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SFUND RECORDS CTR
88015029
Z ^ AnolyticolTechnologies,! nc. 21
SFUND RECORDS CTR
0222-00467
13 S. 48th Street Suite 107 Tempe, AZ 85282 (602) 438-1530
JULY 1 4 , 1988
CkuTu - A - CiAOfvi -(yx.
S S - L •• O i H l l l
MONTGOMERY & ASSOCIATES 1075 E. FT. LOWELL RD. SUITE B TUCSON, AZ 85719
Accession: §^5088
Date Received: 5/18/88
Attention: BILL VICTOR
Project: 661C
Note: DDT SPIKE RECOVERIES MAY BE ELEVATED DUE TO THE PRESENCE OF TOXAPHENE IN THE SAMPLE CHOSEN TO SPIKE. DATES FOR INORGANIC ANALYSES ARE SHOWN ON QUALITY CONTROL REPORT FORMS.
::hael G.(/Bc Michael G.(/Barry Project Manager
Robert V. Woods Laboratory Manager
RVW/clf Note: Samples will be disposed of within 30 days unless otherwise notified.
.f'tCtlVEj
^^l 2 7 1983
O-'TGOMERy ft ASSOC, INC,
Corporate Offices; 5550 Moretiouse Drive San Diego, CA 92121 (619) 458-9141
A
/ K AnolyticolTechnologies, Inc
COMMENTS:
SOME SAMPLES AND THE REAGENT BLANK, ORIGNALLY EXTRACTED 5/23/88 WERE FOUND TO BE RANDOMLY CONTAMINATED WITH TOXAPHENE, DDE. DDD, AND DDT, WHEN INJECTED ON 6/14/88. SAMPLES WERE IMMEDIATELY REEXTRACTED ON 6/16/88 AND INJECTED ON 6/16/88.
ENCLOSED YOU WILL FIND THE ORIGINAL CHROMATOGRAMS TO ACCOMPANY THE SET OF 6/16/88. DATA SHEETS ARE NOW INCLUDED FOR THE REAGENT BLANK AND QC INFORMATION OF 6/14/88. ALL DATA IS TAKEN FROM THE 6/14/88 RUN EXCEPT FOR THE ABOVE MENTIONED COMPOUNDS, WHOSE DATA COMES FROM 6/16/88.
SOME CORRECTIONS HAVE ALSO BEEN MADE TO REFELCT THE PRESENCE OF DDT IN THE SAMPLE CHOSEN FOR THE 6/16/88 MATRIX SPIKE AND DUPLICATE.
AN ASTERISK (*) BESIDE THE COMPOUNDS MEANS THE DATA WAS TAKEN FROM SAMPLES REEXTRACTED ON 6/15/88 AND ANALYZED ON 6/16/88.
INORGANIC ANALYSIS ON A "AS RECEIVED BASIS". THOUGH A DRY WEIGHT BASIS WAS REQUESTED, THE VERY LOW MOISTURE OF THE SAMPLES WOULD NOT HAVE SIGNIFICANTLY CHANGED THE REPORTED VALUES.
r / \ AnolyticolTechnologies, Inc.
CLIENT PROJECT # PROJECT NAME
MONTGOMERY 661 C HASSAYAMPA
& ASSOCIATES
ATI I.D.
DATE RECEIVED : 05/18/88
REPORT DATE : 07/13/88 805088
ATI # CLIENT DESCRIPTION MATRIX DATE COLLECTED
01 02 03 M 05 M~ 07
014392 014393 014394 ,024:1 5-014396 014397 SPLIT OF 80508806 (014397) PER QA
SOIL SOIL SOIL SOIL SOIL SOIL SOIL
05/17/88 05/17/88 05/17/88 05/17/88 05/17/88 05/17/88 05/17/88
TOTALS
MATRIX
SOIL
# SAMPLES
7
ATI STANDARD DISPOSAL PRACTICE
The samples from this project will be disposed of in thirty (30) days from the date of this report. If an extended storage period is required, please contact our sample control department before the scheduled disposal date.
ERROL L. MONTGOMERY & ASSOCIATES, INC. CONSULTANTS IN HYDROOEOIOOY 805088 I07S BAST rOAT lOWSU ROAO, SUITI B TUCSON. ARIZONA 8S7I9 (602) 881. 1912 TElEXt 165397 MONTE TUC
CHAIN OF CUSTODY LETTER OF TRANSMITTAL
ERROI I . MONTGOMERY, P.O.
JOHN W. HARSHBAROER, P.O.. P.E. DONAIO K. 0RCIN6, f . t .
RONAID H. DEWin
Date: / r^ /^-73&
Oob No.: ^ ^ / f T "
Attention of / / / / • ^ / . lO^^^Y
On / /ATY A ^ 7 ^ ^ € .^777 water^foTjJsamplef^ wascjweff)
1n /7^7AA.J^ parcel (s). delivered/shipped to you via A77ki7> /7s7^f&A9*A'
Custody seals were (were not) attached to the sampling and/or shipping
container(s).
Please perform the appropriate analyses within the maximum allowable
holding time limits which are indicated on the attached Analyses Request
Schedule/s.
If you have any questions concerning our analytical requests or if
the integrity of a sample(s) is in question (i.e., air bubbles, inverted
septum, broken custody seal, etc.) please notify us.
Results of your analyses should be reported to our Tucson office as
soon as possible.
Thank you.
Very truly yours,
ERROL L. MONTGOMERY & ASSOCIATES, INC.
By: "JJ^T?/? /<d.y?^
Title; jAf7)/^7^2?r77.A^A:.A^-r-
Attachment(s).
805088
SAMPLE
IDEMTIF IER
^
2A. B£.
j 9(r
CHAIN OF CUSTODY ANALYSES REQUEST SCHEDULE
ORGANICS
SAMPLE COLLECTIOH
BNA, ANO ,^ESTTCIDS"
DATE
^ ^ ^ H ^
TIME
VOLATILE ORGAMICS ^__^
ONLY* OHLy*"^ OTHER
6177-2^77 ^V7-gg )27t7 1 / - / ^
Z l ^ ^
1
£ K U O L L. MU lN l l j iU iV l t . l tX «S£ / i o . 3 0 L l ^ i l i : . c j , j i x L . CONSULTANTS IN HYDROCEOIOCY
MAXIMUM ALLOUABLE HOLDING TIHE,
STARTING FRON TIHE OF COLLECTION
1075 EAST FORT l O W E l l ROAD. SUITE 8
TUCSON, ARIZONA 85719 (602) 8 8 M 9 I 2
TEIEX: 165597 MONTE TUC
Project Ho ( H a s s a y a m p a )
/^/iA
A c c e s s i o n H o .
REMARKS
> ^ . g ; : ^ r ^ ^ i ^ ^ O - ^'<^yi7r
S ^ ^Z>J'Uj'7^jP'yA^A:7 A^AK
TL^^-f/T^^^ ^ d 7 > B ^
Please refer to Table 2 of QAPP - Analytical Methods and Detection Lfmfts for Hazardous Substances
Relinquished by: Affiliation: Date: Time: Received by: Affiliation: D a t e : Time:
: > , ^
S ^ 4 ^ '£t> / / . ' .Si ' 7p(/AfjX\77/AU f^T] fK- jiAT.
WS ^Q{'-r(^oiJ^q-i)ft^ A^^P
E R R O L L. M O N T G O M E I I Y & A S S O C I A T E S , INC. CONSUITANTS IN HYDROOiOlOOY
1C75 EAST'fORT lOWEl l ROAD, SUITE B iUCSON. ARIZONA 85719 (602) 881.4912 TEIEX: 165597 MONTE TUC
ERROI I. MONTCO/.-'raY. P.O. JOHN W. HARSHBARGER, P.O., P.E.
fin^nftft i DONAt.DK. GREENE, P.E. 8 O O O O O WIUIAM R. ViaOR.P.O.
EDWARD W. PEACOCK. P.G. I RONAID H. D£V/tn
CHAIN OF CUSTODY ANALYSES REQllEST SCHEDULE
"'T^^A&'L /h^*:7 ' , '^^<S
TO / 7Y77L Vr/^TTZ Y&^AiAA>7c<^A^S^ 7A/C.
FROM: To/yn r r i f T ^ r y
PROJECT NO:
ACCESSION NO:
c / ic
DATE OF SHIPMENT: ^ V g - g . g > NUMBER OF SAHPLES SHIPPED: ^
SHIPPED Vik- .yT^T)7?^7 t7Q/ r :^ CONTAINER: / ? / > ^ Z ^ ^ Z / t X ^
IDENTIFICATION OF SAMPt-S
Sample Number Itjgnt.lf.ijLlUoa
7lL±3lZ.fL Sampling Date (Time) . S.-iniDTQ Temo./Conductivitv/DH
f(ly (
i ^k^ 773lle?)
± JJUiT) f r f : /^
PPE-TPEATMCNT OF SAMPLES: 7 7 7 ) ^ ^ / i / y . A X , /
mimmmm TO BE mv. y^y}^^^ fg ;^^ j j_6 jAj J^7 l l
f ^ / ^ ^ ^ ^ / f i j J h ^ 017/777<7A7'r J7^ ^ / j ^ 5>;?z. ^ ^ ^ 6 ^
' A^^ ^/fev^^^sr^ ATO T ^ A ^ P / ^
Time: Rellnqulohed Ly
7^7' Received by:
Affiliation:
E.L. Montgomery i Assoclatas, Inc,
Affiliation:
m. Oate:
7« Date:' Time: j
7r7^Ai
CLIENT Q-
ADDRESS /7777^'fjf: A '
ftUTHDRIZED BY
7-7uA^7A7?j2 ^ ^ 7 ? ix7/777/)a.o
-1777777-
SAMPLE LDG-IN'-
ACCESSION NUMBER
DATE RECEIUED
L A B D U E
«i 8Q5088 j
2iAr inologies.lnc.
1 • !
777772>7i. 7 1 77%,
REPORT DUE.
UERBALS
Tn.
TELEPHONE NUMBER
PROJECT MANAGER 3^ TD.
BY
SDWA NPDES HAZ. UASTE PROFILE OTHER
MATRIX: DRINKING UATER GROUND UATER
/UASTEUATER 1 / SOIL
SLUDGE
HAZARDOUS UASTE O I L
SDLUENT A IR O T H E R
COMMENTS : y f ) j I f n ^ f ^
NUMBER OF SAMPLES / ^ ~ 7
SAMPLE CONDITION:
ARE THE SEALS INTACT? © ARE TAGS PRESENT? / ^ CHAIN OF CUSTODY? j T ) ARE TAGS, CONTAINERS AND CHAIN OF CUSTODY IN AGREEMENT? /Y)
DO NUMBER OF SAMPLES ^ ^ AGREE UITH C.O.C.? f j J
ARE SAMPLES COLD? / Y ) ARE THE SAMPLES INTACT? /JL IS THERE HEADSPACE ? . Q J IS THERE SUFFICIENT SAMPLE? TT)
N N N
N
N N N N N
N/A N/A N/A
N/A
N/A N/A N/A N/A N/A
GC/BC-HS
-401/602--404 -i06 -624/625-B010/B020-8240 /8270-
- 5 0 2 . 1 — - 5 0 3 . 1 — - 5 2 4 / 5 2 5 --TTHM
6C
6 1 5 -E D B -DBCP-P C B -
8150 B140 SDLV. SCR-
OTHER
NETALS
3 - ^AT^AM'I — C r + 6 — PREP:
EP TQX-'^'i7&.
INORGANICS
_ - f
— B r — C l — N 0 2 — — N 0 3 — — N H 3 — — 5 0 4 — — C N — p H — A L K — — H A R D -
- T S S — — S S -
— T D S -—COND-— P 0 4 -— O i G -
— S P . Br -— C O L O R -— P H A S E -— O D O R — — P E T . H Y D -—PHENOL —CATION EX-
OTHER LABS
TURBIDITY-COD
-COLIFORH--BOD RADIO-
OTHER
SAN DIEGO
TKN-TOC-
-lOX-Co-No-
mwitm i^mm. TUCSON, ARIZONA:WI« i!(M«''U1~»l2;^4^€ WM*' f69S9r m m wu' "'7 M 7 7 7 ^ 0 m !
^ -'••. • • 7 ' '7. ' :7¥¥
CHAIN OF CUSTODY TRAFFIC REPORT
reject ^^aJzhJjfr
/ J ^ a n l c nGrab - inorganic ^Composite
^ o i l • Water D Other
o
Sampling Site Name/Code/Well No.
Sampling Date ^ - / ' ^ - ' ^ ^
6 ^ - ^
Sampling Personnel: ^ . • Name V^;^/? / 4 g ? ^
Name
Name
and Time of Collection
Signature
Signature
Signature
Sample Number
17-./^
-Z^A
Sampling Point 4^Ai7^^^ xPx^ /TXi yOTTl: and Method of Sampling ^ 2o%> i o Z i ' S i * ^ .
Field Observations J^AT^ot^L^ -^AZ.-T^^ S ' ^ ^ ^ ^ ^ ; /.-r. A3/l^x..4 ^ ; ^ A ^ : TX^A , ^ ^
- T h j S i L 7 ^ ^ J > 5 - 4 > y ^ ^ ^ ^ 7 ^ ^ •Th-
Sample, Sample Container Data
Volume No. Used Lot No. Preservatives
/JAL. - L A'/>Ab'B
Analyses Needed iiC/t> : A e W / ^ o:^7^7L7^£22iS7
Destin. Ship. Method/Date
/\7i 'tZ77fe-e^
Special Handling Procedures A7)77ft31 z / u i ^ v r T^Af TTT^ A 77ZafAL:riA>Ko
Ti^77lfi^V77^7P'h'7t\ w ^^^^^/^WnW74\-'-'77 77x l i t iaSON, AW20NA 85719 ilWO8)'88M0lJ =^3^^
7B«X» I W ^ M 0 « « TW . ^'s'^J
• ; kf';-\ v . .
^^'
1' CHAIN OF CUSTODY TRAFFIC REPORT
roject N0.J2 T-''Organic n6j;ab ->^norganic etomposite
)Oil oWater a Other
03
014393
Sample Number
Sampling Site Name/Code/Well No.
Sampling Date ^ - / ^ • - ^ S '
^7x1.
Sampling Personnel: -Name _ ; 2 2 2 z 2 - ^ ^ 2 ^
Name
Name
and Time of Collection
Signature
Signature
Signature
I Z 3 4-0
W/<^
^ii/ti^^e 0fiA^^7^<^ - ^ 7 Sampling Point l!f}t,r:iibiocip7) di/iOAf m.s and Method of Sampling / >o ^r^^^/xxyi^^A^s.i-rbr
Field Observations AT^/^T^d^if ^?AAri 5;A:Un77^ A$»3gk3>^^j .' £ 7 7 ^ . ^ z ^ ^ ^ ^ ^ ^ - - ^ \ / ^ . s - ^
^ / ' ^ z ^ t7:r.>9 cpA ix^^
Sample,' Sample Container Oata
Volume No. Used Lot No. Preservatives Analyses Needed Destin. Ship. Method/Date
L ^ e>&
Special Handling Procedures C h O j J?f\ TTAX 7 C / ^
77
<»
• m^m^7>"${A7-7. v CHAIN OF CUSTODY TRAFFIC REPORT
1079 EAST WRT lOWIU R6A0/8lllTe'8i|;t.J;S^ TUCSON, ARIZONA 65719 (M2) U i 4 9 l 2 % l s . l f W U * IM«V MOHm TMC 7^-Jx ;^
,'.7'.', '%q:'
I • ••!,!: •• • ..-"J-p.; .-#iS:'.w
; • ; ^ \ :• . r M : ? i % '
i"oject No
"prganic •inorganic
.JMI aXomposite • Water
a Other Sample Number
Sampling Site Name/Code/Well No.
Sampling Date S ^ - 7 1 - f ^
6 ^ - ^ and Time of Collection / ^ O S ~
Sampling Personnel: __ Name T A P D O J A A s r ^ y
Name
Name
Signature
Signature
Signature o;' *?<KLe- Q-a /Sro fe
Sampling Point 77oujC7?i^ft-'rrP 7. r?g v»u n-p and Method of Sampling / P "^/dszi^S7<^^2r/^f:s^r^^^
Field Observations A/C^Y 7 , m j ^ t A ^ S^/bu.^', 7 :A ^ac=Lu^} 7 7 ^ ' A ^ - s ^
Sample,' Sample Container Data
Volume No. Used Lot No. Preservatives Analyses Needed Destin. Ship. Method/Date , '(^(i>a a ^ } ' l / f ( ^ -' '' /
^422:
Special Handling Procedures ( 2 ) / ) / .TT l O A J lAJ^ T
I
-> tif ik-K .'•""••' • ' ' • ' • ^ ' ^ • • 7 . ' - y ; ^ : M 7 r ^ ^ ^ ^ a m ' i m ? m f f t m ' . •'"'".7m7 •' '
^ m m • : \'77'. 'r-m^mm \7]7^i
CHAIN OF CUSTODY TRAFFIC REPORT
roject ^ ^ . M L L C
/i^rganic QGrab o^oil -^Inorganic ja-Composite • Water
D Other
Sampling Site Name/Code/Well No.
Sampling Date 7 . j ' -7 ' J - -3^
o
iple Number
^7^-7 and Tiine of Collection / 3 - ^ ^(7D
Sampling Personnel: Name %f7r? iTJWTA
Name
Name
Signature
Signature
Signature
^7J4 ,
Sampling Point / ^ M ^ i lA7/z i r< i^>^^ and Method of Sampling f p^T i ^ ' y^T^ . ^ /<fev»y^ "^^ X A J \ ^ - ^ * < * ^
Field Observations 671-^"^ 7>A>AoyO ( A ^ ^ / ' A - D X / /S'.4£=& i!L>, 77/9^ 7^2>c -s^ > gg*
Volume No. Used Lot No.
/ z ^ — L
Sample,' Sample Container Data
Preservatives Analyses Needed Destin. -^&7>^ ^ . . ^
' (A<2AO /?/c?. )
Ship. Method/Date
Special Handling Procedures A A ^ L I W /^AJ 7<7if
/
<k7^7ij W7^j7titii7^ I 11 ,/ ' n i 1 ; / ' -• ih '.I'^irar, f M
I \ > w
• ' - - - • • - - - ' : ' - - • • • -•-- -• '• - ' " ' • • ' - V - ^ T V f . f « ! g V f l J 1070 JAtST K m lOV/tl l ROAO, MJiTC »
^TUCSON, AfllWNA W719' WOJ) i 8 | . 4 9 l i a i s ; M
J<oo| ••; ' -"^ 'AriTl -rA''7m'\ 7x:m^x
, tiv. '\A^ •: i
CHAIN OF CUSTODY TRAFFIC REPORT
roject Mo. {?^/A
^ g a n i c a Grab --nnorganic cKomposite
DiT^il DWater D Other
o
Sample Number
Sampling Site Name/Code/Well No,
Sampling Date ^ - ^ / ^
7 7 " ^ and Time of Collection /^>' y S ^
Sampling Personnel: Mame ^ ^ 7 0 f ) A 4 t f 7 ^
Name
Nanie
Signature
Signature
Signature
^Z</ 7 ^ Xi
Sampling Point T^dXiUi 7., zs fm- -zsL -rt-^-e. and Method of Sampling /^^CJga^g'r'^/^/v^g^zgtr^ssj--hoZ. y o ^ ^ ^ ^ ^ A T Z . 2-s*cc^<£rr
Field Observations ^74-7v C7ex^<f^c<x S i w ^ U ^ C . ^ ^ ^ . ^ ;. ,^^^;, i ^ ^ s i ^
Volume Wo. Used Lot No,
[-M. - I — j z :
Sample, Sample Container Data
Preservatives Analyses Needed Destin.
7 ^ 0 ^ < ''^•Jy>K./<«A^S- TUX-(AC i lD 7>J^. )
Ship. Method/Date 1 7 ^ •• / ^
Special Handling Procedures T7h/j7(^.^ < XA> 7A7^
'i^-'V
CHAIN OF CUSTODY TRAFFIC REPORT
. , t707
roject No. f i / ^ f C
^^S^anic ^Inorganic
OGrab oxomposite
o Soil
• Water a Other Sample Number
Sampling Site Name/Code/Well No.
Sampling Date 5 ~ ^ / ' 7 ~ " < ^ ^
7^~L, and Time of Collection / $ ^ V S ^
Sampling Personnel: _ ^ -Name A7iC>ZP / 7 & 9 y Signature
Signature
Signature
'i/72A^^.f< ^ and Method of Sampling
Field Observations -^i t^r^ s^w^ { f p O / 4 ^ ^ \ } ^Ak ' ^^y^ )
Sampling Point
Name
Name
W77 ,
^ ' ^ ^ ^ ) P 7 ^ ^
Volume No. Used Lot No.
/ ^ - I
Sample,' Sample Container Data
Preservatives Analyses Needed Destin.
C^<xOCtc)
Ship. Method/Pate
Special Handling Procedures AA^27de77 , />/\7 7 C ( f
55/ - SSL
/ \ AnolyticalTechnologies, Inc ACCESSION: 8050B8
QUALITY CDNTROL DATA
CLIENTS MONTGOMERY AND ASSOCIATES DATE RECEIVED: 5/18/88
METHOD: 608 UNITS: ug/l DATE ANALYZED: 6/14/88 ANALYST: EP
REFERENCE SAMPLE: SEPARATE SOURCE
ANALYTE VALUE FOUND 7. RECOVERY
LINDANE ENDRIN DDT
0.188 0.178 0.1 A7
. 1 7 94 89 74
PROJECT MANAGERS ^ f m J / U j DATE 8 / 1 8 / 8 8
;HRRT' SPEED 0.6 CM/MIN ^trtN: S ZERO: 10%
-STAT-'/ll-JJECT
1 MIN/TICK. ATTEN: 16 ZERO: 105 I MIN/TICK
~^R:OFF
DBHC
1 1 . 5 7 3 1 2 . 0 1 1 irulu t ^
INDAi4€
n^IEP^CHLO 1 3 . 8 3 9
" ^ b & R l N M . 9 8 5
12.873-
J 7 >-' '
ISO BR tn 17.294 17.773 18.401
16.393
"U-i-ELDRIN 19.028 - 19.402 e ^
A n rl
1 m^er ,£K^0 11 20. 534
20. 022' T)V) T
_£iSRTN~AL 21.588" " 21.213
HB^
22.165 22.700 23,151 23,550
\
24.491 SURR 24.987 25.084
26,997
30.030 30.505
t-'.E: PESTICIDES
HHNNEL NO: 2 SAMPLE: QC 1-38-1
:AK -JO
1 2 3 4
PEAK NAME
A BHC
RESULT UG/ML 0.0000 0.0000 0.0008 Pl - RPlPlO /
TIME CMIN) 7.324 7. 433 1 1 .573
0: 13
METHOD: DB608
TIME OFFSET
-0.207
AREA COUNTS
639 754 1569
SEP CODE BV VB BB
Wl/2 CSEC)
? 5.90 ? 7.45 ? 12.40
"l'l iLt :' K£i 1 1 Cl utS
CHANNE':. NO:. 2
PEAK NO ^ •
o 4 5 6 7 8 9 10 1 1 12 13 14 15 16 17 18 19 20 2 1-
PEAK NAME
A BHC ,. -^ jLlNDANE j,
HEPTACHLO ALDRIN UsODWTjT i 1 HbPI EPOX
ENDO I DDE -DIELDRIN
I H D R U D m ^ ^ ^
22^DDJ\-23 24 25 26 27 28 29 30 31 ~->
i4 35
ENDRIN AL ENDO S04
METHOXY
HBB SURR
TOTALS: 1
SAMPLE:
RESULT UG/ML 0, 0000 0.0000 0.0008 0.0000 / 0. IB107
—0r^'000 0.0048 0.0021 /
12. 3690^/ 0.0012 0.0000 0.0000 0.0013 0.0039 0.0005 0.0000 0.0000 0.0000 0.0259 0.0050 0.0000 0.0340 0.0021 0.0039 0.0000 0,0000 0,0000 0,0000 0,0000 0,0000 0.0028 0,0000 1,4492 0,0000 0.0000
14.0870
QC 1-38-1
TIME C M I N ) 7,324 7, 433 1 1 .573 12.011 12.873 13.839 14.296 14.985 16.393 17.294 17.450 17.773 18,401 18.547 19,028 19,402 19,687 20 , 022-0.1'^ 20,299 20,534 2 1 , 2 1 3 0. VZ-21 . 588*'^ 21 .953 22,165 22,700 22,809 23,151 23,231 23,439 23.550 23.891 24,491 25,084 30,505 30,814
y •
METHOD
T I ME OFFSET
-0,207
-0.207
0. 156 -0.225 -0.007 0.314
0. 291 -0.203 -0.052
t ' / ichin 0. 049 0.024
307-
0. 148 0. 133 •
-0.025
-0.279
0. 084
-0.006
ll 1 4 .
DB608
AREA COUNTS
639 754 1569 695
302673 •-32"ie • 4549 3168
229793 -1730 628
3723 1725 5572 617
2467 1604
14'^R70 . 12720-51^9
161258 i 7 i ^ n r 2144 3260 2273 829 1566 828 867 670 939
31429 721 568 1705
953019
u it a d
SEP CODE BV VB BB BV VV VV VV VB BV VV VV VV VV VV VV VV VV VV VV vv vv vv vv vv vv vv vv vv vv vv vv vv VB vv VB
? ? ? ?
?
7
?
">
?
7 ? -> ? ? ? -> T'
? 7> -?
Wl/2 CSEC) 5. 90 7.45 12.40 7,95 4,80
36,50 5.80 5. 50 6. 00
12. 50 9.50 14.00 15. 00 7.95 7. 00 14.20 14.10 6.10 9, 00 12.30 5.75 6.70 8,50 13.75 24.50
5,00
2,40 16,90 8.25 7.55
34,30 42,80 22.20
i- -", )ETECTED PKS: 47 REJECTED PKS: 12
)IVIS0R: 1,00000 MULTIPLIER: 1.00000
JOISE: 4.9 O F F S E T : 10
JACK: 16 V I A L : 4 INJ: 1
JOTES: DB608 PRIMARY COLUMN
b t
•s)^'^
18.989 19.680
25.261 25.942
29.835
20.329
= — = = 24.546
DETECTEI? PKS: 47 REJECTED PKS: 12
DIVISOR: 1..,00000 MULTIPLIER: 1,00000
NOISE: 4,9 OFFSET: 10
R< ': 16 VIAL: 4 INJ: 1
NOTES: DB60S PRIMARY COLUMN
t-''
• ^
TITLE : PESTICIDE
CHANNEL N O : 1
PEAK NO
1 2 3 4 5 6 7 8 9 10 1 2 13 14 15 16 17 18
PEAK NAME
DBHC
HEPTACHLO
DIELDRIN END ALD DDT
METHOXY"
TOTALS:
CONFIRMATORY
SAMPLE:
RESULT UG/ML 0,0000 0.0000 0.0000 0,0000 0.0039 0.0000 0.0081 0,0000 0,0000 0,6162 0,0201 1.0930 0,0000 0.0000 1 , 8210 0.0000 0.0000 0.0000
3.5623
SAME
TIME CMIN) 7,386 7, 441 8. 365 9,022 10,308 12,250 12,874 13.154 15.698 16.577 18.541 19.416 19.780 20.166 20.917 22.277 23.192 23.381
0:
METHOD
TIME OFFSET
-0,
0.
-0. 0 0
0
0
102
164
193 261 326
157
613
13 14
: DBS
AREA COUNTS
3092 1719 2298 1996 2151
268221 3685 4270 8238
228220 5442
185246 13450 25686 182097 51316 1320 595
989042
JUN 88
SEP CODE BV VB BB BB BB BV VV VB BB BB BB BV VV VB BB BB BV VB
? 7 ?
?
7 ?
? ?
Wl/2 CSEC) 4.80
5.20 5.50 4. 40 6.30 4.80 8.50 5.75 7.30 6.05 7.05 7.65 7.40 7.00 6.30 2.60 2.60
DETECTED PKS: 21 REJECTED PKS: 3
DIVISOR: 1.00000 MULTIPLIER: 1.00000
N I O I S E : 3 4 . 0 OFFSET : 25
RACK: 16 VIAL: 4 INJ: 1
lOTES: DB5 CONFIRMATORY COLUMN
RT SPEED 0.6 CM/MIN I ' E N : e ZERO: l<d'A 1 M I N / T I C K
"STAT—T/INJECT
A T T E N : 16 ZERO: 10% 1 M I N / T I C K
2 . 3 3 4 m ^
1 . 9 2 9
SSI - SSL
AjS AnolylicolTechnologies, Inc
ACCESSION: 805088
QUALITY CONTROL DATA
CLIENT: MONTGOMERY & ASSOCIATES DATE(S) RECEIVED: 5/18/88
METHOD: 608 UNITS: ug/1 DATE ANALYZED: 6/16/88 ANALYST: MGB
EPA REFERENCE SAMPLE: SEPARATE SOURCE
PARAMETER FOUND ug/l % RECOVERY
LINDANE 0.202 101 ENDRIN 0.226 113 DDT 0.229 115
NOTES: NA = NOT APPLICABLE
PROJECT MANAGER: /77 loi/M/lll DATE: 6/24/88
CHART SPEED 0,6 CM/MIN A" N: 8 ZERO: 10% 1 MIN/TICK
rTAT~7INJECT
0, 674
ATTEN: 16 ZERO: 10% 1 MIN/TICK
'^ 1 , 5 5 7 2 . 157
5 . 9 1 8
' ^ ^ 1 ^ 7
— — j 9 , 725
1 1 , 9 8 8 •IND$J4E '
099 -ALJDi^N 1 4 , 7 9 1
o^±u — 1 7 , 2 8 4
- 1 7 , 8 0 2 EHDO I 1 8 , 2 9 3 .
- " T i l L D R I N 1 9 , 0 3 4 n j f i f i f 1 9 . 9 9 6
^0-T-506 ENDR±fc*-'-Rt"~~ 2 1 .259 :NDia S04 2 1 . 870
2 2 . 4 5 6
M&? HOXY 2 3 . 4 6 7 2 4 . 0 3 8
3 0 . 0 1 7 3 0 . 7 7 0
1 2 . 7 2 8 -
1 5 . 5 0 9 =• 1 6 , 166 —^^
/ i d
J 9 . 586 u ^
TITLE: PESTICIDES
CHANNEL NO: 2 SAMPLE: K©*
2:11 1.4 _ iilUa
METHOD: DB60e
30.017 30.770
; TITLE : PESTICIDES 1 r U £ KJ KJ c" 1 kin* n
. U n H M I N
' PEAK 1 NO
1 2 3 4 5
1 6 7
1 B 9 10 1 1 12 13 14 15 6 1
1 8 19 20 21 22 23 24 25 26 27 28 29 30
PEAK NAME
LINDANE HEPTACHLO D-BHC ALDRIN ISODRIN
ENDO I DDE DIELDRIN
ENDRIN ~--^ DDD ENDO I I
D D T • •
ENDRIN AL ENDO S04
METHOXY
TOTALS:
SAMPLE:^
RESULT UG/ML 0,0000 0.0000 0 . 0000 0 . 0000 0.0000 0.0000 / 0. 2017*'^ 0.0028 0.0018 0.0032 /
1 15,7370V/ 0.0000 0,0000 0,0049 0,0012 0.0005 0,0000
_ 0 . 0000 — 0.0250 0.0033 0 , 0 0 6 6 ^:
— 0, 0000-^ f \ iTi yl 7 O 0 04?^ 0.0269 0.0278 0.0000 0.0000 0,0021 0,0000 0.0000
116.0880
_ _ . _ _ — • —
<V' 1 - C= <-
T I M E C M I N ) 6. 994 7.278 7.377 9.725 9,893 11,988 12.728 14.099 14,424 14.791 16,166 17,284 17,802 18,293 18,588
ul9,034 5)>!>f9,383 -^19, 7 0 7 —
l-9-,.-996 ^ 20,290 1^20,506
20,892—
2 1 .259 21 .442 21 .870 22.456 22.598 23.467 24.038 30.770
, ) 2:
METHOD
TIME OFFSET
-0.062 0. 259
-0.086 -0.099 -0.234
0. 183 -0,162 -0,046
0,116 0, 140 0,066
0. 1 79 0. 002 0. 050
-0.283
0, 023
11 16
: DB608
AREA COUNTS
556 593 1062 1696 3786 9956
337299 2656 2710 4868
236680 2155 3149 6380 1678 735
2472 - 1 47124 - 1 6 2 ? 7 ^ ^ 5 4 5 0
7833 - 172733
,32510 27226 23405
986 1398 697
37917 7994
1097940
JUN 88
SEP CODE BV VV VB BV VV VV VV VV VV VB BB BV VV VV VV VV VV VV vv vv vv vv vv Y V ~ ~ vv vv VB BV VB VB
? ?
9 ?
? ?
?
?
? ?
_?_
? ? ?
7
Wl/2 CSEC) 6. 10 6, 00 6. 30 6.00 14,80 25.40 4, 95
15,05 6,20 5.90 12.50 12.25 1 1 .70 16.50 7, 40 12,50 6. 00 8.45 5.70 9. 60 5.60 8.70 3^213-
39.30 4.80 4,20 5.90 7.50
30,65
DETECTED PKS: 35 REJECTED PKS: 5
DIVISOR: 1,00000 MULTIPLIER: 1,00000
N O I S E : 7.3 OFFSET: 3
'RACK: 16 VIAL; INJ: 1
NOTES: DB608 PRIMARY COLUMN
T I Tl D C C T I r I nr r . r \ i . \ r r T rwj, ^ - f /-..-..
NOTES: DB608 P'RIMARY COLUMN
TITLE: PESTICIDE CONFIRMATORY
CHANNEL NO: 1
PEAK PEAK NO NAME
1 2 3 4 5 6 7 ENDO I 8 END ALD 9 DDT
) 10 1 1 12 METHOXY" 13
TOTALS:
SAMPLE:
RESULT UG/ML 0 , 0000 0.0000 0.0000 0.0000 0.0000 0.0000 1.0418 0.0176 1.3537 0,0000 0,0000 2,2430 0,0000
4,6561
SAME
TIME CMIN) 7, 7, 7, 8 12 15 16 18 19 19 19 20 22
274 332 788 579 068 509 381 356 210 586 962 716 055
2:
METHOD
TIME OFFSET
0, 301 0, 076 0, 120
-0.044
0,453
1 1 16
: DB5
AREA COUNTS
6702 2716 2553 3813
322493 9024
2671 16 4749
229434 23628 2561 1
224298 65767
1187900
JUN 88
SEP CODE BV VB BB BB BB BB BB BB BV VV VB BB BB
Wl/2 CSEC) 4,35
? 9.80 4. 05 4.85 6, 60 5, 70 7.40 6,30 7,45 7.90 7.45 7,35 6,55
DETECTED PKS; 16 REJECTED PKS:
D.,IS0R: 1,00000 MULTIPLIER: 1,00000
'NOISE: 30,4 OFFSET: -1
RACK: 16 VIAL: 2 INJ: 1 I
' NOTES:
, DBS CONFIRMATORY COLUMN
•CHART SPEED 0,6 CM/MIN ATTEN: 8 ZERO: 10% 1 MIN/TICK
JTAT—:
ATTEN: 16 ZERO: 10% 1 MIN/TICK
S R :
. 7 2 5
- A - l - . . -4^^
. -1 • R ? A 2 , 3^11
iT - 2 . 8 7 4
4 . 7 1 9
3 . 8 2 2
5 . 9 1 1 SR:OFf
7 . 6 6 3
8 . 5 7 2
B P H ^ T 1 0 . 1 4 8
7 . 2 5 0
rsv
A. AjS AnolyticalTechnologies, Inc
GAS CHROMATOGRAPHY - RESULTS
ATI I.D. : 80508804
TEST : ORGANOCHLORINE PESTICIDES AND PCB'S (EPA 8080)
CLIENT PROJECT # PROJECT NAME CLIENT I.D. SAMPLE MATRIX
MONTGOMERY & ASSOCIATES 661 C HASSAYAMPA 014395 SOIL
DATE SAMPLED DATE RECEIVED DATE EXTRACTED DATE ANALYZED UNITS DILUTION FACTOR
05/17/88 05/18/88 5/23/88 06/14/88 MG/KG
1
COMPOUNDS RESULTS
I II SULFATE
ALDRIN ALPHA - BHC BETA - BHC GAMMA - BHC DELTA - BHC CHLORDANE 4, 4'-DDD 4,4'-DDE 4,4'-DDT DIELDRIN ENDOSULFAN ENDOSULFAN iNDOSULFAN ENDRIN ENDRIN ALDEHYDE ENDRIN KETONE HEPTACHLOR HEPTACHLOR EPOXIDE METHOXYCHLOR TOXAPHENE AROCLOR 1016
1221 1232 1242 1248 1254 1260
AROCLOR AROCLOR AROCLOR AROCLOR AROCLOR AROCLOR
SURROGATE PERCENT RECOVERIES
<0 .005 <0 .005 <0 .005 < 0 . 0 0 5 <0 .005 <0 .05 < 0 . 0 1 * 0 . 0 2 6 * 0 . 0 1 9 * < 0 . 0 1 < 0 . 0 1 < 0 . 0 1 < 0 . 0 1 < 0 . 0 1 < 0 . 0 l < 0 . 0 1 <0 .005 <0 .005 < 0 . 0 5 0 . 1 8 * <0 .05 < 0 . 0 5 <0 .05 <0 .05 <0 .05 <0 .05 <0 .05
<?l^3?7
Calviwj\..
2 S»^ 7 fTt^cwiuhr^WtiiA. AA-.^
j L h t U i M l . M f f f ^ -fk
IUM-J o»vt -ftmn.
Oi/il'lif ^d,js7a oUA,
ISODRIN (%) 95
^ DATA TAKEN FROM SAMPLES REEXTRACTED ON 6/15/88 AND ANALYZED ON 6/16/88.
? • • • • • •
NJ I
W CHART SPEED 0 . 6 C M / M I N g A T T E N : 8 ZERO: 10% 1 M I N / T I C K a" a
ATTEN: 16 ZERO: 10% 1 MIN/TICK
AT :
. 121 ^ / 3,925
4, 492 4, 997 - 5. 47.L
O B BSel 1 3 . 4 0 4
CD D-Bfct£ir l 4 ,
ALSR ...15, 653
21.912 22.508 23.087
' 16.352
20.268
24.479
18.495
20.872
TITLE: PESTICIDES
CHANNEL NO: 2
PEAK PEAK NO NAME
1
)5'^g<?-i SAMPLE: -0 —T -yEf 1
RESULT UG/ML 0.0000
TIME CMIN) 6.296
8:42 14 JUN 88^
METHOD: DB608
TIME OFFSET
AREA COUNTS
AR01
SEP CODE
\ l \ i
W l / 2 (SEC)
O 1 O e:e;
2_ - a .
?
5
o fit r-f
Z p M M CJ O) 00
5~ a
o D) r*
z ro CO "sJ • J
X
0 .4, . o
:i.
TITLE : PESTICIDES
CHANNEL NO: 2
PEAK uo
1 2 3 4 5 6 7 8 9 10 1 1 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 •^1
2 33
O 34 ^ 35 CZ ) 36
37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54
PEAK NAME
A BHC
LINDANE B BHC
HEPTACHLO
D-BHC
ALDRIN
ISODRIN
HEPT EPOX
ENUO I
DDE DIELDRIN
ENDRIN DDT
ENDRIN AL ENDO S04
METHOXY
HBB SURR
TOTALS:
SAMPLE:
RESULT UG/ML 0,0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0,0000 0 , 0000 0.0009 0 , 0000 0.0000 0.0000 0.0044 0.0079 0,0000 0.0000 0.0000 0.0037 0.0000 0,0018 0.0000 0,0000 0,0016 0,0000 0.0000 0,0000
105.3880 0.0000 0. 0021. 0 , 0000 0.0000 0.0007 0 , 0000 0,0037 0,0084 0,0000 0.0000 0,2883 0,4818 0,0000 0,0098 0.0064 0.0000 0.0000 0,0000 0.0000 0.0000 0.0033 0.0000 14.3815 0.0000 0.0000 0.0000
120.5940
QC 1-39-1
TIME CMIN) 6.286 7.4 13^ 8.096 9.024 9. 177 9.779 10.167 11,334 11,530 11.771 12.089 12,369 12,664 12,845 13.404 13.464 13,648 13.906 14.078 14.283 14.442 14.817 14.946 15.224 15.442 15.653 15.669 16.352 16.628 17.318 17.433 17.772 18,113 18,493 18,798 19,318 19,692 19,972 20,268 21,170 21,635 21,912 22.183 22,508 22,673 23,087 23,273 23.731 23,901 24,479 24,705 25.729 26,397 27.807
e:
METHOD
TIME OFFSET
-0,009
-0.235 0, 104
-0,062
-0.068
0.014
-0.048
0.338
0.003
0. 048 0.238
0.018 -0.270
0.092 -0.007
-0,269
-0.295
-0.408
42 14
: DB608
AREA COUNTS
4891 812 1279 658 523
2069 4903 2784 518 1833 2472 31 19 3305 7367 5242 1907 3730 4744 3453 7546 2818 5096 6058 2405 1342 615 698
215517 4394 3107 3161 6197 863
63703 5215 1 1241
938 7913
141659 242094 30504 9905 5414 1805 4953 4371 1937 1785 1 1 16
104522 7155 859 831 713
963959
JUN 88
SEP CODE VV BV VB BV VB BV VB VV VV VV VV VV VV VV VV VV VV VV
vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv VB
?
?
? ?
? ? ? ? ? ? ? ? ? ? ? ? ? ? '> ? ? ? ?
? ? ?
?
? ?
-> ? ?
?
? ? ? ?
Wl/2 CSEC) 12.55 5.95 8.00 7.20 9.90 7. 10 5.90
14. 10
13.00 12.80 9.50 19.40 12.30 28.20
6.20 13.20 5.80 13. 15
8.90 9.55 12.75 14.35 4.85 6.05 6. 10
21.00 13.70 19.40 1 0. 35 8.65 6.85 1 . 10
16.00 6.70
22.50 8.70 5.95 9.70 5.90 1 .70
10.30 17.60 13. 15 6. 00
29.00 6.90 6.95 0.30
25.60 24.20 57.40
DETECTED PKS: 97 REJECTED PKS: 43
DIVISOR: 1.00000 MULTIPLIER: 1.00000
\ SE: 4.9 OFFSET: 10
^RACK: 16 VIAL: 3 INJ: 1
NOTES: DB608 PRIMARY COLUMN
NOTES: DD608 PRIMARY COLUMN
TITLE : PESTICIDE
CHANNEL N O : 1
PEAK NO
1 2 3 4 5 6 7 8 9 10 1 1 12 13 14 15 16 17 *
20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43
PEAK NAME
DBHC
HEPTACHLO ALDRIN
HEPT EPOX
DIELDRIN
ENDRIN DDD END ALD
ENDO S04 DDT
METHOXY"
TOTALS:
CONFIRMATORY
SAMPLE:
RESULT UG/ML 0,0000 0,0000 0,0000 0,0000 0.0000 0.0000 0.0000 0,0000 0,0000 0,0000 0.0050 0,0000 0.0000 0,0000 0.0000 0.0055 0.0198 0 , 0000 0,0245 0,0000 0,6097 0,0000 0,0329 0,0142 0,3396 0.0000 0,0168 0,0633 0.0000 0.0000 0.0000 0,0000 2.4787 0.0000 0.0000 0 , 0000 0,0000 0.0000 0.0000 0. 0000 0 . 0000 0.0000 0.0000
3.6099
SAME
TIME CMIN) 6. 800 7.367 7. 773 7. 875 8.084 8,705 8.902 9.200 9. 937 10.280 10,517 1 1 ,372 12,227 12.396 12.488 12.848 13.704 14.305 14.964 15.678 16.536 17,372 17,547 18. 1 15 18.495 18.715 19.016 19.372 19,725 19.888 20,369 20,607 20.872 21.192 21,418 21.537 22.024 22.200 22.557 23.122 23.302 23,570 23.945
8:
METHOD
TIME OFFSET
0, 107
0. 138 -0.096
0. 004
-0.234
0,047 0, 155 0.215
0,016 0,282
0.112
0.746
42 14
: DBS
AREA COUNTS
3786 192381 1431 1 9537 1 1030 16616 7202 4104 9108 1 1865 2772 10322 5715 3908 2181 2502. 9420 2714 1 1 152 31867
225812 6900 9380 4308
91773 29870 5100 10736 99182 134494 16701 14640
247872 18303 7193 9447 18538 13477
129964 32183 4853 8341 4290
1505850
JUN 88
SEP CODE BV VV VV VV VV VV VV VV VV VV VB BB BV VV VV VB BV VV VV VV VV VV VV VV VV VV vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv VB
?
? ? ?
? ? ?
?
? ?
?
? 7 ? ? ? ? ? ? ? ? ?
? ? ? ? ? ? ? ? ? ?
Wl/2 CSEC) 14.60 6.30 9.65
17.65
33.80 20.50 12.00
4.70 5.40 5.60 15.90 7.00 6.00 7. 10 9.40 12.65 7.20
15. 10 8.90
24.30 5.50 5. 10
15. 10 1 1 .20 7.65 5.20 7.20 7.70
19.80 8.90 4.75 17.20
7.05 8.70
)ETECTED PKS: 69 REJECTED PKS: 26
)1 JOR: 1.00000 MULTIPLIER: 1.00000
•IOISE: 3 4 . 0 OFFSET: - 4
? A C K : 16 V I A L : 3 I N J : 1
40TES: DBS CONFIRMATORY COLUMN
• D I V ! S ' j P.: ! . 0 e 0 ' j 0 t'l Ll •_ T I F' L 1 E F;: l . id 0 v H <:
•"^NOISE: 3 0 ; 4 ' O F F S E T : 46
R A C K : 16 V I A L : 9 I N J : 1
NC'S: 5 CONFIRMATORY COLUMN
ooP "
CHART SPEED 0.6 CM/MIN ATTEN: 8 ZERO: 10% 1 MIN/TICK
~STAT"~7INJECT
ATTEN: 16 ZERO: 10% 1 MIN/TICK
12.265 INE 12.734
-HE^^Cljlgi-^^
> -tL^BRe 14! 686 . 774
ISO D i-N
17.078 17.579
0 ~D4^ D
! -trD-T
L D R I N 19.021 19.41^ DDO
20.021
t E t i £ R ™ ~ A L 21 . 3 7 2
2 2 . 7 6 9
HBfi SURR 2 5 . 2 3 2 2 5 . 8 8 8 2 6 . 2 0 5
2 9 . 2 9 3 2 9 . 9 9 0
3 0 . 8 2 9
2 . 2 9 9
~ ^ R : 0
\^\7'^ ^ ^ 1 6 . 1 7 4
nV\
1 8 . 2 8 3
- I i I E n y ^ I N 1 6 . 6 4 7
=4 DD"T ^ „ „ ^ METHO
2 0 , 8 9 5 — —gg 485-
— = ^ 21 . 8 4 4
Wt>
2 2 . 3 8 5
T E
^ ^ 1 1 / N II 1 L
: PESTICIDES
CHAN Ntl- nu. CL
PEAK NO
1 2 3 4 5 6 7 8 9 10 1 I 12 13 14 15 16 17
^ ^8 ^ 19 ? 20 : 21 ] 22 ) 23 > 24 ; "5 '•) 6
27 ? 28 : 29 L 30
31 : 32 , 33
34 35
? 36 37
'- 38 39
^ 40 J ''1 •) 42 » 43 r 44 L 45 ' 46 . 47 ) 48
PEAK NAME
A BHC
LINDANE
HEPTACHLO
D-BHC ALDRIN ISODRIN ^^'f HEPT EPOX
ENDO I DDE DIELDRIN
ENDRIN DDD
ENDO I I DDT ENDRIN AL
ENDO S04
METHOXY
HBB SURR
r TOTALS:
J DETECTED PKS:
t D I V I S O R : 1 .0000e
<- ISE: 7.3
? RACK
SAMPLE: P1
RESULT UG/ML 0,0000 0 , 0000 0,0000 0,0000 0,0000 0,0000 0 , 0000 0,0000 0.0000 0.0000 0,0004 0.0000 0,0000 0.0004 0.0000 0.0013 0.0000 0,0016 0.0019 /
105.6720v/ 0.0004 0,0000 0,0000 0,0000 0,0000 Ch r > - i rx / .
• k? , icJ o lc' D —
—10.0035 0,0024 0,0000 0.0060 / 0,0217/ 0,0000 0,0044 / 0. 1 156>/ 0,0188 0,0000
• 0,0021 0.0000 0,0000 0,0000 0,0000 0.0000 0,0041 0,0000 2.7135 0,0000 0.0000 0.0000
108.6010
• ^ ^ " > v . rx7^" ^(% 3.BJZ3aS=r'
TIME CMIN) 6, 101 6,299 6. 363 6.921 7.381 7. 940 8. 134 9, 198 9. 742 10,115 1 1 ,502 12.265 12.734 12.836 13.389 13.774 14.159 14.686 14.792 16.174 16.767 17.078 17.313 17.579 17,923
- 1 Q " P"? 1 0 . C-D 0
18.591 19,021 19,412 19,703 20,021 20,322 20.525 20.895 21,372 21,628 21,914 22.048 22,181 22,769 22,947 23.382 23.492 24.071 25.232 25.888 26.205 30.829
7:
\5P METHOD
TIME OFFSET
-0.008
0, 046
-0,066
0, 176 -0,098 -0,226 0,117
Pl 1 "> " v . 1 / 0
-0,159 -0,059
-0,177 -0,129
0,085 -0,185 -0,068
0, 094
-0,258
0,232
-0,510
90 REJECTED PKS: 42
M U L T I P L I E R : 1,
OFFSET: 1 1
: 16 V I A L : 10 INJ: 1
00000
02 16
: DB608
AREA COUNTS
1595 1237 751 992 1955 969 585 542 918
2535 739 1 190 1 179 606
2022 1208 1403 2502 2924
216098 577 1 160 2038 2750 4141
39975*' 4955 3209 2449 3923
JUN 88
SEP CODE VV VV VB BV VV VV VB VB BV VB VB BV VV VV VV VV VB BV VB BV VV VV
-» VV ivhiV— -
-7 vv vv VV VV
,VV 22486,B2i VV 6898 5206
86908^ 19051 4297 1791 2091 3526 3965 2251 2129 1367
135710 1350 1087 939
6021
614200
VV ^-1, Y V "21 VV
^VV VV VV vv vv vv vv vv vv VB BV VV VB BB
^
7 9
?
?
?
? ?
7
7
7
7 7 7 ?
7 ? ?
? ?
Wl/2 CSEC) 6.55 6, 70 9,00 9, 90 7.75 4,25 4,60 4,05 7.50 5,65
10. 30 5. 40 12,20 19.20 6.20 7.90 4,70 6. 40 6. 15 6, 20 3,40 8.25^^
J><75 6.00 9.30 5.65 1 1 .35 10, 00 8.80 9.05 6.50 1 1 .45 10.45 5. 40 8. 10 1 1 ,80 7. 90 7, 10 7.00 6.65 7.10
17.40 1 1 .20 6.85 9. 60 13.50 78. 10 30.70
a
M ^ o/T
.^^
; NOTES: \ DB608 PRIMARY COLUMN
T 1 TLE : PESTICIDE
Ci-,..,.INEL N O : 1
PEAK NO
1 2 3 4 5 6 7 8 9 10 1 1 12 13 14 15 16 17 18
) '9 ' 20
21
PEAK NAME
LINDANE ALDRIN
ENDO I ENDRIN END ALD DDT
METHOXY"
TOTALS:
CONFIRMATORY
SAMPLE:
RESULT UG/ML 0,0000 0,0000 0,0139 0.0066 0.0000 0.8747 0.0072 0.2235 0.0289 0.0000 0.0000 0,0000 0,0000 0,0000 1 ,3277 0,0000 0,0000 0,0000 0,0000 0,0000 0.0000
2.4825
SAME
T IME CMIN) 7.266 7. 778 1 1 .238 13.555 15.515 16.391 17.195 18,361 19,215 19,601 19.748 19.987 20.234 20.485 20.724 21 .844 22.037 22.385 22.974 23.384 23.756
7:
METHOD
TIME OFFSET
0.218 -0,245
0.311 -0.305 0. 081 0. 125
-0.036
0. 149
02 16
: DBS
AREA COUNTS 73629 2332 7319 3148 6397
224280 2045
60393 4896 8719
35312 41 19 2393 3547
132767 3968 6195
153734 8576 2826 3156
749751
JUN 88
SEP ' CODE BB BB BB BB BB BV BB BB BV VV VV VV VV VV VB BV VV VB BV VB BB
?
7
7
7 7 7 7 7
Wl/2 CSEC) 4. 90 4.50 5. 05 5.30 5.65 7. 30 5.80 6. 10 8. 15 8.20 6. 30 4,60 6,20 5, 90 4.35 12,80 9.05 7,00 5.65 5,10 6.25
;DETECTED PKS: 51
D. I ISOR: 1 ,00000
=N0ISE: 30,4 OFFSET:
i RACK: 16 VIAL: 10
REJECTED PKS: 30
MULTIPLIER: 1,00000
12
INJ: 1
NOTES: DBS CONFIRMATORY COLUMN
'CHART SPEED 0,6 CM/MIN LATTEN: 8 ZERO: 10% 1 MIN/TICK ATTEN: 16 ZERO: 10% 1 MIN/TICK
468 1.864
— ^ ' 7.667 — —> 8.587
7.251
CHART SPEED 0.6 CM/MIN A-'"^EN: 8 ZERO: 10% 1 MlN/TlCK
ATTEN: 16 ZERO: 10% 1 MIN/TICK
^-STAT~:y iNJECT
, 1^2
1 1 , 4 4 5 - 2 , 1 1 8 1 2 , 7 0 1
B BHir>13.250 -X =r=i l S . 6 8 9
HEPJ^pttfe^ 14, 122 — ^ ^ 14, 839
1 5 , 2 7 8 _ 5 . 6 9 8
ISODf
=1^023
^ D E
DDD
"^DT
-TTETHOXY
- K B B SUR 2 4 . 7 4 9 2 5 . 3 7 9
2 9 . 3 7 5 2 9 , 8 7 0
1 , 4 8 3
S R : 0 F
L I N D A
= " 1 6 , 3 6 8
' 1 8 , 5 1 1 .
2 0 , 2 9 8
^ .7.m-
~TTDD
"TTDT
TITLE: PESTICIDES
CHANNEL NO: 2 SAMPLE: 805088-4
7:29 14 JUN 88
METHOD: DB60e
PEAK PEAK NO NAMF
RESULT _iir; /Ml
TIME r M I Kl 1
TIME nrrcTT AREA SEP Wl/2
( j«i r\ r-
LE : PESTICIDES
CHANNEL N O : 2
PEAK NO
1 2 3 4 5 6 7 8 9
3 10 D 1 1 ::. 12
13 14 15 16 17 18 19 20 21 22 23 24 25 6
27 28 29 30 31 32 33 34 35 36 37 38 39 40
r) 4 1 •i 4 2
3 43 1 44 ^ 45 ) 46
47 ^ 48
49 3 50 : 51
52 53
; 54" 55
; 56
PEAK NAME
A BHC
LINDANE B BHC
HEPTACHLO
D-BHC
ALDRIN
ISODRIN HEPT EPOX
ENDO I
M£—___ DIELDRIN
ENDRIN DDD ENDO I I
^,=^T ^ 58
59 ; 60
61 ' 62 ) 63 > 64 ) 65
„ - : z—>i=—^~— -— ENDRIN AL ENDO S04
SAMPLE:
RESULT UG/ML 0.0000 0,0000 0.0000 0.0000 0,0000 0,0000 0.0000 0,0000 0.0000 0.0000 0,0000 0.0000 0.0000 0.0000 0 . 0000 0.0000 0,0000 0,0000 0.0000 0,0000 0.0012 0,0000 0,0000 0,0000 0,0031 0,0023 0,0000 0,0000 0.0000 0.0036 0.0000 0.0024 0.0000 0,0000 0,0000 0.0026 0.0000 0.0000 0.0000
111,0030 0,0072 0.0000 0 . 0000 0.0000 0.0184 0,0000 0,0194 0,0040 0,0000 0,0000 0,0000 2,1229 0,0478 0,0582 0,0000 0,0000 0. 021g__ 0,0000 0,0352 0.0148 0.0000 0.0000 0.0000 0.0000 0.0000
805088-4
TIME CMIN) 6.291 6.416 6,573 6,913 7,023 7. 160 7.416 7,777 7,975 8,110 8,285 8.737 9.035 9.237 9,778 10.175 10.843 11.348 11.445 11,541 11,825 12,118 12,371 12,701 12,972 13,250 13.495 13.689 13,895 14, 122 14,304 14.498 14,839 14,950 15,065 15,278 15.471 15.698 15.866 16.368 16.738 17.329 17.474 17.797 18. 143 18.511 18.833 l- .dS?' 19.338 19.689 19,993 ?0.?aa_ PP).^09 20,804 20,995 21,184
,—2J...52.2. 21.641 21.937 22.225 22.318 22.507 22.669 22.953 23.107
7:29 14
M E T H O D : DB608
TIME OFFSET
0, 045
-0.108 -0.050
-0,018
-0.012
0.068
-0,032 -0.242
0.033
0.0R3 -0.027
0.048 _ 0 r099...
-0.006
.. .. 0.032-
0 1 ] 7 0, 035
AREA COUNTS
5562 3281 3464 2431 1466 1684 4883 4207 2125 2927 1629 2556 1032 838
4012 5757 1794 2230 687 716
2310 2270 6421 3500. 5255 1513 5979 3079 5167 3440 10066 3761 2752 5680 141 1 3897 754 1 1 19
^ ^ 9 9 9 r t ^ ^ ^ 6115 12325 41914
1 24079 / 440091
P7415 5357
48771 , 7912
/ 43578 < 1043200
4943^; / 68965 / 42866
7 2538730 L0577 59338 35627
n"?4-6-3^ 1 1094 121 18 16722 12591 27018
JUN 88
SEP CODE VV VV VV VV VV VV VV VV VV VV VV VV VV
vv BV VV VV
vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv
-n vv / vv
vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv
-— vv vv vv vv vv vv vv
7 7 7 7 7 7
? ?
7
7 7 7 7 7
7 7 ? 7 7 ? ? ? ? ? 7 ? ? ? ? ?
? ? 7
- ? ? ? ? ?
_?_ 7 7 ?
_j2_ "~7~ 7
? ? ? ? 7
Wl/2 CSEC) 5.40
1 1 .90 8.80 2.00 2.40 12.40 5. 10 5.00 7.80 8.90 2.90 7.90 6. 15 6. 10 6.20 4.80
13. 00
13.50 1 1 .80 6.00 13.80 7. 10 5.30 12.00 9.30 12.30 9. 90 4.45 3.00 13.50 8.25
1 1 .30 5.40 5.50 5.35 5.90 12.75 1 1 .80 14.60 6.45 6. 70 6.05 4.B0
17.90 6.90
13.40 4. 25 9. ?0 y 4.90 8.50 9.95 1 .90 8. 75 1 1 . 00 9. 50 3,75 8.90
10. 10 14.50 14.?;0
irj
0
Z p
n
IT 3 9
TJ >
: ^ -* z p SJ
M
0) n 5"
s? r* Z P 1
K ^ pfVi
F R B. O
, 43 44 45 46 47 48 9 0
51 52 53 54 55 56 57 58 59 60 61 62 63 64 65 66 67 68 69 70 71 72 73 74 75 76 77 76 79 10
ENDO
DDE
I
DIELDRIN
ENDRIN DDD ENDO
DDT
I I
ENDRIN AL ENDO S04
METHOXY
HBB
TOTALS:
SURR
0.0000 0.0000 0.0184 0.0000 0.0194 0.0040 0.0000 0.0000 0.0000 2.1229 0.0478 0.0582 0,0000 0,0000 0,0210 0,0000 0,0352 0.0148 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0300 0.0000 0.0000
26.5059 0.0000 0.0000 C.0000 0.0000 0.0000 0.0000 0.0000 0.0000
139.9030
17,474 17.797 18.143 18,511 18,833 19.053 19.338 19.689 19,993 20,298 20.609 20,804 20,995 21,184 21,522 21.641 21.937 22,225
^ 22,318 22,507 22.669 22.953 23.107 23.298 23.743 23.901 24.191 24.502 24.749 24.875
• 25.379 25.699 26.269 26.881 26.972 27.290 27.573 29.375
0.
0. -0.
0 0
-0
0
0 0
0
-0
0
033
083 027
048 099 006
082
1 17 035
,021
, 125
01 1
12325 41914
/ 24079 / 440091
27415 5357
4877 1 . 7912
/ 43578 • 1043200
49433 / 68965 / 42866
7 2539730 10577 59338 35627 12463 1 1084 121 18 16722 12591 27018 29207 23942 5416 10059
133738 1 1251 13187 13527 16220 13124
966 599 1447 1399 1680
5235450
VV VV vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv BV
7
7 ? ? ? 7 7 7 '?
?
7 7 ? ? ? ? 7 7 ? 7 7 ? 7
7 ? ? ? ? ? ? ? ? ?
14,60 6,45 6,70 6.05 4,80
17.90 6.80 13.40 4.25 9.20 4.90 8.50 8.95 1 .90 8.75 1 1 .00 9.50 3.75 8.90 10.10 14.50 14.50 12.50 22.90
15.90 7.55 4.40
17. 10 16.00 18.50 9. 10
16.50 15.30 4.50
DETECTED PKS: 121 REJECTED PKS: 41
DIVISOR: 1,00000 MULTIPLIER: 1.00000
NOISE: 4,9 OFFSET: 13
O^RACK: 16 VIAL: 1 INJ: 1
NOTES: DB608 PRIMARY COLUMN
TITLE : PESTICIDE
CHANNEL N O : 1
PEAK ' 0
1 2 3 4 5 6 7 8 9
PEAK NAME
CONFIRMATORY
SAMPLE:
RESULT UG/ML 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0. 0000 0.0000 0,0000
SAME
TIME CMIN) 6. 406 6,768 7, 141 7,371 7.789 8. 144 8.219 8.515 8.776
7:
METHOD
TIME OFFSET
29 14
: DB5
AREA COUNTS 12792 8800 3123
193974 23630 9244 7029 6487 AQQQ
JUN 88
SEP CODE VV VV VV VV VV VV VV VV V \ l
? ? ?
? ? ?
r^
Wl/2 CSEC) 16. 45 34. 25 7.40 6. 40 14.30 9. 10
20. 10 8. 70
< 1 z c
•J., -. 1
1 1
. )
1
; ,
)
)
1
> ) > > ) • *
L
1 t-
J
J
r i
a
D 3 9 L
ZD CD <J J
- 13 14 15 16 17 18
1
. ^ 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 0
Jl 52 53 54 55 56 57 O b
59 60
DBHC
LINDANE
HEPTACHLO
ALDRIN
HEPT EPOX
DIELDRIN
ENDRIN
DDD
END ALD
ENDO S04 DDT
METHOXY"
TOTALS:
0,0000 0.021 1 0.0000 0,0000 0.0037 0.0000 0.0000 0.0000 0,0000 0,0144 0.0000 0.0579 0,0000 0,0215 0.0000 0.0000 0,6776 0.0000 0.0649 0.0000 0.0632 0.0000 1,1669 0,0000 0,0735 0,2195 0, 0000 0,0000 0,0000 0.0000 0,0000 8.5048 0.0000 0,0000 0,0000 0.0000 0.0000 0.0000 0.0000 0,0000 0,0000 0,0000 0,0000 0.0000 0,0000 0,0000 0,0000 0.0000
10.8961
9,915 10.285 10,597 10,820 10.958 1 1 .384 1 1 .581 11,994 12,423 12.864 13.247 13.722 14.320 14,959 15,449 15.720 16,558 17,288 17,438 17,589 17,977 18, 1 14 18,518 18,755 18,913 19,095 19,408 19.764 19.912 20.392 20.622 20,892 21,241 21,627 21,796 22.035 22.204 22,397 22,580 23,140 23.295 23,596 23,768 23,983 24,370 24,4V6 24,861 27.566
-0.
-0.
0,
-0.
-0.
-0.
-0.
0,
0,
-0, 0,
0
-0
125
062
154
078
001
212
,062
,017
,238
,087 .005
, 132
, 1 17
1 1662 1 1698 2542 6387 1945
13868 3183 6939 9737 6527 8174
27569 10285 9772 1 1763 4 1204
250950 3391 1 18551 87647 19160 57253
315370 68430 22276 37207 73148 126050 596234 109129 47482
850477 85510 34250 19460 59866 42241 24909 151719 67896 1501 1 40994 9325 17745 15398 2603 2389 1342
3768910
VV VV VV VV VV VV VV VV VV VV VV VV VV VV VV
vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv VB BB
7
? 7 ?
7 7
7 7 ? ? ? ? ? 7 7 7
7 7 7 ? 7 7 7 ?
7 7 7 7 ? ? 7 ? ?
? 7 7 7 7 ? ? ? ?
4.45 22.05 4.50 7.55
7.30 2.60 17.20 7.75 7.70 5.70 8.25
28. 90 11.10 28.40 19.30 4.85
25.00 7.90 9.00 10. 10 10.60 5.05 5.90
4.90 18.60 14.60 8.30 12.55 9,20 8.05 3.40 7.85 6.00 18.70 7.00 6.25 8.50
23.30
12.40 2.55 10.90 14.90
9. 10 8.90
DETECTED PKS: 87 REJECTED PKS: 27
DIVISOR: 1,00000 MULTIPLIER: 1,00000
NOISE: 34,0 OFFSET: 19
RACK: 16 VIAL: 1 INJ: 1
NOTES: DBS CONFIRMATORY COLUMN
CHART SPEED ATTEN: 8
0.6 CM/MIN ZERO: 10% 1 MIN/TICK ATTEN;
~STAT-1 ^
INJECT 0,734
16 ZERO: 10% 1 MIN/TICK
0 , 9 9 4
S R : O F F
- J7='^^^?12 1 0 , 5 9 0
7 5 9
- A L D S T R " 1 4 , 7 7 9 1 5 , 3 7 3
1 8 , 2 7 4 -&DD
- W & B U S U R R ^ 4 , 7 7 4
2 5 . 5 7 4 2 6 , 0 4 9
3 0 ! 8 4 1
- H E P T A ^ L O 1 2 , 7 3 5
rNDO • 1 6 , 3 8 3
2 2 , 3 7 1
•^ .2 l^9^h^ 2 7 . 4 5 1
T I T L E : P E S T I C I D E S &OhX ~7/\ ^ i j
Cl NEL N O : 2 SAMPLE: 5J»^?-l—1-MSi)
PEAK NO
1 2 3 4 5
PEAK NAME
RESULT UG/ML 0.0000 0.0000 0.0000 0.0000 0.0000
TIME CMIN) 6.292
367 977 383 935
5:13 16 JUN 88
METHOD: DB608
TIME OFFSET
AREA COUNTS
1347 1753 885 805
SEP CODE VV VV VB BV
Wl/2 CSEC) 4.75 15.70 1 1 .70 6.55
T I T L E : PESTICIDES
PWi^MMC") Kir, • ^ V,- rl nl IN IN
PEAK t
2 3 4 5 6 7 8 9 10 1 1
; 12 13
) 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 * 2.
33 34 35 36 37 38 39 40 41 42
5 43 4 4 45
! 46 47
1 48 49
; 50 51
1 52 53 54 55 56
1 ^ ^ 1 58
59 ' 60
61 : 2
PEAK NAME
A BHC
LINDANE B BHC
HEPTACHLO
D-BHC ALDRIN
ISODRIN HEPT EPOX
ENDO I
DDE DIELDRIN
ENDRIN
DDD
ENDO I I
DDT ENDRIN AL
ENDO S04
METHOXY
HBB SURR
> TOTALS: > ) ) > DETECTED PKS:
SAMPLE:
RESULT UG/ML 0,0000 0,0000 0,0000 0,0000 0,0000 0,0000 0,0000 0,0000 0,0019 0,0000 0,0000 0.0000 0,0010 0.0054 0.0000 0.0069 0,0000 0,0000 0,0022 0,0077 0,0000 0,0000 0,0000 0,0000 2,0323 0,0014 0.0000 0.0000 0,0000 0,0000 0,0000 0,0100
^ ^ . S ' Y - J LI
*=^J2.0 I —_l-MC;-n
TIME CMIN) 6,292 6.367 6, 977 7,383 7, 935 9,738 10.112 11.2S4 11.485 11.894 12.233 12,734 12,809 12,900 13,374 13,759 14.022 14.144 14.324 14.779 15.069 15.373 15.656 16.165 16.524 16.840 17.086 17.244 17.385 17.564 17,824 17,993 ,
0. 0000 Ppg'18, 274/v^ 0,0146 0,0122 0,0000 0,0000 0,0296 0,0000 0.0090 0.0000 0.0065 0.0000 0,0783 0,0477 0.0000 0.0152 0.0000 0.0000 0,0000 0,0000 0,0528 0.0000 0,0000 0,0000
30,2304 0.0000 0.0000 0.0000 0.0000
• 0.0000 0.0000
32.5651
18,609 19,003 19,187 19,416 19,757 20,003 20. 1 19 20.317 20,561 20,684 20,964 21 , 365 -0 21,616 22,012 22.175 22,428 22,748 22,910 23,554 24,068 24,342 24,774 25,056 25,574 25.791 26.049 26.414 27,236 29,904
96 REJECTED PKS
,3- 5:
METHOD
TIME OFFSET
-0,025
0,019 -0,110
-0,081
-0,186 -0,111
0, 124 0, 190
-0, 1 17 Cli*"^
-0,141 -0,077
-0,123
-0,031
•0, 121
y-0, 1 16 Ol'l -0. 075
0, 192
-0,196
0,056
-0.687
: 34
13 16 JUN 88
: DB608
AREA COUNTS
1347 1753 885 805 658 1347 4479 1 390 3805 4713 4356 6990 1670 3615 7795 6509 3806 4961 3336 1 1646 3961 2470 4216
232817-<;. 4156 2066 12589 7884 4139 7220 2552 13001
102469^-20688 16365 1 1729 5332 19202-^ 22422^ 9286.'^
2 1 6 1 ' ^ 7663 1751
58867 483 16-^ 16156 12762 6774 13554 18141 9758 17674
145245 19285 5028 15040 1593 3836 1812 6929 1004 1735
1021030
SEP CODE VV VV VB BV VV BV VV BV VV VV VV VV VV VV VV VV VV VV vv vv vv vv VB
5' BV VV VV vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv VB BV BV
?
7
7 7 7 ? 7 7 7 ? 7 7 7 7
7 '>
7 7
7
7
7 7
7
? ?
7
?
7 ?
? ? ? ?
?
Wl/2 CSEC) 4.75
15, 70 1 1 . 70 6.55 3,05 8, 15 5,75 8,50 12,30 5.40 13.20 22.90
22,90 18.00 11.10 4.75
12. 70 8. 50 9.50 6.90 5.95 7.95 14,70 8,90 5,80 2.45 7. 20 9, 60 6. 15 5, 45 -o-LU fpH 10,55 8, 00 9.55 9.20 U ' 0 12.50 i r f ^n i ' - ^ 12.20 f**- i^ 1 .35 9.40 9. 40
9,90 7.90POT 4, 90 7, 15 6,00 10.60 7, 90 9.10
15. 95 6.45 13.75 7.90 1 1 .35 5.40 9. 10 3.20 13.30 7.40
20.85
i
7
,*^j^/^'''' rC^^ I ^
urr /
DIVISOR: 1.00000 MULTIPLIER: 1 .00000
f - r - r r r^Tr - r •
PEAK NO
1 2 3 4
7 8 9 10 1 2 3 4 5 6 17 18 19 20 21 22 23 24 25 26 27 2B 29 30 31 32 33 34
w <
38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56
TOTALS;
PEAK NAME
B BHC DBHC . LINDANE
HEPTACHLO ALDRIN
ENDO I
DDE
ENDRIN
ENDO 1 I DDD END ALD
ENDO S04 DDT
METHOXY
RESULT UG/ML 0,0000 0,0000 0,0000 0,0110 0,0028 0,0180 0,0000 0,0044 0,0081 0, 0000 0,0100 0.0000 0.0322 0.0000 0.0000 0.0508 0.0000 0.1899 0.0684 0.6023 0.0000 0.0000 0,0000 0,0706 0,2523 0,0000 0,0000 0 , 0000 0,0000 0,0000 0,0000 0,5606 0 , 0000 0,0000 0.0000 0 , 0000 0,0000 0,0000 0.0000 0.0000 0.0000 0.0000 0,0000 0,0000 0,0000 0,0000 0.0000 0,0000 0,0000 0,0000 0,0000 0,0000 0,0000 0,0000 0,0000 0.0000
1 .8814
TI CM 7 , 7, 8, 10, 10, 1 1 , 1 1 , 12, 3. 5, 5, 6, 7,
17, 17. 17. 17. 17, 17, 18, 18, 18, IB 18 19 19 19 19 19 20 20 20 20 21 21 21 21 22 22 22 22 23 23 23 24 24 24 24 25 25 25 26 26 26 27 27
ME I N ) 236 750 584 148 394 233 769 735 554 514 870 383 023 173 401' 500 613 798 994 356 489 641 800 936 195
,392 .595 , 786 , 968 . 231 , 388 ,715 ,886 . 135 .431 ,719 , 846 ,042 ,371 ,582 ,962 ,287 ,557 ,688 ,018 ,458 .661 ,781 . 077 ,611 ,918 .043 .616 .998 .451 ,573
T IME OFFSET
0, 008 •0,016 0,213
0, 025 -0, 246
-0,210
0, 173
0. 000
0. 068 0. 034 0.076
-0. 064 0. 105
•0. 045
0.121
AREA COUNTS 78782 2038 2699 2564 1553 9477 1529 1996 3875 9673 2563
284252 11911 13231 20317 14502 22942 17582 20722 162777 24836 8324 9139
21404 42766 29743 32820 37944 57959 25983 38752 56057 54374 77955 31273 23789 26014 41282 178949 12876 54801 32929 21871 10626 23953 25291 4471 18485 19390 34984 7491 7923 8010 5999 9961 1558
1804970
SEP CODE BB BB BB BB BB BB BB BB BB BB BV VV VV VV VV VV VV VV VV VV VV VV VV VV VV vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv VB
7 7 7 ?
7 7 7
7 7 ? ? 7 7 7
7 7 7 7
7 7 7 7 7 ?
7
? 7 -> ? 7 ? 7 ? ? ? ? ? 7 ? 7 ? 7 ? ? ? ? ?
Wl/2 CSEC) 5.95 3.20 4.10 4.60 4.60 4. 90 3.90 3.50 3.05 6. 35 4.80 7.35 8. 10
10. 40 7. 80 3.70 5.55 8.50 9. 90 7.65
14.90
3.70 9.10 10,35 9, 90 12,70 1 1 .60 10. 50 9, 00
14, 55 6,95 10.20 10.55 1 1 .40 10.80 7.00 9.50 5.00
13.60 14. 10 10. 10
13.10 19.50 3.75 7.00
12, 20 23, 00 4.30
8.10 20.30 23.50
DETECTED PKS: 87 REJECTED PKS: 31
D I V I S O R : 1.00000 MULTIPLIER: 1.00000
N O I S E : 30.4 O F F S E T : 55
Rl : 16 V I A L : 7 INJ: 1
N O T E S :
DB5 C O N F I R M A T O R Y COLUMN
SSL
A / A AnalyticalTechnologies, Inc
GAS CHROMATOGRAPHY -.RESULTS
ATI I.D. : 8050880^
TEST : ORGANOCHLORINE PESTICIDES AND PCB'S (EPA 8080)
CLIENT PROJECT # PROJECT NAME CLIENT I.D. SAMPLE MATRIX
MONTGOMERY & ASSOCIATES 661 C HASSAYAMPA 014397 SOIL
DATE S7VMPLED DATE RECEIVED DATE EXTRACTED DATE ANALYZED UNITS DILUTION FACTOR
05/17/88 05/18/88 5/23/88 06/14/88 MG/KG
1
COMPOUNDS RESULTS
<0. <0. <0. <0. <0. <0.
005 005 005 005 005 05
0.025* <0.01 * 0.033* <0 <0 <0 <0 <0 <0 <0 <0 <0 <0 <0 <0 <0 <0 <0 <0 <0 <0
01 01 01 01 01 01 .01 .005 .005 .05 .1 * .05 .05 .05 .05 .05 .05 .05
ALDRIN ALPHA - BHC BETA - BHC GAMMA - BHC DELTA - BHC CHLORDANE 4,4'-DDD 4,4'-DDE 4,4'-DDT DIELDRIN ENDOSULFAN I ENDOSULFAN II ENDOSULFAN SULFATE ENDRIN ENDRIN ALDEHYDE ENDRIN KETONE HEPTACHLOR HEPTACHLOR EPOXIDE METHOXYCHLOR TOXAPHENE AROCLOR 1016 AROCLOR 12 21 AROCLOR 12 3 2 AROCLOR 1242 AROCLOR 124 8 AROCLOR 12 54 AROCLOR 12 60
SURROGATE PERCENT RECOVERIES
ISODRIN (%) 88
•DATA TAKEN FROM SAMPLES REEXTRACTED ON 6/15/88 AND ANALYZED ON 6/16/88.
/ N AnolyticalTechnologies, Inc
55/ ' SSL
TEST
QUALITY CONTROL DATA ATI I.D.
ORGANOCHLORINE PESTICIDES AND PCB'S (EPA 8080) 805088
CLIENT PROJECT # PROJECT NAME
MONTGOMERY & ASSOCIATES 661 C HASSAYAMPA
REF. I.D. DATE ANALYZED SAMPLE MATRIX UNITS
80508801 06/14/88 SOIL MG/KG
COMPOUNDS
DUP. DUP. SAMPLE CONC. SPIKED % SPIKED % RESULT SPIKED SAMPLE REC.SAMPLE REC. RPD
GAMMA BHC HEPTACHLOR ALDRIN DIELDRIN ENDRIN DDT
ND ND ND ND ND ND
0.067 0.067 0.067 0.067 0.067 0.067
0.046 0.050 0.048 0.056 0.046 0.050
69 75 72 84 68 74
0.028 0.040 0.037 0.041 0.042 0.049
42 60 55 61 63 73
49 22 26 31 9 2
(7w777hi (ATAJ^I bcJa. /tA -.
!•) PSAi
2.) ciilW»'^<'jf^^i
oiHsir oiH3<n
3.) TJtycJtH^ AtfC^J T S / T X ^ ColmmW..
a ) ShidiiTL v ^ 0 ^
dtujlW
% Recovery = (Spike Sample Result - Sample Result)
Spike Concentration X 100
RPD (Relative % Difference) = (Spiked Sample - Duplicate Spike) Result Sample Result
Average of SpikecJ Sample X 100
CHART SPEED 0.6 CM/MIN ATTEN: 8 ZERO: 10% 1 MIN/TICK
I AT—7INJECT
1 • 0Rfl
< HEPI^^LO 14.299
"i^^h 043
20,591
22.499 -p^^^ 23. 094
25,321 26,072 26,940
27.503
ATTEN: 16 ZERO: 10% 1 MIN/TICK
5.939 SR:OFF-:
, 10,500 LINDANEr>=l-«-. 706
' 12,937—
13,999-
14, 950-
"" 16, 351
=ta, 492 -HDD
DDT
21,169
24.473
15.657
*=&. 496
19.736
3
-"TITLE: PESTICIDES - v //
CHANNEL NO: 2 SAMPLE: 905099-7 METHOD: DB609
1#1) 9:52 14 JUN BB
PEAK PEAK RESULT 7
TIME TIME AREA SEP Wl/2
CHANNEL N O : 2
PEAK NO
1 ?
i w
4 5 o 7 8 9 10 1 1 12 13 14 15 16 17 19 19 20 21 22 23 24 25 26 27 28 29 30 31 32 ^3 ;
o5 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 59 60
PEAK NAME
A BHC
LINDANE B BHC
HEPTACHLO D-BHC ALDRIN
ISODRIN HEPT EPOX
ENDO I
DDE DIELDRIN
ENDRIN DDD
DDT ENDRIN AL ENDO S04
METHOXY
HBB SURR
TOTALS:
D :i CTED PKS:
SAMPLE:
RESULT UG/ML 0,0000 0.0000 0.0000 0.0000 0,0000 0,0000 0.0000 0.0000 0,0000 0.0000 0.0000 0.0000 0.0000 0,0012 0.0000 0.0000 0. 141 1 0.0099 0.0000 0.0109 0.0026 0.1584 0,0000 0.0000
95,6166 0.0031 0.0000 0.0000 0.0000 0 . 0000 0.0000 0.0023 0. 0000 0.1490 0,0106 0.0000 0.0000 0.2230 0.0357 0.0000 0.0991 0.0195 0.0168 0.0000 0.0000 0.0000 0 , 0000 0.0000 0.0121 0 . 0000
31 .2857 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
127.7980
805088-7
TIME CMIN) 6.265 6.426 7. 289 7, 761 7, 962 8. 094 8,279 9, 005 9, 123 9,765 10,163 1 1 ,338 1 1 ,428 1 1 ,833 12.083 12,378 12,837 13,486 13,888 14.289 14,580 14.950 15.705 15.855 16,351 16.706 17,271 17,433 17.589 17.762 17.964 18.206 18.492 18,816 19.273 19,413 19.973 20.267 20.581 21.168 21.629 21.921 22.302 22.488 22,697 23,094 23,266 23.654 23.903 24.473 24.717 25,321 25.684 26.072 26.324 26.940 27,503 27.695 29.976 30.791
97 REJECTED P
M E T H O D : DB608
TIME
OFFSET
0, 053
-0,243 0, 186
0. 149 0,070 -0,260
-0.049 -0.274
0.096
0,066 0. 193
0.017 0. 071
0. 189 0.101 0.112
•0.267
•0.283
-0.073
37
AREA COUNTS
3587 1474 1389 695 596 850 505 526 1 167 3009 7156 2176 1501 2312 1555 6158
235996 6572
-190598 10322 3939
239595 691 1367
195535 4593 6885 4770 1558 6219 823
2965 56392
210991 14122 12020
159186 109588 36996
331243 49781 19776 14134 6494 13557 14095 10101 5934 4057
116804 15565 6447 7600 4946 12744 8936 1075 893 774 952
2192290
SEP CODE VV VV BV VV VV VV VB BV VV VV VV VV VV VV VV VV VV VV
vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv VB BV VB
Wl/ CSE 11. 15. 5. 5. 4. 5. 3. 8.
21 . 1 1 . 6. 12.
14. 12. 8. 5, 19, 5. 13. 5. 3. 4. 7. 6. 12. 1 1 . 5.
10. 0. 6. 7. 6. 12. 3. 6. 9. 14, 6. 1 1 . 1 1 . 6. 7. 14. 10. 5. 14. 7. 7. 2. 12. 19. 13. 20. 13.
2 C) 30 20 40 45 30 95 40 40 20 50 00 20
00 00
05 -^./37//^/ 60 y/O C^Ji 7lQ^i
30 , 5^ 65-Aa'^./^f^3r,o^/ 75^^ 30 - 7 2% 95 N/ 20 95 00 30
£a
65 20 30 00 15 40 10 35
- W ^ -.0.l''1'-//^ a 40'W^'^•'^^.(^V6J
7, 9,
55 05 65 00 75 05 10 20 90 20 20 40 55 70 95 20 00 30
90 10
r)Drrp,iVi-:i'-.o3»
• D I V I S O R : 1,00000 M U L T I P L I E R : 1,00000
NOISE: 4.9 O F F S E T : 9
RACK: 16
3N0TES:
VIAL; INJ: 1
OT.ES: DB609 PRIMARY COLUMN
ITLE: PESTICIDE CONFIRMATORY
HANNEL N O : 1
EAK NO
1 2 3 4 5 6 7 9 9 10 1 1 12 13 14 15 16 ) "•
1 7 20 21 22 23 24 25 26 27 29 29 30 31 32 33 34 35 36 37 39 39 40 41 42 43 44
PEAK NAME
DBHC
HEPTACHLO ALDRIN
ISODRIN HEPT EPOX
DIELDRIN ENDRIN ENDO I 1 DDD END ALD
ENDO S04 DDT
METHOXY"
TOTALS:
SAMPLE:
RESULT UG/ML 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0,0055 0.0000 0,0000 0,0000 0.0153 0,0463 0,0000
347.0220 0.0090 0,0000 0.5445 0,0876 0.0443 0.0219 0,0409 0,0000 0.7145 0,1124 0,0000 0,0000 0,0000 0,0000 0,0000 0,0000 3,1073 0,0000 0,0000 0.0000 0.0000 0,0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
351.7710
SAME
TIME CMIN) 7. 374 7.789 8.230 8.545 8.724 9.035 9.917 10.278 10.500 10.706 1 1 .365 12.209 12.935 13.702 14.019 14.552 14.976 15.657 16.534 17,543 17.716 17,958 18,123 18.496 18,712 19,077 19.367 19,736 19.887 20,125 20.377 20,597 20,870 21,237 21,594 21.897 22,018 22,219 22,555 23, 1 17 23.566 23.751 23.941 24.221
METHOD
TIME OFFSET
0.
0, -0,
-0. 0
-0 0
-0 -0 -0
-0 -0
0
-0
090
225 099
109 016
236 043 014 002 157
288 013
1 10
,432
: DB5
AREA COUNTS 199319 16903 6140 5531 5970 1944 5903 12071 3067 5661 16760
236756 6965
22050 5235
222450 4093
232792 201652 25029 4105 6629 1 1063 96032
216512 19056
193059 107996 103259 59933 26976 33101
310731 47470 23429 19955 17754 50944 131594 39043 19490 6669 6360 3629
2768460
SEP CODE BV VV VV VV VV VB BV, VV VV VV VV VV VV VV VV VV VV
vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv VB
? ?
? ?
? 7 ?
? 7
? ? 7 7 ? ? ? ? ? ? ? ? ?
? ? ? ? ?
? ? ? ? ?
Wl/2 CSEC) 6.05 1 1 .85 7.00 7.80 9.00 5.95 13.95 1 1 .30 21 .70
5.75 6.40 16.70 13.25
7.00 5.60 4.50 7.20
28.90
9.80 8.90 8. 10 5.00 6.50 4.85 12.90 6. 10 7.45 5.70 9.20 7.75 4.90 8.05 9.00 5.90
14. 15 7.75
21 .00 9.30 4.30 6.20 8. 15
DE ;TED PKS: 64 REJECTED PKS: 20
DIVISOR: 1.00000 MULTIPLIER: 1.00000
^OISE: 34.0 OFFSET: 5
RACK: 16 VIAL: 5 INJ: 1
MOTFS:
ATTEN":-" " B ' ZERO: 10% 1 MIN/TICK ATTEN: 16 ZERO: 10% 1 MIN/TICK
"TiTAT~1/lNJECT
12.215
18.723
T I T L E : PESTICIDES
INEL NO: 2 S A M P L E : 805088-lMS
PEAK NO
) 1
PEAK NAME
2 3 4 5
RESULT UG^ML 0.0000 0.0000 0.0000 0.0000 0.0000
TIME CMIN) 6.293 7.296 7.760 9. 103 8.292
10:27
TIME OKFSEI
' ^ DB608
AREA CuuNTS
5383 1015 644 924 ^ l O l
JUN 88
SEP CuDt VV BB BV VV W Q
?
o
Wl/2 CSEC) 10.05 5.55 6.25 5.60 / I n i ) ,
NO 1 2 3 4 5
8 9 10 1 1 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 54 35 36 ^ J
39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57
is 1 i'l E ••
A BHC
LINDANE B BHC
HEPTACHLO D-BHC
ALDRIN
ISODRIN HEPT EPOX
ENDO I
DDE DIELDRIN
ENDRIN DDD DDT
ENDRIN AL ENDO S04
METHOXY
HBB SURR
TOTALS:
UG-'ML 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0012 0.0000 0.0000 0.0958 0.0016 0.0000 0.0000 0.0000 0.0093 0,0029 0.0000 0.0021 0.0000 0.0000 0.0000
77.9026 0.0029 0.0000 0.0000 0.0000 0.0000 0.0012 0.0000 0.1091 0,0154 0,0000 0,2081 0.0294 0,5313 0,0000 0.0135 0.0100 0.0000 0.0000 0,0000 0.0000 0.0000 0.0038 0.0000 8.4380 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
87.3782
C ('1 i H j 6.293 7. 296 7.760 8. 103 8.292 9.237 9.778 10.169 11.346 11.429 1 1 .842 12,099 12,394 12.839 13,213 13,403 13,500 13,887 14,284 14.478 14,952 15,214 15,461 15.682 15.863 16.357 16.688 17.287 17.443 17.600 17.773 18.228 18.500 18.824 19.287 19.981 20.273 20,583 21,175 21.640 21.926 22.303 22.495 22.703 23.096 23.274 23.684 23.996 24.481 24.726 25.363 25.723 25.924 26.350 26.969 27.141 27.563
IV f'oi.'s
0,
-0. -0.
0, -0,
0,
-0. -0
0
0 0
0 0
-0
0 0
-0
-0
-0
062
241 087
144 032
004
043 292
1 18
074 207
023 073 265
106 1 13
. 274
.274
,584
u u u IN 1 a 5383 1015 644 924 530 673
2393 4912 2182 1783 2290 1999 4810
160154 1031 3867 2405
154638 8789 441 1
192279 3148 2209 839 1384
159310 4265 5765 3802 . 1245 5557 1510
47834 154554 20598 118310 102259 304 1 1
266985 42138 13689 84 19 3506 8136 8867 4729 1454 1267
81 121 4 198 2151 3436 1479 3763 4573 91 1
4173
16851 10
uubt VV BB BV VV VB VV VV VB VV VV VV VV VV VV VV VV vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv VB
?
? ?
? ? 7 7 ?
? ? 7 7 7 ?
? 7 ? 7
? ? 7 ?
7
7 ? ? 7 ? ? 7
? ? ? ? ? ? ? ?
CStU J 10.05 5.55 6.25 5.60 4.20 4.80 12.95 5,90 13.20
14.30 5.20 12.30 5.20<
10.40 2. 10 3.60-
22.90
5.95-/ 18.40 17.55 0.70 5. 15 5.90 12.45 10.90 4.00 1 .60 9.95 7.85 6.90 6.05-19.50 6. 10
^ la ^ « P p H
H H P H H
^ < ? ^ .0^6 ^ f?%|
Jl t/^
<^^^,«P:J->yo|
--•^oll'l M' .// 3'Wl i
JTM-
9 . 3 0 - ^ ; 14.30 6.00f • 9.75^*^'^ 10.65 21 .90 7. 10 12.90 6.50 13.55 17.00 16.35 7.00 17.00 28. 10 23.30
16.50 20.90
28. 10
oJi"^ '-
o . ^ i l
c m
-5*?.
H 3 '-.oH '%
MI 7 J-.OVM
blAl,M 7 K
3r0<;
I f k
DETECTED PKS: 95 REJECTED PKS: 38
DIVISOR: 1,00000 MULTIPLIER: 1,00000
NOISE: 4.9 OFFSET: 9
P •<: 16 VIAL: 6 INJ: 1
NOTES: DB608 PRIMARY COLUMN
< NOTES'^ E. ' DBis08 PRIMARY COLUMN
^TITLE : PESTICIDE
CHANNEL N O : 1
PEAK NO
1 2 3 4 5 6 7 6 9 10 1 1 12 13 14 15 16 17 18 9 .0 21 22
.. 23 f) 2 4 \ — — ? 25 5 26 ] 27 > 28 > 29 ; 30
> ^ l 32 ' 33
34 35 36 37
1 38 39 40
* 41 42
: 43 44
1 , „ ' 45
' 1:t 1 47 • 48
49 >e Jl
' TOTA;
PEAK NAME
A BHC
DBHC LINDANE
HEPTACHLO
ALDRIN
ISODRIN HEPT EPOX
DIELDRIN
ENDRIN DDD E N D ALD
E:NDO S04 DDT
^ETHOXY"
.S:
CONFIRMATORY
SAMPLE:
RESULT UG/ML 0.0000 0.0000 0,0000 0,0000 0.0000 0,0000 0.0000 0.0000 0,0000 0.0000 0.0108 0.0000 0,0000 0.0101 0.01 16 0.0000 0.0000 0.0000 0.0166 0.0000 0.0352 0.0000
308.9520 0,0055 0.0000 0.5075 0.0000 0.0891 0.0151 0.0245 0.0000 0,6020 0.0693 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 3.3062 0,0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
313.6560
SAME
TIME CMIN) 6.413 7,086 7.369 7.778 7.995 8.230 8.354 8.565 8.724 9.040 9.364 9.934 10,287 10.473 10.901 1 1.368 12.215 12.478 12.934 13.203 13.719 14.216 14,557 14,898 15.661 16.538 17.373 17,546 17,954 18.135 18.514 18.723 19.082 19.380 19,765 19.888 20.131 20.386 20.592 20.884 21.603 22.021 22.232 22.568 23.128 23.580 23.702 23.871 24.235 24.394 25,567
10:
METHOD
TIME OFFSET
-0,066
0.063 -0. 1 19
0.224
-0.081
-0,103 -0.062
-0,232
0, 046 -0.006 -0.145
-0.277 -0.008
0. 124
-0.642
27 14 ,
: DB5
AREA COUNTS
2704 7986
199170 24740 3910 9215 2257 6075 7279 9319 6368 13194 16443 5620 6095 19552
193055 7092 7547 7063 16773 5597
198046 2513
209520 187956 16536 25450 4585 6615
68077 182434 1 1749
164178 95178 100634 48793 25063 24630
330624 26684 31846 47408 127398 56186 18917 9689 1 1242 10975 10123 14236
2643230
JUN 88
SEP CODE VV VV VV VV VV VV VV VV VV VV VV VV VV
vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv VB
7
? ?
?
? ?
? 7 ? ?
?
? ? ?
?
? ? ? ?
? ? ? ? ? ? ? ? ? ? ? ? ? ? ? ? ? ? ?
Wl/2 CSEC) 7.05 6.55 5.75 7.40
6.40 9.90 6. 15 8.20 6.50 9.50
21 .30 9,00
25.90 17.40 6.35 6.35
13.95 10.40 15.00 13.60 7.05
7.30 7. 10
26.00 24.55 6.20 5.90 9.00 7.75 3.90 4.90 13.70 14.30 1 .80 3.20 6.00 5. 15 5.70
23.80 13.90 5. 10 19. 10 9.55
4.70
10.95
DETECTED PKS: 75 REJECTED PKS: 24
D I V I S O R : 1 ,00000 MULTIPLIER: 1 .00000
S S I - SST,
/ A S AnalyticalTechnologies, Inc.
TEST
QUALITY CONTROL DATA ATI I.D,
ORGANOCHLORINE PESTICIDES AND PCB'S (EPA 8080)
CLIENT PROJECT # PROJECT NAME
MONTGOMERY & ASSOCIATES 661 C HASSAYAMPA
REF. I.D. DATE ANALYZED SAMPLE MATRIX UNITS
805088
80508801 06/16/88 SOIL MG/KG
COMPOUNDS
DUP. DUP. SAMPLE CONC. SPIKED % SPIKED % RESULT SPIKED SAMPLE REC.SAMPLE REC, RPD
GAMMA BHC HEPTACHLOR ALDRIN DIELDRIN ENDRIN DDT
ND ND ND ND ND ND
0.067 0.067 0.067 0.067 0.067 0.067
0.048 0.039 0.049 0.043 0.050 0.081
72 58 73 64 75 121
0.058 0.053 0.060 0.057 0.058 0.088
87 79 90 85 87 131
19 30 20 28 15 8
% Recovery = (Spike Sample Result
Spike Concentration
Sample Result) X 100
RPD (Relative % Difference) = (Spiked Sample - Duplicate Spike) Result Sample Result
Average of Spiked Sample X 100
CHART SPEED 0.6 CM/MIN ATTEN: 8 ZERO: 10% 1 MIN/TICK
-^TAT—:i
ATTEN: 16 ZERO: 10% 1 MIN/TICK
~ S R : O E E 6 . 389
=^s'ati 7 , 6 9 6
7V. 41
^-WINDA ^ f r iOd-O^
txxi 1 3 • 3 1 9_
• -ALDRIJ
ISOD.g+N-. 6 , 7 9 3
l l< l>l PCU LO'L
/tU)/?!'
J ^ j P g . . ^
L2, 1 15
1 5 . 5 5 7 =• 1 6 , 20
ENDRrWz^ l J . 228
"ETNDO S O ^ ^ ^ ^ ^ ^ f i z 18.4@4
1 9 , 7 9 7
2 1 , 2 0 4 2 0 , 7 6 7
• HfcHB
_
=
-
r
SURR 2 4 . 9 4 5
2 5 , 9 8 2 2 6 , 5 0 1 2 6 . 9 3 1
3 0 , 0 0 5
3 0 , 9 3 9
^ $ ^ ^
T I T L E : P E S T I C I D E S 9 : 1 7 16 JUN _9
CHANNEL N O : 2 SAMPLE: •HCXHNE - ^ Q f ^ ] ; ! ^ ^ METHOD: DB609
PEAK PEAK RESULT TIME TIMF A R F G C T P
-I 1 I L£ : .PtbT i C 1 DES 6:17 lo JUfN Sd
CHANNEL fJO-- 2 SAMPLE: -HS-fffHE-50S^-1 f^S METHOD: DB608
PEAK NU
•i 1
'i
) 3 4 5 6 7 8 9 I 0 1 1 12
PEAK NHMt
3 4 5 6 7 18 19 20 21 22 23 24 25 26 27 28 29 30 31 12 i3 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54
TOTALS:
A BHC
LINDANE
HEPTACHLO
D-BHC ALDRIN ISODRIN HEPT EPOX
ENDO I
DDE DIELDRIN
ENDRIN DDD ENDO I I
DDT ENDRIN AL ENDO S04
METHOXY
HBB SURR
RESULT UG/ML 0. 0. 0, 0, 0. 0. 0, 0. 0. 0, 0, 0, 0. 0, 0, 0, 0, 0, 0,
91 , 0, 0. 0. 0. 0. 0, 0. 0, 0,
- 0, 0, 0, 0, 0, 0, 0 0 0 0 0 0 0 0 0 0 0 0 0 1 0 0 0 0 0
0000 0000 0000 0000 0000 0000 0000 0000 0000 0000 0000 0008 0000 1 190/ 0000 . 1668'/ 0000 0009 / 1355// 2274/ 0015 , 0000 , 0000 , 0000 , 0000 . 0000 ,0000 1 .0032 A . 0000 0^% . 1208 "' . 0071 . 0000 . 0000 . . 18861/ , .0353"'^' .0 169 ,0000 / ,2775/05!, ,0352 ,0132 , 0000 , 0000 , 0000 , 0000 , 0000 , 0000 , 0093 , 0000 , 7989 . 0000 . 0000 . 0000 . 0000 , 0000
T IME CMINJ 6. 6, 6, 6, 7, 7, 7, 7, 8, 9,
10. 1 1 . 12. 12. 13. 13, 14, 14, 14, 16, 16, 16, 17, 17, 17. 17. 17.
^ ' . 18. 19, 19, 19. 19. 20, 20, 20,
-20 21 21 22 22 22 22 22 23 23 24 24 25 25 26 30 30
323 389 588 946 296 41 1 696 970 152 730 141 517 332 769 319 795 178 501 835 207 566 793 113 284 ,392 , 599 837 ,021 ,313 ,618 , 039 , 228 ,383 , 748 , 049 . 360 ,563 .932 .392 , 668 .052 . 204 .474 .81 1 . 977 .341 .551 .116 . 945 ,272 ,882 .501 ,005 , 939
TIME Of-1-St I
0, 007
•0, 021
-0, 045
-0 , 009 -0,055 -0,193 -0, 084
-0,089
-0,132 -0,04 1
•0, 132 •0, 101 -0.080
-0, 148 -0, 048 -0, 152
-0, 199
-0,055
94,1579 -1,577
AREA COUNTS
2258 2443 1708 2762 2760 2269 700 903 697 1568 4789 1644 2251
198919 2742
157350 3949 1440
204984 186559
2225 700
5728 3973 1856 3157 1363 4221
38320 - 171054
9507 6222 5147
122476 36570 19995 6502
208643 35615 1 1085 8354 3856 4672
10462 5399 895
3 103 124057
895 685 1023 1870 659 700
1643680
SEP CODE VV VV VV VV VV VV VV VV VB BV VB BB BV VV VV VV VV VV VB BV VV VV VV VV VV VV VV vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv VB BB BB BV BB BB
7 7 ? 7 7 7 7 7 7
7
7 7
7
7 7 ? ? 7
7
7 7
7
?
7
7 7
? 7
Wl/2 CSEC) 5.20
7,60 6,70 18,45
7, 60 4,80 9,55 5,50 13, 30 6,90 4,90 4, 70 3,55 2, 80 9. 20 5,90 6,05 6,40 4,60 8.90 5,40 6, 60 6, 45 7, 70 6,80 6,30 6, 20
10, 25 6.70 2.55 6,05 8,65 10, 15 9, 60 5,75 1 1 .80 12. 15 7.45 5,70 6,70 6.30 7.35 6.40 10.25 7, 10 6.60 6.30 7.95 15.80 19. 70 18.70
r DETECTED PKS:
•? DIVISOR:
7 MSE:
1 .00000
91 REJECTED PKS;
MULTIPLIER: 1,00000
37
7,3 OFFSET:
> * R A C K : 16 V I A L : 15
iJ N O T E S : ;; DB608 PRIMARY COLUMN T <
INJ: 1
CHANNEL NO: 1
PEAK NO
1 ->
4 5 6 7 8
• 9
10 1 1 12 13 1 4 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 •^3
4 35 36 37 38 39 40
PEAK" NAME
HEPTACHLO ALDRIN ISODRIN HEPT EPOX
ENDRIN
DDD END ALD
ENDO S04 DDT
METHOXY"
TOTALS:
SAMPLE:
RESULT UG/ML 0.0000 0,0000 0,0000 0.0000 0,0000 0,0081 0,0057
363,4640 0,0077 0,0000 0,0000 0,0000 0.0000 0,0264 0.0000 0,0000 0,0449 0,2776 0,0000 0,0402 1,0835 0.0000 0,0000 0,0000 0,0000 0,0000 0,0000 2,2878 0,0000 0,0000 0,0000 0.0000 0,0000 0 . 0000 0.0000 0,0000 0.0000 0.0000 0,0000 0.0000
367.2460
SAME
TIME C M I N J 7,273 8, 410 8,614 1 1 ,277 12,115 12,839 13,597 14,454 14,814 15,557 16,433 17,228 17,441 17,495 17,614 17,850 18,038 18,404 18,608 18.978 19, 26<d.mi 19,437 19,637 19,797 20,022 20,279 20,471 20,767 20,911 21,129 21,204 21,480 21,893 22,095 22.428 23,007 23,420 23,607. 23,797 24.054
METHOD: DBS
T IME OFFSET
0, 129 -0,203 -0,206 -0,146
-0,005
0, 078 0, 124
-0,022 0, 170
0, 007
-0,074
AREA COUNTS 67847 1721 1955 9729
234414 3662 2727
232990 3479
239602 233709
6587 9179 7537 5329 8733 13596 75020
204720 12187
183640 9352
23351 45951 36699 13975 19809
228777 21355 16196 1 1044 15287 29483 50254 155059 36405 16879 7395 6201 3744
2305580
SEP CODE BB BV VB BB BB BB BB BV VB BV VV VV VV VV . VV VV VV VV VV VV VV VV VV
vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv VB
7
7
7
7 7 7 7 7 7
7
7 7 7 7 7 7 7 7 7 7 7 7 7
? ? 7 ? ?
Wl/2 CSEC) 6, 00 4,55 5,50 4, 90 6, 40 5,20 7, 10 7, 05 16, 60 7, 15 7,25 7. 30 7.90
14, 40 8, 50 10,30 7,05 7,45 8,90 7,25 0,50 9,70 9. 10 10.05 7,20 9,40 4.75
5.20
10,50 23,30 8,25 7. 15
26.25 8. 10 4.75 5.40 2.75
DETECTED PKS: 66 REJECTED PKS: 26
DIVISOR: 1.00000 MULTIPLIER: 1,00000
NOISE: 38,8 OFFSET: 36
RACK: 16 VIAL: 15 INJ: 1
NOTES: DBS CONFIRMATORY COLUMN
'ART SPEED 0.6 CM/MIN TEN: 8 ZERO: 10% 1 MIN/TlCK ATTEN: 16 ZERO: 10% 1 MIN/TICK
--2,707 - t \ i \ r i
CHART SPEED 0 . 6 C f ' l /M IN A T T E N : 8 Z E R O : 10?^ 1 \ ' \ \ l \ / l \ C Y - A T T E N : 16 ZERO: 10% 1 MIN/TICK
- H E P m & H t O
- A L D R
i so .e« - t t t -;=.16, 8 0 9
6 7 2
" H f 2 4 , 4 0 1 SURR 2 4 , 9 5 3 2 5 , 8 8 3 2 6 , 4 8 8 2 6 , 9 7 1
2 9 . 7 1 4
3 0 , 8 6 3
1 4 , 8 4 4 — — ^
12, 1 15
1-4.453
f i o ^l-.n ^ 1 6 . 2 1 3
1 5 . 5 7 3
± a = 3 ± s 5 ^ " " " ^
i .1 dr
OQ r
-ErDD 1 7 , 8 3 9
NDO < ^ ' ^ : ^ _ i n . 9 7 P
2 1 . 1 7 2 2 0 , 7 5 7
2 3 . 7 9 1
TITLE: PESTICIDES
CHANNEL NO: 2 SAMPLE:
PEAK PEAK RESULT NO NAME UG/ML
1 0 . 0 0 0 0 2 o OiO,<x&i
TIME CMIN) 6.119
8:52 16 JUN 88
METHOD: DB609
TIME OFFSET
AREA COUNTS
1559
SEP CODE VV
Wl/2 CSEC)
? 13.20
riTLE : PESTICIDES
!;HANNP"I *^n! 9
= EAK NO
1 2 3 4 5 6 7 9 9 10 1 1 12 13 14 15 16 17 18 19 20 21 22
T
t
25 26 27 28 29 30 31 32 33 34 35. 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52
PEAK NAME
A BHC
LINDANE
HEPTACHLO D-BHC ALDRIN
ISODRIN HEPT EPOX
ENDO I
DDE DIELDRIN-^
ENDRIN DDD ENDO I I
DDT ENDRIN AL ENDO S04
METHOXY
HBB SURR
• ^LS:
50&S- \ m S D SAMPLE: .£IiJ2Q MR _J 0_
RESULT UG/ML 0,0000 0,0000 0,0000 0,0000 0 , 0000 0,0000 0 , 0000 0 , 0000 0,0000 0,0008 0,0000 0, 1464^/ 0,0000 0,226l/" 0,0024 0,169l/ 0,0000
108,4560'^ 0,0012 0.0000 0.0000 0 , 0000 0,0000 0,0000 0.0000 0,0033 0, 0000
1— 0. 1381 • ' 0,0081
0.0000 0.0000 y 0, 2184>/ 0,0276 0,0194 0,0000 , 0,2568'/ 0,0424 0.0173 0.0000 0.0000 0,0000 0,0000 0,0000 0.0000 0.01 10 0.0000 0,0000 2.6834 0.0000 0.0000 0.0000 0.0000
112.4280
TIME CMIN) 6,119 6,322 6,408 6, 999 7,296 7,421 7,980 9, 734 10,159 1 1 ,525 12,354 12,780 13,321 13,806 14,510 14,844 15,713 16,213 16,566 16,809 17,120 17,291 17,423 17,596 17,852 18,025 18,315 1 n / ^ 1 O . O c C ^
19,041 19,228 19,354 19,751 20,042 20,362 20,567 20,933 21,392 21,672 22,054 22,206 22.477 22,815 22.975 23,342 23,581 24, 1 17 24.401 24.953 25,278 25,883 26,488 30.863
8:
- MFTHOn 1 ) t_ ( n \./ L>
TIME OFFSET
0,015
-0,010
-0.034 0 , 000
-0,046
-0,187 -0,084
-0,085
— _(0i 1 O O <? . 1 £ia
-0,039
-0,129 -0,108 -0,078
-0,147 -0,048 -0,148
-0,169
-0,047
-1.472
52 16
: DB608
AREA COUNTS
1559 1554 1712 562 1921 1307 595 1794 4308 1657 2076
•244864 4580
213291 3656
255870 1349
221792 1789 740
6674 3529 2247 3018 1562 4251
40207 1 O ET C* /I rt
L V D D n <?
10810 7244 5051
141800 28616 22932 6347
193095 42894 14584 1 1050 5528 9124 13171 7705 2426 3699
152482 3837 1335 1995 1463 845
3303
1914340
JUN 88
SEP CODE VV VV VB BV VV VB BV BV VB BB BV VV VV VV VV VV VB BV VV VV VV VV VV VV VV VV VV vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv VB BB BV BB
7 7 7
7
?
? 7 7
7
7 ? ?
7
? ?
?
?
?
? ?
?
Wl/2 CSEC) 13,20 6,70 9, 10 9.60 5. 10 6. 15 4,60 8.60 5.20 13.50 6,20 4,95 3,40 3.55 10,55 6,10 4.00 6.00 6.65 6.05 9, 10 4.60 1 .95 7. 15 8.30 6.50 6.20 5.90 9.55 6.60
10. 15 6.00 15.70 9.50 8.75 5.90 1 1 .40 13.80 9.00 6.50 6.85 6. 15 7. 10 7.00 6.50 7.05 15.30 8.60 13.95 7.75 13.00 17.20
ETECTED PKS: 86 REJECTED. PKS:. 34
I VISOR:. 1.0.0000 : MULT I PL IER: .1,00000.,.
0 I SE:;-l,.;)^^7.]?J:^:|^0Fi::SET.: - j / : / / 1 5V•^•"• •.;•••• ;. -i',.v;V;":
f^CY.77it^77^777i\'AL-i77:'')^ 7 ' ' ':.IU:T77A'"'^'7XA'"7
TITLE : PESTICIDE
CHANNEL NO: 1
PE NO
1 2 3 4 5 6 7 8 9 10 1 1 12 13 ! 4
15 ' 16
17 ' 18
19 20 21 22 23 24 25 26 27 28 9 i
31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46
PEAK NAME
B BHC LINDANE
HEPTACHLO
ISODRIN
ENDRIN
ENDO I I DDD END ALD
ENDO S04 DDT
METHOXY"
TOTALS:
CONFIRMATORY
SAMPLE:
RESULT UG/ML 0,0000 0.0000 0.0000 0,0385 0,0110 0,0000 0 , 0000 0,0000 0,0000 0,0000 0,0121 0,0000
420.8960 0 . 0000 0.0000 0,0000 0,0000 0,0277 0,0000 0.0965 0,0389 0,3122 0,0000 0,0554 1 ,3025 0,0000 0.0000 0,0000 0.0000 0.0000 0.0000 0.0000 2,2634 0.0000 0 , 0000 0,0000 0,0000 0.0000 0 , 0000 0.0000 0.0000 0.0000 0.0000 0.0000 0,0000 0.0000
425.0540
SAME
TIME CMIN) 7,309 7, 566 7,820 10,246 11,001 1 1 ,275 1 1 ,563 11,717 11,816 12,115 12,837 13,005 14,453 15. - ^ 1 - ^ 15,550 16,427 17,424 17,540 17,599 17,839 18,027 18,396 18,601 18,972 19,251 19,429 19,627 19,826 20.013 20.272 20,423 20.457 20,757 20,918 21,115 21,172 21,477 21 ,768 21,897 22,093 22,422 23.004 23,422 23,597 23,791 24.048
e: METHOD
TIME OFFSET
0, 106 -0,019
0, 127
-0,207
0, 040
0, 109 0,067 0,116
-0,028 0, 161
-0.003
0,469
52 16
: DB5
AREA COUNTS 81285 4361 4648 8949 5784 10738 1613 1622 558
267891 5482 4853
269805 1553
255970 248379
7809 7914 5720 8931 1 1801 84389
234080 16803
220761 15766 30240 35041 49492 18491 13078 14605
226339 38021 19994 19924 17790 17909 16652 56909 174754 25059 12631 5152 4530 2912
2595970
JUN 98
SEP CODE BV VV VB BB BV VV VV VV VV VB BV VB BB BV VB BB BV VV VV VV VV VV VV VV VV VV VV VV VV vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv VB
7 7
7
7
'
7 7 7 7 7
?
'> ? 7
7 ? 7
7 ? 7 7 ? ?
7 7 ? ? ?
Wl/2 CSEC) 5.00
6, 40 2.95 7,65 5. 00 1 ,55 1 ,05 1 ,45 6, 50 5.30 3.50 6,85 5, 05 7,20 7,20 5,60 4,50 6,05 6, 90 8, 65 6,90 7,45 9,65 7,45 3,20 1 1 ,80 9.65 11.10 8,40 6,50
7,45 12,80 6,30
10, 60 8.70 6.05 10.70 7.25
24, 15 9.60 6, 70 7.50 8. 10
DETECTED PKS: 75 REJECTED PKS: 29
DIVISOR: 1.00000 MULTIPLIER: 1.00000
NOISE: 38,8 OFFSET: 24
RACK: 16 VIAL: 1 INJ: l
NOTES:
•)B5 CONFIRMATORY COLUMN
SSI - SS(.
A A i \ AnalyticalTechnologies, Inc
GAS CHROMATOGRAPHY - RESULTS
REAGENT BLANK
TEST : ORGANOCHLORINE PESTICIDES AND PCB'S (EPA 8080) ATI I.D. : 805088
CLIENT : MONTGOMERY & ASSOCIATES DATE EXTRACTED : 05/23/88 PROJECT # : 661 C DATE ANALYZED : 06/14/88 PROJECT NAME : HASSAYAMPA UNITS : MG/KG CLIENT I.D. : REAGENT BLANK DILUTION FACTOR : N/A
COMPOUNDS RESULTS
ALDRIN ALPHA - BHC BETA - BHC GAMMA - BHC DELTA - BHC CHLORDANE 4,4'-DDD 4,4'-DDE 4,4'-DDT DIELDRIN ENDOSULFAN I ENDOSULFAN II ENDOSULFAN SULFATE ENDRIN ENDRIN ALDEHYDE ENDRIN KETONE HEPTACHLOR HEPTACHLOR EPOXIDE METHOXYCHLOR TOXAPHENE AROCLOR 1016 AROCLOR 1221 AROCLOR 1232 AROCLOR 124 2 AROCLOR 124 8 AROCLOR 1254 AROCLOR 1260
<0.005 <0.005 <0.005 <0.005 <0.005 <0.05 <0.01 <0.01 0.041 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.005 <0.005 <0.05 <0.1 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05
f K^ dlenf/t Tn • ON SIS' oiHi'ii
I-) D5f's
?.) ,lc «.Mn Mffn/h/ ^ f i j ^
Sir IXJM- <»*«^;<(J-C4;!^ ; 0(i7lH/i%
Cefi nyforfi. cU fii) oi / i i i l^
SURROGATE PERCENT RECOVERIES
ISODRIN (%) 100
CHPiRT SPEED 0 . 6 CM/MIN ATTEN: 8 ZERO: 10% 1 MIN/TICK
-TTTAT-T/INJECT
ATTEN: 16 ZERO: 10% I MIN/TICK
£ 1 .929
—-^. 20.8^^
25,261 25,942
29,835 rd 30.515
SR OFF
16.396
7.399
— — 15.702
EN&-$ttr 18.540
20.329
m. 24.546
•| LE: PESTICIDES
CHANNEL NO: 2
W
• / -
ul ^
flJ'^ ^
^
0:51 14 JUN 88
SAMPLE: (yMB 5/23 METHOD: DB606
3PEAK :> NO 3 1
2 T.
PEAK NAME
RESULT UG/ML 0.0000 0.0000 •V A ^ ^^ ...
TIME CMIN) 6.320 7.443
TIME OFFSET
AREA COUNTS
975 613
SEP CODE VB BB
Wl/2 CSEC) 9.25 5. 10
TJT.LE:' PESTICIDES 0:51 14 JUN 88
CHANNEL NO; SAMPLE: MB 5/23 METHOD: DB608
OPEAK oo 1 O 1
2 3 4 5 6 7 8 9 10 1 1
PEAK NAME
2 3 4 5 6 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45
LINDANE B BHC
HEPTACHLO
ALDRIN ISODRIN HEPT EPOX
ENDO I
DDE DIELDRIN
ENDRIN DDD ENDO I I DDT ENDRIN AL
ENDO S04
METHOXY HBB SURR
i? TOTALS;
RESULT UG/ML 0.0000 0.0000 0.0000 0.0000 0,0000 0,0000 0.0000 0,0000 0.0000 0.0012 0.0089 0,0000 0,0061 0,0000 0.0019
99.2699 0,0009 0.0000 0.0000 0.0006 0.0000 0.0009 0,0033 0,0000 0.0000 0.1004 0,0031 0,0009 0.3702 0,0099 0,0000 0.0016 0.0000 0.0000 0,0000 0.0000 0.0000 0.3198 9,4470 0.0000 0.0000 0,0000 0.0000 0.0000 0.0000
109.5470
TIME CMIN) 6. 320
443 000 809 200 262 017 399 879 058 543 936 318 859 985 396 712 343 824 191 542 817 368 680 003 329 547 852 217 679 973 551 707 944 135 334 741 546 892 261 748 942 414 927 136
TIME OFFSET
Wl/2 CSEC) 9.25
7 8 9 10 1 1 12 12 12 13 13 13 14 14 14 16 16 17 17 18 18 18 19 19 20 20 20 20 21 21 21 22 22 22 23 23 23 24 24 25 25 25 26 26 27
-0, 022 0.243
0, 178
-0,225 -0,004 -0,268
0.081
0.067 0.288
0,079 0,037 0,042 -0.223 -0,141
0,361
0,376 •0. 108
0,761
3246 1086
186019 10019 7465 1340 1315 231 1 2191 4013 2285
107098 4700 1731 2048 81 1 1663 792 580
693812
? ?
7 ?
5, 4, 7. 5. 12. 15, 5. 7,
10 35 05 45 70 30 45 30
10.55 10.40 8.40 6. 6. 6. 9, 12, 6. 9, 5. 5. 15. 9, 9. 6,
40 40 00 30 40 75 00 95 45 55 90 00 15 15. 00
5. 15 5.90 7.70 9, 6. 8. 1 1 . 9, 5, 7, 6. 16,
10, 10. 34,
35 40 40 90 20 95 90 80 15
15.05
50 05 90
DETECTED PKS:
;;J DIVISOR: 1 . 00000
» NOISE:
iRACK: 16
65 REJECTED PKS: 20
MULTIPLIER: 1.00000
4.9 OFFSET: 9
V I A L : 5 INJ: 1
-, NOTES: i DB608 PRIMARY COLUMN
^ - ' -^1 •- • a . = L £ . ^ , . . . r — .
7'-i7^7A:
:m7^;
43 4-4 4 5
' T O T A L S :
I
DL CTED P K S : . > [ D I V I S O R : 1,00000
0,0000 0.0000 0.0000
109.5470
26.414 26.927 27.136
1 tob.i 792 580
V V
VV VV
1 u , 10,
? 34,
, Z/V
,05 .90
0.761 693912
65 REJECTED PKS: 20
MULTIPLIER: 1,00000
'NOISE:
.RACK: 16
4,9 OFFSET;
VIAL: 5
9
INJ: 1
NOTES; DB608 PRIMARY COLUMN
j* TITLE: PESTICIDE CONFIRMATORY ) {•CHANNEL NO: 1 SAMPLE: SAME
PEAK NO
1 2
3 3 JO ^
6 7 8 9 10 1 1
PEAK NAME
DIELDRIN ENDRIN
END ALD
DDT
METHOXY 16 1 7 18 19 20 21 22 23 24 25
TOTALS:
RESULT UG/ML 0, 0, 0, 0. 0. 0, 0, 0. 0, 0, 0, 0, 0. 0. 0. 0, 0. 0, 0. 0. 0. 0, 0, 0, 0.
0
0000 0000 , 0000 0000 0000 ,5865 ,0107 0000 0127 , 0000 , 0475 ,0000 , 0000 , 0000 ,0548 , 0000 . 0000 ,0000 . 0000 , 0000 . 0000 , 0000 , 0000 , 0000 ,0000
.7122
TIME CMIN) 7.
• 1 1 , 12, 12. 15. 16. 17. 17. 18. 18, 19, 19, 19, 20, 20, 20, 21 . 21 , 21 . 22. 22. 22. 23, 23, 24,
399 412 260 447 702 581 395 61 1 177 ,540 ,415 ,786 ,935 ,417 ,681 ,917 . 291 . 389 . 671 . 060 . 264 . 607 , 157 , 623 , 004
0:51 14
METHOD: DB5
TIME OFFSET
-0.189 -0.105
-0.103
0,325
-0.079
-0.151
AREA COUNTS 78494
14784 3025 7800 5995
217236 3066 6100
/ 3437 / 57844
8049 14848
i/86760 10976
, 5479 / 220050
791 1 5452 4898 14362 7412
143431 19027 13105 6397
965938
JUN 89
SEP CODE BB
BB BV
. VB BB BB BV VB BV VB BV VV VV VV VV VV VV VV VV VV VV VV VV VV VB
?
?
? ? ? ? ? ? ? ?
? ? ?
Wl/2 CSEC) 5,35
4.95 4. 50 4.90 5.40 7. 05 6.30 7.50 7.35 5.95 7.35 9.00 6.55 7.40 9.60 4.45 10. 60
7.30 9.30 7.40 7.30 13.80 9.90 9.00
DETECTED PKS: 32 REJECTED PKS: 7
DIVISOR: 1.00000 MULTIPLIER: 1.00000
NOISE: 34.0 OFFSET: 16
R. .<: 16 VIAL: 5 INJ: 1
)NOTES: ' DB5 CONFIRMATORY COLUMN
SSI - SSL
A /jN-AnolylicolTechnologies, Inc
GAS CHROMATOGRAPHY - RESULTS
REAGENT BLANK
TEST : ORGANOCHLORINE PESTICIDES AND PCB'S (EPA 8080)
CLIENT PROJECT # PROJECT NAME CLIENT I.D.
MONTGOMERY & ASSOCIATES 661 C HASSAYAMPA REAGENT BLANK
ATI I.D. DATE EXTRACTED DATE ANALYZED UNITS DILUTION FACTOR
805088 06/15/88 06/16/88 MG/KG N/A
COMPOUNDS RESULTS
ALDRIN ALPHA - BHC BETA - BHC GAMMA - BHC DELTA - BHC CHLORDANE 4,4'-DDD 4,4'-DDE 4,4'-DDT DIELDRIN ENDOSULFAN I ENDOSULFAN II ENDOSULFAN SULFATE ENDRIN ENDRIN ALDEHYDE ENDRIN KETONE HEPTACHLOR HEPTACHLOR EPOXIDE METHOXYCHLOR TOXAPHENE AROCLOR 1016 AROCLOR 1221 AROCLOR 123 2 AROCLOR 124 2 AROCLOR 124 8 AROCLOR 1254 AROCLOR 1260
<0.005 <0.005 <0.005 <0.005 <0.005 <0.05 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.005 <0.005 <0.05 <0.1 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05
SURROGATE PERCENT RECOVERIES
ISODRIN (%) 100
U T i £ N :
"STAT
• R ' F R 0 : [ 0 % ! M I Ny "! 1 OK •I t N
SR: 0
- t l U ^ f i T ^ E 1 2 . 7 3 6 —I 13,379
- D ^ ^ S ^ 1 4 , 6 7 4
IS0|&f?-H-i—• T EPOX 1 6 , 7 2 3
1 7 . 7 8 2 EN^O I 1 8 . 2 6 6
~D-hELDBI 9 . 0 0 4 •?^!§9i
2 0 , 0 0 0
__ _ 2 0 , 9 9 7 EfemjRTWAL 21 , 3 7 4
2 1 . 9 6 4
2 2 . 7 0 2 MELllHOXY 2 3 . 0 2 8
H&S
n -
SURR 25.223 25,966 26.195
27,661
29,228 29,428
n — — I 30,800 • )
D
JgTiTLE: PESTICIDES
O .,,HANNEL NO: 2
Z PEAK PEAK O NO NAME M 1 ro 2 ^ 3 S 4 LINDANE
RESULT UG/ML 0.0000 0 , 0000 0 . 0000 0.0010 r\ i ^ n . n , i ^
7 T^^rzPS
SR: OF
4,719
3,822
-^? 7, 663
"" 8,572
7.250
i B Brte/ 10, 148
11,248
=^T~ 12,092
16,165 15,518
17,196
METHO
24,068
22.378
SAMPLE: 5t2i9e
2:49 1£^JUN'88
M E T H O D : DB608
TIME CMIN) 6. 290 10.111 12.005 12.736 I 1 T-JQ
TIME OFFSET
-0.054
AREA SEP COUNTS CODE
548 VB 3005 BB 3820 BB 1617 BB 557 BB
Wl/2 CSEC)
? 5.35 5.20
7 5. 10 10.20
M-EJJHOXY. 2 5 , 0,i.'S
HSS
2 4 , 0 6 8
SURR 2 5 , 2 2 3 2 5 . 8 6 6 2 6 . 1 9 5 •
2 7 . 6 6 1
2 9 . 2 2 8 2 9 . 4 2 8
3 0 . 8 0 0
TITLE: PESTICIDES
CHANNEL NO: 2
l7 i l
PEAK NO
1 2 3 4 5 6 7 8 9 10 1 1 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28
, 29 ; 30 , 31
32 33
PEAK NAME
LINDANE
D-BHC ALDRIN ISODRIN
ENDO I DDE DIELDRIN
ENDRIN
ENDO I I DDT ENDRIN AL
ENDO S04
METHOXY
HBB SURR
TOTALS:
RESULT UG/ML 0.0000 0,0000 0,0000 0,0010 0.0000 0.0017 0,0019 /
99. 7834^/ 0 . 000-0 0,0000 0,0039 0,0015 0.0005 0.0000 0,0000 0.0117 0.0000 0,0052 0.0154 0.0177 0.0000 0.0015 0 . 0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.3991 0.0000 3.1075
. 0.0000 0.0000
103.3420
TIME CMIN) 6. 290 10.111 12.005 12.736 13.379 14.674 14,799 16,165 17,299 17.782 18.266 18,580 19.004 19,383 19,679 20. OOO-" 20.299 20.493 20,887 21 ,374 21,608 21,864 22,068 22,195 22,602 22,702 22.917 23.028 24.068 24.329 25.223 25.966 27.661
METHC
TIME OFFSET
-0,054
0, 164 -0,101 -0,235
0, 156 -0.170 -0.076
0, 120
0, 053 -0,193 -0,066
0, 044
0.319
0,223
0, 183
D: DB608
AREA COUNTS
548 3005 3820 1617 557
2606 2788
204056 762
2181 4946 2084 722
2508 2892
SEP CODE VB BB BB BB BB BV VB BB BB BB BV VB BV VV VV
7 5 7 2 ^ VV 261 1 61 13 1 1607 17960 1529 1229 1674 2405 1469 1 163 517
3751 130317
3389 1546 518 797
431259
VV VV VV VV VV VV VV VV VV VV VV
vv vv vv VB BV BB
?
7
? 7
?
7
? ?
7
7
7 -> ? ?
?
? ?
Wl/2 CSEC) 5.35 5.20
5. 10 10,20 5,70 6, 90 5. 80 10. 80 1 1 .00 10.05 1 1 . 70 7.90
13. 00 11.10 8.05 12.00 17.25 5.55 7,45
12, 10 5.55 8.30 6.95 7. 40
22.90
60. 10 6.80 18.00 7.30 10.30 9. 10
DETECTED PKS: 54 REJECTED PKS: 21
VISOR: 1,00000 MULTIPLIER: 1.00000
NOISE: 7.3 OFFSET: 14
RACK: 16 VIAL: 3 INJ: i
NOTES: DB608 PRIMARY COLUMN
T ITLE ) ;CHANN
\J-[ N u ! 1
2 : 3 » 4 I 5
6 7 8 9 10
' 1 1 * 12 ^ 13 I M , 15 r 16 0 17 0 18 0 19
: PESTICIDE
EL NO: 1
PEAK. NAME
B BHC
ENDO I ENDRIN END ALD DDT
METHOXY"
J- TOTALS:
DETECTED PKS:
" D I V I S O R : 1,00000
z ' N O I S E : 30,4 1 (
"0 . .K.
CONFIRMATORY
SAMPLE:
RESULT UG/ML 0,0000 0,0000 0 . 00013 0.0000 0.0139 0 . 0000 0 , 0000 0,0000 0.8853 0,0047 0,0149 0,0160 0,0000 0,0000 0.2937 0,0000 0,0000 0.0000 0.0000
1 .2285
SAME
TIME CMIN) 7,250 7,663 7,771 8,572 10,148 1 1 ,248 12,092 15.518 16,390 17.196 18,360 19,227 19,744 20,475 20,715 22,055 22.378 22.967 23.751
34 REJECTED PKS
2:
METHOD
TIME OFFSET
0, 008
0,310 -0,304 0, 080 0, 137
--0,045
0. 186
: . 15
M U L T I P L I E R : 1,00000
OFFSET:
16 V I A L : 3
^ NOTES: T DB5 CONFIRMATORY COLUMN < D -•> ..A
D D • U a
40
I N J : 1
"
49 16
: DBS
AREA COUNTS 86929 5566 4741 3010 3244 12568 5394 8513
• 227009 1331 4015
.. 27 18 4910 3207
29370 3280
159801 15276 3308
584190
JUN 88
SEP CODE BV VV VB BB BB BB BB BB BB BB BB BB BB BV
• VB BV
• VV VB BB
'
Wl/2 CSEC) 5.50
? 5.20 3.00 5. 20 5,50 5, 10 4,95 5,65 7,45
? 6. 00 5,85
? 10,00 5,20 6,35 5,75
'. 7.05 . 7.20
7.70 6.65
CHART SPEED 0.6 CM/MIN MTTEN: S ZERO; 10% 1 i'i I N.' T i C K ATTEN: 16 ZERO: .10% 1 MIN/TICK
^.i6i
9,724
- t r I N M N E 1 2 . 7 3 4
1 1 . 2 4 5 1 2 . 0 1 9
? ^
6 V /
^
A" 1 ' O'"'
CHART SPEED 0.6 CM/MIN ATTEN: 8 ZERO: 10% 1 MIN/TICK
I
"STAT—r INJECT
ATTEN: 16 ZERO: 10% 1 MIN/TICK
f i i / m - ^ ^ ^ ~
7^7^7 ' "5^ I
11,172 — A BHC
•"LINDANE
r)'TiEPTACHILX ) —
' " T N D O J _
isoDEm=-4-^4^-2a&
-re,42z
^NDO I I
ENDRIN AL
-nETHOXY_
-WBB SUW^
.23.. 408 -2?i . f l54
2 6 . 4 4 1
2 9 . 1 2 3 9 , 7 2 7
1 7 . 4 1 7 ' 1 8 . 0 4 9
2 4 . 7 0 1 —
1 2 . 1 2 4 1 3 . 0 1 9
sM-^^^ ^
oAM^
TIiwc': PESTICIDES
CHANNEL NO: 2
PEAK PEAK NO NAME
1 2 .
\ ^
SAMPLE: MIX XI
RESULT UG/ML 0.0000 0 . 000C^
TIME CMIN) 6.083 -> 1 T T
1 9 : 1 4 1_3_ JUN 88
METHOD: DB609
TIME AREA SEP Wl/2 OFFSET COUNTS CODE CSEC)
548 BB 5.30
CHANNEL N O : 2
PEAK NO
1
4 5 6 7 8 9 10 1 1 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32
35 36 37 38 39 40 41 42 43 44 45 46 47 48 49
PEAK NAME
A BHC
LINDANE B BHC HEPTACHLO D-BHC
ALDRIN
ISODRIN
HEPT EPOX
ENDO I
DDE DIELDRIN
ENDRIN DDD ENDO I I DDT ENDRIN AL ENDO S04
METHOXY HBB SURR
TOTALS:
SAMPLE:
RESULT UG/ML 0,0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.7680 0.0000 0.0000 0,8487 1.1706 1 .2835-0.9096. 0.0000 0,0000 0.9448 0.0000 0,0000 0,7888 0,0000 0.9093 0.0000 0.0000 0.9909 0.0000 0.9131 0.9192 0,0000 0,0000 1.6992 0,9126 0.9103 1.7106 0,9713 1,2997 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0,0000 0,0000 6,7012
702.9490 0.0000
727.1890
1
MIX XI
TIME CMIN) 6,083 7.173 7^465 8.300 9.026 9,202 9. 885 10.249 11,723 12,593 12.674 13.019 13,238 14.0;?4 14,438 14.813 14.954 15,143 15.855 16.078 16.285 16.546 16.91 1 17.417 17.636 18,048 18,427 18.686 19,018 19,508 19,779 20,182 20.435 20,738 21,368 21,745 22,121 22,548 22.729 22.944 23,003 23.169 23.408 23.488 23.780 23,854 24,091 24,701 29.727
METHOD: DB608
TIME OFFSET
-0,057
-0,061 -0,062 -0,066 -0,072
-0.067
-0, 1 15
-0,069
-0,062
-0.064 -0.062
-0,068 -0,075 -0,072 -0,072 -0.075 -0,069
-0.079 -0,299
-1,566
AREA COUNTS
548 1055 2863 776
6656 1059 1720
22694 1526910
12864 10738
1419200 777806
-1210840 1397230
17973 ,,..-l-3 ?««v /l 4293 10 r 4'758
A 16l"3 ' l33567/
izu'rr/0 51771 10878
1163040 5456
JJ-5iii^ 1228850
12556 9514
830066 ,9-4-^79 T 0 /Bb>'7'i5
'§'81864 1093170
18638 36761 6043 5973
25179 1 1436 7307
35801 5459
2244210 349726
935
21177600
SEP CODE BB EV VB BB BV VV BV VB BV VV VV VV VV VV VV VV VV VV VV VV
\ VV
/ vv vv vv vv vv vv vv vv vv vv vv vv vv
^ vv vv vv vv vv vv vv vv vv vv vv vv vv VB BV
?
? ?
7 ? ? ?
?
? 7
?
?
? ? 7 7 ? 7 ? ?
?
1 Wl/2 • " ^ ^ 1 CSEC) 1 5.30 1 5.40 i 5.05 1 5.80 1 5.35 1 15.90 1 5.95 1 7.45 § 6.65 1 8.50 1 8.70 1 6.55- g 4.95 1 6.75— 1 6.20 1 5.60 g 6.60 1 4.75- i
i 6.75
6.55 6.95 6. 40 6.95 7.05 1 1 .70 1
7.20-S)feM 1 1 1 .25 1 7.50 . 1 6 , 50'"'JvA 1 6.35 1
6.45 E 6.20 1 13.10 1 8.50 3.00 1 .40
1 1 .60 9.90 5. 10 14.50 1 . 80 6. 15 7. 50 13.65
DETECTED PKS: 75 REJECTED PKS: 26
DIVISOR: 1,00000 MULTIPLIER: 1,00000
^IOISE: 4.9 OFFSET: 15
RACK: 16 VIAL: 9 INJ: 1
^IOTES:
DB608 PRIMARY COLUMN
ri i^E : PESTICIDE
CHANNEL NO: 1
'EAK NO
1 2 3 4 5 6 7 8 9 10 1 1 12 13 14 15 16 17 18 19 20 21 22 23 -, /I
iio
27 28 29 30 31 32 33 34 35 36 37 38 39 40
PEAK NAME
A BHC DBHC LINDANE
HEPTACHLO
ALDRIN
ISODRIN ENDO I DIELDRIN DDE ENDO I I END ALD
ENDO S04 DDT
METHOXY"
OTALS:
CONFIRMATORY
SAMPLE:
RESULT UG/ML 0. 0000 0. 0000 0. 0000 0. 0000 0 . 0000 0.0256 0.0093 0.1139 0.0000 0.0000 0.0000 0.0892 0.0000 0.0000 0.0000 0.0910 0.0000 0 . 0000
944.6830 2.4815 0.1392 1.5628 0.8884 2.0640 0.0000 1.8809 0.1354 0.0000 0.0000 0.0000 0.0000 0.9488 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
955.1130
SAME
TIME CMIN) 6. 741 7,537 7. 666 8,692 8,896 9.602 10.547 10.890 1 1 .420 12.124 12.419 12.770 13.019 13.379 13.591 13,840 13,928 14.502 14,767 15,871 16,750 17.020 17.737
_-18, 148 18,701 18.927 19.280 19.583 19.803 19.928 20.325 20.679 21 .060 21 .297 21 .792 21 .997 22.056 22,442 22,662 23.171
19:
METHOE
TIME OFFSET
0. 172 0. 137
-0.130
0. 060
0. 040
0, 107 -0,209 -0,020 0. 170 0, 007
-0,132
-0,073 0. 190
-0.091
0.239
14 13 JUN 88
): DBS
AREA COUNTS
3391 5689 15096 40677 9154 15057 5159
59973 737798 393331 674327 40558
644432 39219 10013 43315 25684 261 1
605566 636290 51549
578828 82262
557825N 5 1 1 157^ 569974 22947
474813 460819 459170 498412 94880
674654 57974 40321 17783 20337
234751 735435 201 13
10171300
SEP CODE BB BV VB BV VB BB BB BV VV VV VV VV VV VV VV VV VB BV VB BV VV VV VV VV VV VV VV VV VV vv vv vv vv vv vv vv vv vv vv VB
? 7
?
?
7 7 7 ?
7 ? ? ?
? ? ? ? ? ? ?
?
Wl/2 CSEC) 8.55 5.20 4.95 5.75 7.90 5.00 4.20 6.20 7.95 6. 15 7.90 1 1 .95 7.50 10.05
6.00 19.60 4.95 9.00 9. 15 6.30 8.00 6.70 8.05 7.70 8.20 4.50 5.00 7.90 8.30 7.80 10.80 6.30 4. 90 16.40 7.30
5.45 10. 45 10.60
ETECTED PKS: 49 REJECTED PKS: 9
IVISOR: 1,00000 MULTIPLIER: 1,00000
OISE: 34,0 OFFSET: -42
ACK: 16 VIAL: 9 INJ: i
OTES: DBS CONFIRMATORY COLUMN
HART SPEED 0.6 CM/MIN
n ;* CHART SPEED 0 . 6 C M / M I N R A T T E N : 9 ZERO: 10% 1 M I N / T I C K ATTEN: 16 ZERO: 10% 1 MIN/TICK
o o 29.554 _ ,30,015
Q)
ICIDES
%i7% -
\\X!'!SULT
o.m!^ SAMPLE: MIX X
TIME
16:45 13 JJJN_-a9
METHOD: DB608
TIME AREA SEP
11.419 12.125
' 13.017
15.970
17.020
Wl/2
CHANNEL NO: 2 SAMPLE: MIX X ^ M E T H O D : DB608
PEAK NO
1 2 3 4 5 6 7 8 9 10 1 1 12 13 14 15 16 17 19 19 20 21 22 23 24 25
I 26 > 27
29 29 30 31 32 ^3 4
35 36 37 38 39 40 41 42 43 44 45
PEAK NAME
A BHC
LINDANE B BHC
HEPTACHLO D-BHC
ALDRIN
ISODRIN HEPT EPOX
ENDO I
DDE DIELDRIN
ENDRIN DDD ENDO I I
DDT ENDRIN AL ENDO S04
METHOXY HBB SURR
TOTALS;
RESULT UG/ML 0.0000 0.0000 0.0000 0.1954 0.0000 0.0000 0.0000 0.1929 0.2293 0.0000 0.2173 0.2053 0.0000 0.0000 0.2140 0.0000 5,2922 0.1741 0. 0000 0.0000 0.1929 0.0000 0.1700 0.1788 0.0000 0.0000 0.0000 0.3088 0.1767 0.1676 0.0000 0.2963 0.1511 13.2097 0.0000 0.0000 0.0000 0. 0000 0.0000 0.0000 0.0000 1.9098
113.7300 0.0000 0.0000
124.1840
TIME CMIN) 7.456
019 242 717 222 589 665 012 230 762 067 429 800 953 138 014 545 906 418 638 047 400 688 018 342 498 767 179 432 734 135 368 742 1 18 570 735 922 173 332 550 733 086 696
002 226
9, 10. 1 1 . 12. 12, 12, 13, 13 13 14 14 14 14 15 16 16 16 17 17 18 18 18 19 19 19 19 20 20 20 21 21 21 22 22 22 22 23 23 23 23 24 24 27 27
TIME OFFSET
-0.063
•0.068 -0, 070
-0, 073 -0,081
•0,072
0, 145 -0. 074
-0,063
-0,062 -0,062
-0, 071 -0. 078 -0. 076
-0, 072 -0.078 •0. 072
-0,084 -0. 104
-1.178
AREA COUNTS
507 1215 4303
368523 3494 14894 7518
322630 152352 3769
_204963 315367
9356 6233
323811 9565
. 10802 259896 1 1890 4699
238735 2305
240764 239070
1201 1801 1407
151744 182934 198568 2013
149911 152888 176508 3124 7374 1991 6951 3450 41 1 1 4564
639593 56582
678 658
4504590
SEP CODE VB BB BB BV VV VV VV VV VV VV VV VV VV VV VV VV VV vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv
Wl/2 CSEC) 5.25
7 7 7 '>
7 7 7
?
? ?
5. 6, 4,
14 1 2 4
5 4 4 6 3
6 5 5. 5. 6. 3. 5. 6.
3. 5. 5. 5. 5. 8. 5, 5. 5, 6, 7.
30 75 80
40 90 85 90
,85-,75 ,50 ,80 ,60 —
,55 ,90 ,90 , 10 .00 .60 . 40 . 05rX)'« 17 80 00 8 0 •'• 50 80 70 80-45 65 70 00
;:^^7m7l/^^
0.70 14.10 0 4 6 6 7 13 9
80 10 80 80 50 60 40
"•pp ,f
DETECTED PKS: 76 REJECTED PKS: 31
DIVISOR: 1.00000 M U L T I P L I E R : 1.00000
NOISE: 4.9 O F F S E T : 11
RACK: 16 VIAL: 8 INJ: 1
NOTES: DB608 PRIMARY COLUMN
TITLE: PESTICIDE CONFIRMATORY
l ll LLLLliU—_hiilJ_.. 1 CftMPir; SAME
16:45 13 JUN 98
METHOD: DBS
o 3 .-f (fi
5
2 p rsj SJ bli
CX>
o" •U
a. • ^
n F+
0
ISJ LO ^ ^ 0 X
0 -4. -A
o D a. 2-
h ^ |J CD
TITLE : PESTICIDE
L NNEL NO: 1
PEAK NO
1 2 3 4 5 6 7 8 9 10 1 1 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 "•7
I B 29 30 31 32 33
PEAK NAME
A BHC LINDANE
HEPTACHLO
ALDRIN ISODRIN ENDO I DIELDRIN DDE ENDO I I END ALD
ENDO S04 DDT
METHOXY"
TOTALS:
CONFIRMATORY
SAMPLE:
RESULT UG/ML 0.0000 0.0000 0.0000 0.0100 0.0180 0.0000 0 . 0000 0.0000 0.0116 0.0000 0. 0000 0.0213
374.8090 0.9727 0.0255 0.5957 0.1985 0.7822 0.0000 0.7306 0.0264 0.0000 0.0000 0.0000 0.0000 0.1494 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
378.3510
SAME
TIME CMIN) 7.546 7,661 8, 688 9,607 10.890 1 1 ,419 12.125 12.419 12.719 13.017 13.316 13.849 14,764 15.870 16.751 17,020 17.738 18,148 18.699 18.927 19,216 19,584 19.804 19.931 20.327 20.685 21.062 21.307 21.795 22.137 22.446 22.662 23,180
16:
METHOD
TIME OFFSET
0, 177 -0,130
0, 009
0,049 0. 104
-0.210 -0.019 0. 170 0.008
-0.132
-0.073 0. 126
-0,075
0,004
45 13
: DBS
AREA COUNTS
2816 4776 12853 5899 9493
287879 138326 268392
5258 248536
4299 10159
240262 249400
9435 220625 18383
21 1392 206504 221400
4492 179391 182061 163750 165830 14942
265779 6959 5707 5369
72646 399707
4182
3844890
JUN 88
SEP CODE BV VB BB BB BB BV VV VV VV VV VB BB BB BV VV VV VV VV VV VV VV VV VV VV VV VV vv vv vv vv vv vv VB
? 7
7
?
?
?
7 ?
? 7 ? 7 ? ?
?
Wl/2 CSEC) 4.80 5.30 5.35 5.60 5.80 6.25 5.95 6.30
6.20 13.90 5.30 6. 70 7.05 5.95 7.00 7,20 7.25 7. 10 7.45
7.30 7. 50 7.55 7.60 10.30 5.35 5.00 12.30 23.00 5.70 7.40 8.90
DETECTED PKS: 37 REJECTED PKS: 4
DIVISOR: 1.00000 MULTIPLIER: 1.00000
NOISE: 42.5 OFFSET: 17
RACK: 16 VIAL: 8 INJ: 1
NOTES: DBS CONFIRMATORY COLUMN
CHART TEN;
^ -TAT n o TI
5
SPEED 9
:'RESET
0.6 CM/MIN ZERO: 10% 1 MIN/TICK ATTEN; 16 ZERO: 10% 1 MIN/TICK
I—
CHART SPEED 0 . 6 CM/MIN ATTEN: 8 ZERO: 12)% 1 MIN/TICK
STAT : INJECT
~ 5 R : 0 ^
-1 . 5 3 0
3 . 9 9 4
7 . 2 2 6
1 0 , 3 1 7
(5) CO
c m r-O O
HEPTAXfHlrO 15.12133-
_ L S e ^ i m L 1 6 . 6 3 0 -...
H E g ^ ^ P O X 1 7 , 5 0 4
U (fi = - £ I
o 3
5 o Q) J *
z 9 ro
I r UJ
' m 00
w a.
O 0) r*
z o ro I ro w
ENDO
_£NDO " 2 2 , 6 6 5 2 3 , 2 7 5
23-.-Qm
-METHO XY/—
26,020 26,665 27,377 27,959
29,195 29,999 30.465 30.930
24.921
ATTEN: 16 ZERO: 10% 1 MIN/TICK
9.963
-riNDAMET 10.959
13.093
14.512 -FTLDR7^='^f3.92
18,133 18,771-
15,946
17.102
-HETHOXY' /5 -20. 770
o
T3 TITLE: PESTICIDES Q)
w CHANNEL NO: 2 SAMPLE: MIX 100
12:30 13 JUN 88
METHOD: DB608
PEAK PEAK RESULT TIME TIME AREA SEP ,-•. , - ; T. r-
Wl/2
..)
3 -4 5 6 7 8 9 0 1 1 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 10 1
,42 '43 44 45 46 47 48 49 50 51
) TOTALS:
LINDANE B BHC
HEPTACHLO
D-BHC
ALDRIN
ISODRIN
HEPT EPOX
ENDO I DDE DIELDRIN
ENDRIN
ENDO I I DDT ENDRIN AL
ENDO S04
METHOXY
«> DETECTED PKS: a r- DIVISOR: 1 . 00000
!i NOISE:
) RACK: 16
: NOTES: DB608
4. 9
0,y000 0,0000 0.0000 0.0000 0.0000 0.0000 0.0456 0.0077 0,0000 0.1827 0.0000 0.0017 0.0000 0.0006 0.0000 1 . 8719 0.0000 0.0039 0.0000 0.0000 0.0000 0.1021 0.0952 0.0017 0.0000 0.0000 0,0000 0,0000 0,2220 0.0000 0,0783 0, 1753 0,0959 0.0000 0.0088 0.0000 0,0000 0.0000 0.1227 0.0000 0.0000 0.0000 0,0000 0,0000 0.0000 0.0000 0.0000 0.0000 0.0000
3.0161
1 y , 3 1 1 1 1 ,419 1 1 .793 12.671 12.747 13.093 13.309 13.684 14.149 14.512 14.894 15.033 15.220 15.911 16.189 16,630 16.988 17.504 17.721 18.133 18,400 18,771 19,104 19.581 19.894 20.006 20.273 20.527 20.832 21.237 21.462 21.838 22.215 22,665 22,830 23.275 23.883 24,197 24,821 26.020 26.346 26.665 26.809 27.377 27.640 29,185 29.999 30.465 30.830
64 REJECTED PKS
-0. -0.
- 0 ,
0,
0,
-0,
0
0 -0 -0
-0
0 -0 -0
0
-0
-0
M U L T I P L I E R : 1.00000
OFFSET: 14
191 066
088
053
21 1
170
004
071 196 069
018
,042 , 192 , 165
. 030
, 179
.923
13
2597 426^'
197541 6932 3085
178735 76225 5136
132565 - 172392
3590 2595
173431 853
3519 3828
139470 5786 992
128572 . 2562 ^ 133267
134797 2250 1378 1065
/ 88352 1 103777 109105
4061 92796
,^88109 ^ 97051
4826 7400 7030 17932
384102 41084 13059 4133 3135 3320 1451 1231 631 500 1396 2386
2596520
BB BV VV VV VV VV VV VV VV VV VV VV VV VV
vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv BV
vv vv VB
7 7 7 7 7
7
7 7 7 7 7 ?
7 7 ?
7 ? 7 7
?
7
? 7
? ?
7
?
7 7
6.95 1 .90 2.95 14.60
7^l^7^=Dfm^ A 0 5 t,.**/** ^ ^
5:l0'A/^^^.<?^9 1.00
V.iU^-o.^^'] 10.40 4.40 5.90 7.00 7.00 3.65
2'»- 15 ^ ^ 5.25--P5e. aaa 6.00p;ela../^'P.'?'?f
26.65 12.60 2-80 / ,-YiCi
5.55 5.80
5. 55-PPT ''Q.'Ttj 6.30 5.95
25.90 14. 10 28.70 28. 10 7.00 9.20
55.70 6.40 8.40
6.95 6.25
19. 10 10.40 29.60 45.70
V I A L : 11 INJ: 1
PRIMARY COLUMN
T I T L E : P E S T I C I D E CONFIRMATORY
CHANNEL NO: 1 SAMPLE: SAME
12:30 13 JUN 88
METHOD: DBS
2 NOTES:. 0 - DB603 ro I
ro bJ s4
Pr.IMARY COLUMN
SL. T I T L E : PESTICIDE CONFIRMATORY
CHANNEL NO: 1 SAMPLE: SAME
OJ
7> n
PEAK NO
1 2 3 4 5 6 7 9 9 10 1 1 12 13 14 15 16 17 19 19 20 21 22 23 24 25 26 27 29 29 30 31 32
PEAK NAME
LINDANE
HEPTACHLO
ALDRIN HEPT EPOX ENDO I DDE
ENDO I I END ALD
ENDO S04
METHOXY'
0 TOTALS:
1 DETECTED PKS:
^ DIVISOR: 1 .00000 0
RESULT UG/ML 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0123 .0.0000 0.0000 0.4093 0.0000 0.0000 0.0190 0.3728 0.6757 0.0200 0.0000 0.1174 0.5336 0.0000 0.4803 0.0000 0.0000 0.0000 0.0000 0.0535 0.0000 0,0000 0.0000 0.0000 0.0000 0.0000
2.6929
TIME CMIN) 7.595
717 965 495 745 963 959 489 201 494 093 404 921 839 946 833 102 922 232 784 013
7 7 8 8 9 10 1 1 12 12 13 13 13 14 15 16 17 17 19 19 19 19.669 19.891 20. 20. 20. 21 , 21 , 21 , 22. 22, 23.
015 413 770 147 392 896 537 749 271
35 REJECTED PKS;
12:30 13 JUN 88
METHOD: DBS
r i M E DFFSET
-0.061
-0,216
0. 121 -0.121 -0.134 -0.017
0.092 -0.048
0.013
0.010
-0.361
AREA COUNTS
5092 3694 5462 2036 10022 4363 6499
204533 92739 195573 179597 2225 9051
169437 173266
7421 154507 10974
144223 140411 145560 121004 123122 117900 104727 / 5352
,/74212 ^ 1533
1963 42623
267322 531
2615750
SEP CODE BV VV VV VV VV VB BB BB BV VB BV VV VB BB BB BV VB BV VV VV VB BV VV VV VV VV VV VB BB BV VB BB
? ? ? ?
?
?
? ?
?
? ? ?
?
Wl/ CSE 6. 5. 10. 6. 6. 7. 5. 6. S. 6. 6. 12. 5. 6. 6. 6. 6. 6. 6. 6. 6. 6. 6. 7. 6. 8. 7. 5. 6. 3. 6. 3.
NOISE: 30.4
MULTIPLIER: 1.00000
OFFSET: -12
RACK: 16 VIAL: 11 INJ: 1
C) 20 90 90 30 75 90
2Q-%7c.txXa.^^ 60 10 05 60 65 75 90 00 80 15 80 65 95 55 80 35 60 90 85 10 50 95 75 85
NOTES: J DBS CONFIRMATORY COLUMN
CHART ATTEN;
SPEED 9
0.6 CM/MIN ZERO: 10% 1 MIN/TICK ATTEN: 16 ZERO: 10%
f 1 MIN/TICK
CHART SPEED ATTEN: 9
0.6 CM/MIN ZERO: 10% 1 MIN/TICK ATTEN: 16 ZERO: 10% 1 MIN/TICK
'INJECT
1 . 496 2.091
~ H R : 0
23.426
;5j],?2
3 u 3. 0
26.407 26.922 27.477
29,172 29.645 30.199 30.812
~ENDO S04
-METHOXY" 20.104
637
22.917
3
TITLE: PESTICIDES
CHANNEL NO: 2 SAMPLE: TOX IPPM
PEAK PEAK NO NAME
1
RESULT UG/ML 0.0000
TIME CMIN) 6. 024
20:02 13 JUN 89
METHOD: DB608
TIME AREA SEP Wl/2 OFFSET COUNTS CODE CSEC)
20: 02 13 JUN 88
CHANNEL N O : 2
PEAK NO
1 2 3 4 5 6 7 8 9 10 1 1 12 13 14 15 16 17 18 19 20 21 22 23 24 25 •^6
.7 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 S3 54 55 56
,' ' 1
PEAK NAME
A BHC
LINDANE B BHC
HEPTACHLO
D-BHC
ALDRIN
ISODRIN HEPT EPOX
ENDO I
DDE DIELDRIN
ENDRIN DDD ENDO I I
DDT ENDRIN AL
ENDO S04
METHOXY
HBB SURR
TOTALS:
SAMPLE:
RESULT UG/ML 0.0000 0.0000 0,0005 0.0000 0,0022 0.0025 0.0000 0.0054 0.0000 0.0045 0.0000 0,0016 0.0000 0.0000 1.3281 0.0027 0.0000 0.0000 0.0000 0.0000 0.0068 0,0000 0,0173 0,0176 0,0000 0.0000 0,0000 0,0280 0.0375 0.0353 0.0000 0 . 0000 0.0704 0.0539 0,0000 0.0442 0.0000 0. 0000 0.0000 0.0000 0.0000 0 . 0000 0,0000 0.0000 0,0387 0.0000 0.0000 7.7506 0,0000 0 . 0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0,0000
9.4478
TOX IPPM
TIME CMIN) 6, 024 1 1 ,425 1 1 ,649 12,819 1 2,949 13,193 13,609 14,045 14.242 14,376 15,004 15,222 15.358 15,981 16.455 16.840 17.194 17.431 17.668 17.907 18.298 18.533 18.793 19,358 19.572 19.809 20.101 20,191 20,440 20,727 20.957 21.208 21.393 21.732 21.918 22,069 22.350 22.496 22.628 22.790 23.227 23.427 23.806 23.951 24.104 24.338 24.539 24.904 25,102 25.379 25.541 25.902 26.407 26.922 27.088 27.477 30.812
MET
TIME OFFSET
-0,
-0. - 0 .
- 0 ,
-0,
0,
0, -0.
0
0 0
-0 -0 -0
-0 -0
-0
-0
-0
-0
131
131 107
095
134
012
055 140
188
043 278
059 070 083
047 088
121
. 066
.096
.792
HOD: DB608
AREA COUNTS
572 1706 1005 1694 3754 1689 3642 5139 2459 6963 2725 2445 2173 5269 2716 4073 1814 8614 6962 4449 8824 7534
24470 2)3490 1^0732 J7360 1 1783t/, . 1 3 7 6 7 ^ 38844/
]A- plt 1840V/
^ 6927 24213 353691/ 54576 6201
37244 14579 10023 17280 22836 61 154 48092 10074 1688
12969 1 1997 24642 3856 9469 7479 5265 4289 2567 1029 1312 3369 758
717764
SEP CODE BB BV VV BV VV VV VV VV VV VV VV VV VV VV VV VV
vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv VB BV vv vv VB VB
7 ? ?
7 7 7 ? 7
?
?
7
7
? 7 7 7 ? ? ? ? ? 7
? ? ? ? 7 ?
? 7 ?
?
? ?
? ? ? ?
Wl/2 CSEC) 5.65 13.80 9.50 1 1 .30 6.05 6.80 14,30 12,30 10.30 7.20 5.60 6. 15 6. 00 6.50 14.50 7.40 15.60 7.25 7.75 12.05 8.50 6.80 14.20 13. 10 1 1 .30 9.60 1 1 . 00 4.20 15.00 6.25 6.60 14.80 12. 10 13.60 1 .90
13.50 8.20 5.60 8. 70
10. 60 10.65 7. 60 7.60 1 . 10 5. 15 1 1 .60 9.10 8.20 9.65 8.50 7.90 12.20 13.40 14.00 7.90 1 1 .85 17.60
A ^ ' ?/t5 /^J/.^^>
DETECTED PKS: 71 REJECTED PKS: 14
DIVISOR: 1.00000 MULTIPLIER: 1.00000
>.ir> T r r : « rrr-or T '
».;.tOTALSi 9.4478 -0,792 717764
o
DETECTED PKS: 71 REJECTED PKS: 14
•Drvl"s6R:~lV00000 "" MULtiPLTER:"!. 00000
J. .SE:
RACK: 16
4.9 OFFSET:
VIAL: 12
8
INJ: 1
NOTES: DB608 PRIMARY COLUMN
TITLE : PESTICIDE
CHANNEL N O : 1
PEAK NO
1 2 3 4 5 6
r) 7 •) 3
: 9 ] 10
I '7 13
: 14 ' 15 I 16
17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 ^8
1
-.0
PEAK NAME
HEPTACHLO
ENDO I DIELDRIN DDE
ENDRIN ENDO I I
DDD END ALD
ENDO S04 DDT
METHOXY"
TOTALS:
CONFIRMA"
SAMPLE:
RESULT UG/ML 0.0000 0.0000 0.0000 0,0077 0.0000 0.0319 0.0319 0.0204 0.0000 0.0000 0.0416 0.0352 0.0000 0.0391 0.0657 0.0000 0,1463 0.3726 0.0000 0.0000 0.0000 0.0000 0.0000 0,0000 0.5106 0,0000 0.0000 0,0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0,0000 0.0000 0.0000 0.0000 0,0000 0.0000
1.3030
TORY
SAME
TIME CMIN) 7.463 1 1 .337 12,336 12.934 15.527 16,258 16,711 16.888 17.161 17,300 17,376 17,619 17,942 18.050 18,257 18.510 18.691 19,197 19,468 19,869 20,104 20,257 20,349 20.637 20,801 21 . 143 21,365 21.560 21 ,748 22.142 22,315 22.505 22,917 23,175 23,456 23,715 23.896 24.141 24.558 24.669
201
METHOD
TIME OFFSET
0,
0. -0. 0.
-0, - 0 ,
0, -0
-0 0
0
0
224
178 059 038
124 1 1 1
090 023
309 107
04 1
.052
02 13
: DBS
AREA COUNTS
3260 2588 4806 3513 6275 8181 1 1804 7571 8462 10166 1 1875 3258 19422 1 1843 17766 13807 44321 63149 65200 87704 72522 31638 31928 43030 51061 80697 82701 35485 53725 125882 63997 74420 80473 61276 19621 49935 16151 58394 15757 7951
1461520
JUN 99
SEP CODE BB BB BB BB BB BV VV VV VV VV VV VV VV VV VV VV VV VV VV VV vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv VB
? 7
7
7 7 7 ? ? 7 ? 7 7 ? ? ? 7
7 ? ? ? 7 ? 7 ? ? ? 7 ? 7 ? ? ? ? ? ? ? ?
Wl/2 CSEC) 4.90 5.90 4.50 4.50 6.50 1 1 .80 7.80 8.75 12.20 7.30
8. 10 6.90 10.90 10. 90 6.45 16.30 12. 10 26. 80 10.20 5.40 1 .20
19.20 9.35
22.90 11.10 5.30 10. 70 29. 10 8.30 9.70
27.90 12.30 7.60 16.30 4.45 14.70 6.70
DETECTED PKS: 42 REJECTED PKS: 2
DIVISOR: 1.00000' MULTIPLIER: 1,00000
==l 5 , 5 9 6 " 3 R : 0 F F "
7 . 3 2 4
1 9 . 8 0 3 DBHC
8 . 3 6 5 9 . 0 2 2
1 0 . 3 0 9
=l \ 1 1 . 5 7 3 1 2 . 0 1 1 . i i u h UAi
INDf
"TTEFTjACHLO 1 3 . 9 3 9
nffbiRTN 1 4 . 9 9 5
^ 1 2 . 9 7 3 -
j j o c i f
ISOr&Ri-N
1 7 . 2 9 4 1 7 . 7 7 3 1 9 . 4 0 1
n y l ^ L D R I N 1 9 . 0 2 8 1 9 . 4 0 2
"THB^^H _ERBto I I 2 0 . 5 3 4
=• 1 6 . 3 9 3
1 3 . 1 5 4
1 5 . 6 9 8
^Ari,^
\ ) \ } - \
_ £ ^ K 1 N AL 21 . 5 8 8 2 2 . 1 6 5
- ^
2 2 . 7 0 0 2 3 . 1 5 1 2 3 . 5 5 0 2 4 . 0 5 1 . .
3 0 . 0 3 0 3 0 . 5 0 5
2 4 . 4 9 1 SURR 2 4 . 9 8 7 2 5 . 0 8 4
2 6 . 9 9 7
2 0 . 0 2 2 '
2 1 . 2 1 3 "
i T I T L E : P E S T I C I D E S
. CHANNEL N O : 2 SAMPLE: QC 1 - 3 8 - 1
AaX C'. =M A^^-tAf^A
PEAK NO
1 2 3 4 3 6 7 8 9
10 1 1 12 13
PEAK NAME
A BHC
HEPTACHLO L L D R I N
' I S M f H t r n ^ E P O X
ENDO I
RESULT UG/ML 0.0000
0000 0008 0000 / 1810^-0000 0 0 4 a - ^
- .•<d<S2.\'JJ p 2 , 369.0V' Vj2L^0i2rt2
0 . 0 0 0 0 0 . 0 0 0 0 0 . 0 0 1 3
METHOD: DB608
TIME OFFSET
-0.207
-0.207
0. 156 -0.225 -0.007 0.314
0. 291
AREA COUNTS
639 754 1569 695
302673 3210 4549 3168
229793 1730 628
3723 1725
SEP CODE BV VB BB BV VV VV VV VB BV VV VV VV VV
Wl/2 CSEC) 5.90 7 12 7 4
36 5 5 6 12 9 14 15
45 40 95 80 50 90 ,50 00 ,50 ,50 00 ,00
K7^
w V
3
XI
. 7 ••• 8
9 l e 11 12 1 3
4 . 5 16 17 19 19 20 21 22 23 24 25 26 27 29 29 30 31 32 33 34 35
HEPTACHLO ftLDRIN ffsODSiJl] ReFTEPOX
ENDO I DDE -DIELDRIN
1EN_DRJ5J
•D5TA-ENDRIN AL ENDO S 0 4
METHOXY
HBB SURR
0. ©.
112. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0, 0, 0, 0, 0, 0. 0, 0. 0. 0. 0. 0, 0, 1 , 0. 0
0048 , 0021 / 3690'' 0012 0000 0000 00 13 0039 0005 0000 0000 0000 0259 0050 0000 0340 0021 , 0039 , 0000 . 0000 , 0000 , 0000 , 0000 , 0000 ,0029 , 0000 ,4492 , 0000 . 0000
14. 14. 16. 17. 17. 17. 18. 18. 19. 19. 19. 20. 20, 20, 21 . 21 . 21 . 22, 22, 22, 23, 23, 23, 23, 23, 24. 25, 30, 30.
296 985 393 294 450 773
547 028 402 6 8 7 / 022 ol*^ 299 534 2 13 0. Vi 588»-^ 9 S 3 \ 165 700 809 151 231 439 550 891 491 084 505 814
0 -0 -0 0
om'!^l
lbt) 225 007 314
291 203 052
i'/it'rii
0. 0,
049 024
3pr
.
0, 148 0, 133
-0,025
•0,279
0,084
3168 229793 •
1730 629
3723 1725 5572 617
2467 1604
lAZiEZSL. 12720>
161258 . 17107-2144 3260 2273 829
1566 828 867 670 939
31429 721 568
1705
V V
VB BV VV VV VV VV VV VV VV VV VV vv vv vv vv vv vv vv vv vv vv vv vv vv vv VB vv VB
5,50 6,00
12,50 9.50
14. 00 15.00 7.95 7.00
14.20 14.10 6.10-9.00
12.30 5. 75-6.70 8.50
13.75 24,50
5.00
2.40 16.90 8.25 7.55
34. 30 42.80 22.20
.l>1 J | ( ^
'0
7']7i»
TOTALS: 114,0870 -0.006 953019
DETECTED PKS: 47 REJECTED PKS: 12
D I V I S O R : 1.00000 MULTIPLIER: 1.00000
£''" . 7
NOISE: 4.9 OFFSET: 10
k .K: 16 VIAL; INJ: 1
NOTES: DB608 PRIMARY COLUMN
TITLE : PESTICIDE
CHANNEL NO: 1
PEAK NO
1 2 3 4 5 6 7 8 9 3 1
12 13 14 15 16 17 16
PEAK NAME
DBHC
HEPTACHLO
DIELDRIN END ALD DDT
METHOXY"
CONFIRMA
SAMPLE:
RESULT UG/ML 0,0000 0,0000 0.0000 0.0000 0.0039 0.0000 0,0081 0,0000 0.0000 0,6162 0,0201 1,0930 0.0000 0.0000 1.8210 0.0000 0.0000 0.0000
TORY
SAME
TIME CMIN) 7,386 7,441 8,365 9,022 10,308 12,250 12,874 13,154 15,698 16,577 19.541 19,416 19,780 20,166 20,917 22.277 23.192 23.381
0:
METHOD
TIME OFFSET
-0,102
0, 164
-0,193 0, 261 0,326
0, 157
13 14
: DBS
AREA COUNTS
3092 1719 2299 1996 2151
269221 3695 4270 9236
228220 5442
185246 13450 25686 182097 51316 1320 595
JUN 89
SEP CODE BV VB BB BB BB BV VV VB BB BB BB BV VV VB BB BB BV VB
7 7 7
?
7 7
? ?
Wl/2 CSEC) 4.80
5,20 5.50 4.40 6,30 4.60 8.50 5.75 7.30 6.05 7.05 7.65 7. 40 7.00 6.30 2.60 2.60
34 35 .
TOTALS:
0.0000 0.0000
114.0670
30.505 30.814
-0.006
Stob 1705
953019
r TCTED PKS: 47 REJECTED PKS: 12
DIVISOR: 1,00000 M U L T I P L I E R : 1,00000
NOISE: 4.9 OFFSET: 10
V V r -ic:. oo VB ? 22.20
- " : - t b-
RACK:
NOTES
16 VIAL
:
: 4
DB606 PRIMARY COLUMN
7) n
0 Tl
z p 00 (fi 5= TITLE : PESTICIDE
3 CHANNEL NO: 1
"TJ PEAK > NO
u 2 ^ 2 f ' ' 6 w 7 S s " 9 g 10 & 1 1
12 0 13 ^ 14 z 15 0 16 NJ 17 ro 18 CO
PEAK NAME
DBHC
HEPTACHLO
DIELDRIN END ALD DDT
METHOXY"
Ii TOTALS:
0
^ DETECTED PKS:
Q DIVISOR: 1,00000
g_ NOISE CA
RACK:
INJ: 1
CONFIRMATORY
SAMPLE:
RESULT UG/ML 0,0000 0.0000 0.0000 0.0000 0.0039 0.0000 0.0061 0.0000 0,0000 0.6162 0.0201 1.0930 0,0000 0,0000 1.8210 0,0000 0.0000 0.0000
3.5623
SAME
TIME CMIN) 7,386 7. 441 8.365 9.022 10.308 12,250 12,874 13,154 15,698 16,577 18,541 19,416 19.780 20.166 20.917 22.277 23.192 23.381
21 REJECTED PKS:
0:
METHOD
TIME OFFSET
-0.
0.
-0 0 0
0
0
MULTIPLIER: 1,00000
:: 34,0 O F F S E T :
16 V I A L : 4
NOTES:
25
INJ: 1
DBS CONFIRMATORY COLUMN CD
rv) CD
102
164
193 261 326
157
613
3
13 14
: DBS
AREA COUNTS
3092 1719 2298 1996 2151
266221 3665 4270 8236
226220 5442
185246 13450 25686 162097 51316 1320 595
969042
JUN 68
SEP CODE BV VB BB BB BB BV VV VB BB BB BB BV VV VB BB BB BV VB
7 7 7
7
7 7
7 7
Wl/2 CSEC) 4.80
5.20 5.50 4.40 6.30 4.60 6.50 5.75 7.30 6.05 7.05 7.65 7,40 7.00 6.30 2.60 2.60
CHART ATTEN;
SPEED 8
0.6 CM/MIN ZERO: 10% 1 MIN/TICK ATTEN:
] 16 ZERO: 10% 1 MIN/TICK
4e-i
SR: C>FF
L I N £ A . ^ & -1 0 . 6 3 a .
1 1 . 163 1 1 . 8 7 1 1 2 . 7 5 8
1 4 , 1 6 9 ' 1 4 , 8 5 3
1 7 , 6 8 7 = 1 8 , 3 2 7
2 0 , 9 4 2
- 2 2 . 0 9 5 2 2 . 7 1 1
- ? 3 . 1??
1 9 , 4 9 4 2 0 , 0 1 7
-HfrB SURR 2 4 , 5 5 5 2 4 , 0 8 8
r d 2 6 . 3 5 1 2 6 , 7 7 9
2 7 , 7 2 5
3 0 , 4 9 4
^ i/iWn M ^ <Ai Mu<^
TITLE
::HANh
= EAK HO
1 2 3 4 5 6 7 8 9 10
: PESTICIDES
EL NO: 2
PEAK NAME
A BHC
LINDANE B BHC HEPTACHLO
ALDRIN
SAMPLE
RESULT UG/ML 0,0000 0,0000 0.0838 0.0000 0.0000 0.0931 0.1138 0.1118 0.0000 0.1060
O. /
o'<^
O ^
O^
TIME CMIN) 8.880 10.078 11.520 12.367 12,414 12.787 13.004 13.616 14.169 14.653
9:
METHOD
TIME OFFSET
0.010
-0.003 -0.006 -0.024
-0.037
37 16
: DB608
AREA COUNTS
619 3071
166580 4570 2574
155650 75586 105477 163475 160392
JUN 88
SEP CODE BB BB BV
Wl/2 CSEC) 4.95 6.45 5.00
VV ? 10.50 VV ? VV VV VV VV VV
5.00 • 5.00 5.85 4.90 5.85
CHANNEL' NO: 2 SAMPLE: HEXA -Hr:- M E T H 0 D : D B 6 O 8
PEAK NO
1 2 ~
5 6 7 8 9 10 1 1 12 13 14 15 16 17 18 19
• 20 21 •22 23 24 25 26 27 28 29 30 "T 1
32 33 1
J
36 37 38 39
!^EAK NAME
A BHC
LINDANE B BHC HEPTACHLO
ALDRIN ISODRIN HEPT EPOX
ENDO I DDE DIELDRIN — ^
ENDRIN DDD ENDO I I DDT ENDRIN AL ENDO S04
METHOXY
TOTALS:
RESULT UG/ML
. 0,0000 0,0000 0,0838 0,0000 0,0000 0, 093 1 0'^ 0,- 1 138 0 , 1 1 1 8 o> 0,0000 0, 1060 C- 1 ,5203 0.0883 0.0000 0.0000 0.0000 0,0970
A- 0,0883 — 0,0008 0,0000 0,1174^^ 0,0932 0,0991 0, 0993O\^ 0,0853 0,1185 0,0000 0,0000 0,0000 0,0000 0,0000 rt. f^ r* c\ A\
1.0131 0.0000 0.0000 0,0000 0.0000 0.0000 0.0000 0.0000
3.9291
TIME C M I N ) 8,880 10,078 11.520 12,367 12,414 12.787 13.004 13.816 14.169 14.853 16.221 16.577 17.082 17,308 17,687 18,327 18,633 19,088 19,387 19,759 20,030 20,308 20,942 21,293 21,663 22,095 22,292 22,711 22,914 22,982 C O . I £ . C
23,565 24,088 26,351 26,519 26,779 27,725 30,494 30,631
T IME OFFSET
0,010
-0.003 -0.006 -0.024
-0.037 -0.179 -0.073
0.217 -0.117 — 0. 008
-0.121 -0.120 -0.132 -0.138 -0,147 -0,157
-0,185
-1,204
AREA COUNTS
619 3071
166580 4570 2574
155650 75586 105477 163475 160392
3109 131751
4 129 1474
124612 126692 125 139
1025 2287
76213 96504 1 17364
• 74625 86366 99721 3059 5292 5567 1601 1923 3213
339284 34531 2298 827 536
2255 2293 1654
2313340
SEF CODE BB BB BV VV VV VV VV VV VV VV BV VV VV VV VV VV vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv BV vv vv VB BV VB
7 7
'>
7
7 7 7 7 7
-> 7 7 7 7 7
Wl /2 CSEC) 4,95 6,45 5,00 10.50
5.00 5. 00 5,85 4,90 5,85 5,75 5,85 5,65 5,35 5,90 5,55 5,95 4,20 8,45 5,90 5,60 6, 00 5,50 6,30 5,95 9, 10 6,75 15,30 1 ,80
3, 90 7, 10
27, 10 25, 60 32,70 40,60 43, 80 47, 10
)ETECTED PKS: 52 REJECTED PKS: 13
)IVISOR: 1,00000 MULTIPLIER: 1,00000
-IOISE: 6.1 OFFSET: 16
?ACK: 16 VIAL: 4 INJ: 1
JOTES: DB608 PRIMARY COLUMN
-E: PESTICIDE CONFIRMATORY
HANNEL NO: 1 SAMPLE: SAME
9:37 16 JUN 88
METHOD: DBS
EAK NO
1 2 3 ^
PEAK NAME
RESULT UG/ML 0,0000 0.0000 0.0000
TIME CMIN) 7.326 8,450 10.639
TIME OFFSET
^ • / I z • . -
AREA COUNTS
2966 4025 7164
: • , - , • - —
SEP CODE BB BB BB
Wl/2 CSEC) 4.90 5.35 5.85
34 35 36 37 38
TOTALS
0.0000 0.0000 C.0000 0.0000 0.0000 0.0000 0,0000
3,9291
2'-'. 26 26 26 27 30 30
t'88 351 519 779 725 494 631
-1.204
34531 2298 827 536
2255 2293 1654
2313340
VV BV VV VV VB BV VB
7 '> '> 7 ? 7
7, 27, 25 32 40 43 47
10 10 60 70 60 80 10
DETECTED PKS: 52 REJECTED PKS: 13
DIVISOR: 1,00000 MULTIPLIER: 1,00000
NOISE: 6,1 OFFSET: 16
RACK: 16 VIAL: 4 INJ: 1
NOTES: DB608 PRIMARY COLUMN
fl
:TITLE: PESTICIDE CONFIRMATORY 9: 37 16 JUN 88 J • CHANNEL N O : 1
' PFAK V
5 1 3 2
3 4 5 6 7
I 8 9
, 10 1 1 12 13
. M
. 15 » 16 ; 17
18 19
- 20 21
> 22 23 24 25
> 26 1 27
PEAK NAME
LINDANE
HEPTACHLO ALDRIN ISODRIN
DIELDRIN ENDRIN DDD END ALD
DDT
METHOXY"
! TOTALS:
SAMPLE:
RESULT UG/ML 0,0000 0,0000 0,0000 0,4007 0,0000 0,0000 0,4256 0,01 15
276,6040 0.0000 0,0000 0,4516 0,0371 0,5265 0, 5699 0,0000 0.8040 0 , 0000 0,0000 0 . 0000 0 , 0000 2,1524 0,0000 0.0000 0,0000 0.0000 0.0000
261.9830
SAME
TIME CMIN) 7,326 8,450 10,639 11,163 11,871 12,159 12,758 13,572 14,486 15,582 16,459 16,731 17,443 17,850 18,418 18,627 19,275 19,494 19,642 20,017 20,397 20,755 20,939 21,472 22, 1 15 22,357 22.737
METHOD
TIME OFFSET
0. 143
0, 048 -0,228 -0,174
-0,039 -0.057 -0.110 0, 138
0, 185
-0,005
-0,099
: DBS
AREA COUNTS
2966 4025 7184
210895 100057 198639 193469
5490 177310 184042
6408 167272 1061 1
159546 154026 163098 136266 141983 141655 132074 10376
215237 5435 3700
55188 322371
1754
2911060
SEP CODE BB BB BB BV VV VV VB BB BB BB BV VB BV VV VV VB BV VV VV VV VV VV VB BB BV VV VB
Wl/2 CSEC) 4, 90 5,35 5,85 6,50 5,90 6,40 6,30 5,80 6,80 6,90 5.05 6.85 5.75 7. 05 6,80 7, 00 6. 65
? 6.30 ? 7,20
6,95 ? 7.80 ? 5,80 ?
6.40 6. 15 7.10
?
L^iECTED PKS: 30 REJECTED PKS: 3
iDIVISOR: 1.00000 MULTIPLIER: 1,00000
^^OISE: 38.6 OFFSET: 21
K: 16 VIAL: 4 INJ: 1
- r c
:.HART SPEED 0,6 CM/MIN ^TTEN: e ZERO: 10? i MIN/TICK
s r ^ j — : INJECT
~SR: OFT?
11,172 -A BHC
"TINDANE -12. 593
HEPTACHLO
ISOD
T N D O J-_ 1-8, 42Z
-&NDO I I ^—^
-€-NDRIN~AL
-METHOXY -HBB SURR
-ALDRIN 14,074
-DIELDRttt 1 7 , 4 17
= ^ 1 8 , 0 4 8 '
I SODRThf 1-4, 5 ^ Z
:NDO I
124
0 1 9
1 5 , 8 7 1
-UDT
2 4 , 7 0 1 .
T J A J M ^ ^ S^'^
927
ITLE: PESTICIDES
HANNEL NO: 2 SAMPLE: MIX XI
EAK PEAK NO NAME
1
RESULT UG/ML 0.0000
TIME CMIN) 6.083
18:14 13 JUN^BB
METHOD: DB608
TIME AREA SEP Wl/2 OFFSET COUNTS CODE CSEC)
548 BB 5.30
UHMi-Jf'j£u -NO: 2
PEAK NO
1 ? 3
> • ;
] 5 ^ 6
7 8 9 10 1 1 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33
7) ' n 5 : 36 S 37 - 38
I 29 40
: 41 •> 42 0 43 > 44 r 45 r 46 I 47
48 3 49
PEAK NAME
A BHC
L INDANE B BHC HEPTACHLO D-BHC
ALDRIN
ISODRIN
HEPT EPOX
ENDO I
DDE DIELDRIN
ENDRIN DDD ENDO I I DDT ENDRIN AL ENDO S04
METHOXY HBB SURR
^TOTALS:
SAMPLE:
RESULT UG/ML .0 . 0000 0 . 0000 0 . 0000 0,0000 0,0000 0,0000 0,0000 0,0000 0,7680 0,0000 0,0000 0,8487 1,1706 1 .2835-0, 9096. 0,0000 0,0000 0,9448 0.0000 0,0000 0,7888 0,0000 0,8093 0,0000 0.0000 0,8909 0.0000 0,8131 0,9192 0,0000 0,0000 1,6892 0,9126 0,9103 1,7106 0,8713 1,2987 0,0000 0.0000 0,0000 0,0000 0,0000 0,0000 0,0000 0,0000 0,0000 6,7012
702,9490 0,0000
727,1890
f'l I X ;< 1
T I M E C M I N ) 6,083 7. 173 7. 465 8. 300 9.026 9.202 9.885 10.249 11.723 12.593 12.674 13.019 13.238 14.0;?4 14.438 14.813 14,954 15,143 15.855 16,078 16,285 16,546 16,911 17,417 17,636 18,048 18,427 18.686 19.018 19.508 19.779 20.182 20.435 20.738 21.368 21.745 22.121 22.548 22.729 22.944 23.003 23,169 23,408 23,488 23,780 23,854 24.091 24.701 29,727
METHOE
TIME OFFSET
-0,057
-0,06 1 -0,062 -0,066 -0,072
-0,067
-0, 1 IS
-0,069
-0,062
-0,064 -0,062
-0,068 -0,075 -0.072 -0.072 -0.075 -0.069
-0.079 -0.299
-1,566
: DB608
AREA COUNTS
548 1 055 2863 776
6656 1059 1720
22694 1526910
12864 10738
1419200 777806 1210840 1397230
17973 12700
1429310 4758 7574 1613
33567 •1207970
51771 10878
1163040 5456
1151710 1228850
12556 9514
830066 944679 1078590
SEP CODE BB D W
VB BB BV VV BV VB BV VV VV VV VV VV VV VV VV VV VV VV VV vv vv vv vv vv vv vv vv vv vv vv vv vv
859592'•^ VV 881864 1093170
18638 36761 6043 5973
25179 1 1436 7307
35801 5459
2244210 349726
935
21177600
vv vv vv vv vv vv vv vv vv vv vv vv VB BV
7
7 7
7 7 7 7
7
7 7
7
7
7 7 7 7 7 7 7 7
7
Wl /2 CSEC) 5,30 5,40 5.05 5,80 5,35 15,90 5,95 7,45 6, 65 8, 50 8,70 6,55 4, 95 6,75 6,20 5.60 6.60 4,75
6.75
6.55 6.95 6.40 6. 95 7, 05 1 ,'70 4. 15 7,20 1 1 ,25 7,50 6,50 6,35 6.80 6.40 6.45 6.20
13, 10 8.50 3.00 1 .40
I 1.60 9.90 5, 10 14,50 1 .80 6. 15 7.50 13.65
TDETECTED PKS:
jDIVISOR: 1,00000
75 REJECTED PKS: 26
MULTIPLIER: 1,00000
aNOISE
•RACK: 16
• NOTES:
4,9 O F F S E T : 15
VIAL: 9 INJ: 1
DB608 PRIMARY COLUMN
5 6 H BHC 7 DBHC 8 LINDANE 9 1
J
1 2 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40
HEPTACHLO
ALDRIN
ISODRIN ENDO I DIELDRIN DDE ENDO I I END ALD
ENDO DDT
S04
METHOXY"
(7) V)
c, m i~ o p z p SL 2 DETECTED PKS: o S DIVISOR: 1.00000
^TALS;
0. 0. 0. 0. 0. 0, 0, 0, 0, 0, 0, 0, 0. 0, 0,
944, 2, 0, 1 , 0, 2, 0, 1 , 0, 0. 0, 0, 0, 0, 0 0 0 0 0 0 0 0
0000 0000 0256 0093 1 139 0000 0000 0000 0892 0000 , 0000 . 0000 ,0910 . 0000 . 0000 . 6830 ,4815 , 1392 ,5628 , 8894 , 0640 , 0000 ,8809 , 1354 . 0000 , 0000 . 0000 . 0000 , 9488 , 0000 . 0000 . 0000 . 0000 . 0000 . 0000 , 0000 , 0000
955.1130
8, 9 _
10, 10. 1 1 . 12. 12, 12, 1 3, 3, 3, 3 3, 4 4 15 16 17 17 18 18 18 19 19 19 19 20 20 21 21 21 21 22 22 22 23
8 96 60 2 547 890 420 124 419 770 019 379 591 840 928 502 767 971 750 020 737 148 701 927 280 583 803 928 325 679 , 060 , 297 , 792 997 , 056 , 442 , 662 ,171
0. 172 0. 137 -0.130
0. 060
0. 040
0. 107 -0. 209 -0.020 0. 170 0. 007 -0.132
-0.073 0. 190
-0.081
0. 236
91 54 15057 5159
59973 737798 393331 674327 40558
644432 39219 10013 43315 25684 261 1
605566 636290 51549
578828 82262
557825 511157 569974 22947
474813 460819 459170
• 498412 94880
674654 57974 40321 17783 20337
234751 735435 201 13
10171300
VB BB BB . BV VV VV VV VV VV VV VV VV VB BV VB BV VV VV VV VV VV VV VV VV VV vv vv vv vv vv vv vv vv vv vv VB
7
7
? 7 7 7
7 7 7 7
7 7 7 7 ? ? 7
?
7. 5. 4 , 6, 7, 6, 7, 1 1 , 7, 10.
6, 18, 4, 8, 8 6 8 6 8 7 8 4 5 7 6 7 10 6 4 16 7
5 10 10
90 00 20 20 95 15 80 85 50 05
00 60 95 00 IS 30 00 70 05 70 20 50 00 90 30 80 ,80 .30 .90 .40 .30
.45
. 45
.60
49 REJECTED PKS:
MULTIPLIER: 1,00000
JNOISE;
O RACK: 0)
34.0 OFFSET:
16 VIAL:
-42
INJ: 1
2 NOTES: P DBS CONFIRMATORY COLUMN NJ I
ro CO OJ 00
6-O.
o to
z p KJ ro to
CHART SPEED 0.6 CM/MIN ATTEN: 8 Z E R O : 10% l MIN/TICK
~STAT"7INJECT
0. 741
•"S/ 1 .495
A T T E N : 16 Z E R O : 10% 1 MIN/TICK
o TJ 0)
a
2.204
i-.m SR:aBF
6,825
• ' • - . • . • • • • ' ^ ' ^ ' - V ' ' » ^ ' ^ ^ * i ^ t t ^ . ^ ^ - ^
ITLE: PESTICIDES
HANNEL NO: 2 SAMPLE: MIX X5
17:28 13 JUN 88
METHOD: DB608
EAK NO
1 2 3 4 5 6 7 8 9 10 1 1 12 13 14 15 16 17 18 19 20
.' 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46
PEAK NAME
A BHC
LINDANE
HEPTACHLO D-BHC
ALDRIN
ISODRIN HEPT EPOX
ENDO I
DDE DIELDRIN
ENDRIN DDD ENDO I I DDT ENDRIN AL ENDO S04
METHOXY HBB SURR
)TALS:
RESULT UG/ML 0.0000 0,0000 0,0000 0.0000 0,1743 0,0000 0,0000 0.1881 0,0000 0.0000 0,2299 0,1935 0.0000 0,0000 0,2035 0,0000 3.3487 0, 1644 0,0000 0 , 0000 0,1743 0 . 0000 0. 1656 0,1762 0.0000 0 . 0000 0.2988 0.1723 0,1638 0.3042 0.1497 0.2049 0,0000 0.0000 0,0000 0,0000 0.0000 0.0000 0.0000 0.0000 1 ,8873
117,0260 0.0000 0.0000 0.0000 0.0000
125.2260
TIME CMIN) 7, 406 8,975 10,201 1 1 ,299 1 1 .674 12,539 12.618 12.971 13.189 13.722 14.026 14.389 14,764 . 14,907 15,096 15,938 16,502 16,863 17.371 17.591 18.001 18.400 18,637 18,968 19,455 19.735 20.133 20.386 20.690 21.320 21.696 22.072 22,522 22,683 23,134 23,349 23,427 23.518 23.685 23.706 24.036 24,650 26,996 27.701 30,515 30,812
TIME OFFSET
-0,
-0.
-0, -0,
-0,
0. -0,
-0,
-0, -0,
-0, -0, -0 -0 -0 -0
-0 -0
-1
106
109
1 14 121
1 14
102 1 17
109
1 13 1 12
1 17 124 120 120 124 1 18
, 134 , 150
,920
AREA COUNTS
651 1812 4598 2022
346515 10685 5059
314598 --' •136205
2203 216871 297204
5438 4242
307918 4962 6848
245447 9374 1696
227602 1868
234627 235621
2091 871
146828 178348/ 194046 152873-15 1525. .. 172506
2252 8518 10622 2991 1248 3598 2047 2968
632054 58222
630 713
2283 2976
4354260
SEP CODE BB BV BB BV VV VV VV VV VV VV VV VV VV VV VV VV VV vv vv vv vv vv vv vv vv vv vv vv vv vv
. vv vv vv vv vv vv vv vv vv vv vv vv vv VB vv VB
7
7
7
?
?
?
? ? ? '> ? ?
7 7 7 ?
Wl/2 CSEC) 5,20 4.80 7,05 1 1 .50 4.95 14.80 1 .85 4.95 4.70
5.55 4.95 3, 70 6, 90 6, 00
30.80 5.70 5,70 6.05 4,30 6,05 7.55 5,60 6, 00 6,90 5.40 5.85 5.55 5.75 5.40 5.70 5,80 10,60 8,80 13,40 1 ,60
4, 40 5.90
6.85 7.30
20. 10 26.30 59.30 17.20
:TFCTED PKS: 69 REJECTED PKS: 23
V.JOR: 1.00000 MULTIPLIER: 1.00000
USE: .4.9 OFFSET: 14
ICK: 16 VIAL: 9 INJ: 1
TES: •^f^'MX'^-:- i^.rs'. i i - ^ i ^
1CV4 31.0 4326
CHART SPEED 0.6 CM/MIN ATTEN: 8 ZERO: 10% 1 MIN/TICK ATTEN: 16 ZERO: 10% 1 MIN/TICK
CHART SPEED 0.6 CM/MIN ATTEN: 9 ZERO: 10% 1 MIN/TICK
>
-STAT- INJECT
0. 775
"SR: Of
3. 804
5. 500
7,083
8,246
=/ 9,158 9,833
1 1 . 299
"LINDANE
D-BHC.
12,539
ATTEN: 16 ZERO: 10% 1 MIN/TICK
1 4 , 7 6 ^
I se^WT^ 16.5j3t2-1 7 , 3 7 1
"TN&Os^i:
— <- 1 9 . 7 3 5 END
r5TET4 ,QXY J i B B r S t t W ^
2 5 . 1 2 1
' = \ 2 6 . 139
2 7 . 7 0 1
= 12 .971
= "14 , 389
-ENDO I
"UDE
^ 18. 0 0 1 '
I W ^ ° ^ - ^ = i ^ ^ 2 0 . 1 3 3
-WETHOXY" 3 0 . 6 5 7
21 . 696-
2 4 . 0 3 6
2 1 , 2 5 1
2 3 , 1 3 0
2 4 , 6 5 0
1 2 . 0 7 5
1 2 . 9 7 0
1 5 . 8 2 3
1 6 . 9 7 3
1 8 . 9 7 9
2 2 . 3 9 6
5"TMT""T^INJECT
22
""SR:0 ^
7.W 3, 859
L2,654
HEPTAC^ea
- =r X- -X! ^A-
16,333
HEPf ' - ^ 0 X 17,488
;NDO-
_DIELB41^^ 19,601
23.593
_tl£TH0^ --24 , •6 »•5-HBB ^ p R 25, 169
26", 542 26,947
^ 1 27,469
~SR:OFF
INDAt 10.926
W.kll ± rNDO 1
-^lELDRIt^ rl6, 81'
18,113 18. 753-
" 24, 165
^
11,458 12,174
13,071
1-5.927
TITLE: PESTICIDES
NNEL NO: 2 S A M P L E : ,«-H<—Li J»
PEAK NO
1 2 3 4
... 5
PEAK NAME
RESULT UG/ML 0.0000 0.0000 0.0000 0.0000 0.0000
9 10 1 1 1 1
TIME CMIN) 7.796
070 296 1 10 283
1 3 : 2 3 13 JUi
METHOD: DB608
TIME OFFSET
AREA COUNTS
507 957
2169 1759
SEP CODE BV BB BB BV
Wl/2 CSEC) 6. 20 5. 6. 6, Q
60 45 30
%;
f
• 8
10 1 1 12
t
15 1 6 17 18 1 9 20 21
L INDAiJE B BHC
HEPTACHLO
D-BHC
ISODRIN HEPT EPOX
26 ENDO I 27 DDE 28 DIELDRIN 29 30 31 32 33 ENDRIN 34 DDD 35 36 ENDO I I 37 38 DDT 39 40 ENDO S04 41 42 43
y . s 46 47 48 49 50 METHOXY 51 52 HBB SURR 53 54 55 56 57 58 59 60 61 62 .63 64
TOTALS:
0.0000 0,0000 0 . 0-000 0.0443 0,0085 0,0000 0.1735 0,0000 0,0023 0,0000 0,0000 0,0000 0,0000 0.0000
66,1651 0,0051 0,0000 0,0000 0,0000 0, 1037 0.0921 0.0033 0.0000 0.0000 0,0000 0,0000 0,2140 0,0100 0.0000 0.0893 0.0000 0,1889 0,0000 0,0076 0,0000 0,0000 0.0000 0,0000 0,0000 0,0000 0,0000 0,0000 0,0000 0.0041 0,0000 2.3738 0.0000 0.0000 0.0000 0,0000 0.0000 0.0000 0.0000 0,0000 0,0000 0,0000 0.0000 0.0000
69.4656
'•/(
1 c:. o :• 4
12.734 13.082 1 ... 303 O. /'t' 13.669 'f?!"'' 14. 139 I-'..L-1 4 , 506 ),C(/.C 14,879 15,021 15,212 'IM 16,148 16,333 16,403 16,618 16,979 17.488 17.712 18.113 18.392 18.753 19,084 19,60 1 19,865 20,006 20,252 20,506 20.81 1 21,021 21 ,240 21,440 21,819 , 22, 194 112 ^ 22,624 22,809 23,031 23,260 23,288 23,593 23,837 23,907 24,165 m% 24,603 24,786 25,169 25,354 25,424 25,726 25,816 26,020 26,341 26,416 26,542 26,616 26,715 26,947 27,148 27,178 30,008
•0.197 •0,08 1
•0,094
0, 04 1
0, 179 -0,012
0, 053 •0,216 •0 , 049
•0, 039 0,011
0, 020
0, 164
0 , 009
0, 169
-0,066
•0, 108
4 0 14 167152.''. 74028^ 5655
12 89 03'..' 16370 16'
4790 3457
168 122(1') 4934 691 994
4655 135307d)
7685 1835
126869:f> 2538
-•135364& 130442©
4463 1843 1 185
89067© 103957®; 105169©
1038 3273
105841^!/ 85952© 94937® 4552 6426 1744 3946 3822 3879 2630 1207
3754895-3878
32944 1378 947 1181 827 765 1 183 1 122 879 735 728 595 1944 655 1360 504
2527810
X-J V V VV
vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv
-?
7
7 7 7 7
-> 7 7
7 7 7 7
7 '7
7 7 ? 7 7
7 ?
?
7 ? 7 ? 7 7 7 7 7
7 7 ? ?
3,40 5 . 3 0 f- ''•''••
5,2 5 t'':')•/
5,55 C'.4tl 4.70 (•'71 3,60 < -2® 6,00 -'"'^ 1 1 , 90
5,10 5,80 7, 05 7.50 3.55
22.30 5, 40 6,05 14, 20 8,30 4, 40 3,55 5,40 5.80
13.30 5.60 6. 00 5.55 14,60 1 1 ,20 1 ,30
13.30
9. 80 10.60 3.00 6, 70 14,50 7.95 4,40 5,20
8.50 4. 80 13. 30 14,20 5,60 5, 60 3, 10 3,50 6,60 0,70
14,30
ii
DETECTED PKS: 94 REJECTED PKS: 30
DIVISOR: 1,00000 MULTIPLIER: 1,00000
NOISE: 4,9 OFFSET: 13
f K: 16 VIAL: 11 INJ: 1
NOTES: DB606 PRIMARY COLUMN
.ii^A±A^_ Wr,
TITLE: "PESTICIDE CONFIRMATORY 23 13 JUN 88
CHANt-
K INO
1 2 3 4 5 6 7 8 9 10 1 1 12 13 14 15 16 17 18 19 20 21 22 23
EL NO: 1
PEAK NAME
LINDANE
HEPTACHLO
ALDRIN HEPT EPOX ENDO I DDE
ENDO I I END ALD
ENDO S04
METHOXY"
TOTALS:
• SAMPLE:
RESULT UG/ML 0.0091 0.0000 0.0000 0.3881 0.0000 0.0053 0.3580 0.6286 0.0167 0.0000 0.1168 0,5099 0,0000 0,4620 0,0000 0,0000 0,0000 0,0000 0,0000 0,0448 0,0000 0,0000 0.0000
2.5393
SAME
TIME CMIN)
10,926 1 1 ,458 12,174 12,466 13.071 13.900 1 4.822 15.927 16.815 17.084 17.805 18.212 18.765 18.992 19.650 19.870 19.997 20.162 20.393 20.750 21.131 22,517 22,734
METHOD: DBS
TIME OFFSET -0.094
-0.244
0, 100 -0,138 -0.153 -0,035
0, 075 -0,068
-0,008
-0,010
-0,575
AREA COUNTS
4767 191945 88356 176389 163070
2538 162750 161191
6193 143145 10815
137813 136618 140012 116811 1 14730 108850 1 1331
100864 4484
174780 39022
261557
2458030
SEP CODE BB BB BV VV VB BB BB BB BV VB BV VV VV VB BV VV VV VV
. VV VV VB BV VB
Wl/2 CSEC)
? 4, 80 6, 15 5.65 6,20 6, 15 5,30 6, 65 6,75 6, 25 6, 70 5,85 6,70 6,60 6,90 6.35
? 6,60 ? 7.35 ? 10. 10
6.80 ? 4,90 ? 4,95
6,35 6.65
DETECTED PKS: 25 REJECTED PKS:
'ISOR: 1,00000 MULTIPLIER: 1,00000
NOISE: 46,1. OFFSET: -10
RACK: 16 VIAL: 11 INJ: 1
NOTES:
DBS CONFIRMATORY COLUMN
' CHART SPEED •ATTEN: 8
STAT :'RESET
0,6 CM/MIN ZERO: 10% 1 MIN/TICK ATTEN; 16 ZERO: 10% 1 MIN/TICK
r-5TAT~T INJECT
1 , 6 6 2
~ S R : O F F
7, 648
1 1 , 5 4 2
~
HEPT D-BFP
1
7) HEpTi r> — < - ENDe< S D D ^ -> D
5-DDT_
T ft^LO 14,498 ^ 15,204
;=J6,250
.EPOX 17,439 > 1"7A976 ^I lS,406 k 19,150
^=-20,252
j 7 21 ,887 g_E.NDCr-^04 22,700 tl
0 ) 23,630
24,131 I -METHeX'^ 24,822 i HBB 0 >
0
.. Z 3
O
Sj j i 7) » 3" U iTITLE
StWR 25,435 —7 26,146
: PESTICIDES
nCHANNEL N O : 2 01
2 PEAK 0 NO ro 1 r 2 w 3
4 cr 5 S 6 o ^ ° 8 O 9 XJ 1 0 g. 1 1 S, 12
1 T
PEAK NAME
LINDANE HEPTACHLO
ISODRIN HEPT EPOX
ENDO I nnc
..> . o SAMPLE:
RESULT UG/ML 0 , 0000 0.0000 0.0004 0,0071 0.0000 0,0000 0.0000 0.661 1 0.0020 0.0000 0.0000 0.0036
_C«. 001 s
/ />p»^ MIX 100
TIME CMIN)
1 1 .542 13,074 13,295 14,498 15,328 16,250 16,613 16,968 17.439 17.976 18.406 18.757 19.150
1 2 . 4 7 2 1 3 . 0 7 7
1 1 : 5 3 l J _ _ J L U b L ^
M E T H O D : DB608
T IME OFFSET
- 0 . 2 0 5 - 0 . 1 0 2
0 . 168 • 0 , 0 6 1
0 . 0 5 7 - 0 . 150
AREA COUNTS
1339 9540 596
6654 927 1651 6734 1352 2999 5492 4593 4765 2097
SEP CODE BB BV VB BB VB BV VV VV VV VV VV VV VV
? ? ?
7
?
Wl/2 CSEC) 5. 10 3. 10 9,50 5.40 13.80 19.20 6. 15 4.65 16. 15 16.25 14.20 10. 10 16. 10
Hfti.|NEL t-l.Q: 2 "
:AK - 0
1 1
1
5 6 7 8 9 10 1 1 12 13 14 15 < -•r 1 ^
17 18 19 20 21 22 23 24 25 26 27
PEAK NAME
L I NDANE HEPTACHLO
ISODRIN HEPT EPOX
ENDO I DDE DIELDRIN
r ~ k 1 T-s (-1 T y I l _ t 1 !_/ I \ 1 1 1
ENDO I I
DDT ENDO S04
METHOXY HBB SURR
DIALS:
SAMPLE:
RESULT UG/ML 0 •. 0000 0.0000 0.0004 0.0071 0.0000 0.0000 0 . 0000 0.66 1 1 0.0020 0 . 0000 0,0000 0,0036 0,0015 0 , 0040 0.0000 r . r, —t —. -» V , - J C C t
0, 0160 0,0000 0,0100 0.0034 0.0000 0 . 0000 0,0000 0.0134 10.5404 0,0000 0,0000
11,2856
i'l IX 10 0
TIME CMIN)
1 1 ,542 13,074 13,295 14,496 15,328 16,250 16,613 16,968 17,439 17,976 18,406 18.757 19.150 19.524 20.252 — . • - ) . f T --i - >
C '-' . £- w
21.445 21.887 22.138 22.700 23,630 24,007 24,131 24,822 25,435 25,757 26,146
METHOD: DB608
TIME OFFSET
- 0 , 2 0 5 - 0 , 1 0 2
0 . 168 • 0 , 0 6 1
0 , 0 5 7 • 0 , 150 • 0 , 126
0 , 0 2 5
0 , 108 - 0 , 1 0 0
• 0 , 178 • 0 , 0 5 5
- 0 , 9 4 7
AREA COUNTS
1339 9540 596
6654 927 1851 6734 1352 2999 5492 4593 4765 2097 5363 10005 1 1 155 18915 5503 5045 2820 16485 2726
• 3097 4497 5244 1449 923
142166
SEP CODE BB BV VB BB VB BV VV VV VV VV VV VV VV VV VV VV vv vv vv vv vv vv vv vv vv vv vv
? ? ?
7
7 7 7 ?
? 7 7 7 7 7 7 7
Wl/2 CSEC) 5, 10 3, 10 9,50 5,40 13,80 19,20 6. 15 4,85 18, 15 18,25 14,20 10,10 16,10 24.20 29, 90 16, 60 23.60 1 1 . 70 9,90
29, 30 57,70 1 .45
37.60 47, 10 9, 60 14,90
:T£CTED P K S : 32 REJECTED PKS: 5
I JOR: 1,00000 MULTIPLIER: 1,00000'
)ISE: 4,9 O F F S E T : 12
^CK: 16 VIAL: 11 INJ: 1
)TES: DB608 PRIMARY COLUMN
TLE: PESTICIDE CONFIRMATORY 1 1 : S3
lANNEL NO: 1 SAMPLE: SAME
AK PEAK 0 NAME 1 HEPTACHLO 2 3 DIELDRIN 4 ENDO S04 5 --
METHOXY"
iTALS:
RESULT UG/ML 0,0591 0,0000 0,0316 0,0127 0.0000 0,0000 0,0909
0,1943
TIME CMIN)
12,472 13,077 16,807 18,758 19,641 19,997 21,130
TIME OFFSET -0,238
0, 037 -0,242
0, 370
-0.073
3 13
DBS
AREA COUNTS 26886 12876 1 1721 3836 6220 2874 9099
JUN 98
SEP CODE BB BB BB BB BB BB BB
Wl/2 CSEC) 5.20 5,05 5,65
? 5,40 5.75
? 5.60 5.85
72503
TECTED PKS: 9 REJECTED PKS: 2
VISOR: 1.00000 MULTIPLIER: 1.00000
•OTAL 9,; 2.6635 • 0. 164 1 0 8 7 3 V 0
DETECTED PKS: 31 REJECTED PKS: 3
D P ' I S O R : 1.00000 MULTIPLIER: 1.00000
No.dE: 34.0 OFFSET: 53
RACK: 16 VIAL: 11 INJ: 1
-2
NOTES: DBS CONFIRMATORY COLUMN
CHART SPEED 0,6 CM/MIN A T T E N : 8 Z E R O : 10% 1 MIN/TICK
-STAT-T| INJECT
A T T E N : 16 Z E R O : 10% l MIN/TICK
1 , 4 9 6 2 , 091
4 . 672
B Bf
H E P T 4 C H L 0 1 4 . 0 4 5
~f^Lfte1-N 1 5 . 0 0 4
1 5 , 9 8 1
1 9 . 5 7 2 E N D R I N : : ^ ^ ^ ^ ; 1 0 1
o D 01
a M
2 6 . 4 0 7 2 6 . 9 2 2 2 7 . 4 7 7
2 9 . 1 7 2 2 9 . 6 4 5
~ g R : 0
ENDO S04
-JiETHOXY"
' P - ? 5 7
2 3 . 4 2 6
TITLE: PESTICIDES
ANNEL N O : 2
PEAK NO
1 2 3 4 5 6 7 8 9 1 0 1 1 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 iB 29 30 31 32 33 34 35 36 37 38 39 40 4 1 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57
PEAK NAME
A BHC
L INDANE B BHC
HEPTACHLO
D-BHC
ALDRIN
ISODRIN HEPT EPOX
ENDO I
DDE DIELDRIN
ENDRIN DDD ENDO I 1
DDT ENDRIN AL
ENDO S04
METHOXY
HBB SURR
ALS:
SAMPLE:
RESULT UG/ML 0.0000 0.0000 0.0005 0,0000 0,0022 0,0025 0,0000 0,0054 0,0000 0,0045 0,0000 0,0016 0,0000 0 , 0000 1 ,3281 0,0027 0,0000 0 , 0000 0,0000 0,0000 0,0068 0,0000 0,0173 0,0176 0,0000 0,0000 0,0000 0,0280 0,0375 0.0353 0,0000 0,0000 0,0704 0,0539 0,0000 0,0442 0,0000 0 , 0000 0,0000 0.0000 0,0000 0 , 0000 0 , 0000 0,0000 0,0387 0 , 0000 0 , 0000 7,7506 0 , 0000 0.0000 0,0000 0,0000 0,0000 0 , 0000 0.0000 0,0000 0.0000
9,4478
TOX IPPM
TIME CMIN) 6, 024 1 1 ,425 1 1 ,649 12,819 12.949 13.193 13.609 14.045 14.242 14,376 15.004 15.222 15.358 15.981 16.455 16.840 17.194 17.431 17.668 17.907 18.298 18.533 18.793 19.358 19.572 19.809 20.101 20.191 20.440 20,727 20,957 21 ,208 21 ,393 21,732 21 ,918 22,069 22,350 22.496 22.628 22.790 23,227 23.427 23.806 23.951 24.104 24.338 24.539 24.904 25.102 25.379 25.541 25.902 26.407 26,922 27.088 27,477 30,812
METHOD
TIME OFFSET
-0,
-0, - 0 ,
-0,
-0,
0,
0, -0
0
0 0
-0 -0 -0
-0 -0
-0
-0
-0
-0
131
131 107
095
134
012
055 140
188
043 278
059 070 093
047 088
121
, 066
, 096
, 792
r
i,/^
: DB608
AREA COUNTS
572 1706 1005 1694 3754 1689 3642 5139 2459 6963 2725 2445 2 173 5269 2716 4073 1814 8614 6962 4449 8824 7534
24470 2|3490
> ^ 0 7 3 2 J7360
r/1 17831/, \ \ Z 1 6 1 X
" 38844/ /)IO41840\/
^ - ^ 6927 24213 35369/ 54576 6201
37244 14579 10023 17280 22836 61 154 48092 10074 1688
12969 1 1997 24642 3856 9469 7479 5265 4289 2567 1029 1312 3369 758
717764
SEP CODE BB BV VV BV VV VV VV VV VV VV VV VV VV VV VV VV vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv VB BV vv vv VB VB
7 7 7
7 7 7 7 7
?
7
?
7
7 7 7 7 7 7 7 7 7 7
? 7 7 7 7 7
? 7 ?
7
? ?
? ? ? ?
Wl/2 CSEC) 5,65 13,80 9,50 1 1 ,30 6.05 6. 80
14, 30 12. 30 10.30 7, 20 5,60 6. 15 6, 00 6,50 14,50 7.40 15.60 7.25 7.75 12.05 8,50 6,80 14,20 13, 10 1 1 ,30 9,60 1 1 ,00 4, 20 15,00 6.25 6. 60 14.60 12. 10 13.60 1 , 90
13.50 6,20 5,60 6,70 10,60 10,65 7, 60 7. 60 1 , 10 5, 15 1 1 ,60 9,10 8, 20 9.65 8,50 7.90 12.20 13.40 14.00 7.90
1 1 .85 17.60
m s u n7^>
DETECTED PKS; 71 REJECTED PKS; 14
i
