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title:AirQualityManagement:ConsiderationsforDevelopingCountriesWorldBankTechnicalPaper.EnergySeries
author: Wijetilleke,Lakdasa.;Karunaratne,Suhashini,A.R.
publisher: WorldBankisbn10|asin: 0821331914printisbn13: 9780821331910ebookisbn13: 9780585224251
language: English
subjectAirqualitymanagement--Developingcountries,Air--Pollution--Environmentalaspects.
publicationdate: 1995lcc: TD883.7.D44W541995ebddc: 363.73/92/0091724
Airqualitymanagement--Developing
subject: countries,Air--Pollution--Environmentalaspects.
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AirQualityManagementConsiderationsforDevelopingCountries
WORLDBANKTECHNICALPAPERNUMBER278ENERGYSERIES
LakdasaWijetillekeandSuhashiniA.R.Karunaratne
EnergySeries
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Pageiii
Copyright©1995TheInternationalBankforReconstructionandDevelopment/THEWORLDBANK1818HStreet,N.W.Washington,D.C.20433,U.S.A.
AllrightsreservedManufacturedintheUnitedStatesofAmericaFirstprintingApril1995
TechnicalPapersarepublishedtocommunicatetheresultsoftheBank'sworktothedevelopmentcommunitywiththeleastpossibledelay.Thetypescriptofthispaperthereforehasnotbeenpreparedinaccordancewiththeproceduresappropriatetoformalprintedtexts,andtheWorldBankacceptsnoresponsibilityforerrors.Somesourcescitedinthispapermaybeinformaldocumentsthatarenotreadilyavailable.
Thefindings,interpretations,andconclusionsexpressedinthispaperareentirelythoseoftheauthor(s)andshouldnotbeattributedinanymannertotheWorldBank,toitsaffiliatedorganizations,ortomembersofitsBoardofExecutiveDirectorsorthecountriestheyrepresent.TheWorldBankdoesnotguaranteetheaccuracyofthedataincludedinthispublicationandacceptsnoresponsibilitywhatsoeverforanyconsequenceoftheiruse.Theboundaries,colors,denominations,andotherinformationshownonanymapinthisvolumedonotimplyonthepartoftheWorldBankGroupanyjudgmentonthelegalstatusofanyterritoryortheendorsementoracceptanceofsuchboundaries.
Thematerialinthispublicationiscopyrighted.Requestsfor
permissiontoreproduceportionsofitshouldbesenttotheOfficeofthePublisherattheaddressshowninthecopyrightnoticeabove.TheWorldBankencouragesdisseminationofitsworkandwillnormallygivepermissionpromptlyand,whenthereproductionisfornoncommercialpurposes,withoutaskingafee.PermissiontocopyportionsforclassroomuseisgrantedthroughtheCopyrightClearanceCenter,Inc.,Suite910,222RosewoodDrive,Danvers,Massachusetts01923,U.S.A.
ThecompletebacklistofpublicationsfromtheWorldBankisshownintheannualIndexofPublications,whichcontainsanalphabeticaltitlelist(withfullorderinginformation)andindexesofsubjects,authors,andcountriesandregions.ThelatesteditionisavailablefreeofchargefromtheDistributionUnit,OfficeofthePublisher,TheWorldBank,1818HStreet,N.W.,Washington,D.C.20433,U.S.A.,orfromPublications,TheWorldBank,66,avenued'Iéna,75116Paris,France.
Thecoverphotographshowsfactorychimneysinaresidentialdistrict,Estonia;photographbyCurtCarnemark©1993theWorldBank;printprovidedcourtesyofMr.MichaelWishart,WorldBankExternalAffairsDepartment.
ISSN:0253-7494
LakdasaWijetillekeisaprincipalchemicalengineerintheIndustryandEnergyDepartmentoftheWorldBank.SuhashiniA.R.Karunaratneisaconsultanttothesamedepartment.
LibraryofCongressCataloging-in-PublicationData
Wijetilleke,Lakdasa,1933-Airqualitymanagement:considerationsfordevelopingcountries/LakdasaWijetillekeandSuhashiniA.R.Karunaratne.p.cm.(WorldBanktechnicalpaper,ISSN0253-7494;no.
278.Energyseries)ISBN0-8213-3191-41.AirqualitymanagementDevelopingcountries.2.AirPollutionEnvironmentalaspects.I.Karunaratne,Suhashini,A.R.,1965-.II.Title.III.Series:WorldBanktechnicalpaper;no.278.IV.Series:WorldBanktechnicalpaper.Energyseries.TD883.7.D44W541995363.73'92'0091724dc2095-3248CIP
Pagev
ContentsForeword ix
Abstract xi
Preface xiii
Acknowledgments xv
AbbreviationsandSymbols xvi
ConversionFactors xvii
ExecutiveSummary 1
EffectsofAirPollutantsonHealthandtheEnvironment
1
GreenhouseGases,AcidRain,Ozone,andChlorofluorocarbons
4
AmbientAirQualityandEmissionStandards 6
ValuationoftheBenefitsofMitigatingAirPollution 7
OptionsforMitigatingAirPollution 8
ConclusionsandRecommendations 12
1.AirPollution:AGrowingProblem 15
2.HealthandEnvironmentalEffectsofMajorPollutants,PartI:CarbonMonoxide,Hydrocarbons,OxidesofNitrogen,SuspendedParticulateMatter,andLead
21
CarbonMonoxide 21
Hydrocarbons 27
OxidesofNitrogen 30
SuspendedParticulateMatter 33
Lead 34
3.HealthandEnvironmentalEffectsofMajorPollutants,PartII:GreenhouseGases,SulfurOxides/AcidRain,Ozone,andChlorofluorocarbons
41
CarbonDioxideandtheGreenhouseEffect 41
SulfurOxidesandAcidRain 43
Ozone 48
CFCsandStratosphericOzoneDepletion 54
RelevancetoDevelopingCountries 56
Pagevi
4.AmbientAirQualityandEmissionStandards 59
AirQualityStandards 59
TheU.S.CleanAirActandAmendments 71
5.ValuationoftheBenefitsofMitigatingAirPollution 75
AHealth-BenefitsModel 76
TheCaseofThailand 77
RelevancetoDevelopingCountries 80
6.OptionsforMitigatingAirPollution 81
OptionsforReducingStationary-SourceEmissions 81
OptionsforReducingMobile-SourceEmissions 83
7.TowardanAirQualityManagementProgram 87
LegalFrameworkandInstitutionalArrangements 87
DevelopinganIntegratedProgramtoManageAirPollution
89
Glossary 93
References 97
Tables
1.1ApproximateToxicityWeightingFactorsforSelectedPollutants
18
2.1PredictedCOHbBloodConcentrationsforSubjectsEngagedinDifferentTypesofWork
22
2.2SignsandSymptomsofIncreasingCOHbLevelsinanAverageAdult
23
2.3SummaryofCOEmissionsOutlook,19802005 26
2.4ContributionofRoadTransportSectortoTotalHCEmissionsinSelectedCities
30
2.5SummaryofNOxEmissionsOutlook,19802005 32
2.6SuspendedParticulateMatterinVariousCitiesBetween1980and1984
35
3.1IncreaseinGreenhouseGases 43
3.2ConcentrationsofSO2atSelectedGEMS/AirSites,198089(mg/m3)
45
3.3OzoneLevelsinSelectedCities,1989 50
3.4EffectsofOzoneatVariousConcentrations 52
3.5HumanResponsetoSingleOzoneExposure 53
Pagevii
4.1ComparativeAmbientAirQualityStandardsof14Countries/EconomiesandTwoInternationalOrganizations
61
4.2China'sNationalAmbientAirQualityStandards(mg/m3)
62
4.3India'sAmbientAirQualityStandards(mg/m3) 62
4.4WorldHealthOrganizationGuidelinesforAmbientAirQualityStandards
63
4.5TransportSectorContributiontoNationwidePollutantEmissionLevelsinFrance,1990
64
4.6TransportSectorContributiontoAirPollutantEmissionsinSelectedCountries
65
4.7ExhaustEmissionStandardsforGasoline-PoweredLight-DutyVehiclesinSelectedIndustrializedCountries(g/km)
67
4.8Brazil'sEmissionStandardsforGasoline-andAlcohol-PoweredLight-DutyVehicles(g/km)
68
4.9Mexico'sEmissionStandardsforGasoline-PoweredMotorVehicles(g/mile)
68
4.10U.S.EmissionStandardsforLight-DutyDieselVehicles(g/mile)
70
4.11U.S.EmissionStandardsforHeavy-DutyDieselVehicles(g/BHP-hr)
70
4.12CurrentHeavy-DutyDieselPollutantLimitsinEurope(g/kWh)
71
4.13U.S.FuelSpecifications19922000,BasedonU.S.CleanAirActAmendmentsof1990
72
5.1Bangkok:EstimatedImpactsonMorbidityandMortalityof20PercentReductioninAmbientConcentrationsofSPM
77
5.2Bangkok:EstimatedImpactsonMorbidityandMortalityof20PercentReductioninAmbientConcentrationsofLead
77
5.3Bangkok:EstimatedImpactsonMorbidityof20PercentReductioninAmbientConcentrationsofSO2
78
5.4Bangkok:EstimatedImpactsonMorbidityof20PercentReductioninAmbientConcentrationsofO3
78
5.5SummaryofHealthBenefitsof20PercentImprovementinAirQualityinBangkok
78
Figures
1.1RelationshipBetweenLevelofDevelopmentandAirQuality
17
2.1UptakeofCObyBlood,aDose-ResponseCurve 24
2.2TheDramaticRiseofAromaticsinU.S.GasolinePool,197989
29
Pageviii
2.3EffectsofInorganicLeadonChildrenandAdultsLowestObservableAdverseEffectLevels
37
2.4CorrelationBetweenLevelsofLeadinGasolineandinBloodstream
38
2.5LeadPollutioninSelectedCities 38
3.1AverageConcentrationsofNO,NO2,andO3atVariousTimesofDayinLosAngeles
49
Boxes
2.1ChemicalNatureofCarbonMonoxide 25
2.2TheTrafficPoliceofJaipur,India 28
2.3ChemicalNatureofNitrogenOxides 31
2.4HarvardSixCitiesStudy 33
2.5TheEffectsofLead 39
3.1TheChemicalNatureofSulfurOxides 44
3.2SO2andEffectsofAcidRainintheCzechRepublic 47
3.3ChemistryofTroposphericOzoneFormation 49
3.4ChemistryofStratosphericOzoneFormation 54
3.5DepletionofStratosphericOzone 55
Pageix
ForewordThisstudyofairqualitymanagementfordevelopingcountriesreinforcesanimportantthemeoftheIndustryandEnergyDepartment'sworkonenergyandtheenvironmentthevalueofanearlyandproactiveapproach.Althoughsomedevelopingcountrieshaveregardedsustainedattentiontoenvironmentalissuesparticularlyonesthatdonothaveimmediate,localimplicationsaspreconditionedonfurthereconomicgrowth,alonger-runperspectiveshowsthatearlyadoptionofpoliciesforenvironmentallysaferenergyproductionandusecanallowdevelopingcountriestoresolveoramelioratesomeofthemostdifficultproblemsofindustrializationandgrowthatlowerhumanandeconomiccost.Further,goodpoliciestowardindustrialpollutionwillhelpeconomicgrowth,notreduceit.
LikeotherrecentworkintheWorldBankandelsewherethatincorporatesvaluationofenvironmentalandhealthfactorsintoeconomicappraisalcriteria,thisstudymakestheeffectsofairqualitytangibleatthelevelsoflocalproductivityandwell-being.Thestudydoesnotseeksimplytoimposetheairqualitystandardsoftheindustrialcountriesonthedevelopingcountriesbutratherarguesthatevaluationandregulatorymodelsdevelopedintheindustrialcountriescanprovideausefulbasisforfeasible,cost-effectiveairqualitymanagementprogramsthattakeaccountofthedistinctiveeconomicandepidemiologicalfeaturesofpollutionindevelopingcountries.Ataminimum,thestudysuggests,airqualitymanagementprogramsindevelopingcountriesshouldlimitemissionstocriticalpollutantloadsandprovideformaintainingandupdatingstandardsinanticipationofeconomicgrowthandtechnologicalprogress.Ultimately,thisapproachisbothsensibleandbeneficialinthelocalandglobalcontexts.
Reformsareineffectualwithoutsupportfromlegal,institutional,andregulatorystructurescapableofmonitoringandenforcingsocialgoals.Integratedairqualitymanagementprogramsarenoexception.Focusingastheydoonindustry,transport,infrastructure,energyproduction,andsocialpolicy,airqualityprogramsnecessarilyrequireacross-sectoralapproachandacommitmenttoaddresstheproblemasanationalpriority.TheBankandtechnicalassistanceprogramssuchastheEnergySectorManagementAssistanceProgramme(ESMAP)arealsoseekingtomarshalexpertiseonthesesubjects.AnIENstudynowinprogressonfuelsreformulationforreducedemissionsandaforthcomingpaperoncleancoaltechnologiesfordevelopingcountriesareamongthepublicationswearepreparingtoassistdevelopingcountriesinmakingenvironmentallyandeconomicallysounddecisionsonenergyproductionanduse.
RICHARDSTERNDIRECTORINDUSTRYANDENERGYDEPARTMENT
Pagexi
AbstractTheburningoffossilfuelsleadstotheproductionofpollutantssuchascarbonmonoxide(CO);sulfuroxides(SOx);nitrogenoxides(NOx);hydrocarbons(botharomaticsandaliphatics);lead;andinhalableparticulatessuchasdust,smoke,andfumes.Insufficientquantitiesthesepollutantscaninjurepeople,forests,andcrops.Moreover,consumptionoffossilfuelsandproductionofcertainindustrialchemicalsalsoappeartobedamagingthelayerofstratosphericozone,whichhelpsprotecttheearthfromtheharmfuleffectsofthesun'srays.Pollutionalsoappearstobedrivingthegreenhouseeffect,whichmaythreatentheoverallstabilityoftheglobalecosystem.
Althoughairpollutionismostoftenassociatedwiththeindustrializedcountries,ithasbecomeasignificantandincreasingprobleminmanydevelopingcountries,aseconomicgrowthstimulatesconsumptionoffossilfuelsforuseinindustryandtransport;pollutionlevelsinsomedeveloping-countrycities(especiallywherebasicindustriesarelocatedinmetropolitansettingsandregulationislaxorabsent)arealreadyworsethanthoseofsomeindustrialcountries.Theinhabitantsofdevelopingcountriesarealsomorelikelytosufferthedetrimentalhealtheffectsthatcanresultfrombreathingpollutedair,inpartbecausetheygenerallyspendmoretimeoutdoorsandaremorelikelytotravelinopenmotorvehicles.Thisstudyseekstoprovideabasisfordevelopingcountriestodevelopeffectiveairqualitymanagementprograms.
Thepaperbeginsbyoutliningthenatureandextentoftheproblemaswellassomebasicconceptsthatareofrelevancetodevelopingcountries(suchastoxicityweightingfactors).Chapters2and3introducetheairpollutantsofconcernanddetailtheirdetrimental
effectsonthephysicalenvironmentandonthehealthofchildrenandadults.Chapter4providesinformationontheambientairqualityandemissionstandardsofvariouscountries,includingtheUnitedStates,aswellasthoseestablishedbytheWorldHealthOrganization.Sincemostdevelopingcountrieshavenotyetestablishedairqualitystandards,industrializedcountriesprovidemostoftheexamples.Thesestandardsneednotnecessarilybeduplicatedbythedevelopingcountriesbutrathercanbeusedasguidelines.Chapter5showshowtoevaluatethebenefitsofreductionofvariousairpollutants.UsingThailandasanexample,thechaptershowshowairqualityanalysishelpedtechniciansandofficialspinpointleadandSPMashavingthemostdangerousconcentrationsintheBangkokareaandasrepresentingthebesttargetsformitigation.Chapter6looksatsomeoptionsformitigatingairpollutionfromstationaryandmobilesources.Chapter7presentsconclusionsandrecommendationsaboutairqualitymanagementstrategiesthatmaybehelpfultodevelopingcountries.
Botheconomicandenvironmentallogicargueforvigorousactiontocontrolairpollutionintheearlystagesofdevelopment,whenitisbothcheaperandmoreeffectivetodeployanti-pollutionmeasures.Conversely,failuretodevelopeffectiveairqualitymanagementsystemswillmeanworseningairpollutionatthelocalandgloballevels.
Pagexiii
PrefaceMitigatingtheadverseenvironmentalandhealtheffectsassociatedwitheconomicdevelopmentthroughtimelyandcost-effectiveprogramsshouldbeahighpriorityfordevelopingcountries,forbothlocalandglobalreasons.Thechallengesforthedevelopingcountriesaretobenefitfromtheexperienceoftheindustrializedcountries,avoidtheirmistakes,andestablishthebasisforsoundeconomicdevelopmentwhilepreservinghumanhealthandthequalityoftheenvironment.Eachcountryofcoursewillfaceuniqueproblems,butallcountriesthatwishtoensureenvironmentalqualitywillhavetomakethecommitmenttodosoahighpriority.
Unfortunately,airqualitymanagementandenhancementoftenbecomesubjectsofconcernonlywhenairpollutionreachescrisislevels.Generally,bythetimeairpollutionisrecognizedasamajorhealthhazard,thefactorsthatexacerbateitmayhavebecomeirreversibleorextremelycostlytoremedy.Developingcountriesgenerallyhavebeenmuchslowerthantheindustrialcountriesinrecognizingtherisksandintakingtechnicalstepstoreduceairpollutionfromautomobilesandindustrialfacilities.Clearly,however,theproblemhasimmediate,localeffectsaswellasglobalimplications.
Onereasonforthispatternofneglectisalackofunderstandingofthebenefitsofenhancingairquality.Thisstudydescribestheproblem,thehealtheffects,andthebenefitsthatcouldaccruefromreducingpollution.Thedataarepresentedinaconciseformsothatpolicymakers,administrators,andtechnocratsespeciallyindevelopingcountriescanfocustheireffortsondevelopingresults-orientedprograms.
Evenwhenairpollutionisrecognizedasaproblem,addressingitinitscorrectperspectiveanddefiningthescopeofremedialmeasuresarecomplextasks.Themagnitudeofthetechnicalandpolicyissuesandthecapital-intensivenatureofmanysolutionstendtodiscourageasystematizedapproach.Withoutoversimplifyingtheoptions,thisstudyattemptstopresentcost-effectiveandsystematicstrategiesforaddressingthepollutionproblem.
Iftheyhavenotdonesoalready,developingcountriesshouldpromulgateclearlegalframeworksforcontrollingairpollution.Thiswillfacilitatetheestablishmentofairqualitystandardsandregulations,alongwithagenciestomonitorcomplianceandundertakeenforcement.Amongthefirststepsshouldbeaccuratemeasurementsofambientairqualityandthecorrelationofthesemeasurementswithepidemiologicaldatatodeterminetheharmfuleffectsofairpollutionaswellasthepotentialsocialandeconomicbenefitsofreducingit.Thestudyalsoemphasizestheimportanceofinstitutionalstrengtheningandtrainingofstaffasprerequisitesforthedevelopmentofanairqualitymanagementprogramandidentifieskeyobjectivesofaneffectiveprogram.
Thestudyprovidesthebackgroundagainstwhichanairqualitymanagementprogram'ssubcomponentssuchastrafficmanagement,fuelssubstitution,fuelsreformulation,andenergydemandmanagementshouldbedeveloped.Clearlythecosts
Pagexiv
ofimplementingthesedifferentoptionswilloftenbesubstantial.Anassessmentofinvestmentrequirementsforeachoftheabove-mentionedoptionswouldbeastudybyitself,butafollow-upstudytothepresentworkwilladdressoneofthesubcomponents,fuelsreformulaiton,anditishopedthatthiswillclarifysomeofthecostsandbenefitsofprogramsneededtomitigateairpollutionandstimulatefurtherworkinthefield.
Pagexv
AkcnowledgementsThispaperisbasedonareviewofcurrentliteratureanddataonairpollution.SpecialthanksgotoMichaelWalsh;toMohanMunasingheandMadeleineNawar(PollutionandEnvironmentalEconomicsDivision,EnvironmentDepartment,WorldBank)fortheircomments;andtoPhillipsawickiandPaulWolmanfortheireditorialassistanceandhelpfulsuggestions.WordprocessingwasprovidedbyCarole-SueCastronuovo.GraphicswerepreparedbyS.A.D.SubasingheandCathyA.Kocak.
Pagexvi
AbbreviationsandSymbolsCFCs Cholorofluorocarbons
CO Carbonmonoxide
CO2 Carbondioxide
COHb Corboxyhemoglobin
g/BHP-hr
Gramsperbrakehorsepowerperhour
g/km gramsperkilometer
g/kWh gramperkilowatthour
g/l Gramsperliter
g/mile Gramspermile
g/test gramspertestkm Kilometer(103meters)
l Wavelengthoflight
n Frequencyoflight
mg/m3 Milligramspercubicmeter
nm Nanometer(10-9meters)
NOx Oxidesofnitrogen(NOandNO2)
O3 Ozone
PM10 Particulatematterof10micronsorlessinsize
ppb Partsperbillion
ppm Partspermillion
SOx Oxidesofsulfur(SO2andSO3)
SPM Suspendedparticulatematter
TSP Totalsuspendedparticulates
VOCs Volatileorganiccompounds
vol-% Volumepercent
wt-% Weightpercent
mg/m3 Microgramspercubicmeter
mm Micrometer(10-6meters)
°C DegreesCelsius
°F DegreesFarhrenheit
Pagexvii
ConversionFactorsUnitsoflength
1mile(mi)=1.6kilometer(km)
Massunits
1pound(lb.)=0.45kilogram(kg)
1metricton(t)=103Kilogram(kg)
1shortton(shton)=2000lb.=9.07x102kilogram(kg)
Pressureunits
1atmosphere(atm)=101.325kilopascal(kPa)
1psi(lb/in2)=6.895kilopascal(kPa)
Temperatureunits
1°F=1.8°C+32
Volumeunits
1liter(L)=1000cm3=10-3m3
1USgallon(gal)=3.785x10-3m3
Toconvertvolumemeasures(ppm)toweightmeasures(mg/m3)forair
pollutants,thefollowingformulawasused:
mg/m3=ppmxmolecularweightx40.91
Page1
ExecutiveSummaryAirpollutionisamajorprobleminmostcountries.Itiscausedprimarilybyenergyuseintransportationandindustry,althoughnaturealsocontributesthroughsucheventsasvolcaniceruptionsandforestfires.Thisreportdiscussesthehealthandenvironmentalimpactsofairpollution,thecostsofmitigationmeasures,andthecostsofinaction.Itconcludesbymakingrecommendationsforpreparationofanintegratedairqualitymanagementprogram.
Manufacturedgoodsandservicesaretheproductsofindustrialactivity,andvigorousindustrialactivityistheeconomicbasisformanyotheractivities,includingsocialservices.Itisthereforeimportantthatactivitiesthatraisethestandardofliving,especiallyindevelopingcountries,shouldsucceed.Thissuccess,however,shouldnotandneednotbeachievedbyturningablindeyetoenvironmentaldegradation.Economicdevelopment,ifproperlyplanned,neednotcauseextensiveorirreversibleenvironmentaldamage;conversely,environmentalprotectioncanbeachievedwithoutthwartingdevelopment.
Theconcentrationofpollutantsintheambientairhasgenerallyincreasedasurbanizationhasproceeded.Therefore,strategiestoprotectairqualitycanandshouldbeputintoplaceasdevelopmentproceeds,beforeseriousandirreversibledamageisdone.
EffectsofAirPollutantsonHealthandtheEnvironment
Moststudiesofairpollutantshavebeenbasedondatafromtheindustrializedcountries.Nonetheless,theirfindingsarehighlyrelevanttodevelopingcountriesaswell,wherehighratesofurbanizationandnonexistentorinadequateenvironmentalregulations
oftenleadtoairpollutionratesgreaterthanthoseincomparableregionsinNorthAmericaandEurope.
CarbonMonoxide
Gasolineconsumedinmotorvehiclesisthemainsourceofcarbonmonoxide(CO)inmetropolitanareas.CarbonmonoxidelevelsintheUnitedStatesincreasedfrom73millionmetrictonsin1940to100milliontonsin1973,astheU.S.motorvehiclefleetincreasedtremendously(WHO1979:23).SimilardatafromotherOECDcountriesconfirmtheCO-vehiclelinkage.Concomitantly,theinstallationofcatalyticconvertersinmotorvehiclesintheUnitedStatesreducedCOemissionsaswellasambientCOconcentrationsdramatically.Emissionsintheindustrializedcountriesaregenerallyonthedeclinebecauseofmorestringentstandardsandthemorerapidreplacementratesofoldervehicleswiththosehavingloweremissionfactors(Holdgateandothers1982;Flachsbart1992).EmissionsofCOinthedevelopingcountries,incontrast,areprojectedtoincreasefrom40percentoftheworld'ssharein1980to58percentin2005(OECD/IEA1991:56).
Page2
InhalationofCOhasdetrimentaleffectsonhumanhealthbecausetheaffinityofhemoglobininthebloodforCOisabout240timesthatofitsaffinityforoxygen(Romieu1992).Onceinhaled,COformsastrongcoordinatebondwiththeironatomoftheprotohaemcomplexinhemoglobintoproducecarboxyhemoglobin(COHb).Thiscompound,inturn,impairstheoxygen-carryingcapacityofbloodandreducestheamountofoxygenavailableinthebloodtocarryoutnormalbodilyactivities.COHblevelsofapproximately1.2to1.5percentarenormallyfoundinthegeneralpopulation,butinareasoftrafficcongestion,COHblevelsinhumanscanreach3percent.ElevatedCOHblevelsareparticularlydangerousforpeoplewithheartdiseaseorrespiratoryproblems,pregnantwomen,andinfants.
Hydrocarbons
Hydrocarbonsareorganiccompoundsconsistingmainlyofcarbonandhydrogen.Straight-chaincompoundsareknownasaliphatics;compoundshavingacyclicstructurearecalledaromatics.Hydrocarbonsareprecursorstoozoneformation.Aromaticsingasolinepromotetheformationofnitrogenoxides,andhydrocarbonsinteractwiththesenitrogenoxidesinthepresenceofsunlighttoformozone.Athighconcentrations,hydrocarbonscauseminorirritationofmucosaandhaveageneralnarcoticeffect.Benzene,a6-carbonaromatic,isamajorindustrialchemicalandisclassifiedasaknownhumancarcinogenbecauseofitslinktoadultleukemia.Formaldehydeisashort-termrespiratoryandskinirritantandapossiblecarcinogen.
Coalandpetroleumarethetwolargeorganicreservoirsfromwhicharomaticcompoundsareobtained.Petroleumisthemainsourceofbenzene,toluene,andxylene,allusedinthechemicalindustryandintheproductionofhigh-octanegasoline.Ironically,theU.S.decisiontophaseoutanotherdangerouspollutantleadatthebeginningofthe
1970s,alongwithadesireforhighergasolineoctanelevels,increasedthedemandforaromatics.Hence,beforelimitsof1percentonbenzeneand25percentonaromaticswereimposedbythe1990U.S.CleanAirActAmendments,benzenelevelshadrisentoabove5percentandaromaticstomorethan30percent(seeOxy-FuelNews1990).Maximumpermissiblelevelsofbenzeneandaromaticsinmostcountriesare3percentand30percent,respectively.
OxidesofNitrogen
GenerallyexpressedintheinclusivetermNOx,thevariousoxidesofnitrogencompriseNO(nitrogenoxide),N2O(nitrousoxide),andNO2(nitrogendioxide).Nitrogenoxidesintheatmospherereducevisibility,contributetotheformationofacidaerosols,exacerbateglobalwarming,formozoneatgroundlevel,andactascatalystsinthedecompositionofozoneintheupperatmosphere.Inpeopleexposedtothepollutantforlongperiods,nitrogendioxidealsocausesirreversiblelungdamage.Otherilleffectsincludebronchitis,chesttightness,burningoftheeyes,andheadaches.Asthmaticsareparticularlyvulnerabletotheseproblems.RecurrentexposuretohighconcentrationsofNO2ismoreharmfulthancontinuousexposuretolower-levelconcentrations.
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Bacterialactioninthesoil,volcaniceruptions,andlightningallnaturaleventsputmuchgreateramountsofoxidesofnitrogenintotheatmospherethanhumanactivities.Naturalemissionsaredilutedovertheentireplanet,however.Hence,whereasthenaturalconcentrationofnitrogendioxideisabout0.4to9.4microgramspercubicmeter(mg/m3)worldwide,theaverageannualmeaninurbanareasrangesfrom20to90mg/m3(WorldBank1988:218),illustratingboththedamagingeffectsofhumanactivityandthepotentialforremediation.
SuspendedParticulateMatter
Suspendedparticulatematter(SPM),particles10micronsorlessinsize,remainintheatmospherelongerthanlargerparticles.Intheatmosphere,SPMreducesvisibilityandreactswithotherairpollutantstocreatenewpollutants.SPMalsocontributestorespiratoryillnessesbypenetratingdeepintotherespiratorytract.Thetoxiceffectdependsontheparticle'sphysicalandchemicalnature,particularlywithrespecttogasesadsorbedonthesurfaceorabsorbedwithinit.
InhalableSPMcomesprimarilyfromthecombustionofdieselfuelintrucksandbusesandisincreasedbyotherfactors,includingpoor-qualitydieseloil,substandardengineoperationandmaintenance,andtrafficcongestion.Althoughthetoxicityofparticulatesislowerthanthatofotherairpollutants,suchaslead,largevolumesofparticulatesareemitted,andinhalableSPM,especiallyparticlessmallerthan2microns,poseamuchgreaterriskthanlargerSPMbecauseoftheirgreaterabilitytopassthroughthenaturalprotectivemechanismsofthehumanrespiratorysystemandclingtotheinnertissuesofthelungs.AGlobalEnvironmentMonitoringSystems(GEMS)studyoftheglobalspreadofparticulatesfrom1980to1984foundthatallowableSPMlevelsin37of41citiescameclosetoorexceededWorldHealthOrganization(WHO)guidelines(French1990:11).The
WorldBankestimatesthatreductionofSPMtosafelevelscouldreduceprematuredeathsby300,000to700,000annuallyindevelopingcountries(WorldBank1992:52).
Lead
Regulatoryagenciesandhealthorganizationshavenotreachedaconsensusonexactlyhowmuchleadinthebloodconstitutesleadpoisoning.Overtheyears,however,alloftheseorganizationshaveloweredthethresholdoftoxicityasnewinformationhasbecomeavailableabouttheneurologic,reproductive,andpossiblehypertensiveeffectsoflead.Leadpoisoningcanoccurevenwithoutexposuretomajordosesoflead,sincethebodyaccumulatesleadovertimeandreleasesitonlyslowly.Itisthusthetotalbodyburdenofleadthatistherelevantfactor(AgencyforToxicSubstancesandDiseaseRegistry1992:6).
Theforegoingnotwithstanding,leadintakehasmoresevereconsequencesforchildrenthanforadults.Medicalevidencenowshowsthatdevelopmentofthenervoussysteminchildrencanbeaffectedadverselyatblood-leadlevelsof10mg/dl(Agencyfor
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ToxicSubstancesandDiseaseRegistry1992:8).Neuralgicandotherdefectscausedbyleadpoisoningmaybeirreversible,andacuteexposuresometimesleadstodeath.
Adefinitecorrelationhasbeenfoundbetweenthelevelofleadingasolineandinthehumanbloodstream.Asnotedabove,leadadditivesingasolineweredrasticallyreducedintheUnitedStatesbetween1972and1984,andasharpdeclineinambientleadlevelsaswellasleadlevelsinthebloodwasobservedatthesametime(Shy1990).
Significantcontributorstoairborneleadaremetalsmelters,batterymanufacturingplants,andemissionsfromfueladditivesandleadedgasoline.Thelastisnowconsideredtobebyfarthemostseriousproblem.Althoughonlyabout10percentofallrefinedleadgoesintogasoline,suchleadmayconstitute60percentofleademissionsintotheatmosphere.Incitieswithhightrafficcongestion,thisproportionmaybecloserto90percent.
GreenhouseGases,AcidRain,Ozone,andChlorofluorocarbons
Airpollutionhaslongbeenassociatedwithurbanizationandindustrialization.Althoughmanydevelopedcountrieshavemanagedtoreducethelevelsofsomeairpollutants,others,forexampleinSouthernandEasternEurope,haveseenlevelsofairpollutionincrease.OfparticularconcernistheworseningairpollutioninthepopulouscitiesofLatinAmerica,China,India,andSoutheastAsia.Itisestimatedthatoneofeverytwopeopleintheworldwillbeanurbanresidentbytheyear2000,andoneineverythreewillliveinacityofatleast100,000inhabitants.Eightoutofevery10peoplewillliveinadevelopingcountry.Againstthisbackground,thegrowingintensityofairpollutioniscauseforrealconcern.
Whereaslocalpollutantsareprimarilyresponsibleforthe
deteriorationofurbanairquality,regionalandglobalpollutants(suchassulfuroxides,nitrogenoxides,ozone,andgreenhousegases)arethecausesofelevatedlevelsofairpollutioninresidentialurbanareas,ruraltowns,nationalparks,andrecreationalsites.Regionalandglobalpollutantsknownoboundariesandaretransportedintheairtofardistances.Thegreenhouseeffect,depletionofthestratosphericozonelayer,andacidrainarecausedbyaggregationsofregionalandglobalpollutantsemittedbydifferentandwidespreadsources.Thus,forexample,emissionsintheIndiansubcontinentorAfricacouldultimatelyaffecttherestoftheworld.
TheGreenhouseEffect
Carbondioxide(CO2),nitrousoxide(N2O),methane(CH4),ground-levelozone(O3),andchlorofluorocarbons(CFCs)absorbinfraredradiationfromtheearth,actingineffectasaninsulatingblanketthatpreventsheatfromescapingtheatmosphere.Overthepastcenturyaverageglobaltemperaturehasincreasedbybetween0.3°Cand0.6°C,whichconformswellwiththeavailablemodelsoflong-termresponsetogreenhousegasproduction.Approximately50percentofglobalwarmingisattributedtoCO2.Chlorofluorocarbonsareresponsibleforabout20percent,methaneabout16percent,and
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ground-levelozone8percent.Thebulkoftheremaining6percentorsoiscontributedbynitrousoxide(Tétrault1992).
TheIntergovernmentalPanelonClimateChange(seeTétrault1992)hasestimatedthatatthecurrentrateofproductionofCO2andtheothergases,adoublingoftheirpreindustrialconcentrationswilloccursometimeinthe21stcentury.Thepanelhasestimatedthattheaverageplanetarytemperaturecouldrisebybetween1.5°Cand4.5°Cinthisperiod.Globaltemperaturechangesof1°to2°Chavetypicallytaken1,000to10,000years,andariseof5°CwasresponsibleforbringingtheEarthoutofthelasticeage.
Drasticchangesintheglobaltemperaturecouldcauseashiftinclimaticzones,changesinpatternsofrainfall,moreextremeweatherconditions,andariseinthesealevelthatcouldseriouslyaffectlifeinmanycountries.Ifglobalwarmingcontinuesunchecked,meltingofthepolaricecapscouldraisetheoceanlevel5to6metersbytheendofthe21stcentury,floodinglow-lyingcoastalareasallovertheworld(EnvironmentalUpdate1990).
Deforestationandthecombustionofcoal,oil,andnaturalgasinjectbillionsoftonsofcarbonintotheatmosphereeachyearandareresponsiblefortheincreaseinatmosphericCO2.Theburningoffossilfuelsalonegenerates20billiontonsofCO2,annually.Agasoline-fueledmotorvehicle,housingasingle16gallontankoffuel,generatesbetween300and400poundsofCO2(DeLuchiandothers1988).Itisestimatedthatmotorvehiclesemitalmost15percentoftheworld'stotalCO2.Asdevelopingcountriesindustrialize,theiremissionswillrisesteeplyandmaycompoundenvironmentalproblemsunlessthesecountriesacttolimitemissions.
SulfurOxidesandAcidRain
Mostsulfuremissionsareintheformofsulfurdioxide(SO2)andare
producedbypublictransport,industries,andthermalpowergeneration.Extrapolationofdatafroma54-citystudyconductedbyGEMSovertheperiod198084,toinclude1.8billionurbanresidentsworldwide,foundthatwhereas625millionpeoplearoundtheworldliveinurbanareaswhereSO2levelswerewithintheWHOannualguidelinesof40to60mg/m3,upto1.2billionurbanresidentsliveinareaswheretheairqualityforSO2iseithermarginal(550millionresidents)orunacceptable(625millionresidents).
Clinicalstudiesusinghumansubjectsindicatethatchildrenandbothhealthyandat-riskadultsarevulnerabletotheeffectsofSO2.Individualswhosufferfromchronicrespiratorydiseases,suchasbronchitis,emphysema,andasthmamayexperiencecoughingandbreathingdifficultieswhenambientSO2concentrationsincreasefrom0.1to0.2ppm(U.S.Congress1987).
AtmosphericSO2combineswithwatertoproducedilutesulfurousandsulfuricacids,whichfalltoearthasacidrain.Becausetheacidsareformedhighintheatmosphere,theymaytravelasfaras1,000milesbeforeprecipitating.Untilrecently,acidrainwaslimitedtothenorthernhemisphere,withWesternEuropeandNorth
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Americaputtinganestimated90milliontonsofSO2intotheaireachyear.Theacidrainproblemhasnowintensifiedindevelopingcountriesasthesecountriesexpandtheirindustrialactivities.RecentdataindicatethreateninglevelsofsoilacidityinpartsofBrazil,Colombia,Venezuela,India,SoutheastAsia,Japan,andChina(Tétrault1992).
PlantsareverysensitivetoconcentrationsofatmosphericSO2andtothesynergisticeffectofSO2withlowlevelsofozoneornitrogenoxides.Itisestimatedthatabout75percentofEurope'scommercialforestshavesufferedfromdamagingconcentrationsofSO2(WorldResourcesInstitute1992:208).
TheindirecteffectsofSO2canbeseeninthemanylakesaroundtheworldthatcannolongersupportplantandanimallife.Acidrainisespeciallyharmfulinareaswherethebedrockisgraniteorwhereothermaterialispresentthatisincapableofneutralizingacid-forminghydrogenions.Acidrainisalsoerodingtheworld'srichheritageofoutdoorartandarchitecture,includingtheGreekruinsontheAcropolisandtheTajMahalinIndia.
Ozone
Ozoneisabluishgaswithapungentodor.Itspresenceintheatmospherecanhaveeitherharmfulorbeneficialeffectsonhumanhealthandwell-being,dependingonitsaltitude.
Ozoneatlowaltitudes(upto15kilometers)isreferredtoastroposphericozoneandisharmful.Itisformedthroughacomplicatedseriesofchemicalreactionsbetweenhydrocarbonsandnitrogenoxidesinthepresenceofsunlight.Thisozoneisthechiefconstituentofphotochemicalsmog,andevenoneortwohoursofexerciseinsmog-ladenaircanresultincoughing,painfulbreathing,andtemporarylossoflungfunction.Repeatedexposuretoozonemay
resultinpermanentlungimpairmentorthedevelopmentofchroniclungdiseases,suchaspulmonaryfibrosis.
Stratosphericozone(above15kilometers)isbeneficialbecauseitshieldstheEarthtosomedegreefromultravioletB(UV-B)radiationfromthesun.A1percentdepletionofstratosphericozoneresultsina2percentincreaseinUV-Bradiationanda4percentincreaseinskincancer(Titus1986:1).IncreasedUV-Bradiationcanalsocausecataractsintheeyesandimpairtheskin'simmuneresponses.Meteorologicalconditionsandconcentrationsofcertainindustrialchemicalscontributetothedestructionofstratosphericozone.CFCs,throughaseriesofchemicalreactions,yieldchlorineatomsthatdepletetheozonelayer.Reportsfromaroundtheworldindicatethatthestratosphericozonelayerisshrinking,adevelopmentthatcouldhaveserioushealthandenvironmentalimplications.
AmbientAirQualityandEmissionStandards
Thecreationandemissionofairpollutantsareunavoidable,butemissionsandtheirambientconcentrationsarecontrollable.Theimpactofanypollutantisdeterminedbyitsconcentrationanddurationatanyparticularlevelintheatmosphere.Airquality
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standardsessentiallyidentifylevels,withanadequatemarginofsafety,beyondwhichapollutantcancauseharm.
Emissionstandardstocontrolharmfulemissionsaregenerallylinkedtoambientpollutionconcentrations.Thesestandardsshouldbebasedonepidemiologicaldata,ambientairquality(i.e.,theconcentrationsofpollutantsinthesurroundingarea),andambientairqualitystandards.EmissionstandardssetbytheU.S.EnvironmentalProtectionAgency(EPA)havebeenadoptedbymostcountries.Someofthesestandardscouldberelaxedindevelopingcountries.WesternEuropeancountrieshaverespondedtotheirtransport-relatedairpollutionbyimplementingincreasinglyrigorousmotorfuelstandards.Gasolinespecificationsandformulationsnowconsideredessentialintheindustrializedcountriestomeetthesestringentstandardswouldrequireamajorrestructuringofrefineries.Sincetheuseofdieseloilfarexceedsgasolineconsumptionindevelopingcountriesasawhole,reformulationofgasolinetothestandardsneededinindustrializedcountriescanbefollowedatareducedpace.
Transport-RelatedEmissions
Automobiles,light-andheavy-dutytrucks,motorcycles,off-highwayvehicles,trains,aircraft,andshipsallcontributetoairpollution.ThetransportsectoristhelargestsourceofCO,HC,NOx,SPM,andleadintheatmosphere.Byfarthelargestcontributorstopollutioninmetropolitanareasareroadvehicles.
Transportemissionsareintensifiedbycongestedroads,poorvehiclemaintenance,oldvehicles,inferiorfuels,andtheincreasingnumberofvehiclesinuse.Forexample,thenumberofvehiclesinBangkokisincreasingatanastronomicalrate.Thailandaddsabout300to400newvehiclesaday(Sayeg1992:23).Thenumberofdiesel-poweredvehiclesworldwideisalsorisingquickly.Themajorconcernwithregardtodieselvehiclesisemissionofparticulates.
TheU.S.CleanAirAct
TheU.S.CleanAirActwaspromulgatedtoensuretheprotectionandenhancementofU.S.airresources.The1970Act,asamended,setsasocietalgoalofachievinggoodairqualitywithoutconsiderationofthecostsinvolved.The1990CleanAirActAmendmentstightenedpollution-controlmeasuresincities,stipulatednecessarychangesintransportationfuels,andestablishedmorestringentexhaustemissionstandards.Amongthemoresignificantchangeswasarequirementthat2.7weight-percent(wt-%)minimumaverageoxygenmustbeaddedtogasolineduringthewinterincitiesthatarenotincompliancewithfederalairqualitystandards.TheU.S.standardsmaybetoostrictforsomedevelopingcountries,buttheyshouldprovideausefulbasisfordevelopingregulationsappropriatetoeachcountry.
ValuationoftheBenefitsofMitigatingAirPollution
Untilrecently,noattemptshadbeenmadetoquantifythebeneficialimpactsofcleanair.Thebenefitsusuallywerelumpedintoanall-inclusiveterm:improvementin
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thequalityoflife.Itisimperativethatappropriatecriteriaareadoptedtomeasurethehealthandotherbenefitsofreducingconcentrationsofambientairpollution.HealthbenefitsmodelshavenowbeendevelopedintheUnitedStates,WesternEurope,andJapan.Themodelsarelessthanperfect,buttheydoprovideausefulbasisforvaluationofbenefits,andwithappropriatemodificationtheycanbeusedtoquantifybenefitsindevelopingcountries.
Thehealthbenefitsmodelisbasedonthedamage-functionapproachtoestimatingbenefits.ThispaperpresentsanevaluationofacasestudyonThailandthatusesthismodeltodeterminetheeffectsonhumansofa20percentreductioninconcentrationsofambientairpollution.Beginningwithbaselineandprojectedchangesintheconcentrationofspecificpollutants,dose-responsefunctionsfromepidemiologicalandpopulationdataareusedincalculatingchangesinavarietyofhealthendpoints.Theeconomicvalueofthesehealthbenefitsisthenestimated.A1994estimateforThailandsuggeststhatthebenefitsaccruingfroma20percentreductionofambientairpollutantscouldrangefrom$750millionto$3.1billionannually(WorldBankdata).
OptionsforMitigatingAirPollution
Althoughthemajorsourceofairpollutioninmostmetropolitanregionsisthetransportsector,exceptionstothisrulearecommon.InThailand,Mexico,thePhilippines,India,Indonesia,andKorea,largepercentagesofthecountry'sindustrialplantsarefoundwithinmetropolitanareas.Hence,thecontributionstoairpollutionofboththeindustrialandtransportsectorsmustbetakenintoaccountwhenoptionsformitigatingairpollutionarebeingstudied.
ReducingStationarySourceEmissions
Mostdevelopingcountriesarguethatverystringentemission
standardscouldhamperindustrialization,andsomehavemadecompellingargumentsforadoptingecologicallybasedemissionstandards.Suchstandardspresupposeacceptanceoftheconceptofcriticalpollutantloadsbycalculatingtheseforeachcountry.Forlargecountries,criticalpollutantloadsmustbecalculatedonanarea-widebasis.Theconceptimpliesthatdevelopingcountriescandecidetoadoptlessstringentstandardsthanhighlyindustrializedcountriesunlessepidemiologicaldataindicatethatsomeairpollutantisalreadycausinghealthproblems.Thisconceptshouldbeappliedwithcaution,ifatall.Ifacountryisindustrializingrapidly,morestringentstandardswillhavetobeadoptedinanticipationofhigherlevelsofpollution.
Airpollutionmitigationprogramsmayincludebothtechnological-andpolicy-basedchangesandwillbemosteffectiveifthechangesareidentifiedearlyinthedevelopmentcycle.
SwitchingtoNaturalGas.Switchingtocleanerfuelsisoneofthemostcost-effectivestrategiesforreducingemissions,particularlyofSO2andCO2.Thefuelofchoiceisnaturalgas,whichcontainsvirtuallynosulfurandwhosecombustionproduces
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farlessNOxthancoalorfueloil.Sincenaturalgashasahigherhydrogen-to-carbonratio,italsoproducesfarlessCO2duringcombustionthaneithercoalorfueloil.Acombined-cyclepowerplantusingnaturalgasproduces55percentlessCO2thanacoal-firedpowerplantperunitofelectricityproduced.
UsingHigher-Quality,CleanCoal.Greateruseoflow-sulfurcoalisanotheroptionfordevelopingcountriesdespitecoal'senvironmentaldrawbacks.Ifhigh-quality(i.e.,low-sulfur)coalcanbeproducedorimportedatareasonableprice,newcoal-washingtechnologiescanfurtherreduceitssulfurcontentby20to50percent.Othernewtechnologies,suchasfluidized-bedcombustionorintegratedgasificationcombined-cyclepowergeneration,alsohaveresultedinsubstantialSO2andNOxreductions(TavoulareasandCharpentier1994).
Thescrubbingofstackgasesfromcoal-firedpowerplantsalsocanreducebothSO2andNOxemissions.Scrubberscanremoveabout95percentoftheSO2andbetween70and90percentofNOxthatwouldotherwisebereleasedduringcombustion.Thecostsofinstallingscrubbersarehigh,however,especiallyforoldplants.Anotherdrawbackofscrubbersisthatlargequantitiesofsludgeandlow-gradegypsumareproducedduringthescrubbingprocess,creatingdisposalproblems.
EnhancingConservation.Energyconservationhasbotheconomicandenvironmentalbenefits.Modernizingofexistingplantsandinstallingequipmenttorecoverwasteheatforre-usetogeneratesteamorasprocessheatareenergyconservationoptionsthatalsoreduceemissionsofpollutants.Identifyingtheappropriateoptionsanddeterminingtheireconomicandenvironmentalbenefitsrequireamajorstudyofexistingfacilities,butthenecessaryinvestmentsarerelativelymodestandthebenefitssubstantial.
TappingAlternativeEnergySources.Alternativeenergysources,suchashydro,wind,solar,geothermal,nuclear,andhydrogenpowercanbesubstitutedforfossilfuels.Nuclearpowerandhydropowerarethemostcommonlyusedalternativesources.Manydevelopingcountrieshavemadesignificantprogressindevelopingtheirhydropowerelectricgeneratingcapacity.Useofnuclearpowerhasnotmademuchprogressindevelopingcountries,withthenotableexceptionofKorea.
CuttingMobileEmissions
Motortransportvehiclescontributemosttotheincreasingconcentrationofairpollutantsinmetropolitanareas.Oldandpoorlymaintainedvehicles,congestedroads,andpoor-qualityfuelsaretheprimaryreasons.Thereplacementofoldervehicleswithneweroneswithemissioncontroldevices,maintenanceofin-usevehicles,cleanerreformulatedfuels,bettertrafficmanagement,introductionorexpansionofmasstransitsystems,androadimprovementsarethebestwaystoreducesuchpollution.
ReformulatingGasoline.Theindustrializedcountrieshavedonesubstantialworkonreformulatingmotorvehiclefuels,ashavesomeofthemoreadvanceddevelopingcountries.Reformulation,however,ishighlycapitalintensive,andthe
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developmentofacost-effectiveprogramiscriticaltoensurethatresourcesareusedtomaximizeenvironmentalandeconomicbenefitswhileavoidingsecondaryproblems.
OnesuchsecondaryproblemaccompaniedtheintroductionofcatalyticconverterstoreduceemissionsofCO,HC,andNOxfrommotorvehicles,whichinturnrequiredremovaloftheleadadditivesingasolinebecauseleadinterfereswiththecatalyst.(Theinitialobjectivewastoprotectthecatalystratherthantoprotecthumanhealth.Theharmfuleffectsofatmosphericleadonlybecameanissuelater.)Tocompensateforthelossinoctaneresultingfromtheremovaloflead,oilrefineriesincreasedthelevelsofbenzeneandaromatics,which,itsoonbecameclear,werethemselvesdangeroustohealthandtheenvironment.TheEPAhasnowlimitedthelevelsofaromaticsandbenzeneingasoline,forcingrefinerstomakemajorinvestmentstocompensateforthislossinoctane.
Severallessproblematicmethodsareavailabletoboostoctane(i.e.,withoutaddingleadorbenzeneandaromatics).Forexample,moreseverereformingofnaphthaandanincreaseinthereformer'scapacitywillmakeitpossibletomeetoctanerequirements.Ifreformingaloneisinadequate,isomerizationoralkylationprocessescanbeinstalledaswell.
Thecomplexinteractionsofabatementmeasuresunderlinetheneedforcarefulappraisaloftheextentoftheproblem,especiallywhenapplyingindustrial-countrymodelstodevelopingcountries.Inmostdevelopingcountries,dieseloilconsumptiongreatlyexceedsgasolineconsumption.Sincethequantityofgasolineconsumedisrelativelysmall,theamountofleadreleasedisalsolow.Thus,unlessepidemiologicaldatashowsserioushealtheffectsfromleadorhighlevelsofleadinambientair,leadremovalmaynotbehighpriorityinmanydevelopingcountriesatthistime.Ifevidenceshowsthatleadis
asignificantproblem,however,thenitsremovalshouldreceivethehighestpriority.
AddingOxygenatestoGasoline.TheadditionofoxygenatestogasolineisnowmandatedinseveralU.S.citiesduringthewintermonths.Methyl-tertiary-butyl-ether(MTBE)istheoxygenateofchoice.MTBEprovidesadditionaloxygentocompletethecombustionprocessinadditiontoactingasanoctanebooster.TheuseofMTBEmayinvolveeitherconstructionofMTBEplantsorimportsofMTBEthatcanbeblendedintogasoline.
ReformulatingDieselOil.ThereformulationofdieseloilbyreducingitssulfurcontentwoulddecreaseemissionsofSO2andconsequentlyofsulfatesthatcontributetoSPMconcentrations.Inaddition,reductionoftheheavierhydrocarbonfractionsindieseloilbyreducingthetemperatureatwhich90volume-percentofthedieseloilisdistilledwilldecreasetheformationofparticulatesmeasuring10micronsorlessindiameter.Dieseloilreformulationisexpensive,butitshouldhavehigherpriorityindevelopingcountrieswheredieselconsumptionishigh.
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IncreasingUseofAlternativeFuels.Liquefiedpetroleumgas(LPG)andcompressednaturalgas(CNG)arecost-effectiveandenvironmentallybeneficialoptions,ifdomesticsourcesofnaturalgasandLPGareavailable.Itmayevenbecost-effectiveincountriesthatmustimportCNGandLPG.Themajorcostsarethecostsofliquefaction,regasification,andconstructionofportfacilities.Ifdemandforgascanjustifytheseexpendituresonthebasisoftheirenvironmentalbenefitsandimprovementsinthermalefficiency,CNGwillbemorethancompetitivewithdieselfuel.
End-of-TailpipeControlsandStandards.Twootheroptionsforreducingmotorvehicleemissionsareend-of-tailpipecontrols,suchascatalyticconverters,andemissionstandards.
Catalyticconverters.Twotypesofcatalyticconvertersarecommonlyinuse:oxidationortwo-waycatalysts,whichreduceCOandHCemissions;andoxidation/reductionthree-waycatalysts,whichcontrolNOxemissionsaswell.Formanydevelopingcountries,catalyticconvertersarenotahighpriority.Wherevehicleturnoverisrapid,though,catalyticconvertersshouldbeamongtheoptionsforemissionreductions.Acatalyticconverteraddsabout$600tothecostofamedium-sizedcarandsubstantiallymoreforlargervehicles.
Emissionstandards.ExperienceinOECDcountrieshasshownthatemissionstandards,ifenforced,resultinsignificantreductionsofallpollutants.Standardsmustbeestablishedfornewandin-usevehiclesindevelopingcountries,andeffectiveinspectionandmaintenanceproceduresarenecessary.Establishmentandenforcementofemissionstandardsindevelopingcountriesmaybedifficult,butwithoutthemanygainsfromfuelsreformulationorothermeasurescouldbequicklyeroded.Wherepublictransportiscommon,however,thetasksmaybeeasier.
ImprovingRoadInfrastructure.Urbanroadseverywhereareoftenso
congestedthattrafficslowstoacrawlandexacerbatesairpollution.Yetimprovingtheroadsindevelopingcountriesisoftendifficultbecausetheirmetropolitanareashaveevolvedinwaysthathamperroadconstruction.Eveniftechnicallyfeasible,suchimprovementsareoftencostlybothintermsofcapitalrequirementsandimplementationtime.Wherepossible,however,thisoptionispreferabletoanyothercapital-intensiveoption.Tominimizecosts,roadimprovementsshouldbestudiedsimultaneouslywithtrafficmanagementoptions.
TrafficManagement.Moreeffectivetrafficmanagementcaneasetrafficcongestionsignificantly.Thelargenumberofvehiclesinservice,inadequateparkingfacilities,undisciplineddrivers,frequentvehiclebreakdowns,andpoorlydesignedtrafficmanagementplanscontributetotrafficproblemsinmostcitiesindevelopingcountries.Restrictingtheuseofmainarteries,encouragingcarpools,providingincentivestousepublictransport,establishingmasstransportsystemswherefeasible(seebelow),improvingpublictransport,levyingataxoncarsenteringcitylimits,andraisingparkingfeescanallreducetheuseofautomobiles.
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Thedisincentives,suchastaxationandincreasedparkingfees,willlikelybepoliticallyunpopularandcanonlybemadepalatablebyamajorpublicrelationsefforttoeducatethecitizenryabouttheharmfulconsequencesoftrafficcongestionandairpollution.Yetwithoutatrafficmanagementstrategy,increasingmotorvehicleusewillnegateanygainsfromotherprograms.
MassTransit.Masstransitsystemsareasociallyvaluablealternativetouseofpersonalvehicles.Masstransitsystems,however,arehighlycapitalintensive,areunlikelytoyieldaprofit,andoftenmustbesubsidizedbythegovernment.Arecentstudyof20masstransitsystemsimplementedindevelopingcountriesinrecentyearsfoundthatnotonewasprofitableinpurelyeconomicterms(Allportandothers1990).However,healthbenefitswerenotfactoredintotheassessment.Whenhealthbenefitsarecounted,thereislikelytobeaneteconomicbenefit,andthiscouldprovideajustificationforstatesubsidies.
ConclusionsandRecommendations
Conclusions
Thestudyendeavorstopresenttheairqualityproblem,healthimpacts,andvalueofbenefitsandoptionsformitigatingthisproblem.Thestudyalsohighlightstheimportanceofdevelopingreliabledataonambientairquality.Inmanydevelopingcountries,thedata-gatheringsystemispoorlyfundedandthedatatendtobeweak.Epidemiologicaldataalsoarenotassembledinascientificmanner.Thus,thestatisticstodrawmeaningfulconclusionsareoftenlacking.
Developingcountrieshavebeguntoestablishairqualitystandardsonlyrecently.Mostofthemdonothaveemissionstandardsfortransportvehiclesorindustries,andmostlackinstitutionstoensurecomplianceeveniftheyhaveestablishedstandards.Finally,
environmentalregulation,compliance,andenforcementaregenerallyweakandpoorlyfunded.
Theneedtomitigatethehealthimpactsofairpollutionisincontestable,butairqualitymanagementislikelytoreceivelowerprioritythanothersocialprogramsunlessitsvalueisunderstoodbypolicymakers.Thecasestudypresentedinchapter5showsthevaluationofbenefits(andthemagnitudeoftheproblem)andunderlinesboththemethodsofvaluationandtheneedforpolicymakerstogiveairqualitymanagementhighpriority.
Thebestprogramswillensurethatenvironmentalstandards,emissionlevels,regulatorymeasures,andthelegalframeworkforenforcementandcomplianceareestablishedearlyinthedevelopmentcycle.Itisimportanttoensurethateconomicprogressdoesnotimposeunacceptablelevelsofairqualityorenvironmentaldegradation.Selectingthepropermixofoptionsandadoptingacost-,time-,andresults-orientedstrategyisfundamentaltothesuccessofanairqualityenhancementprogram.
Becauseairpollutionistheresultofmanyfactors,identifyingthefactors,selectingthemitigationmeasures,andensuringthattheseareoptimalrequiretechnical
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skillsandknowledgeofahighorder.Forexample,whentheMexicoCityairpollutionprogramwasdevelopedbytheWorldBank,Bankstaffwereassistedbyateamoftechnicalspecialistsandeconomistsfromallovertheworldandapanelwasformedtomonitortheworkofthespecialists.Theresultwasaprogramthathasnowbecomethebasisforsimilarprogramsinothercountries.
Attimes,thecostofenvironmentalmitigationmayfallmostheavilyonthesegmentofthepopulationleastabletobeartheburden.Forexample,areductionofSPMmaydictatethereformulationofdieseloil.Thecostofreformulation,ifpassedontothetransportsector,willincreasetransportationcostsparticularlyforthepoor,themostfrequentusersofbuses,andmaythereforebepoliticallyunpalatable.Insituationssuchasthese,thecostwouldhavetobepassedontothepublicasawhole,whichsuggestsataxsubsidyofsomesortaswellasfundingatconcessionaryrates.
Aneffectivemasstransitsystemcanreduceairpollutionbyreducingtrafficcongestion.Yettoassumeinfrastructuralchangesofthissortcouldbedevelopedinafewyearswouldnotberealistic.Again,ifcostsarenotknownandfinancingisunavailable,masstransitwouldonlyremainaplan.Thesameistrueoffuelsreformulation,retrofittingofvehicles,oranyotheroption.Theaboveexamplesindicatethatthedevelopmentofasuccessfulairpollutionmitigationprogramdependsonbothitstechnicalandeconomicfeasibilityanditsacceptancebythepublic.
Recommendations
TheWorldBankcanhelpdevelopingcountriesimplementfeasibleandcost-effectiveairpollutionprograms.Thisreportsuggeststhatdevelopingcountriesshouldinitiatesuchprograms,commencingwiththefollowingsteps:
Establishprogramstocollectaccuratedataonambientairquality.
Determinecurrentlevelsofvariouspollutants.
Instituteepidemiologicaldata-gatheringsystems.
Establishambientairqualitystandards.
Projectemissionlevelsintheforeseeablefuture(e.g.,15years).
Withtheassistanceofinstitutionsexpertatmodelingemissionseffectsontheambientair,projectlikelyambientconcentrationsovertheperiodselected.
Ascertainthepotentialbenefitsofreductionsofairpollutants.
Rankpollutantsinorderoftheireffectsonhealthanddevelopcost-andtime-effectiveprogramstoreducethesepollutants.
Acoordinated,comprehensiveprogramtomanageairpollutionisessentialtoensurethecost-effectivenessanddurabilityofmitigationmeasures.Airqualitymanagementprograms(AQMPs)shouldbedevelopedforeachcountryinawaysimilartothatinwhichtheEnergySectorManagementAssistanceProgramme(ESMAP)
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preparesitscountryenergystrategies.Suchacross-sectoralapproachisdesirable,asairqualitymanagementaffectstheeconomybroadly,andacoordinatedprogramcanbedevelopedonlyfromacomprehensivestudy.AcasecanbemadetojustifytheuseofUNDPorotherfundstopreparethesestudies.TheWorldBankshouldremainreadytoprovideassistancethatcountriesmayneedinthepursuitofensuringcleanair.ThetechnicalskillsandfundsrequiredtodevelopAQMPswillbesubstantial,butsowilltheultimatehealthandenvironmentalbenefits.
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1AirPollution:AGrowingProblemInbothindustrializedanddevelopingcountries,inbothurbanandruralareas,airpollutionisaseriousandgrowingproblem.InSouthAfrica'sEasternTransvaalHighveldregion,wherecoal-firedpowerstationsgenerate80percentofthecountry'selectricity,stagnantairmassesallowthebuildupofsulfurparticlesthatcometoearthinacidrain(WorldResourcesInstitute1993:420).Acidrainisresponsiblefordeadlakesinalmost7,000squaremilesofsouthernNorway(WorldResourcesInstitute1993:544)andhasaffected150,000Canadianlakes(WorldResourcesInstitute1993:576).InRiga,Latvia,emissionsfromautomobileswithoutemissioncontroldevicesaccountfor80percentofthecountry'sairpollution(WorldResourcesInstitute1993:554).ThicksmogisbecomingcommonplaceinSantiago,Chile,becauseofuncontrolledindustrialpollutionandvehicleemissions.TheamountsofsulfurdioxideintheatmosphereabovenineofIndia'stenmajorcitiesexceednationalstandards,andparticulatematterintheairabovemanyurbanregionsinIndiaexceedstheamountsfoundintheairabovecomparableregionsinNorthAmericaandEurope(WorldResourcesInstitute1993:460).
Airpollution,particularlyinurbanareas,iscausedprimarilybyproductionofelectricity,vehicularemissions,andindustrialactivities.Naturalevents,likeeruptionsofvolcanoesandforestfires,alsosendhugeamountsofcertainpollutantsintotheatmosphere.TheJune1991eruptionofMountPinatubointhePhilippines,forexample,isestimatedtohavedischarged20milliontonsofsulfateaerosolsintotheupperatmosphere,generatingconcernthatthisonslaughtmaydepletetheprotectivelayerofozoneabovethemidlatitudinalareasoftheearth(Mock1993:306307).Urbanpollution,however,islargely
anthropogenic,theresultofactivitiessuchaspassengerandfreighttransportationandtheproductionoffood,fiber,rawmaterials,andmanufacturedgoods.
Robustindustrialactivityistheeconomicbasisofallotheractivities,includingeducationandmedicalcare.Economicsuccess,however,shouldnotcomeatthecostofunacceptablelevelsofairpollution.Ifproperlyplanned,economicdevelopmentneednotresultinenvironmentaldamage.Conversely,environmentalconcernsneednotstifledevelopment.Theobjectiveofeconomicdevelopmentistoprovidethegoodsandservicesdeemeddesirabletoimprovethequalityofhumanexistence.Economic
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developmentcanbemeasured,whereasmeasurementsofthequalitiesthatcharacterizeahealthyenvironmentarestillbeingdebated.Whateverthedifficultiesofmeasurement,however,thegoalmustbeanetbenefit.
Airpollutionisnotsimplyafunctionoftheamountofpollutantsreleasedintotheatmosphere.Topography,weatherconditions,timeofday,andthekindsofpollutantsandtheinteractionsamongthemallhelptodeterminepollutionlevels.MexicoCity,forexample,liesinavalleyamonghighmountains;frequentthermalinversionstrappollutantsinthevalley(Satterthwaite1992).Ingeneral,thevolumeoftraffic,thequalityoffuel,orthemechanicaldesignofindustriesandvehiclesmaynotbesignificant,takenindividually,butaremajorcontributingfactors.Thereareclearlinkagesamongthemthatneedtobeunderstoodinordertodevelopcost-effectivemanagementofairpollution.
Theadversehealtheffectsofvariousairpollutantshavebeendocumentedinnumerousstudies.Highconcentrationsofairpollutantsinmanydevelopingcountriesleadtoincreasedillness,particularlyamongindividualssufferingfromrespiratoryproblems,andcauseprematuredeathamongtheelderly(Romieu1992).Theairpollutantsofgreatestconcernarecarbonmonoxide,hydrocarbons,sulfuroxides,nitrogenoxides,suspendedparticulatematter,lead,andsecondarypollutants,particularlyozone.Theeliminationofleadasanadditivetogasolinehashighpriority,sinceitcanhaveharmfuleffectsonthehumannervoussystem,particularlythatofchildren.Table1.1showslead'shightoxicitycomparedwithotherairpollutants.Itisestimated,forexample,thatchildrenintheBangkokmetropolitanarealoseanaverageof4IQpointsbythetimetheyreachtheageofseven,and29percentofthemhaveunhealthyamountsofleadintheirblood.Thereisacorrelationbetweenthelevelofleadingasolineandblood-leadlevels,andintheUnitedStatesandJapan,blood-lead
levelshavefallenonaveragebytwo-thirdssinceleadadditivesingasolinewerefirstreducedandthenprohibited(WorldBank1992:53).
Exposuretosuspendedparticulatematter(SPM)isanequallyseriousrisktohealth.InhalableSPM,particularlyparticleslessthan10micronsinsize,canpassthroughthenaturalprotectivemechanismofthehumanrespiratorysystem.Thesmallestparticulates(2micronsorless)arecreatedprimarilybythecombustionofpetroleumfuels.TheWorldBankestimatesthatreducingSPMtosafelevelscouldreduceprematuredeathsby300,000to700,000ayearindevelopingcountries(WorldBank1992:52).
Theconcentrationofpollutantsinambientairincreaseswithratesofurbanizationandenergyuse.Airpollutioninsomeofthenewlyindustrializeddevelopingcountriesisworsethanintheindustrializedcountries.Thisisbecauseindustriesindevelopingcountriesoftenuseoutdatedtechnologyandbecausemostvehiclestherelackemissioncontrols.Strategiesforairqualityprotectionshouldthereforebeinplaceascountriesdevelop.Figure1.1illustratestheconsequencesofapathy.Theareabetweenthesolidanddottedlinesrepresentstheconcentrationofairpollutantsthatcouldhavebeenavoidedifairpollutioncontrolmeasureshadbeenimplementedinatimelymanner.
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Althoughtheeconomiesofmanydevelopingcountriesaregrowing,thisgrowthneednotbefollowedbyadeclineinairquality.Inmanydevelopedcountries,emissioncontroldeviceshavebeguntocauseadeclineinseverepollutantlevels;similardeclinesinpollutantlevelscanbeeffectedinthedevelopingcountriesaswell.
Figure1.1RelationshipBetweenLevelofDevelopmentandAirQuality
Source:UNEPandWHO(1992).
Airpollutionmanagementprogramsareintendedtokeepairpollutantsbelowthelevelsthatwoulddamagetheenvironmentorharmthehealthofhumans.Iftheambientconcentrationofapollutantiswellbelowpermissiblelevels,theneedtocontrolemissionsofthepollutantmaynotbeurgentunlessepidemiologicaldatastronglyindicateotherwise.Anall-encompassingairpollutionmanagementprogramshouldincludeclearlydefinedobjectivesthatwouldmeetambientairqualitystandards,theidentificationofallairpollutantsandtheirsources,thelevelsofpollutantsintheambientair,andthetypesofpollutantsthatareatriskofexceedingpermissiblelevels.
Unfortunately,dataoftherequiredqualityareseldomfoundindevelopingcountries,whichoftendecideonthebasisofpoordatathatpollutionisnotaproblem.Developingascientificdatabaseandestablishingpermissiblepollutantlevelscouldtakethreetofiveyearsinmostdevelopingcountries.Theremay,however,besomepollutantsthatarealreadyatpotentiallydangerouslevels.Thus,projectstoreduceconcentrationsofsuchpollutantsshouldbestartedassoonaspossibleandneednotawaitthedevelopmentofacompletescientificdatabase.
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Thecollectionofascientificdatabase,establishmentofrealistictargets,anddevelopmentofacomprehensiveprogramrequireastronginstitutionalandlegalframework.Implementatingaprogramwillrequirethemonitoringofactivitiesinallsectorsoftheeconomytoensurethatfacilitieswithanti-pollutiondevicesaredesigned,built,andoperatedcorrectly.
Table1.1ApproximateToxicityWeightingFactorsforSelectedPollutantsPollutant RelativeweightLead 85NOx 4.7PM10 2.3VOCs 1.8SOx 1.4Dust 0.9CO 0.04
Note:PM10=particulatematterof10micronsorlessinsize.VOCs=Volatileorganiccompounds.Source:1992WorldBankdata.
Thegovernmentsofmanydevelopingcountriesoftencomplainaboutthestringentindustrialemissionstandardsstipulatedbymostinternationalagencies,includingtheWorldBank,asaconditionforprojectassistanceandfinancing.Thecostofpollutionabatementdeviceshassometimespreventedtheimplementationofotherwiseeconomicallyrobustprojects.Developingcountriesoftenarguethatthetotalvolumeofaparticularpollutantemittedeitheronacountrywideorregionalbasisisfarlowerthaninthedevelopedcountriesandthatstringentstandardsshouldbeappliedonlywhenthetotalvolumeofaparticularpollutantemittedfromallsourceswillresultinambientconcentrationsexceedingpermissiblelevels.
Ineffect,thesecountriesarearguingfortheadoptionofecologicallybasedemissionstandardsforindustrialplants.Establishingecologicallybasedemissionstandardspresupposesacceptanceoftheconceptofcriticalpollutantloadsbycalculatingtheseloadsforeachcountry.Forlarge
pollutantloadsbycalculatingtheseloadsforeachcountry.Forlargecountries,criticalpollutantloadsmighthavetobecalculatedonanarea-by-areabasis.Thisimpliesthatdevelopingcountriescouldadoptlessstringentstandardsthanindustrializedcountriesunlessepidemiologicaldataindicatedthataparticularpollutantwasalreadycausinghealthproblems.Thisconceptmustbeappliedwithcaution,however.Ifacountryisindustrializingrapidly,morestringentstandardsmustbeadoptedinanticipationofhigheremissions.
Pursuingeconomicdevelopmentwithoutregardtoitsenvironmentalconsequencesisunacceptable.Itislesscostlytomakeincrementalinvestmentsinstate-of-the-arttechnologynowtocontrolpollutionthantomakefurtherinvestmentslater,if
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thoseinvestmentsarelikelytobeneededinthenot-too-distantfuture.However,thecostsoftheseinvestmentsmustbereasonable,andthelikelyimpactofthisspendingonothersectorsmustbetakenintoaccount.Medicalfacilitiesandservices,food,education,transportation,andothersocialservicesneedtobeprovidedaswellascleanair.Abalancemustbestruckbetweenwhatisdesirableandwhatisachievable.Crucialtothedevelopmentandimplementationofanyprojectistheabilitytofinanceit.Financingisunlikelytobeavailablefrominternationalagenciesunlessenvironmentalmitigationmeasuresarebuiltintotheproject.Environmentalimpactassessments,whicharenowaprerequisiteforWorldBankprojectappraisal,ensurethatnecessarycontrolmeasureswillbeincludedinprojects.
Technology-andpolicy-basedoptionsneedtobeidentifiedearlyinthecycle.Discussionofthetechnologicaloptionswillbeintroductory,sinceadetailedreviewwouldrequiretheidentificationofalltheavailabletechnologies,thefactorsthatmustbetakenintoaccountintheestimationofcapitalrequirements,andadiscussionoftheproblemsofcost-benefitanalysis.
Whenthecostsofinvestinginairpollutionprogramsarehighandsuchinvestmentscoulddivertresourcesfromotherusefulandpopularprograms,investmentsthatcanbejustifiedineconomicandfinancialtermsunderstoodbypolicymakersaremorelikelytowinapproval.Inthedevelopingcountriesthequestionthatmustbeansweredbypolicymakersandinternationalagenciesisnotwhetheraprogramhasmeritbutwhetheritiscrucialforhumanwelfare.Suchproblemsaschildmalnutrition,polluteddrinkingwater,andhighlevelsofunemploymentwillordinarilytakeprecedenceoverprogramstocombatairpollution.Nevertheless,thebenefitsofairqualityenhancementareveryreal.Aswillbeshowninthisreport,theycanbemeasuredandshouldthereforereceivehighpriority.
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2HealthandEnvironmentalEffectsofMajorPollutants,PartI:CarbonMonoxide,Hydrocarbons,OxidesofNitrogen,SuspendedParticulateMatter,andLeadThischapterandtheonethatfollowsdiscussthepotentialhealthandenvironmentaleffectsofmajorairpollutants.Theseeffectsarediscussedtodemonstratetheneedfortheirreduction,particularlyinhigh-population-densityareasandmajorcities.Thefindingsfromseveralstudies,mainlyfromtheindustrializedcountries,arepresented,inasmuchasverylittlemeaningfulinvestigativeworkhasbeendoneonairpollutioninthedevelopingcountries.Nonetheless,thelessonsofthestudiesarehighlyrelevanttodevelopingcountries,especiallybecausetheyarenowpassingthroughsomeofthesamestagesofgrowththattheindustrialcountrieshavetraversedpreviously.
CarbonMonoxide
Effects
Inhalationofcarbonmonoxide(CO)byhumanbeingshasdetrimentaleffectsonhealth.TheamountofharmdependsontheconcentrationofCOandthedurationofexposureandiscausedbythespecialaffinityofhemoglobininthebloodforcarbonmonoxideabout240timesthatofitsaffinityforoxygen(Romieu1992).Carbonmonoxideformsastrongcoordinatebondwiththeironatomoftheprotohaemcomplexinhemoglobintoproducecarboxyhemoglobin(COHb).COHb,inturn,reducestheamountofavailableoxygenneededinthebloodtocarryoutnormalbodilyactivities.Hence,morebloodneedstobepumpedtodeliverthesameamountofoxygen,resultingin
strainontheheart.COHblevelsofapproximately1.2to1.5percentarefoundinanormalpopulation.Intraffic-congestedareas,however,elevatedconcentrationsofCO(20to30mg/m3,or17to26ppm)arefoundintheambientair,andthiscanleadtoequilibriumCOHbbloodlevelsof3percent,comparabletothe3to4percentCOHbfoundincigarettesmokers(Romieu1992).Table2.1givestheexpectedlevelsofCOHbinthebloodatdifferentconcentrationsofCO.
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Table2.1PredictedCOHbBloodConcentrationsforSubjectsEngagedinDifferentTypesofWork
COconcentration PredictedCOHblevel(%)forthoseengagedinppm mg/m3 Exposuretime Sedentarywork Lightwork Heavywork100 115 15minutes 1.2 2.0 2.850 57 30minutes 1.1 1.9 2.625 29 1hour 1.1 1.7 2.210 11.5 8hours 1.5 1.7 1.7
Note:ppm=partspermillion;mg/m3=milligramspercubicmeterSource:Romieu(1992).
Ingeneral,thosewhoexerciseheavilyoutdoorsorworkoutdoorsaremorepronetosuffertheeffectsofelevatedCO.TheclassicsymptomsofCOpoisoningarerevealedatlevelsabove10percentCOHb.Betweenthelevelsof10and30percent,thesesymptomsareheadacheanddizziness.Atlevelsabove30percent,thesymptomsaresevereheadache,cardiovasculareffects,andmalaise.Thechancesofcomaanddeathareheightenedwhenthelevelexceeds40percent(Romieu1992).ThesefindingsseemtobeinaccordwiththesignsandsymptomsofCOHbshowninTable2.2(Watkins1991).Otherstudies,however,indicatethatdrowsiness,impairedperceptionandthought,andslowedreflexesoccuratlevelsof5to10percent(Adams1990).AccordingtoWatkins(1991),theconcentrationsinTable2.2aremuchhigherthanthoseusuallyexperiencedbyroadusersorothersexposedtovehicleexhaustfumes.However,otherstudiesindicatethatparkingattendantsandtrafficpoliceshowincreasedratesofchronicrespiratoryandcardiacdisorderslinkedtoCOexposure(Adams1990).ThereisnodoubtthatCOisfatalwheninhaledatveryhighconcentrations,andheartdiseasepatients,pregnantwomen,infants,seniorcitizens,andthoseespeciallysusceptibletorespiratoryproblemsmayexhibitsymptomsofCOpoisoningatlowerpercentagesofCOHbthanindicatedinTable2.2.Concentrationshigherthan9ppm,forexample,mayincreasetheprobabilityofanginaattacksfortheestimated5to7millionpeople,aprevalencerateof3percent,intheUnitedStateswhoareatrisk(Krupnik
prevalencerateof3percent,intheUnitedStateswhoareatrisk(Krupnik1991:13).
AlthoughstudieshavebeenconductedtodeterminethehealtheffectsofCOatvariousambientlevels,thedataneededtodeterminedose-responsefunctionsaccuratelyhavenotbeencollected.VariousempiricalequationshavebeenproposedrelatingconcentrationsofCOinambientairtotheformationofCOHblevelsinblood.Mostrelationshipsseemtobelinear,atleastinitially,andthenreachanequilibriumconcentrationofCOHbafterexposureoflongduration(seeFigure2.1).AccordingtotheWHO(1979:90),analyzingCOlevelsinairandCOHblevelsinbloodshouldnotberegardedasalternativemethodsofmonitoring,sinceitisnoteasytoestimatetherelationshipbetweentheCOlevelinambientairandCOHblevelinbloodbecausethe
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concentrationofCOanddurationofexposureareinfluencedbycomplexfactorsthatis,weatherconditions,trafficdensity,ageandstateofrepairofthevehiclefleet,thetypesofemissioncontrolequipmentandenforcement,highwaydesign,timeofday,andlevelofventilationwillallaffecttheconcentrationofambientCOatanyparticularlocationandthereforethecorrespondinglevelsofCOHb.Congestedstreetsandconfinedspacessuchastunnelsandparkinggarages(particularlythosewithinadequateventilation)arelikelysitesforhighconcentrationsofCO,whereaswidestreetswithfree-flowingtrafficareunlikelytohaveunsafeCOaccumulations.Dispersionfactorsmayalsoplayaroleindiscrepanciesinthedatagatheredatmonitoringstations.NumerousstudieshaveindicatedthatthelevelsofCOandotherairpollutantsinsidemotorvehiclesandalongroadsidesaretypicallyhigherthanthelevelsrecordedsimultaneouslyatfixed-sitemonitors.Thissuggeststhatpeopleinmotorvehiclesareatmostrisktoairpollutants,followedbypedestriansandstreetvendors,andthenbythegeneralurbanpopulation,sincelevelsofmotorvehiclepollutantsdeclinewithincreasingdistancefromroads(Flachsbart1992).
Table2.2SignsandSymptomsofIncreasingCOHbLevelsinanAverageAdultCOHb(%)
Signsandsymptoms
010 None1020 Tightnessacrosstheforehead,possibleslightheadache,dilationofthe
cutaneousbloodvessel2030 Headacheandthrobbinginthetemples3040 Severeheadache,weakness,dizziness,dimnessofvision,nausea,
vomitingandcollapse4050 Sameasabove,greaterpossibilityofcollapse,syncope(fainting)and
increasedpulseandrespiratoryrates5060 Syncope,increasedpulserate,coma,intermittentconvulsions,and
Cheyne-Stokesrespiration6070 Coma,intermittentconvulsions,depressedheartactionandrespiratory
rate,andpossibledeath7080 Weakpulse,slowrespiration,respiratoryfailureanddeathwithinafew
hours8090 Deathinlessthananhour90+ Deathwithinafewminutes
Source:Watkins(1991).
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Figure2.1UptakeofCObyBlood,aDose-ResponseCurve
Note:ThistypicalCOdose-responsecurvehasbeenderivedfromobservationsmadebyForbesandothers(1945).ActualCOHblevelinanyindividualmayvaryconsiderablyfromthatpredictedinthisfigure,
dependingonprevailingconditionsanddurationofexposure.Source:WHO(1979:91).
Typically,ambientCOstandardsareaveragedover8hours.Thisisbecauseittakesapproximately4to12hoursforCOHblevelstoreachequilibriumwithambientCOlevels(UNEPandWHO1988).TheUnitedStatesandWHOhavestringentCOstandards(9ppmor10mg/m3)foran8-hourperiod.Theseconcentrationsmayseemtoostringent,sincetheexpectedcorrespondingCOHblevel(basedonamodelbyCoburnandothers1965)appearstobeapproximately1.5percentforsubjectsatrestand1.7percentforthoseengagedinheavyphysicalwork(WHO1979:119),andaccordingtosomestudies
wouldhavenonoticeableeffectonthegeneralpopulation.Itshouldbeborneinmind,however,thattheseguidelinesaredesignednotonlytogivethegeneralpopulationanadequatemarginofsafetybutalsotoprotectthosewhoareparticularlysusceptible.AstudybytheGlobalEnvironmentalMonitoringSystem(GEMS),usingarelativelysmallsampleof20cities(predominantlyinindustrialcountries),foundthatapproximatelyhalfwereviolatingtheWHO8-hourguideline(UNEPandWHO1988).
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ManyurbancitiesindevelopingcountriesprobablyexceedtheWHOCOguidelineaswell,althoughthedataneededtoprovethisdonotexist.
Sources
PetroleumfuelsusedinmotorvehiclesarethelargestcontributorsofCOemissions(seeBox2.1).Forexample,between1940and1970theU.S.motorvehiclefleetincreasedrapidly.Carbonmonoxideemissionsduringthesameperiodrosefrom73milliontonstoapproximately100milliontons(WHO1979:23).ThisincreaseinCOemissionsinparallelwiththeincreaseinnumberofvehiclesmayhaveresultedprimarilyfromlackofstringentemissioncontrols.Evenwithemissioncontrolsinplace,thetransportsectorremainsthemajorsourceofCOemissionscausedbyanthropogenicactivities.Approximately90percentoftheCOintheurbanenvironmentsofmanycountriesisattributedtomobilesources(Romieu1992).COcanalsoaccumulateindoorsinacuteorfataldosesfromtheuseofcoal,gas,oroilforcookingorinheatingappliancesthataremaladjustedandinadequatelyventedtooutsideair.
Box2.1ChemicalNatureofCarbonMonoxide
Carbonmonoxide(CO)isacolorless,odorless,tastelessgasthatisslightlylessdensethanair.Incompletecombustionofcarbon-containingfuelsproducescarbonmonoxide,andtheprincipalsourceisemissionsfrommotorvehicles.Intheory,allthecarbonatomsinfuelareconvertedtocarbondioxide(CO2)ifenoughoxygenispresentintheair/fuelmixtureinthecarburetorofamotorvehicle:
Ifthefuelmixtureistoo''rich"thatis,containstoomuch
fuelandtoolittleairconsiderableamountsofCOwillbeformed:
Theoretically,theCOwillbeconvertedtoCO2intheatmosphere:
Butthisconversionisnormallyquiteslow,andCOcontinuestobeCOfor0.2to0.3yearsorfortwoorthreemonths.
Note:(l)=liquidphase;(g)=gasphase.
Source:Mastersonandothers(1985:534).
Table2.3summarizestheoutlookforworldwideCOemissionsfortheperiod1980to2005.Theseestimatesassumemoderateeconomicgrowthgloballyandrisingoilprices.Basedontheseestimates,totalworldwideCOemissionsareexpectedtobeonlyslightlyhigherin2005thantheywerein1980.The57percentprojecteddeclineinCOemissionsfromtheOECDtransportsectorfrom1980to2005istheprincipalfactorlimitingtheoverallincrease.ThetransportsectorwillremainthemajorsourceofCOemissions,however,especiallyintheOECDcountries.COemissionsinboththecentrallyplannedeconomies(CPEs)andthedevelopingcountriesarealsoontherise.As
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Table2.3SummaryofCOEmissionsOutlook,19802005Risingoilpricecase(103metrictonsofCOperyear)
Region 1980 1986 1995 2005OECDsummaryElectricitygeneration 1243(1%) 1346(1%) 1721(2%) 2136(1%)Industry 1170(1%) 1024(1%) 1000(1%) 1150(1%)Residential/commercial 13827(8%) 12317(9%) 9860(9%) 8487(11%)Transport 152427(90%) 127508(89%) 99198(88%) 64783(84%)Transformation 565(0%) 507(0%) 475(0%) 382(0%)Total 169232(100%)142702(100%) 112254(100%) 76938(100%)CPEsummaryElectricitygeneration 897(2%) 1042(2%) 1302(2%) 1863(2%)Industry 1247(3%) 1294(2%) 1484(2%) 1864(2%)Residential/Commercial 31944(64%) 31968(60%) 32104(51%) 33230(42%)Transport 15429(31%) 18622(35%) 27951(44%) 40960(52%)Transformation 92(0%) 350(1%) 452(1%) 658(1%)Total 49609(100%) 53276(100%) 63293(100%) 78575(100%)DevelopingcountrysummaryElectricitygeneration 203(0%) 332(0%) 568(0%) 1082(1%)Industry 341(0%) 424(0%) 562(0%) 769(0%)Residential/commercial 99711(68%) 86046(59%) 93468(53%) 96741(45%)Transport 46440(32%) 58589(40%) 80024(46%) 11571(54%)Transformation 111(0%) 165(0%) 273(0%) 400(0%)Total 146806(100%)145556(100%) 174895(100%) 21463(100%)WorldsummaryElectricitygeneral 2343(0%) 2720(1%) 3591(1%) 5081(1%)Industry 2748(1%) 2742(1%) 3045(1%) 3783(1%)Residential/commercial 145483(40%) 130331(38%) 135432(39%) 138458(37%)Transport 214296(59%) 204719(60%) 207173(59%) 220913(60%)Transformation 768(0%) 1022(0%) 1200(0%) 1439(0%)TOTAL 365648(100%)341534(100%) 350441(100%) 369674(100%)Note:Duetorounding,somepercentagesmaynotaddupto100.Source:OECD/IEA(1991:147-48).
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thevehicularpopulationsofCPEsanddevelopingcountriesincrease,theshareofworldCOemissionsfromOECDcountriesisexpectedtodeclinefromthe46percentof1980to21percentin2005,whilethedevelopingcountries'shareisexpectedtorisefrom40percentto58percentandtheCPEsharefrom14percentto21percent.Thesechangesareprimarilyattributabletodifferencesinemissioncontrolpoliciesinthethreegroups.SimilardifferencesaffectednationalemissionsofCOduringthe1970s.COemissionsfrommotorvehiclesroseinFinland,France,Sweden,andSwitzerlandintheearly1970s,andtheUnitedKingdomsawanincreaseinCOemissionsovertheentiredecade.Meanwhile,theUnitedStatesandCanadaevidencedadeclineinCOemissionsresultingfromtheearlycreationandenforcementofstringentemissionstandards(Holdgateandothers1982:520).
Inlinewiththeobservationthatdevelopmentneednotworsenenvironmentalquality,itisworthnotingthatanincreaseinvehicledensitydoesnotnecessarilyleadtoanincreaseinCOemissionswhenemissionstandardsandenforcementofemissioncontrolsareeffective.Astudydonein1980tomeasureCOconcentrationsinsidevehiclesonasuburbanhighwayinCaliforniafoundthataverageCOconcentrationswere51percenthigherthanwhenvehiclesonthehighwaywereresurveyedin1991bythesameresearchersusingasimilarmethodology.Theresearchersattributedthedeclinetothereplacementoftheoldervehiclefleetwithnewermodelshavingloweremissionfactors,anditwasparticularlysignificantthatthedeclinewassosubstantialeventhoughvehicledensityonthehighwayhadincreasedby17percentduringthesameperiod(Flachsbart1992).
Unfortunately,thevehicleturnoverrateindevelopingcountriesislow,andthevehiclesnowontheroadaregenerallyolderandhavenopollutioncontroldevices.Undersuchcircumstances,anincreaseinvehicledensityisboundtoincreasetheconcentrationofambientCO.
Sincevehicleinspectionandmaintenanceprogramsarenotwelldevelopedindevelopingcountries,itisalsomorelikelythatdangerousorevenlethalconcentrationsofCOmayaccumulateinsidemotorvehiclesbecauseoffracturesinexhaustsystemsorothermechanicaldefects.Furthermore,thestop-and-gotrafficthatisthenorminurbancentersindevelopingcountriesmayaggravateexposuretoCOemissions,whicharehighestwhenanengineidlesanddecreasewithincreasingenginespeed(seeBox2.2).
Hydrocarbons
ChemicalNatureandEffects
Hydrocarbons(HCs)areorganiccompoundsconsistingmainlyofcarbonandhydrogen.Straight-chaincompoundsareknownasaliphatics;thosewithacyclicstructureareknownasaromatics.Hydrocarbonsareprecursorstoozoneformation.Aromatics(particularlybenzene,whichimprovestheoctanevalueofgasoline)alsopromotetheformationofnitrogenoxides.Whenhydrocarbonsinteractwithnitrogenoxidesinthepresenceofsunlight,ozoneistheresult.Athighconcentrations(100to
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Box2.2TheTrafficPoliceofJaipur,India
Adarkzoneofblacksmokehangsabovetheground,acommonsightinJaipurCityduringthelateeveningandearlymorninghours.Thesmokehasbeenattributedtoanincreasingrateofvehicularpollution.ArandomcheckoftheambientairqualityofJaipurCitybytheDepartmentofEnvironmentinRajasthanrevealedthattheamountsoflead,carbonmonoxide(CO),sulfurdioxide(SO2),nitrogenoxides(NOx),andsuspendedparticulatematter(SPM)overa24-hourperiodwereabovethelimitsconsideredacceptablebytheWorldHealthOrganization.Itisestimatedthat90percentofthepollutioniscausedbyvehicularemissions.
Inordertoassesstheimpactofmotorvehicleemissionsonhumanbeings,astudywasconductedusingonehundredtrafficpoliceconstables.Theconstablesareexposedcontinuouslyforperiodsof6hoursormoretoemissionsfromvehiclesidlingatintersectionswithelevatedconcentrationsofCOandHC.SO2emissionsattheseintersectionsarealsosubstantial.
Thestudyrevealedthat94percentoftheconstablessufferedfromsomesortofphysicaldisorder.Eyeirritation,itchingskin,nasalcongestion,fatigue,coughs,lossofappetite,"burning"sensations,and"tenderness"intheabdomenwerecommoncomplaints.Respiratorydifficultiesanddigestiveproblemswerealsonumerous.Themoststartlingrevelationwasthehighincidence(55percent)oftuberculosisamongconstablesbetween20and30yearsold.
Whatmakesfindingsliketheseparticularlydisturbingis
thatthemajorityofIndia'surbanpoorlivebytheroadside,andtrafficintersectionsaretheplaygroundsofpoorchildren.
Source:Sinha(1993).
1,000timesthelevelsinambientair),hydrocarbonscauseminorirritationofmucosaandhaveageneralnarcoticeffect.BenzeneisclassifiedbytheU.S.EnvironmentalProtectionAgency(EPA)asahumancarcinogenbecauseofitslinktoadultleukemia.Concentrationsofbenzeneshouldbekepttomuchlessthan1ppm.Theothervolatilearomatichydrocarbonswithmethylsidechainsarenotconsideredtobecarcinogenicormutagenic.Formaldehydeisashort-termrespiratoryandskinirritantandmaybeacarcinogen.Individualvariabilityinsusceptibilitytotheharmfuleffectsofformaldehydeislarge,butmanypeopleinworksituationsshowsensitivitywhenexposedto500to3,000microgramsformaldehyde/m3.Thethresholdlevelisreportedtobeaslowas12micrograms.Astudyontheeffectsofformaldehydefoundthat120microgramsofformaldehyde/m3wasthethresholdlevelforhumanperceptionofitsodorandforirritationofeyes,nose,andthroat,whereas600microgramscausedlachrymation(tearing)and1,200microgramscausedrhinorrhoea(runnynose)anddrythroat(Suessandothers1985:97101).
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SourcesofHydrocarbons
Coalandpetroleumarethetwolargestorganicsourcesofaromaticcompounds.Petroleumisthemainsourceofbenzene,toluene,andxyleneusedinthechemicalindustryandintheproductionofhigh-octanegasoline.TheU.S.decisiontoeliminateleadedgasolinegraduallyatthebeginningofthe1980sandcompetitionforhigheroctanelevels(above91)resultedinaphenomenalincreaseinthelevelsofbenzeneandaromaticsingasolinebetween1979and1989.Figure2.2depictstheincrease.
Figure2.2TheDramaticRiseofAromaticsinU.S.GasolinePool,197989
Source:HyOx,Inc.,ofFallbrook,California,inOxy-FuelNews(1990).
Anywherefrom1to5percentofthecontentofmarketedgasolineconsistsofbenzene.Asgasolineismovedfromtherefinerytothemarketplace,benzeneisemittedintotheatmosphereatbulkgasolineterminals,depots,andservicestationsandfromtanktrucks.Itisalsoemittedwhengasolineispumpedintomotorvehicles(AlcoholOutlook1990).Thelargestsourceofatmosphericbenzene,however,ismotorvehicles.TheEPAstatesthat70.2percentofallbenzeneemissionscomefromvehicles.Ofthatfigure,70percentcomesfrom
motorvehicleexhaustpipesand14percentfromevaporation(Sinhaandothers1990).
Straight-chainoraliphatichydrocarbons,suchasaldehydes,areemittedbybothgasoline-anddiesel-fueledvehicles.Gasolineproducesfromabout0.6to2.3g/laldehydes,anddieseloil1to2g/l.Some50to70percentofallmotorvehicleemissionsareformaldehyde.Table2.4showsthecontributionoftheroadtransportsectortototalhydrocarbonemissionsin14cities.ExceptinOsakaandSeoul,theycontributedmorethan50percent.
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Table2.4ContributionofRoadTransportSectortoTotalHCEmissionsinSelectedCities
Region Year %HCMexicoCity 1987 89SãoPaulo 1981 83
1987 76Ankara 1980 73Manila 1987 82KualaLumpur 1987 95Seoul 1983 40Athens 1976 81aGothenburg 1980 89aLondon 1978 94LosAngeles 1976 61a
1982 50Munich 1974/75 96Osaka 1982 17Phoenix 1986 64aPercentsharesapplytoalltransport.Motorvehiclesaccountfor75to95percentofthetransportshare.Source:AdaptedfromWorldResourcesInstitute(1992:196).
OxidesofNitrogen
Effects
GenerallyexpressedasNOx,oxidesofnitrogenincludeNO(nitrogenoxide),N2O(nitrousoxide),andNO2(nitrogendioxide)(seeBox2.3).Nitrogenoxidesintheatmospherereducevisibility,helptoformacidaerosols,contributetoglobalwarming,andactascatalystsinthedecompositionofozoneintheupperatmosphere.Nitrogenoxidesalsocanformozonethroughinteractionwithhydrocarbonsinthepresenceofsunlight.Nitrogendioxideisarespiratoryirritantthatalsocausesirreversiblelungdamagetopersonsexposedtoitforlongperiodsof
time.Otherilleffectsincludechesttightness,burningoftheeyes,andheadaches.Peoplewithasthmaareparticularlyvulnerabletotheseeffectsandtobronchitis.RecurrentexposuretohighconcentrationsofNO2ismoredamagingthanconstantexposuretolower-levelconcentrations.
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Box2.3ChemicalNatureofNitrogenOxides
Oxidesofnitrogenareproducedduringtheburningoffuelsinaninternalcombustionengine.Nitrogenoxideiscreatedfirst;itthencombineswithmoreoxygentoformnitrogendioxide.Noticeableamountsofnitrogenoxideareproducedbythefollowingreaction:
Inurbanair,NOisconvertedtoNO2:
OxidesofnitrogenoftencontributetothegenerationofacidrainthereactionofNO2withwatervaporinairformsnitricacid(HNO3):
AcidrainfallinthewesternUnitedStatesisattributedmainlytonitricacid.
Note:(g)=gasphase;(l)=liquidphase;(aq)=aqueousphase.
Source:Mastersonandothers(1985:515-46).
Sources
Bacterialactioninthesoil,volcaniceruptions,andlightningarethemajorsourcesofatmosphericNOx.Althoughsuchnaturalphenomenageneratemuchlargeramountsofoxidesofnitrogenthananthropogenicsources,naturalemissionsofNOxarenotsignificantintermsofharmtotheenvironmentbecausetheycomefromsourcesallovertheglobeandgenerallyproducenegligibleconcentrationsinthe
air.Therelativelyminorroleofnaturalsourcescanbeseeninthefactthatnaturalconcentrationsofnitrogendioxideabovelandareasrangefrom0.4to9.4microgramspercubicmeter,whereasaverageannualmeanconcentrationsinurbanareasworldwidearesome20to90microgramspercubicmeter(WorldBank1988:218).
Theprincipalsourceofnitrogenoxidecreatedbyhumanactivityistheinternalcombustionengine,althoughthecombustionoffossilfuelsinhomesisalsoasource.Oxidesofnitrogenalsoareemittedbyplantsmanufacturingexplosives,fertilizer,andglass;inironorepreparationplants(sinteringandpelletizing);andatpetroleumrefineriesandelectricpowerstationsthatburnfossilfuels.
Table2.5summarizesexpectedNOxemissionsintheworldfortheperiod1980to2005.ThetransportsectorwillcontributethemajorshareofNOxemissions,withgenerationofelectricityaclosesecond.InbothdevelopingandOECDcountriesthetransportsectorcontributesthelargestshareofNOxemissions,whereasthegenerationofelectricityyieldsthemostNOxemissionsinCPEs.Itisestimatedthatwhereastransport-relatedNOxemissionsfromOECDcountrieswilldeclinefrom63percentto40percent,thedevelopingcountries'sharewillincreasefrom19percentto35percentandtheCPEs'sharewillrisefrom18percentto24percentoverthisperiod.
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Table2.5SummaryofNOxEmissionsOutlook,19802005BilliongramsofNOx
Region 1980 1986 1995 2005OECDsummaryTransport 20352(50%) 19828(52%) 19366(54%) 18244(52%)Residential/commercial 2082(5%) 1977(5%) 1915(5%) 1891(5%)Industry 5304(13%) 4040(11%) 3545(10%) 3288(9%)Electricitygeneration 11566(28%) 10623(28%) 9994(28%) 10617(30%)Othertransformation 1706(4%) 1415(4%) 1063(3%) 782(2%)
Total 41010(100%) 37883(100%) 35883(100%) 34822(100%)CPEsummaryTransport 5644(24%) 6231(24%) 8959(27%) 11056(25%)Residential/commercial 2666(11%) 2920(11%) 3308(10%) 3774(9%)Industry 4606(20%) 4726(18%) 5347(16%) 6794(15%)Electricitygeneration 9790(42%) 11023(42%) 13615(41%) 19381(44%)Othertransformation 561(4%) 1593(6%) 2130(6%) 3314(7%)
Total 23267(100%) 26493(100%) 33359(100%) 44319(100%)DevelopingcountrysummaryTransport 6196(48%) 7750(48%) 11853(49%) 16075(45%)Residential/commercial 2236(17%) 2106(13%) 2615(11%) 3088(9%)Industry 1536(12%) 1766(11%) 2365(10%) 3194(9%)Electricitygeneration 2271(18%) 3633(23%) 6071(25%) 11455(32%)Othertransformation 644(5%) 852(5%) 1349(6%) 1948(5%)
Total 12883(100%) 16107(100%) 24253(100%) 35760(100%)WorldsummaryTransport 32192(42%) 33808(42%) 40178(43%) 45375(39%)Residential/commercial 6984(9%) 7003(9%) 7838(8%) 8753(8%)Industry 11446(15%) 10532(13%) 11257(12%) 13276(12%)Electricitygeneration 23626(31%) 25279(31%) 29679(32%) 41453(36%)Othertransformation 2910(4%) 3860(5%) 4542(5%) 6045(5%)
TOTAL 77158(100%) 80482(100%) 93494(100%) 114902(100%)Note:Duetorounding,somepercentagesmaynotaddupto100.Source:OECD/IEA(1991:149-50).
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Box2.4HarvardSixCitiesStudy
Studiestodeterminetheassociationbetweenairpollutionandmortalityrateshaveoftenbeencriticizedongroundsthattheinvestigatorsdidnotdirectlycontrolforotherfactors,suchastobaccosmoking.Theconsistentfindingsobtainedfromawell-characterizedcohortofadultsbytheHarvardSixCitiesStudysuggestthatthecriticismhaslimitedvalidityatbest.
DatafortheHarvardstudywereobtainedfrom8,111adultsinsixcitiesintheUnitedStates,commencingin1974andconcludingin1991.Theobjectofthestudywastodeterminetheeffectsofairpollutiononmortalitywhilecontrollingforseveralriskfactors,includingtobaccosmoking;sex;age;educationlevel;andoccupationalexposuretodust,gases,andfumes.Dataonambientconcentrationsoftotalsuspendedparticulatematter,sulfurdioxide,ozone,andsuspendedsulfateswereobtainedforeachcommunityfromacentrallylocatedairmonitoringstation.
Theinvestigatorsfoundthatairpollutionhadsignificanteffectsonmortalityrateswhentheycontrolledfortheabove-mentionedriskfactors.Astatisticallysignificantassociationwasfoundbetweenfineparticulateairpollutionanddeathsfromcardiopulmonarydisease,andlungcancer.Theinvestigatorsconcludedthattheirconsistentfindingsprovidedanadditionalreasontoreduceurbanairpollution.
ThefindingsofthestudytookonglobalsignificancewhentheGlobalEnvironmentalMonitoringSystemoftheUnitedNationsestimatedthat70percentofthe
world'surbanpopulationlivesincitieswherethelevelofsuspendedparticulatesexceedsWHOguidelines.
Source:Dockeryandothers(1993:175359,1807);andGEMS,WHO,andUNEP(1987:47).
SuspendedParticulateMatter
ChemicalNatureandEffects
Particulatematteristhenameforabroadarrayoffinelydividedsolidsorliquidsthatmaybedispersedintotheairbycombustionprocesses,industrialactivities,ornaturalevents.Thenatureoftheparticulatesvariesdependingontheirsource.Particulatescanrangeindiameterfromlessthan0.1micrometers(µm)to1,000µmorso.Particulatessmallerthan10µmarereferredtoassuspendedinhalableparticulates;particulates2.5µmorsmallerareknownasfineparticulates.
Suspendedparticulatesthatmeasure10micronsorlessremainintheatmospherelongerthanlargerparticlesandaresmallenoughtobeinhaleddeeplyintotherespiratorytract.Hence,particulatemattercancontributetorespiratoryillnesses,withthetoxiceffectdependentonthechemicalnatureoftheparticulateandongasesthatmaybeadsorbedonparticulatesurfacesorabsorbedwithinparticulates(seeBox2.4).Particulatesintheatmospherealsoreducevisibility.
Sources
Largerparticlescomeprimarilyfromsoilandothercrustalmaterials,whereasfineparticulatescanbecombinationsofsoot,acidcondensates,andsulfateandnitrate
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particles.Respirableparticlesinurbanareasoftencontainlead,othermetals,organiccompounds,sulfuricacid,andothersulfates.However,thereisnosharpdividinglinebetweensmallerandlargerparticulates,sinceeventhelargerparticulatescanbefoundintheairundercertainconditions.
Naturalsourcesofparticulatematterincludevolcanicactivity,duststorms,forestfires,strongwindsblowingoverdrysoil,andpollenfromtreesandflowers.Combustionoffuelsforheatingandpowergenerationinindustrialprocessesandforpoweringmotorvehiclesalsogeneratesparticulates.Particulatescontainingleadcompoundsareemittedfromtheexhaustsofvehiclesthatuseleadedgasoline.Theblacksmokeofdieselvehiclesalsocancontainsubstantialamountsofparticulatematter;infact,uncontrolleddieselenginesemitsome30to70timesmoreparticulatematterthanvehiclesequippedwithcatalyticconvertersandusingunleadedgasolineasfuel(Sinhaandothers1990).
AstudyconductedbytheGEMSnetworkontheglobalspreadofparticulatepollutionovertheperiod198084foundthatparticulateemissionsin37of41citieseitherexceededorcameclosetoexceedingWHOguidelinesforparticulates(French1990:11).Nearly1.4billionurbanresidents,mostlyindevelopingcountries,maybeexposedtoairwithborderlineorunacceptableamountsofparticulates.Althoughtheselevelswerepartiallyattributedtonaturaldust,themainoffenderswerediesel-fueledvehicles,whichmaygenerate10timesmoreparticulatesthangasolineengines,andmotorscootersequippedwithtwo-cycleengines.AccordingtotheWHOandtheUnitedNationsEnvironmentProgramme,oneineveryfivepersonsintheworldisexposedtoexcessiveconcentrationsofparticulatematter.Table2.6liststenofthecitiesthatexceededtheWHOguidelineofanannualmeanof60to90µg/m3forparticulatematter.AnnualmeanconcentrationsofparticulatesinKuwait,New
Delhi,andBeijingexceededWHOguidelinesbyasmuchasfivetimes(French1990:1112).
Lead
Effects
Atpresentregulatoryagenciesandhealthorganizationshavenotreachedafirmconsensusonthemaximumpermissibleconcentrationofleadintheblood.Evenso,thegroupshaveallloweredtheamountofleadconsideredtocauseleadpoisoningasnewinformationabouttheneurologic,reproductive,andpossiblehypertensiveeffectsofleadtoxicityhasbecomeavailable.Currently,theWorldHealthOrganizationsuggeststhatalevelof20microgramsofmetalperdeciliterofblood(20µg/dl)isthemaximumacceptableconcentration.Otherstudiesconsiderthatthedetrimentaleffectsofexposuretoleadappearatconcentrationsofbetween10and15µg/dl(Correa1989:2).Itisnotnecessary,however,tohavebeenexposedtomajordosesofleadtocontractleadpoisoning.Thebodytendstoaccumulateleadoveralifetimeandcanreleaseitonlyslowly.Hence,evenexposuretosmallconcentrationsofleadoveralongperiodcan
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Table2.6SuspendedParticulateMatterinVariousCitiesBetween1980and1984City Annualmeana(µg/m3) Daysabovestandardb(peryear)
Kuwait 603 N/ANewDelhi 405 294Beijing 399 272Tehran 245 174Jakarta 231 173Bangkok 197 97KualaLumpur 130 37Zagreb 127 34RiodeJaneiro 114 11Lisbon 104 12Note:µg=1×10-6gm.aWHOannual-meanstandardis6090µg/m3.bWHOdailystandardis230µg/m3.Citiesareinviolationofthestandardwhentheyexceeditmorethansevendaysperyear.Source:French(1990).
produceharm.Itisthetotalbodyburdenofleadthatisrelatedtotheriskofadverseeffects(AgencyforToxicSubstancesandDiseaseRegistry1992:6).
Theprimarypathwaysofexposuretoleadareinhalationandingestion.Onceinhaledoringested,inorganicleaddoesnotundergobiologictransformation.Thisisincontrasttoorganiclead,whichentersthebodythroughinhalationorskincontactandisthenmetabolizedintheliver.Theprimarysourceoftheorganicformistetra-alkyl-leadadditivesingasoline.Irrespectiveofthemodeofexposure,however,thebiologicoutcomesarethesame:normalcellfunctionandanumberofotherphysiologicprocessesaredisrupted.Chieflyaffectedareperipheralandcentralnervoussystems,bloodcells,andthemetabolismofvitaminDandcalcium.
Lead'sdetrimentaleffectshavemoresevereconsequencesforchildrenthanforadults(seeBox2.5).Increasingmedicalevidenceshowsthatlead
thanforadults(seeBox2.5).Increasingmedicalevidenceshowsthatleadatrelativelylowlevelsinthebloodcanharmthementaldevelopmentofchildrenandthattheharmfuleffectspersistintoadulthood.Thedevelopingnervoussysteminchildrencanbeaffectedadverselyatblood-leadlevelsoflessthan10µg/dl(AgencyforToxicSubstancesandDiseaseRegistry1992:8).Neurologicdeficitsaswellasothereffectscausedbyleadpoisoningmaybeirreversible.Effectsonchildrengenerallyoccuratlowerconcentrationsthaninadults.Figure2.3showsblood-leadlevelsassociatedwithspecifichealtheffectsinchronicallyexposedchildrenandadults.
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Acuteexposuretoleadcanhaveharshoutcomes,insomecasesendingindeath.Severetoxicityisoftenassociatedwithblood-leadlevelsof70µg/dlorhigherinchildrenand100µg/dlorhigherinadults(AgencyforToxicSubstancesandDiseaseRegistry1992:12).Atlevelsof80µg/dl,poisoningofthecentralnervoussystemcanoccur,causingconvulsions,coma,anddeep,irreversiblementalretardation.Functionalchangesintheperipheralnervoussystemandanemiacanalsooccuratthatlevel.Alaginthetransmissionofnervesignalsfromthebraintotherestofthebodyhasbeenobservedatlevelsbelow40µg/dl(Correa1989:2).
Otherscientificstudieshavedemonstratedthatleadisalsolinkedtohighbloodpressureandmaysignificantlyincreasetherisksofheartattacksandstrokesinadults.Leadalsocausesreproductivetoxicity.Maternalleadstorescaneasilybetransmittedtothefetusthroughtheplacenta,therebyplacingthefetusatgreatriskofsufferingreductionsingestationalage,birthweight,andmentaldevelopment(Romieu1992).
Ithasbeendeterminedthatthelevelsofleadingasolinearecorrelatedwithlevelsinthebloodstreamofthepopulation.Between1972and1984theconsumptionofleadadditivesingasolinedeclinedandwasfollowedbyadecreaseinleadconcentrationsinambientair.Thischange,inturn,hadstrikingeffectsontheblood-leadlevelsoftheU.S.population(Shy1990).Figure2.4depictsthecorrelation:aparalleldecreaseinblood-leadlevelsasthequantityofleadusedingasolinedecreased.Thepresentaverageblood-leadconcentrationintheU.S.populationisbelow10µg/dl;itaveraged16µg/dlbeforethelegislatedremovalofleadfromgasoline(AgencyforToxicSubstancesandDiseaseRegistry1992:14).Figure2.5givesblood-leadlevelsofpersonsincitiesinseveralcountries.Peopleincountriesthatstilluseleadedgasoline,onaverage,havehigherleadcontentintheirblood.
Sources
Metalsmelters,batterymanufacturingplants,andleadedgasolinearetheleadingsourcesofairbornelead.Althoughthedetrimentaleffectsofleadonhumanhealthhadbeenknownforalongtime,itwasnotwidelyrealizedthatgasolinewasamajorsourceofleadintheairuntilthemid-1970s.Althoughleadingasolineaccountsforonlyabout10percentofallrefinedleadproducts,itisnowunderstoodtoaccountfor60percentofanthropogenicleademissions(possibly90percentincitieswithhightrafficcongestionandvehicleswithoutadequateemissioncontrolsystems).
Gasolineisnowconsideredbyfarthegreatestcontributortoairborneleadintheindustrializedworld(GEMS,UNEP,andWHO1988).Nearlyalltheleadaddedtogasolineisreleasedtotheatmosphereatsomepoint.Theorganicformstetra-ethyl-lead(TEL)ortetra-methyl-lead(TML)arereleasedintotheair,principallyasinorganicleadsaltsandoxidesinaerosolform.Only1percentoftheleadingasolineisemittedunchangedasTELorTML.Leadparticlesremainsuspendedinairforlongdurationsbeforesettling.Theymayalsobedepositedinthesoilandcontaminatefoodandwater.Thus,leadcanbeinhaledfrommotorvehicleemissionsoringestedthroughfoodandwater.
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Figure2.3EffectsofInorganicLeadonChildrenand
AdultsLowestObservableAdverseEffectLevelsSource:AgencyforToxicSubstancesandDiseaseRegistry(1992).
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Figure2.4CorrelationBetweenLevelsofLeadinGasolineandin
BloodstreamSource:Shy(1990).
Figure2.5
LeadPollutioninSelectedCitiesSource:UNESCAP(1992).
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Box2.5TheEffectsofLead
About10percentoftheleaddischargedbymotorvehiclesisdepositedwithin100meters(0.6miles)ofroadsidesareasfrequentlyoccupiedbychildrenatplayindevelopingcountries.Onlyafewstudieshavebeenconductedindevelopingcountriesontheeffectsofleadonchildren'shealth,however.Thesestudies,conductedbytheWHO,revealthatchildrenindevelopingcountrieshaveabody-leadcontentthreetimesthatfoundinchildrenintheUnitedStates,Japan,orWesternEurope.Althoughthereisincreasingevidenceoflead'sharm,amajorityofthedevelopingcountriescontinuetouseleadedgasoline.
AstudyconductedinmetropolitanManila(JimenezandValasquez1989:55)foundconcentrationsofleadinbloodsamplesfrom544infantsandchildrenbetweentheagesof4monthsand14yearstobesufficienttowarrantconcern.Theaverageleadlevelinthesampledpopulationwas22.8µg/dl,withapproximately8percentofthechildrenhavinglevelsgreaterthan30µg/dl.Theselevelsareconsideredtobehighenoughtohavedetrimentaleffectsonthechildren(seeFigure2.3).Thestudyalsofoundasignificantcorrelationbetweenhighleadlevelsinthebloodandproximityofthehouseholdtodensetraffic.
Thenegativeeffectsofleadareenduring.Astudythatmeasuredtotalbody-leadburdeninprimaryschoolchildrenwithhightooth-leadlevelsbutwithnoknownhistoryofleadpoisoningfoundthatthechildrenhadlowintelligencescoresandattentionspans,poorspeechand
languageskills,andpoorclassroomperformancecomparedwithchildrenhavinglowerconcentrationsoflead.Afollow-upreportonchildrenwithelevatedlevelsofleadintheirteethfoundasevenfoldincreaseinfailuretograduatefromhighschool,greaterabsenteeism,morereadingdisabilities,anddeficitsinvocabulary,finemotorskills,reactiontime,andhand-eyecoordination11yearslater.Theseobservedeffectsarebelievedtohavebeenasignoftheenduringtoxicityofleadratherthanofexcessiveacuteexposure,sincetheblood-leadlevelsoftheyoungadultswerelessthan10µg/dl(AgencyforToxicSubstancesandDiseaseRegistry1992:9).
Anotherstudy(Satterthwaite1993:93)conductedbetween1979and1981andinvolvingadultvolunteersin10citiesaroundtheworldrevealedthattheblood-leadlevelsofMexicoCityresidentswerethehighestandexceededWHOguidelines.Furthermore,theblood-leadlevelsweretwotofourtimesthoseofresidentsofcitieswherelow-leadandunleadedgasolinewereused.Sincematernalleadstoresreadilycrossthroughtheplacenta(AgencyforToxicSubstancesandDiseaseRegistry1992:2),itisnotsurprisingthata1988studyrevealedthatmorethan25percentofnewborninfantsinMexicoCityhadblood-leadlevelshighenoughtoimpairneurologicalandmotor-physicaldevelopment(Satterthwaite1993:93).
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3HealthandEnvironmentalEffectsofMajorPollutants,PartII:GreenhouseGases,SulfurOxides/AcidRain,Ozone,andChlorofluorocarbonsTwenty-fiveyearsagoitwasthoughtthatairpollutionwasaproblemonlyinpopulouscitiesoftheindustrializedregions.Itisclear,however,thatairpollutionisnowamajorprobleminurbanareasofthedevelopingworldaswell.Thischapterlooksbrieflyatsomeregionalandglobalairpollutionproblemsthegreenhouseeffect,depletionoftheozonelayerintheupperatmosphere,andacidrainthathavereceivedincreasingattentionsince1970.
CarbonDioxideandtheGreenhouseEffect
Theaccretionintheatmosphereofcarbondioxide(CO2),nitrousoxide(N2O),methane(CH4),ground-levelozone(O3),andchlorofluorocarbons(CFCs)hasledtoglobalwarming.Thesegasesabsorbinfraredradiation(IR)fromtheearth,ineffectactingasaninsulatingblanketpreventingheatfromescapingtheearth'satmosphere,causinga''greenhouseeffect."Approximately50percentofglobalwarmingisattributedtoCO2.CFCsareresponsibleforabout20percent,methaneforabout16percent,andground-levelozoneforabout8percent;nitrousoxideaccountsformostoftheremaining6percent(Tétrault1992:48).CFCs,CH4,O3,andN2OabsorbinfraredradiationmoreeffectivelythanCO2,andcollectivelytheirheat-trappingabilitymayequalthatofCO2.
Areportpreparedbyagroupof200scientistsfrommorethan24countriesknownastheIntergovernmentalPanelonClimateChange(IPCC)concludedthatcontinuedproductionofCO2andother
greenhousegasesatcurrentlevelswouldcauseadoublingoftheirpreindustrialconcentrationsby2050.Thepanelalsoconcludedthattheaverageplanetarytemperaturewouldriseby3°Cbytheendofthetwenty-firstcentury,andtheearth'ssurfacetemperaturewouldthenbeapproximately18°C(64°F);thecurrentmeanglobaltemperatureattheearth'ssurfaceisabout15°C(59°F).Thismaybecontrastedtoanormforglobaltemperaturechangesof1to2°Coveraspanof1,000to10,000years,anditmaybesignificantthatittookariseofa"mere"5°Ctobringtheearthoutofthelasticeage(Tétrault1992:48).Hence,thecurrentrateofchangeintheearth'stemperaturemaywellbecauseforalarm.
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Table3.1summarizestheincreaseingreenhousegases.Acenturyago,theCO2concentrationintheatmospherewaslessthan300,000ppb(300ppm).Thecurrentconcentrationis354,000ppb(354ppm)andisexpectedtodoubleearlyinthetwentyfirstcentury(GraedelandCrutzen1990).AccordingtoSilver(1993:314)atmosphericCO2hasincreasedby25percentsincethebeginningoftheindustrialrevolution,morethan200yearsago.
Givenacontinuationofthecurrentrateofincreaseof0.4percentperyear,CO2couldhavesignificantadverseimpactsontheworld'sclimate.Theseeffectsmightincludeshiftsinclimaticzones,changesinrainfallpatterns,moreextremeweatherconditions,andariseinsealevel.Suchchangeswouldseriouslyaffectlifeinmostcountries.Ifglobalwarmingincreasesuncheckedthepolaricecapsmayshrink,causingtheoceanleveltoriseby5or6meters.Mostcoastalcitiesworldwidecouldbeaffected.Itisalsocontendedthatever-largerconcentrationsofCO2willhaveadirecteffectonfarmsandforestseveniftheydonotelevateworldtemperatures.Plantswouldgrowatanacceleratedrate,buttheirqualitywouldbepoor.Plantlifewouldcontainfewernutrients,andplantswouldharborincreasednumbersofinsects,whichwouldconsumemoreleaves.Ultimately,plantswoulddecomposemoreslowly,anditwouldtakelongerfortheirnutrientstoberestoredtothesoil(EnvironmentalUpdate1990).
Deforestationandthecombustionofcoal,oil,andnaturalgasinjectbillionsoftonsofcarbonintotheatmosphereeachyearandareresponsiblefortheincreaseinCO2.Fossilfuelstodaygenerateapproximately20billiontonsofCO2annually,andincreasesinvehicleusesuggestthatwithoutstrictemissioncontrolsCO2emissionswillcontinuetogrow.Between300and400poundsofCO2aregeneratedduringcombustionofthecontentsofasinglestandard(16gallon)tankofgasoline.Ithasbeenestimatedthatmotorvehiclesemitalmost15percentoftheworld'sCO2emissions(DeLuchiand
others1988).In1986,themobilesector,withapproximately25percentoftotalCO2emissionsintheOECDcountries,wasthesecondlargestcontributortoCO2emissions.Thissectorisexpectedtoaccountfor26percentinOECDcountriesin2005(OECD/IEA1991:48).Landclearing,cultivationofricepaddies,livestockproduction,andincreaseduseoffertilizers(Tétrault1992)alsocontributetoglobalwarmingbycausingtheaccumulationofmethaneandnitrousoxide.
Themostrecentavailabledataarefrom1989(WorldResourcesInstitute1992:208)andindicatethattheUnitedStatesandtheformerSovietUnion(FSU)arecurrentlythelargestandsecondlargestemitters,at18percentand14percent,respectively,ofgreenhousegases.TheEuropeanCommunityranksthird,at11percent.Indescendingorderbycountry,thelargestgreenhousegasemittersaretheUnitedStates(17.8to18.4percent),FSU(13.5to13.6percent),China(8.4to9.1percent),Japan(4.7to5.6percent),India(3.5to4.1percent),andBrazil(3.8to3.9percent).Together,thesecountriesaccountformorethan50percentofcurrentemissions.Itisworthnotingthatthreeofthesecontributorsaredevelopingcountries.
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Table3.1IncreaseinGreenhouseGasesConcentrationinatmosphere(ppb)
Gas
Majoranthropogenic
sources
Totalannualanthropogenic
emissions(millionsoftons)
Averageresidenceinatmosphere(years)
Average100yearsago
Current(approx.)
Projectedinyear2030
CO2 Fossilfuelcombustion,deforestation
5,500/~5,500
100 290,000 350,000 400,000to
550,000CH4 Ricefields,cattle,
landfills,fossil-fuelcombustion
300to400/550 10 900 1,700 2,200to2,500
N2ONitrogenousfertilizers,deforestation,biomassburning
6/25 170 285 310 330to350
CFCsAerosolsprays,refrigerants,foams
~1/1 60to100 0 About3(chlorineatoms)
2.4to6(chlorineatoms)
Note:ppb=partsperbillion;CO2=carbondioxide;CH4=methane;N2O=nitrousoxide;CFCs=chlorofluorocarbons.Source:AdaptedfromGraedelandCrutzen(1990).
Asdevelopingcountriesindustrialize,theiremissionswillrisesteeplyandmaycompoundenvironmentalproblemsunlessthesecountriesactinconcertwithorfollowtheleadofindustrializedcountriesinlimitingemissions.
SulfurOxidesandAcidRain
SourcesofSulfurOxides
Thelargestshareofsulfuremissionsfromhumanactivitiestakestheformofsulfurdioxide(SO2)andcomesfromtheburningofcoalandpetroleumproducts,petroleumrefining,andnonferroussmelting(seeBox3.1fora
products,petroleumrefining,andnonferroussmelting(seeBox3.1forabriefexplanationofthechemicalmakeupandbehaviorofsulfuroxidesaspollutants).LargemetropolitanareaswithheavydailyenergyproductionandindustrialactivitytendtohavesubstantialSO2thataccumulateinthelocalatmosphereanddisperseonlyslowly.AstudywasconductedbyGEMS/Air(GEMS,UNEP,andWHO1988:1620)overtheperiod198084todeterminethelevelsofSO2intheambientairof54citiesworldwide.ThestudyfoundthatwhereashalfthecitieshadacceptableSO2levels,theotherhalfhadeithermarginal(20percent)orunacceptable(30percent)SO2levelswithreferencetoWHOannualaverageguidelinesof4060mg/m3.Datafromthe54-citystudywasextrapolatedtoincludeapopulationof1.8billion,andanapproximationofthetotalglobalurbanpopulationatriskforSO2wasobtained.Thisapproximationrevealedthatwhereas625millionpeopleliveinurbanareaswithaverageSO2levelsthatarewithinWHOannualguidelines,upto1.2billionurbanresidentsliveinareaswheretheairqualityforSO2is
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eithermarginal(550millionresidents)orunacceptable(625millionresidents).Furthermore,nearlyone-fifthoftheworld'spopulation(975million)areestimatedtoliveincitieswheretheshort-termWHOguidelinesof100150mg/m3limitfor98percentofdailyaveragesisexceededmorethan7daysayear.
Box3.1TheChemicalNatureofSulfurOxides
Sulfurdioxideisacolorlessgasthatcanbedetectedbytastebymostpeopleatconcentrationsintherangeof1,000to3,000microgramspercubicmeter(0.35to1.05ppm).Itspungent,asphyxiatingodorbecomesapparentatconcentrationsaboveabout10,000microgramspercubicmeteror3.5ppm.Mostfossilfuelscontainsulfurinfreeorcombinedform.Mostofthesulfurandsulfurderivativesreleasedtotheairaretheproductsofcombustionprocesses.Sulfurcompoundsreactwiththeoxygenpresentinairtoformoxidesofsulfur,whichareprecursorstoacidrain.Muchofthesulfurdioxidepresentinairisconvertedtosulfurtrioxide:
Sulfurdioxideandsulfurtrioxidereactwiththewatervaporinairtoformdilutesulfurous(H2SO3)andsulfuric(H2SO4)acids:
Thesediluteacidsareformedhighintheatmosphereandmaybecarriedbyprevailingwindsasfaras1,000milesbeforefallingtoearthasacidrain.Sulfurpollutantscanalterawholeecosystemwhentheyfalltoearthasacid
rain.
Note:(g)=gasphase;(aq)=aqueousphase.
Source:Mastersonandothers(1985:515-46).
Table3.2providesdataonSO2concentrationsinselectedcitiesintheGlobalEnvironmentMonitoringSystems(GEMS)network(UNEP1991).Thedataarebasedontheannualmeanconcentrationsfortwoyears,withthetotalnumberofobservationsduringeachtwo-yearperiodshowninparentheses.Althoughmanymonitoringstationsmadedailyobservations,somemadethemlessfrequently(e.g.,onceeverysixdays),andthusthedatavaryincompletenessandmustbeinterpretedwithsomecaution.
Mostofthecitiesshowedagradualameliorationinairquality.Severaldevelopingcountries,however,reportedaworseningtrend.Ironically,concentrationsofSO2incitiesinlow-incomecountriesinthelate1970swere,onaverage,lessthanthoseincitiesofhigh-incomecountries.The1980s,sawareversal,however,asSO2concentrationsdeclinedincitiesofmiddle-andhigh-incomecountriesbutroseinthecitiesoflow-incomecountries(WorldBank1992:53).Thisshiftmayhavebeentheresultofthewealthiercountries'adoptionofmorestringentregulationofthesulfur
Table3.2ConcentrationsofSO2atSelectedGEMS/AirSites,198089(mg/mAnnualmeanconcentration(numberofobservations)
Country City Site 198081 198283 198485 198687 198889U.S. NewYork SR
CCRCCI
40.0(728)70.5(725)50.5(726)
35.0(716)64.6(730)47.0(723)
31.0(725)61.0(724)45.0(729)
27.0(361)a52.0(364)a40.0(350)
Brazil SãoPaulo CCRCCM
120.0(729)127.0(723)
97.0(728)99.0(723)
62.0(727)60.0(725)
54.5(120)73.0(120)
55.0(61)50.0(61)
China Beijing SICCCSRCCR
38.0(104)a66.0(113)a6.0(93)a98.0(110)a
60.5(365)101.5(374)15.0(349)147.0(368)
79.0(76)a130.0(86)a27.0(80)a161.0(78)a
61.5(297)112.5(326)28.5(324)125.0(293)
53.5(336)103.0(351)29.5(326)114.5(330)
Guangzhou SRCCRCCCCCI
38.0(104)a66.0(113)a117.0(76)a12.0(55)a
60.5(365)101.5(374)93.5(349)14.5(333)
79.0(76)a130.0(86)a67.5(336)113.0(317)
61.5(297)112.5(326)59.5(345)122.0(333)
53.5(336)103.0(351)58.5(353)135.5(354)
Shanghai CCICCRCCC
23.0(88)a52.0(87)a65.0(85)a
52.5(341)69.0(354)57.5(355)
49.0(86)a84.5(353)51.0(358)
40.5(357)98.0(351)77.5(358)
55.5(338)104.0(294)69.0(343)
Shenyang CCRCCICCCSI
29.0(73)a136.0(72)a72.0(72)a27.0(72)a
130.5(288)238.5(288)130.5(288)46.0(287)
135.0(288)320.0(288)58.0(72)a17.0(72)a
115.5(290)223.0(288)134.0(288)49.0(288)
70.0(288)207.5(288)101.5(288)29.0(276)
Xian SRCCRCCCSI
22.0(98)a108.0(119)a160.0(120)a46.0(117)a
30.0(383)118.0(396)104.5(397)66.5(394)
29.5(313)100.5(324)120.5(323)52.0(321)
31.0(276)118.0(289)92.5(288)66.5(287)
37.0(252)97.5(288)95.5(286)79.5(288)
Iran Tehran CCCSISR
169.5(172)137.5(154)140.0(160)
145.5(122)161.5(135)111.0(125)
97.5(115)87.5(94)47.5(98)
90.0(49)120.5(31)45.5(33)
211.0(42)149.0(28)81.5(30)
Japan Tokyo CCCSRCCI
42.0(719)40.0(722)48.5(724)
25.5(719)37.0(726)31.0(724)
24.0(731)31.0(727)31.0(731)
20.5(730)21.5(729)29.5(730)
19.0(360)18.0(366)26.0(366)
Thailand Bangkok SR 14.0(155) 18.0(310) 14.0(166) 14.5(1210) 13.0(190)Poland CCC 39.0(577) 40.5(583) 62.5(565) 35.0(488) 53.0(564)
Poland CCCCCICCR
39.0(577)27.5(583)31.5(558)
40.5(583)34.5(563)31.0(527)
62.5(565)48.5(547)44.0(522)
35.0(488)26.0(445)32.0(446)
53.0(564)34.5(542)40.0(506)
Spain Madrid CCCSRCCI
111.5(578)46.0(653)113.5(310)
80.5(566)33.5(654)91.0(208)a
47.5(499)27.5(582)
50.5(667)25.5(680)
31.5(663)17.5(658)
Yugoslavia Zagreb CCCSRCCI
87.5(671)41.5(730)41.5(731)
85.0(716)42.5(712)53.0(705)
104.5(727)64.5(694)75.0(721)
110.0(703)63.0(725)73.0(679)
82.5(694)44.0(637)102.0(698)
Note:=notavailable.;CCC=citycentercommercial;CCI=citycenterindustrial;CCM=citycentermobile;CCR=citycenterresidential;SI=suburbanindustrial;SR=suburbanresidential.aBasedononeyearofmeasurementonly.Source:AdaptedfromUNEP(1991).
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contentinfuels(seechapter4),conservation-basedenergypolicies,andashiftfromoiltosulfur-freeenergysourcessuchasnaturalgasandnuclearenergy(OECD/IEA1991).ItisalsopossiblethatthebuildingoftallersmokestacksindevelopedcountrieshassimplydispersedSO2emissionsfurtherafield.
Untilrecently,acidrainwasfoundonlyinthenorthernhemisphere.Butasdevelopingcountrieshaveexpandedtheirindustrialbasesandusedmorefossilfuel,acidrainhasalsoappeared.RecentdatashowthreateninglevelsofsoilacidityinpartsofBrazil,Colombia,Venezuela,India,SoutheastAsia,Japan,andChina.SoilsthathavebecomeacidicfromlandclearingandbiomassburninghavealsobeendetectedeveninpartsofunindustrializedAfrica(Tétrault1992).
EffectsofSO2andAcidRain
Anestimated1billionormorepeopleworldwideareexposedtounhealthylevelsofatmosphericSO2(WorldBank1992:53).Clinicalstudiesusinghumansubjectshavefoundthatchildrenandbothhealthyandat-riskadultsarevulnerabletoSO2emissions,dependingonhealthstatus,individualsensitivity,andactivitylevel.Individualswhosufferfromchronicrespiratorydiseasessuchasbronchitis,emphysema,andasthmamayexperiencecoughinganddifficultiesinbreathingwhentheSO2concentrationrisesfrom0.1to0.2ppm.Ithasbeendocumentedthatasthmaticsareupto20timesmoresensitivetoatmosphericSO2thanhealthyadults(U.S.Congress1987).AcuterespiratorydiseasesareamajorprobleminbigcitiessuchasShanghai,wherehousingiscrampedandalackofzoningrestrictionsplaceslargenumbersofpeopleindwellingsadjacenttoindustrialplantsthatemithighlevelsofSO2.Thecity'sairqualityproblemsareattributedtoits91,000industrialboilersandtoitshouseholdstoves,whichburn25milliontonsofcoalayear.GEMShasrecordedSO2levelsinShanghaiatoraboveWHOguidelines,and
thelevelsmaywellbetwiceashighasrecommendedinareasnotmonitoredbyGEMS(UNEPandWHO1992:33).SO2pollutionisalsomeasurablyaffectingthehealthofarmyinducteesinPoland.ChronicbronchitiswasfoundtobethreetimesasprevalentininducteesatarmyrecruitmentcentersincitieswithelevatedconcentrationsofSO2thanatcentersincitieswithcleanerair(WorldResourcesInstitute1993:546).
SO2isaprimarycomponentofaciddepositionanddamagestheecosystembothdirectlyandindirectly.Thedirectharmisseeninfoliage,particularlycropplantssuchaswheat,barley,oats,whitepine,cotton,alfalfa,buckwheat,andsugarbeets,whichcanbeseverelyinjuredbySO2concentrationsofaslittleas0.3ppm.SO2alsodisruptsecosystemsindirectlythroughacidificationofsoilsandsurfacewaters.ThesynergisticeffectofSO2andlowlevelsofozoneornitrogenoxidescausessevereinjurytoplants.ThisisevidentinEurope,whereforestshavesuffereddramaticallysincethe1970s.Accordingtoarecentanalysis,about75percentofEurope'scommercialforestshavebeenaffectedbySO2.Thecostsofforestdiebackscanrangefromdecreasedrevenuesfromsmallertimberharvestsandsubsequentlossestowoodmanufacturingindustriestoscarringofrecreationalareasandparks(WorldResourcesInstitute1992:208).
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BarrenlakesthroughouttheworldrevealtheindirectdamagethatcanbecausedbySO2.Theconcentrationofhydrogenionsinacidrainis5to100timesthatindistilledwater.Whenacidrainfallsinareaswherethebedrockisgranite,orwhereothermaterialispresentthatisincapableofneutralizinghydrogenions,itisespeciallyinjurious(U.S.Congress1987).Astheconcentrationofacidgrowsinlakes,marinelifefromalgaetobrooktroutdies,leavingaclearbutbarrenbodyofwater.IntheUnitedStates,lakesinNewYork'sAdirondackmountainsandinthemountainsofnorthernNewEnglandareendangeredbyannualdepositsofasmuchas4metrictonsofsulfuricacidpersquarekilometer.Morethan200sterilelakescanbefoundintheAdirondacksalone,allofthemvictimsofacidrain.InEurope,heavilyindustrializedregionsareprimarysourcesofacidrain.Inadditiontothelocaldamagetheycause(seeBox3.2),SO2emissionscanwreakhavocondistantecosystems.Morethan50percentofthesulfurdepositioninFinlandisattributedtoemissionsfromothercountries.EmissionsfromCentralEuropeandtheU.K.havealsoacidifiedsome7,000squaremilesoflakesinsouthernNorway(WorldResourcesInstitute1993:544).
Box3.2SO2andEffectsofAcidRainintheCzechRepublic
SulfurdioxideemissionsandacidrainhavecausedseveredamagetotheenvironmentandthepopulationintheCzechRepublic.
EnergyconsumptionintheCzechRepublic(whichpartedcompanywiththeSlovakRepubliconJanuary1,1993)isquitesubstantialandhasbeentheleadingcauseofenvironmentalharmsinceWorldWarII.Oneofthekeyproblemsisthattheprimaryfossilfuelislignite(browncoal),whichhasaverylowcaloriccontentanda
highsulfurcontent(5to10percent).Ligniteisstripminedprimarilyinasmall(2,500km2)regionofthecountry,NorthernBohemia,thatishometo500,000inhabitants.Theregionharborsthecountry'shighestconcentrationofcoal-firedpowerplantsandproduces45percentofallSO2and40percentofnitrogenoxideemissionsfortheentireCzechRepublic.
OnlyafewforestsintheRepublicremainhealthy;thousandsofhectaresoflandhavebecomebarrenfromthedailyonslaughtofacid.InNorthernBohemiaandsurroundingareasinparticular,thesoilissoacidic(pHof4.3to2.3)thatitisunabletosupportlifeofanykind.Withthedemiseofforests,soilerosionisinevitable.
DecreasedlifeexpectancyinsomeareasoftheCzechRepublichasbeenattributedtothedetrimentaleffectsofSO2pollution.InNorthernBohemia,theaveragelifespan(foraman,65.4years;forawoman,73.3years)istwoyearslessthanthecountry'saveragelifeexpectancy.Moreover,thepeopleofNorthernBohemiasufferfrombronchitisandotherdiseasesoftheupperrespiratorytractandallergiesatrates260and300percenthigher,respectively,thantheCzechRepublic'spopulationasawhole.
Source:Havlicek(1993).
SO2emissionsalsohavedamagedEurope'sheritageofoutdoorsculptureandarchitecture.SmoghangsoverAthens;theSO2inthesmogcanturnmarbleandotherstoneintogypsumthatiswashedawaybyrain.Greece'soutdoormonumentsand
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statues,includingthepricelessruinsontheAcropolis,havebeenpockedanddiscoloredbythischemicalreaction.Moredamagehasbeendoneinthe20thcenturythaninthepreceding2,000years.AcidicparticlesalsothreatenstonemonumentsinItaly.Morethan8milliontouristsvisitGreeceeachyear,andabout50millionvisitItaly(WorldResourcesInstitute1993:532,540).Damagetohistoricartifactsandbuildingscouldproduceadecreaseintourism,followedbyadeclineintheireconomies.
Ozone
Ozoneisabluishgaswithapungentodorthatispresentintheatmospherefromtheearth'ssurfaceuptoatleast100km.Dependingonitsconcentrationanddistancefromtheearth'ssurface,ozonecanhaveeitherharmfulorbeneficialeffectsontheenvironmentandonthehealthofindividuals.Ozonefoundneargroundlevel(within10to15kmoftheearth)isreferredtoastroposphericozoneandcomprisesapproximately10percentofatmosphericozone.Ozonefoundataltitudesof15kmormoreisknownasstratosphericozoneandcomprises90percentormoreofatmosphericozone.
Dynamictransportofmaterialsfromthetropospheretothestratosphereandviceversaisimportanttothechemicalcompositionofbothregions.Globaltroposphericchemistryisimportanttotheoverallatmosphericbehaviorofozone,sinceprecursormolecules,suchasNO2,andsinkmolecules,suchasNOandCl,arederivedfromorremovedinthetroposphere.
Ground-LevelOzone
OzonemeasurementsnearthegroundinthemiddleandhighlatitudesoftheNorthernHemispherehaveincreasedoverthepastfewdecadesatarateof1to2percentperyear.Aslittleas0.2ppmofozoneneartheearth'ssurfacepromotestheformationofsmog.Troposphericor
ground-levelozoneisformedintheatmospherethroughacomplicatedseriesofchemicalreactionswhenitsprecursors,hydrocarbonsandnitrogenoxides,combineinthepresenceofsunlight(seeBox3.3forasimplifiedchemistryoftroposphericorground-levelozoneformation).Thereactivehydrocarbons,volatileorganiccompounds(VOCs),areproducedbyseveralsources,includingmotorvehicleemissions,evaporationofsolventsandgasoline,chemicalmanufacturing,petroleumrefining,andtoalesserdegreewastedisposalsitesandwastewatertreatmentplants.
Thenitrogenoxides(NOx)arisemainlyfromcombustionoffossilfuels.GroundlevelozoneisoneofmorethanahundredcompoundsformedwhenVOCsandNOxreactchemicallyinthepresenceofsunlight.Theresultingmixtureisknownasphotochemicalsmog.PhotochemicalsmogwasinitiallynotedinLosAngeles,butitisnowcommoninmanycitiesinEurope,Japan,SouthAmerica,andelsewhereintheUnitedStates.BrightsunnymorningswithrelativelyhighlevelsofNO2areidealforsmogformation,asarehightemperatures.Ozoneconcentrationsarelowestaroundsunrisenearzeroinmosturbanareasandreachamaximumconcentrationintheearlyafternoon.SeeFigure3.1foraprofileofdailypollutionconcentrationsinLosAngeles.Ozoneformationisaggravatedwhentemperature-inducedairinversionstrapthecomponentsthatformsmog.
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Box3.3ChemistryofTroposphericOzoneFormation
Thechemicalreactionsgivenbelowareasimplifiedversionofthecomplexseriesofchemicalreactionsthatoccurduringtheformationoftroposphericorground-levelozone.Sunlightisessentialbecauseitprovidestheenergynecessaryforthesereactionstooccur.Thephoto-oxidationofCO,CH4,andhydrocarbons(foundintheatmosphere)givesrisetoavarietyofcomplexorganicperoxyradicalsrepresentedasNitrogenoxide(NO)inairreactswiththeseperoxyradicalstoformnitrogendioxide(NO2):
Thekeystepinsmogformationisthephotodissociationofnitrogendioxide:
Theabovereactiontakesplaceattheedgeofthevisibleregionintheatmosphere(392nm).TheoxygenatomsproducedreactwithsurroundingO2moleculestoformozone:
Note:(g)=gasphase.SeeWorldMeterologicalOrganization(1985:117-50)foradetailedaccountoftroposphericchemistry.
Source:WorldMeteorologicalOrganization(1985:119,127);Mastersonandothers(1985:536-37).
Figure3.1AverageConcentrationsofNO,NO2,andO3atVariousTimesofDayinLosAngeles
Source:Mastersonandothers(1985).
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Table3.3givesthehighesthourlymaximumlevelsoftroposphericozoneinselectedcitiesaroundtheglobe.Mostofthemetropolitanareasmonitoredforozoneexceededtheshort-term(1hour)WHOguidelinesforozoneof150to200mg/m3(0.0766to0.1005ppm).
Table3.3OzoneLevelsinSelectedCities,1989Concentration
Metropolitanarea Population ppm mg/mTokyo-Yokohama 28,700,000 0.0738a 145MexicoCity 19,400,000 0.4050 793NewYork 17,400,000 0.2780 545SãoPaulo 17,200,000 0.1549 304BuenosAires-LaPlata 12,400,000 0.0560b 110bLosAngeles 11,500,000 0.3500 686Paris 10,000,000 0.1170 229Karachi 7,300,000 0.0900 176Tianjin 5,625,000 0.1900 372SanFrancisco-Oakland-SanJose 5,225,000 0.1500 294HongKong 5,175,000 0.1070 210Nagoya 4,925,000 0.0699b 131Santiago 4,700,000 0.3990 782Johannesburg 4,600,000 0.1200 235Berlin(EastandWest)d 3,940,000 0.2600 509Houston 3,225,000 0.2300 450Guadalajara 3,100,000 0.1900 372Montreal 2,950,000 0.1550 303Naples 2,925,000 0.0780b 137SanDiego-Tijuanad 2,720,000 0.2500c 489Budapest 2,575,000 0.1100 216CapeTown 2,425,000 0.1030 202Note:Highesthourlymaximumin1989orlatestavailableyearfromresponsestoPopulationCrisisCommitteequestionnaire.aAverageconcentrationfortwoyears.bMeasuresmorethan1hour.cSanDiegoonly.dInternationalcities:DataareprovidedseparatelyforSanDiego-Tijuanabutnotfor
dInternationalcities:DataareprovidedseparatelyforSanDiego-TijuanabutnotforEastandWestBerlin.Source:Camp(1990).
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HealthandEnvironmentalEffectsofOzoneandOtherPhotochemicalOxidants
Thephotochemicalreactionofhydrocarbonswithoxidesofnitrogenproducesmanyphotochemicaloxidants,mostofwhicharecolorlesstoxicgases.Apartfromozone(O3),theseincludeformaldehyde(HCHO);peroxyacylnitrate(CH3[CO]OONO2),commonlyabbreviatedasPAN;acrolein(CH2CHO);andperoxybenzoylnitrate(PBzN).TheeffectofozoneatdifferentconcentrationsisgiveninTable3.4,andTable3.5providesarecentupdateontheshort-termoracuteeffectsofozoneonhealthyindividuals.Theeffectsoflong-termorchronicexposuretoozonearepoorlydefinedandshouldbestudiedmoreintensively.ThedetrimentaleffectsofozonemayalsobecausedbythesynergiesbetweenNO2,acidsulfate,andotherphotochemicaloxidants.
Excessivelevelsofozonehavebeenfoundtobeharmfultopeople.Evenshort-termexposuretoozonecanresultincoughing,painfulbreathing,andtemporaryreductionoflungfunctionafteroneortwohoursofexercise.Repeatedexposuretoozonemayresultinretardationoflungdevelopmentinchildren,acceleratedagingofthelung,permanentimpairmentoflungfunction,andthedevelopmentofchroniclungdiseasessuchaspulmonaryfibrosis.Manyindividualsexposedtoozonesuffereyeirritationandasthmaattacks.Ozone'sprecursors,NO2andVOCs,alsoposeathreattohumanhealthandtheenvironment.NO2isarespiratoryirritant,whereasVOCsarerespiratoryandeyeirritantsandmayalsobecarcinogenic.InJuly1992,whenozoneinAthenssurpassedthedangerouslevelandNO2alsoreacheddangeroushighs,manypeoplewenttohospitalswithheartandrespiratorycomplaints(Walsh1992b:19).
Onthebasisofstudiesofthehealtheffectsofshort-term(one-hour)exposuretoozone,EPAhasconcludedthat0.12ppm(240mg/m3)is
thepermissibleexposurelevel.Butozoneconcentrationsatlevelsbelow0.12ppmhaveadverseeffectsifexposureisprolonged(about6hours;ChiltonandSholtz1989).A1991studyconductedbytheAmericanLungAssociationrevealedthathealthyyoungadultssufferedfromareductioninlungfunction,aswellaswheezing,coughing,andchestirritationwhenexposedtoozoneconcentrationsof0.08ppm(Walsh1994a:1314).Hence,thecurrentEPAstandardmaynotbelowenoughtoprotectpeoplewhoareexposedforlongperiods,andrevisionofthestandardiscontemplated.
Elevatedozonelevelsalsoaffectvegetation.Visiblesignsofexposureincludelightflecks,darkstipples,andyellowspotsorpatchesonleaves,theseareindicationsofprematureaging.OzonemayalsobecontributingtothedeclineoftreespeciesintheUnitedStates,Canada,andEurope.ThedeclineofponderosaandJeffreypinesintheSanBernardinoMountainseastofLosAngelesandthedeclineofeasternwhitepinetreesacrosstheEasternUnitedStates,forexample,havebeenattributedprimarilytoozone(OfficeofTechnologyAssessment1989).
Table3.4EffectsofOzoneatVariousConcentrationsConcentration(partspermillion)
Effectsa
0.01 Odorthreshold0.02for8hours Damagetotobaccoleavesbegins0.03for8hours Significantdamagetotobaccoleaves0.05 Noseandthroatirritationthreshold0.05for1hour Damagetotobaccoleavesbegins0.10for1hour Significantdamagetotobaccoleaves;pinetreeneedletipsburn0.05 Thresholdforeyeirritationinsensitivepeople(ambientoxidant)0.15b Eyeirritationthresholdformostpeople(ambient)0.10 Reductioninoxygenconsumptionandbloodoxygentension
(concentration)levelsinemphysemapatients0.1to0.25longterm Shortenslifespanofguineapigs0.10for8hours Definitesymptomaticeffectsinsensitivepeople0.20for3hours Decreaseofvisualacuity0.60 Coughirritationthreshold,pronouncednoseandthroatirritation1for1-1/2hour Coughing,irritation,severeexhaustion3to12forafewhours
Lethaltosmalllaboratoryanimals
Note:WHOguidelinesare0.076to0.1ppm(150to200mg/m3)for1hourexposureand0.05to0.06ppm(100to120mg/m3)for8hourexposure.aAsconcludedfromlaboratoryexperimentsutilizingozoneexceptwhereotherwiseindicated.Ambientmeasurementsarefor''totaloxidants."b0.25ppmbythephenolphthaleinmethod.Source:U.S.DepartmentofTransportation(1984).
Table3.5HumanResponsetoSingleOzoneExposureResponse Subjects Exposureconditions
510%meandecrementinFEBa
Healthyyoungmen
0.18ppmwithintermittentheavyexercisefor2hoursO3inpurifiedair0.1ppmwithmoderateexercisefor6.6hoursOinpurifiedair0.1ppmwithveryheavyexercisefor0.5hourinambientair
Healthychildren 0.1ppmnormalsummercampprogramOpurifiedair
Increasedcough Healthyyoungmen
0.12ppmwithintermittentheavyexercisefor2hoursO3inpurifiedair
Healthyyoungmen
0.08ppmwithmoderateexercisefor6.6hoursO3inpurifiedair0.12to0.13ppmheavyexercisefor16to28minutesO3inpurifiedair
Reducedathleticperformance
Healthyyoungmen
0.18ppmwithexerciseatVEbof54L/minutefor30minutes,120L/minutefor30minutesOpurifiedair
Healthyyoungmenandwomen
0.12to0.13ppmwithexerciseatVEbof30to120L/minute16to28minutesO3inpurifiedair
Increasedairwayreactivity
Healthyyoungmen
0.08ppmwithmoderateexercisefor6.6hoursO3inpurifiedair
Healthyyoungmenwithallergicrhinitis
0.18ppmwithheavyexercisefor2hoursOpurifiedair
Increasedairwaypermeability
Healthyyoungmen
0.4ppmwithintermittentheavyexercisefor2hoursO3inpurifiedair
Increasedairwayinflammation
Healthyyoungmen
0.08ppmwithmoderateexercisefor6.6hoursO3inpurifiedair
Acceleratedtracheobronchialparticleclearance
Healthyyoungmen
0.2ppmwithintermittentlightexercisefor2hoursO3inpurifiedair
aForcedexpiratorybreathing.bExpiratoryvolume.
bExpiratoryvolume.Source:AdaptedfromRomieu(1992:19).
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Upper-LevelOzone
Ozoneisbothproducedanddestroyedintheupperatmosphere(seeBox3.4forthesimplifiedchemistryofupper-levelorstratosphericozoneformation).Satellitemonitoringoftheupperatmospherehasshownthattheozonelayerataltitudesof28to35kmisbeingdepletedandthatasmuchas5percentoftheozoneatthe45kmlevelhasdisappeared.
Box3.4ChemistryofStratosphericOzoneFormation
Ozoneisproducedintheupperatmospherewhenoxygenmoleculesabsorbsolarultravioletradiation.First,oxygenatoms(O)arereleasedbythephotodissociationofmolecularoxygen(O2)byshort-wavelengthultravioletradiation(<243nm):
ThisisfollowedbyacollisionbetweenanOatomandanO2moleculetoproduceanunstablemoleculeofthreeoxygenatomsknownasozone(O3):
Note:(g)=gasphase;E=hn,whereE=energy,h=Planck'sconstant,n=frequencyoflight.SeeWorldMeteorologicalOrganization(1985:2756)foramoredetailedaccountofstratosphericozonechemistry.
Source:Mastersonandothers(1985).
Depletionofstratosphericozonehasimportantdetrimentaleffectsonhealthandtheenvironment.StratosphericozoneshieldstheearthfromultravioletB(UV-B)radiationfromthesun.A1percentdecreasein
ozoneintheatmospherecausesa2percentincreaseinUV-Bradiation,whichinturnmayresultina4percentincreaseinskincancer(Titus1986:1).IncreasesinUV-Bradiationcanalsocauseeyecataractsandinjuretheskin'simmuneresponses.
Severalfactorssuchasmeteorologicalconditions,type,andconcentrationsofindustrialchemicalscontributetoozonedestructioninthestratosphere.Theprincipalchemicalsinvolvedarenitrogenoxideandchlorofluorocarbons(Box3.5givesabriefdescriptionofthecomplexchemicalprocesses).
CFCsandStratosphericOzoneDepletion
Theindustrialchemicalsknownaschlorofluorocarbons(CFCs)yieldchlorineatoms(Cl)throughaseriesofcomplexchemicalreactions.TheClatomsarethedirectcausesofthedepletionoftheozonelayer.CFCsareprimarilyresponsibleforthefactthatozone-depletingchlorinatedcompoundsinthestratosphereare4to5timeshigherthannormal.UnlessfurtherstepstocurbCFCemissionsaretaken,chlorinecompoundsinthestratospherewillincreaseatapproximately5percentperyear(GraedelandCrutzen
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Box3.5DepletionofStratosphericOzone
Ozonemoleculesdecaytoanoxygenmoleculeandanoxygenatomwithintheozonelayer.Thishappensinseveralways;oneofthemostimportantisthedirectcollisionofanozonemolecule(O3)withanoxygenatom(O):
RoleofNitrogenOxideinOzoneDestruction
Certainsinkmolecules,suchasNOandchlorine,actascatalystsinthedecompositionofozone.ThesemoleculescompetewithO2moleculesforfreeoxygenatomsintheozonelayerandhinderozoneformation.Ozoneisdepletedintwosteps:
NOmolecule:
Overallreaction:
Theoverallreactionisthesameaswhenanozonemoleculecollideswithanoxygenatom.
RoleofCFCsinOzoneDestruction
Sincethemid-1970s,CFCshavebeenrecognizedasasourceofchlorineinthestratosphereandhenceathreattotheozonelayer.CFCsareunaffectedbynaturalcleansingmechanisms,suchasrainfall,andescapeintothestratospherewithintenyears,wheretheysurvivefor
about400years.Freongases,suchasCFCl3andCF2Cl2,areasourceofchlorine(Cl)atomsintheupperatmosphere.ThesecompoundsdecomposetoformClatomswhenexposedtoultravioletradiationat200nm.Atanaltitudeof40km,lightofthiswavelengthisfreelyavailable:
Thechlorineatomsactascatalysts(whichacceleratetherateofachemicalreactionandarefreedunalteredattheend)inthedecompositionofstratosphericozone.First,thechlorine(Cl)breakstheozoneintoordinaryoxygen(O2)andanoxygenatom(O).Itthencombineswiththefreeatomtoformchlorinemonoxide(ClO):
ThisisthenstrippedofitsOatombyanotherfreeOatomthatcombineswithittogivemolecularoxygen(O2).Thechlorineatom(Cl)isleftintactandcanrepeatthiscycle100,000timesbeforeitisfinallyneutralized:
IthasbeensuggestedthattheCl-catalyzedreactioncouldultimatelydecreasetotalozoneintheupperatmosphereby5to9percent.UseofCFCsasaerosolpropellantshasbeenphasedoutintheUnitedStates,Canada,andSweden.
Note:(g)=gasphase.SeeWorldMeteorologicalOrganization(1985:2756)foradetailedaccountofstratosphericchemistry.
Source:WorldMeteorologicalOrganization(1985:
2938);Mastersonandothers(1985:527-28).
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1990:1718).CFCsareusedasrefrigerants,solvents,propellantsinspraycans,andblowingagentstoproducefoam.TheinertnessofCFCsintheloweratmospherewasinitiallyconsideredapositiveattributeinpreventingCFCsfromposingadirectthreattolivingorganisms.Unfortunately,thisalsoallowsCFCstoreachtheupperatmosphereunchanged,wheretheyarebrokenapartbyexposuretostrongsunlight,beginningachainreactionleadingtothedestructionofozone.BeforetheinventionofCFCs,ozoneconcentrationinthestratospherewas220Dobsonunits(Dobsonunitsarethestandardozonemeasure).By1987theozonereadinghadfallento120Dobsonunits.Itwasaboutthesamein1990,butin1992arecordlowmeasurementof105DobsonunitswasobtainedovertheAntarctic(Walsh1992a:8687).
TheUnitedKingdom's1993StratosphericOzoneReportstatedthatozonedepletionisworseninginEurope,withrecordlossesoccurringintheNorthernHemisphere'smid-latitudes.Thereportattributesthe3percentperdecadelossofozonetochlorineandbromine.ThereportalsostatesthattheaveragethicknessoftheglobalozonelayerfromMay1992toMay1993measuredbytheTotalOzoneMappingSpectrometerwas3percentlessthaninanyyearsince1978,whenmeasurementscommenced(Walsh1994b:78).TheNationalOceanicandAtmosphericAdministrationfounda5to18percentdecreasebelowaverageconcentrationintheozonelayerovertheUnitedStatesduringtheperiodJanuary1992toMay1993.Theseverestthinning(18percent)occurredfromMarchthroughMay1993.Thesevaluesarerecordlowsforthepast20years.BelgiumandtheNetherlandsalsoreportedalossof17to18percentbelowaveragelevelsforozonebetween1971and1993.TherecordlowsmayberelatedtotheJune1991eruptionofMountPinatubo(Walsh1993b:12),whichspeweddropletsofsulfuricacidintotheatmosphere.Thesedropletsprovidesurfacesforgeneratingtheozone-destroyingreactiveformsof
chlorine.
ThemostalarminglossofstratosphericozonehasbeenobservedoverAntarctica.SixscientistswhospenttwomonthsintheAntarcticin1990wereexposedtosunlightthroughagiganticholeintheozonelayer.Unlesstheyworeprotectiveclothing,theywereseverelyburnedandbecamenauseatedafterexposureofjustafewhours.Exceptionallyhighconcentrationsofozone-depletingClOmoleculeshavebeendetectedintheAntarcticstratosphere(EnvironmentalUpdate1990),andasimilarsituationmaynowbeoccurringinthehighnorthernlatitudes.Approximately1.5ppbbyvolumeofClOhavebeendetectedinthestratosphereoverthehighnorthernlatitudes,aconcentrationcomparablewiththatfoundintheAntarctic(Walsh1992c:8586).
RelevancetoDevelopingCountries
Asstatedatthebeginningofchapter2,littlemeaningfulworkhasbeendoneinthedevelopingcountriestomonitorairpollutantsandassesstheireffectsonadults,children,andtheenvironment.AvailabledataindicatethatemissionsofallmajorpollutantsSO2,suspendedparticulatematter,CO,andNOx,andleadaregrowingindevelopingcountries;noneofthesecountrieshaveissuedozone,particulate,orother
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pollutionalerts.Thepollutantsdiscussedinchapters2and3arepresentinalmostallmajorcitiesinsome,atlevelsthatmayhaveacriticalimpactonhealth.
Governmentsandindustriesaremakingmajoradvancesineffortstofindalternativestoozone-destroyingCFCsandhalons,forexample(seeAhmed1994b).Withafewsalientexceptions,however,developingcountrieshavebeenrelativelyslowtoincorporatenewproductsandtechnologies.
Theinactioninmostdevelopingcountriesisnottheproductofignorance;mostdevelopingcountriesrecognizetheneedtotakecorrectivemeasurestomanageairpollution.Theyareunabletoactbecauseofcompetingclaimsforlimitedresourcesandbecausemanylegislatorsandpolicymakersmisperceivetheextentoftheproblem,therelativecostsofamelioration,andthedangersofinaction.
Sincemorethan50percentofallairpollutantsareemittedbyindustrializedWesterncountries,itisfortunatethatthesecountrieshaveboththefinancialandtechnicalresourcestoimplementsuccessfulpollutioncontrolstrategies.ThatsuchstrategiesarehavinganeffectisindicatedbythedownwardtrendsinSO2,suspendedparticulatematter,andleadlevelsinthesecountries.Meanwhile,however,pollutionlevelsindevelopingregionsareincreasing.OfparticularconcernistheworseningairpollutioninpopulousdevelopingareasinLatinAmerica,China,India,andSoutheastAsia.Itisestimatedthatbytheyear2000,everyotherpersonwillbeanurbanresident,andoneinthreepersonswillliveinacityofatleast100,000people.Eightoutof10peoplewillliveinadevelopingcountry.
Airpollutionhasnoboundaries,andemissionsintheIndiansubcontinentorAfricacouldultimatelyaffecttherestoftheworld.Airqualitymanagementwillrequiretheexperienceandtechnical
expertiseaswellasfinancialassistanceoftheindustrializedworldandwouldinthelongrunbenefitbothdevelopedanddevelopingcountries.Forthesereasons,itisusefultoexaminesomebasicaspectsofaprogramtoadaptairqualitymanagementtothepresentandemergingneedsofdevelopingcountries.
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4AmbientAirQualityandEmissionStandardsInmostdevelopingcountries,formulatinganairqualitymanagementprogramgenerallyhasalowerprioritythanimplementingprogramstopromotehousing,generateelectricpower,orprovidesocialservices,education,andmedicalcare.Countrieswithlimitedfinancialmeansmustmakedifficulteconomicandpoliticalchoicesabouthowtoallocatetheirresources,andgenerallytheypursueprogramsthatwillshowthemostvisibleresults.Giventheirprioritiesandconstraints,thedevelopingcountriesmaynotbeabletoimplementthesamecleanaircontrolsastheindustrialcountriesintheshortormediumterm.Butnocountrydevelopedordevelopingcanaffordtoignoretheneedforprogramstoachieveminimumlevelsofcleanair.ThischapterdiscussescurrentandproposedairqualitystandardsinvariousdevelopedanddevelopingcountriesandreviewsthestandardsproposedbytheWorldHealthOrganization(WHO).
AirQualityStandards
Measurements
Theharmfuleffectsofanairpollutantaredeterminedinpartbyitsvolumeconcentrationandbyitsdurationintheatmosphere.Partspermillion(ppm)isthestandardmeasureofthevolumeofairpollutants;partsperhundredmillion(pphm)andpartsperbillion(ppb)areusedforverylowconcentrations.(1ppmisequivalentto10(-4)percent;theoxygencontentinairis20.946percent,equalto209,460ppmbyvolume.)Theothermeasureofvolumeisfoundedonweightperunitvolume,andtheunitsarerepresentedasmicrogramspercubicmeter(µg/m3).Thismeasurementisassociatedwithppmat25°C(77°F)andoneatmospherepressure(BellomoandLiff1984:2627).
Differenttechniquesareusedtomeasureairpollutantconcentrations.Thesetechniquesrangefromsimplemeasuringprocedurestocomplexsimulationsthattracedispersedpollutantsthroughtimeandspace.Computerprogramsareavailablethatcanpredictlevelsofemissionsunderdifferentconditions.
TypesofStandards
Airqualitystandardsareintendedtopreventconcentrationsofairpollutantsfromreachingharmfullevels.Twostandardsarewidelyused.Emissionstandardspertainto
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pollutantscomingfromspecificsourcessuchasindustrialsmokestacksandmotorvehicleexhaustsystemsandspecifyallowableconcentrationsofpollutantsatreleasesites.Ambientstandardsareconcernedwiththeoverallairqualityofacommunityorindustrialareaandspecifyallowablepollutantconcentrationsinsuchareas.Emissionstandardsmakeitpossibletoidentifyspecificsourcesofairpollutionandtodesigncorrectiveactions.Ambientstandardsaredefinedwithanadequatemarginofsafetytopreventharmtohumanbeingsandtheenvironment.
Ambientairqualitystandardsareoftensubdividedintoprimaryandsecondarystandards.Theprimarystandardsareintendedtoprotecthumanhealthandhaveamarginofsafety;economicandtechnicalfeasibilityaredisregarded.Primarystandardsalsoestablishdeadlinesforcompliance.Secondarystandardsrefertoenvironmentaleffectsandareintendedtoprotectoverallorlong-termhumanwelfare.Theypertaintovisibility,soil,water,vegetation,domesticanimals,wildlife,materials,property,transportation,andeconomicissues.Secondarystandardscanbeattainedatamoreleisurelypace.
AmbientAirQualityStandards
Table4.1givesambientairqualitystandardsinselectedcountries.ThosegivenfortheUnitedStatesareprimarystandardsandarebasedonworkbytheEPA,otherregulatoryagencies,andindustry.BrazilandIndonesiahaveambientairqualitystandardsthatareverysimilartothoseoftheUnitedStates,anditisnotapparentwhetherthesestandardsweresetindependentlybyBrazilandIndonesiathemselvesorsimplyechotheU.S.standards.
ChinaandIndiaestablishedambientairqualitystandardsin1982.UnlikeJapan,theUnitedStates,andseveralEuropeancountries,whichhavenationwidestandards,ChinaandIndiahaveambientstandardsthatvaryinregionswherelivingconditionsdiffer.Because
oftheircomplexity,thesestandardsaregiveninseparatetables(Tables4.2and4.3).ThelimitssetforheavilypollutedareasinChinaarethreetimesashighasthelimitssetfornaturalconservationareas.ThestringencyofIndia'sstandardsvarieswithregionaldesignationsmadebyStatePollutionControlBoardsonthebasisoflanduseandotherfactors.TheClassIIstandardsinChina,andthosepertinenttoregionsdenoted"B"inIndia,typicallyconcernresidentialandcommercialregions.ApartfromIndia'sparticulatestandards(whicharelessstringent)andChina'scarbonmonoxidestandards(whicharemorestringent),thesestandardsdonotvarygreatlyfromthestandardsinJapan,Sweden,andtheUnitedStates,andcanbeconsideredadequatetosafeguardpublichealth.
Table4.4furnishesambientairqualityvaluesgivenbytheWorldHealthOrganization.Thesevaluesareguidelinesratherthanstandards.Theysignifythelevelandexposuretimeatwhichnodetrimentaleffectsareanticipatedandbelowwhichthereisnoexpectedhazardtothehealthofpeople.Anoteofcautioniswarranted,sinceguidelinesareprovidedonlyforindividualpollutants;exposuretoamixtureofpollutants(noneofwhichbyitselfexceedstheguidelines)mayhavedetrimentaleffects.
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Table4.1ComparativeAmbientAirQualityStandardsof14Countries/EconomiesandTwoInternationalOrganizations
Pollutant: TSPg SO2 CO NOx LeadConcentration: µg/m3 ppm ppm ppm ppm µg/mSamplingtime: 24hours 24hours 8hours 1hour (seenotes) (seenotes)
Brazila 240 0.14 9.0 0.08 0.25HMiChilea 260 0.14 9.0 0.08 0.16DMjIndonesiab 260 0.10 20.0 0.10 0.05DMj 60.024hr.Japanc 100 0.04 20.0 0.06 0.040.06DMjKoreac 300 0.15 20.0 0.1 0.15HMiKuwaitc 350 0.06 10.0 0.08 0.05DMj 2.024hr.Malaysiac 260 0.04 9.0 0.10 0.17HMi 3.0QAMexicod 275 0.13 13.0 0.11 0.21HMiPeruc 350 0.30 17.0 0.20(30min.) 0.11DMj 15.0MASaudiArabiac 340 0.15 9.0 0.15 0.35HMiTaiwanc 250 0.10 9.0 0.12 0.25hmn 1.0MMThailande 330 0.11 17.0 0.10 0.17hmn 10.024hr.Turkeyf 300400 0.15 0.16DMj 2.0AAMUSAc 260 0.14 9.0 0.12 0.05AAMo 1.5QAEECf 300 0.15 2.0AAMWHOd 150230 0.04 9.0 0.10 0.05(8hours) 0.51.0Note:=notavailable.;µg=1x10-6gm;mg=1x10-3gm;ppm=partspermillion;µg/m3=ppmx40.91xMW,whereMW=molecularweight;(H=1,C=12,N=14,O=16,S=32);SO2=sulfurdioxide;NOx=nitrogenoxide.aWeitzenfeld(1992).bSinha(1989).cMurley(1991).dFaizandothers(1990).e1994WorldBankdata.fSebastian(1990).gTotalsuspendedparticulates.hPhotochemicaloxidants(ozone).iHourlymaximum.jDailymean;meanconcentrationnottobesurpassedbyanydailymean.kQuarterlyaverage(3months).
kQuarterlyaverage(3months).lMonthlyaverage.mMonthlymean:themathematicalmeanvalueofeachdailymeanvalueobtainedinamonth.nHourlymeanvalue.oAnnualarithmeticmean.
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Table4.2China'sNationalAmbientAirQualityStandards(µg/m3)Pollutant Averagingtime Firstclassa Secondclassb ThirdclassTSP Dailymeand 150 300 500
Notoncee 300 1000 1500Flydust Dailymeand 50 150 250
Notoncee 150 500 700SO2 Annualdailymeanf 200 600 100
Dailymeand 50 150 250Notoncee 150 500 700
NOx Dailymeand 50 100 150Notoncee 100 150 300
CO Dailymeand 4000 4000 6000Notoncee 10,000 10,000 20,000
O3 Hourlymean 120 160 200Note:µg=1x10-6grams;TSP=totalsuspendedparticulates;SO2=sulfurdioxide;NOx=nitrogenoxides;CO=carbonmonoxide;O3=ozone.aNaturalconservationareas,scenicspots,historicalsites,andconvalescentplaces.bResidentialareas,mixedareasofbusiness,culturalareas,historicalsitesinrelevanturbandevelopmentprograms,andopenareas.cCities,towns,andindustrialareashavingseriousairpollutionproblems,aswellasurbantrafficcentersandmainroads.dMeanconcentrationlimitnottobesurpassedbyanydailymean.eConcentrationlimitnottobesurpassedevenonceinsamplinganddetermination.fMeanconcentrationlimitnottobesurpassedbyanydailymeaninanyyear.Source:Faizandothers(1990).
Table4.3India'sAmbientAirQualityStandards(µg/m3)Pollutant Averagingtime AreaAa AreaBb AreaC
TSP 8-houraverage 500 200 100SO2 8-houraverage 120 80 30CO 8-houraverage 5,000 2,000 1,000NOx 8-houraverage 120 80 30O3Note:=notavailable;µg=1x10-6grams;TSP=totalsuspendedparticulates;SO
Note:=notavailable;µg=1x10-6grams;TSP=totalsuspendedparticulates;SOsulfurdioxide;NOx=nitrogenoxides;CO=carbonmonoxide;O3=ozone.aIndustrialandmixedareas.bRuralandresidentialareas.cSensitiveareas.Source:Siddiqi(1984).
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Table4.4WorldHealthOrganizationGuidelinesforAmbientAirQualityStandardsPollutant Samplingtime Standard
Particulatematter Annualmean 4060µg/m3b,d98percentilec 100150µg/m3b,dAnnualmean 6090µg/m3b,d98percentilec 150230µg/m3b,d
Thoracicparticles(PM10)a 24hours 70µg/m3bSO2 Annualmean 4060µg/m3b,d
98percentilec 100150µg/m3b,d10minutes 500µg/m31hour 350µg/3
CO 15minutes 100mg/m330minutes 60mg/m31hour 30mg/m38hours 10mg/m3
NO2 1hour 400µg/m324hours 150µg/m3
Lead Annualmean 0.51.0µg/m3Photochemicaloxidants(O3) 1hour 150200µg/m3
8hours 100120µg/m3PAHs n.a. NoguidelinesyetNote:n.a.=notapplicable;µg=1×10-6grams;mg=1×10-3gm;SO2=sulfurdioxide;NO2=nitrogendioxide;CO=carbonmonoxide;O3=ozone;PAHs=polynucleararomatichydrocarbons.aUNEPandWHO(1992).bValuesgivenareforthecombinedeffectofSO2andsuspendedparticulatematter.Thesefiguresmaynotbeapplicablewhenonlyonecompoundispresent.cOfthedailymeans,98percentneedtobebelowthisconcentration.dStandardestablishedforblacksmoke.Source(exceptasnoted):UNEPandWHO(1988).
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EmissionStandards
Anemissionstandardisalegallimitonthequantityofapollutantanindividualsourceisallowedtoemit(Tietenberg1992:372).Emissionstandardshavebeensetbymostindustrializedcountriestocurbpollutionfrombothstationaryandmobilesources.Stationarysourcesusuallyinvolvepowergenerationandindustrialprocesses.Themanydifferentmanufacturingprocessesmayemitdifferenttypesofpollutants.Hence,emissionstandardsareindustry-andsite-specific.Althoughmobilesourcesemitmanyofthesamepollutantsasstationarysources,theiremissionsaremoredifficulttocontrol,anditismoredifficulttotailoremissionratestolocalpollutionpatterns.Thesedifficultiesmaybeattributedtotheintrinsicallytransientnatureofvehiclesourcesevenwithinametropolitanareaandtothepossibilitythataparticularvehiclewilltraveltomanydifferenturbanandruralareasduringitsusefullife(Tietenberg1992:450).Mobilesourcesarealsomorenumerousthanstationarysources,addingtothedifficultyofcontrollingtheiremissions.
Transport-RelatedEmissions
Thetransportationsectorisasignificantcontributortoairpollution.Forexample,emissionsfromtransportationsourcesinFrancein1990accountedforabout76percentofemissionsofCO,69percentofHCs,56percentofNOx,30percentofparticulates,21percentofSOx,and80percentoflead(Faiz1993).Motorvehiclesarethelargestcontributorsofmobile-sourceemissions(seeTable4.5).
Table4.5TransportSectorContributiontoNationwidePollutantEmissionLevelsinFrance,1990
(%oftotalanthropogenicemissions)Modeoftransport CO HC NOx SPM SOx
Motorvehicles 76 69 48 26 8Railways .. .. 1 1 ..Aviation(withinairports) .. 1
Coastalnavigation .. .. 7 3 12(NorthSeaandMediterranean)
TOTAL 76 69 56 30 21..=Lessthan1percentcontribution.=notavailable.Source:AdaptedfromFaiz(1993).
Table4.6givesthecontributionofthetransportsectortoconventionalairpollutantemissionsinselectedcountries.ThebulkofanthropogenicCOemissionsisfromthetransportsectorincluding58to85percentinOECDcountries,above90percentintheMiddleEast,andbetween50and60percentinthetropicalAsiancountries.
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Table4.6TransportSectorContributiontoAirPollutantEmissionsinSelectedCountriesPercentageattributabletotransport
Country Year CO HC NOx SOxOECD
Canada 1985 66 40 64 3USA 1988 67 33a 41 4Austria 1986 58 87 72Finland 1980 80 60 50France 1990 76 69a 48 21Germany 1986 74 52 61 5Greece 1985 32 55 3Ireland 1983 81 55 33 4Italy 1985 82 56 43 7Netherlands 1987 80 87 59 7Switzerland 1984 73 27 74 6U.K. 1985 75 40 48 3
EasternEuropeHungary 1987 99 39 2Poland 1988 40 37 33 3U.S.S.R 1988 66 40 29Estonia 1989b 73 56 1
MiddleEastandAsiaIsrael 1988 99 100 52 4Kuwait 1987 96 76 26 0.1SouthKorea 1987b 25 57 85 8Taiwan 1988b 46 53 50 14Malaysia 1988b 50 95 36 1Thailand 1982b 60 46 23 15
=notavailable.Note:ForamoredetailedlookatthetrendinemissionsandthecontributionoftransporttopollutantemissionsseeFaiz(1993):170-71.PM=particulatematter.aVolatileorganiccompounds,excludingmethane.bPercentageattributabletotransportappliesonlytomotorvehicles.
Source:Faiz(1993).
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HydrocarbonemissionsfromthetransportsectorinOECDcountriesrangefrom30to87percent,andinnon-OECDcountriesfrom37to100percent.Thedeveloping-countryshareissomewhathigher(46to100percent)becausethehigheraveragetemperaturesinmanydevelopingcountriesincreasetheamountofevaporativeemissions.
NOxemissionsfromthetransportsectorareapproximatelythesameinbothOECDandnon-OECDcountries.WiththeexceptionoftheUnitedStatesandCanada,NOxemissionsincreasedduringthe1980sinbothdevelopingandindustrializedcountries.
Thetransportsector'sroleinSOxemissionsinOECDandEasternEuropeancountriesis,withtheexceptionofFrance,generallylowbecauseofthelowsulfurcontentoffuelintheseregions.SOxemissionsarehigherindevelopingcountriesbecauseofthehighersulfurcontentoffuelandgreateruseofdieselfuelinpassengertransport.(Sulfurcontentisinexcessof0.6percentbyweightindevelopingcountriesand0.3percentbyweightintheUnitedStates.)TheproportionofSOxfromthetransportsectorinFranceishighbecauseofdrasticreductionsinSOxemissionsfromothersources,suchascoal-andoil-firedindustrialderivatives.(NuclearenergyisalargesourceofpowerinFrance.)
Thenatureofparticulatesandthevariationsinthemethodologiesusedtoobtainparticulateemissionsinventoriestendtomakecomparisonsofparticulatesamongcountriesunreliable.Ingeneral,thetransportsectorintheOECDcountriesemitsmoreparticulatematterthandothemorerigorouslycontrolledstationarysources(Faiz1993).
GasolineVehicles
Themid-1970ssawtheintroductionofmotorvehicleemissioncontrolprogramsinmajorindustrializedcountries,butthestandardsdiffered
fromcountrytocountry.Table4.7showsemissionstandardsforgasoline-poweredvehiclesintheUnitedStates,Japan,andtheEuropeanCommunity.UntilquiterecentlytheUnitedStateshadthemoststringentstandards.Switzerland'sbecameasstringentin1988,Sweden'sin1989.
ItislikelythattheemissionstandardsgiveninTable4.7willbeunachievableinmanydevelopingcountries,sincemeetingthemwouldrequiremodernizingvirtuallyallexistingvehicles.However,severaldevelopingcountrieshaveintroducedstringentemissionstandardsfornewvehiclesandsomewhatrelaxedrequirementsforin-usefleets.Forexample,Brazil,Mexico,Taiwan,Thailand,andKoreaareamongdevelopingcountriesthathaveadoptedbothmobile-andstationary-sourceemissionstandards.TheexhaustemissionstandardsadoptedbyBrazilforbothalcohol-andgasoline-poweredvehiclesandbyMexicoforgasoline-poweredvehiclesaregiveninTables4.8and4.9,respectively.Thesearereasonableemissionstandardsfordevelopingcountries.
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Table4.7ExhaustEmissionStandardsforGasoline-PoweredLight-DutyVehiclesinSelectedIndustrializedCountries(g/km)
Country Year CO HC NOxUnitedStatesa 1980 5.6 0.25 1.2
1992 2.1 0.25 0.6By1995 2.1 0.16 0.25By2003 2.1 0.08 0.125
Japanb* 1975 2.7 0.39 1.21978current 2.7 0.39 0.48
EECc,** ByJuly1992f 2.72# 0.97g,#AfterJanuary1993f
ByJuly1992f 3.16## 1.13g,##AfterJanuary1993f1996proposed 2.2 0.5g
Swedend After1988 2.1 0.25 0.620.76Australiae 1986 9.3 0.9 1.9Switzerlande 1987 9.3 0.9 1.2
1988 2.2 0.21 0.62Canadae 1987 2.1 0.25 0.62=notavailable.*Testprocedureusedwasthe10-modetestcycle;standardsgivencorrespondtomaximumlimits.**ThisisaConsolidatedDirective(91/441/EEC)givingemissionstandardsforallnewvehiclesbelow2.5metrictons,ofwhateverfuelandenginetype,boughtintheEC.(Particulatelimitsnotgivenastheyarenotapplicabletogasolinevehicles.)#Typeapprovallimits.##Conformityofproduction.Note:g/km=gramsperkilometer.Foreachpollutantatypeapprovallevelisdefinedfornewvehiclemodels,asisaconformityofproductionlevelagainstwhichasampleofvehiclesfromagivenproductionrunischecked.aMageandWalsh(1992).bWatkins(1991).cOECD/IEA(1993b):145-54.dEconomicCommissionforEurope(1991:35).eOECD(1988).fAllnewmodelsoflight-dutyvehiclesarerequiredtomeetthislimitbyJuly1992
fAllnewmodelsoflight-dutyvehiclesarerequiredtomeetthislimitbyJuly1992andallnewcarsafterJanuary1,1993.gHC+NOx.
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Table4.8Brazil'sEmissionStandardsforGasoline-andAlcohol-PoweredLight-DutyVehicles(g/km)
Typeofemission Year CO HC NOx RCHOExhaust 19891991 24.0 2.1 2.0
19921993 12.0 1.2 1.4 0.15March1994 12.0 1.2 1.4 0.15January1997 2.0 0.3 0.6 0.03
Evaporative 19891991 6.0(g/test)19921993 6.0(g/test)bMarch1994 6.0(g/test)bJanuary1997 6.0(g/test)b
=notavailable.Note:g/km=gramsperkilometer;g/test=gramspertest.aOnlyforalcohol-fueled,light-dutyvehicles.bExpressedaspropaneforgasohol,orcorrectedtoethanolforalcoholvehicles.Source:Walsh(1993c:4143).
Table4.9Mexico'sEmissionStandardsforGasoline-PoweredMotorVehicles(g/mile)Description HC CO
1989cars,notrucks 3.20 35.21990cars 2.88 28.8GVWupto6,012poundsa 3.20 35.2GVW6,013to6,614poundsb 4.80 56.01991cars 1.12 11.2GVWupto6,012poundsa 3.20 35.2GVW6,013to6,614poundsb 4.80 56.01992cars 1.12 11.2GVWupto6,012poundsa 3.20 35.2GVW6,013to6,614poundsb 3.20 35.21993cars 0.40 3.4GVWupto6,012poundsa 3.20 35.2GVW6,013to6,614poundsb 3.20 35.21994cars 0.40 3.4
GVWupto6,012poundsa 1.00 14.0GVW6,013to6,614poundsb 1.00 14.0
Note:GVW=Grossvehicleweight.aCommercialvehicles(e.g.,NissanvanandCombis).bLight-dutytrucks.Source:MageandWalsh(1992).
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Diesel-PoweredVehicles
Diesel-fueledmotorvehiclesareontheriseinmanydifferentpartsoftheworld.Sincemillionsofpeopleareexposeddailytodieselfumes,emissionstandardsfordieselvehiclesareimperative.Theindustrializedcountrieshaveattemptedtocontroldieselparticulatesbysettingrisingstandards,amongothermeasures.Tables4.10and4.11presenttheexhaustemissionstandardsforlight-andheavy-dutydieselvehicles,respectively,intheUnitedStates.Table4.12givesthestandardsforheavy-dutydieselvehiclesinEurope.
StandardsforSulfurContent.In1990theU.S.EnvironmentalProtectionAgencyannouncedplanstoreducethesulfurcontentofdieselfuelsby80percentfrom0.25wt-%to0.05wt-%effectiveOctober1,1993(''EPAIssues1993andLater:DieselSulfurRegulations"1990).Mexico,aspartofanongoingprogram,loweredthesulfurcontentofdieselfuelto0.1wt-%.AlthoughTaiwan'sdieselfuelpresentlycontains0.5wt-%ofsulfur,itproposestoreducesulfurcontentto0.3wt-%by1993andtotheU.S.standardof0.05wt-%by1997.Brazil'sdieselfuelcurrentlyhasasulfurcontentofabout1wt-%,butattemptsarebeingmadetointroducea0.5wt-%sulfurdieselfuelincitybuses(Walsh1993a:9,1617).Ageneraltrendtowardloweringthesulfurcontentinfuelisapparent,atleastincountrieswherethisisfinanciallyandtechnologicallyfeasible.Reductionofsulfurinfuelwillreducedieselexhaustemissions'contributiontotheproductionofsulfurdioxide.
LimitsonParticulateEmissions.Controlofparticulatesfromdieselfuelhasgainedincreasedimportanceovertime.Thefirstdiesel-fuelparticulatestandardswereestablishedbytheEPAin19800.6g/mileforallcarsandlight-dutytruckscommencingwithmodelyear1982.Thestandardwasloweredto0.2g/mileforcarsin1985andto0.26g/mileforlight-dutytrucksbeginningin1987(Walsh1993a:2).
CanadaadoptedtheU.S.dieselparticulatestandardsof0.20(0.13g/km)and0.26g/mile(0.16g/km)forautomobilesandlight-dutytrucks,respectively,in1985.SwedenalsoadoptedtheU.S.standardforparticulateemissionsforautomobiles.
InAustriathemaximumpermissiblelimitforparticulateemissionsis0.6g/mile(0.38g/km),butbothAustriaandSwitzerlandareexpectedtoadoptU.S.light-dutytruckstandardsinthenearfuture(Walsh1992d).TheEuropeanCommunity(EC)decidedinJune1991toadoptstandardsforallnewmodelsofbothgasolineanddiesellight-dutyvehicles,commencinginJuly1992,ofnomorethan4.35g/mile(2.72g/km)ofCOandamaximum1.55g/mile(0.97g/km)ofvolatileorganiccompounds(VOCs)andNOxcombined,andfordieselvehiclesamaximumemissionof0.22g/mile(0.14g/km)ofparticulates.ConformityofProductionlimitsareasfollows:CO5.06g/mile(3.16g/km),VOCandNOxcombined1.81g/mile(1.13g/km),andfordieselvehiclesaparticulatelimitof0.29g/mile(0.18g/km)(OECD/IEA1993b:149).
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Table4.10U.S.EmissionStandardsforLight-DutyDieselVehicles(g/mile)Modelyear VOC CO NOx Particulates
1981 0.41 7.0 2.019821986 0.41 7.0 2.0 0.619871994 0.41 7.0 2.0 0.219941996limitstobephasedin:
First50,000miles 0.25 3.4 0.4 0.08Second50,000miles 0.31 4.2 0.6 0.1
From2004 0.125 1.7 0.2 0.08Note:g/mile=gramspermile.Light-dutyvehiclesincludecars,taxis,vans,andlighttrucks(lessthan3.5metrictonsinEuropeandlessthan3.9metrictonsintheUnitedStates).Source:OECD/IEA(1993a):136.
Table4.11U.S.EmissionStandardsforHeavy-DutyDieselVehicles(g/BHP-hr)Modelyear HC CO NOx Particulates
1983 1.3 15.5 10.7 0.61990 1.3 15.5 6.0 0.61991 1.3 15.5 5.0 0.251991(buses) 1.3 15.5 5.0 0.101994 1.3 15.5 5.0 0.101994(buses) 1.3 15.5 5.0 0.05a1998 1.3 15.5 4.0 0.1b2004 1.3 15.5 3.0 0.1cNote:Unitsareingramsperbrakehorsepower-hour.Heavy-dutyvehiclesincludegoodsvehiclesandbusesexceeding8,500pounds(3.9metrictons).aOr0.07if0.05g/BHP-hrprovesnotfeasible.bFederalproposal.cCaliforniaproposal.Source:OECD/IEA(1993c):119.
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Table4.12CurrentHeavy-DutyDieselPollutantLimitsinEurope(g/kWh)Country CO HC NOx Particulates
SwitzerlandStep1(October1989)andAustriaStep1(January1988)
8.4 2.1 14.4
SwitzerlandStep2(October1991)andAustriaStep2(October1991)
4.9 1.23 9.0 0.7
Sweden93MY(A-30)andNorway(October1993) 4.9 1.23 7.0 (0.35or0.40)
ECStep1(1992) 4.5 1.1 8.0 0.63(<85kW)
Typeapproval0.36(>85kW)
Conformityofproduction (4.9) (1.23) (9.0) (0.7)(<85kW)
(0.4)(>85kW)
SwitzerlandStep3 (4.9) (1.23) (9.0) (0.4)ECStep2(1995)(AlsolikelySwissStep4)
4.0 1.1 7.0 0.15
ECStep3(2000)orlater Newtestpossible
Note:g/kWh=gramperkilowatthour.Heavy-dutyvehiclesincludegoodsvehiclesandbusesofmorethan3.5metrictons.Source:Walsh(1992d).
TheU.S.CleanAirActandAmendments
TheU.S.CleanAirActof1970,asamended,establishedemissionstandardsfordifferenttypesofvehiclesforCO,HC,andNOx;authorizedtheEPAtoestablishregulationsforfuelqualityforconventionalandalternativefuels,performancestandardsforvehiclesusingalternativefuels,andemissionstandardsforvehiclesnotregulatedbytheAct;andauthorizedtheEPAtoestablishNationalAmbientAirQualityStandards(NAAQS)fordesignatedpollutants(CO,NOx,ozone,particulatematter,SOx,andlead)thatwouldensuretheprotectionandenhancementofthecountry'sairresources.
ensuretheprotectionandenhancementofthecountry'sairresources.
TheCleanAirActAmendments(CAAA)of1990tightenedrevisionstothe1970Act(CleanFuelsLegislationDirectory1994)bytighteningpollutioncontrolmeasuresincitiesthatwerenotcomplyingwithfederalairqualitystandards,makingchangesinfuelspecifications,andendorsingtheuseofalternativefuelsinareaswiththeworstairqualityproblems(seeTable4.13forasummaryofthefuelprovisionsoftheCAAAof1990).Morestringenttailpipeemissionstandardswereestablished,anduseofcleanerfuelsingasolineanddiesel-poweredvehicleswasstipulated.Theamendmentsrequiredbasicreformulationofpetroleumfuels,reductionofsulfurlevelsindieseloil,andlimitationsonbenzeneandaromaticsingasoline,loweringofvaporpressure,andadditionofoxygenates.TheEPAissuescleanfuelrequirementsandemissionsstandardsunderTitleIIoftheCAAA(CleanFuelsLegislationDirectory1994).
Table4.13U.S.FuelSpecifications19922000,BasedonU.S.CleanAirActAmendmentsof1990
Fuelsprovision Effectivedate
Amendments
OxygencontentinCOnonattainmentareas(moderateandserious)
11/1/92 2.7wt-%minimumaverageoxygencontentfornolessthanfourwintermonths
IffederalairqualitystandardforCOhasnotbeenachievedbyaspecifiedattainmentdate,minimumoxygencontentwillincreaseto3.1wt-%
Oxygencontentinozonenonattainmentareas
1/195 2.0wt-%minimumaverage
Aromaticscontent 1/1/95 25vol-%maximumBenzene 1/1/95 1.0vol-%maximumLead 1/1/95 Prohibitedtomanufacture
1/1/96 Illegaltosellgasolinewithleadorleadadditivesforhighwayuse
Additives 1/1/95 Required,fordepositcontrolAirtoxics 1/1/95 15%reduction
2000 20%reductionVOCs 1/1/95 15%reduction
2000 25%reduction;ifEPAdecidesitistoocostlyorisnotfeasible,then20%reduction
NOx NoincreaseinNOxOzonenonattainmentareasaffectedbyrequirement
1/1/95 Ninecities(with1989ozonedesignvalueof0.18ppmorgreater)with"opt-in"provisionforothermoderateorseriousozonenonattainmentareas.
Reidvaporpressure(Rvp)Summer1992
9.0psiforallgasoline
Summer1992
10psiforgasolinewitha10%orgreaterethanolcontent,whichisgranteda1.0psiwaiverofRvpstandard.
Sulfur(diesel) 10/1/93 0.05wt-%maximumCetaneindex(diesel) 10/1/93 40minimumNote:VOCs=volatileorganiccompounds.Forimplementationpurposes,the1990CleanAirActAmendmentsdefineanareaaseithera"nonattainmentarea"oran"attainment
AirActAmendmentsdefineanareaaseithera"nonattainmentarea"oran"attainmentarea."AreasinviolationoftheNationalAmbientAirQualityStandards(NAAQS)forozoneorcarbonmonoxideorparticulateemissionsbecome"nonattainmentareas."Source:AdaptedfromOECD/IEA(1993a:138)andCleanFuelsLegislationDirectory(1994:4144).
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The1990legislationcallsfora2.7wt-%minimumaverageoxygencontentfornolessthanfourwintermonthsinallgasolinessoldinbothmoderateandseriousCOnonattainmentareas,risingto3.1wt-%inallCOnonattainmentareasifthestandardisnotmet.A2.0wt-%minimumaverageoxygencontentisrequiredforthenineworstozonenonattainmentareasbythebeginningof1995.Citieswithalessseriousproblemmaychoosetoadopttherequirementsthen.Benzenecontentislimitedto1.0vol-%andaromaticsto25vol-%.Allheavymetaladditivesareprohibited;leadandmanganesearementionedspecifically.
MostindustrializedcountrieslooktotheUnitedStatesasaleaderinestablishingstandardsforairqualityandcontrolofharmfulemissions.OtherOECDcountrieseventuallyadoptedtheU.S.airqualitystandardsestablishedin1970.ThismayindicatethatOECDcountrieswilladoptthe1990changesaswell.However,futuregasolineanddieselspecificationsandformulationsnowconsideredessentialintheindustrializedcountrieswillrequireamajorrestructuringofrefineriesinthosecountries.Ifthedevelopingcountriesaretoadoptthesamestandards,evenatareducedpace,similarmajorinvestmentsinrefineriesmayberequired.
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5ValuationoftheBenefitsofMitigatingAirPollutionDevelopingcountriesmustmakechoicesinallocatingresourcestomeetmanypriorities,includinghealth,education,reductionofpoverty,andprotectionoftheenvironment.InThailand,Mexico,Taiwan,Indonesia,andKorea,recentandrapideconomicgrowthhasprovidedtheresourcesneededtoimproveenvironmentalquality.Inmanyoftheleast-developedcountries,however,suchresourcesmaynotbesoavailable.Nonetheless,countriesthatproducemoregoodsandservicesanduseincreasingamountsofenergyintransportationareboundtoproducemorepollutionandwillhavetotakeearlyanddecisive,ifnotcomprehensive,stepstoaddresstheproblemorriskcontinuingdegradationoftheenvironment.Forthesecountries,implementingthenecessaryenvironmentalmeasuresmayrequiretheassistanceofinternationalagencies.
Onewaycountrieswhatevertheirstageorrateofdevelopmentcanjustifyandplanforenvironmentalprotectionisbymakingeffortstoquantifyfactorsaffectingenvironmentalqualityandestimatetheireconomiceffects.Thisisacomplexexercise,inasmuchasthecostsareprimarilyintheformofadversehealthimpactsanddonotlendthemselvesreadilytoquantification,andadequateenvironmentaldataareoftenlackingindevelopingcountries.Moreover,applicationofvaluationmethodologiesrequireshighlyspecializedskills.Mostdevelopingcountrieswilllikelyfindthetasksofevaluationandameliorationdauntingbothinfinancialandmanagerialterms.Thismakesitallthemoreimportanttomakerealisticassessmentsofenvironmentalproblemsandtodevelopaffordableprogramsthatcanbecarriedoutinorderoftheirnetbenefits.
Thisreportdoesnotattempttosetenvironmentalorsocialprioritiesfordevelopingcountries.Suchanexercisemustbebasedonmoreextensivestudiesandinanycasewillhavetooriginatewithinthespecificcountriesthemselves.Instead,thechapteraddressesoneofthefoundationsofairqualitymanagementevaluatingthebenefitsofmitigatingairpollutionassociatedwithincreasesinindustrialoutput,energyuse,andtransportation.Includedareamethodologyforestimatingenvironmentalbenefitsaccruingfromthereductionofvariouspollutantsanddiscussionofthelimitsofcurrentenvironmentalprotectionmethods.Toillustratethebasisforvaluingbenefits,the
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chaptersummarizessomerecentWorldBankresearchonthepotentialhealthbenefitsofimprovingambientairqualityinBangkok,Thailand.
AHealth-BenefitsModel
Reductionsinconcentrationsofambientairpollutantswillreduceexposureofthepopulationtopollutantsandthusreduceacuteandchronicillness,thecostsofmedicalservices,andprematuremortality.Theywillalsoincreaseproductivityandimprovethequalityoflife.Asocietythatbenefitsfromimprovementsinairqualitywillnormallybeexpectedtopayforthesebenefits,butfullcostrecoveryisnotfeasibleformostdevelopingcountries.Forexample,althoughareductionofsulfuremissionsfromdieseloilusedinpublictransportwouldhavemajorbenefits,thecostisveryhigh,andthelowincomepeoplewhoarethelargestusersofpublictransportcouldnotabsorbitallifitwerepassedontothemintheformofincreasedpassengerfares.Eveninthedevelopedcountries,increasesinthecostofaproductorservicewillultimatelyhaveanimpactoneconomicactivity.Hence,itisimperativethatappropriatecriteriaareadoptedtomeasurethehealthbenefitsofreducingvariouspollutantsandthatairpollutionmanagementprogramsaredevelopedinacost-effectivemanner.
Twocomplementaryapproachesaregenerallyusedtoestimatetheimpactsofpollutiononhealth.Wherewell-establishedrelationshipsareavailablethatlinkconcentrations(orexposures)tohealthimpacts(dose-responseorconcentration-responsefunctions),aswithairpollutantssuchasSPM,lead,SO2,andozone,thesefactorscanbecombinedwithdataonambientairqualityoremissionstoderiveestimatesofmortalityandmorbidity(Ostro1994;Krupnickandothers1992).Inthiscase,ahealth-benefitsmodelisusedtocalculatetheeconomicvalueoftheresultingmortalityandmorbidityeffects.
Wheredose-responserelationshipsarenotwellestablished,aswithCO,onepossibleapproachistoestimatethepopulationatrisk.
Thehealth-benefitsmodelisbasedonthedamage-functionapproachtoestimatingbenefits.Beginningwithbaselinedataandprojectedchangesintheconcentrationofspecificpollutants,dose-responsefunctionsfromepidemiologicalandpopulationdataareusedincalculatingchangesinavarietyofhealthendpoints.Theeconomicvalueofthesebenefitsisthenestimated,basedonhealthbenefitsfrompublisheddata.Themodelaggregatesthebenefitsassociatedwithprojectedchangesinpollutantconcentrations.Eachofthesecalculationsisperformedusingstatisticalandjudgmentalconfidenceintervalsonthecoefficientsofthedose-responseandvaluationfunctions.Theresultingrangesofimpactsandbenefitsarepropagatedusingthecrudebutcommonapproachofmultiplying"low"healthimpactestimatesby"low"values,"high"impactsby''high"values,and"expected"impactsby"expected"or"best"values.
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TheCaseofThailand
SummaryDataandKeyFindings
Applicationofthehealth-benefitsmodelisillustratedina1994WorldBankstudyonThailandthatanalyzesthepotentialhealthimpactsofa20percentreductionofambientconcentrationsofvariouspollutants.Tables5.1through5.4showtherangeandbestestimatesofthehealthimpactsassociatedwithsuchachangeinBangkok.Table5.5summarizestherangeofhealthbenefitsofsuchareduction.
Table5.1Bangkok:EstimatedImpactsonMorbidityandMortalityof20PercentReductioninAmbientConcentrationsofSPM
ReductioninnumberofcasesperyearHealthimpacts Low Mid High
Restrictedactivitydays 3,300,000 5,330,000 8,370,000Emergencyroomvisits 3,120 34,600Asthmaattacks 322,000 5,800,000 51,300,000Chronicbronchitisinchildren 863 78,600 156,000Chroniccoughinchildren 537 90,700 181,000Respiratoryhospitaladmissions 3,450 14,900Respiratorysymptomsdays 159,000,000 200,000,000 251,000,000Mortalityreductions
SchwartzandDockery(1992a)-SPM 152 405SchwartzandDockery(1992b)-SPM 459 761
Note:SPM=suspendedparticulatematter.Source:1994WorldBankdata.
Table5.2Bangkok:EstimatedImpactsonMorbidityandMortalityof20PercentReductioninAmbientConcentrationsofLead
ReductioninnumberofcasesperyearHealthimpacts Low Mid High
ReductioninIQpointsinchildren 16,000 26,700Hypertensioninadultmales Nonegiven 9,500 NonegivenCoronaryheartdiseaseeventin10year Nonegiven 677 Nonegiven
MortalityreductionsNeonatalmortality Nonegiven 4.27 NonegivenAdultmalemortality(in12years) Nonegiven 846 Nonegiven
Source:1994Worldbankdata.
Table5.3Bangkok:EstimatedImpactsonMorbidityof20PercentReductioninAmbientConcentrationsofSO2
ReductioninnumberofcasesperyearHealthimpacts Low Mid High
Coughingbychildren 15,900 152,000 288,000Chestdiscomfortinadults 6,630 169,000 331,000Source:1994WorldBankdata.
Table5.4Bangkok:EstimatedImpactsonMorbidityof20PercentReductioninAmbientConcentrationsofO3
ReductioninnumberofcasesperyearHealthimpacts Low Mid High
Minorrespiratory-relatedrestrictedactivitydays 32,400 239,000 489,000Anysymptom-day 762,000 1,930,000 3,090,000Asthmaattacks 16,200 59,300 101,000Eyeirritationdays 1,790,000 2,430,000 3,070,000Coughingdays 436,000 1,060,000 1,700,000Coughincidents 5,110,000 8,830,000 13,000,000Shortnessofbreath 3,390,000 7,600,000 11,800,000Discomfortinchest 3,170,000 6,490,000 9,940,000Source:1994WorldBankdata.
Table5.5SummaryofHealthBenefitsof20PercentImprovementinAirQualityinBangkok
Pathway:impact Total($million) Healthbenefits(1989)percapita(s)Particulates:mortality 1381,315 18169Lead:mortality 302309 3940Lead:morbidity 68 0.81Sulfurdioxide:morbidity 0.2 <0.1Ozone:morbidity 936 15
TOTAL 7463,138 96402Source:1994WorldBankdata.
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Themodelsuggeststherangesofbenefitsfromreductionofdifferentairpollutants.Therangesindicatetheuncertaintiesinherentinsuchanexercise.Theestimatesareindicativeoftheorderofmagnitudeofexpectedbenefits,andthelowlevelsshowexpectedminimumbenefits.Yetdespitesuchlimitations,thestrikingfeatureoftheseestimatesisthatthehighestbenefitswouldcomefromreductionsinconcentrationsofSPMandlead.Thus,thelowestimatesofbenefitsfromreducingleadexceedthehighbenefitsofreducingambientSO2orozone.ThedisparityinbenefitsreflectsthemuchhigherambientlevelsofparticulatesandleadrelativetoSO2andozone.Moreover,exposuretothesehighlevelsofSPMandleadcausesdeath,makingreductionofthesepollutantsfarmorevaluablethanreductionsoftheillnessesthatresultfromexposuretoSO2orozone.
LimitationsoftheModel
Threefeaturesofthemodel,however,maylimititsvalue.Thesepertaintotheprocessoftransferringthedose-responseandvaluationfunctionsdevelopedinonecountrytoanother.
ProblemsinTransferabilityofDose-ResponseFunctionsfromDevelopedtoDevelopingCountries.First,althoughthedose-responsefunctionsarerecentandemploystate-of-the-artstatisticalandsurveytechniques,theywereestimatedforspecificregionsoftheUnitedStates.ThemostseriousdifficultyinapplyingthemtoBangkokisthattheepidemiologicalstudiesonwhichtheyarebasedalsoinvolvedtheUnitedStates.Thesestudieslinkchangesinambientconcentrationstohealtheffects,withanassumedlinkbetweentheamountofapollutantactuallyinhaledbyapersonduringagivenperiodanditsambientconcentration.Totheextentthatpeopleactuallybreathemorepollutedairperperiod(exposureordose)forgivenambientconcentrationsofpollutants,theseepidemiologicalstudiesunderestimatetherelationshipindevelopingcountries.Thatis,thereisgoodreasonto
believethatexposuretoairpollutantsinBangkokaswellasinthemetropolitanareasofmostdevelopingcountriesishigherbecausepeoplespendagreateramountoftimeonthesidewalksandstreetsandinopenvehiclesthaninU.S.cities(particularlyLosAngeles,thesiteofanumberoftheepidemiologicalstudies).Furthermore,morepeopleindevelopingcountriesliveclosertotrafficarteries.Finally,inferiorhousingandlessuseofairconditioningmeanthatthediffusionofairfromoutdoorstoindoorsmaybegreaterincitieslikeBangkok.
Theproblemsinextrapolatingdose-responsefunctionsarealsoexacerbatedbythepotentialforinaccuracyinestimatingthepredictedhealthimpactscausedbythefactthattheaveragepersoninBangkokislesshealthythantheaveragepersonintheUnitedStates.Lesshealthypersonsaremoresusceptibletopollution-induceddiseases,soadose-responsefunctionforacitylikeBangkokmaybesignificantlysteeperthanonefortheUnitedStates.
ProblemsinBalancingInformationfromLaboratoryandEpidemiologicalResearch.Asecondlimitationisthattheseestimatesexcludethehealthimpactsofairpollutionthathavebeenfoundinlaboratoryandtoxicologicalresearchbuthaveyettobe
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reproducedinepidemiologicalstudies.Note,forexample,thattheeffectsofSO2onhealtharerelativelysmall.ThisisaconsequenceoftheprevailingviewthatparticulateeffectssurpassthoseofSO2wheneverthetwopollutantsaretreatedtogetherinstatisticalanalysis.TheeffectsofSO2throughitstransformationtoacidaerosolscannotberuledout,however,becausethesesulfatesarecountedasparticulates.Thus,somefractionofthebenefitsfromreducingparticulatesinBangkokcouldprobablybeattributedtoreductionsinSO2throughassociatedreductionsinsulfates.
SkewingofDatabyLimitsinSampling.Third,itmaybequestionedaswellwhetherthequalityofthedataresultsinanoverestimationofhealtheffects.Themonitorsusedtogatherdatawerelocatedindensedowntownareasandthereforemayoverestimateeffectsonpeoplewholiveandworkinoutlyingareas.ThismaybeparticularlytrueforleadandSPM,butlesssignificantforozoneconcentrations,whichdispersemorebroadly.Arelatedissueiswork-lossdays,whichagainwerederivedfromU.S.data.AbsenteeratesaregenerallythoughttobelowerinThailandthanintheUnitedStatesbecauseofgreaterpenaltiesimposedonworkersforabsenteeism,soworkdayslostthereforemightbefewerinBangkok.
Notwithstandingitsshortcomings,themodeldoesofferarational,asopposedtoasubjective,basisforevaluatinghealthbenefits.Ideally,ifnewbenefitsmodelsweredevelopedthatmorecloselysimulatedtheconditionsindevelopingcountries,amorerealisticandpreciseassessmentofbenefitscouldbemade.Thedevelopmentofcountryorregion-specificmodelswouldentailsubstantialtimeandcosts.Withcarefuladjustmentoftheinputdata,however,thecurrentmodelcouldbeavaluablebasisfordesigninganairpollutionmanagementprogram.
RelevancetoDevelopingCountries
Themethodologyandthehealth-benefitsmodeldiscussedinthischapterareapplicabletoallcountries,providednecessarychangesaremadeintherelevantcoefficients.ThehealthbenefitsintheThailandstudyassumedareductionof20percentinambientpollutionconcentrations,irrespectiveofwhethertheseconcentrationsexceededpermissiblelimits.Fordevelopingcountries,thepermissibleconcentrationlevelsestablishedbytheWHOaresound.Controlstrategieswouldbedesignedtoaddresspollutantsthatarealreadyatornearthesafelimitsandlikelytoexceedtheselimitsintheforeseeablefuture.
Beforeamajorairpollutionmanagementprogramisputinplace,thevalueofitsbenefitsmustbeassessed,asinthecasestudyofThailand.However,dataonambientpollutionconcentrationswillhavetobeextrapolatedtocoveraperiodofatleast15years,usingamodellinkinggrowthinemissionswithambientairquality.Epidemiologicaldatacoveringaslongaperiodaspossibleshouldbeusedtoidentifymajororchronichealthproblems.Valuationofbenefitsmusttakecognizanceofallthesefactors.
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6OptionsforMitigatingAirPollutionPreviouschaptershaveexaminedtheenvironmentalandhealthimplicationsofvariousairpollutantsandthebenefitsofreducingambientairpollution.Thediscussionhasstressedthatevaluationmodelsmusttakecarefulaccountofthedifferencesintheeconomicandepidemiologicalcontextsofdevelopedanddevelopingcountries.
Similarspecificityisnecessaryinselectingoptionsformitigatingairpollutionbecauseofthevaryingprofilesofpollutionsourcesindevelopedaswellasindevelopingcountries.Inbothdevelopedanddevelopingcountries,themainsourceofurbanairpollutionisthetransportsector.Insomedevelopingcountries,however,industryisalsoakeyurbanairpolluter.Thedifferenceisattributabletothefactthatwhereasdevelopedcountrieshaveforsometimetendedtolocateindustrialplantsawayfromthecentersofcities,developingcountrieshaveallowedandevenencouragedindustriestoclusteraroundpopulouspolitical,commercial,andbankingcenters.Forexample,theBangkokmetropolitanregionaloneencompassessome73percentofThailand'smanufacturingindustries,contributingmorethan50percentofgrossdomesticproduct(GDP).Similarly,largecitiesinMexico,thePhilippines,India,Indonesia,andKoreaallcontainhighconcentrationsofheavyindustries.Hence,mitigatingairpollutioninthecitiesofmanydevelopingcountrieswillrequirelimitingemissionsfrombothstationaryandmobilesourcestolevelsthatwouldnotcollectivelypushconcentrationsofpollutantspastsafelimits.Choosinganyspecificstrategywillrequireabasicappreciationoftheoptionsforreducingbothstationaryandmobilesourceemissions.
OptionsforReducingStationary-SourceEmissions
Developingcountriesalmostuniversallyperceiveindustrializationasthekeytoeconomicprosperity.Duringthelastdecadeinparticular,theyhaveprovidedliberaltaxincentivesfornewindustriesandinsomecasesdismantledurbanandenvironmentalregulationsthatwereconsideredasimpedimentstotheflowofinvestmentcapital.Thebroadeffectofsuchpolicieshasbeentodrawhigh-pollutingindustriesfromdevelopedtodevelopingcountriesand,concomitantly,toacceleratethedeteriorationoftheambientairqualityofmanycitiesinthedevelopingworld.Ifthistrendistobearrested,developing
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countrieswillneedtoidentifyandpursueoptionsforreducingemissionsfromexisting,relocated,andnewindustries.Someofthemoreattractiveoptionsarediscussedbelow.
SwitchingtoNaturalGas
Switchingtocleanerfuelsisoneofthemostcost-effectivestrategiesforreducingemissions,particularlyofSO2andCO2.Thecleanfuelofchoiceisnaturalgas.Korea,whichhasnoreserves,importsnaturalgasforusebyindustriesandinpowerplants.Naturalgascontainsvirtuallynosulfur,andburningitalsoproducesfarlessNOxthancoalorfueloil.Sincenaturalgashasahigherhydrogentocarbonratio,itproducesfarlessCO2,agreenhousegas,thaneithercoalorfueloil.Acombined-cyclepowerplantusingnaturalgasproduces55percentlessCO2thanacoal-firedpowerplantperunitofelectricityproduced.
UsingLow-SulfurCoal
Low-sulfurcoalisanotherfueloptionfordevelopingcountriesdespiteitsenvironmentaldrawbackscomparedwithgas.Ifhigh-quality,low-sulfurcoalcanbeimportedatareasonableprice,newtechnologiessuchascoalwashing(whichcanreducethesulfurcontentofhigh-qualitycoalfrom50percentto20percent)maymakecoalaviableoption.Also,newcombustiontechnologiescanreduceNOxemissionsbyabout50percent.Useoffluidized-bedcombustionorintegrated-gasification/combined-cyclepowergenerationatnewplantshasalsoresultedinsubstantialSO2andNOxcontrol.
Scrubbingofstackgasesfromcoal-firedpowerplantsreducesbothSO2andNOxemissions.Thecostsarehigh,however,especiallyforretrofittingoldplantswithscrubbers.Anotherdrawbackofscrubbersisthattheyproducelargequantitiesofsludgeandlow-gradegypsumwastethatmustbedisposedof.Butscrubberscanremoveabout95percentoftheSO2andbetween70and90percentoftheNOx
producedbycoalcombustion(formoredetail,seeTavoulareasandCharpentier1994).
EncouragingandPracticingConservation
Energyconservationoptionsincludemodernizationofexistingplants,includinginstallationofwasteheatrecoveryequipmenttogeneratesteamorasprocessheat,andimprovementsinefficiency.Identifyingtheseoptionsandtheireconomicandenvironmentalbenefitsrequiresmajorstudiesofexistingfacilities,buttheinvestmentsarerelativelymodestandthebenefitssubstantial.
ExploitingAlternativeEnergySources
Alternativeenergyoptionsincludehydro,wind,solar-thermalandphotovoltaicpower,geothermal,nuclear,andhydrogen.Nuclearpowerandhydropowerarethemostcommonoptions.Manydevelopingcountrieshavedevelopedtheirhydropowerpotentialtoasubstantialextent.Useofnuclearpower,exceptinKorea,hasnotprogressedmuchbecauseofsafetyandenvironmentalconcernsaswellasthelargecapitalrequirements.Forcurrentdataonpromisingrenewableenergyoptions,seeAhmed(1994a).
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OptionsforReducingMobile-SourceEmissions
Optionsforreducingairpollutionfrommobilesourcesincludereplacingoldvehicles,maintainingin-usevehiclesmoreeffectively,usingalternativecleanerfuels,reformulatingfuels,improvingtrafficmanagement,expandingmasstransitsystems,andimprovingroadandhighwaycapacity.Theseoptionsareexploredbrieflybelow.
ReformulatingFuels
Substantialworkhasbeendoneintheindustrializedcountriesonthereformulationoftransportfuelstoreducepollutantemissions.Someofthemoreindustriallyadvanceddevelopingcountrieshavealsoembarkedonsuchprogramsdespitetheircapital-intensity.Abriefintroductiontofuelsreformulationfollows.
Gasoline.Themainpollutantsemanatingfromgasolinearelead,aromatics,benzene,carbonmonoxide,andhydrocarbons.WhencatalyticconvertersweredevisedtoreduceemissionsofCO,HCandNOx,itthenbecamenecessarytoremoveleadfromgasolineaswellbecauseleaddeactivatesthecatalystintheconverter.Theobjectatthattimewasnottoprotecthumanhealth;theharmfuleffectsofleadbecameanissueonlylater.Inaninitialefforttocompensatefortheoctanelosscausedbytheremovaloflead,U.S.refiners,inparticular,increasednaphthareformingcapacityasawaytoincreasehigh-octanearomaticsandbenzenecontentofgasoline.Then,whentheU.S.EPArestrictedthearomaticsandbenzenecontentofgasoline,refinershadtomakeadditionallargeinvestmentstocompensatefortheconsequentlossinoctane.
Currently,severaltechnologicaloptionsareavailabletocompensateforleadloss.Ifreformingaloneisinadequate,isomerizationoralkylationprocessescanbeused.SomeU.S.citiesthosedesignatedasCOorozonenonattainmentareasarenowrequiredduringthewinter
monthstoaddoxygenatestogasoline;thesehelptocompletethecombustionprocessandboostoctane.Methyltertiarybutylether(MTBE)istheoxygenateofchoice.
Ingeneral,developingcountriesconsumerelativelysmallquantitiesofgasoline,andhencethetotalamountofleadreleasedisalsolow.Regulationsmandatingremovalofleadthusmaynotbeofhighpriorityinsuchcontexts,particularlybecausetheinvestmentsneededtoreformulategasolinetocompensateforleadlossarehigh.Itmustberemembered,however,thatleadcanhaveseriouseffectsonhumanhealth.Thus,anydecisionregardingthepermissiblelevelofleadmustbemadeaftercarefulevaluationofthelikelyimpactofchange.Ifthereisanyevidencethatleadisaproblem,itsremovalshouldhavethehighestpriority.
Diesel.Mostdevelopingcountries,areheavyconsumersofdieseloil.ReformulatingdieseloilbyreducingitssulfurcontentwilldecreasetheemissionsofSO2andconsequentlyofsulfatesthatcontributetoelevatedconcentrationsofSPM.Inaddition,reductionintherefiningprocessoftheheavierhydrocarbonfractionsindieseloilbyreducingthetemperatureatwhich90volume-percentofthedieseloilisdistilled(therebyeliminatingagreaterproportionoftheSPM-formingdieseloilcomponents)will
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decreasetheformationofSPM10micronsorlessindiameter.Thecostofreformulatingdieseloilishigh,butbecausedemandfordieseloilishighandtheambientSPMconcentrationsarealsohigh,reformulationofdieseloilwilllikelymerithigherpriorityindevelopingcountriesthanreformulationofgasoline.
UsingAlternativeFuels
Liquefiedpetroleumgas(LPG)andcompressednaturalgas(CNG),whereavailable,canbecost-effectiveandenvironmentallybeneficialoptionsformanydevelopingcountries.However,theiradoptionastransportationfuelshasbeenslow,primarilybecauseoftheirlimitedavailabilitycomparedwithgasolineanddieseloil.
LimitingVehicleEmissions
Twootheroptionsareend-of-tailpipecontrols,suchascatalyticconvertersthatreduceexhaustemissions,andvehicleemissionstandards:
Catalyticconverters.Thetwotypesofcatalyticconverterscommonlyinuseareoxidationortwo-waycatalysts,whichreduceCOandHCemissions,andoxidation/reductionthree-waycatalyststhatcontrolNOxemissionsaswell.Formanydevelopingcountriescatalyticconvertersarenotahighpriority.Theycanaddabout$600tothecostofamediumsizecar(whichisabout3to5percentofthepriceofsuchavehicle)andsubstantiallyincreasethecostoflargervehicles.
Emissionstandards.ExperienceinOECDcountrieshasshownthatemissionstandards,ifenforced,cansignificantlyreduceairpollution.Effectiveinspectionandmaintenanceproceduresmustalsobeestablishedandimplemented.Thisisdifficultformostdevelopingcountries,otherthanfornewvehicles.Suchstandards,however,areimperativeforpublictransitvehicles.
ImprovingRoadInfrastructure
Congestedurbanroadsaresignificantsourcesofurbanairpollutioninallcountriesparticularlyduringpeakhours,whentrafficslowstoacrawl.Yetdevelopingcountriesinparticularoftenfindthatimprovingtheirroadinfrastructuretorelievetheproblemisnearlyimpossiblebecausetheirmetropolitanareashaveoftenexpandedsohaphazardlyastomakesignificantroadcapacityimprovementsalogisticandeconomicnightmare.Improvingroadinfrastructureisalsocostlybothintermsofcapitalrequirementsandtimetakentoimplementprojects,butwhenitispossible,itshouldtakeprecedenceoverothercapital-intensiveoptions.
EnhancingTrafficManagement
Alesscostlyapproachtorelievingtrafficcongestionisbyenhancingtrafficmanagement.Theurbanareasofdevelopingcountriesareplaguedbylargenumbersofvehiclesoninadequateroads,lackofsufficientparkingfacilities,undisciplineddrivers,frequentvehiclebreakdowns,andpoorlydesignedtrafficmanagementplans.Improvedpracticesformanagingtrafficcouldreducecongestionsignificantlyindeveloping
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countries.Animprovedplancouldincludesuchincentivesanddisincentivesasrestrictinguseofmainarteries,encouragingcarpooling,providingincentivestousepublictransport,improvingpublictransitsystemsorestablishingnewones,taxingcarsenteringcitylimits,andimposingsteeperparkingfees.
Disincentivessuchastaxationandincreasedvehicleorparkingfeesarelikelytobeunpopular.Therefore,majorpublicrelationseffortsmayberequiredtoeducatepeopleabouttheconsequencesoftrafficcongestionandairpollution.Withoutatrafficmanagementstrategy,developingcountrieswillseecontinuedincreasesinmotorvehicleusenegateairqualitygainsfromotherprograms.Trafficmanagementandroadimprovementsthusshouldbestudiedsimultaneously,andbothshouldhavehighpriorityinanystrategytoreduceairpollution.
DevelopingMassTransit
Masstransitsystemsarehighlycapitalintensive,andtheyareunlikelytoyieldaprofitunlesstheirconstructionandoperationaresubsidizedbythestate.Arecentstudyof20masstransitsystemsimplementedinrecentyearsindevelopingcountriesfoundthatnoneofthemwasprofitableinpurelyeconomicterms(Allportandothers1990).However,hadhealthbenefitsbeenfactoredintothisassessment,thesystemswouldlikelyhaveshownaneteconomicbenefit.Carefulproposalevaluationthatincludesthehealthbenefitscouldthereforeprovidejustificationforneededstatesubsidies.
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7TowardanAirQualityManagementProgramAsthisreporthasargued,theimportanceofmaintainingambientairqualityatacceptablelevelscannotbeoveremphasized.Thereporthasdiscussedthesourcesandcausesofdifferentpollutants,thespecificimpactofemissionsonambientconcentrationsofairpollutants,andtheresultingadversehealthandenvironmentalimpacts.Theneedtomitigatethedetrimentaleffectsofpollutantsisbeyonddispute.Yetbecausetheeffectsofabatementmeasuresoftentakesometimetobecomeevident,theircostsandbenefitsareseldomfullyappreciated.Theresultisfrequentlyapolicyof''benign"inactionthatenduresuntilpollutionbecomesunbearableandirreversible.Thathashappenedinmanycities,perhapsmostnotablyinMexicoCityandBangkok.Unfortunatelyfordevelopingcountries,theideahasbecomeprevalentthatattentiontoenvironmentalmattersmusttakeabackseattoimprovedeconomicconditions.ArecentarticleinTheEconomist("AllthatGas"1994),forexample,suggestedthatincomesmustreachanannualthresholdofUS$5,000percapitabeforeairqualityandenvironmentalissuesbegintoattractattentionandconcern.Thisnotionneednotandshouldnotbetakenasinevitable.
Thischapteroutlinessomeessentialstepsneededtodevelopacost-effectiveandtimelyairqualitymanagementprogram.Manyofthedetailsofsuchprogramsmustbedecidedanddevelopedatthenationallevelineachcountryandcannotbedetailedhere.Butanumberofvitalcommonrequirementscanbeidentified.Hence,thechapterfocusesondevelopmentofanappropriatelegalframework,adequateinstitutionalarrangements,andsufficientmanpowerresourcestoensureproperdesignandcontinuityofprograms.Italsostressestherequirementsforevaluatingtheentirerangeofoptionsand
forcreatingintegratedprograms.Clearly,concertedeffortsbytheinternationalcommunityarealsonecessarytosupporttheadaptationandimplementationofairqualitymanagementprogramsinthedevelopingworld.
LegalFrameworkandInstitutionalArrangements
Pollutionisdirectlyrelatedtoindustrialandeconomicactivity,andenvironmentalproblemswillincreasewithdevelopmentregardlessofacountry'spercapitaincomelevels.Themosteffectiveabatementprogramsthusmustproceedinvirtuallockstep
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withtheexpansionofindustrialandeconomicactivities.Putanotherway,itishardlyevertooearlyinthedevelopmentcycletoestablishenvironmentalstandards,regulatorymeasures,andframeworksforcomplianceandenforcement.Theneededstandardswillcoverambientairqualitylevelsaswellasemissionlevelsfrommobileandstationarysources.Atthesametime,inawell-conceivedand-executedprogram,economicactivitieswillbedesignedfromthegroundupsothatpollutionemissionsonaregionalornationalbasisdonotputthehealthofpeopleatriskorharmtheenvironmentwithinacountry'sboundariesorbeyondthem.
Ensuringahighlevelofairqualityplanning,management,andenforcementrequiresaneffectivelegalfoundationembodyingnationalvalues,laws,andprecedents.Inaddition,ifthegoalsofprovidingasafeandsalubriousenvironmentaretomovefromstatutetoreality,airqualityandpollutionmanagementeffortswillrequirestronginstitutions,competenttechnicalandmanagerialstaff,andcleargovernmentmandates.
Manydevelopingcountrieshavealreadybeguntodraftenvironmentallawsandtoestablishthenecessaryinstitutions.Yet,toooften,mitigationandcomplianceeffortsarefragmentedbyinternecinepoliticalandbureaucraticconflicts.Itisnotunusual,forexample,tofindthreeormoreinstitutionswithoverlappingjurisdictionsissuingcountervailingdirectivesandcompetingoverlimitedresources.Tosomeextent,theinvolvementandcooperationofmanyinstitutionsinmitigationeffortsisdesirableandevenessential,giventhatpollutionproblemsgenerallyhavecross-sectoralcausesandimplications.Buteffectivemanagementwilllikelyrequirethatanoverarchingresponsibilityisfirmlyplacedwithanagencygivenspecificauthorityfordeveloping,coordinating,andmonitoringenvironmentalprograms.Anagencyoragenciesshouldalsobeidentifiedasresponsibleforensuringcomplianceandenforcement.
Ongoingmanagementofairandenvironmentalqualityarenecessarilynationalresponsibilities.RatherthansimplyadoptamodeldevelopedforacityintheUnitedStates,forexample,eachdevelopingcountryultimatelywillhavetoevolveitsownpollutionmanagementmodel,basedonitsdistinctivepatternsofeconomicgrowth,demography,geography,andpublicpriorities.This,inturn,willrequiretheresponsibleagenciestohavecompetenceinthetechnicalandpolicyaspectsofenvironmentalmanagement.Theywillneedtodevelopdispersionmodels,correlateepidemiologicaldatawithambientpollutionconcentrations,andusethisdatatodevelopcost-effectiveintegratedairpollutionprograms.
Theywillalsoneedtoquantifyandevaluatethebenefitsofincreasedproductivity,reductionsinmortality,andimprovementsinthequalityofliferesultingfromairqualityimprovementsothatthemodelcandevelopandadapttochangingprioritiesandpatternsofgrowth.Stafftrainingthusmustbeatthecoreofanyprogramtomitigateairpollution.Similarly,environmentalagenciesmustdevelopthecompetenceandinstitutionalclouttomobilizetheneededresources.
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DevelopinganIntegratedProgramtoManageAirPollution
Puttinginplaceanintegratedairpollutionmanagementprogramandmeetingallinstitutional,staffing,training,andequipmentrequirementscouldtakeadecadeormoreinmanydevelopingcountries.YetmanyareasinSouthAsia,EastandWestAfrica,andLatinAmericahavealreadyreachedcrisisornear-crisislevelsofdegradationinairquality.TheycannotaffordtowaitforadecadetocountertheilleffectsofleadandSPM.Therecommendationssketchedbelowthusareintendedtoassistcountriesinaddressingairpollutionconcernsanddevelopingstrategiesimmediately.
IdentificationoftheAirPollutionProblem
Assessment.Thestartingpointforanyabatementprogramisanaccurateassessmentofcurrentambientairquality.Ifreliabledatadonotexist,andiflocalcollectionandadequateanalyticalskillsarenotathand,specializedfirmswiththenecessaryequipmentandstaffareavailable.Ideally,airqualityatcriticalpointsshouldbemonitoredoverayeartoaccountforseasonalvariationsinwinddirection,precipitation,andtemperature.Alternatively,monitoringcanbedoneoverthreetosixmonthsifitcaneffectivelyprovidedatarepresentativeofambientairpollutionconcentrationsthroughouttheyear.Asthestudyhassuggested,themostlikelypollutantsforstudywillbeCO,CO2,NOx,SOx,SPM,HC,andlead.Analysisofthecollecteddatashouldhelpidentifyspecificpollutantsthatareabovepermissiblelevels.
ProjectionofEmissionsGrowthandDevelopmentofaModel.Theassessmentexercisemustbefollowedbyaprojectionofthelikelyfuturedimensionsoftheproblem.Thisworkshouldbeginwithassessmentsofcurrentemissionsandintegrateexpectedchangesinthelevelsofthesepollutantsoveratleasta10-yearperiod.Estimating
thechangesinemissionswillrequireprojectionsofchangesinpassengertransportmiles,shiftsfromautomobilestomasstransportsystems,andalterationsinlikelyvehiclespeedsstemmingfromchangesinvehiclepopulationsmeasuredagainstimprovementordegradationofthetransportinfrastructure.
Emissionmodelsthatcanpredictlikelyambientconcentrationsofpollutants,basedonprojectedemissions,shouldthenbedeveloped.Thisdatacouldthenbeusedtoidentifypollutantspeciesatriskofexceedingstandards.
CorrelationwithEpidemiologicalData.Epidemiologicaldatafromhospitalsandotheragenciesshouldbethestartingpointforidentifyinglinkagesbetweenambientpollutionlevelsandchronicoracutehealthproblems.Wheredocumenteddataarenotavailable,healthrecordsofpatientsfrommetropolitanareascanbeexamined.Formonitoringpurposes,establishmentofalaboratorycapableofgauginghumanexposuresandtoxicitylevelswillberequired.Thisphaseofdatagatheringwillconstituteacriticalphaseindevelopingameaningfulairqualitymanagementprogram,innosmallmeasurebecauseitbeginstheworkofputtingahumanfaceonthedata.
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ValuationofPollutionImpactsandBenefitsofReduction.Thebenefitsofreducingpollutioncanbeprojectedclearlyonlyafteractivitiesdescribedintheprecedingparagraphshavebeencarriedout.InThailand,forexample(seechapter5),theprojectedhealthbenefitsofa20percentreductionofpollutionwerethebasisforillustratingthedimensionsoftheproblemandwinningsupportformitigationefforts.Airqualitymanagementprogramswilllikelybemostsuccessfuliftheyincludesimilarassessmentstojustifythenecessaryexpenditures.
MitigationOptionsandStrategies
Asdiscussedinthereport,airpollutionistheresultofmanyfactors.Eliminatingthesefactorsorreducingtheireffectsrequiresapplyingadvancedtechnicalskillsandsubstantialcapital.
LeadasaCaseExample.Thesophisticationrequiredforasuccessfulmitigationstrategycanbeillustratedbyadiscussionoftheproblemsinremovingleadfromgasoline(theprimarysourceofleademissionsinmetropolitanareas).Ofcourse,theleadcouldsimplyberemovedornotaddedtobeginwith,butthiswouldreducetheoctanevalueofgasoline,causingmechanicalandemissionsproblems.However,themostcommonoptionsforcompensatingforthelostoctanehavetheirowndrawbacks.Moreseverereformingofgasolineincreasesoctanebutalsoincreasesemissionsofcarcinogenicaromaticsandbenzene.Addinghigh-octane-valuelightendsalsoincreasesoctanebutatthecostofincreasingvaporpressureandhydrocarbonemissions.Evenaddingoxygenatesmaybeproblematic,assomearehighlyvolatileandtoxic.
Otheroptionsforreducingleademissionsmayrequirecomplextechnicalandsocioeconomicstrategies.Forexample,moreefficientvehicledesignswillresultinlowerconsumptionofgasoline,andamoreefficientin-cityroadandtrafficsystemwillincreasevehicle
speed,reducegasolineconsumption,andtherebylowerleademissions.Amasstransitsystemwouldshiftautomobilepassengerstoamoreefficienttrainsystem,thusreducingtrafficcongestionandpollution.Similarly,trafficmanagementorenergydemandmanagementstrategiescanbeeffectiveinreducinggasolineconsumptionandtherebyreducingtheemissionoflead.Alloftheseoptionscutacrosssectorsandoftenrequirelarge-scaleplanningandinvestment.Inshort,manyoptionsareavailableforreducingemissionsofleadandmostotherpollutantsandeachoptionhascriticaltimeandcostfactors.
ShapeofaStrategy.Clearly,awell-designedairqualitymanagementprogrammusteffectivelyweighthemanyfactorsinvolvedinthechoiceofmitigationoptions.Themostimportantofthesefactorsarecosts,implementationtime,theepidemiologicalimpactofthedifferentpollutants,andtheexpectedbenefits.Onthebrighterside,actionstoreduceonepollutantareoftenlikelytohavethebeneficialeffectofreducingotherpollutantsaswell.Forexample,reductionoftrafficcongestion,mayreducenotonlyleadbutallotheremissionslinkedtocombustionoftransportfuels.Addressingonepollutant
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atatime,ontheotherhand,maybecounterproductiveandultimatelytooexpensive.Anintegratedandcomprehensiveapproachisneeded.
Thekeytothedevelopmentofasuccessfulprogramisitstechnicalandeconomicfeasibility.Establishingrealisticgoalsbasedondemonstrableurgencyisessentialtoobtainthefundsrequiredfromwithinacountry'sownresourcesandfrominternationalagencies.Anewmasstransitsystem,forexample,mayreducetrafficcongestion,buttheinitialcostsofsuchsystemsaregenerallyhigh,andimplementationmaytakealongtime.Moreover,aspointedoutinchapter6,areviewof20masstransitsystemsshowedthatnonewasprofitableunlessthehealthandenvironmentalbenefitswerecarefullyfactoredinastheywouldhavetobetohaveanyhopeofjustifyingthenecessarystatesubsidies.
Acomprehensiveanalysisandapproachdoesnotmeananattempttosolveallproblemssimultaneously.Suchanapproachislikelytobesocomplexandexpensivethatitstopstheprogramaltogether.Amorepracticalstrategyistosetcoreprioritiesbyrankingpollutantsinorderoftoxicity,adversehealtheffects,andresultingcoststotheeconomy.Thisallowsplannerstoidentifysecond-orthird-stageactivitiesforimplementationaseconomicconditionsimproveorastheadverseimpactsofotherpollutantsbegintoincrease.
RoleofInternationalAssistance
Establishingrigidnationalorinternationaltargetsorstandardswithoutappropriateprogramstoachieveobjectiveswouldbeasfruitlessasdictating,say,thatacountryshouldsimplydoubleitsGDPinayear.Internationalagenciescanplayafruitfulrolebyprovidingtechnicalassistancetohelpcountriesdevelopenvironmentalmanagementprograms.Sustainedmitigationeffortsmustremainanationalresponsibility,butinternationalagenciescanhelpcountriesidentifyandfulfilltheirinstitutional,staffing,training,equipment,and
laboratoryrequirements.
Intheinitialstageofinternationalassistance,priorityobjectivesmayincludeestablishingprogramstomeasureambientairquality,developingepidemiologicaldata-gatheringsystems,establishingstandardsforambientairquality,identifyingcurrentandlikelyfutureairpollutionproblems,developingmodelstomeasuretheimpactofemissions,establishingtargetsforpollutionreduction/containment,andvaluingthepotentialbenefitsofreducingpollutionandthecostsofinaction.
AnencouragingprecedentforsucheffortsistheMexicoCityairpollutionprogram.Inthiscase,WorldBankstafftooktheleadroleandcalledonassistancefromothertechnicalspecialistsandeconomistsasrequired.Amonitoringpanelwasalsoformedtoreviewtheworkofthespecialists.Theresultingprogramhasbecomeabasisforseveralsimilarprogramsinothercountries.Mostdevelopingcountrieswillrequiresimilarteamefforts,evenifnotonthescaleoftheMexicoCityprogram.
Althoughdevelopingcountriesaccountformorethan60percentoftheworldpopulation,theycurrentlyaccountforlessthan30percentoftheworld'semissionsof
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greenhousegases.Butifmitigationmeasuresarenotestablished,theirsharewillsoonexceedthatofthedevelopedcountries.Greenhousegasesfromdevelopingcountrieswillalmostdoublewithin10years.Itisthusclearlyintheinterestofbothdevelopedanddevelopingcountriestocontainorreversethegrowthofgreenhousegasemissions.
Internationalfinancialassistancemayberequiredtobuildairpollutionmitigationmeasuresintoexistingprojectsortoincorporatethemintonewprojects.Generally,projectswillnotbeabletoabsorbthesignificantadditionalcosts,andtheeffectofpassingtheincreasesontoconsumers(particularlyforfuelssuchasdiesel,whosepriceaffectsprimarilylow-incomeconsumers)couldbesociallyandpoliticallydisastrous.Confrontedbydomesticunrest,governmentsinseveraldevelopingcountrieshavealreadyhadtoretreatfromplanstoeliminateconsumerenergysubsidiesortoimplementfullycost-reflectiveenergytariffs.
Concessionaryfundingarrangementsmaybeanessentialtoolinanefforttopromoteabatementandminimizecosts.Sucharrangementswouldlikelyrequirecountriestohaveintegratedairqualitymanagementprogramsthatcaptureallfactorscontributingtoairpollutionandrankoptionsformitigation.Fromtherankingwouldflowmutualdecisionsregardingfundingofmitigationactivitiessuchashighwayimprovement,fuelsreformulation,trafficmanagement,andsoon.Ofcourse,systematicmitigationeffortsareamajorundertaking,evenifsubsidized,andthedetailsoffinancing,management,andimplementationinvitesubstantialfurtherdiscussion.
Itremainsclearthatacloserrelationshipbetweencountriesandinternationalagenciesonhowtocombatairpollutionisneeded,andthatresults-oriented,integrated,airqualitymanagementshouldreceivehighpriorityintheplansofalldevelopingcountries.
Ultimately,integrationofalllocalairqualitymanagementeffortswillbeessentialifglobalproblemssuchasgreenhousewarming,acidrain,andozonedepletionaretobebroughteffectivelyundercontrol.
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GlossaryAcidrain:RainfallthathasapHlessthanabout5.6,thevalueobservedwhenpurewaterissaturatedwithatmosphericcarbondioxide.Acidraintypicallycontainssulfuricacid,nitricacid,orboth.
Aerosol:Asuspensionoffinesolidorliquidparticlesingasorair,suchassmoke,fog,andmist;also,theparticlesthatmakeupthissuspension.
Airquality:Ambientpollutantconcentrationsandtheirtemporalandspatialdispersions.
Aldehydes:AnorganiccompoundcontainingtheC=Ogroup,generallyrepresentedas&obc:,whereRmaybeanaliphatic(q.v.)oraromatic(q.v.)compound.
Aliphatics:Agroupofstraightchainedhydrocarbons.Typicalaliphaticsareethanol,methanol,propane,andformaldehyde.
Ambientairquality:Theexistingstateoftheatmosphericpollutioninanoutdoorarea.
Ambientstandards:Thosestandardsconcernedwiththeoverallairqualitysurroundingacommunityoranindustrialarea;theseareusuallysetataleveldeemedsufficienttoprotectpublichealth.
Aromatics:Agroupofcyclicallystructuredhydrocarbonsofwhichbenzeneistheparent.Theyarecalledaromaticsbecausemanyoftheirderivativeshavesweetaromas.Thesehydrocarbonsareofrelativelyhighspecificgravityandpossessgoodsolventproperties.Certainaromaticshavevaluableanti-knock(octane)characteristics.Typicalaromaticsarebenzene,toluene,andxylene.
Benzene:Apurearomatichydrocarbon(q.v.)ofcharacteristicodor
occurringinsignificantproportionsincertainFarEasterncrudeoils.
Catalyst:Asubstancethataffectstherateofareactionwithoutbeingusedupitself.
Catalyticconverter:Adevicebuiltintotheexhaustsystemofanautomobilecontainingacatalystgenerallymadeupoffinelydividedplatinum(Pt),rhodium(Rh),andpalladium(Pd),whichconvertscarbonmonoxide(CO)tocarbondioxide(CO2);unburnedhydrocarbonstoCO2andwater(H2O);andnitrogenoxide(NO)tonitrogendioxide(NO2),nitrogen(N2),andoxygen(O2).
Chlorofluorocarbons:ThesecompoundsarealsoknownasfreonsandconsistofCFCl3andCF2Cl2.Mainlyusedasrefrigerants,theyareasourceofchlorineatomsintheupperatmosphere.
CleanAirAct:U.S.Congressionalactsandamendmentstopromoteimprovementsinairquality.
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Conformityofproduction:Thisreferstothetestingofsamplevehiclesfromaproductionruntodeterminewhetherthevehiclesmeetestablishedemissionsstandards.
Dispersion:Themannerinwhichatmosphericpollutantsareconveyedanddilutedbywindandturbulentmixing.
Dollars:AllpricesandcostsinthisreportareexpressedinU.S.dollars.
Effluent:Pollutantmaterialsdischargedintotheenvironment.
Emissionrate:Therateatwhichpollutantsarereleasedfromanexhaustsystem.
Emissionstandards:Standardsforpollutantsfromspecificsources,suchassmokestacks,ventilationsystems,andautomotiveexhaustsystems.Itisalegallimitontherateofsuchemissions.
Globalpollutants:Damagecausedbyglobalpollutantsisevidencedworldwide(e.g.,throughglobalwarming).Thegreenhousegases,whichincludecarbondioxide,nitrousoxide,methane,ground-levelozone,andchlorofluorocarbons,areoneclassofglobalpollutants.
Greenhouseeffect:Theabsorptionofoutgoinginfrared(IR)radiationbywatervaporandcarbondioxide,whichtherebyraisestheearth'stemperature.
Hydrocarbons:Materialscomposedentirelyofcarbonandhydrogen.Thecarbonatomsmaybeinlinear(aliphatic)orring(aromatic)formations.
Inspectionandmaintenance(I/M):AU.S.emissionstestingandinspectionprogramimplementedinnonattainmentareas(q.v.)toensurethatvehiclesmeetemissionsstandards.
Inversion(thermalinversion):Areversalofthenormalatmospheric
temperaturegradientwherethetemperatureincreaseswithaltitude.
Localpollutants:Theseincludelead,sulfuroxides,particulatematter,carbonmonoxide,ground-levelozone,andnitrogendioxide.Damagecausedbythemisevidencedinthevicinityofemissions.Alocalpollutantmayalsobearegionalpollutant(q.v.).
Naphtha:A"cut"coveringtheendofthegasolinerangeandbeginningofthekerosenerange.Itisfrequentlyusedasafeedstockforreformingprocessesandisalsoknownas"heavybenzene"or"heavygasoline.''
NationalAmbientAirQualityStandards(NAAQS):PollutantstandardsdevelopedbyU.S.EnvironmentalProtectionAgency.
Nonattainmentarea:Anareathathasnotmetorisunlikelytomeetnationalambientairqualitystandards.
Octanenumber:Thisisameasureofgasoline'santi-knockvalue.Thehighertheoctanenumber,thehighertheanti-knockqualityofgasoline.
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Ozone:Abluishirritatinggasofpungentodor.ItisanallotropicformofoxygeninwhichthemoleculeisO3.
Photochemicaloxidants:Toxicgases,mainlycolorless,thatareproducedinthepresenceofsunlightfrominteractionofhydrocarbonsandnitrogenoxides.Ozone,formaldehyde,peroxylnitrate,acrolein,andperoxybenzoicnitrateareexamples.
Photodissociation:Dissociation(asofNOx)undertheinfluenceofradiantenergy.
Pointsource:Asingleoriginofemissionsstationedatafixedpoint.
Pollutant:Acontaminant,orforeignspecies,presentinasample;usuallyhasadeleteriouseffectonqualityofsampleasfaraslivingthingsareconcerned.
Primarypollutant:Achemicalcontaminantemitteddirectlytotheatmospherebyasource.
Primarystandard:ThisisaspecificationsetbytheNationalAmbientAirQualityStandards(q.v.)toprotecthumanwelfareandhealth.
Reforming:Aprocessinwhichstraight-runfeedstocks(e.g.,naphtha)aresubjectedtohightemperaturesandpressureswiththeobjectofchangingtheirchemicalstructureinsuchawayastoincreasetheiroctanenumber(q.v.).
Regionalpollutants:Regionalpollutantsaresulfuroxides,nitrogenoxides,andozone.Aregionalpollutantmayalsobealocalpollutant(q.v.).Damagecausedbyregionalpollutantsoccursatsignificantdistancesfromtheemissionpoint.
Secondarypollutant:Atmosphericcontaminantsformedbychemicalprocesses,suchashydrolysis,oxidation,andphotochemicalreactions.
Smog:Smokyfogcontainingharmfulspecies,suchassulfurdioxide
(SO2),sulfurtrioxide(SO3),nitrogendioxide(NO2),andozone(O3).
Stratosphere:Theupperportionoftheatmosphere,from10to50kmabovetheearth'ssurface.
Troposphere:Theportionoftheatmospherebetweentheearth'ssurfaceandthestratosphere.
Ultravioletradiation:Lighthavingawavelengthgreaterthanabout10nmbutlessthan400nm.
Volatileorganiccompounds:Reactivehydrocarbonsemittedbyfossil-fueledmotorvehicles,evaporationofsolventsandgasoline,chemicalmanufacturing,petroleumrefining,andtoalesserdegreefromwastedisposalsitesandwastewatertreatmentplants.
Wavelength:Acharacteristicpropertyoflight,similartoitscolor,andequaltothelengthofafullwave;oftenexpressedinnanometers(nm).
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