Data validation package for mercury EPA 7471a · j ; SFUND RECORDS CTR 5133-00005 SFUND RECORDS CENTER ) 88224854 Data Validation Package for MERCURY EPA 7471A TABLE OF CONTENTS LABORATORY

POOR LEGIBILITY

ONE OR MORE PAGES IN THIS DOCUMENT ARE DIFFICULT TO READ DUE TO THE QUALITY OF THE ORIGINAL

j ; SFUND RECORDS CTR

5133-00005

SFUND RECORDS CENTER ) 88224854

Data Validation Package

for

MERCURY

EPA 7471A

TABLE OF CONTENTS

LABORATORY NAME: APPL Inc.

Case Narrative 3

Chain of Custody and ARF _4_

QC Summary

Sample Data /^/

Calibration Data j_j_

Raw Data ^ /

APPL, IIMC. I

02

A^tjwc=l

MERCURY EPA 7471A

Case Narrative

03

CASE NARRATIVE Mercury for Ecology and Environment

APPL, Inc. State Certification No. 1312

ARF Numbers: 26739 Project: KJ93103 Eagle One

Sample Receipt Information:

The sample group was received on January 07, 1998. The samples were assigned Analytical Request Form (ARF) number 26739. The sample numbers and requested analyses were compared to the chain of custody. No exceptions were encountered.

Sample Table for Metals Analyses

E & E APPL Date Date Date Date ID ID Matrix Sampled Received Digested Analyzed

Eagle One-160 59786 Soil 12/11/97 01/07/98 01/07/98 01/08/98 Eagle One-155 59787 Soil 12/11/97 01/07/98 01/07/98 01/08/98

Sample Preparation

The analyses were performed within holding time. The Mercury analyses were performed using a Thermo Jarrell Atomic Absorption Spectrophotometer.

Analysis

All samples were analyzed within acceptable holding time. No problems were encountered.

Quality Control/Assurance

Laboratory Duplicate

The laboratory duplicate results met acceptance criteria.

Spike Recovery

An MS/MSD and an LCS were used for the spikes. All recoveries were acceptable.

Method blanks

The preparation blank contained no target analytes at or above reporting limits.

04

Calibration

Initial Calibration

All initial calibrations were performed according to the methods. All acceptance criteria were met.

Continuing Calibration

All continuing calibrations were performed according to the method. All acceptance criteria were met.

Certification

I certify that this data package is in compliance with the terms and conditions of the contract, both technically and for completeness, for other than the conditions detailed above. Release of the data contained in this hard copy data package has been authorized by the Laboratory Manager or his designee, as verified by the following signature.

05

MERCURY EPA 7471A

Chain of Custody and ARF

Am,, awe. I

06

• ' APPL - Analysis Request Form #26739 ^ ^ — — —

Client: Ecology & Env - San Francisco (ECOL-SF) Received by: ML

* Name: Ecology & Environment Date Received: 01/07/98 Time: 09:55

Address: 500 Howard, Suite 202 Date Sampled: 12/11/97

Address: San Francisco, CA 94105 Delivered by: FED. EXPRESS

Attn: Howard Edwards Ph: (415) 981-2811 Shuttle Custody seals (Y/N): N

Client job # or location: KJ93103 Eagle One Chest Temp(s): 2 V59773 .

PO# if available: NA Time in/color: 1055 ORANGE/ PURPLE '

Chain of Custody (Y/N): Y Project Manager: Diane Anderson

RAD Screen (Y/N): Y pH (Y/N): N QC Report Type: DVP4

Samples chilled until placed in refrigerator/freezer (Y/N): Y

Turn Around Type: 3 DAY Due Date: - 01/07/98 • C ,\ L \ C;

Charges Sample Distribution

Comments: HOLDING TIME UP 01/08/98 FROM E&E START BOA CONTRACT

Fage 1

07 #26739

EN VI HONMENTAL PROTECTION AGENCY

Office of Enforcement

CHAIN OF CUSTODY RECORD

REGION 9

75 Hawthorne Street'

PROJ NO.

• "Si r?<

PROJECT NAME

1 T . . - < NO.

OF

CONTAINERS

/ ^ [T

/////// A PTT fj / / / / / / / REMARKS OO7_/

/ / V / / / /

SAMPLERS: (Signature) NO.

OF

CONTAINERS

/ ^ [T


/ / V / / / / STA. NO. DATE TIME

CO

MP GO

< cr o

STATION LOCATION

NO.

OF

CONTAINERS

/ ^ [T


/ / V / / / /

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Relinquished by: (Signature)


Date/Time Received by: (Signature)

Date / Time


for Laboratory b y : ure) /•' / 1/1 /

Distribution: Original Accompanies ShTp'rifent; Copy 1,6 otjj^fnafor Field Files / L

j pfate /Time

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Date / Time Received by: (Signature)

Remarks

9 25117

4

<

TnrTimi nq Sample Notice

r l i n T 1 f . E C c L o b 7 f t . Initials: _£f&-^ Date of call: £L&_

—: Client Job: Phone: ZZ'V Name: PO Delivered >J: _ - Date expected;

CO Sample Date: Due Date- ——

Client ID: ^ $>oiLs

L T/r>X*>

f^-cJr Icl»- ^

Special Tnst-.ructions: cJ-hAs

o

CONTAINER

TIER 500ML

PL 250MI. PL LITER - I IM03

L 500ML -IIN03 L 250ML -1IM03

PL LITER -112S0-

PL 500ML - I-I2S0' L 250ML - N2S0<I

CYANIDE SULFIDE "OC

VOAS- l-ICL

VOAS - NA2S203 VOAS - NP OIL & GREASE AMBER LITER SOIL SLEEVE 102 JAR

OOZ JAR I60Z JAR 320Z JAR

SUBCONTRACT:

QA/QC SAMPLE

B l I C I t l P T l : O R M ARE IE ,' T."SC>)

PROJECT

COOL] COOLER RECEIPT FORM

Z7/^-Date Received: Number of Coolers: /

USE OTHER SIDE OF THIS FORM TO NOTE DETAILS CONCE

A. PRELIMINARY EXAMINATION PHASE: Date Cooler Opened:

by (print)

G CHECK-IN PROBLEMS.

C-O-C #

1. Did cooler come with a shipping slip (air bill, etc.)? -S7- QTTiS^yNC

If Yes, enter carrier name and air bill number here:

Were custody seals on outside of cooler?

How manv? Date on Seal?

YE3'"^ND~~^

Name on seal?

j.

4.

5.

6.

7.

8.

9.

Were custody seals unbroken and intact at the date and time of arrival? YES pO

Did you screen sample for radioactivity using the Geiger Counter0 (^TES^NO

Were custody papers sealed in a plastic bag &. taped inside to the lid0 ( . ^YES^ NO

Were custody papers filled out properly (ink, signed, etc.)? (T. YESJ) NO

Did you sign custody papers in the appropriate place0

Was project identifiable from custody papers0 If YES. enter project name at die top of Litis form

If required, was enough ice used? Type of ice:

10. Shutde temDeraturefsi: d

£j-

1 1 . H a v e d e s i g n a t e d p e r s o n i n i t i a l h e r e t o a c k n o w l e d g e r e c e i p t o f c o o l e r

B. LOG-IN PHASE: Date samples were logged-in

Serial number of certified thermometer used: SY2ZO

by (print)

Did all botdes arrive unbroken & were labels in good condition? . P ,S -.Vr^.

Were all botde labels complete (ID, date, time, signature, preservadve, etc.)? N'0

Did all botde labels agree with custody papers? N O

Were correct containers used for the tests indicated? ( • YES jNO

Were correct preservarives added to samples? YES^ NO

Was a sufficient amount of sample sent for tests indicated? L , YF'v- NO

Were bubbles absent in volatile samples? If NO, list by sample ID YESri NO

10. Was the project manager called and status discussed? If YES, give details on die back of this form YES^NO

1 1 . W h o w a s c a l l e d ? Bv whom? (date)

11

MERCURY EPA 7471A

QC Summary

APPI.IMC.)

1 2

E & E H g B Y M E T H O D 7 4 7 1 A A R F # 2 6 7 3 9 QCG: 010798-7471A-1

DATE: 01/08/98

NAME TRUE RESULT % RECOV.

ICV ICB

CCV-1 CCB-1

CCV-2 CCB-2

PB-1 LCSW-1

59787S 59787SD 59787S S1 59787S S2

4ppb Oppb

5ppb Oppb

5ppb Oppb

(PPb) 0.0360 3.9869

(mg/kg) 0.7469 0.7989 1.5531 1.5401

4.1807 0.0360

4.9122 0.0360

4.9934 0.0360

105%

98.2%

99.8%

SPIKED AT 4ppb 98.4%

(SPIKED AT 0.667mg/kg) 121% (SPIKED AT 0.667mg/kg) 119%

RPD=6.7%

RPD=0.84%

LCSW/Sample spike recovery acceptance limit. (±20%) Sample spike recovery acceptance limit. (±25%) LCSW/ Matrix duplicate RPD acceptance limit. (±20%)

13

Metals Analysis

Ecology & Environment

500 Howard, Suite 202

San Francisco, CA 94105

Attn: Howard Edwards

Project: KJ93103 Eagle One

Sample ID: EAGLE ONE-160 APPL ID: AP59786

Sample Collection Date: 12/11/97 ARF: 26739

Method Analyte Result PQL Units Prep Date Analysis Date

(Concentrations and Limits have been adjusted to reflect 4.3 Percent Moisture.)

7471A Mercury (Hg) 0.73 0.10 mg/kg 1/7/98 1/8/98

APPL Inc.

4203 West Swift Avenue

Fresno, CA 93722

15 Printed: 1/6/98 4:27:44 PM

Metals Analysis




APPL Inc.


Fresno, CA 93722



Sample ID: EAGLE ONE-155

Sample Collection Date: 12/11/97 APPL ID: AP59787

ARF: 26739


(Concentrations and Limits have been adjusted to reflect 2.4 Percent Moisture.]

7471A Mercury (Hg) 0.72 0.10 mg/kg 1/7/98 1/8/98

i

IB Printed: 1/8/98 4:27:44 PM

MERCURY EPA 7471A

Calibration Data

APPl, IIIMC/1

17

E & E Hg BY METHOD 7471A QCG: 010798-7471A-1

DATE: 01/08/98

ARF#26739

Hg RUN LOG (01/08/98) Calibration 01/08/98 ICV 01/08/98 ICB 01/08/98 CCV-1 01/08/98 CCB-1 01/08/98 PB QCG: 010798-7471 A-1 01/08/98 LCSW QCG: 010798-7471 A-1 01/08/98 59786S QCG: 010798-7471 A-1 01/08/98 59787S QCG: 010798-7471 A-1 01/08/98 59787SD QCG: 010798-7471 A-1 01/08/98 59787S S1 QCG: 010798-7471 A-1 01/08/98 59787S S2 QCG: 010798-7471 A-1 01/08/98 CCV-2 01/08/98 CCB-2 01/08/98

18

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20

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24




Wet Lab Analysis

APPL Inc.


Fresno, CA 93722






CLP MOIST Moisture 4.3 2 % 1/7/98 1/7/98

25

Initials: wy

Printed: 1/&98 9:58:31 AM

Wet Lab Analysis









CLP MOIST Moisture 2.4 2 % 1/7/98 1/7/98

APPL Inc.


Fresno, CA 93722

?6

APPL, Inc. Wet Chemistry Lab

QC Summary

Client: Ecology Environment ARF#: 26739

Method CLP3/9Q

Analyte: % MOISTURE

Matrix Duplicate (Batch QC)

Sample SR(%M) RPD QCG

59421S 28.4 5.5 010798-CLP3/90-1

59421SD 30.0 „ 010798-CLP3/90-1

Acceptable limit for a matrix duplicate is RPD <20.

SA=spike amount SR=sample recovery SSR=sample spike recovery %R=%recovery RPD=relative % difference QCG=quality control group

Page 1

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Documents

Data validation package for mercury EPA 7471a · j ; SFUND RECORDS CTR 5133-00005 SFUND RECORDS CENTER ) 88224854 Data Validation Package for MERCURY EPA 7471A TABLE OF CONTENTS LABORATORY