2001 triazole derivatives

triazole derivativesR 0280

49 - 092A Tandem of the Cornforth Rearrangements of 4-(1,2,3-Triazol-1-yl)iminomethyl-1,2,3-thiadiazole. — A facile method for the synthesisof dimethylmorpholinothiadiazolecarbaldehyde (V) is given. Its reaction withsodium triazoloate (VI) follows a tandem of the Cornforth rearrangement tofurnish triazolylcarbamoyltriazolate (VII) instead of the expected title imine.— (GLUKHAREVA, T. V.; MORZHERIN, YU. YU.; SAVEL’EVA, E. A.;ROZIN, YU. A.; TKACHEV, A. V.; BAKULEV, V. A.; Russ. Chem. Bull. 50(2001) 2, 268-271; Ural State Tech. Univ., Ekaterinburg 620002, Russia; EN)

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