slaked lime
Formula: Ca(OH)2
Quantity Provided: 500g
Storage: Keep in a dry place. Children should not have access without adult supervision.
Use: 5g is added to 250mls of water and left for 24 hours. The resultant solution is then filtered and used to
test for carbon dioxide.
Hazards: Corrosive in the event of eye contact and an possible irritant of the skin
Unit: Plants
Lesson: 5&6 – What enters a leaf?
Spill process: Dry wipe the affected area and then wash with clean water
Disposal: Can be poured down the normal waste stream
In the event of:
Eye Contact: Check for and remove any contact lenses. In case of contact, immediately flush eyes with
plenty of water for at least 15 minutes. Cold water may be used. Get medical attention immediately.
Skin Contact: In case of contact, immediately flush skin with plenty of water for at least 15 minutes while
removing contaminated clothing and shoes. Cover the irritated skin with an emollient. Cold water may be
used.Wash clothing before reuse. Thoroughly clean shoes before reuse. Get medical attention immediately.
Serious Skin Contact: Wash with a disinfectant soap and cover the contaminated skin with an anti-bacterial
cream. Seek medical attention.
Inhalation: If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult,
give oxygen. Get medical attention immediately.
Ingestion: Do NOT induce vomiting unless directed to do so by medical personnel. Never give anything by
mouth to an unconscious person. Loosen tight clothing such as a collar, tie, belt or waistband. Get medical
attention if symptoms appear
Hazard Symbols:
P a g e | 14
Chemical Safety Data Sheet Date Created: 27/02/2018
Boric Acid
Other names: Hydrogen Borate
Formula: H3BO3
Quantity Provided: 100g
Storage: Keep in the tray provided by Empiribox and in a dry place
Use: Approx. 5g of boric acid is mixed with methylated spirit, which is then ignited to produce a green
flame
Hazards: Can be toxic if swallowed
Unit: Chemical Change
Lesson: 1&2 Chemical Change
Spill process: Can be removed with a wet tissue which can then be disposed of in the waste paper basket.
Disposal: Can be disposed down the normal waste stream.
In the event of:
Eyes Contact: with the solid or dust may be irritating to the eyes. Rinse with plenty of cold water and if
symptoms persist, seek medical attention.
Skin contact: The solid and solutions may be irritating to the skin. Repeated exposure may cause dermatitis.
Rinse with plenty of cold water.
Ingestion Toxic if swallowed and can cause vomiting and diarrhoea. Drink plenty of water and if symptoms
persist, seek medical attention.
Inhalation Dust may produce irritation of the eyes, nose, throat and respiratory tract. Move to fresh air.
Hazard Symbols:
P a g e | 15
Chemical Safety Data Sheet Date Created: 27/02/2018
Calcium Carbide
Other names: Calcium Dicarbide
Formula: CaC2
Quantity Provided: 100g
Storage: The container should be stored in an area free of humidity and away from moisture of any kind
Use: Approx. 5g of calcium carbide is added to approx. 60mls of water to produce acetylene which is then
ignited
Hazards: In contact with water releases flammable gases (acetylene) which may ignite spontaneously.
Causes severe skin burns and eye damage.
Unit: Chemical Change Lesson: Lesson 5 and 6: Chemical Structures
Spill process: Clear the area with a dry tissue until no calcium carbide remains. Do NOT clean up with a
damp cloth.
Disposal: Once the reaction is complete (there will be no more bubbles produced), the liquid can be poured
into the waste stream
In the event of contact with:
Eyes Irrigate thoroughly with plenty of water for at least 10 minutes, holding the eye open. OBTAIN
MEDICAL ATTENTION URGENTLY.
Skin Wash off skin thoroughly with water. Remove contaminated clothing immediately and wash before re-
use. OBTAIN MEDICAL ATTENTION.
Inhalation Remove from exposure. Keep warm and at rest. If conscious place in a sitting position. If there is
difficulty in breathing give oxygen if available. If breathing stops or shows signs of failing, apply artificial
resuscitation. OBTAIN MEDICAL ATTENTION.
Ingestion If conscious give plenty of water to drink. Do not induce vomiting. OBTAIN MEDICAL ATTENTION
URGENTLY.
Hazard Symbols:
P a g e | 16
Chemical Safety Data Sheet Date Created: 27/02/2018
Calcium Chloride
Other names: none
Formula: CaCl2
Quantity Provided: 100g
Storage: Keep in tray provided by Empiribox. Keep in a cool, dry place
Use: Gaviscon is ‘injected’ into calcium chloride to produce gel worms
Hazards: Can cause serious eye irritation.
Unit: Chemical Change
Lesson: Observing and Measuring Chemical Changes
Spill process: Can be removed with a wet tissue and placed in the waste paper basket
Disposal: Can be poured down the normal waste stream
In the event of:
Eye contact Irrigate thoroughly with plenty of water for at least 10 minutes, holding the eye open. OBTAIN
MEDICAL ATTENTION.
Skin contact Wash off skin thoroughly with water. Remove contaminated clothing immediately and wash
before re-use. If discomfort persists OBTAIN MEDICAL ATTENTION.
Inhalation Remove from exposure.
Ingestion Wash out the patients mouth thoroughly with water. Do not induce vomiting. In severe cases or if
exposure has been great, OBTAIN MEDICAL ATTENTION.
Hazard Symbols:
P a g e | 17
Chemical Safety Data Sheet Date Created: 27/02/2018
Calcium Oxide
Other names: Quicklime
Formula: CaO
Quantity Provided: 2 kg (in cement mixture)
Storage: Store in a dry place
Use: Mixed with water to produce concrete
Hazards: Can cause burns
Unit: Chemical Change
Lesson: 7&8 Irreversible Chemical Changes
Spill process: Brush into the waste paper basket with a dry paper towel until none remains on the work
area
Disposal: Can be disposed into the waste paper basket. Do not pour down the drain.
In the event of:
Eye Contact: Check for and remove any contact lenses. In case of contact, immediately flush eyes with
plenty of water for at least 15 minutes. WARM water MUST be used. Get medical attention immediately.
Skin Contact: In case of contact, immediately flush skin with plenty of water for at least 15 minutes while
removing contaminated clothing and shoes. Cover the irritated skin with an emollient. Wash clothing
before reuse. Thoroughly clean shoes before reuse.
Inhalation: If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult,
give oxygen. Get medical attention.
Ingestion: Do NOT induce vomiting unless directed to do so by medical personnel. Never give anything by
mouth to an unconscious person. If large quantities of this material are swallowed, call a physician
immediately. Loosen tight clothing such as a collar, tie, belt or waistband.
Hazard Symbols:
P a g e | 18
Chemical Safety Data Sheet Date Created: 27/02/2018
Copper Sulphate
Other names: Copper Sulfate, Copper (II) Sulphate
Formula: CuSO4.5H2O
Quantity Provided: 500g
Storage: Keep in a dry place. Children should only have access under adult supervision
Use: A small portion of iron wool is added to 100mls of copper sulphate solution, and the temperature of
the resultant reaction is taken.
Hazards: Harmful if swallowed. Irritating to eyes and skin. Very toxic to aquatic organisms, may cause long-
term adverse effects in the aquatic environment.
Unit: Particle Theory
Lesson: 7&8 Exothermic and Endothermic Reactions
Spill process: Use a dry tissue to wipe the area until completely dry. The tissue can be disposed of in the
waste paper bin.
Disposal: Unused or ‘reacted’ copper sulphate solute can be poured into the waste stream.
In the event of:
INHALATION Remove victim immediately from source of exposure. Provide rest, warmth and fresh air. Get
medical attention if any discomfort continues.
INGESTION Immediately rinse mouth and drink plenty of water. Get medical attention immediately!
SKIN CONTACT Immediately remove contaminated clothing. Wash the skin immediately with soap and
water. Get medical attention if irritation persists after washing.
EYE CONTACT Promptly wash eyes with plenty of water or eye wash solution while lifting the eyelids. If
possible remove any contact lenses and continue to wash. Get medical attention if any discomfort
continues.
Hazard Symbols:
P a g e | 19
Chemical Safety Data Sheet Date Created: 27/02/2018
Ethanol
Other names: Alcohol, Methylated Spirit
Formula: CH3CH2OH
Quantity Provided: 500mls
Storage: Store in a cool dry place. Should not be placed in direct sunlight or near a source of heat or naked
flames.
Use: 50mls of alcohol is poured into a water-cooler bottle, which is shaken for one minute and the excess
alcohol poured out. The evaporated alcohol vapour is then ignited to produce a characteristic ‘whoosh’
sound and flame.
Hazards: Alcohol is extremely flammable and should be kept away from naked flames except in
recommended use.
Unit: Particle Theory Lesson: 1&2 – Introduction to Particle Theory
Unit: Particle Theory Lesson: 9: Rates of Chemical Reaction
Unit: Chemical Change Lesson: 3: Money to Burn
Unit: Chemical Change Lesson: 9: Blue Bottle Reaction
Spill process: Dry area with a dry tissue until completely dry. Place the tissue into a sealable bag. This can
then be disposed of in the waste paper basket.
Disposal: Unused alcohol can be poured into the waste stream.
In the event of contact with:
Inhalation Remove victim immediately from source of exposure. Provide rest, warmth and fresh air. Get
medical attention if any discomfort continues.
Ingestion Do not induce vomiting. Rinse mouth thoroughly with water Get medical attention.
Skin contact Remove contaminated clothing and wash before re - use. Flush skin thoroughly with water. If
irritation or discomfort occurs obtain medical attention
Eye contact Promptly wash eyes with plenty of water or eye wash solution while lifting the eyelids.If
possible remove any contact lenses and continue to wash. Get medical attention if any discomfort
continues.
Hazard Symbols:
P a g e | 20
Chemical Safety Data Sheet Date Created: 27/02/2018
Methanol
Other names: Methyl alcohol
Formula: CH3OH
Quantity Provided: 250mls
Storage: Keep away from naked flame, direct sunlight or sources of heat and in the tray supplied by
Empiribox.
Use: Approx. 10mls of methanol is mixed with 5g of boric acid and ignited to produce a green flame.
Hazards: Extremely flammable and acutely toxic
Unit: Chemical Change
Lesson: 1&2 Chemical Change
Spill process: Wipe up with a dry tissue until the area is dry. Place the tissue in a sealable bag which can
then be placed in the waste paper basket
Disposal: Can be poured into the waste stream
In the event of contact with:
Eyes Irrigate thoroughly with plenty of water for at least 10 minutes, holding the eye open. OBTAIN
MEDICAL ATTENTION.
Skin Wash off skin thoroughly with water. Remove contaminated clothing immediately and wash before re-
use.
Inhalation Remove from exposure. Keep warm and at rest. If there is difficulty in breathing give oxygen if
available. If breathing stops or shows signs of failing, apply artificial resuscitation. If unconscious place in
the recovery position. OBTAIN MEDICAL ATTENTION URGENTLY.
Ingestion If conscious give plenty of water to drink. Do not induce vomiting. If there is difficulty in breathing
give oxygen if available. If breathing stops or shows signs of failing, apply artificial resuscitation. If
unconscious place in the recovery position. OBTAIN MEDICAL ATTENTION URGENTLY.
Hazard Symbols:
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Chemical Safety Data Sheet Date Created: 27/02/2018
Methylene Blue
Other names: Methylthioninium Chloride
Formula: C16H18N3SCl
Quantity Provided: 5g
Storage: Keep dry and in the tray provided by Empiribox. Children do not have access at any time
Use: Methylene blue is added to alkalinated glucose solution
Hazards: Harmful if swallowed.
Unit: Chemical Change
Lesson: 9&10 Observing and Measuring Chemical Changes
Spill process: Brush into sealable bag and wash the area with plenty of water until no blue stain remains
Disposal: put in a sealable bag. Empiribox will collect any remaining Methylene Blue
In the event of contact with:
Eyes Irrigate thoroughly with plenty of water for at least 10 minutes, holding the eye open. If discomfort
persists OBTAIN MEDICAL ATTENTION.
Skin Wash off skin thoroughly with water. Remove contaminated clothing immediately and wash before re-
use.
Inhalation Remove from exposure.
Ingestion Wash out the patients mouth thoroughly with water.
Hazard Symbols:
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Chemical Safety Data Sheet Date Created: 27/02/2018
Potassium Hydroxide
Other names: Potash
Formula: KOH
Quantity Provided: 100g
Storage: Keep dry and away from children
Use: Approx. 5g of potassium hydroxide is added to glucose solution
Hazards: Is an irritant, especially to the eyes
Unit: Chemical Change
Lesson: 9&10 Observing Chemical Changes
Spill process: Spilled pellets can simply be swept into the waste paper basket
Disposal: Any solution can be poured into the normal waste stream
In the event of contact with:
Eyes Irrigate thoroughly with plenty of water for at least 10 minutes, holding the eye open. If discomfort
persists OBTAIN MEDICAL ATTENTION.
Skin Wash off skin thoroughly with water.
Inhalation Remove from exposure.
Hazard Symbols:
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Chemical Safety Data Sheet Date Created: 27/02/2018
Propan-2-ol
Other names: Isopropyl alcohol
Formula: C3H7OH
Quantity Provided: 50mls
Storage: Keep away from direct sunlight, naked flames and sources of heat. Children should not have
access at any time.
Use: Added to a mixture of bicarbonate of soda and icing sugar and ignited
Hazards: Extremely flammable
Unit: Chemical Change
Lesson: 7: Soda Snake Firework
Spill process:
Disposal: Empiribox will remove all unused propan-2-ol.
In the event of:
Inhalation Move to fresh air in case of accidental inhalation of vapours. If breathing is irregular or stopped,
administer artificial respiration. Call a physician immediately.
Skin contact Wash off immediately with soap and plenty of water while removing all contaminated clothes
and shoes. Wash contaminated clothing before re-use. If skin irritation persists, call a physician.
Eye contact Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician.
Ingestion If swallowed, seek medical advice immediately and show this container or label. Do not induce
vomiting without medical advice. Never give anything by mouth to an unconscious person.
Hazard Symbols:
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Chemical Safety Data Sheet Date Created: 27/02/2018
Sodium Polyacrylate
Other names: none
Formula: (C3H3NaO2)n
Quantity Provided: Derived from absorbent part of a nappy, so the amount will vary but no more than 10g
Storage: not applicable
Use: water will be added to sodium polyacrylate so that it increases in volume
Hazards: irritant to the respiratory system, eyes and skin
Unit: Chemical Change
Lesson: 1&2 Changing Form
Spill process: not applicable, but ensure the area is free of the powder after the experiment
Disposal: can be thrown into the waste paper basket
In the event of:
If inhaled If breathed in, move person into fresh air.
In case of skin contact Wash off with soap and plenty of water.
In case of eye contact rinse thoroughly with plenty of water for at least 15 minutes and consult a physician.
If swallowed never give anything by mouth to an unconscious person. Rinse mouth with water. Consult a
physician
Hazard Symbols:
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Chemical Safety Data Sheet Date Created: 27/02/2018
Ammonium Chloride
Other names: none
Formula: NH4Cl
Quantity Provided: 500g
Storage: keep in a dry place in the tray provided by Empiribox. Children should not have access.
Use: 100g of ammonium chloride is reacted with 100g of barium hydroxide to produce an endothermic
reaction.
Hazards: irritant in the case of contact with the eyes, skin and respiratory tract.
Unit: Mixtures, Separation and Geology
Lesson: 7&8 Mixtures in the Real World
Spill process: Simply brush the powder into the waste paper basket and they wash the surface with water.
Disposal: Can be put into the waste paper basket or poured into the waste stream.
In the event of:
Eye Contact: Check for and remove any contact lenses. In case of contact, immediately flush eyes with
plenty of water for at least 15 minutes. Cold water may be used. Get medical attention if symptoms persist.
Skin Contact: In case of contact, immediately flush skin with plenty of water. Cover the irritated skin with an
emollient. Remove contaminated clothing and shoes. Cold water may be used. Wash clothing before reuse.
Thoroughly clean shoes before reuse.
Inhalation: If inhaled, remove to fresh air.
Ingestion: Do NOT induce vomiting unless directed to do so by medical personnel. Never give anything by
mouth to an unconscious person. If large quantities of this material are swallowed, call a physician
immediately. Loosen tight clothing such as a collar, tie, belt or waistband.
Hazard Symbols:
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Chemical Safety Data Sheet Date Created: 27/02/2018
Ammonium Dichromate
Other names: none
Formula: (NH4)2Cr2O7
Quantity Provided: 500g
Storage: Store in the box provided by Empiribox and keep in a dry place away from naked flames.
Use: 100g of ammonium dichromate is heated until a volcano effect is observed.
Hazards: Irritant in the case of eye and skin contact as well as ingestion and inhalation.
Unit: Geology, Mixtures and Separation
Lesson: 9&10 Introduction to Rocks, Minerals and Fossils
Spill process: Simply brush into the waste paper basket until no orange crystals remain
Disposal: Can be placed in a waste paper basket. Do not pour down the drain.
In the event of:
Eye Contact: Check for and remove any contact lenses. In case of contact, immediately flush eyes with
plenty of water for at least 15 minutes. Cold water may be used. Get medical attention if symptoms persist.
Skin Contact: In case of contact, immediately flush skin with plenty of water for at least 15 minutes while
removing contaminated clothing and shoes. Cover the irritated skin with an emollient. Cold water may be
used. Wash clothing before reuse. Thoroughly clean shoes before reuse.
Inhalation: If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult,
give oxygen.
Ingestion: If swallowed, do not induce vomiting unless directed to do so by medical personnel. Never give
anything by mouth to an unconscious person. Loosen tight clothing such as a collar, tie, belt or waistband.
Get medical attention immediately.
Hazard Symbols:
P a g e | 27
Chemical Safety Data Sheet Date Created: 27/02/2018
Barium Hydroxide
Other names: none
Formula: Ba(OH)2
Quantity Provided: 500g
Storage: Store in a dry place in the tray provided by Empiribox.
Use: 100g of barium hydroxide is reacted with 100g of ammonium chloride to produce an endothermic
reaction.
Hazards: toxic in the case of ingestion and an irritant in the case of eye and skin contact.
Unit: Geology, Mixtures and Separation
Lesson: 7&8 Mixtures in the Real World
Spill process: Brush into the waste paper basket and then wash the affected area with water.
Disposal: Can be placed into the waste paper basket or poured down the drain.
In the event of:
Eye Contact: Check for and remove any contact lenses. In case of contact, immediately flush eyes with
plenty of water for at least 15 minutes. Cold water may be used. Get medical attention if symptoms persist.
Skin Contact: In case of contact, immediately flush skin with plenty of water. Cover the irritated skin with an
emollient. Remove contaminated clothing and shoes. Cold water may be used. Wash clothing before reuse.
Thoroughly clean shoes before reuse.
Inhalation: If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult,
give oxygen.
Ingestion: Do NOT induce vomiting unless directed to do so by medical personnel. Never give anything by
mouth to an unconscious person. If large quantities of this material are swallowed, call a physician
immediately. Loosen tight clothing such as a collar, tie, belt or waistband.
Hazard Symbols:
P a g e | 28
Chemical Safety Data Sheet Date Created: 27/02/2018
Ammonia Solution
Other Names: Ammonia Water, Aqueous Ammonia, Ammonium Hydroxide
Formula: NH3 (aq)
Quantity Provided: 1 litre
Storage: Keep container tightly closed and store in a well-ventilated place.
Use: Used with universal indicator paper to measure pH
Hazards: Irritant in the case of eye and skin contact as well as ingestion and inhalation.
Unit: Acids and Alkalis Lesson: 3: Rainbow tube
Spill process: Dry wipe until surface is dry and then wash surface with clean water. Dry completely.
Disposal: Do not pour down the waste stream. Empiribox trainers will collect unused solution.
In the event of:
Eye Contact: Check for and remove any contact lenses. In case of contact, immediately flush eyes with
plenty of water for at least 15 minutes. Cold water may be used. Get medical attention if symptoms persist.
Skin Contact: In case of contact, immediately flush skin with plenty of water for at least 15 minutes while
removing contaminated clothing and shoes. Cover the irritated skin with an emollient if required. Cold
water may be used. Wash clothing before reuse. Thoroughly clean shoes before reuse.
Inhalation: If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult,
give oxygen.
Ingestion: If swallowed, do not induce vomiting unless directed to do so by medical personnel. Never give
anything by mouth to an unconscious person. Loosen tight clothing such as a collar, tie, belt or waistband.
Get medical attention immediately.
Hazard Symbols:
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Chemical Safety Data Sheet Date Created: 27/02/2018
Zinc Nitrate
Other names: Zinc Nitrate Hexahydrate
Formula: Zn (NO3)2
Quantity Provided: 100g
Storage: Store in a cool dry place.
Use: Reacted with ammonia solution to produce a milky substance.
Hazards: Hazardous in case of skin contact (irritant), of eye contact (irritant), of ingestion, of inhalation.
Prolonged exposure may result in skin burns and ulcerations. Over-exposure by inhalation may cause
respiratory irritation.
Unit: Acids and Alkalis Lesson: 3: Union Jack Chemistry
Spill process: Dry wipe until the area is completely clear and then wash thoroughly with water.
Disposal: Can be disposed into the normal waste stream.
In the event of:
Eye Contact: Check for and remove any contact lenses. In case of contact, immediately flush eyes with
plenty of water for at least 15 minutes. Cold water may be used. Get medical attention if symptoms persist.
Skin Contact: In case of contact, immediately flush skin with plenty of water for at least 15 minutes while
removing contaminated clothing and shoes. Cover the irritated skin with an emollient if required. Cold
water may be used. Wash clothing before reuse. Thoroughly clean shoes before reuse.
Inhalation: If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult,
give oxygen. Seek immediate medical attention.
Ingestion: If swallowed, do not induce vomiting unless directed to do so by medical personnel. Never give
anything by mouth to an unconscious person. Loosen tight clothing such as a collar, tie, belt or waistband.
Get medical attention immediately.
Hazard Symbols:
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Chemical Safety Data Sheet Date Created: 27/02/2018
Phosphoric Acid
Other names: Orthophosphoric acid, Phosphoric (V) Acid
Formula: H3PO4
Quantity Provided: 1 litre
Storage: Store in a cool dry place. Ensure the lid is tightly screwed on.
Use: Used with universal indicator to show pH of acids
Hazards: Irritant to eyes, skin and respiratory system. Corrosive.
Unit: Acids an Alkalis Lesson: 5: The Periodic Table
Spill process: Dry wipe the area and then wash with clean water.
Disposal: Can be poured down the normal waste stream
In the event of:
Eye Contact: Check for and remove any contact lenses. In case of contact, immediately flush eyes with
plenty of water for at least 15 minutes. Cold water may be used. Get medical attention if symptoms persist.
Skin Contact: In case of contact, immediately flush skin with plenty of water for at least 15 minutes while
removing contaminated clothing and shoes. Cover the irritated skin with an emollient if required. Cold
water may be used. Wash clothing before reuse. Thoroughly clean shoes before reuse.
Inhalation: If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult,
give oxygen.
Ingestion: If swallowed, do not induce vomiting unless directed to do so by medical personnel. Never give
anything by mouth to an unconscious person. Loosen tight clothing such as a collar, tie, belt or waistband.
Get medical attention immediately.
Hazard Symbols:
P a g e | 31
Chemical Safety Data Sheet Date Created 27/02/2018
Magnesium Hydroxide
Other names: Milk of Magnesium
Formula: Mg(OH)2
Quantity Provided: 500g
Storage: Store in a cool dry place
Use: Used with universal indicator to measure pH of alkalis
Hazards: Irritant in case of skin, eye and respiratory system contact
Unit: Acids and Alkalis Lesson: 5: The Periodic Table
Spill process: Dry wipe the area of dispose in the bin. If necessary wash surface with clean water
Disposal: Can be disposed of in the waste paper bin
In the event of:
Eye Contact: Check for and remove any contact lenses. In case of contact, immediately flush eyes with
plenty of water for at least 15 minutes. Cold water may be used. Get medical attention if symptoms persist.
Skin Contact: In case of contact, immediately flush skin with plenty of water for at least 15 minutes while
removing contaminated clothing and shoes. Cover the irritated skin with an emollient if required. Cold
water may be used. Wash clothing before reuse. Thoroughly clean shoes before reuse.
Inhalation: If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult,
give oxygen.
Ingestion: If swallowed, do not induce vomiting unless directed to do so by medical personnel. Never give
anything by mouth to an unconscious person. Loosen tight clothing such as a collar, tie, belt or waistband.
Get medical attention immediately.
Hazard Symbols:
P a g e | 32
Chemical Safety Data Sheet Date Created: 27/02/2018
Lithium Hydroxide
Other names: Lithin
Formula: LiOH
Quantity Provided: 500g
Storage: Keep in a dry cool place
Use: Used with universal indicator to measure pH of alkalis
Hazards: Corrosive in the even of skin and eye contact. Very hazardous in the event of inhalation
Unit: Acids and Alkalis Lesson: 5: The Periodic Table
Spill process: Add water to affected area. Use gloves to mop up. Ensure the area is dry before re-use.
Disposal: Can be disposed of in the waste bin
In the event of:
Eye Contact: Check for and remove any contact lenses. In case of contact, immediately flush eyes with
plenty of water for at least 15 minutes. Cold water may be used. Get medical attention if symptoms persist.
Skin Contact: In case of contact, immediately flush skin with plenty of water for at least 15 minutes while
removing contaminated clothing and shoes. Cover the irritated skin with an emollient if required. Cold
water may be used. Wash clothing before reuse. Thoroughly clean shoes before reuse.
Inhalation: If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult,
give oxygen. See immediate medical attention.
Ingestion: If swallowed, do not induce vomiting unless directed to do so by medical personnel. Never give
anything by mouth to an unconscious person. Loosen tight clothing such as a collar, tie, belt or waistband.
Get medical attention immediately.
Hazard Symbols:
P a g e | 33
Chemical Safety Data Sheet Date Created: 27/02/2018
Zinc Hydroxide
Other names: none
Formula: ZnOH
Quantity Provided: 500g
Storage: Store in a cool dry place
Use: Used with universal indicator to measure the pH of alkalis
Hazards: Slight irritant in case of skin, eye and respiratory tract contact
Unit: Acids and Alkalis Lesson: 5: The Periodic Table
Spill process: Add water and use dry towels to mop up the area.
Disposal: Can be disposed of in the waste paper basket
In the event of:
Eye Contact: Check for and remove any contact lenses. In case of contact, immediately flush eyes with
plenty of water for at least 15 minutes. Cold water may be used. Get medical attention if symptoms persist.
Skin Contact: In case of contact, immediately flush skin with plenty of water for at least 15 minutes while
removing contaminated clothing and shoes. Cover the irritated skin with an emollient if required. Cold
water may be used. Wash clothing before reuse. Thoroughly clean shoes before reuse.
Inhalation: If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult,
give oxygen.
Ingestion: If swallowed, do not induce vomiting unless directed to do so by medical personnel. Never give
anything by mouth to an unconscious person. Loosen tight clothing such as a collar, tie, belt or waistband.
Hazard Symbols:
P a g e | 34
Chemical Safety Data Sheet Date Created: 27/02/2018
Copper Carbonate
Other names: Cupric Carbonate, Copper (II) Carbonate
Formula: CuCO3
Quantity Provided: 500g
Storage: Store in a cool dry place
Use: Reacted with hydrochloric acid to produce copper chloride and carbon dioxide
Hazards: Very hazardous in the case of ingestion and eye contact. Slight irritant in the case of skin contact
Unit: Water, Acids and Alkalis Lesson: 5: Acids and Carbonates
Spill process: Wear gloves and add water to affected area.
Disposal: Can be placed in waste paper bin.
In the event of:
Eye Contact: Check for and remove any contact lenses. In case of contact, immediately flush eyes with
plenty of water for at least 15 minutes. Cold water may be used. Get medical attention if symptoms persist.
Skin Contact: In case of contact, immediately flush skin with plenty of water for at least 15 minutes while
removing contaminated clothing and shoes. Cover the irritated skin with an emollient if required. Cold
water may be used. Wash clothing before reuse. Thoroughly clean shoes before reuse.
Inhalation: If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult,
give oxygen.
Ingestion: If swallowed, do not induce vomiting unless directed to do so by medical personnel. Never give
anything by mouth to an unconscious person. Loosen tight clothing such as a collar, tie, belt or waistband.
Get medical attention immediately.
Hazard Symbols: