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POOR LEGIBILITY
ONE OR MORE PAGES IN THIS DOCUMENT ARE DIFFICULT TO READ DUE TO THE QUALITY OF THE ORIGINAL
j ; SFUND RECORDS CTR
5133-00005
SFUND RECORDS CENTER ) 88224854
Data Validation Package
for
MERCURY
EPA 7471A
TABLE OF CONTENTS
LABORATORY NAME: APPL Inc.
Case Narrative 3
Chain of Custody and ARF _4_
QC Summary
Sample Data /^/
Calibration Data j_j_
Raw Data ^ /
APPL, IIMC. I
02
A^tjwc=l
MERCURY EPA 7471A
Case Narrative
03
CASE NARRATIVE Mercury for Ecology and Environment
APPL, Inc. State Certification No. 1312
ARF Numbers: 26739 Project: KJ93103 Eagle One
Sample Receipt Information:
The sample group was received on January 07, 1998. The samples were assigned Analytical Request Form (ARF) number 26739. The sample numbers and requested analyses were compared to the chain of custody. No exceptions were encountered.
Sample Table for Metals Analyses
E & E APPL Date Date Date Date ID ID Matrix Sampled Received Digested Analyzed
Eagle One-160 59786 Soil 12/11/97 01/07/98 01/07/98 01/08/98 Eagle One-155 59787 Soil 12/11/97 01/07/98 01/07/98 01/08/98
Sample Preparation
The analyses were performed within holding time. The Mercury analyses were performed using a Thermo Jarrell Atomic Absorption Spectrophotometer.
Analysis
All samples were analyzed within acceptable holding time. No problems were encountered.
Quality Control/Assurance
Laboratory Duplicate
The laboratory duplicate results met acceptance criteria.
Spike Recovery
An MS/MSD and an LCS were used for the spikes. All recoveries were acceptable.
Method blanks
The preparation blank contained no target analytes at or above reporting limits.
04
Calibration
Initial Calibration
All initial calibrations were performed according to the methods. All acceptance criteria were met.
Continuing Calibration
All continuing calibrations were performed according to the method. All acceptance criteria were met.
Certification
I certify that this data package is in compliance with the terms and conditions of the contract, both technically and for completeness, for other than the conditions detailed above. Release of the data contained in this hard copy data package has been authorized by the Laboratory Manager or his designee, as verified by the following signature.
05
MERCURY EPA 7471A
Chain of Custody and ARF
Am,, awe. I
06
• ' APPL - Analysis Request Form #26739 ^ ^ — — —
Client: Ecology & Env - San Francisco (ECOL-SF) Received by: ML
* Name: Ecology & Environment Date Received: 01/07/98 Time: 09:55
Address: 500 Howard, Suite 202 Date Sampled: 12/11/97
Address: San Francisco, CA 94105 Delivered by: FED. EXPRESS
Attn: Howard Edwards Ph: (415) 981-2811 Shuttle Custody seals (Y/N): N
Client job # or location: KJ93103 Eagle One Chest Temp(s): 2 V59773 .
PO# if available: NA Time in/color: 1055 ORANGE/ PURPLE '
Chain of Custody (Y/N): Y Project Manager: Diane Anderson
RAD Screen (Y/N): Y pH (Y/N): N QC Report Type: DVP4
Samples chilled until placed in refrigerator/freezer (Y/N): Y
Turn Around Type: 3 DAY Due Date: - 01/07/98 • C ,\ L \ C;
Charges Sample Distribution
Comments: HOLDING TIME UP 01/08/98 FROM E&E START BOA CONTRACT
Fage 1
07 #26739
EN VI HONMENTAL PROTECTION AGENCY
Office of Enforcement
CHAIN OF CUSTODY RECORD
REGION 9
75 Hawthorne Street'
PROJ NO.
• "Si r?<
PROJECT NAME
1 T . . - < NO.
OF
CONTAINERS
/ ^ [T
/////// A PTT fj / / / / / / / REMARKS OO7_/
/ / V / / / /
SAMPLERS: (Signature) NO.
OF
CONTAINERS
/ ^ [T
/////// A PTT fj / / / / / / / REMARKS OO7_/
/ / V / / / / STA. NO. DATE TIME
CO
MP GO
< cr o
STATION LOCATION
NO.
OF
CONTAINERS
/ ^ [T
/////// A PTT fj / / / / / / / REMARKS OO7_/
/ / V / / / /
•' • ' : i , ' i «•:•'. 1 ,'i , ; \ 4 . T /
r - X L i / - / i k . / \ '
I " .. \ |0 - ; f , V'"
.1 1
£ ^2 ! ;
1 ' \
— . /.../...
D /"*'S .. , X)
J*' 1 - '•% O
-
V/s -a§r/ /
\ —
Relinquished by: (Signature)
Relinquished by: (Signature)
Date/Time Received by: (Signature)
Date / Time
Relinquished by: (Signature)
for Laboratory b y : ure) /•' / 1/1 /
Distribution: Original Accompanies ShTp'rifent; Copy 1,6 otjj^fnafor Field Files / L
j pfate /Time
f/W / A
/'! , 'ir, r IL
/y
Date / Time Received by: (Signature)
Remarks
9 25117
4
<
TnrTimi nq Sample Notice
r l i n T 1 f . E C c L o b 7 f t . Initials: _£f&-^ Date of call: £L&_
—: Client Job: Phone: ZZ'V Name: PO Delivered >J: _ - Date expected;
CO Sample Date: Due Date- ——
Client ID: ^ $>oiLs
L T/r>X*>
f^-cJr Icl»- ^
Special Tnst-.ructions: cJ-hAs
o
CONTAINER
TIER 500ML
PL 250MI. PL LITER - I IM03
L 500ML -IIN03 L 250ML -1IM03
PL LITER -112S0-
PL 500ML - I-I2S0' L 250ML - N2S0<I
CYANIDE SULFIDE "OC
VOAS- l-ICL
VOAS - NA2S203 VOAS - NP OIL & GREASE AMBER LITER SOIL SLEEVE 102 JAR
OOZ JAR I60Z JAR 320Z JAR
SUBCONTRACT:
QA/QC SAMPLE
B l I C I t l P T l : O R M ARE IE ,' T."SC>)
PROJECT
COOL] COOLER RECEIPT FORM
Z7/^-Date Received: Number of Coolers: /
USE OTHER SIDE OF THIS FORM TO NOTE DETAILS CONCE
A. PRELIMINARY EXAMINATION PHASE: Date Cooler Opened:
by (print)
G CHECK-IN PROBLEMS.
C-O-C #
1. Did cooler come with a shipping slip (air bill, etc.)? -S7- QTTiS^yNC
If Yes, enter carrier name and air bill number here:
Were custody seals on outside of cooler?
How manv? Date on Seal?
YE3'"^ND~~^
Name on seal?
j.
4.
5.
6.
7.
8.
9.
Were custody seals unbroken and intact at the date and time of arrival? YES pO
Did you screen sample for radioactivity using the Geiger Counter0 (^TES^NO
Were custody papers sealed in a plastic bag &. taped inside to the lid0 ( . ^YES^ NO
Were custody papers filled out properly (ink, signed, etc.)? (T. YESJ) NO
Did you sign custody papers in the appropriate place0
Was project identifiable from custody papers0 If YES. enter project name at die top of Litis form
If required, was enough ice used? Type of ice:
10. Shutde temDeraturefsi: d
£j-
1 1 . H a v e d e s i g n a t e d p e r s o n i n i t i a l h e r e t o a c k n o w l e d g e r e c e i p t o f c o o l e r
B. LOG-IN PHASE: Date samples were logged-in
Serial number of certified thermometer used: SY2ZO
by (print)
Did all botdes arrive unbroken & were labels in good condition? . P ,S -.Vr^.
Were all botde labels complete (ID, date, time, signature, preservadve, etc.)? N'0
Did all botde labels agree with custody papers? N O
Were correct containers used for the tests indicated? ( • YES jNO
Were correct preservarives added to samples? YES^ NO
Was a sufficient amount of sample sent for tests indicated? L , YF'v- NO
Were bubbles absent in volatile samples? If NO, list by sample ID YESri NO
10. Was the project manager called and status discussed? If YES, give details on die back of this form YES^NO
1 1 . W h o w a s c a l l e d ? Bv whom? (date)
11
MERCURY EPA 7471A
QC Summary
APPI.IMC.)
1 2
E & E H g B Y M E T H O D 7 4 7 1 A A R F # 2 6 7 3 9 QCG: 010798-7471A-1
DATE: 01/08/98
NAME TRUE RESULT % RECOV.
ICV ICB
CCV-1 CCB-1
CCV-2 CCB-2
PB-1 LCSW-1
59787S 59787SD 59787S S1 59787S S2
4ppb Oppb
5ppb Oppb
5ppb Oppb
(PPb) 0.0360 3.9869
(mg/kg) 0.7469 0.7989 1.5531 1.5401
4.1807 0.0360
4.9122 0.0360
4.9934 0.0360
105%
98.2%
99.8%
SPIKED AT 4ppb 98.4%
(SPIKED AT 0.667mg/kg) 121% (SPIKED AT 0.667mg/kg) 119%
RPD=6.7%
RPD=0.84%
LCSW/Sample spike recovery acceptance limit. (±20%) Sample spike recovery acceptance limit. (±25%) LCSW/ Matrix duplicate RPD acceptance limit. (±20%)
13
Metals Analysis
Ecology & Environment
500 Howard, Suite 202
San Francisco, CA 94105
Attn: Howard Edwards
Project: KJ93103 Eagle One
Sample ID: EAGLE ONE-160 APPL ID: AP59786
Sample Collection Date: 12/11/97 ARF: 26739
Method Analyte Result PQL Units Prep Date Analysis Date
(Concentrations and Limits have been adjusted to reflect 4.3 Percent Moisture.)
7471A Mercury (Hg) 0.73 0.10 mg/kg 1/7/98 1/8/98
APPL Inc.
4203 West Swift Avenue
Fresno, CA 93722
15 Printed: 1/6/98 4:27:44 PM
Metals Analysis
Ecology & Environment
500 Howard, Suite 202
San Francisco, CA 94105
APPL Inc.
4203 West Swift Avenue
Fresno, CA 93722
Attn: Howard Edwards
Project: KJ93103 Eagle One
Sample ID: EAGLE ONE-155
Sample Collection Date: 12/11/97 APPL ID: AP59787
ARF: 26739
Method Analyte Result PQL Units Prep Date Analysis Date
(Concentrations and Limits have been adjusted to reflect 2.4 Percent Moisture.]
7471A Mercury (Hg) 0.72 0.10 mg/kg 1/7/98 1/8/98
i
IB Printed: 1/8/98 4:27:44 PM
MERCURY EPA 7471A
Calibration Data
APPl, IIIMC/1
17
E & E Hg BY METHOD 7471A QCG: 010798-7471A-1
DATE: 01/08/98
ARF#26739
Hg RUN LOG (01/08/98) Calibration 01/08/98 ICV 01/08/98 ICB 01/08/98 CCV-1 01/08/98 CCB-1 01/08/98 PB QCG: 010798-7471 A-1 01/08/98 LCSW QCG: 010798-7471 A-1 01/08/98 59786S QCG: 010798-7471 A-1 01/08/98 59787S QCG: 010798-7471 A-1 01/08/98 59787SD QCG: 010798-7471 A-1 01/08/98 59787S S1 QCG: 010798-7471 A-1 01/08/98 59787S S2 QCG: 010798-7471 A-1 01/08/98 CCV-2 01/08/98 CCB-2 01/08/98
18
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20
MERCURY EPA 7471A Raw Data
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METHOD DETECTION LIMIT REPORT
ANALYTICAL METHOD-
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O\ 13TI — 7^+—} i A — 1
* REAG E N T B L ANK SPIKE RESULTS luf f /1 ) % RECOVERY
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t —3. 143 TRUE Sr IKE VALUE: O. HH^ IV^ t o
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24
Ecology & Environment
500 Howard, Suite 202
San Francisco, CA 94105
Wet Lab Analysis
APPL Inc.
4203 West Swift Avenue
Fresno, CA 93722
Attn: Howard Edwards
Project: KJ93103 Eagle One
Sample ID: EAGLE ONE-160 APPL ID: AP59786
Sample Collection Date: 12/11/97 ARF: 26739
Method Analyte Result PQL Units Prep Date Analysis Date
CLP MOIST Moisture 4.3 2 % 1/7/98 1/7/98
25
Initials: wy
Printed: 1/&98 9:58:31 AM
Wet Lab Analysis
Ecology & Environment
500 Howard, Suite 202
San Francisco, CA 94105
Attn: Howard Edwards
Project: KJ93103 Eagle One
Sample ID: EAGLE ONE-155 APPL ID: AP59787
Sample Collection Date: 12/11/97 ARF: 26739
Method Analyte Result PQL Units Prep Date Analysis Date
CLP MOIST Moisture 2.4 2 % 1/7/98 1/7/98
APPL Inc.
4203 West Swift Avenue
Fresno, CA 93722
?6
APPL, Inc. Wet Chemistry Lab
QC Summary
Client: Ecology Environment ARF#: 26739
Method CLP3/9Q
Analyte: % MOISTURE
Matrix Duplicate (Batch QC)
Sample SR(%M) RPD QCG
59421S 28.4 5.5 010798-CLP3/90-1
59421SD 30.0 „ 010798-CLP3/90-1
Acceptable limit for a matrix duplicate is RPD <20.
SA=spike amount SR=sample recovery SSR=sample spike recovery %R=%recovery RPD=relative % difference QCG=quality control group
Page 1
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