ecology and environment, inc

ecology and environment, inc' 'ernaticnai Specialists :n tê '~r\forwent

' ;verleat Building J - '405 Mr-ten1*Overland Park. Kansas <•>•""?'•i\ ;913) 432-9561 •' \\ j':•'; 4:il_'

M E M O R A N D U M

TO: Paul Doherty, EPA START/PO

FROM: Gary Murphy. E & E/STM .-

THRU: Robert C. Overfelt. CPG. E & E/START PM

DATE: March 7, 1999

SUBJECT: Removal Assessment: Container Recvclinc, Kansas Citv, Kansas

TDD: S07-9708-004PAN: 0610CRSFXXCERCLIS ID NO : KSD065764995SSID: 07Z5EPAOSC: JimMacDonald

INTRODUCTION

S00134203SUPERFUND RECORDS

The Ecology and Environment. Inc. lE & E). Superrund Technical Assessment and Response Team(START) was tasked by the U.S. Environmental Protection Agency (EPA) Region 7 Superrund Division

(SUPR) to assist with a removal assessment at the Container Recycling, Inc.. site in Kansas City, Kansas.

This facility operated as a drum reconditioning and recycling taciiity from 1965 until Novernoer 1996.

Subsequent to cessation of operations, the company filed for bankruptcy.

As part of the current removal assessment being conducted by the EPA and START, sources for the

surface soil lead contamination (as determined by subsurface and surface sampling) are being sought.

Material safety data sheets (MSDS) for paint products currently on sue will help determine if lead-bearing

paint residues were accepted by Container Recycling. To obtain the MSDS sheets, the manufacturer

(predominantly Pratt and Lambert) requires a product number from each container of paint material. The

GM/PJW 06IOCRSFXX/9708-004/rep2

product numbers are located on the drum or the lid, or are affixed as part of a drum label. This

information will be collected by START and submitted to the manufacturer.

SITE BACKGROUND

Background

The Container Recycling site is located at 1161 South 12th Street, in the Armourdale District of Kansas

City, Kansas. The 20-acre site is situated in an industrial area north of the Kansas River's northern levee.

Structures on the site include an office/process facility, a drum deheader building, and a wastewater pre-

treatment facility. The eastern 2 b of the site is strewn with an estimated 67,000 drums (most of which are

empty) and approximately 60 truck trailers, many of which contain empty drums. The facility had operated

as a drum reconditioning and recycling facility from its inception in 1965 until November 1996. The

facility opened in 1965 under the name Great Lakes Container and continued to operate under that name

until it was purchased by Richard Greenwald and Ed Handley in 1986. when the facility name was changed

to Container Recycling, Inc. Prior to development as a drum recycling facility, it was reported that the

site was utilized by a local steel mill in the 1950's and 1960's to dispose of automobile fluff (Barr, 1997).

Fluff is produced when vehicles are shredded to recover recyclable steel. A magnet removes the steel and

the non-metallic fluff is discarded. The fluff fill reportedly averages 15 to 18 feet over most of the site,

except for a small area in the north-central portion. An involuntary Chapter 7 bankruptcy proceeding was

initiated in April 1997 and is currently ongoing. Thousands of drums and an undetermined amount of

process waste remain on the site.

On-Site Activities

On March 3. !(X)°. START members (STMs) Gary Murphy and Brooke Barren mobilized to the site

to obtain product numbers and manufacturer's information from specific drums of paint in the paint storage

area. Table 1 contains product numbers and product information obtained during the field work.

Table 1PRODUCT INFORMATION FROM DRUMMED PAINT WASTE

Container RecyclingMareh 3, 1999

Manufacturer

Pran and Lambert

Pran and Lambert

Pran and Lambert

Pran and Lambert

Pran and Lambert

Pran and Lambert

Pran and Lambert

Pran arm Lambert

Pran and Lambert

Pran and Lambert

Pran and Lambert

Pran and Lambert

Pran and Lambert

Pran and Lambert

Pran and Lambert

Pran and Lambert

Pran and Lambert

Pran and Lambert

Pratt and Lambert

Product Number

524-022

524-024

520-020

526-020

521-020

522-020

521-022

522-030

522-015

526-010

523-020

526-040

523-014

526-030

527-007

546-00222

502-518 63

527-006

522-028

Product Description

Yellow

White

Red

Black

Blue

Phillips Grey

Chevron Blue

Amoco Blue

M-blue

Mobile Red

Total Red

Exxon Red

Green

Total Red

Jacum brown

Enamel Red

3.5VOCDK 3 MBIue

Brown

Harbor Blue

The product numbers were submitted to Sherwin Williams to obtain MSDS sheets for the products

contained in the drums (Pratt and Lambert was acquired by Sherwin Williams in January 1996). All MSDS

sheets are enclosed as Attachment 1 to this report.

According to data gathered from the MSDS sheets, eight of the products stored on-site contain lead

compounds. These products are listed in Table 2.

Table 2LEAD-BEARING PAINT PRODUCTS

Product Number

524-024

524-022

523-014

523-020

•146-002

527-006

526-040

Number ot 55- GallonDrums

1

1/3

2 1/3

-i

two 5-pallon containers

.'4

1'3

Lead Compounds

lead chromatelead as Fh

lead chromacelead sulfate

lead chiomatclead sulfate

lead chromatelead sulfate

lead fatty acid napthenatc complex

lead chromate

lead chromatelead su l fa te

Percent Lead Compound By Weight

9608

15< I

<1< 1

<5< 1

< \

5

5•' 1

CONCLUSIONS AND RECOMMENDATIONS

The actions documented in this report are a portion ot a larger removal assessment currently being

conducted by the EPA and START under the same TDD. Purther information pertaining to this site is

contained in a Removal Assessment Report completed on November 13, 1998.

GM/PJW 06lOCRSFXX/9708-004/rep2

ATTACHMENTS

Attachment 1: Material Safetv Data Sheets

ATTACHMENT 1

Material Safew Data Sheets

GM/pj\v 6 06lOCRSFXX/9708-004/rep2

.rain. CAPEWMANUFACTURER'S NAME

THE SHERWIN-WILLIAMS COMPANY101 Prospect Avenue N.W.Cleveland, CH 44115

DATE ?F PREPARATION:3 -MAR - 9 -

EMERGENCY TELEPHONE .'."0 .

INFORMATION TELEPHONE NO.'216' 5 6 6 - 2 9 C 2

Section I -- PRODUCT IDENTIFICATION

PRODUCT NUMBER KMIS CCDESHealth 2*

524024 Flammability 3Reactivity 0

PRODUCT NAME**** HIGH SOLIDS ****SHELL YELLOW A/C ENL

PRODUCT "LASS

Section II -- HAZARDOUS INGREDIENTS_ NOK ".. — - :'-.» - A.̂ .sj j.: i S H/-i.

'AS N.;. I by WT TLV PEL "NITO V.P.

V. M. u P. Naphtha. 31 300 300 PPM 12.00•: 4742-69-6 STEL 400 PPM

Mineral Spirits. 8 100 100 PPM 2.00T47"i^-cS-

Pine îl. 2 Not Estaoiishea 0.10T 0 0 2 - C 9 - 3

alt 2 -Ethyihexanoate. 0.1 Not Established 0.00136-52-7

Lead Chrcmate. 9 C.05 : .05 MG/M3 0.001344-37-2

Lead as Pb) 6.08 0.15 ",.05 MG/M3Chromium VI is Cr) 1.29 3.C5 MG/M3

Section III - PHYSICAL DATA

PRODUCT WEIGHT -- 8.CG Ib./gal. EVAPORATION RATE -- Slower than EtherSPECIFIC GRAVITY -- C.97 VAPOR DENSITY -- Heavier than Air

BOILING POINT -- 240-435 F MELTING POINT -- N.A.VOLATILE VOLUME -- 54 I SOLUBILITY IN WATER -- N.A.

VOC Theoretical; -- 3.42 Ib. 410 gm. less Federally Exempt Solvents)

Section IV -- FIRE AND EXPLOSION HAZARD DATA

FLASH POINT LEL UEL•31 F TOO 0.9 6.0

FLAMMABILITY CLASSIFICATIONRED LABEL -- Flammable, Flash below 100 F

Tontinuea cr. page 2

.524024

niT»'rt"- HTI ' M i nn ;. LJMJb 1:rarccr. Dioxide, Dry Chemical, Foam

UNUSUAL DIRE AND EXPLOSION HAZARDSKeep containers tightly closed. Isolate from heat, •-iectricai

•="-":ipmer.t , sparks, and open flame. Closed containers may explode when:sed t c extreme heat. Application to hot surfaces requires special

êoauticr.s. During emergency conditions ^verexpcsure ro deccrr.pcsit ionprcauctc- ".ay cause a health hazard. Symptoms may r.ot be immediatelyapparent. Obtain medical, attention.SPECIAL FIRE FIGHTING rROCEDURES

Full protective equipment including sel f • cor.t a : r.ed breathing apparatusshould be used. Water spray nay be ineffective. If water is used, fognozzles are preferable. Water may be used to cool closed containers toprevent pressure build-up and possible autoigr.it ion or explosion whenexposed to extreme heat.

Section V -- HEALTH HAZARD DATA

ROUTES OF EXPOSUREExposure may be by INHALATION and/or SKIN or EYE contact, depending on

conditions :: use. To minimize exposure, follow recommendations for properuse, ventilation, and personal protective equipment.ACUTE Health HazardsEFFECTS DF DVEREXPOSURE

Irritation or eyes, .:'.<ir. and respiratory system. May -ause nervoussvstom decression. Extreme overexposure may result in unconsciousness andpossibly death.

Acute occupational exposure to Lead is uncommon, but results in effectsand svm.ptcms similar to chronic overexposure described be^cw.SIGNS"AND SYMPTOMS OF CVEREXPOSURE

Headache, dizziness, nausea, and loss of coordination are indications ofcessive exposure to vapors or spray mists.Redness ana itching or burning sensation may indicate ^ye i:r excessive

SKin exposure.MEDICAL /DNDITIONS AGGRAVATED BY EXPOSURE

None generally recognized.EMERGENCY AND FIRST AID PROCEDURES

If INHALED: If affected, remove from exposure. Restore breathing.Keep warm and quiet.

'.i r. SKIN: Wash affected area thoroughly with soap and water.Remove contaminated clothing and launder betcre re-use.

I r in EYES: Flusn eyes with large amounts r.r water tor 1L minutes.Get medical attention.

If SWALLOWED: let medical attention.

:ntinuea on page 2

524 G 24 oaqe'

,-nrcnic overexposuro - Lead may result: ir. asmaaS !* M.6

nervous, .irir.ary, and reproductive systems ' ir.ciudir.a embryctcxic effects; .Symptoms include abdominal discomfort or pain, constipation, loss of- -etite, metallic taste, nausea, insomnia, nervous irritability, weakness,

:le and joint pains, headache and dizziness.Cobalt and cobalt compounds are classified by I ARC as possibly

carcinogenic to humans ^rcup 23) based on experimental animal data,however, there is inadequate evidence in humans : or its carcinogenicity .

Ohrcmates are listed by I ARC and NTP . Although studies have associatedexposure to Chromium VI compounds with an increased risk of respiratcrvcancer, available evidence indicates that Lead "hrcmate Chrome Yellow,Xoiybdate Orange; DOES :."CT present this hazard.

Proicnged cverexposure tc solvent ingredier.tc ::: Section II may causeadverse -ffeots to the liver and urinary systems.

Reports have associated repeated and prolonged ~verexposure to solventswith permanent brain and nervous system damage.

Section VI -- REACTIVITY DATA

STABILITY •- StableCONDITIONS TO AVOID

None ,-;nown .INCCMPATI5ILITY

None .-'.nown.-•~r7-'-T-—'-^ — " ̂ r^ VDr^CTr^1"r'^>vT ~ C r^"^' -,'~"" c;;n/jr\t\^ ̂ ̂ ^ ^ n, ̂O.̂ .rOo » . ̂ _ i-i .- r<- U ̂ „ C » b

3y fire: Carbon Dioxide, Oarbon Monoxide, :xides of Metals in Section IIHAZARCC'CS POLYMERIZATION

Will not occur

Section VII -- SPILL OR LEAK PROCEDURES

.PS TO BE TAKEN IN CASE MATERIAL IS RELEASED CR SPILLEDRemove ail sources of ignition. Ventilate and remove with inert

absorbent.WASTE DISPOSAL METHOD

Waste from this product may be hazardous as defined under the ResourceConservation and Recovery Act RCRA) 40 CFR 2G1.

Waste must be tested fcr ignitability and •-•xtractabii ity - c determine• r.e ioci i cacle E?A hazardous waste numbers.

'. ::c ir.ei ate : n approved facility. Do not incinerate 'icsed container.Liscose :i in accordance with Federal, State, >na L^cai regulationsreaaroina ociiuticn.

Section VIII -- PROTECTION INFORMATION

Continued on page 4

I 52*02* page 4

PRECAUTIONS TO BE TAKEN IN USE•iercre initial use, rcnsult CSHA's Standard fir r.ccucat i .inai Exposure to

-eaa :. 3 CFR 1310.102SI.".*se only with adequate ventilation. Avoid breathing vapor and spray

~- ~t . .-.void contact with skir. and eyes. Wash hands atter '..sing.This coating may contain materials classified as nuisance particuiates

_^sted "AS Cust" in Section III which may be present at hazardous levelsonly v.;rir.̂ sanding or abradir.q of the dried film. If no specific dustsare .istea in Section II, the applicable limitc for nuisance dusts areACGIK TLV 1- m,g./m.3 'total dust , 3 mg./m3 respirable traction: , OSHA PEL15 '.r.'-. . T.3 total dust1 , 'i mg.,'m.3 'respirable traction, i .VENTILATION

Local, exhaust preferacie. General exhaust acceptable if the exposure tomaterials in Section II is maintained below applicable exposure limits.Refer to OSHA Standards 1310.34, 1910.107, 1310.108.RESPIRATORY PROTECTION

If personal exposure cannot be controlled below applicable limits byventilation, wear a properly fitted organic vapor/particuiate respiratorapproved by NIOSK/MSKA for protection against materials in Section II.

When sanding, wirebrushing, abrading, burning or weldina the dried film,wear a particuiate respirator approved by NICSH/MSHA for protection againstnon-volatile materials in Section II.PROTECTIVE GLOVES

Wear jloves which are recommended by glove oucdier i~r : rotectionagainst materials in Section II.EYE PROTECTION

'Wear safety spectacles with unperforated siaeshieids.

Section IX -- PRECAUTIONS

DOL STORAGE CATEGORY1C

jlCAUTICNS T2 BE TAKEN IN HANDLING AND STORINGContents are FLAMMABLE. Keep away from heat, sparks, ind open flame.During use and until all vapors are gone-. Keep area ventilated - Do not

smoke - Extinguish all flames, pilot lights, and heaters Turn off stoves,electric tools and appliances, and any other sources of ignition.

Consult NFPA Code. Use approved Bonding and Grounding procedures.Keep container closed when not in use. Transfer only to approved

containers with complete and appropriate labelina. To not take internally.Keep out or the reach cr children.:THER PRECAUTIONS

CONTAINS LEAD. Do not apply on toys and other children's articles,furniture, or any interior surface of a dwelling cr facility which may beoccupied cr used by children. Do not apply on any exterior surface ofdwelling units, such as window sills, porches, stairs, or railings to whichchildren may be commonly exposed.

Intentional T.isuse by deliberately concentrating and inhaling thecontents can be harmful or fatal.

Section X -- OTHER REGULATORY INFORMATION

,J ^ TI> ;* ~ " ~ : *'1 ^ TT D.DrtKA J^J tJ ^rK

TAS No.

SUPPLIER NOTIFICATIONCHEMICAL /COMPOUND bv WT % Element

Chromium CompoundCobalt Compound.Lead Compound.

lontinued on page 5

0 . 1q

1 .30 .06 . 1

, ^ZiO^-: page 5": i j j r==-================ = = = = = = = = = = = = = « = « = = = = = = = = = = = = = = = = = = = = = = = = = = = = = = = = -

CALIFORNIA ?ROPOSIT:CN ^5WARNING: This product contains chemicals known to the State cf

California to cause cancer and birth defects or other reproductive harm.~^CA CERTIFICATION

All chemicals in this product are listed, cr are exempt from listing,y.

The above information pertains to this product as currently formulated,.ind is based on the information available at this time. Addition ofreducers or other additives to this product may substantially alter thecomposition and hazards of the product. Since conditions of use arecutside cur control, we make no warranties, express or implied, and assumeno liability in connection with any use of this information.

PRATT & L,!MBERT 316-733-1361Industrial coating civ.1?1 rnrospect AvenueCleveland,

w v**» u wurnDOT EMERGENCY CHEMTEL (800)255-3924 (24hrs>INFORMATION PHONE NO. 216-566-2902 (M-F 8 AM-5 PM CT)

CORPORATE CONTACT 216-566-2917 (M-F 8 AM-5 PM CT)

H.M.I.S.HEALTHFLAMMABILITY

REACTIVITY1*3

ratings fihdfl ft? UCMpart of * u l l y imciementea H.M.I.S. program.

M A T E R I A L S A F E T Y D A T A S H E E T

SECTION I

PRODUCT CLASS I L K Y D , " E D 1 U M - L O N G

TRADE NAME .... H I G H S O L I D S * * * * C A T Y E L L O W A / 0 D R E N L

MANUFACTURER CODE I .D . S 2 4 0 2 2 7 5

REVISED ON 1 1 / 0 7 / 9 6

8 0 1 0 -M A N U F A C T U S E R C A G E 6 1 1 9 6 C O N T R A C T

SECTION II - HAZARDOUS INGREDIENTS

INGREDIENT % BYWOT

CAS NO./NIOSH*

ALLOWABLEEXPOSURE LEVEL

SARA313

VPmm Hg

20 DEC.

N A P T M A ( ? E T R O L E U M )H E A V Y A L < Y L A T E

P E T R O L E U M H Y D R O -: A R B o >. M I X T U R E. E A D C - ' C M A ' E

>A T E

S O L V E N T- 6 5 - 7 M F R

3 0 3 2 - 3 2 - 4 T L V - T U A316180000 O S H A - P E L

1 5 " 5 8 - 9 7 - 6 - L V - T U A= I G M E N T G B 2 9 7 5 0 0 0 C S H A - P E L

O S H A - C E I L

P I G M E N T

S O L V E N T

- 1- - 2 T L V - TUAO S H A - P E L

8 0 0 0 - 4 1 •

PPM MG/CU.M.

100 525

100 525100 525

0 . 0 1 2 00 . 0 5 0 00 . 1000

0. 15000 .0500

NONE E S T A B L I S H E D

MPPCF SKIN

S < 1 N - S K I S A B S O R P T I O N M U S T 3 E C O N S I D E R E D A S A R O U T E O F E X P O S U R EC E I . 1 N G = A L L O W . E X P O S U R E L E V E L S H O U L D N O T B E E X C E E D E D - O R A N Y T I M E P E R I O D

; R r M A N U F A C T U R E R R E C O M M E N D E D E X P O S U R E L I M I T., ; E ; - S H O R T ' E R M E X P O S U R E L I M I TX - S A R A 3 ' 3 = C H E M I C A L I S S U B J E C T T O R E P O R T I N G R E Q U I R E M E N T S O f S E C T I O N 3 1 3OF < '. T L £ ! '. I CF S . A . R . A . i 0 CFR P A R T 372•» I 0 S H » - N i O S H R E G I S T R Y O F T 0 X 1 C E F F E C T S OF C H E M I C A L S U B S T A N C E S N U M B E R .

SECTION III - HEALTH INFORMATIONEFFECTS OF SHORT TERM OVEREXPOSURE

SWALLOWING- ,1 t e r ' i

INHALATION"ay c a L

e n t r .1 l- a u b e a

EYEM a y

SKIN

s e q a s t ^ c i n t e s t• " t o . j n g nay

s e n o s e o r t r - r o an e r v o u s s y s t e m

a n a c o n f u s i o n .

n a i • r r ic a u s e e n

t • - r i t ad e p r e s s )

t a t i o n , - a u s e a , and v o m i t • n q . A s p i r a t i o n o*e m i c a i c n e u m o n i t ' s » n i c n c a n D e t a t a l .

t i c n . H i q h r c n c e n t r a t i a n s n a y c a u s e a c u t eo n c h a r a c t e r i z e d o y n e a a a c n e s , d i z z i n e s s ,

c a u s e e y e i r r i t a t i o n .u a y

EFFECTSa u s e d e f a t t i n q a n d

OF REPEATED OVKREXPOSUREi r r i t a t i o n o f t h e

^ e o c a t e d a n a p r o l o n g e d•nay c a u s e t u n g c a n c e r .; n r o n i c D v e r e x p o s u r e t

o v e r e x p o s u r e t o r e l a t i v e l y i n s o l u b l e c h r o m a t e s

„ r i n a r yr e x p o s u r e i n c

' e r v o u s. v ei n x

a n du d e

J c c u p a^ r e x i sR e p o r tt o s o l• i i s u s ea r m f

e t v ,t p a i

o n s t i p a t if i n e t r

o n ,e m o r

o n a l e x p o s u r e ti n g K i d n e y c o n d iM a v e a s s o c i a t e d

e n t s w i t h c e r m a nc y d e l i b e r a t e l yo r t a t a l .

SIGNIFICANT LABORATORY DATA WITHC h r o m i u m a n d c e r t a i n c hD y T h e N a t i o n a l T o x i c o l. e a a c i r o m a t e h a s b e e nI n t e r n a t i o n a l A g e n c y f o

l e a d m a y r e s u l t i n s e v e r e d a m a g e t o b l o o d f o r m i n g ,e p r o d u c t i v e s y s t e m s . S o m e c o m m o n s y m p t o m s o f c h r o n is s o f a p p e t i t e , m e t a l l i c t a s t e i n t h e m o u t h ,n a u s e a , w e a k n e s s , n s o m n i a , l e a d a c h e , m u s c l e a n ds , n u n b n e s s , d i z z i n e s s , n y p e r a c t i v i t y a n d c o l i c ,o l e a d i s r e g u l a t e d b y O S H A - 2 9 C F R 1 9 1 0 . 1 0 2 5 .t i o n s m a y b e a g g r a v a t e d b y e x p o s u r e s t o l e a d .p r o l o n g e d a n d r e p e a t e d o c c u p a t i o n a l o v e r e x p o s u r e

e n t b r a i n a n d n e r v o u s s y s t e m d a m a g e . I n t e n t i o n a lc o n c e n t r a t i n g and • n n a t i n g the c o n t e n t s may be

POSSIBLE RELEVANCE TO HUMAN HEALTH.r o m i u m c o m p o u n d s a r e l i s t e d a s p o t e n t i a l c a r c i n o g e ro g y P r o g r a ml i s t e d a s a p o t e n t i a lr R e s e a r c h o n C a n c e r .

a n i m a l c a r c i n o g e n b y t h e

SECTION IV - FIRST AND EMERGENCY PROCEDURESALLOWING

: f s w a l l o w e d d o r o t ' n d u c e v o m i t i n g . C a l l p o i s o n c o n t r o l c e n t e r , h o s p i t a l

5 2 4 T 5 2 2 7 3 DATE 1 1 / 0 7 / 9 6

fiEOTIOH IV - FIRST AID A^BBIBHW PROCEDURES; (CONTINUED)SWALLOWING

e m e r g e n c y - o o m o r p h y s i c i a n i m m e d i a t e l y .INHALATION

R e m o v e t o f r e s h a i r i m m e d i a t e l y . I f b r e a t h i n g h a s s t o p p e d , g i v e a r t i f i -c i a l r e s p i r a t i o n . < e e p » a r m a n d q u i e t . G e t n e d i c a i a t t e n t i o n i m m e d i a t e l y .: I u s h M i t h l a r g e a m o u n t s o f w a t e r , l i f t i n g u p p e r a n d l o w e r l i d s o c c a s i o n a l -v . C o n t i n u e f o r a t . e a s t 1 5 m i n u t e s . G e t m e d i c a l a t t e n t i o n

SKINR e m o v e c o n t a m i n a t e d i . o i h i n g . W a s h a f f e c t e d a r e a w i t h s o a p a n d w a t e r .O b t a i n , m e d i c a l a t t e n t - s n i f i r r i t a t i o n p e r s i s t s .

NOTES TO PHYSICIANA n y t r e a t m e n t t h a t f i g h t t e r e q u i r e d f o r o v e r e x p o s u r e s h o u l d b e-! i r c c t c d at the c o n t r o l cf s y m p t o m s ond the c l i n i c a l c o n d i t i o n s .

SECTION V - PHYSICAL DATABOILING RANGE

FREEZING POINT:VAPOR PRESSURE:VAPOR DENSITY

EVAPORATION RATES l o w e r r n a n d i e t h y l e t h e r

WEIGHT L B . / G A L . 3 . 9S P E C I F I C G R A V I T Y 1 . 1

1 6 5 O E G . F . ( 7 i , D E G . C . ) T O 4 1 4 D E G . F . (

- 5 0 D E G . ' . ( - 4 5 D E G . C . )

1 mm u g a 68 D E G . F.(20 D E G . C.)

H e a v i e r t h a n a i r . % VOLATILE BY VOLUME b2

VOC 3 . 3 5 Ib/gal lees water &

VOC 6.98 Ib/gal

2 1 2 O E G . C . )

-02 g/1 less watarC A l

8 3 8 g / 1 anlifte C A L C U L A T E D

APPEARANCE i ODOR:

VISCOSITY:

- i q u i d , S o l v e n t o d o r

No i n f o r m a t i o n ' o u n a

SOLUBILITY:

PH:

S l i g h t • n w a t e r

- • 7 ; S T D U N I T S )

All Physical data determined at 68 DEG. F. (20 DEG. C.) 760 iron Hg« Negligibly Photochemically Reactive MaterialsVOC values reported here are verif ied by ASTM method D-3960______

SECTION VI - FIRE AND EXPLOSION DATAF L A M M A B L E L I Q U I D - C L A S S : C

( 3 4 D E G . C , ) C A L C U L A T E D

DECOMPOSITION TEMP ' 8 3 2 D E G . F . ( 1 0 0 0 D E G . C . )

MAGNETISM N o t a p p l i c a b l e

NFPA FLAMMABILITY CLASSIFICATIONFLASHPOINT 93 D E G . F ,

OIGNITION 5 7 2 D E G . F . ( 3 0 0 D E G . C . )

JRROSION RATE s o t a p p l i c a b l e

N E T EXPLOSIVE W G T . N o t a p p l i c a b l e

EXTINGUISHING MEDIAU s e N F P A C l a s s 8 F i r e e x t i n g u i s h e r s ( c a r b o n d i o x i d e . a l l p u r p o s e d r y c h e m ic a l o r a l c o h o l f o a m ) d e s i g n e d t o e x t i n g u i s h f l a m m a b l e l i q u i d f i r e s . P o l y -m e r ' o a m i s p r e f e r r e d f o r l a r g e f i r e s .

UNUSUAL FIRE AND EXPLOSION HAZARDSd u r i n g e m e r g e n c y c o n d i t i o n s , o v e r e x p o s u r e : o a e c o m p o s t i o n p r o d u c t s m a yc a u s e a h e a l t h h a z a r d . S y m p t o m s m a y n o t a e i m m e d i a t e l y a p p a r e n t . O b t a i n-n e a i c a i a t t e n t i o n .. A R N i N G i F L A M M A B L E .

SPECIAL FIRE FIGHTING PROCEDURES• a t e r m a y b e i n e f f e c t i v e , b u t m a y b e u s e d t o c o o l e x p o s e d c o n t a i n e r s t op r e v e n t p r e s s u r e b u i l d - u p a n d p o s s i b l e a u t o - i g n i t i o n o r e x p l o s i o n w h e ne x p o s e d t o e x t r e m e h e a t . I f__w a t e r i s u s e d , f o g n o z z l e s a r e p r e f e r a b l e .

SECTION VII - REACTIVITY DATANEUTRALIZING AGENT N o i n f o r m a t i o n f o u n d

STABILITYN o r m a l l y s t a b l e .

CONDITIONS TO AVOIDA v o i d e n c e s s i v e h e a t ( > 1 1 5 F (46 C) and s o u r c e s of i g n i t i o n .

INCOMPATABILITY (MATERIALS TO AVOID)S t r o n g a c i d s o r a l k a l i n e m a t e r i a l s .

HAZARDOUS DECOMPOSITION PRODUCTSB u r n i n g , ' n c l u d i n g w h e n h e a t e d b y w e l d i n g o r c u t t i n g , w i l l p r o d u c e s m o k e ,c a r b o n m o n o x i d e n n d c a r b o n d i o x i d e . I n a d d i t i o n , o x i d e s o f c h r o m i u m. o x i d e s o f l e a d , m a y b e g e n e r a t e d .w e l d i n g , b r a z i n g , o r t o r c h c u t t i n g m a t e r i a l s c o a t e d w i t h t h i s p r o d u c t m a yp r o d u c e m e t a l o x i d e s . O v e r e x p o s u r e t o t h e s e m e t a l o x i d e s m a y r e s u l t i n" M e t a i > u m e f e v e r " . S y m p t o m s i n c l u d e a f l u - l i k e i l l n e s s w i t h f e v e r , c h i l l sa n d c o u g h . A n a i r p u r i f y i n g o r s u p p l i e d a i r r e s p i r a t o r m a y b e r e q u i r e da e p e n a i n g u p o n l e v e l s o f e x p o s u r e . C o n s u l t a q u a l i f i e d h e a l t h a n a s a f e t yp r o f e s s i o n a l .

HAZARDOUS POLYMERIZATIONw i l l n o t o c c u r

:ONDITIONS TO AVOIDN o n e K n o w n

5 2 « 2 2 7 3PAGEDATE 1 1 / 0 7 / 9 6

SECTION VIII - ENVIRONMENTALGTEPS TO BE TAKEN IF MATERIAL IS RELEASED OR SPILLED

«, e e p s p e c t a t o r s a w a y . Els u r f a c e s , a n d s o u r c e s o fD i k e a n d c o n t a i n s p i l l w i

i m i net

a t e all i

l i q u i d s tw i t h i n e rm a t c r i a i so f s e w e r sa b s o r b e n t

WASTE DISPOSALD 1 S D 0 S C

RCRA CLASSIFICATION

a l , s t a tm a t e r i a

r e a r, e tr D e n t .

c o v ea b s on c o v e r e ds t r e a m s ,

a iU

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l e c t r i ch i n e r t

c o n t a i n e r so n l y n o n - s p a

l c o n t a i n e r sr o u n d w a t e r w i

f o

t • c ni c oI ( c

r r e c or k i n g

o u r c c s ( f l a m e s , h o tf r i c t i o n a l s p a r k s ) .

e a r t h ) . I r a n s fr e m o v e

• g .e • y0 0 l S

a n dap

s p o s a , . •>' . l e d n a t e

s p o s aa c ee v ei a l

a b s o r b e n t d i k i n go n t a m iu s e a

n a t ion

n a c c o r d a n c e w i t h f e d e r a l s t a t e a n d o c a I e g u l a t i o n s

T h ias hT h i sD a s e dd e g .T h i s- l o r e

s p r o d u c ta z a r d o u sp r o d u c t

- \ i t sd e g . C

a I a r d o u bo u I a c

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r o m i u m W a s t eF R P a r t 261

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ENVIRONMENTAL HAZARDSN o n e x n o w n

SECTION IX - PERSONAL PROTECTION INFORMATIONRESPIRATORY PROTECTION

R e f e r t o O S H A s t a n d a r d•or i c a d , 2 9 C F R 1 9 1 0 . 1P r o p e r ' . e l e c t i o n o f r e• n c l u d i n g d u r a t i o n / l e ve x p o s u r e t o o r g a n i c c hn o t • • e Q U ' r e t h e u s e o f,1'eas. I n r e s t r i c t e d v• e s p i r a t o r iray De r e q u'-. e c n a n i c a l p r c f i I t e r mu S H A . i p p r o v e d a : r s u p pj r e e x c e e d e d use a proa p p r o p r i a t e p r o t e c t ' o nP r o t e c t ' o n " , ana " R e s p1 n a u s t r • a i h y g i e n e Ass

VENTILATIONR e f e r t o O S H A s t a n d a r d, e a d - 2 9 C c R 1 9 1 0 . 1 0 2 5 .P r o v i d e g e n e r a l d i ; u t ia n a p a t t e r n t o K e e p c oS e c t i o n : : b e l o w t h e Ip r o d u c t s t h a t a r e g e n ec o a t e d w i t h t h i s p r o d uR e c o m m e n d e d P r a c t i c e "

HAND PROTECTIONS o l v e n t ' m p e r m e a b l e g l

EYE PROTECTIONU e a r s a f e t y s o e c t a c l e s

OTHER PROTECTIVE EQUIPMENTA s r e q u i r e d t o p r e v e n t

' o025s p ie le m ir e

e n t

s p e c i f i c r e s p i r a t o r y p r o t e c t i o n r e q u i r e m e n t s

r ao fc as pi I

t o r y p r o t e c t i o ne x p o s u r e ana c

I s s u c h a si r a t o r y p r o

d e p e n d s u p o nn a i t i o n s o f

f

• ai v

a t i o n a r e a si - n Q e r c e r t a

s o b e r e q u i rr e s p i r a t o r .

t h ot e cai ne d

s e c o n t a i n e do n i0 S Ho n d i'. n ch e T

u s e d

f a c t o ri t t e d N I O S H / M S H A

R e fi r a t o r y P r o t

e r t o O S H Ae C t l o n A M

i 9a n u a

a p p r ot i o n so n t i nL V ' sp p r o v

C F R

iv e d

m a n yu s e . 1n t h i sn w e l l v ec h e m i c a

a c t o r sg e n e r a

p r o d u c t m a yn t i I a t

s u c he d a r e a. ' s t e de d r e s p• 9 1 0 . 1 3

s Ps e aS e c tt o r

c a r ta y i n

e dr i d g eg , a

N 1 0 S H /

A n d G u i d e

i o n I Iw i t h a n

R e s p i r a t o r ye , A m e r i c a n

f o r s p e c i f i c v e n t i l a t i o n r e q u i r e m e n t s

o n a n d l o c a ln c e n t r a t i o n so w e s t e x p o s u r e l i m i tr a t e d w h e n w e l d i n g , cc t . R e f e r t o " I n d u s t r

A C G I H .

e x h a u s t v e n t i l a t i o n i n s u f f i c i e n t v o l u m eO f h a z a r d o u s ' n g r e o i e n t s . i s t e d i n

s t a t e d . R e m o v e d e c o m p o s i t i o n•j t t i n g b r a z i n g ) e c t sl a l V e n t i l a t i o n M a n u a l o f

o v e s a r e r e q u i r e d f o r r e p e a t e d p r o l o n g e d c o n t a c t

k i n c o n t a c t S e e O S H A t a n d a r d f o r l e a d

SECTION X - SPECIAL PRECAUTIONSPRECAUTIONS TO BE

- 0 " o t , t 0 r: j m o i i j P c e

OTHER PRECAUTIONSDo not t a n eK e e p a w a y tD ow a sf m pC o nD oM e v

nhttne

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r ea sn tr se Ie

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TAKEN IN HANDLING AND STORAGEe a b o v e ' ' 5 a c g . F (46 d e g . C ) s t o r e , , i r g e a u a nw i t h C S H A 2 9 C F R 1 9 1 0 . 1 0 6 .

i n t e r n a l l y . C l o s e c o n t a i n e r a t t e r e a c h u s e .r o m c h i l d r e n .tais,r

h e s a n d i n g d u s t .n d f a c e t h o r o u g h l y b e f o r e e a t i n g o r d r i n k i n g .n e r s m u s t n o t b e w a s h e d a n d r e - u s e d f o r a n y ph o u l d b e g r o u n d e d a n d b o n d e d t o t h e r e c e i v i n gb r a z e o r c u t o n e m p t y c o n t a i n e r .

e s s u r e t o e m p t y . D r u m i s n o t a p r e s s u r e v e s s

t • t • e s

u r p o s e .c o n t a i

e I .

• n

n e r .

SECTION XI - OTHER INFORMATION

SECTION XII - TRANSPORTATION DATAP R O

3 0 1

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v 52

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PAGE 4DATE 11 /07 /96

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1 N 11 N 11 N 11 A 11 A 21 A 11 A2i G

A S T i : C O N T A I N E R SJ N I T C O N T A I N E R ) .

' J I L L U N I T C O N T A I N E R C S L Y U S E D F O R 1 C O M P O N E N T O F

H I SH E

: s TOE S T OF

C E R TO U R

f Y T H A T 'K N O W L E D G E

H I S I T E M I SC O R R E C T .

H A Z A R D O U S A N D I N F O R M A T I O N S T A T E D I S T 0

R E G U L A T O R Y I N F O R M A T I O N S E R V I C E S

T H E ' . ̂ F O R M A T I O N C O N T A I N E D H E R E I N I S B A S E D O N D A T A C C N S I D EA C C U R A T E . W H I L E T H E I N F O R M A T I O N I S B E L I E V E D ' 0 B E R E L I A B LE X P R E S S E D O R I M P L I E D R E G A R D I N G T H E A C C U R A C Y O F T H I S D A T A5 E O B T A I N E D F R O M T H E U S E ' H E R E O F . S I N C E ' H E U S E O F T H I S IC 0 N 0 ' . ' I O N S A N D U S E O F T H I S P R O D U C T A R E C O N T R O L L E D 6 * ' H Eu S E R ' S O B L I G A T I O N T O D E T E R M I N E T H E C O N D I T I O N S O f S A F E U S E

T h , c C o r p o r a t e S a f e t y a n d E n v i r o n m e n t a l A f f a i r s D e p a r" e s p o n s i b t c t o r t i e p r e p a r a t i o n o f t h i s H a t e r • a i S a f e t y

RE0N

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PRATT & LAMBERT 316-733-1361Industrial Coatings Div.101 Prospect AvenueCleveland, OH 44115DOT EMERGENCY CHEMTEL (800)255-3924 (24hrs)INFORMATION PHONE NO. 216-566-2902 (M-F 8 AM-5 PM CT)

H.M.I.S.HEALTH 1 *FLAMMABILITY 3REACTIVITY 0

These rat ings should DO used only.is part c* *u l lv imciemented H .M . l .S . program.

CORPORATE CONTACT 216-566-2917 ( M - F 8 AM-5 PM CT)

M A T E R I A L S A F E T Y D A T A S H E E TSECTION I

PRODUCT CLASS A L K Y D , M E D I U M - L O N G

TRADE NAME .... H I G H S O L I D S * * * * B A R T O N G R E E N A D O R E NMANUFACTURER CODE I . D . 5 2 3 0 1 4 33

REVISED ON ' 1 / 0 7 / 9 6

8 0 1 0 -H A N U F A C T J R E R C A G E 6 1 1 9 6 C O N T R A C T


INGREDIENT % BYWOT

CAS NO./NIOSH#


SARA313

VPrani HQ (

20 DEG.c

N A P T M A ( P E T R O L E ' J M )H E A V Y A . K Y L A T E

X Y L E N E

POLY C M L O R O C C P P E RP H T H A L O C Y A N I E.tAD C H R O M A T E

LEAD S U L F A T E

'AN I DM D I CX IDE.

P E T R O L E U M H Y D R OCARBON M I X T U R E

« I N E R A . S » ! R I " S

-1 N E c : L

PPM MG/CU.M.

SOLVENT64741 - 65 - 7 MFR

5 ',330-20-7 - L V - T U AS O L V E N T 7E2100000 T L V - S T E L

OSHA-PELOSHA-STEL

P ! GHENT

•_ F L 1.0

1328-53-6 HV-TWAOSHA-PEL

100

100150100150

525

435655-35655

UFL

7758-97-6 TL V - T U AP I G M E N T GB2975000 OSHA-PEL

OSHA-CEIL

i ?446-u-2 TLV-TWAP I G M E N T OSHA-PEL

13463-67-7 TLV-TUAPIGMENT XR2275000 OSHA-PEL8032-32-4 T L V - T W A016180000 OSHA-PEL

64742-88-7 T L V - T U AOSHA-PEL

IFL 1 .

100100

100100

0.01200.05000.1000

0. 15000.0500

1010

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MPPCF SKIN

.'•I . O W E S F . A M M A B I L ' i T Y L I M I T P E R C E N Tj F L = U P P E R ^ L A M M A B I L I T Y L I M I T P E R C E N TS K I N = S K I N A B S O R P T I O N M U S T B E C O N S I D E R E D A S A R O U T E O FC - C E ! L I N G = A L L O W . E X P O S U R E L E V E L S H O U L D N O T B E E X C E E D E DM F R = M A N U F A C T U R E R R E C O M M E N D E D E X P O S U R E L I M I TS T E L = S H O R T T E R M E X P O S U R E L I M I TX - S A R A 3 1 3 = C H E M I C A L I S S U B J E C T T O R E P O R T I N G R E Q U I R E M E N T SO F T I T L E I I I O F S . A . R . A . 4 0 C F R P A R T 3 7 2N I O S H * = N I O S H R E G I S T R Y O F T O X I C E F F E C T S O F C H E M I C A L S U B S T A N C E S N U M B E R .

E X P O S U R EF O R A N Y T I M E P E R I O D

O F S E C T I O N 3 1 3

SECTION III - HEALTH INFORMATIONEFFECTS OF SHORT TERM OVEREXPOSTJRE

SWALLOWINGC a n c a u s e g a s t r o i n t e s t i n a l i r r i t a t i o n , n a u s e a , a n d v o m i t i n g . A s p i r a t i o n o fm a t e r ' s l - n t o l u n g m a y c a u s e c h e m i c a l p n e u m o n i t i s w h i c r i c a n b e t a t a l .

INHALATIONM a y c a u s e n o s e o r t h r o a t i r r i t a t i o n . H i g h c o n c e n t r a t i o n s m a y c a u s e a c u t ec e n t r a . n e r v o u s s y s t e m d e p r e s s i o n c h a r a c t e r i z e d b y h c a a a c n e s , d i z z i n e s s ,l a u s e a a n d c o n f u s i o n .

EYEM a y c a u s e e y e i r r i t a t i o n .

SKINM a y c a u s e d e f a t t i n o a n d i r r i t a t i o n o f t h e s k i n .

EFFECTS OF REPEATED OVBREXPOSUREQ y e r e x p o s u r e t o x y l e n e m a y c a u s e i n j u r y t o t h e l i v e r , K i d n e y s . a n db l o o d .R e p e a t e d a n d p r o l o n g e d o v e r e x p o s u r e t o r e l a t i v e l y i n s o l u b l e c h r o m a t e sm a y c a u s e l u n g c a n c e r .C h r o n i c o v e r e x p o s u r e t o l e a d m a y r e s u l t • n s e v e r e d a m a g e t o b l o o d f o r m i n g .

5 2 2 T Q 1 4 3 3J!

DATE 1 1 / 0 7 / 9 6

mm in • mm 1EFFECTS OF REPEATED

n e r v o u s , u " i^ v e r e x c o s u r eci n x i e t y , con

o i n t p a i n ,O c c u p a t i o n a lP r e x i s t i n g kR e p o r t s h a v et o s o l v e n t smi s u s e

a r m t u I

OVEREXPOSUREn a r y » n d r

i n c l u d e . 0s t i p a t i o P, ,' i n e t r e m o re x p o s u r e t

i d n e y c o n d ia s s o c i a t e d

w i t h p e r m a nb y d e l i b e r a t e l y

e pS sn as ,0t 1p

e

r o d u c t i v e s y s t e m s . S o m e c o m m o nc f a p p e t i t e , m e t a l l i c t a s t e i n t h e

u s e a , w e a k n e s s , • n s o m n i a , h e a d a c h e ,n u m b n e s s , d i z z i n e s s , . " y p e r a c t ' v i t y

l e a d is r e g u l a t e d by O S H A - 29 C F Ro n s m a y b e a g g r a v a t e d b y e x p o s u r

y m p t o m st

e s

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o l o n g e d a n d r e p e a t e d o c c u p a t i o n a lnt b r a. i n and n e r v o u s s y s t e m d a m a g e ,

c o n c e n t r a t i n g a n d i n h a l i n g t h e c o n t e n

of c h r o n im o u t h ,™i u s c I e and

a n d c o l i c .' 9 1 0 . 1 0 2 5 .t o l e a d ,o v e r e x p o s u r eI n t e n t i o n a lt s may be

SIGNIFICANT LABORATORY DATA WITH POSSIBLE RELEVANCE TO HUMAN HEALTH.T iT 0o rr e9 rt h0 ft hb ed r-, i.: hD yL e'. n

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dylaoinhIVnatmo

l O x i d e I S N O T ' , i s t e d a s a p o t e n t i a l c a r c i n o g e n b y t h e N a t i o nP r o g r a m , the I n t e r n a t i o n a l A g e n c y 'or R e s e a r c h on C a n c e r , 0

. H . T i t a n i u m d i o x i d e i n a 2 4 - m o n t h ' n h a I a t i o n s t u d y w i t h r a ts i g n i f i c a n t i n c r e a s e i n b e n i g n a n d m a l i g n a n t l u n g t u m o r s i n

s e a t o 2 5 0 m g / M 3 r e s p i r a b l e T i 0 2 d u s t . A t l o w e r e x p o s u r e l e v ef i c a n t e f f e c t w a s n o t o b s e r v e d . T h e n o r m a l c l e a r a n c e m e c h a n ig s m a y h a v e b e e n o v e r w h e l m e d a t t h e 2 5 0 m g / M 3 e x p o s u r e l e v e l ,a v e c o n t r i b u t e d t o t h e t u m o r f o r m a t i o n . " h e s e r e s u l t s m a y n oy r e l e v a n t t o t h e w o r k p l a c e w h e r e o c c u p a t i o n a l e x p o s u r e I i m ie d . A t t h e T L V t h e T i 0 2 m a n u f a c t u r e r c o n c l u d e s t h a t t h e r e i st h a z a r d ' o r m a n .n d c e r t a i n c h r o m i u m c o m p o u n d s a r e l i s t e d a s p o t e n t i a l c a r c i nl o n a l T o x i c o l o g y P r o g r a mate has b e e n I • s t e d as a p o t e n t i a l a n i m a i c a r c i n o g e n by then a l A g e n c y f o r R e s e a r c h o n C a n c e r .

aSsIstt

o

IH A ,

t h es ,m sa n dsn og e n s

SECTION IV - FIRST AID AND EMERGENCY PROCEDURESSWALLOWING

I f s h a l l o w e d d o n o t • n d u c c v o m i t i n g . C a l l p o i s o n c e n t r e . c e n t e r , h o s p i t a le m e r g e n c y " c o m o r p h y s i c i a n i m m e d i a t e l y .

INHALATIONR e m o v e t o f " e s n a i r ' ^ m e d i a t e l y . I f b r e a t h " n g 'ins s t o p p e d , 3 i v e a r t i f i •. • a . - e s p ' r a t i o n . < e e p w a r m a n d q u i e t . G e t r a d i c a l a t t e n t i o n i m m e d i a t e l y

EYE : I u s n « i t h . a r g e a m o u n t s o f w a t e r , l i f t i n g u p p e r a n d l o w e r l i d s o c c a s i o n a li y . C o n t i n u e f o r j t . e a s t ' 5 m i n u t e s . G e t m e d i c a l a t t e n t i o n .

SKINR e m o v e c o n t a m i n a t e d c . o t h i n g . U a s h a f f e c t e d a r e a w i t h s o a p a n d w a t e r .O b t a i n - n e d i c a i a t t e n t i o n ' f i r r i t a t i o n p e r s i s t s .

NOTES TO PHYSICIANA n y t r e a t m e n t t h a t i r i g h t b e r e q u i r e d f o r o v e r e x p o s u r e s h o u l d b ed i r e c t e d a t t h e c o n t r o l o f s y m p t o m s a n d t h e c l i n i c a l c o n d i t i o n s .

SECTION V - PHYSICAL DATAJILING RANGE

FREEZING POINT:

VAPOR PRESSURE:

VAPOR DENSITY

• 6 5 D E G . F . ( 7 4 O E G . C . ) T O 4 1 4 D E G . F . (

50 D E C . : . ( - 4 5 D E C . C.)

5 mm Hg S 68 D E C . F.(20 D E C . C.)

H e a v i e r t h a n a i r . % VOLATILE BY VOLUME 5 4

212 D E G . C . )

EVAPORATION RATES . o w e r t h a n d i e t h y l e t h e r .

WEIGHT L B . / G A L . " . 9S P E C : r ' . c ; , R A v i ; * 3.9

VOC 3 . 4 8 Ib/gal leea water &

VOC 7 . 5 8 Ib/gal solids

APPEARANCE & ODOR: L • q u i a , S o l v e n t o d o r

VISCOSITY: N o i n f o r m a t i o n f o u n d

SOLUBILITY:

PH:

• - 1 8 g/1 less waterCA L

5. 1 o g/1 solids C A L C U L A T E

S l i g h t • n w a t e r

4 - 7 ( S T O U N I T S )

F L A M M A B L E L I Q U I D

All Physical data determined at 68 DEG. F. (20 DEC. C.) 760 mm Hg• Negligibly Photochvmically Reactive MaterialsVOC values reported here are verif ied by A3TM method D-3960______

i________________SECTION VI - FIRE AND EXPLOSION DATANFPA FLAMMABILITY CLASSIFICATION

FLAMMABLE LIMITS ' . 0 X - 7 . 0 %

FLASHPOINT 80 D E G . F ,

AUTOIGNITION 5 7 2 D E G . F . (300 D E G . C . )

CORROSION RATE *otNET EXPLOSIVE WGT.Not

C L A S S I

a p p I i c a b I e

a p p l i c a b l e

( 2 7 O E G . C , ) C A L C U L A T E D

DECOMPOSITION TEMP ' 8 3 2 D E C . F . ( 1 0 0 0 O E G . C . )


EXTINGUISHING MEDIAj s e N F P A C l a s sc a l o r a l c o h o l

' o a m i s p r e f e r r e drner 'oam i s p r e f e r r e d f o r;SDAL FIRE AND EXPLOSION HAZARDS

D u r i n g e m e r g e n c y c o n d i t i o n s

B F i r e e x t i n g u i s h e r s ( c a r b o n d i o x i d e a l l p u r p o s e d r y c h e m io a m ) d e s i g n e d t o e x t i n g u i s h f l a m m a b l e l i q u i d f i r e s . P o l y -

f o r l a r g e f i r e s .

o v e r e x p o s u r e t o d e c o m p o s t i o n p r o d u c t s m a y

5 2 3 C 14 33PAGEDATE 11/07/96

SECTION VI - FIRE AMD EXPLOSION DATA; (CONTINUED)

UNUSUAL FIRE AND EXPLOSION HAZARDSc a u s e h e a l t h h a z a r dT e d i c a i a t t e n t i o n .W A R N I N G ' F L A M M A B L E .

IAL FIRE FIGHTING PROCEDURESw a t e r r r a y b e i n e f f e c t i v e ,p r e v e n t p r e s s u r e b u i l d - u pe x p o s e d t a e x t r e m e h e a t .

S y m p t o m s m a y n o t D C m e d i a e l y a p p a r e n t . b t a i n

out may be u s e d ta n d p o s s i b l e a u t c' w a t e r i s u s e o ,

c o o l e x p o s e d c o n t a i n e r s t oc, n i t ' c n c r e x p l o s i o n w h e ng n o z z i e s a r e p r e f e r a b l e .

! SECTION VII - REACTIVITY DATANEUTRALIZING AGENT No • n « o r n a t i o n f o u n d

STABILITYN o r m a l i v s t a b l e .

CONDITIONS TO AVOIDA v o i d e x c e s s i v e h e a t ( ' 1 1 5 F ( 4 6 C ) a n d s o u r c e s o* • g - i i t


HAZARDOUS DECOMPOSITION PRODUCTSB u r n i n g , i n c l u d i n g w h e n h e a t e d b y w e l d i n g o r c u t t i n g , » ic a r b o n - i c n o x i d e a n d c a r b o n d i o x i d e . I n a d d i t ' c n , o x i d e s o. o x i d e s o f l e a d , m a y b e g e n e r a t e d .w e l d i n g , b r a z i n g , o r t o r c h c u t t i n g m a t e r i a l s c o a t e d w i t hp r o d u c e m e t a l o x i d e s . C v e r e x p o s u r e t o t h e s e n e t a l c - x i d e s" M e t a l • u m e F e v e r " . S y m p t o m s i n c l u d e a f l u - i i k e i l l n e s sa n d c o u g h . A n a i r p u r ' f y i n g o r s u p p l i e d a i r ^ e s p i r a t o r mJ e p e n d i n g u p o n , e v e I s of e x p o s u r e . C o n s u l t > q u a l ' f i e a hp r o f e s s i o n a l .


CONDITIONS TO AVOIDN o n e u n o w n

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m a ynh i l l s ,de t y

SECTION VIII - ENVIRONMENTAL INFORMATIONSTEPS TO BE TAKEN IF MATERIAL IS RELEASED OR SPILLED

«. e e p s p e c t a t o r s a w a y . E l i m i n a t e all i g n i t • c n s o u r c e s ('s u r f a c e s , a n d s o u r c e s : • e l e c t r i c a l , s t a t i c o r f r - c t i o n a^ i * e and c o n t a i n s p i i , w i t h i n e r t m a t e r i a l ( e . g . s a n d , '.'. i q u i d s t o c o v e r e d i r e t a i c o n t a i n e r s f o r r e c o v e r y o r d i s pw i t h - n e r t a b s o r b e n t . „ s e o n l y n o n - s p a r * •. ng t o o l s . r I a c•n a t e r • a i s in c o v e r e d T e t a i c o n t a i n e r s tor d i s p o s a l . * r e vo f s e w e r s , s t r e a m s , > t n d g r o u n d w a t e r w i t h s p i l l e d n a t c r i aa p s o r o e n t .-;TE DISPOSALD i s p o s e • n a c c o r d a n c e w i t h f e d e r a l , s t a t e a n d , j c a i • e g u

.<A CLASSIFICATION" h i s p r o d u c t c o n t a i n s c h r o m i u m . W a s t e ~ e s i d u c i ; t t h i s p r. ] s h a z a r d o u s w a s t e ( - 0 C F R P a r t 2 6 1 . 7 * - C h a r a c t e r i s t i c o• h i s c r o d u c t , i f d i s c a - c e d d i r e c t l y , w o u l d b e c . a s s i f ' c dB a s e d ^ n i t s ' g n i t a p i . i t y c h a r a c t e r i s t i c , ' . e . h a s a f l ad e g . - . ( 6 0 d e g . C ) c r , e s s . T h e p r o p e r R C R A c i a s s i f i c a t i o* " i b p r o d u c t c o n t a i n s i e a d , w h i c h , i f p r e s e n t i n w a s t e an o r e a f t e r b e i n g e x t r a c t e d , i s c o n s i d e r e d F P T O X I C , a n d

, o u ; d b e D 0 0 8 .ENVIRONMENTAL HAZARDS

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R e f e r t o O S H A s t a n d a r d f o r s p e c i f i c r e s p i r a t o r y p r o t e c t i• o r : e a d , 2 9 C F R 1 9 1 0 . 1 3 2 S .^ r o p e r s e l e c t i o n o f ' e s p i r a t o r y p r o t e c t i o n d e p e n d s u p o ni n c l u d i n g d u r a t i o n / l e v e l o f e x p o s u r e a n d c o n d i t i o n s o f ue x p o s u r e t o o r g a n i c c h e m i c a l s s u c h a s t h o s e c o n t a i n e d i n- o t - e q u i r e t h e u s e c f r e s p i r a t o r y p r o t e c t i o n i f u s e d i na r e a s . : - r e s t r i c t e d v e n t i l a t i o n a r e a s a N I O S H a p p r o v e dr e s p i r a t O ' m a y b e r e q u i r e d . U n d e r c e r t a i n c o n d i t i o n s , s um e c h a n i c a l p r e f i l t e r m a y a l s o b e r e q u i r e d . I n c o n f i n e d aH S M A a p p r o v e d a i r s u p p l i e d r e s p i r a t o r . ' , f t h e T . V ' s l i s t. i r e e x c e e d e d u s e a p r o p e r l y f i t t e d N l O S H / M S H A a p p r o v e da p p r o p r i a t e p r o t e c t i o n f a c t o r . R e f e r t o O S H A 2 5 C F R 1 9 1 0P r o t e c t ' o n " , a n d " R e s p i r a t o r y P r o t e c t i o n A M a n u a l A n d G u! n d u s t " • a i H y g i e n e A s s o c . "

VENTILATION• < e t e r t o O S H A s t a n d a r d s f o r s p e c i f i c v e n t i l a t i o n r e q u i r e

; ' r a v i a e g e n e r a l d i l u t i o n a n d l o c a l e x h a u s t v e n t i l a t i o n '

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v o l u m ee p c o n c e n t r a t i o n s o ft h e l o w e s t e x p o s u r e

a n d p a t t e r n t o n e eS e c t i o n i ; b e l o wp r o d u c t s t h a t a r e g e n e r a t e d w h e n w e l d i n g ,c o a t e d w i t h t h i s p r o d u c t . R e f e r t o " I n d u s« e c o t n m e n d e d P r a c t i c e " A C G I H

HAND PROTECTIONw e a r a p p r o p r i a t e i m p e r m e a b l e

E PROTECTION

h a z a r d o u s i n g r e d i e n t s l i s t e d i ni m i t s t a t e d . R e m o v e d e c o m p o s i t i o n

u t t i n g , j r b r a z i n g o b j e c t s• a i V e n t i l a t i o n A M a n u a l o f

g l o v e s ( N o r t h I v e r S h i e l d

w e a r s a f e t y s p e c t a c l e s .

523014 3 3PAGE 4DATE 11/07/96

; '_________SECTION IX - PERSONAL PROTECTION INFORMATION; (CONTINUED)OTHER PROTECTIVE EQUIPMENT

» s r c a u i r e d t : p r e v e n t ' • . < i n c o n t a c t . See C S H A . t a n a a ~ d I e a a .

SECTION X - SPECIAL! PRECAUTIONSCAUTIONS TO BE TAKEN IN HANDLING AND STORAGE

D o n o t s t o r e a b o v e 1 1 5 d e g . F ( 4 6 d e g . C ) s t o r e l a r g e; o m p I • . a n c e - l t d C S H A 2 9 C F R 1 9 1 0 . 1 0 6 .

OTHER PRECAUTIONS; ) o r o t t a k e i n t e r n a l l y . C l o s e c o n t a i n e r o t t e r e a c h u« , e e p a w a y f r o m c h i . a r e n .Do not c r e a t n e s a n d i n g a „ s t .j a s h r - a n a s and f a c e t h o r o u g h l y b e f o r e e a t i n g c rE m p t y c o n t a i n e r s ~ u s t n o t r : e w a s h e d a n d r p - u s e aC o n t a i n e r s s h o u l d E p g r o u n d e d a n d b o n d e d t o t h eD o n e t w e l d , D r a z e c r c j t o n e m p t y c o n t a i n e r .S e v e • u s e p r e s s u r e t o e t i p t y . D r u m i s n o t n p r e s s u r e

d r i n k i n g .fir ,i n y P - r p o s e .^ e c c i v i n g c o n t a i n e r

v e s s e l .


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TRANSPORTATION DATAP A I N T D O T M A R K I N G T " I S S I D E U P

A M . M A B L E L I O U I D i z H E R G E N C Y A C C I D E N T P R E C A U T I O N S

A M M A B L E i P R O C E D U R E S S E E A B O V E

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N

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' •> \ S I T E M ISE , C O R R E C T .

H A Z A R D O U S A N D N F O R 1 A T 1 C N S T A T E D I S T 0

E G o . A ' 0 R 0 R M A ; : 0 N S E R V I C E S

T H E I N F O R M A T I O N C O N T A I N E D H E R E I N I S B A S E D C N D A T A C O N S I D E R E D T O B EA C C U R A T E . J H I L E T H E I N F O R M A T I O N I S B E L I E V E D T O B E R E L I A B L E , N O W A R R A N T Y I SE X P R E S S E D O R I M P L I E D R E G A R D I N G T H E A C C U R A C y O F T H I S 3 A T A O R T H E R E S U L T S T O3 E O B T A I N E D F R O M T H E U S E T H E R E O F . S I N C E T » E U S E O F T H I S I N F O R M A T I O N A N D T H EC O N D I T I O N S A N D U S E O F T H I S P R O D U C T A R E C O N T R O L L E D B Y T H E U S E R I T I S T H EJ S E R ' S O B L I G A T I O N * - 3 D E T E R M I N E T H E C O N D I T I O N S 3 F S A F E U S E C F T H E P R O D U C T .

' h e C o r p o r a t e S a f e t y a n d E n v i r o n m e n t a l A f f a i r s D e p a r t m e n t i se s D o n s ' . D i e f o r t * e c r e p a r a t i o n o f t h i s M a t e r i a l S a f e t y D a t a S h e e t .

PRATT. & J.AMBERT 316-733-1361Industrial Coatings Div.101 Prospect AvenueClbveiana, OH 44115

DOT EMERGENCY CHEMTEL (800)255-3924 (24hrs)INFORMATION PHONE NO. 216-566-2902 (M-F 8 AM-5 PM CT)

HEALTH 1 •FLAMMABILITY 3REACTIVITY 0

These ratings should be usea onlypart of fully imoiementea H.M.I.S. program.



SECTION I


TRADE NAME . . . . H I G H S O L I D S • • ' • S T R O N G

MANUFACTURER CODE I .D . 5 2 3 0 2 0 5 2

REVISED ON • 1 / 0 7 / 9 6

S E E N A / D E N L

S 0 1 0 -M A N U F A C T U R E R

I

INGREDIENT

C A G E » 5 1 1 9 6

SECTION II -

% BY CAS NO.WGT , NIOSH»

C O N T R A C T a

HAZARDOUS INGREDIENTSALLOWABLE

EXPOSURE LEVELPPM MG/CU.M. MPPCF

SARA313

SKIN

VPma Hg

20 DEC.

S A P T H A ( P E T R O L E U M )H E A V Y A : < Y L A T E

* Y L E N t

_ E A C C H R O M A T E

^ E AD SuL F A T E

T I T A N I U M D I O X I D E

S O L E U M H Y D R O -*BCN H 1 X T U R E

P I N E O I L

64741 •65 - 7 MFRSOLVENT

< 5 '330-20-7 T L V - T U ASOLVENT 2E2100000 T L V - S T E L

OSHA-PELO S M A - S T E L

L F L 1 .0

100

100150•00•50

5 "758-97-6 T L V - T U AP I G M E N T GS29750CO O S H A - P E LOSHA-CE1L

P!GHENT7446-14-2 T L V - T W A

OSHA-PEL

13463-67-?PIGMENT XR2275000

T L V - T U AOSHA-PEL

8032-32-4 T L V - T U A016180000 OSHA-PEL

8000-41 -7

100100

525

655-35655

JFL '

0.01200.05000.1000

0.15000.0500

1010

525525

SOLVENTNOME E S T A B L I S H E D

E X P O S U R EF C R AN" M E P E R I O D

O F S E C T I O N 3 1 3

M U M B E R .

. o w E R F L A M M A B I L I T Y . I M I T P E R C E N TU F L = U P P E R ' L A M M A B I L 1 T Y L I M I T P E R C E N TS K I S - S K I N A B S O R P T I O N M U S T B E C O N S I D E R E D A S A R O U T E O F

• • • . I N G - A t L 0 U . E X P O S U R E L E V E L S H O U L D NOT 3E E X C E E D E D"(R M A N U F A C T U R E R R E C O M M E N D E D E X P O S U R E . I M I T- - • ' S H O P " ' E R M E X P O S U R E - 1 M I T. v ; ^ f r 5 . • 3 . : - i E M ! C A L I S S U B J E C T T O R E P O R T I N G R E Q U I R E M E N T S; i • : T i E ::: : F S . A . R . A . -o CFR P A R T 372s ; o S H » - s l O S H R E G I S T R Y O F T O X I C E F F E C T S O F C H E M I C A L S U B S T A N C E S _________

| _____________________ SECTION III - HEALTH INFORMATION ___________________EFFECTS OF SHORT TERM OVEREXPOSURESWALLOWING

C a n c a u s e g a s t r o i n t e s t i n a l i r r i t a t i o n , n a u s e a , a n d v o m i t i n g . A s p i r a t i o n o fn a t e r i . i i ' n t o l u n g m a y c a u s e c h e m i c a l p n e u m o n i t i s w h i c h c a n b e f a t a l .

INHALATIONM a y c a u s e n o s e o r t h r o a t i r r i t a t i o n . H i g h c o n c e n t r a t i o n s m a y c a u s e a c u t ec e n t r a l n e r v o u s s y s t e m d e p r e s s i o n c h a r a c t e r i z e d b y h e a d a c h e s , a i z z i n e s s ,- a u s e a a n a c o n f u s i o n .


SKINM a v c a u s e d e f a t t i n g a n d i r r i t a t i o n o f t h e s u i n .

EFFECTS OF REPEATED OVEREXPOSUREJ v e r e x o o s u r e t o x y l e n e m a y c a u s e i n j u r y t o t n e l i v e r , K i d n e y s , a n dD I o o a .R e p e a t e d a n d p r o l o n g e d o v e r e x p o s u r e t o r e l a t i v e l y i n s o l u b l e c h r o m a t e s-i a y c a u s e l u n g c a n c e r .C h r o n i c o v e r e x p o s u r e t a l e a d m a y r e s u l t • n s e v e r e d a m a g e t o b l o o d f o r m i n g ,n e r v o u ; . , ^ r i n a r y j n d r e p r o d u c t i v e s y s t e m s . i o m e c o m m o n s y m p t o m s o f c h r o n iD v e r e x p o s u r e i n c l u d e ' , o s s o f a p p e t i t e , m e t a l l i c t a s t e i n t h e m o u t h ,a n x i e t y , c o n s t i p a t i o n . n a u s e a . w e a k n e s s , ' n s o m n i a , H e a d a c h e , m u s c l e a n dj o i n t p a i n , ' i n e t r e m o r s , n u m b n e s s , a i z z i n e s s , n y p e r a c t i v i t y . a n d c o l i c .O c c u p a t i o n a l e x p o s u r e t o l e a d i s r e g u l a t e d b y O S H A - 2 9 C F R 1 9 1 0 . 1 0 2 5 .P r e x i s t i n q k i d n e y c o n d i t i o n s m a y b e a g g r a v a t e d b y e x p o s u r e s t o l e a d .R e p o r t s h a v e a s s o c i a t e d p r o l o n g e d a n d r e p e a t e d o c c u p a t i o n a l o v e r e x p o s u r e

• 5 2-3 020 52PAGE 2DATE 11/07/96

SECTION III - HEALTH INFORMATION; (CONTINUED)

EFFECTS OF REPEATED OVEREXPOSURE• o s o l v e n t s w i t h p e r m a n e n t D r a i n a n d n e r v o u s s y s t e m d a m a g e .T i s u s e c y d e l i b e r a t e l y c o n c e n t r a t i n g and i n h a i •, r g the

IFICANTULABORATORY DATA WITH POSSIBLE RELEVAMCE TO HUMAN HEALTH." • t a n i u m d i o x i d e IS NOT ' i s t e d as a p o t e n t i a l c a r c i n o g e n D y the

n t e n tio n a Ic o n t e n t s m a y b e

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- a s n o t o b s e r v e de n o v e r w h e l m e d

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o n C a n c e rt u d y w i t hu n g t u m o re x p o s u r er a n c e m e cp o s u r e l ee s u I t s mae x p o s u r e

0 S H A ,r a t s

s i n t h el e v e l s ,h a n i s m sv e l , a n dy notl i m i t s

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u m c o m p o u n d s a r e l i s t e d a s p o t e n t i a l c a r c i n o g e n sP r o g r a me d a s a p o t e n t i a l a n i m a l c a r c i n o g e n b y t h es e a r c h o n C a n c e r .

SECTION IV - FIRST AID MtD EMERGENCY PROCEDURESSWALLOWING

! t s w a l l o w e d d o n o t i n d u c e v o m i t i n g . C a l l o o i s o n c o n t r o l c e n t e r , h o s p i t a le m e r g e n c y r o o m or c h y s ' c i a n i m m e d i a t e l y .

INHALATIONR e m o v e t o f r e s h a i r i m m e d i a t e l y . I f b r e a t h i n g h a s s t o o p e d , g i v e a r t i f i -c i a l r e s p i r a t i o n . X e e p » a r m a n d q u i e t . d e t n e d i c a l a t t e n t i o n i m m e d i a t e l y

EYE

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s h » i t h l a r g e a m o u n t s ~C o n t i n u e f o r 3 t l e a s t ' 5 m i n u t e s .

w a t e r , l i f t i n g u c D e r .ind l o w e r , i d s o c c a s i o n a l3 e t ~ e d i c a i a t t e n t i o n .

j a p a n d w a t e r .R e m o v e c o n t a m i n a t e d ; . o t h i n g . J a s n a f f e c t e d a r e a w i t hC b t o i n n e a i c a i a t t e n t i o n • ; i r r i t a t i o n p e r s i s t s .

NOTES TO PHYSICIANA n y t r e a t m e n t t h a t t r i g h t D e r e q u i r e d f o r o v e r e x p o s u r e s h o u l d b ed i r e c t e d a t t h e c o n t r o l o f s y m p t o m s a n d t h e c . i n i c a l c o n d i t i o n s .

SECTION V - PHYSICAL DATABOILING RANGEFREEZING POINT:

?OR PRESSURE:

VAPOR DENSITY

E G . F C

EVAPORATION RATES l o w e r t h a n d i e t h y l e t h e r .

WEIGHT LB. /GAL. 3 . 0S P E C I F I C G R A V I T Y

' 6 5 D E G . F . ( 7 4 D E G . C . ) T O 4 1 4

50 D E G . •'.(-<. 5 D E C . C.)

5 m m H q 3 6 8 D E G . F . ( 2 0 D E G . C . )

e a v i e r t h a n a i r . % VOLATILE BY VOLUME S 4

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2 1 2 D E G . C . )

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APPEARANCE & ODOR : L i q u i d , S o l v e n t o d o r

VISCOSITY : No • . n f o r n a t i o n f o u n d

7 . 6 6 Ib/gal foUrte

SOLUBILITY:

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9 1 9 g / 1 solids C A L C U L A T E D

S l i g h t i n w a t e r

- - 7 ( S T D U N I T S )

All Physical data determined at 68 DEC. F. (20 DEC. C.) 760 mm Hg* Negligibly Photochemically Reactive MaterialsVOC values reported here are verified by ASTM method D-3960_______

SECTION VI - FIRE AND EXPLOSION DATANFPA FLAMMABILITY CLASSIFICATION

FLAMMABLE LIMITS 1.0 '. • 7 . 0 '/.FLASHPOINT 80 D E G . F ,

AUTOIGNITION 5 7 2 D E C . = . ( 3 0 0 O E G . C . )

CORROSION RATE N o tNET EXPLOSIVE WGT.Not

F L A M M A B L E L I Q U I D C L A S S 1 C

a p p I i c a D I e

a p p I i c a b I e

( 2 7 D E G . C , ) C A L C U L A T E D

DECOMPOSITION TEMP 1 8 3 2 D E G . F . M O O O D E G . C . )


EXTINGUISHING MEDIAu s e N F P A C l a s sc a l o r a i c o h o l•ner ' c a m i s p r e f e r r e d f o r

UNUSUAL FIRE AND EXPLOSION HAZARDS

8 F i r e e x t i n g u i s h e r s ( c a r b o n d i o x i d e . a l l p u r p o s e d r y c h e m i -f o a m ) d e s i g n e d t o e x t i n g u i s h f l a m m a b l e l i q u i d f i r e s . P o l y -

r e f e r r e d f o r l a r g e f i r e s .O u r i n g e m e r g e n c y c o n d i t i o n s , o v e r e x p o s u r e t o d e c o m p o s t i o n p r o d u c t s m a yc a u s e a h e a l t h h a z a r d . S y m p t o m s m a y n o t b e i m m e d i a t e l y a p p a r e n t . O b t a i n• n e d i c a i a t t e n t i o n .W A R N I N G ' F L A M M A B L E .:CIAL FIRE FIGHTING PROCEDURESU a t e r m a y D e i n e f f e c t i v e , b u t m a y b e u s e d t o c o o l e x p o s e d c o n t a i n e r s t op r e v e n t p r e s s u r e o u i l d - u p a n d p o s s i b l e a u t o - i g n i t i o n o r e x p l o s i o n w h e n

PAGE 3 ,2y 52 ________________________________________DATE 1 1 / 0 7 / 9 6

I___________SECTION VI - FIRE AND EXPLOSION DATA; (CONTINUED)____________

SPECIAL FIRE FIGHTING PROCEDURES____i- x p o s e d t o e x t r e m e n e a t . : f w a t e r i s u s e d , ' 0 9 n o z z l e s a r e p r e f e r a o l e . _ _ _ _

' ________________SECTION VII - REACTIVITY DATA_____________________________RALIZING AGENT N o - " . f o r m a t i o n f o u n d

g n i t

c u t t i n g , w i l l p r o d u c e s m o k e ,i n , o x i d e s o f c h r o m i u m

c o a t e d w i t h t h i s p r o d u c t m a y-. c t a I o x i d e s ray r e s u l t -nk e i l l n e s s w i t h f e v e r , c h i l l se s p i r a t o r m a y D e r e q u i r e dq u a l i f i e d h e a l t h a n d s a f e t y


CONDITIONS TO AVOIDA v o i d e x c e s s i v e h e a t ( > 1 1 5 F ( 4 6

INCOMPATABILITY (MATERIALS TO AVOID)S t r o n g a c i d s o r a l k a l i n e m a t e r i a l

HAZARDOUS0c

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u r na r ba x ie I dr o dM e tn de p er o f

HAZARDOUSu i 1 I

DECOMPOSITION PRODUCTSi n g , i n c l u d i n g w n e n n e a t e d byo n m o n o x i d e a n d c a r b o n d i o x i dd e s o f l e a d . m i y b e g e n e r a t e d .i n g , b r a z i n g , : r t o r c h c u t t i nu c e m e t a l o x i c e s . C v e r e x p o s u ra i F u m e F e v e r " . S y m p t o m s i n c lc o u g h . A n a i r c u r i f y i n g o r s un d i n g u p o n l e v e i s o f e x p o s u r ee s s i o n a I .POLYMERIZATIONi o t o c c u r

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CONDITIONS TO AVOIDN o n e k n o w n


< e e p s p e c t a t o r s a w a y . E l i m i n a t e a l l i g n i t i o n s o u r c e s ( f l a m e s , h o ts u r f a c e s , a n d s o u r c e s o f e l e c t r i c a l , s t a t i c o - f r i c t i o n a i s p a r K s ) .D i k e a n d c o n t a i n s D i i ' , w i t h i n e r t m a t e r i a l ( e . g . • , a n a , e a r t h ) . T r a n s f e r. i q u i d s t o c o v e r e c n e t a i c o n t a i n e r s f o r r e c o v e r y o r a i s p o s a , , o r r e m o v e« i t n i n e r t a b s o r o e n t . ~ s e o n l y n o n - s p a r k i n g t c o i s . P l a c e a b s o r b e n t d i k i n gm a t e r i a l s i n c o v e r e d m e t a l c o n t a i n e r s f o r d i s p o s a l . P r e v e n t c o n t a m i n a t i o no t s e w e r s , s t r e a m s , and g r o u n d w a t e r w i t h s p i i . e d m a t e r i a l or u s e da b s o r b e n t .

WASTE DISPOSALd i s p o s e - n a c c o r d a n c e w i t h f e d e r a l , s t a t e a n d l o c a l r e g u l a t i o n s .

RCRA CLASSIFICATION' h i s p r o d u c t c o n t a i n s c h r o m i u m . W a s t e r e s i d u e c f t h i s p r o d u c t m a y q u a l i f ya s h a z a r d o u s w a s t e ( - 0 C F R P a r t 2 6 1 . 7 4 - C h a r a c t e r i s t i c o f F . P T o x i c i t y ) ." h i s p r o d u c t , i f d i s c a r d e d d i r e c t l y , w o u l d b e c l a s s i f i e d a h a z a r d o u s w a s t eb a s e d o n i t s i g n i t a b i : i t y c h a r a c t e r i s t i c , i . e . h a s a f l a s h p o i n t o f 1 4 0d e 9 . F . ( 6 0 a e g . C ) o r l e s s . T h e p r o p e r R C R A c l a s s i f i c a t i o n w o u l d b e 0 0 0 1 .T h i s p r o d u c t c o n t a i n s l e a d , w h i c h , i f p r e s e n t • n w a s t e a t 5 . 0 m g / l o r• n o r e a f t e r b e i n g e x t r a c t e d , i s c o n s i d e r e d E P T o x i c , a n d t h e r e f o r e ah a z a r d o u s w a s t e u n d e r R C R A r e g u l a t i o n s . T h e h a z a r d o u s w a s t e n u m b e rw o u l d b e 0008.

ENVIRONMENTAL HAZARDSN o n e k n o w n


3 e t e - t o O S H A s t a n d a r d ' o r s p e c i f i c r e s p i r a t o r y c r o t e c t i o n r e q u i r e m e n t s•or . o a a , 2 9 C F R 1 9 ^ 0 . 1 0 2 5 .'• r o p e r - . e l e c t i o n ;• ' c s p i r a t o r y p r o t e c t i o n d e p e n d s u p o n T a n y f a c t o r s

n c i ' j c t . n q d u r a t i o n / l e v e l o f e x p o s u r e a n d r e n d i t i o n s o f u s e . I n g e n e r a le x p o s u r e t o o r g a n i c c - . e m i c a i s s u c n a s t n o s c c o n t a i n e d i ~ . T r - i s p r o d u c t m a y- o t " e q u i r e t h e u s e C T r e s p i r a t o r y p r o t e c t i o n • T u s e d i n w e l l v e n t i l a t e d. 1 r e a s . i n r e s t r i c t e d v e n t i l a t i o n a r e a s a N I O S H a p p r o v e d c h e m i c a l c a r t r i d g er e s p i r a t o r m a y b e r e q u i r e d . U n d e r c e r t a i n c o n d i t i o n s , s u c h a s s p r a y i n g am e c h a n i c a l p r e f i l t e r m a y a l s o b e r e q u i r e d . I n c o n f i n e d a r e a s u s e a N I O S H /" S H A a p p r o v e d a i r s u p p l i e d r e s p i r a t o r . ; f t h e I L V ' s l i s t e d i n S e c t i o n I Ij r e e x c e e d e d u s e a p r o p e r l y f i t t e d N I O S H / M S H A a p p r o v e d r e s p i r a t o r w i t h a na p p r o p r i a t e p r o t e c t i o n f a c t o r . R e f e r t o O S H A 2 9 C F R 1 9 1 0 . ' 3 4 " R e s p i r a t o r yP r o t e c t i o n " , a n d " R e s p i r a t o r y P r o t e c t i o n A M a n u a l A n d G u i d e l i n e , A m e r i c a nI n d u s t r i a l H y g i e n e A s s o c . "

VENTILATIONR e f e r T O O S H A s t a n d a r d s f o r s p e c i f i c v e n t i l a t i o n r e q u i r e m e n t s f o rt e a d - 2 9 C F R 1 9 ! 0 . 1 0 2 5 .P r o v i d e g e n e r a l d i l u t i o n a n d l o c a l e x h a u s t v e n t i l a t i o n i n s u f f i c i e n t v o l u m ea n d p a t t e r n t o k e e p c o n c e n t r a t i o n s o f h a z a r d o u s i n g r e d i e n t s l i s t e d i nS e c t i o n i l b e l o w t h e l o w e s t e x p o s u r e l i m i t s t a t e d . R e m o v e d e c o m p o s i t i o np r o d u c t s t h a t a r e g e n e r a t e d w h e n w e l d i n g , c u t t i n g , o r b r a z i n g o b j e c t sc o a t e d w i t h t h i s o r o d u c t . R e f e r t o " I n d u s t r i a l V e n t i l a t i o n - A M a n u a l o fR e c o m m e n d e d P r a c t i c e " A C G I H

HAND PROTECTION.ear a p p r o p r i a t e i m p e r m e a b l e g l o v e s ( N o r t h - S i l v e r S h i e l d ) .

EYE PROTECTIONJ e a r s a f e t y s p e c t a c l e s .

OTHER PROTECTIVE EQUIPMENTA s r e q u i r e d t o p r e v e n t s k i n c o n t a c t . S e e O S H A s t a n d a r d f o r l e a d .I——————————————————————-——————————————————^——————-————————————————————————————————————————————————

' ______________SECTION X - SPECIAL PRECAUTIONS__________________________CAUTIONS TO BE TAKEN IN HANDLING AND STORAGE

D o n o t s t o r e a b o v e ' 1 5 d e g . F ( 4 6 d e g . C ) s t o r e l a r g e q u a n t i t i e s i n

53302C 52 PAGE 4DATE 11/07/96

SECTION X - SPECIAL PRECAUTIONS; (CONTINUED)

PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGEc o m p l i a n c e w i t h O S H A 2 9 C F R 1 9 1 0 . 1 0 6 .

OTHER PRECAUTIONSD o n o t t a K e i n t e r n a l l y . C l o s e c o n t a i n e r a f t e r e a c h u s e .K e e p a w a y f r o m c h i l d r e n .D o n o t b r e a t h e s a n d i n g d u s t .W a s h h a n d s < i n d f a c e t h o r o u g h l y b e f o r e e a t i n g c r d r i n k i n g .E m p t y c o n t a i n e r s m u s t n o t b e w a s h e d a n d r e - u s e d f o r a n y p u r p o s e .C o n t a i n e r s • . , n o u I d b e g r o u n d e d a n d b o n d e d t o t h e r e c e i v i n g c o n t a i n e rD o n o t - e l d , b r a z e o r c u t o n e m p t y c o n t a i n e r .n e v e r u s e p r e s s u r e t o e m p t y . D r u m i s n o t a p r e s s u r e v e s s e l .

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ECTION

5CTION X( A R T 1 C L

E N I N T

N 01 2 6 J

D . 0 .

2 N2 N2 N1 7 C1 7 K1 7 C1 7 K1 2 B

R S W I L L) .

XI -

E )

F L

F L

F L

R A N S P

R . 0

T . J

.

11111i.

BE A

OTHER INFORMATION

TRANSPORTATION DATAP A I N T D O T M A R K I N G T H I S S I D E U P

A M M A B L E L I Q U I D E M E R G E N C Y A C C I D E N T P R E C A U T I O N S

A M M A B L E & P R O C E D U R E S S E E A B O V E

A M M A B L E

0 R T A T I 0 N

A E R O S O L P R O P E L L E N T : N o t a p p l i c a b l e. N O . U . S . P O S T A L F O R B I D D E N

N

N 1N 1N 1A 1A 2A 1A 2G

U N I T C O N T A I N E R O N L Y U S E D c C R ' < C O M P O N E N T O F

T H I S ' . S T O C E R T I F Y T H A T T H I S I T E M I ST H E B E S T C F O U R K N O W L E D G E , C O R R E C T .

H A Z A R D O U S A N D N F O R M A T I O N S T A T E D I S T 0


• M E : N F O R M A T I O N C O N T A I N E D H E R E I N I S B A S E D O N D A T AA C C U R A T E . J H I L E T H E I N F O R M A T I O N I S B E L I E V E D * 0 B EE X P R E S S E D O R I M P L I E D R E G A R D I N G T H E A C C U R A C Y O F T H 1B E O B T A I N E D F R O M T H E U S E T H E R E O F . S I N C E T H E U S E O FC O N D I T I O N S A N D U S E O F T H I S P R O D U C T A R E C O N T R O L L E DU S E R ' S O B L I G A T I O N T O D E T E R M I N E T H E C O N D I T I O N S O F

T h e C o r p o r a t e S a f e t y a n d E n v i r o n m e n t a l A f f ae s p o n s i P l e f o r t h e p r e p a r a t i o n o t t h i s M a t e r i a l

C O N S I D E R E D T C B ER E L I A B L E . N O W A R R A N T Y I SS D A T A O R T H E R E S U L T S T O

T H I S I N F O R M A T I O N A N D T H EB Y T H E U S E R , I T I S T H E

S A F E U S E O F T H E P R O D U C T ,r s D e p a r t m e n t i sS a f e t y D a t a S h e e t .

VRATT &•LAMBERT 316-733-1361Industrial Coatings Div,101 Prospect AvenueClfeveiana, OH 44115OOT EMERGENCY CHEMTEL (800)255-3924 (24hrs)INFORMATION PHONE NO. 216-566-2902 (M-F 8 AM-5 PM CT)



H.M.I.S.HEALTH 2*FLAMMABILITY 3REACTIVITY 0

'hese ratings should be usea only.is part of fu l ly implemented H . M . I . S . program.

SECTION I

PRODUCT CLASS A i K Y D ,

TRADE NAME E N A M E L

Y R V T REVISED ON 1 1 / 0 7 / 9 6

MANUFACTURER

8 0 1 0 -M A N U F A C T U R

INGREDIENT

CODE I .D . 5 4 6 0 0 3

E R C A G E » 6 1 1 9 6

SECTION II -

% BY CAS NO.WGT /NIOSH*

2 2 R 3

HAZARDOUS

0 0 - <. 7 5

C O N T R A C T 0

INGREDIENTSALLOWABLE

EXPOSURE LEVELSARA VT

313 mm Ha20 DBG.

@C

X Y l E N E

PPM M G / C U . M .4 5 ' 3 3 0 - 2 0 - 7 T L V - T U A

S O L V E N T 2 E 2 1 0 C O O O T L V - S T E LO S H A - P E LO S H A - S T E L

LFL 1 .

1 0 : o o - * . i - -S O L V E N T CA0700000

T L V - T U AT L V - S T E LOSHA-PELO S H A - S T E L

LFL 1 ,

S T Y R E S E

D F A T T Y A C I DT H E N A I E C C M P L E x

A N T I M O N Y " » I O X 1 C E

S O L V E N T N A P T H A ,L I G H T A R O M A T I C

S O L V E N T S A P T H A , H E A V YA R O M A T I ;

< 1 100-42-5 T L V - T U AR E S I N T L V - S T E L

OSHA-PELOSHA-STEL

LFL 1 .

1 79803-79-5 T L V - T U AO SHA-PEL

i '109-64-4 T L V - T U A

100150100150

100125100125

5010020100

435655435655

U F L

435545435545

U F L 6. 7

215425215425

UFL 6.0

0. 15000.0500

0.50000.5000P I G M E N T CC5650000 OS H A - P E L

64742-95-6 NONE E S T A B L I S H E DS O L V E N T

S O L V E N T6 4 7 4 2 - 9 4 - 5 NONE E S T A B L I S H E D

MPPCF SKIN

S K I N

R O U T E O FE X C E E D E D

• L . O W E S ^ L A M M A B I L I T Y L I M I T P E R C E N Ti i j P P F » ^ L A M M A B I L I T Y L I M I T P E R C E N T

i < I S = S K I N A B S O R P T I O N M U S T BE C O N S I D E R E D AS A: L I . I N G = A. L O W . E X P O S U R E * t V E L S H O U L D NOT BE

v f R = M A N U F A C T U R E R R E C O M M E N D E D E X P O S U R E L I M I TS T E L = S H O R T T E R M E X P O S U R E L I M I TK - S A R A 3 1 3 = C H E M I C A L I S S U B J E C T T O R E P O R T I N G R E Q U I R E M E N T SO F - : T L E M I O F S . A . R . A . 4 0 C F R P A R T 3 7 2N I 0 S H S = N I O S H R E G I S T R Y O F T O X I C E F F E C T S O F C H E M I C A L S U B S T A N C E S N U M B E R .


O F S E C T I O N 3 1 3

SECTION III - HEALTH INFORMATIONEFFECTS OF SHORT TERM OVEREXPOSURESWALLOWING

C a n c a u s e g a s t r o i n t e s t i n a l i r r i t a t i o n , n a u s e a , a n d v o m i t i n g . A s p i r a t i o n o fm a t e r i a l • n t o l u n g m a y c a u s e c h e m i c a l p n e u m o n i t i s w h i c h c a n b e f a t a l .

INHALATIONM a y c a u s e n o s e o r t h r o a t i r r i t a t i o n . H i g h c o n c e n t r a t i o n s m a y c a u s e a c u t ec e n t r a l n e r v o u s s y s t e m d e p r e s s i o n c h a r a c t e r i z e d b y h e a d a c h e s , d i z z i n e s s ,n a u s e a a n d c o n f u s i o n .


SKINM a y c a u s e d e f a t t i n g a n d i r r i t a t i o n o f t h e s k i n .

EFFECTS OF REPEATED OVEREXPOSUREO v e r e x p o s u r e t o x y l e n e m a y c a u s e i n j u r y t o t h e l i v e r , k i d n e y s , a n do l o o d .J r t r o n i c o v e r e x p o s u r e t o l e a d m a y r e s u l t i n s e v e r e d a m a g e t o b l o o d f o r m i n g ,n e r v o u s , j r i n a r y a n d r e p r o d u c t i v e s y s t e m s . S o m e c o m m o n s y m p t o m s o f c h r o n i co v e r e x p o s j r e i n c l u d e l o s s o f a p p e t i t e , m e t a l l i c t a s t e i n t h e m o u t h ,a n x i e t y , c o n s t i p a t i o n , n a u s e a w e a k n e s s , i n s o m n i a , h e a d a c h e , m u s c l e a n d; o i n t p a i n , f i n e t r e m o r s , n u m b n e s s , d i z z i n e s s , h y p e r a c t i v i t y , a n d c o l i c .

546002 22PAGE 2DATE 11/07/96

SECTION - mm iHPOfflaTffl! (coNTlii)EFFECTS OF

O c c u pR e p o rt o s om i s u s

A n t i mi n t e ri d e n tc a r c it r i o xS t y r eA g e n c

REPEATED OVEREXPOSUREa t i o n a l e x p o s u r e t o l e a d i s r e g u l a t e d b y O S H A - 2 9 C F R 1 9 1 0 . 1 0 2 5 .t ? n a v e a s s o c i a t e d p r o l o n g e d a n d r e p e a t e d o c c u p a t i o n a l o v e r e x p o s u r el v e n t s w i t h p e r m a n e n t b r a i n a n d n e r v o u s s y s t e m d a m a g e . I n t e n t i o n a le b y d e l i b e r a t e l y c o n c e n t r a t i n g a n d i n n a l i n g t h e c o n t e n t s m a y b eJ LABORATORY3 DATA WITH POSSIBLE RELEVANCE TO HUMAN HEALTH.o n y t r i o x i d e i s l i s t e d a s b e i n g p o s s i b l y c a r c i n o g e n i c t o h u m a n s b y t h en a t i o n a l A g e n c y F o r R e s e a r c h o n C a n c e r ( 1 A R C G r o u p 28). T h e A C G I Hi f i e s t h e p r o d u c t i o n o f a n t i m o n y t r i o x i d e a s b e i n g a s u s p e c t e d h u m a nn o g e n . l o w e v e r , A C G I H d o e s n o t l i s t t h e h a n d l i n g a n d u s e o f a n t i m o n yi d e t o b e p o s s i b l y c a r c i n o g e n i c .n e h a s D e e n i - s t e d a s a p o t e n t i a l c a r c i n o g e n b y t h e I n t e r n a t i o n a ly f o r R e s e a r c h o n C a n c e r ( 1 A R C G r o u p 23).

SECTION IV - FIRST AID AMD EMERGENCY PROCEDURESSWALLOWING

I f s w a l l o w e d d o n o t i n d u c e v o m i t i n g . C a l l p o i s o n c o n t r o l c e n t e r , h o s p i t a le m e r g e n c y r o o m o r p h y s i c i a n i m m e d i a t e l y .

INHALATIONR e m o v e t o f r e s h a i r i m m e d i a t e l y . I f b r e a t h i n g h a s s t o p p e d , g i v e a r t i f i -c i a l r e s p i r a t i o n . K e e p w a r m a n d q u i e t . G e t m e d i c a l a t t e n t i o n i m m e d i a t e l y .

EYEf l u s h w i t h l a r g e a m o u n t s o f w a t e r , l i f t i n g u p p e r a n d l o w e r l i d s o c c a s i o n a l -, y . C o n t i n u e t o r j t l e a s t 1 5 m i n u t e s . G e t m e d i c a l a t t e n t i o n .

SKINR e m o v e c o n t a m i n a t e d c l o t h i n g . W a s h a f f e c t e d a r e a w i t h s o a p a n d w a t e r .3 b t a i n m e d i c a l a t t e n t i o n i f i r r i t a t i o n p e r s i s t s .

NOTES TO PHYSICIANA n y t r e a t m e n t t h a t r c i g h t b e r e q u i r e d f o r o v e r e x p o s u r e s h o u l d b ed i r e c t e d a t t h e c o n t r o l o f s y m p t o m s a n d t h e c l i n i c a l c o n d i t i o n s . ______________

i SECTION V - PHYSICAL DATABOILING RANGE

FREEZING POINT:

VAPOR PRESSURE:

VAPOR DENSITY

2 7 5 D E G . F . ( 1 3 5 D E G . C . ) T O - . 0 1 D E G . F . t

> 0 D E G . r . ( • < . 5 D E G . C. )

5 m m H g 3 6 8 D E G . F . ( 2 0 D E G . C . )

h e a v i e r t n a n a i r .


IGHT LB. /GAL. 8 . 2. P E C I F 1 C G R A V I T Y 1 . 3

% VOLATILE BY VOLUME 6 8VOC 5 . 0 0 Ib/gal less water & NPRS*

VOC 1 6 . 0 5 Ib/gal

205 D E G . C . )

tQO g/1 less water c A L

1 9 2 6 g / 1 nrVI-irfa C A L C U L A T E D

APPEARANCE & ODOR: l i q u i d , S o l v e n t o d o r


SOLUBILITY:PH:


4 - 7 ( S T D U N I T S )

All Physical data determined at 68 DEG. F. (20 DEG. C.) 760 mm Hg• Negligibly Pnotochemically Reactive MaterialsVOC values reported here are verified by ASTM method D-3960______

SECTION VI - FIRB AND EXPLOSION DATANFPA FLAMMABILITY CLASSIFICATION

FLAMMABLE LIMITS 1.0 ' : - 7.0

F L A M M A B L E 1 1 0 U I C C L A S S ', 8

FLASHPOINT

AUTOIGNITION

CORROSION RATE

5 9 D E G . F , 1 5 D E G . C , ) C A L C U L A T E D

5 7 2 D E G . F . ( 3 0 0 D E G . C . ) DECOMPOSITION TEMP

N o t a p p l i c a b l e MAGNETISM

1 8 3 2 D E G . F . ( 1 0 0 0 O E G . C . )

N o t a p p l i c a b l e

N E T EXPLOSIVE W G T . N o t a p p l i c a b l eEXTINGUISHING MEDIA

J s e N F P A C l a s s B F i r e e x t i n g u i s h e r s ( c a r o o n d i o x i d e . a l l p u r p o s e d r y c h e m ical o r a i c o h o l ' o a m ) d e s i g n e d to e x t i n g u i s h f l a m m a b l e l i q u i d f i r e s . P o I y -r r e r t o a m i s p r e f e r r e d f o r l a r g e f i r e s .

UNUSUAL FIRE AND EXPLOSION HAZARDSD u r i n g e m e r g e n c y c o n d i t i o n s , o v e r e x p o s u r e t o d e c o m p o s t i o n p r o d u c t s m a yc a u s e a h e a l t h h a z a r d . S y m p t o m s m a y n o t b e i m m e d i a t e l y a p p a r e n t . O b t a i nm e d i c a l a t t e n t i o n .W A R N I N G ' F L A M M A B L E .

SPECIAL FIRE FIGHTING PROCEDURESU a t e r m a y b e i n e f f e c t i v e , b u t m a y b e u s e d t o c o o l e x p o s e d c o n t a i n e r s t op r e v e n t p r e s s u r e b u i l d - u p a n d p o s s i b l e a u t o - i g n i t i o n o r e x p l o s i o n w h e ne x p o s e d t o e x t r e m e h e a t . I f M a t » r i s u s e d , f o g n o z z l e s a r e p r e f e r a b l e .

SECTION VII - REACTIVITY DATAJTRALIZING AGENT N o i n f o r m a t i o n f o u n d

STABILITYN o r m a l I y s t a b l e

PAGE 3546002______22________________________ DATE 11/07/96

SECTION: VII _ REACTIVITY t>ATA; (CONTINUED)CONDITIONS TO AVOID

A v o i d e x c e s s i v e h e a t ( > 1 1 5 F ( 4 6 C ) a n d s o u r c e s c f i g n i t i o n .INCOMPATABILITY (MATERIALS TO AVOID)

S t r o n g a c i d s o r a l k a l i n e m a t e r i a l s .\RDOUS DECOMPOSITION PRODUCTS

S u r n i n g , i n c l u d i n g w h e n h e a t e d b y w e l d i n g o r c u t t i n g , w i l l p r o d u c e s m o k e ,c a r b o n m o n o x i d e a n d c a r b o n d i o x i d e . . o x i d e s C T l e a d , n a y b e g e n e r a t e d .w e l d i n g , b r a z i n g , > - t o r c h c u t t i n g m a t e r i a l s c o a t e d w i t h t h i s p r o d u c t m a yp r o d u c e T i e t a i o x i d e s . D v e r e x p o s u r e t o t h e s e m e t a l o x i d e s t i a y r e s u l t i n" M e t a * ' - u m e f e v e r " . S y m p t o m s i n c l u d e a f I u • i i « e ' i i n e s s w i t h f e v e r , c h i l l s, 1 n d c o u g h . A n a i r p u r - f y i n g o r s u p p l i e d a i r r e s p i r a t o r m a y b e r e q u i r e dd e p e n d i n g u p o n l e v e l s o f e x p o s u r e . C o n s u l t ,i q u a I i ' • e d h e a l t h a n d s a f e t yp r o f e s s i o n a l .

HAZARDOUS POLYMERIZATIONJ i l l n o t o c c u r

CONDITIONS TO AVOIDH o n e k n o w n


w e a r r e s p i r a t o r s . e y e , h a n d , a n d b o d y p r o t e c t i o n a p p r o p r i a t e f o r t h es i z e o f t h e s p V l l a n d t h e e x p o s u r e s e n c o u n t e r e d .K e e p s p e c t a t o r s a w a y . E l i m i n a t e a l l i g n i t i o n s o u r c e s ( f l a m e s , h o ts u r f a c e s , a n d s o u r c e s o f e l e c t r i c a l , s t a t i c o r f r i c t i o n a l s p a r k s ) .D i k e a n d c o n t a i n s p i l l w i t h i n e r t m a t e r i a l ( e . g . s a n d , e a r t h ) . T r a n s f e r. i q u i d s t o c o v e r e d m e t a l c o n t a i n e r s f o r r e c o v e r y o r d i s p o s a l , o r r e m o v e„ i t h i n e r t a b s o r b e n t . u s e o n l y n o n - s p a r k i n g t o o l s . P l a c e a b s o r b e n t d i k i n gm a t e r i a l s i n c o v e r e d n e t a l c o n t a i n e r s f o r d i s p o s a l . P r e v e n t c o n t a m i n a t i o no f s e w e r s , s t r e a m s , a n d g r o u n d w a t e r w i t h s p i l l e d m a t e r i a l o r u s e da b s o r b e n t .

WASTE DISPOSALD i s p o s e i n a c c o r d a n c e w i t h f e d e r a l , s t a t e j n d l o c a l r c g u l a t i o n s .

RCRA CLASSIFICATION" h i s p r o d u c t , i f d i s c a r d e d d i r e c t l y , w o u l d b e c l a s s i f i e d a H a z a r d o u s w a s t ec a s e d o n < t s i g n i t a b i l i t y c h a r a c t e r i s t i c , . e . h a s a t l a s n p o i n t o f 1 4 0a e g . c . ( 6 0 d e g . C ) o r l e s s . " h e p r o p e r R C R A c . a s s i f i c a t i o n w o u l d b e 0 0 0 1 ,

ENVIRONMENTAL HAZARDSN o n e k n own______________________________________________ __ __ ______________________

I SECTION IX - PERSONAL PROTECTION INFORMATIONRESPIRATORY PROTECTION

R e f e r t o O S H A s t a n d a r d f o r s p e c i f i c r e s p i r a t o r y p r o t e c« o r l e a d , 2 9 C F R 1 9 1 0 . ' 0 2 5 .^ r o p e r • , e l e c t i o n o f r e s p i r a t o r y p r o t e c t i o n d e p e n d s u p o• n c i u d i n g d u r a t i o n / l e v e i o f e x p o s u r e a n d c o n d i t i o n s o fe x p o s u r e t o o r g a n i c c h e m i c a l s s u c h a s t h o s e c o n t a i n e dn o t r e q u i r e t h e u s e o f r e s p i r a t o r y p r o t e c t i o n i f u s e da r e a s . I n r e s t r i c t e d v e n t i l a t i o n a r e a s a N I O S H a p p r o v er e s p i r a t o r m a y b e r e q u i r e d . U n d e r c e r t a i n c o n d i t i o n s ,m e c h a n i c a l p r e f i l t e r m a y a l s o b e r e q u i r e d . I n c o n f i n e dM S H A a p p r o v e d a i r s u p p l i e d r e s p i r a t o r . I f t h e T ; . v ' s 1 1a r e e x c e e d e d u s e . 1 p r o p e r l y f i t t e d N I O S H / M S M A a p p r o v e da p p r o p r i a t e p r o t e c t i o n f a c t o r . R e f e r t o O S H A 2 9 C F R 1 9P r o t e c t i o n " , a n d " R e s p i r a t o r y P r o t e c t i o n A M a n u a l A n dI n d u s t r i a l H y g i e n e A s s o c . "

VENTILATION• ( e t c r t o O S H A s t a n d a r d s f o r s p e c i f i c v e n t i l a t i o n r e q u i, e a d - 2 9 C F R 1 9 1 0 . 1 0 2 5 .• ) | - o v i a e g e n e r a l d i l u t i o n and l o c a l e x h a u s t v e n t • I a t i o ni n d p a t t e r n t o n e e p c o n c e n t r a t i o n s o f h a z a r d o u s i n g r e d

p r o d u c t s t h a t a r e g e n e r a t e d w h e n w e l d i n g , c u t t i n g , o rc o a t e d w i t h t h i s p r o d u c t . R e f e r t o " I n d u s t r i a l V e n t i l aR e c o m m e n d e d P r a c t i c e " A C C I H

HAND PROTECTIONw e a r a p p r o p r i a t e i m p e r m e a b l e g l o v e s ( N o r t h - S i l v e r S h i

EYE PROTECTIONw e a r s a f e t y s p e c t a c I e s .

OTHER PROTECTIVE EQUIPMENTE y e w a s h f a c i l i t y , s a f e t y s h o w e r .

SECTION X - SPECIAL PRECAUTIONS

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o n

0 f

PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGED o n o t s t o r e a b o v e ' 1 5 d e g . F ( 4 6 d e g . C ) s t o r e l a r g e q u a n t i t i e sc o m p l i a n c e w i t h O S H A 2 9 C F R 1 9 1 0 . 1 0 6 .

OTHER PRECAUTIONSD ou a sE m pC o n0 0N e v

nhttne

0 th

Ya i0 tr

t a k e i n t e r n a l l y . C l o s e c o n t a i n e r aa n d s a n d f a c e t h o r o u g h l y b e f o r e e a tc o n t a i n e r s m u s t n o t b e w a s h e d a n d rn e r s s h o u l d b e g r o u n d e d a n d b o n d e dw e l d , b r a z e o r c u t o n e m p t y c o n t a i

u s e p r e s s u r e t o e m p t y . D r u m i s n o t

f t ei n ge - ut 0n e ra

r e ao r

s e dt h ep r e s

c hd r if o rr e c

s u r

u s e .n k i na n y

e i v i

e v e

9 •P u

n g

s s e

rc

1

p o s eo n t a i n e r .


SECTION XII - TRANSPORTATION DATA

t

I

\p

3

D

D

J

15

Sc

5*46 002 22

SECTION XII -R 0 P

0 T

R E C

I M I. 0 .

N I T

P 10 UG AG A

5 G

I B E

E R S

C L A S

. A B E

P L A C

A J T I

T E D: . iC O N

N T 1A R TL L C NL L 0 N

A L L C

R B 0 A

H

S

L

A

C

0

T

EM

N

R

I

I

R

N

UD

A

TEMM

D

p

r

0

S

A

I

ATEE

M

P

1

N

N

LATT

E

5

I *, G N A M

C A T I O N

- 3 BE T

T '. T Y :N U M B E R

E R

LA ..A ..

T A L

0 X

E ( A R T

A K E N 1

N oU N 1 2 6

D

22211111

PAGE 4DATE 11/07/96

TRANSPORTATION DATA; (CONTINUED); c L

N T

3

. 0 .

NNN7 C7 K7C7 K2 B

E )

F L

F L

F L

R A N S P

R . 0

T . U

1111111i.

P A I N T D O T M A R K I N G T - I S S I D E U P


A M M A B L E & P R O C E D U R E S S E E A B O V E

A M M A B L E

0 R T A T I 0 N

A E R O S O L P R O P E L L E N T : N o t a p p l i c a b l eN O . U . S . P O S T A L F O R B I D D E N

N

N 1N 1N 1A 1A 2A 1A2G

( N O P L A S T I C C O N T A I N E R S W I L L B E A U N I T C O N T A I N E R O N L Y U S E D F O R i C O M P O N E N T O FA K ; T U N I T C O N T A I N E R ) .

H I S : S T O C E R T I F Y T H A T ' H I S I T E M I S H A Z A R D O U S A N D I N F O R M A T I O N S T A T E D I S , T OH E 5 E S " O F C U R K N O W L E D G E , C O R R E C T .


• H E I N F O R M A T I O N C O N T A I N E D H E R E I N I S B A S E D O N D A T A C O N S I D E R E D T O B EA C C U R A T E . U H I L E T H E I N F O R M A T I O N I S B E L I E V E D ' 0 B E R E L I A B L E , N O W A R R A N T Y I SE X P R E S S E D O R I M P L I E D R E G A R D I N G T H E A C C U R A C Y O F T H I S D A T A C R T H E R E S U L T S T OB E O B T A I N E D F R O M T H E U S E T H E R E O F . S I N C E T H E U S E O F T H I S I N F O R M A T I O N A N D T H EC O N D I T I O N S A N D U S E O F T H I S P R O D U C T A R E C O N T R O L L E D B Y T H E U S E R , I T I S T H EU S E R ' S O B L I G A T I O N T O D E T E R M I N E T H E C O N D I T I O N S O F S A F E U S E O F T H E P R O D U C T .

T h e C o r p o r a t e S a f e t y a n d E n v i r o n m e n t a l A f f a i r s D e p a r t m e n t i s- e s p o n s i o l c f o r '.he p r e p a r a t i o n o f t h i s M a t e r i a l S a f e t y D a t a S h e e t .

PRA1T i LAM3ERT 216-733-1361Industrial Coatings Div.101 Prospect AvenueClevelana, OH 44115DOT EMERGENCY CHEMTEL (800)255-3924 (24hra)INFORMATION PHONE NO. 216-566-2902 (M-F 8 AM-5 PM CT!CORPORATE CONTACT 216-566-2917 (M-F 8 AM-5 PM CT)

H . M . I . S .HEALTH 1 *FLAMMABILITY 3REACTIVITY 0

These ratings should be used only•is part cf fully 'nolemented H .M. l .S . program.


SECTION I

PRODUCT CLASS i L < Y D , M E D I U M - L O N G

TRADE NAME .... H I G H S O L I D S • • • • B R O W N t t

MANUFACTURER CODE I .D . 5 2 7 0 0 6 22

REVISED ON : 1 / 0 7 / 9 6

8 0 1 0 -M A N U F A C T U R E R C A G E 6 1 1 9 6

26 A/D D R E N L

C O N T R A C T «

! SECTION II - HAZARDOUS INGREDIENTS

INGREDIENT % BYWGT

CAS NO./ NIOSH*


SARA313

VPmm Hg <

20 DEC.

S A P T H A ( P E T R O L E U M )H E A V A L KY LAT E

< Y L E » . E

.EAD C'fROMAT E

: T A N i u M D I O X I D E

P E T R O L E U M H v D R 0 •M I X T U R E

, E R A L S P I R I T S

P I N E G I L

PPM MG/CU.M.64741-65-7 «FR

SOLVE N T

5 '330-20-7 T L V - T U ASOLVENT JE210QOOO T L V - S T E L

O S H A - P E LOSHA-STEL

L F L 1 .0

100

100150100150

PIGMENT7758-97-6 T L V - T U A3B2975000 3SHA-PEL

OSHA-CEIL

13463-67-7 T L V - T W AP I G M E N T XR2275000 CSHA-PEL

8032-32-4 T L V - T U A016180000 OSHA-PEL


LFL 1.0

100100

100100

525

435655-35655

UFL '

0.01200.05000.1000

1010

525525525525

SOLVENT8000-41-7

UFL

NONE ESTABLISHED

MPPCF SKIN

. f lu F :s < ; s

L O W E R ' L A M M A B I L I T Y L I M I T P E R C E N TU P P E R F . A M M A B I L I T V L I M I T P E R C E N TS K I N A B S O R P T I O N M U S T B E C O N S I D E R E D A S A

' >J G = A L L C U . E X P O S U R E L E V E L S H O U L D NOT 3EM A N U F A C T U R E R R E C O M M E N D E D E X P O S U H E L I M I TS H O R T - E R M E X P O S U R E L I M I T5 : 3 ^ C H E M I C A ^ I S S U B J E C T T O R E P O R T I N G R E Q U I R E M E N T S

-f • ' T L E ' ' . I O c S . A . R . A . i. 0 CFR P A R T 372•MCSH8 = S I O S H R E G I S T R Y C F T O X I C E F F E C T S O F C H E M I C A L S U B S T A N C E S N U M B E R

R O U T E O F E X P O S U R EE X C E E D E D F O R A N Y * ! M E P E R I O D

O F S E C T I O N 3 1 3


C a n c a u s e g a s t r o i n t e s t i n a l i r r i t a t i o n , n a u s e a , a n d v o m i t i n g . A s p i r a t i o n o fm a t e r i a l i n t o l u n g m a y c a u s e c h e m i c a l p n e u m o n i t i s w h i c h c a n b e f a t a l .



SKINM a y c a u s e d e t a i l i n g a n d i r r i l a t i o n o f t h e s k i n

EFFECTS OF REPEATED OVEREXPOSUREO v e r e x p o s u r e t o x y l e n e m a y c a u s e i n j u r y t o t h e l i v e r , k i d n e y s , a n db I o o d .R e p e a t e d a n d p r o l o n g e d o v e r e x p o s u r e t o r e l a t i v e l y i n s o l u b l e c h r o m a t e sn a y c a u s e l u n g c a n c e r .C h r o n i c o v e r e x p o s u r e t o l e a d m a y r e s u l t i n s e v e r e d a m a g e t o b l o o d f o r m i n g ,n e r v o u s , u r i n a r y a n d r e p r o d u c t i v e s y s t e m s . S o m e c o m m o n s y m p t o m s o f c h r o n i co v e r e x p o s u r e i n c l u d e l o s s o f a p p e t i t e , m e t a l l i c t a s t e i n t h e m o u t h ,j n x i e t y , c o n s t i p a t i o n , n a u s e a , w e a k n e s s , i n s o m n i a , h e a d a c h e , m u s c l e a n dj o i n t p a i n , f i n e t r e m o r s , n u m b n e s s , d i z z i n e s s , h y p e r a c t i v i t y a n d c o l i c .O c c u p a t i o n a l e x p o s u r e t o l e a d i s r e g u l a t e d b y O S H A - 2 9 C F R 1 9 1 0 . 1 0 2 5 .P r e x i s t i n g k i d n e y c o n d i t i o n s m a y b e a g g r a v a t e d b y e x p o s u r e s t o l e a d .

• 527006 22

; SECTION III - HEALTH:INFORMATION; (CONTINUED)

PAGEDATE ll/

207/'9 6

EFFECTS OF REPEATED OVEREXPOSURER e p o r t s n a v e a s s o c i a t e dt o s o l v e n t s w i t h p e n m a nm i s u s e b y d e l i b e r a t e l yh a r m f u l o r f a t a l .

..JIFICANT LABORATORY DATA WITHT i t a n i u m a i o x i d e I S N O TT o x i c o l o g y P r o g r a m , t h ec r A . C . G . I . H . T i t a n i u mr e v e a l e d a s i g n i f i c a n tg r o u p e x p o s e d to 2 5 0 m g /t h i s s i g n i f i c a n t e f f e c t; r t h e l u n g s m a y h a v e bt h i s m a y h a v e c o n t r ' D u tD e d i r e c t , y r e l e v a n t t oa r e o b s e r v e d . A t t h e I .s i g n i f i c a n t h a z a r d f o rC h r o m i u m a n d c e r t a i n c hb y t h e N a t i o n a l T o x i c o lL e a d c n r o m a t e h a s b e e nI n t e r n a t i o n a l A g e n c y f o

p r o l o n g e d a n d r e p e a t e d o c c u p a t i o n a l o v e r e x p o s u r ee n t b r a i n a n d n e r v o u s s y s t e m d a m a g e . I n t e n t i o n a lc o n c e n t r a t i n g a n d i n h a l i n g t h e c o n t e n t s m a y b e

POSSIBLE RELEVANCE TO HUMAN HEALTH.. i s t e d a s a p o t e n t i a l c a r c i n o g e n b y t h e N a t i o n a lI n t e r n a t i o n a l A g e n c y < o r R e s e a r c h o n C a n c e r , O S M A ,

d i o x i d e i n a 2 4 - m o n t h i n h a l a t i o n s t u d y w i t h r a t s' ^ c r e a s e i n b e n i g n a n d m a l i g n a n t l u n g t u m o r s i n t h eM 3 r e s p i r a b l e T i 0 2 d u s t . A t l o w e r e x p o s u r e l e v e l s ,- a s n o t o b s e r v e d . T h e n o r m a l c l e a r a n c e m e c h a n i s m s

e e n o v e r w h e l m e d a t t h e 2 5 0 m g / M 3 e x p o s u r e l e v e l , a n de d t o t h e t u m o r ' o r m a t i o n . T h e s e r e s u l t s m a y n o tt h e w o r k p l a c e w h e r e o c c u p a t i o n a l e x p o s u r e l i m i t s

V t r i e T i 0 2 m a n u f a c t u r e r c o n c l u d e s t h a t t h e r e i s n o• n a n .r o m i u m c o m p o u n d s a r e l i s t e d a s p o t e n t i a l c a r c i n o g e n so g y P r o g r a mM s t e d a s a p o t e n t i a l a n i m a l c a r c i n o g e n b y t h er R e s e a r c h o n C a n c e r .

SECTION IV - FIRST AID Alfc) EMERGENCY PROCEDURESSWALLOWING

I f s w a l l o w e d d o n o t • - i d u c e v o m i t i n g . C a l l p o i s o n c o n t r o l c e n t e r , h o s p i t a le m e r g e n c y r o o m o r p h y s i c i a n i m m e d i a t e l y .

INHALATIONS e m o v e t o f r e s h a i r i m m e d i a t e l y . I f b r e a t h i n g h a s s t o p p e d , g i v e a r t i f i -c i a l r e s p i r a t i o n . < e e D ..arm a n d q u i e t . G e t m e d i c a l a t t e n t i o n i m m e d i a t e l y .

EYE' l u s h w i t h l a r g e a m o u n t s o f w a t e r , l i f t i n g ^ p p e r a n d . e w e r I ' d s o c c a s i o n a l -l y . C o n t i n u e f o r a t l e a s t 1 5 m i n u t e s . G e t n e d i c a l a t t e n t i o n .

SKINS e m o v e c o n t a m i n a t e d c l o t h i n g . W a s h a f f e c t e d . i r e a w i t h s o a p a n d w a t e r .O b t a i n m e d i c a l a t t e n t i o n i f i r r i t a t i o n p e r s i s t s

NOTES TO PHYSICIANA n y t r e a t m e n t t h a t m i g h t b e r e q u i r e d f o r o v e r e x p o s u r e s h o u l d b ed i r e c t e d a t t h e c o n t r o l o f s y m p t o m s a n d t h e c l i n i c a l c o n d i t i o n s .


FREEZING POINT:POR PRESSURE:

,/APOR DENSITY

' 6 5 D E G . F . ( 7 4 O E G . C . ) T O

-50 D E G . F . ( - 4 5 D E C . C.)

5 mm H g i 68 D E G . F.(20 D E G .

1 4 D E G . F . ( 2 1 2 D E G . C . )

H e a v i e r t h a n a ' r .



% VOLATILE BY VOLUME r; 2VOC 3 . 4 0 Ib/gal less water & NCRS* .08 g/1 less vmtarC A I

VOC 7 . 1 6 Ib/gal aolids

APPEARANCE & ODOR: L i q u i d , S o l v e n t o d o r


SOLUBILITY:

PH:

859 g/1 enlifte


, • 7 ( S T O U N I T S )

C A L C U L A T E D

All Physical data determined at 68 DEG. P. (20 DEG. C.) 760 mm Hg• Negligibly Photochemically Reactive MaterialsVOC values reported here are verified by A3TM method D - 3 9 6 0


FLAMMABLE LIMITS 1.0 X - 7 . o *

FLASHPOINT 80 D E G . F ,

AUTOIGNITION 5 7 2 D E G . F . (300 D E G . C . )

CORROSION RATE N o t

NET EXPLOSIVE WGT.Not

F L A M M A B L E L I Q U I D C L A S S 1 C

a p p I i c a 0 I e

a p p I i c a o I e

( 2 7 D E G . C , ) C A L C U L A T E D



EXTINGUISHING MEDIAU s e N F P A C l a s sc a l o r a l c o h o l

B F i r e e x t i n g u i s h e r s ( c a r b o n d i o x i d ef o a m ) d e s i g n e d t o e x t i n g u i s h f l a m m a b

m e r f o a m i s p r e f e r r e d f o r l a r g e f i r e s .UNUSUAL FIRE AND EXPLOSION HAZARDS

cS y m p t o m s m a y n o t

a l l p u r p o s e d r y c h e m i -e l i q u i d f i r e s . P o l y -

D u r i n g e m e r g e n c y c o n d i t i o n s , o v e r e x p o s u r e t o d e c o m p o s t i o n p r o d u c t s m a y' e a l t h h a z a r d . ~c a u s e a h

m e d i c a l a t t e n t i o n .W A R N I N G ' F L A M M A B L E .

iCIAL FIRE FIGHTING PROCEDURESJ a t e r m a y b e i n e f f e c t i v e ,

b e i m m e d i a t e l y a p p a r e n t . O b t a i n

b u t m a y b e u s e d t o c o o l e x p o s e d c o n t a i n e r s t o

5270U6 22 DATE 11/07/96

SECTION VI - FIRE AND EXPLOSION

SPECIAL FIRE FIGHTING PROCEDURESp r e v e n t p r e s s u r e D u i 1 d - u p ae x p o s e d t o e x t r e m e n e a t . I f

SECTION VIINEUTRALIZING AGENT No i n f o r m a t

STABILITYN o r m a l I v s t a b l e .

CONDITIONS TO AVOIDA v o i d e x c e s s i v e h e a t ( > 1 1 5

INCOMPATABILITY (MATERIALS TO AVOID)S t r o n g a c i d s o r a l k a l i n e m a

HAZARDOUS DECOMPOSITION PRODUCTSB u r n i n g , i n c l u d i n g w h e n h e ac a r b o n m o n o x i d e a n d c a r b o n, o x i d e s o f l e a d , m a y b e g e n eW e l d i n g , b r a z i n g , o r t o r c hp r o d u c e m e t a i o x i d e s . O v e r e" * e t a I • u m e F e v e r " . S y m p t o ma n d c o u g h . A n a i r p u r i f y i n gd e p e n d i n g u p o n l e v e l s o f e xp r o f e s s i o n a l .

HAZARDOUS POLYMERIZATIONU i l l n o t o c c u r

CONDITIONS TO AVOIDN o n e K n o w n

SECTION VIII

nd p o s s i b l e aw a t e r i s u s e

- REACTIVITYi o n f o u n d

F (46 C ) and

t e r i a I s .

t e d b y w e l d i nd i o x i d e . I n a or a t e d .c u t t i n g m a t e rx p o s u r e t o t hs i n c l u d e a fo r s u p p l i e d

p o s u r e . C o n s u

DATA; (CONTINUED)

u t o - i g n i t i o n o r e x p l o s i o n w h e nd , ' o g n o z z l e s a r e p r e f e r a b l e .

DATA

s o u r c e s o f i g n i t i o n .

g o r c u t t i n g , w i l l p r o d u c e s m o k e ,d i t i o n , o x i d e s o f c h r o m i u m

l a l s c o a t e d w i t h t h i s p r o d u c t m a ye s e m e t a l o x i d e s m a y r e s u l t i nl u - l i k e i l l n e s s w i t h f e v e r , c h i l l s ,a i r r e s p i r a t o r m a y b e r e q u i r e dI t a q u a l i f i e d h e a l t h a n d s a f e t y

- ENVIRONMENTAL INFORMATIONSTEPS TO BE TAKEN IF MATERIAL IS RELEASED OR SPILLED

n e e p s p e c t a t o r s a w a y . E l i m i n a t e a l l i g n i t i o n s o u r c e s ( f l a m e s , M o ts u r r a c e s , j n d s o u r c e s o f e l e c t r i c a l , s t a t i c o r f - i c t i o n a i s p a r e s ) .D i k e j n d c o n t a i n s p i l l w i t h i n e r t m a t e r i a l ( e . g . s a n d , e a r t h ) . T r a n s f e rl i q u i d s t o c o v e r e d m e t a l c o n t a i n e r s f o r r e c o v e r y o r d i s p o s a l , o r r e m o v e» i t h i n e r t a b s o r b e n t . U s e o n l y n o n - s p a r k i n g t o o l s . " l a c e a b s o r o e n t d i k i n gm a t e r i a l s i n c o v e r e d m e t a l c o n t a i n e r s f o r d i s p o s a l . P r e v e n t c o n t a m i n a t i o nc f s e w e r s , s t r e a m s , a n d g r o u n d u a t e r w i t h s p i l l e d m a t e r i a l o r u s e da b s o r b e n t .

WASTE DISPOSALD i s p o s e i n a c c o r d a n c e w i t h f e d e r a l , s t a t e a n d l o c a l r e g u l a t i o n s .

RCRA CLASSIFICATIONT h i s p r o d u c t c o n t a i n s c h r o m i u m . W a s t e r e s i d u e o f t h i s p r o d u c t m a y q u a l i f ya s r - a z a r d o u s w a s t e ( * 0 C F R P a r t 2 6 1 . 7 4 - C h a r a c t e r i s t i c o f E P T o x i c i t y ) .' h i s p r o d u c t , i f d i s c a r d e d d i r e c t l y , w o u l d b e c l a s s i f i e d a h a z a r d o u s w a s t eb a s e d o n i t s i g n i t a b i l i t y c h a r a c t e r i s t i c , i . e . h a s a f l a s h p o i n t o f 1 4 0d e g . : . ( 6 0 d e g . C ) o r l e s s . T h e p r o p e r R C R A c l a s s i f i c a t i o n w o u l d b e D 0 0 1 .T h i s p r o d u c t c o n t a i n s l e a d , w h i c h , i f p r e s e n t i n w a s t e a t 5 . 0 m g / l o rm o r e a f t e r b e i n g e x t r a c t e d , i s c o n s i d e r e d E P T o x i c , a n d t h e r e f o r e ah a z a r d o u s w a s t e u n d e r R C R A r e g u l a t i o n s . T h e h a z a r d o u s w a s t e n u m b e rw o u l d b e 0008.

ENVIRONMENTAL HAZARDSN o n e K n o w n

SECTION IX - PERSONAL PROTECTION INFORMATION

' e s pm e c n ,

RESPIRATORY PROTECTIONs e t e r t o O S M A s t a n d a r d f o r s p e c i f i c r e s p i r a t o r y p r o t e c t i o n r e q u i r e m e n t s•or . o a o , : 9 C f R 1 ° ' 0 . ' 0 2 5 .; r o p e r - e l e c t i o n o f r e s p i r a t o r y p r o t e c t i o n d e p e n d s u p o n n a n y ' a c t o r sn c i u O i n g d u r a t i o n / l e v e l o f e x p o s u r e a n d c o n d i t i o n s O T u s e . ; n g e n e r a l

e x p o s u r e t o o r g a n i c c h e m i c a l s s u c h a s t h o s e c o n t a i n e d i n t h i s p r o d u c t m a yn o t r e q u i r e t h e u s e o f r e s p i r a t o r y p r o t e c t i o n i f u s e d i n w e l l v e n t i l a t e da r e a s . I n r e s t r i c t e d v e n t i l a t i o n a r e a s a N 1 0 S H a p p r o v e d c h e m i c a l c a r t r i d g e

i r a t o r m a y b e r e q u i r e d . U n d e r c e r t a i n c o n d i t i o n s , s u c h a s s p r a y i n g , aa n i c a l p r e f i l t e r m a y a l s o b e r e q u i r e d . I n c o n f i n e d a r e a s u s e a N 1 0 S H /

H S H A a p p r o v e d a i r s u p p l i e d r e s p i r a t o r . I f t h e T L V ' s l i s t e d i n S e c t i o n I Ia r e e x c e e d e d u s e a p r o p e r l y f i t t e d N I O S H / M S H A a p p r o v e d r e s p i r a t o r w i t h a na p p r o p r i a t e p r o t e c t i o n f a c t o r . R e f e r t o O S H A 2 9 C F R 1 9 1 0 . 1 5 4 " R e s p i r a t o r yP r o t e c t i o n " , a n d " R e s p i r a t o r y P r o t e c t i o n A M a n u a l A n d G u i d e l i n e , A m e r i c a nI n d u s t r i a l H y g i e n e A s s o c . "

VENTILATIONR e f e r t o O S H A s t a n d a r d s f o r s p e c i f i c v e n t i l a t i o n r e q u i r e m e n t s f o rl e a d - 2 9 C F R 1 9 1 0 . 1 0 2 5 .P r o v i d e g e n e r a l d i l u t i o n a n d l o c a l e x h a u s t v e n t i l a t i o n i n s u f f i c i e n t v o l u m ea n d p a t t e r n t o k e e p c o n c e n t r a t i o n s o f h a z a r d o u s i n g r e d i e n t s l i s t e d i nS e c t i o n i l b e l o w t h e l o w e s t e x p o s u r e l i m i t s t a t e d . R e m o v e d e c o m p o s i t i o np r o d u c t s t h a t a r * g e n e r a t e d w h e n w e l d i n g , c u t t i n g , o r b r a z i n g o b j e c t sc o a t e d w i t h t h i s p r o d u c t . R e f e r t o " I n d u s t r i a l V e n t i l a t i o n - A M a n u a l o fR e c o m m e n d e d P r a c t i c e " A C G I H

HAND PROTECTIONw e a r a p p r o p r i a t e i m p e r m e a b l e g l o v e s ( N o r t h - S i l v e r S h i e l d ) .

EYE PROTECTIONU e a r s a f e t v s p e c t a c l e s .

OTHER PROTECTIVE EQUIPMENTA s r e q u i r e d t o p r e v e n t s k i n c o n t a c t . S e e O S H A s t a n d a r d f o r l e a d .

SECTION X - SBBdA|i PRECAUTIONSPRECAUTIONS TO BE TAKEN IN HANDLING AND STORAOB

3 o n o t s t o r e a b o v e 1 1 5 d e g . F ( 4 6 d e g . C ) s t o r e l a r g e q u a n t i t i e s


OTHER PRECAUTIONS3 o n o t : a * e i n t e r n a l l y . C l o s e c o n t a i n e r a f t e r e a c h u s e .D o n o t b r e a t h e s a n d i n g d u s t .W a s h h a n d s a n d f a c e t h o r o u g h l y b e f o r e e a t i n g o r d r i n k i n g .E m p t y c o n t a i n e r s m u s t n o t b e w a s h e d a n d r e - u s e d f o r a n y p u r p o s e .C o n t a i n e r s s h o u l d b e g r o u n d e d a n d b o n d e d t o t h e r e c e i v i n g c o n t a i n e rD o n o t w e l d , b r a z e o r c u t o n e m p t y c o n t a i n e r .N e v e r u i e p r e s s u r e t c e m p t y . D r u m i s n o t a p r e s s u r e v e s s e l .


SECTION XII - TRANSPORTATION DATAP R 0 P E

DOT C

DOT I

DOT P

P R E C A

. ; M i TD . 0 . •

J N I T

P ! NC L A

' G A L5 GAL

55 G A

F I B E R

( N 0A 1C 1

R

L A

A B

L A

U T

F D

C 0

TR *I 0: 0

1 1B 0

P i7

S

sE

C

:N

M

NN

0

A

A'J

H

S

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A

0

Q

T

FM

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1

I

R

N

UD

A

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D

TI

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0

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!

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M

IT

P

I

N

N

LATT

E

B

C

1

C

T

TN

E

IAA

T

0

C

N G N A M E

A T I 0 N

C BE T A K

I T Y :U M B E R U N

R

LL

A L

X

C 0 N T A 1 N E0 N T A 1 N E R

( A R T I C L

E N I N T

N o1 263

D . 0 .

2 N2 N2 N1 7C1 7 K1 7 C1 7 1C1 2 B

R S W I L L) .

E ) P

F L A MM

F L A H H

F L A M M

R A N S P O R T

A E RR . Q . N

T . U N

1 N 11 N 11 N 11 A 11 A 21 A 11 A24G

BE A UN

A I N T D O T M A R K I N G T H I S S I D E U P

A B L E L I Q U I D E M E R G E N C Y A C C I D E N T P R E C A U T I O N S

A B L E & P R O C E D U R E S S E E A B O V E

A B L E

A T I 0 N

O S O L P R O P E L L E N T : N o t a p p l i c a b l e0 . U . S . P O S T A L F O R B I D D E N

I T C O N T A I N E R O N L Y U S E D F O R 1 C O M P O N E N T O F

T H I ST H E

1 SE S

T O C E R TO F O U R

I F Y T H A TK N O W L E D G E

H I S I T E MC O R R E C T

I S H A Z A R D O U S A N D I N F O R M A T I O N S T A T E D I S T 0


• H EA C C

I N F O R M A T I O N C O N T A I N E D H E R E I NU R A T E .

E X P R E S S EBE 0C 0 N D

T A II T I 0 N S

W H I L E T H ED O R I M P L I E DN E D F R O M T H E

I S B A S E D O N D A T AN F O R M A T I O N I S B E L I E V E D T O B ER E G A R D I N G T H E A C C U R A C Y C F T HU S E T H E R E O F . S I N C E T H E U S E 0

A N D U S E O F T H I S P R O D U C T A R E C O N T R O L L E

C O N S I D E R E D T O B ER E L I A B L E ,

I S D A T A O RT HB Y

U S E R ' S O B L I G A T I O N T O D E T E R M I N E T H E C O N D I T I O N S O F S A F E

1 S IT H EU S E

N O W A R R A N T YT H E R E S U L T S

N F 0 R M A TU S E R ,O F T H E

1 0 N1 T

A N D

I S

T h e C o r p o r a t e S a f e t y a n d E n v i r o n m e n t a l A f f a i r s D e p a r t m e n tR e s p o n s i b l e f o r t h e p r e p a r a t i o n o f t h i s M a t e r i a l S a f e t y D a t a S h e e t

I S T H EP R O D U C T

PRATT S, -LAMBERT 316-733-1361In'dustrial Coatings Div.101 Prospect AvenueCleveland, OH 44115DOT EMERGENCY CHEMTEL (800)255-3924 (24hrs)INFORMATION PHONE NO. 216-556-2902 (M-F 8 AM-5 PM CT)

H . M . I . S .HEALTH 1•FLAMMABILITY 3REACTIVITY 0

"hese rat ings should be used onlyas oart of fu l ly implemented M . M . l . S . program.



SECTION I

PRODUCT CLASS A L < Y D , M E D I U M - L O N GTRADE NAME .... H I G H S O L I D S *

MANUFACTURER CODE I . D . 5 2 6 0 4 0

5 706 A1 3

3 0 1 0M A N U F A C T U R E R C A G E 6 1 1 9 6

F X X 0 N RED

C O N T R A C T

REVISED ON '1/07/96

A/0 OR E N L


INGREDIENT

N A P T H A (PE T R O L E U M )H E A V Y A L K Y L A T E

X Y L E N E

P E T R C L L - - . M H Y D R O -: A R S O N M.'X'URE

.EAD C H R O M A TE

_EAD SJL fATE

AH 1UM D I O X I D E

P I N E O I L

% BYWGT

CAS NO./NIOSHtt

S O L V E N T

S O L V E N T

6 4 7 4 1 - 6 5 - 7 M F R

• 3 3 0 - 2 0 - ;Z E 2 1 C O O O O

U V - T U AT L V - S T E LO S H A - P E LO S H A - S T E L

. FL 1

8 0 3 2 - 3 2 - 4 T L V - T U AS O L V E N T 0 1 6 1 8 0 0 0 0 O S H A - P E L

P I G M E N T

<. 1P I G M E N T

7 7 5 8 - 9 7 - 6G B 2 9 7 5 0 0 0

7 4 4 6 - 1 4 - 2

1 3 4 6 3 - 6 7 - 7 T L V - T U AP I G M E N T X R 2 2 7 5 0 0 0 C S H A - P E L

PPM M G / C U . M .

100 525

100 -35150 655100 435150 655

UFL '

T L V - T U AO S H A - P E LO S H A - C E I L

T L V - T W AO S H A - P E L

S O L V E N T8 0 0 0 - 4 1 - 7

100 525100 525

0 . 0 1 2 00 . 0 5 0 00 . 1 0 0 0

0. 15000 . 0 5 0 0

101 0



SARA313

MPPCF SKIN

VPmm Hg @

20 DBG.C

. [ IJ F Ls K : N™ . r r i • J« F R «'> * c .• - S A R A; c T ; • LH ': 2 3 H g

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N i

R f ^ A M M A B I . I T Y L I M I T P E R C E N TR F L A M M A B I . I T Y L I M I T P E R C E N TA B S O R P T I O N M U S T B E C O N S I D E R E D A S A

i . L O U . E X P O S U R E . E V E L S H O U L D NOT BEA C T U R E R R E C O M M E N D E D E X P O S U R E L I M I 'T - E R M E X P O S U R E _ : u I T

C H E M I C A L : S S U B J E C T T O R E P O R T I N G! C F S . A . R . A . - 0 C F R P A R T 3 7 2O S H R E G I S T R Y C F T O X I C E F F E C T S O F C H

R 0 UF X C

R E Q U

E M I C

TE

I

A

EE

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L

0 FD E D

E M E N

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E X P O S U R EF O R A N Y

T S OF S E

S T A N C E S

• ! M E

c T : o N«. U M B E

P E R I O D

3 1 3R .


C a"n a

n c a u s e g a s t r o i n t e s t i n a l i r r i t a t i o n , n a u s e a , a n d v o m i t i n gt e r i a l i n t o l u n g m a y c a u s e c h e m i c a l p n e u m o n i t i s w h i c h c a n b

Aes Pf

ia

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i o n 0

INHALATIONH a: en a

EYEH a

SKINM a

EFFECTSJ VD IR e-i aC hn p

3 Vd n

1 00 cP rR e

y c a u s e n o s e o r t h r o a t i r r i t a t i o n . H i g h c o n c e n t r a t i o n s m an t r n i n e r v o u s s y s t e m d e p r e s s i o n c h a r a c t e r i z e d b y h e a d a c h eu s e a a n d c o n f u s i o n .

y c a u s e e y e i r r i t a t i o n .

y c a u s e d e t a i l i n g a n d i r r i t a l i o n o f t h e s k i n .OF REPEATED OVEREXPOSURE

e r e x p o s u r e t o x y l e n e m a y c a u s e i n j u r y t o t h e l i v e r , k i d n eo o d .p e a t e d a n d p r o l o n g e d o v e r e x p o s u r e t o r e l a t i v e l y i n s o l u b l ey r a u s e l u n g c a n c e r .r o n i c o v e r e x p o s u r e t o l e a d m a y r e s u l t i n s e v e r e d a m a g e t or v o u s , u r i n a r y j n d r e p r o d u c l l v e s y s l e m s . S o m e c o m m o n s y me r e x p o s u r e i n c l u d e l o s s o f a p p e t i t e , m e t a l l i c t a s t e i n t hx i e t y , c o n s t i p a t i o n , n a u s e a . w e a k n e s s , i n s o m n i a , h e a d a c h ei n t p a i n , f i n e t r e m o r s , n u m b n e s s , d i z z i n e s s , M y p e r a c t i v i tc u p a t i o n a l e x p o s u r e t o l e a d i s r e g u l a t e d b y O S H A • 2 9 C F Re x i s t i n g K i d n e y c o n d i t i o n s m a y b e a g g r a v a t e d b y e x p o s u r e sp o r t s n a v e a s s o c i a t e d p r o l o n g e d a n d r e p e a t e d o c c u p a t i o n a l

ys ,

y sc

bP te

X \t0

c

,

h

I0mm

90V

a3

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0moua1

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5260-40 13PAGE 2DATE 11/07/96

SECTION III - HEALTH INFORMATION; (CONTINUED)EFFECTS OF REPEATED OVEREXPOSURE

t o s o l v e n t s w i t h p e n m a nm i s u s e b y d e l i b e r a t e l yh a r m f u l o r f a t a l .-.FICANT LABORATORY DATA WITHT i t a n i u m d i o x i d e I S N O T" o x i c o l o g y P r o g r a m , t h eor A . C . G . ! . H . T i t a n i u mr e v e a i t: d a s i g n i f i c a n tg r o u p e x p o s e d to 2 5 9 m g /t h i s s i g n i f i c a n t e f f e c tof ! h e i u n g s may n a v e bt h i s m a y h a v e c o n t r i b u tb e d i r e c t l y r e l e v a n t t oa r e o o s e r v e d . A t t h e T Is i g n i f i c a n t h a z a r d f o rC h r o m i u m a n d c e r t a i n c hb y t h e N a t i o n a l T o x i c o lL e a d c h r o m a t e h a s b e e ni n t e r n a t i o n a l A g e n c y f o

e n t b r a i n a n dc o n c e n t r a t i n g

n e r v o u s s y s t e m d a m a g e . I n t e n t i o n a la n d i n h a i ' . n g t h e c o n t e n t s m a y b e

POSSIBLE RELEVANCE TO HUMAN HEALTH.- i s t e d a s a p o t e n t i a l c a r c i n o g e n D y t h e N a t i o n a lI n t e r n a t i o n a l A g e n c y ' o r - R e s e a r c h on C a n c e r , 0 S H A ,

a • o x i d e i n a 2 4 - m o n t h i n h a l a t i o n s t u d y w i t h r a t si n c r e a s e i n b e n i g n a n d n a t i g n a n t , u n g t u m o r s i n t h eM } ' e s p i r a b l e T i 0 2 d u s t . A t l o w e r e x p o s u r e l e v e l s ,w a s n o t o b s e r v e d . ' h e n o r m a l c l e a r a n c e m e c h a n i s m s

e e n o v e r w h e l m e d a t t h e Z 5 0 m g / M 3 e x p o s u r e l e v e l , a n de d t o t h e t u m o r f o r m a t ' o n . T h e s e r e s u l t s m a y n o tt h e w o r k p l a c e w h e r e o c c u p a t i o n a l e x p o s u r e l i m i t s

V t h e T i 0 2 m a n u f a c t u r e r c o n c l u d e s t h a t t h e r e i s n om a n .r o m i u m c o m p o u n d s a r e l i s t e d a s p o t e n t i a l c a r c i n o g e n so g y P r o g r a ml i s t e d a t a p o t e n t i a l a n i m a l c a r c i n o g e n b y t h er R e s e a r c h o n C a n c e r .

SECTION IV - FIRST AID AH& EMERGENCY PROCEDURESSWALLOWING

; f s w a l l o w e d d o n o t ' " d u c e v o m i t i n g . C a l l p o i s o n c o n t r o l c e n t e r , h o s p i t a le m e r g e n c y r o o m o r p h y s i c i a n i m m e d i a t e l y .

INHALATIONR e m o v e t o f r e s h a i r i m m e d i a t e l y . I f b r e a t h i n g h a s s t o p p e d , g i v e a r t i f i -c i a l ' c s p i r a t i o n . K e e p w a r m a n d q u i e t . G e t m e d i c a l a t t e n t i o n i m m e d i a t e l y .

EYEl u s h w i t h l a r g e a m o u n t s o f w a t e r , l i f t i n g u p p e r ,ind l o w e r l i d s o c c a s i o n a l

, y . C o n t i n u e T o r a t l e a s t 1 5 m i n u t e s . G e t m e d i c a l a t t e n t i o n .SKIN

R e m o v e c o n t a m i n a t e d c l o t h i n g . W a s h a f f e c t e d a r e a w i t hO b t a i n m e d i c a l a t t e n t i o n i f i r r i t a t i o n p e r s i s t s .


a p a n d w a t e r .


FREEZING POINT:

->OR PRESSURE:

*>OR DENSITY

'65 D E G . F . ( 74 D E G . C . ) TO 414 0 E G . F . ( 212 D E G . C . )

50 D E C . : . ( - i 5 O E G . C.)

5 mm Ng i 68 D E C . f . ( 2 0 O E G . C.)

H e a v i e r t h a n a i r .



% VOLATILE BY VOLUME - 5VOC 3 . 5 5 Ib/gal lesa water & M>RS* •. 2 6 g/1 less waterc A l

VOC 7 . 9 3 Ib/gal nolifte

APPEARANCE & ODOR: . i q u i d . S o l v e n t o d o r

VISCOSITY : N o i n f o r m a t i o n f o u n d

SOLUBILITY:PH:

952 g/1 eolids


<. - 7 ( S T D U N I T S )

C A L C U L A T E D

All Physical data determined at 68 DEG. F. (20 DEC. C.) 760 mm Hg* Negligibly Photochemically Reactive MaterialsVOC values reported here are verified by ASTM method D-3960______

SECTION VI - FIRE AND EXPLOSION DATANFPA FLAMMABILITY CLASSIFICATION F L A M M A B L E L I Q U I D C L A S S 1 C

FLAMMABLE LIMITSFLASHPOINTAUTOIGNITION

CORROSION RATE

1 . 0 '/. - 7 . 0 X

8 0 D E G . F ,

5 7 2 D E G . F . (300 D E G . C . )


( 2 7 D E G . C , ) C A L C U L A T E D

DECOMPOSITION TEMP 1 8 3 2 D E G . F . ( 1 0 0 0 D E G . C . )


NET EXPLOSIVE W G T . N o t a p p l i c a b l e

B F i r e e x t i nEXTINGUISHING MEDIA

U s e N F P A C l a s sc a i or

( rb a l l p u r p o s e d r y c h e m i -e l i q u i d f i r e s . P o l y -a l c o h o l f o a m ) d e s i g n e d t o e x t i n g u i s h f l a m m a b

m e r f o a m i s p r e f e r r e d f o r l a r g e f i r e s .UNUSUAL FIRE AND EXPLOSION HAZARDS

D u r i n g e m e r g e n c y c o n d i t i o n s , o v e r e x p o s u r e t o d e c o m p o s t i o n p r o d u c t s m a yc a u s e a h e a l t h h a i a r d . S y m p t o m s m a y n o t b e ' m m e d i a t e l y a p p a r e n t . O b t a i nm e d i c a l a t t e n t i o n .W A R N I N G ' F L A M M A B L E .

•CIAL FIRE FIGHTING PROCEDURESw a t e r m a y b e i n e f f e c t i v e , b u t m a y b e u s e d t o c o o l e x p o s e d c o n t a i n e r s t op r e v e n t p r e s s u r e b u i l d - u p a n d p o s s i b l e a u t o - i g n i t i o n o r e x p l o s i o n w h e n

PAGEDATE 1 1 / 0 7 / 9 6

5 2 6 0 - 4 0

SECTION VI - FIRE AND EXPLOSION DATA; (CONTINUED)

SPECIAL FIRE FIGHTING PROCEDURESe x p o s e d t o e x t r e m e * e a t M a t e r i s u s e d , f o q n o z z l e s a r e p r e f e r a b l e .

SECTION VII - REACTIVITY DATA.RALIZING AGEKT N o i n f o r m a t i o n f o u n d


CONDITIONS TO AVOIDA v o i G e x c e s s i v e h e a t ( > 1 1 5

INCOMPATABILITY (MATERIALS TO AVOID)S t r o n g a c i d s or a I K a l i n e m a t e r

HAZARDOUS DECOMPOSITION PRODUCTSB u r n i n g , i n c l u d i n g w h e n h e ac a r b o n m o n o x i d e a n d c a r b o n. o x i d e s of I e a d , m a v D e g e n e

( 4 6 C ) a n d s o u r c e s o f

i a I s

w e l d i n g , C r a z i n g ,p r o d u c e m e t a l o x i" 1 e t a l F u m e F e v e ra n d c o u g n . A n a i r

c rd e s

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d e p e n d i n g u p o n l e v e l s o f e x p o s u r e . C o n s u l t a q u a lp r o f e s s i o n a l .

HAZARDOUS POLYMERIZATION' J i l l n o t o c c u r

CONDITIONS TO AVOIDS o n e * n o w n

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I If

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p r o d u c t m a ye s u I t ine v e r (r e q u ia n a s a f e t y

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< e e D s p e c t a t o r s a w a y . E l i m i n a t e a l l i g n i t i o n s o u r c e s ( f l a m e s. u r t a c e s , and s o u r c e s cf e i e c t r i c a l , s t a t i c o ' • - i c t i o n a I ;, p aD i k e a n d c o n t a i n s p i l l w i t h i n e r t m a t e r i a l ( e . g . s a n d , e a r t h ). i q u i d s t o c o v e r e d m e t a l c o n t a i n e r s f o r - e c o v e r y c r d i s p o s a l ,« i t h i n e r t a P s o r b e n t . ^ s e o n l y n o n - s p a r * i n g t o o i s . P l a c e a b s• n a t e r i a . s i n c o v e r e d m e t a l c o n t a i n e r s f o r d i s p o s a l . P r e v e n t co f s e w e r s , s t r e a m s , a n d g r o u n d u a t e r w i t h s p i l l e d m a t e r i a l o ra P s o r b e n t .

HASTE DISPOSALD i s p o s e i n a c c o r d a n c e w i t h f e d e r a l , s t a t e a n d l o c a l r e g u l a t i o

RCRA CLASSIFICATIONT h i s p r o d u c t c o n t a i n s c h r o m i u m . W a s t e r e s i d u e o * t h i s p r o d u c tj s h a z a r d o u s w a s t e ( 4 0 C F R P a r t 2 6 1 . 7 4 - C h a r a c t e r i s t i c o f E PT h i s p r o d u c t , i f d i s c a r d e d d i r e c t l y , w o u l d b e c l a s s i f i e d a h ao a s e d o n i t s i g n i t a b i l i t y c h a r a c t e r i s t i c , i . e . h a s a f l a s h p oa e g . E . ( 6 0 d e g . C ) o r l e s s . T h e p r o p e r R C R A c l a s s i f i c a t i o n w o u' h i s p r o d u c t c o n t a i n s l e a d , w h i c h , i f p r e s e n t i n w a s t e a t 5 . 0m o r e a f t e r D o i n g e x t r a c t e d , i s c o n s i d e r e d E P T o x i c , a n d t h e r eh a z a r d o u s w a s t e u n d e r R C R A r e g u l a t i o n s . T h e H a z a r d o u s w a s t e n» o u l d b e D008.

ENVIRONMENTAL HAZARDS^ o n e k n o w n


S e t e r t o O S H A s t a n d a r d f o r s p e c i f i c r e s p i r a t o r y p r o t e c t i o n r r• o r , c a d , 2 9 C F R 1 9 1 0 . 1 0 2 5 .;" r o D c r s e l e c t i o n ot r e s p i r a t o r y p r o t e c t i o n d e p e n d s - p o n m a n y^ e l u d i n g d u r a t i o n / l e v e l o f e x p o s u r e a n d c o n d i t i o n s o t u s e .

e x p o s u r e t o o r g a n i c c h e m i c a l s s u c h a s t h o s e c o n t a i n e d • n t h i s" O t r e q u i r e t h e u s e c f r e s p i r a t o r y p r o t e c t i o n i f u s e d i n w e l la r e a s . I n r e s t r i c t e d v e n t i l a t i o n a r e a s a N I O S H a p p r o v e d c h e m i

m e c h a n i c a l p r e f i l t e r m a y a l s o b e r e q u i r e d . ' . n c o n f i n e d a r e a sM s H A a p p r o v e d a i r s u p p l i e d r e s p i r a t o r . : f t h e T L V ' s l i s t e d i nj r e e x c e e d e d u s e a p r o p e r l y f i t t e d N 1 0 S H / M S H A a p p r o v e d r e s p i ra p p r o p r i a t e p r o t e c t i o n f a c t o r . R e f e r t o O S H A 2 9 C F R 1 9 1 0 . 1 3 4P r o t e c t i o n " , a n d " R e s p i r a t o r y P r o t e c t i o n A M a n u a l A n d G u i d e l iI n d u s t r i a l H y g i e n e A s s o c . "

VENTILATIONR e f e r t o O S H A s t a n d a r d s f o r s p e c i f i c v e n t i l a t i o n r e q u i r e m e n t si e a d - 2 9 C F R 1 9 1 0 . 1 0 2 5 .P r o v i d e g e n e r a l d i l u t i o n a n d l o c a l e x h a u s t v e n t i l a t i o n i n s u fa n d p a t t e r n t o k e e p c o n c e n t r a t i o n s o f h a z a r d o u s i n g r e d i e n t s IS e c t i o n i : b e l o w t h e l o w e s t e x p o s u r e l i m i t s t a t e d . R e m o v e d e cp r o d u c t s t h a t a r e g e n e r a t e d w h e n w e l d i n g , c u t t i n g , o r b r a z i n gc o a t e d w i t h t h i s p r o d u c t . R e f e r t o " I n d u s t r i a l v e n t i l a t i o nR e c o m m e n d e d P r a c t i c e " A C G 1 H


EYE PROTECTIONw e a r s a f e t y s p e c t a c l e s .

OTHER PROTECTIVE EQUIPMENTA s r e q u i r e d t o p r e v e n t s k i n c o n t a c t . S e e O S H A s t a n d a r d f o r I

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SECTION X - SPECIAL PRECAUTIONS.; CAUTIONS

D o n o tTO BE

s t o rTAKEN INe a D o v e

HANDLING AND'15 d e g . f

STORAGE( A 6 d e g C ) t o r e l a r g e q u a n t i t i e s

526040 13 PAGE 4DATE 11/07/96

SECTION X - SPECTXt


OTHER PRECAUTIONSD o n o t t a k e i n t e r n a l l y . C l o s e c o n t a i n e r a f t e r e a c h u s e .K e e p a w a y f r o m c h i l d r e n .D o n o t b r e a t h e s a n a i n g d u s t .W a s h h a n d s a n d f a c e t h o r o u g h l y b e f o r e e a t i n g o r d r i n n i n g .E m p t y c o n t a i n e r s n u s t n o t b e w a s h e d and r e - u s e d * o r a n y p u r p o s e .C o n t a i n e r s s h o u l d b e g r o u n d e d a n d b o n d e d t o t h e r e c e i v i n g c o n t a i n e rD o r o t w e l d , o r a z e o r c u t o n e m p t y c o n t a i n e r .N e v e r u s e p r e s s u r e t o e m p t y . D r u m i s n o t a p r e s s u r e v e s s e l .

SECT

SECT!P R O P E R S H I P P I N G N A M E ( A R

D O T C L A S S I F I C A T I O N

D O T L A B E L

D O T P L A C A R D

P R E C A U T I O N S T O B E T A K E N

L I M I T E D Q U A N T I T Y : N o0 . 0 . T . ! . D . K U M B E R UN 12

U N I T C O N T A I N E R

P I N T M E T A LQ U A R T •< E T A LG A L L C N M E T A .

•; G A L L O N " E T A L

S S c. A L L C N M E * A L' I B E R B O A R D B O X

( N O P . A S T I C C O N T A I N E R SA > C ; T U N I T C O N T A I N E R ) .

'ION

ON XT I C L

I N T

6 3

D . 0 .

2 N2 N2 N• 7 C1 7 K1 7C' 7 K• 2 B

- I L L

XI - OTHER INFORMATION

II - TRANSPORTATION DATAE ) P A I N T D O T M A R K I N G T H I S S I D E U P

F L A M M A B L E L I Q U I D E M E R G E N C Y A C C I D E N T P R E C A U T I O N S

F L A M M A B L E & P R O C E D U R E S S E E A B O V EF L A M M A B L E

R A N S P O R T A T I O N

A E R O S O L P R O P E L L E N T : N o t a p p l i c a b l eR . 0 . NO. U . S . P O S T A L F O R B I D D E N

T . U N

1 N 11 N 11 N 11 A 11 A 21 A 11 A24 G

B E A U N I T C O N T A I N E R C N L Y U S E D -"OR 1 C O M P O N E N T O F

T H I ST H E

I SE S

T O C E R T I F Y T H A T T HO F O U R K N O W L E D G E ,

I S I T E M IC O R R E C T .

S H A Z A R D O U S A N D I N F O R M A T I O N S T A T E D I S T 0


I S F 0 R M A T IONU R A T E . W H I L E

' M E<v c cE X P R E S S E DBE C B T A I N EC O N D I T I O N SU S E R ' S

Tr e s p o n s i

C O N T A I N E D H E R E I N

OR I M P LD F R O M

H EI E DT H E

I S B A S E D O N D A T A C O N S I D E R E DN F O R M A T I O N I S B E L I E V E D ' 0 B E R E L I A BR E G A R D I N G T H E A C C U R A C Y O F T H I S D A T AU S E T H E R E O F . S I N C E T H E U S E C F T H I S

O B L I G A T I O Nh e C o r p o r a l

TA N D U S E O F T H I S P R O D U C T A R E C O N T R O L L E D B Y T H

b I e

T O D E T E R M I N E T H Ee S a f e t y a n d E n v i

C O N D I T I O N S O Fr o n m e n t a l A f f a

f o r t h e p r e p a r a t i o n o f t h i s M a t e r i a l

O BEI E M O W A R R A N T Y I SO R T H E R E S U L T S T O

I N F O R M A T I O N A N D T H EE U S E R , I T I S T H E

O F T H E P R O D U C T .D e p a r t m e n t ' s

a f e t y D a t a S h e e t .

S A F E U S Er sS

PRATT & LAMBEF.T 316-733-1361Industrial Coatings Div.

Cleveland, OH 44115DOT EMERGENCY CHEMTEL (800)255-3924 (24hr«)INFORMATION PHONE NO. 216-566-2902 IM-F 8 AM-5 PM CT)


H.M.I.S.HEALTH 1•FLAMMABILITY 3nraivm o

"hese ratings should be used onlypart cf f u l L y implemented H.M.I.S. program.

M A T E R I A L S A F E T Y D A T A S H E E TSECTION I


TRADE NAME .... H I G H S O L I D S • * * * B R O U N «

MANUFACTURER CODE I .D. 5 2 7 0 0 6 22

REVISED ON ' > 1 / 0 7 / 9 6


26 A / D OR E N L

C O N T R A C T

!INGREDIENT


% BYWOT

CAS NO./ NIOSH*


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SAPT HA ( P E T R O L E U M )H E A V Y AIK.YL ATEX Y I E K E

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100150100•50

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13463-67-7 T L V - T U AP I G M E N T XR2275000 CSHA-PEL

8032-32-u T L V - T W A016180000 OSHA-PEL

64742-88-7 TLV-TUAOSHA-PEL

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MPPCF SKIN

F L L O W E R - L A M M A B I L 1 T Y L I M I T P E R C E N Tj F L U P P E R ( L A M M A B I L I T Y L I M I T P E R C E N TS K I N ^ K I N A B S O R P T I O N M U S T B E C O N S I D E R E D A S A• • • : • • ; N G = A L L C U . E X P O S U R E . E V E L S H O U L D NOT BE" f R M A N U F A C T U R E R R E C O M M E N D E D E X P O S U R E L I M I T

• r S M O R T - E R M E X P O S U R E L I M I TS A R A 5 ' 3 - I n E M I C A L I S S U B J E C T T O R E P O R T I N G R E Q U I R E M E N T S O F

• • • ' T L E I J I OF S . A . R . A . -.0 CFR P A R T 372S i O S r t S = N l O S H R E G I S T R Y C F T O X I C E F F E C T S O F C H E M I C A L S U B S T A N C E S

R O U T E O F E X P O S U R EE X C E E D E D ' O R A N Y ' : M E P E R I O D

S E C T I O N 3 1 3

N U M B E R .


C a n c a u s e g a s t r o i n t e s t i n a l i r r i t a t i o n , n a u s e a , j n d v o m i t i n g . A s p i r a t i o n o fm a t e r i a l ' n t o l u n g m a y c a u s e c h e m i c a l p n e u m o n i t i s w h i c h c a n b e f a t a l .

INHALATION" a y c a u s e " o s e o r t h r o a t i r r i t a t i o n . H i g h c o n c e n t r a t i o n s m a y c a u s e a c u t ec e n t r a l n e r v o u s s y s t e m d e p r e s s i o n c h a r a c t e r i z e d b y h e a d a c h e s , d i z z i n e s s ," a u s e a a n a c o n f u s i o n .


SKINM a y r . i u s e d e f a t t t n q a n d i r r i t a t i o n o f t h e s k i n .

EFFECTS OF REPEATED OVEREXPOSUREQ v e r e > p o s u r e t o n y i e n e m a y c a u s e i n j u r y t o t h e l i v e r , k i d n e y s , a n dD I o o d .R e p e a t e d a n d p r o l o n g e d o v e r e x p o s u r e t o r e l a t i v e l y i n s o l u b l e c h r o m a t e sm a y c a u s e , u n g c a n c e r .C h r o n i c c v e r e x p o s u r e t o l e a d m a y r e s u l t i n s e v e r e d a m a g e t o b l o o d f o r m i n g ,• ^ e r v o u s , u r i n a r y a n d r e p r o d u c t i v e s y s t e m s . S o m e c o m m o n s y m p t o m s o f c h r o n i; v e r e x p o s i _ , r e i n c l u d e l o s s o f a p p e t i t e , m e t a l l i c t a s t e i n t h e m o u t h ,a n x i e t y , ^ o n s t i p a t i o n , n a u s e a . w e a k n e s s , i n s o m n i a , h e a d a c h e , m u s c l e a n do i n t p a i n , ' i n e t - e m o r s , n u m b n e s s , d i z z i n e s s , h y p e r a c t i v i t y a n d c o l i c .

O c c u p a t i o n a l e x p o s u r e t o l e a d i s r e g u l a t e d b y O S H A - 2 9 C F R ' 9 1 0 . 1 0 2 5 .P r e x i s t i n g k i d n e y c o n d i t i o n s m a y b e a g g r a v a t e d b y e x p o s u r e s t o l e a d .

527006 22PAGE 2DATE 11/07/96

SECTION III - HEALTH INFORMATION; (CONTINUED)

EFFECTS OF REPEATED OVEREXPOSURER e p o r tt o s o l11 1 S U S 6i a r m f u

JIFICANTT IT 0

t h

t a n ix i c o

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9

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I . H . Ta s i g n

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T 0 xas oq e n c

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WITHN 0 Tt i e

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p r o l o n g e d a n d r e p e a t e d o c c u p a t i o n a l o v e r e x p o s u r ee n t b r a i n a n d n e r v o u s s y s t e m d a m a g e . I n t e n t i o n a lc o n c e n t r a t i n g a n d i n h a l i n g t h e c o n t e n t s m a y b e

POSSIBLE RELEVANCE TO HUMAN HEALTH.l i s t e d a s a p o t e n t i a l c a r c i n o g e n b y t h e N a t i o n a lI n t e r n a t i o n a l A g e n c y f o r R e s e a r c h o n C a n c e r , O S H A ,

d i o x i d e i n a 2 4 - m o n t h i n h a l a t i o n s t u d y w i t h r a t si n c r e a s e i n b e n i g n a n a n a i i g n a n t l u n g t u m o r s i n t h eM 3 r e s p i r a b l e T i 0 2 3 u s t . At l o w e r e x p o s u r e l e v e l s ,w a s n o t o b s e r v e d , " h e n o r m a l c l e a r a n c e m e c h a n i s m s

e e n o v e r w h e l m e d a t t h e 2 5 0 m g / M 3 e x p o s u r e l e v e l , a n de d t o t h e t u m o r f o r m a t i o n . T h e s e r e s u l t s m a y n o tt h e w o r k p l a c e w h e r e o c c u p a t i o n a l e x p o s u r e l i m i t s

V t h e T i 0 2 m a n u f a c t u r e r c o n c l u d e s t h a t t h e r e i s n om a n .r o m i u m c o m p o u n d s a r e l i s t e d a s p o t e n t i a l c a r c i n o g e n so g y P r o g r a ml i s t e d a s a p o t e n t i a l a n i m a l c a r c i n o g e n b y t h er R e s e a r c h on C a n c e r .


i f s w a l l o w e d a o n o t i n a u c e v o m i t i n g . C a l l p o i s o n c o n t r o l c e n t e r , h o s p i t a le m e r g e n c y r o o m o r p n y s i c i a n i m m e d i a t e l y .

INHALATION .R e m o v e t c f r e s h a i r i m m e d i a t e l y . I f b r e a t h i n g h a s s t o p p e d , g i v e a r t i t i -c i a l - e s p i r a t i o n . K e e p w a r m a n d q u i e t . G e t m e d i c a l a t t e n t i o n i m m e d i a t e l y .

EYE( l u s h w i t h . a r g e a m o u n t s o f w a t e r , l i f t i n g u p p e r n n a l o n e r , i d s o c c a s i o n a l -, y . C o n t i n u e t o r a t l e a s t 1 5 m i n u t e s . G e t m e d i c a l a t t e n t i o n .

R e m o v e c o n t a m i n a t e d c . o t h i n g . U a s h a f f e c t e d a r e a w i t h s o a p a n d w a t e r .O b t a i n m e d i c a l a t t e n t i o n i f i r r i t a t i o n p e r s i s t s .

NOTES TO PHYSICIANA n y t r e a t m e n t t h a t r i g h t b e r e q u i r e d f o r o v e r e x p o s u r e s h o u l d b ea , r e c t e g a t t h e c o n t r o l o f s y m p t o m s a n d t h e c l i n i c a l c o n d i t i o n s .

SECTIONBOILING RANGE

FREEZING POINT:POR PRESSURE:

vAPOR DENSITY

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. ( - 4 53 68

a i r .

V - PHYSICAL4 D E C . C . )

D E G . C . )

D E G . f . ( 2

% VOLATILE

T 0

0

BY

DATA4 1 4 D E G . F . (

D E G . C . )

VOLUME '. 2

2 1 2 D E G . C . )

EVAPORATION RATES l o w e r t h a n o i e t h y l e t h e r .


VOC 3.40 Ib/gal less water & NPRS*

VOC 7 . 1 6 Ib/gal

- 0 8 g/1 less vwcerc A L

8 5 9 g / 1 aolitte C A L C U L A T E !

APPEARANCE & ODOR:

VISCOSITY:

L i q u i d , S o l v e n t o d o r

N o i n f o - n a t i o n f o u n d

SOLUBILITY:PH:

S l i g h t

- • r ( s T Di w a t e r

U N I T S )

All Physical data determined at 68 DEG. F. (20 DEG. C.) 760 mm Hg• Negligibly Photochemically Reactive MaterialsVOC values reported here are verified by ASTM method D-3960_______

SECTION VI - FIRE AND; EXPLOSION DATAF L A M M A B L E L I Q U I D C L A S S 1 CNFPA FLAMMABILITY CLASSIFICATION

FLAMMABLE LIMITS 1.0 % - 7 . 0 '/.

FLASHPOINT 8 0 0 E G . F , ( 2 7 D E G . C , ) C A L C U L A T E D

AUTOIGNITION 5 7 2 D E G . F . ( 3 0 0 D E G . C . ) DECOMPOSITION TEMP 1 8 3 2 D E G . F . ( 1 0 0 0 D E G . C . )

CORROSION RATE N o t a p p l i c a b l e MAGNETISM N o t a p p l i c a b l e

NET EXPLOSIVE WGT . N o t a p p l i c a b l e

EXTINGUISHING MEDIAU s e N F P A C l a s s B F i r e e x t i n g u i s h e r s ( c a r b o n d i o x i d e a l l p u r p o s e d r y c h e m i -c a l o r a i c o h o l f o a m ) d e s i g n e d t o e x t i n g u i s h f l a m m a b l e l i q u i d f i r e s . P o l y -m e r f o a m i s p r e f e r r e d f o r l a r g e f i r e s .

UNUSUAL FIRE AND EXPLOSION HAZARDS3 u r i n g e m e r g e n c y c o n d i t i o n s , o v e r e x p o s u r e t o d e c o m p o s t i o n p r o d u c t s m a yc a u s e a h e a l t h h a z a r d . S y m p t o m s m a y n o t b e i m m e d i a t e l y a p p a r e n t . O b t a i nm e d i c a l a t t e n t i o n .W A R N I N G ' F L A M M A B L E .

CIAL FIRE FIGHTING PROCEDURESW a t e r m a y b e i n e f f e c t i v e , b u t m a y b e u s e d t o c o o l e x p o s e d c o n t a i n e r s t o

527006 22

PAGEI I

• FIRS AND EXPLOSION DATA; (CONTINUED)• • '

SPECIAL FIRE FIGHTING PROCEDURESD r e v0 X D 0

e n ts e d

p r e s s u r e D u i l d - u p a n d p o s s i b l e a u t o - i g n i t i o n o r e x p i o s it o e x t r e m e h e a t . I f w a t e r i s u s e d , f o g n o z z . e s a r e p r e f

o n w h e ne r a b I e .

SECTION VII - REACTIVITY DATAjTRALIZING AGENT N o : - f o r m a t i o n f o u n d


CONDITIONS tO AVOIDA v o i d e x c e s s i v e h e a t

INCOMPATABILITY (MATERIALS TOS t r o n g a c i d s o r a l k a l i n

HAZARDOUS DECOMPOSITION PRODUCTS

C > 1 1 5 FAVOID)n e m a t e

a n d s o u r c e i g n i t i o n

B u r n i n g , i n c i u d ic a r b o n m o n o x i d eo x i d e s o f l e a d

W e l d i n g , b rp r o d u c e m e t" M e t a l F u m ea n d c o u g h .d e p e n d i ngp r o f e s s i o n


CONDITIONS TO AVOIDN o n e i n o w n

n g wa n dm a y

a z i n g , ora I o x i d e sF e v e r " .

A n a i rI ei p o n

I I

h e n l e a t e d b y w e l d i n g o r cc a r b o n d i o x i d e . I n a d d i t i o nb e g e n e r a t e d .t o r c h c u t t i n g m a t e r i aO v e r e x p o s u r e t o t h e s e

S y m p t o m s i n c l u d e a f l u - lp u r ' f y i n g o r s u p p l i e d a i r

s of e x p o s u r e . C o n s u l t a

t to

9 ,d e s

I If

o d u c eo m i u m

s m o k e

v e I

s c o am e t a l

k e •e s p iq u a I

t e do

i i t hd e s

t h i s

I I n e s sr a t o ri f i e d

p r o d u c t m a ye s u I t in

m a yh e a

t n f e v e r ,be r e q u i

I t h and s

c hr e da f e t y

i l l s

SECTION VIII - ENVIRONMENTAL INFORMATIONSTEPS TO BE TAKEN IF MATERIAL

«, e e p s p e c t a t o r s a w a y ,• l u r f a c e s , a n d s o u r c e s3 i K e and c o n t a i n s p i i, - q u i d s t o c o v e r e d m« i t h i n e r t a b s o r b e n tm a t e r i a l s i n c o v e r e do f s e w e r s , s t r e a m s ,a p s o r p e r t .

c

a

ISc

t aJ

m en d

RELEASED OR SPILLEDE l i m i n a t e all • g n i t i o n s o u r c e s ( ' l a m e s , hot• e . e c t r i c a t , s t a t i c c r t - i c t i o n a l s p a r x s ) .n i t h i n e r t m a t e r i a l ( e . g . s a n d , ? a r t h ) . - aistea9

c

ir

o n t a i n e r s f o r r e c o v e r y o r d i s p o s a l , o r ro n l y n o n - s p a r k i n g t o o i s . P l a c e a b s o r b e nc o n t a i n e r s f o r d i s p o s a l . P r e v e n t c o n t a m

o u n d w a t e r w i t h s p i l l e d m a t e r • a i or u s e d

neti

sm

n

f0da

e rv ei k i n gt i o n

WASTE DISPOSAL

RCRAD i s p o s e i n a c c o r d a n cCLASSIFICATION" h i s p r o d u c t c o n t » i na s h a z a r d o u s w a s t e (T h i s p r o d u c t , i f d i sD a s e d on its i g n i t a ba e g . :.(60 d e g . C ) or" h i s p r o d u c t c o n t a i nm o r e a f t e r b e i n g e x th a z a r d o u s w a s t e u n d e

e

s

ci

srr

M

C0a rI :, e

a cR

i

ncd

setC

t

rFeysaeR

h

0Rd

daA

f e d e r a l , s t a t e a n d l o c a l r e g u l a t i o n s .

m i u m . W a s t e r e s i d u e o ' t h i s p r o d u c t m a yP a r t 2 6 1 . 7 4 - C h a r a c t e r i s t i c o f E P T o x i cd i r e c t l y , w o u l d b e c l a s s i f i e d a h a z a r d o

c h a r a c t e r i s t i c , i . e . h a s a f l a s h p o i n t oT h e p r o p e r R C R A c l a s s i f i c a t i o n w o u l d b ew h i c h , i f p r e s e n t i n w a s t ; ' a t 5 . 0 m g / l

, ' s c o n s i d e r e d E P T o x i c , a n d t h e r e f o r er e g u l a t i o n s . T h e h a z a r d o u s w a s t e n u m b e r

qif

a

ut

D0

ay10r

I i f y

4 00 1 .

w o u l d b e D 0 0 8ENVIRONMENTAL HAZARDS

N o n e u n o w n


R e f e r t o 0•or . e a a ,V r c p e r •. e I' n c i u d i n ge x o o s u r e tn o t r e q u i ra r e a s . I n' e s p i r a t o rn e c h a n i c a lM S H A a p p r o,i r e e x c e e dj p p r o p r i a tP r o t e c t i o nI n d u s t r i a l

VENTILATIONR e f e r t o

HA s t a n d a2 9 C F R 1 9 1 0

e c t i o n c fd u r a t i o n / Io o r g a n i ce t h e u s er e s t r i c t e dmay be r ep r e f i I t e r

v e d air s us e a po t e c t i

a n d " R ey g i e n e A

e de p

r a f o. • C 2 5r 0 s P le v e ic n e m io f r ev e n t

q u i r eTi a y

p p I i er o p e r

s p e c i f i c r e s p i r a t c r y p r o t e c r e q u i r e m e n t s

o ns p i

r a t o r y p r o t e c t - o no f e x p o s u r e a n d cc a l s s u c h a s t h o ss p i r a t o r y p r o t e c ti l a t i o n a r e a s a Nd . U n d e r c e r t a i na l s o b e r e q u i r e d ,d r e s p i r a t o r . i ft y f i t t e d N I O S H / Mc t o r . R e f e r t o O St o r y P r o t e c t i o n A

d e p e n d s ^ p o n m a n yt

f a c t o r sn g e n e r a

s p r o d u c tv e n t i I

o n d i t ' o n s o f u s ee c o n t a i n e d i n t n ii o n i f u s e d i n w e l lI O S H a p p r o v e d c h e m i c a l c a r t rc o n d i t i o n s , s u c h a s s p r a y i n g , a

o n f i n e d a r e a s use a N I 0 S H /V ' s l i s t e d i n S e c t i o n I I

a p p r o v e d r e s p i r a t o r w i t h a n" C F R 1 9 1 0 . 1 3 4 " R e s p i r a t o r y

m a ya t e d

i d g ea

I n ct h eS H AHA 29M a n u a l A n d G u i d e l i n e , A m e r i c a n

• a d - 2 9 C F Rg e

r a s o r s p e c i f i c v e n t i l a t i o n r e q u i r e m e n t s f o r

a n d l o c a l e x h a u s tn t r a t i o n s o f h a i as t e x p o s u r e l i m i te a w h e n w e l d i n g ,R e f e r t o " I n d u s t

G I H .

r d o u s is t a t e d

c u t t i n g , o rr i a l V e n t i I t i o n

P r o v i d e g e n e r a l d i l u t i o na n d p a t t e r n t o k e e p c o n c eS e c t i o n I I b e l o w t h e l o w ep r o d u c t s t h a t a r e g e n e r a tc o a t e d w i t h t h i s p r o d u c t .R e c o m m e n d e d P r a c t i c e " A C


EYE PROTECTIONu e a r s a f e t

OTHER PROTECTIVEA s r e q u i r e d t o p r e v e n t s k i n c o n t a c t

v e n t i l a t i o n i n s u f f i c i e n t v o l u m en g r e d i e n t s l i s t e d i n

R e m o v e d e c o m p o s i t i o nb r a z i n g o b j e c t s

A M a n u a l o f

y s p e c t a c lEQUIPMENT

• d t o p r e v e S e e O S H A s t a n d a r d f o r l e a d

SECTION X - SBEC1AL PRECAUTIONSTO BE TAKEN IN HANDLING AND STORAGE

d u a n t i t i e s

527006 22 PAGE 4DATE 11/07/96

SECTION X - SPECIAL PRECAUTIONS; (CONTINUED)

PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGEc o m p l i a n c e » i t h O S H A 2 9 C F R 1 9 1 0 . 1 0 6 .

OTHER PRECAUTIONSD o n o t t a k e i n t e r n a l l y . C l o s e c o n t a i n e r a f t e r e a c h u s e .D o n o t b r e a t h e s a n d i n g d u s t .W a s h h a n d s a n d f a c e t h o r o u g h l y b e f o r e e a t i n g o r d r i n k i n g .E m p t y c o n t a i n e r s m u s t n o t b e w a s h e d a n d r e - u s e a f o r a n y p u r p o s e .C o n t a i n e r s s h o u l d b e g r o u n d e d a n d b o n d e d t o t h e r e c e i v i n g c o n t a i n e rD o n o t w e l d , b r a z e o r c u t o n e m p t y c o n t a i n e r .N e v e r „ s e p r e s s u r e t o e m p t y . O r u n i s n o t a o r e s s u r e v e s s e l .


SECTIONP R O P E R S H I P P I N G N A M E

D O T C L A S S I F I C A T I O N

D O T . A B E LD O T P L A C A R DP R E C A U T I O N S T O B E T A

L I M I T E D Q U A N T I T Y :D . O . T . I . 0 . N U M B E R U

U N I T C O N T A I N E R

1 P I N T " E T A LQ U A R T M E T A L

• C - A L L C N M E T A L5 G A L L O N M E T A L5 5 G A L L O N M E T A LF I B E R B C A R D B O X( N O P L A S T I C C O N T A I NA K I T U N I T C O N T A I N E

( A R T I C

K E N I N

N 0N 1 2 6 3

0 . 0

2 N2 N2 N' 7C1 7 K1 7 C1 7 K1 2 B

E R S U I LR ) .

XII - TRANSPORTATION DATAL E ) P

F L A M M

F L A M M

F L A M M

T R A N S P O R T

A E RR . 0 . N

. T . U N

1 N 11 N 11 N 11 A 11 A31 A 11 A 24 G

L BE A UN

A 1 N T D O T M A R K I N G T H I S S I D E U P

ABLE. L I Q U I D E M E R G E N C Y A C C I D E N T P R E C A U T I O N S

A B L E i P R O C E D U R E S S E E A B O V E

A 8 L |

A T I 0 N

O S O l P R O P E L L E N T : N o t a p p l i c a b l e0 . U . S . P O S T A L F O R B I D D E N

I T C O N T A I N E R O N L Y U S E D F O R ' C O M P O N E N T O F

T H I S I S T O C E R T I F Y T H A T T H I S I T E M I S H A Z A R D O U S A N DT H E 3 E S T O F O U R K N O W L E D G E , C O R R E C T .

N F O R M A T I C N S T A T E D I S T 0

R E G U L A T O R Y N F O R M A T I O N S E R V I C E S

' i E I N F O R M A T I O N CA C C U R A T E . . M I L EL X P R E S S E C O R 1 M P L3 E O B T A I N E D F R O MC O N D I T I O N S A N D UU S E R ' S O B L I G A T I O N

T h e C o r p o r a tr e s p o n s i b l e f o r

0 NM E1 ET HS E

Tet h

T

DE

0Se

A|

0

a

I N E D H E R E I N IS B A S E D " H D A T A C C N S I D E R E D TO^ F O R M A T I O N I S B E L I E V E D " 0 8 E R E L I A B L E . S O UR E G A R D I N G T H E A C C U R A C Y O F T H I S 0 A T A O R T H EU S E T H E R E O F . S I N C E T H E U S E O F T H I S ; N F O R M A TF T H I S P R O D U C T A R E C O N T R O L L E D B Y T H E U S E RD E T E R M I N E T H E C O N D I T I O N S O F S A F E U S E O F T H Ef e t y a n d E n v i r o n m e n t a l A f f a i r s D e p a r t m e n t ip r e p a r a t i o n o f t h i s M a t e r i a l S a f e t y D a t a S h

BARII

Se

ERE0TP

e

RSN

R

t

AU

I0

NLASD

TTN

U

YSDTC

I ST 0T H

H ET .

MATERIAL SAFETY DATA SHEET

MANUFACTURER' S NAME1RATT i LAMBERT Industrial boatings Div.••.0. Box -D027:leve_dr.d, CH 441C1-1C27

C T "' ——rt . ~ PREPAR

•'AR - ? 2

Section I

EMERGENCY TELEPHCNE NO.. 2IG. 5-36-2^17

INFORMATI 2N TELEPHONE NO.:' 2 1 G ' =3 6 6 - 2 :• 0 2

PRODUCT IDENTIFICATION

PRODUCT NUMBER HMIS CCDESHealth 2*rlammabiiity 3Reactivity 0

PRODUCT NAME• .- VOC :<:S Enamel, Biacr:

PRODUCT CLASSAlkvd Er.arr.el

ection II HAZARD C US I NGRED I ENTSACC

% by WT TSKA:T V.P

V. :•: . •. P. N'apr.ta.v4742-r?--'

Xir.eral Spirits.-. 4742 - ri S - '•'

Pine '_ 1 1 .- G C 2 - C 5 - 7i

r a i t 2 -Ethy ihexanoate .1 3 6 - v 2 - ""

Carbon Black.1333-86-4

29STEL9

2

C.2

S

300 PPM40C PFX100 PPM

300

100

Not Established

Not Established

3.5 3.5 MG/M3

12. CO

2.00

0.10

0.00

0.00

Section III PHYSICAL DATA

: RCDUCT '.•.'EIGHT::rKc:"ic GRAVITY

EVAPCRATICN KATEVAPOR LENSITY

VOLATILE VOLUMEVOC Theoretical)

SOLUBILITY IN WATER - -382 gm. less Federall

Slower • r.an Etherieavic-r than Air•;. A .N. A./ Exemct Solvents)

FIRE 7uND EXPLOSION HAZARD 2ATA

FLASH POINT LEL-' 0 F PMCC 0.9

FLAMMAB I L I TY CLASS I F I CAT I ONRED LABEL -- Flammable, Flash below 100 F

EXTINGUISHING MEDIA.'arbor. Dioxide, Dry Chemical, Foam

UEL- . C

rntinuea on oaae

521

"JNUS'JAL FIRE AND EXPLOSION HAZARDSKeep containers tightly closed. Isolate from heat, electrical

equipment, .sparks, and open flame. Closed containers nay explode whenexposed to extreme heat. Application to hot surfaces requires specialprecautions. During emergency conditions cverexposure to decomposition

ducts may cause a health hazard. Symptoms may net be immediately^parent. Obtain medical attention.

SPECIAL FIRE FIGHTING PROCEDURESFull protective equipment including self contained breathing apparatus

should be used. Water spray may be ineffective. If water is used, fognozzles are preferable. Water may be used " o cool -iosed containers toprevent pressure build-up ana possible autcignition or explosion whenexccsed ~-~ extreme heat.

Section V -- HEALTH HAZARD DATA

ROUTES CF EXPOSUREExposure may be by INHALATION and/or SKIN or EYE contact, depending on

conditions cf use. To minimize exposure, follow recommendations for properuse, ventilation, and personal protective equipment.ACUTE Health HazardsEFFECTS CF OVEREXPOSURE

Irritation of eyes, skin and respiratory system. May oause nervoussvstem repression. Extreme cverexposure may result in unconsciousness andccssiblv aeatn.SIGNS AND SYMPTOMS OF OVEREXPOSURE

Headache, dizziness, nausea, and loss cf coordination are indications ofexcessive exposure to vapors or spray mists.

Redness and itching or burning sensation may indicate eye or excessiveskin exposure.MEDICAL* CONDITIONS AGGRAVATED BY EXPOSURE

None generally recognized.IRGENCY AND FIRST AID PROCEDURESIf INHALED: If affected, remove from exposure. Restore breatning.

Keep warm and quiet.If on SKIN: Wash affected area thoroughly with soap and water.

Remove contaminated clothing and launder before re-use.If in EYES-. Flusn eyes with large amounts of water for 15 minutes.

Get medical attention.If SWALLOWED: Get medical attention.

CHRONIC Health Hazards'arccn Black is classified by IARC as possibly --arcir.caer.ic re r.umans

.group IB) based on experimental animal data, however, there isinsufficient evidence in humans for its carcinogenicity.

Cobalt and cobalt compounds are classified by IARC as possiblycarcinogenic to humans (group 2B) based on experimental animal data,however, there is inadequate evidence in humans for its carcinogenicity.

Prolonged overexposure to solvent ingredients in Section II may causeadverse effects to the liver and urinary systems.

Reports have associated repeated and prolonged overexposure to solventswith permanent brain and nervous system damage.

Section VI -- REACTIVITY DATA

'Tontinuea on oaae •

page jS T A B I L I T Y - - Stable

CCND:T:CNS TC AVOID"one .-'.r.cwn.

IN COX ? AT I 2 I LIT YNone known.ARDCUS DECOMPOSITION PRODUCTS3v tire: Carbon Dioxide, Carbon Monoxide

HAZARDOUS POLYMERIZATIONWill not cccur

Section VII -- SPILL OR LEAK PROCEDURES

. •*- * 7 ^~» •*• r> *-^ » « TV T^ 'r^ *"}"*" T\ "" "^ f^ n T* T T"^ T\ C* T^ ^> >""'• T^ , -^ --> T •»• •- T—. T->i r . t - - - — -rt _N ^.t\Sc. .-J\i c,RÂ^ ^S RELEASED R b r1 IL.L.E.L,Remove all sources of ignition. Ventilate and remove w:th inert

absorbent.WASTE DISPOSAL METHOD

Waste from this product T.ay be hazardous as defined under the ResourceConservation and Recovery Act ;RCRA) 40 CFR 2G1.

Waste rust be tested for ijnitability to determine "he applicable EPAhazardous waste numbers.

Incinerate in approved facility. Do not incinerate r'.osed container.Dispose of in accordance v.-ith Federal, State, ind I.jcai regulationsreaarair.d cO'iluticn.

PROTECTICN INFORMATION

PRECAUTIONS TO 3E TAKEN IN USEUse ,,niy with adequate ventilation. Avoid breathing vapor and spray

mist. Avoid oontact with skin and eyes. 'Wash hands after using.This coating may contain m.aterials classified as nuisance partiouiates

listed "as Dust" in Section II) which may be present at hazardous levels'y during sanding or abrading of the dried film. If no specific dustslisted in Section II, the applicable limits for nuisance dusts are

.->._JIH TLV ID n-^g./rnS \total dust:, 3 mg./m3 (respirabie fraction/, :SHA PEL15 mg. / rn3 (total dust! , 5 mg./m3 (respirabie fraction) .VENTILATION

Local -xhaust preferable. General exhaust acceptable if the exposure tomaterials in Section II is maintained below appiioaoie exposure limits.Refer -o OSHA Standards 1310.94, 1910.107, 191G.1C8.RESPIRATORY PROTECTION

: i rerscnal --xpcsure 'ar.r.ct be controlled below -jpplicable limits byventilation, v;ear a properly iitted organic viper rartiouâto respiratorapproved by NIOSH/MSHA nor protection against materials in Section II.

When sanding or abrading the dried film, wear a dust/mist respiratorapproved by NIOSH/MSHA for dust which may be generated from this product,underlying paint, or the acrasive.PROTECTIVE GLOVES

Wear gloves which are recommended by glove supplier tor protectionagainst materials in Section II.EYE TROTECTION

Wear safety spectacles with unperforated sideshieids.

Section IX -- PRECAUTIONS

DOL STORAGE CATEGORY13

Continued en page 4

5 2 1 0 2 0 p a g e 4

PRECAUTIONS TO BE TAKEN IN HANDLING AND STORINGnor>^ts aye rjlMMAELE. Keep away from iieai, ccrae, a»w c?en f l a m e-Curing use and until all vapors are gone: Keec area ventilated - Do not

smoke Extinguish ail flames, pilot lights, and heaters Turn off stoves,e'ectnc tools and appliances, and any other sources of ignition.

Consult NFPA Code. Use approved Bonding and Grounding procedures.Keep container closed when not in use. Transfer only to approved

containers with :cmpie~-r ;nd appropriate labelim. 7o net take internally.Keep ut "f r ne : o-acn :. 'hildren.OTHER T RECAUTIONS

Intentional misuse :;y deliberately concentrating and inhaling thecontents can he harmful ^:r fatal.

Section X -- OTHER REGULATORY INFORMATION

SARA 213 40 CFR 272. 65C) SUPPLIER NOTIFICATION

OAS No. CHEMICAL/COMPOUND % by WT % Element

Cobalt Compound. D.2 0.0

CALIFORNIA PROPOSITION -'.WARNING: This product contains chemicals known to the State :f

California to cause cancer and birth defects r . tr.er reproductive harm.TSCA CERTIFICATION

All chemicals in this product are listed, :r are exempt i rom. listing,on the TSCA Inventory.

The above information pertains to this product as currently formulated,~mci 13 based en the information available at this time. Addition ofreducers or other additives to this product may substantially alter thecomposition and hazards of the product. Since conditions of use areoutside our control, we make no warranties, ^xpress or implied, and assumeno lâciiity in connection with any use of this information.

PRATT S. LAMBERT 316-733-1361Industrial Coatings Div.101 Prospect AvenueCleveland, OH 44115

DOT EMERGENCY CHEMTEL (800)255-3924 (24hr«)INFORMATION PHONE NO. 216-566-2902 (M-F 8 AM-5 PM CT)

H.M.I.S.HEALTH 1FLAMMABILITY 3REACTIVITY 0

"hese ratings should be used onlyoart ot f u l l y imolemented H . M . I . S . program.



SECTION 1 !

PRODUCT CLASS A L K Y 0 , M E D I U M - L O N G

TRADE NAME .... H I G H S O L I D S ' " • " O f f W H I T E A / D D R E N L


REVISED ON 1 1 / 0 7 / 9 6

8 0 1 0 -K A N U F A C T U R E R C A G E 6 1 1 9 6 C O N T R A C T *


INGREDIENT

S A P T H A" E A V Y

? E T R O .: A R S O M

( »£ T R O L E U M )A L < Y L A T E

E u M H Y D R O -M I X T U R E

% BY CAS NO.WGT /NIOSHS

6 4 7 4 1 - 6 5 - 7 M F RS O L V E N T

8 0 3 2 - 3 2 - - T L V - T U A3 1 6 1 8 0 0 0 0 : S H A - P E L

ALLOWABLE SARA VPEXPOSURE LEVEL 313 mm Hg ®

20 DEG.CPPM MG/CU.M. MPPCF SKIN

100

t o ot o o

5 2 5

5 2 55 2 5

• : *AS i c ; e x I D E

S I L : C A , A M O R P H O U S- Y D R A T E :

1 3 4 6 3 - 6 7 - 7 - L V . T W A

= I G M E N T X R 2 2 7 5 0 0 3 C S H A - P E L

7 6 3 1 - 8 6 - v - . V - T U Az I G M E N T O S H A - P E L

8 0 0 0 - 4 1 - 7S O L V E N T

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S K I N A B S O R P T I O N M U S T B E C O N S I D E R E D A S A R O U T E O F E X PN G = A . L O W . E X P O S U R E L E V E L S H O U L D N O T B E E X C E E D E D r O RA N U F A C ' J R E R R E C O M M E N D E D E X P O S U R E L I M I TS H O R T - E R M E X P O S U R E L I M I T3 * 3 = C H E M I C A L I S S U B J E C T T O R E P O R T I N G R E Q U I R E M E N T SE I I I O F S . A . R . A . 4 0 C F R P A R T 3 7 2

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SWALLOWINGC a n c a u s e g a s t r o i n t e s t i n a l i r r i t a t i o n , n a u s e a c a n d v o m i t i n g . Ai a t e r ' ;i * - n t o . u n g rr, ay c a u s e c h e m i c i I p n e u m o n i t i s w h i c h can DC

INHALATION

.o r , t • .1 i - c r v c LI s s y s t e m d e p r e s s i o n c h a r a c t e r i z e d by h e a d a c h e s ,•• a u s e a a r- a c o n t u s i o n .

EYE^ a y c a u s e e y e i r r i t a t i o n .

SKIN«ay c a u s e d e t a i l i n g and • r r i t a t i o n ot the s k i n .

EFFECTS OF REPEATED OVEREXPOSURER e p o r t s n a v e a s s o c i a t e d p r o l o n g e d a n d r e p e a t e d o c c u p a t i o n a l o vt o s o l v e n t s w i t h p e r m a n e n t b r a i n a n d n e r v o u s s y s t e m d a m a g e . I nn i s u s e b y d e l i b e r a t e l y c o n c e n t r a l i n j a n d i n n a l i n g t h e c o n t e n t sh a r m f u l o r f a t a l

SIGNIFICANT LABORATORY DATA WITH POSSIBLE RELEVANCE TO HUMAN HEALTH." i t a n i u m d i o x i d e I S N O T . i s t e d a s a p o t e n t i a l c a r c i n o g e n D y t h" o x i c o l o g y P r o g r a m , t i e I n t e r n a t i o n a l A g e n c y ' o r R e s e a r c h o n Cj r A . C . G . I . r t . T i t a n i u m d ' o x i d e i n a 2 4 , - m o n t h i n h a l a t i o n s t u d y- e v e a l e d a s i g n i f i c a n t - n c r e a s e i n b e n i g n a n d m a l i g n a n t l u n g tg r o u p e x p o s e d t o 2 5 0 m g / M 3 r e s p i r a b l e T i 0 2 d u s t . A t l o w e r e x p o s; n i s s i g n i f ' c a n t e f f e c t - a s n o t o b s e r v e d . T h e n o r m a l c l e a r a n c e: - t t h e i ^ n g s m a y h a v e b e e n o v e r w h e l m e d a t t h e 2 5 0 m g / M 3 p x p o s u rt h i s n a y n a v e c o n t r i b u t e d t o t h e t u t i o r f o r m a t i o n . T h e s e r e s u l tD e d i r e c t 1 , y r e l e v a n t t o t h e w o r k p l a c e w h e r e o c c u p a t i o n a l e x p o sj r e o o s e r v e d . A t t h e T L V t h e l i O Z m a n u f a c t u r e r c o n c l u d e s t h a ts i g n i f i c a n t h a z a r d f o r m a n .

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I f s w a l l o w e d d o n o t i n d u c e v o m i l i n g . C a l l p o i s o n c o n t r o l c e n t e r , h o s p i t a le m e r g e n c y r o o m o r p h y s i c i a n i m m e d i a t e l y .

ALATIONR e m o v e t o f r e s h a i r i m m e d i a t e l y . I t b r e a t h i n g h a s s t o p p e d , g i v e a r l i t i -

_ _ - - - - „ „ PAGE 2520020______3_7_______________________________ DATE 11/07/96

SECTION IV - FIRST AID AND EM1RQENCY PROCEDURES; (CONTINUED)

INHALATIONr i a i r e s p i r a t i o n . - S e e p w a r m a n d q u i e t . G e t m e d i c a l a t t e n t i o n i m m e d i a t e l y .c i u s h w i t h l a r g e a m o u n t s c f w a t e r , l i f t i n g u p p e r a n a l o w e r l i d s o c c a s i o n a l -, y . C o n t i n u e f o r a t l e a s t 1 5 m i n u t e s . G e t ^ e d i c a i a t t e n t i o n .R e m o v e c o n t a m i n a t e d c l o t h i n g . W a s h a f f e c t e d a r e a w i t h s o a p a n a w a t e r .O b t a i n m e d i c a l a t t e n t i o n i f i r r i t a t i o n p e r s i s t s .

NOTES TO PHYSICIANA n y t r e a t m e n t t h a t r i g h t C e r e q u i r e d f o r o v p r e x p o s u r e s h o u l d b ed i r e c t e d a t t h e c o n t r o l o r s y m p t o m s a n d t h e r l i n ' c a l c o n d i t i o n s .

SECTION V - PHYSICAL DATABOILING RANGE '65 C E G . F . ( 71. D E G . C . ) TO .. ' 4 D E G . F . C 212 D E G . C . )

FREEZING POINT: -50 D E C . - . ( - 4 5 D E C . C . }

VAPOR PRESSURE: 1 mm Kg 3 68 D E C . F . ( 2 0 D E C . C.)

VAPOR DENSITY H e a v i e r t h a n a i r . % VOLATILE BY VOLUME -9

EVAPORATION RATE VOC 3 . 1 8 Ib/gal lees water & NPRS* 3 8 2 g/1 less watarC A LS l o w e r t h a n d t e t h y l e t h e r .

WEIGHT LB . /GAL. ' 0 . 2 VOC 6 . 2 4 Ib/g&l solids 749 g /1 solids C A L C U L A T E DS P E C I F I C G R A V I T Y 1 . 2

APPEARANCE & ODOR : - i q u i c , S o l v e n t o d o r SOLUBILITY: S l i g h t i n w a t e r

VISCOSITY: N o i n f o r m a t i o n f o u n d P H : 4 - 7 ( S T D U N I T S )

All Physical data determined at 68 DEC. F. (20 DEC. C.) 760 mm Hg• Negligibly Photochemically Reactive MaterialsVOC values reported here are verif ied by ASTM method D - 3 9 6 0 ___________

SECTION VI - FIRE AND EXPLOSION DATANFPA FLAMMABILITY CLASSIFICATION F L A M M A B L E L I Q U I D - C L A S S 1 C

FLASHPOINT 9 3 0 E G . F , < 3 4 D E G . C , ) C A L C U L A T E D

AUTOIGNITION 572 D E G . ? . ( 3 0 0 D E G . C . ) DECOMPOSITION TEMP ' 8 3 2 3 E G . F . ( 1 0 0 0 D E G . C . )

rôRGSION RATE N o t a p p l i c a b l e MAGNETISM N o t a p p l i c a b l e

EXPLOSIVE W G T . N o t a p p l i c a b l e

EXTINGUISHING MEDIAu s e N F P A C l a s s 8 F i r e e x t i n g u i s h e r s ( c a r o o n d i o x i d e a l l p u r p o s e d r y c h e m i -c a l o r a l c o h o l f o a m ) d e s i g n e d t o e x t i n g u i s h ' i a m m a b I e l i q u i d f i r e s . P o l y -m e r f o a m i s p r e f e r r e d f o r l a r g e f i r e s .

UNUSUAL FIRE AND EXPLOSION HAZARDSD u r i n g e m e r g e n c y c o n d i t i o n s , o v e r e x p o s u r e t o d e c o m p o s t ' o n p r o d u c t s m a yc a u s e a h e a l t h h a z a r d . S y m p t o m s m a y n o t b e i m m e d i a t e l y a p p a r e n t . O b t a i nm e d i c a l a t t e n t i o n .W A R N I N G ! F L A M M A B L E .

SPECIAL FIRE FIGHTING PROCEDURESJ a t e r - i a y D e • n e f f e c t i v e , b u t m a y b e u s e d t o r 3 o i e x p o s e d c o n t a i n e r s t op r e v e n t p r e s s u r e b u i . d - u p a n d p o s s i b l e a u t o - i g n i t i o n o r e x p l o s i o n w h e ne x p o s e d t o e x t r e m e f e a t . i f w a t e r i s u s e a . « o q n o z z l e s a r c p r e f e r a b l e . _ _ _ _ _ _ _

|________________SECTION VII - REACTIVITY DATA________________________NEUTRALIZING AGENT N o i n f o r m a t i o n f o u n d


CONDITIONS TO AVOIDA v o i d e x c e s s i v e h e a t ( > 1 1 5 f ( 4 6 C ) a n d s o u r c e s o f i g n i t i o n .


HAZARDOUS DECOMPOSITION PRODUCTSB u r n i n g , i n c l u d i n g w h e n h e a t e d b y w e l d i n g o r c u t t i n g , w i l l p r o d u c e s m o k e ,c a r b o n m o n o x i d e a n d c a r b o n d i o x i d e .




K e e p s p e c t a t o r s a w a y . E l i m i n a t e a l t i g n i t i o n s o u r c e s ( f l a m e s , h o ts u r f a c e s , a n d s o u r c e s c f e l e c t r i c a l , s t a t i c o r f r i c t i o n a l s p a r k s ) .D i k e a n d c o n t a i n s p i l l w i t h i n e r t m a t e r i a l ( e . g . s a n d , e a r t h ) . T r a n s f e rl i q u i d s t c c o v e r e d m e t a l c o n t a i n e r s f o r r e c o v e r y o r d i s p o s a l , o r r e m o v ew i t h i n e r t a b s o r b e n t . ^ s e o n l y n o n - S p a r k i n g t o o i s . P l a c e a b s o r b e n t d i k i n g

520020 37

511 fill . llliil Illitl! (0011STEPS TO BE TAKEN IF MATERIAL IS RELEASED OR SPILLED

"i a t c r i a i s in c o v e r e d ir e t a t c o n t a i n e r s 'or o • s p c s a I . r - e v e n tc t s e w e r s , s t r e a m s , a n a g r o u n d u a t e r w i t h s p - l i e a m a t e r i a l ca p s o r o e n t .

"E DISPOSALD i s p o s e • n a c c o r d a n c e w i t h f e d e r a l , s t a t e a n d l o c a l r e g u l a r

^nA CLASSIFICATIONT h i s p r o d u c t , i f d i s c a r d e d d i r e c t l y , w o u l d b e c . a s s • f ' e a ac a s e d o n i t s i g n i t a b i . i t y c h a r a c t e r i s t i c , - . e . i a s a f l a s hd e q . f . ( 6 0 d e g . C ) o r l e s s . T h e p r o p e r R C R A c . a s s i r i c a t i o n w

ENVIRONMENTAL HAZARDSN o n e t n o u n


P - o p e r s e l e c t i o n o f r e s p i r a t o r y p r o t e c t i o n c e p e n d s u p o n n a n• n c l u d i n g d u r a t i o n / l e v e l o f e x p o s u r e a n d c o n d i t i o n s o f u s e .e x p o s u r e t o o r g a n i c c h e m i c a l s s u c h a s t h o s e c o n t a i n e d i n t hnot r e q u i r e the use o* r e s p i r a t o r y p r o t e c t i o n i < u s e d in wea r e a s . ; ~ i r e s t r i c t e d v e n t ' l a t i o n a r e a s a N I 0 S H a p p r o v e d c h er e s p i r a t o r m a y P e r e q u i r e d . U n d e r c e r t a i n c o n d i t i o n s , s u c hm e c h a n i c a l p r e f i l t e r T I a y a l s o b e r e q u i r e d . I n c o n f i n e d a r e aM S H A a p p r o v e d a i r s u p p l i e d r e s p i r a t o r . I f t h e T ^ V ' s . i s t e da r e e x c e e d e d u s e a p r o p e r l y f i t t e d N I O S H / M S H A a p p r o v e d • - p s pa p p r o p r i a t e p r o t e c t i o n f a c t o r . R e f e r t o O S H A 2 9 C F R ' 9 1 0 . 1 3P r o t e c t i o n " , a n d " R e s p i r a t o r y P r o t e c t i o n A M a n u a l A n d G u i d eI n d u s t - i a I H y g i e n e A s s o c . "

VENTILATIONP r o v i d e g e n e r a l d i l u t i o n a n d l o c a l e x h a u s t . e n t • I a t i c n i na n d p a t t e r n t o k e e p c o n c e n t r a t i o n s o f h a z a r d o u s ' i g r e d i e n t sS e c t i o n I I b e l o w t i e . o w e s t e x p o s u r e l i m i t ; t a t e d . R e m o v e ap r o d u c t s t n a t are g e n e r a t e d w h e n w e l d i n g , : „ t t • H g , • - bra 21: o a t e d « i t h t h i s c r o d u c t . R e f e r t o " I n d u s t ' - a l , ' e n t i . a t i o nR p c c n m e n a e d P r a c t i c e " a C G 1 H

HAND PROTECTIONS o l v e " t • - i p e r m e a p . e g l o v e s a r e r e q u i r e d ' c - - e p e a t e d o r p r o

EYE PROTECTION« e a r s a f e t y s o e c t a c l e s .

OTHER PROTECTIVE EQUIPMENTsot . •. K e i y to be r e e d e a .

SECTION X - SPECIAL PRECAUTIONSPRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE

3 o r o t s t o r e a b o v e ° " 5 d e g . F ( 4 6 d e g . C ) s t o r e l a r g e a u a n t ic o m p l i a n c e w i t h O S H A 2 9 C F R 1 9 1 0 . 1 0 6 .

5R PRECAUTIONSD o n o t t a i c e i n t e r n a l l y . C l o s e c o n t a i n e r a f t e r ^ a c n u s e .E m p t y c o n t a i n e r s m u s t n o t b e w a s h e d a n d r e - u s e d f o r a n y p u rC o n t a i n e r s s h o u l d b e g r o u n d e d a n d b o n d e d t o t h e r e c e i v i n g cD o n o t w e l d , b r a z e c r c u t o n e m p t y c o n t a i n e r .S e v e r u s e p r e s s u r e t o e m p t y . D r u m i s n o t a p r e s s u r e v e s s e l


| SECTION XII - TRANSPORTATION DATA• R C P f ? i - 1 P P 1 N G N A M E ( A R T I C L E ) P A I N T S O T M A R K I N G

D O T C L A S S I F I C A T I O N F L A M M A B L | L I Q U I D E M E R G E N C Y A C C I

3 0 T L A B E L F L A M M A B l f ^ P R O C E D U R E S

D O T I . A C A R O F L A M M A B L EP R E C A U T I O N S • 0 B E T A K E N I S T R A N S P O R T A T I O N

L I M I T E D Q U A N T I T Y : N O A E R O S O L P R O P E L L E N T : N o t0.0. T . I . 0 . N U M B E R U N 1 2 6 3 R . Q . N O . U . S . P O S T A L

U N 1 T " C O N T A I N E R D . O . T . J N

I P I N T M j T A L 2 N 1 N 11 Q U A R T « E T A L 2 N 1 N 1T G A L L O N M E T A ^ 2 N 1 N 1S G A , I O N - E T A , . 1 7 C 1 A 1

1 7 K 1 A 25 5 G A L L O N M f c T A L ' 7 C 1 A 1

1 7 K 1 A 2F I B E R B O A R D B O X 1 2 B 4 G

( N O P i A S T I C C O N T A I N E R S W I L L B E A U N I T C O N T A I N E R O N L Y U S E D F O RA K I T U N I T C O N T A I N E R ) .

PAGE 3DATE 11/07/96

11

r o n t a m i n a t i o nr u s e d

i o n s .

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i s p r o d u c t m a y1 1 v e n t i l a t e dm i c a l c a r t r i d g ea s s p r a y i n g , as jse a N I O S H /i n S e c t i o n 1 1i r a t o r w i t h a n4 " R e s p i r a t o r yl i n e , A m e r i c a n

e f f i c i e n t v o l u m el i s t e d i n

e c o r n p o s i t i onn g o b j e c t s

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l o n g e d c o n t a c t .

t i e s i n

p o s e ,o n t a i n e r .

I S S I D E U P

D E N T P R E C A U T I O N S

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a p p i i c a b I eF O R B I D D E N

C O M P O N E N T O F

GOVERNMENT SPEC. PRODUCTS /QSA520020 37

PAGE 4DATE 11/07/96

SECTION XII - TRANSPORTATION DATA; (CONTINUED)

H I S I S " 3 C E R T 1 F v T H A T T H I S I T E M I S H A Z A R D O U S A N D I N F O R M A T I O N S T A T E D I S , T O• = B E S T O F O U R K N O W L E D G E , C O R R E C T .


'HE 1 N F 0 R M A TA C C U R A T E . hi H- X P R E S S E D O R3 E O B T A I N E D ' R O M: o N D : • : z N s

O N C O N T A I N E D " E R E I N I S B A S E D O N D A T AL E " « E I N F O R M A T I O N I S B E L I E V E D ' 0 B E: M P L ; E D R E G A R D I N G T H E A C C U R A C Y : F - M

T i E USE ' H E R E O F . S I N C E 'HE o S E 0N O U S E

- S E R S O B L I G A T I O NT h e C o r p o r a t e

H I S P R O D U C T A R E C O N T R O L

e s p o n s i b i e f o r

3 D E T E R M I N E T H E C O N D IS a f e t y a n d E n v i r o n m e n t

O N S O F

C O N S I D E R E D T O B ER ES

i A 8 L E ,A T A OR

E D BS A F E

H I SY T H

N O U A R R A N T YT H E R E S U L T S

U S E

N F 0 R M A T I 0 NU S E R , i T

I ST 0

A N D T H EI S T H E

H E P R O D U C T

i e p r e p a r a t i o n o f t h i s M a t e rA f f a i r s D e p a r

S a f e t yt m e n t isD a t a S h e e t


H.H.I.SiHEALTH 1FLAMMABILITY 3REACTIVITY 0

These ratings should be used onlypart of ful ly iiroiementea H . M . I . S . program.



SECTION)I


TRADE NAME .... H I G H S O L I D S • • • • O X 3 M B L U E A / D O R E N

MANUFACTURER CODE I . D . 5 2 2 0 2 0 6 2

REVISED ON • 1 / 0 7 / 9 6

8 0 1 0M A N U F A C T U R E R C A G E 6 1 1 9 6 C O N T R A C T

INGREDIENT

SECTION II - HAZARDOUS

% BYWGT

CAS NO./NIOSH*

5 INGREDIENTSALLOWABLE

EXPOSURE LEVELSARA

313VP

nm HQ20 DEG.

9C

N A P T H A ( P E T R O L E U M )H E A V Y A ^ H Y L A T E

X Y L E N E

• i T A N i U M c:cx ; DE

PETROLEUM H " D R 0 -C A R B O N M I X T U R E

P I N E : : L

SOLVENT64741-65-7 MFR

PPM MG/CU.M.100 525

MPPCF SKIN

5 - 3 3 0 - 2 0 - 7 T L V - T W AS O L V E N T :E2100000 * i. V • S T E L

O S H A - P E LOSHA-STEL

L FL 1.0

•3463-67-'P I G M E N T XR2275000

T L V - T U AO S H A - P E L

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- L O W E R C L A M M A B I L I T Y L I M I T P E R C E N T= U P P E R ' . A M M A B I L I T Y L I M I T P E R C E N TI N = S K I S A B S O R P T I O N M U S T B E C O N S I D E R E D AC E I L ! N G = A L L O W . E X P O S U R E L E V E L S H O U L D NOTR = M A N U F A C T U R E R R E C O M M E N D E D E X P O S U R E L I ME ' . - S H O R T T E R M E X P O S U R E L I M I TS A R A 3 1 3 = C H E M I C A L I S S U B J E C T T O R E P O R T I

- • T L E 1 : I OF S . A . R . A . 40 CFR P A R T 3720 S H 8 = M I O S H R E G I S T R Y O F T O X I C E F F E C T S O F

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T i a t e r i . i l • i t o l u n g m a y c a u s e c h e m i c a l p n e u m o n i t i s w h i c i c . i n DINHALATION

May c a u s e n o s e or t h r o a t < r r i t a t i o n . H i g h c o n c e n t r a t i o n s mayc e n t r a l n e r v o u s s y s t e m d e p r e s s i o n c h a r a c t e r i z e d b y h e a d a c h e s ,n a u s e a a n d c o n f u s i o n .


SKINM a y c a u s e d e f a t t i n g a n d i r r i t a t i o n o f t h e s x i n .

EFFECTS OF REPEATED OVERHXPOSTJREO v e r e x p o s u r e t o x y t e n e m a y c a u s e i n j u r y t o t h e l i v e r , k i d n e y sD I o o d .R e p o r t s n a v e a s s o c i a t e d p r o l o n g e d a n d r e p e a t e d o c c u p a t i o n a l ot o s o l v e n t s w i t h p e r m a n e n t b r a i n a n d n e r v o u s s y s t e m d a m a g e . Im i s u s e b y d e l i b e r a t e l y c o n c e n t r a t i n g a n d i n h a l i n g t h e c o n t e n th a r m f u l o r f a t a l

SIGNIFICANT LABORATORY DATA WITH POSSIBLE RELEVANCE TO HUMAN HEALTH.T i t a n i u m d i o x i d e I S N O T l i s t e d a s a p o t e n t i a l c a r c i n o g e n b y tT o x i c o l o g y P r o g r a m , t h e I n t e r n a t i o n a l A g e n c y f o r R e s e a r c h o no r A . C . G . I . H . T i t a n i u m d i o x i d e i n a 2 4 - m o n t h i n h a l a t i o n s t u d yr e v e a l e d a s i g n i f i c a n t i n c r e a s e i n b e n i g n a n d m a l i g n a n t l u n gg r o u p e x p o s e d t o 2 5 0 m g / M 3 r e s p i r a b l e T i 0 2 d u s t . A t l o w e r e x p ot h i s s i g n i f i c a n t e f f e c t w a s n o t o b s e r v e d . T h e n o r m a l c l e a r a n co f t h e > u n g s m a y h a v e b e e n o v e r w h e l m e d a t t h e 2 5 0 m g / M 3 e x p o s ut h i s m a y h a v e c o n t r i b u t e d t o t h e t u m o r f o r m a t i o n . T h e s e r e s u lb e d i r e c t l y r e l e v a n t t o t h e w o r k p l a c e w h e r e o c c u p a t i o n a l e x p oa r e o P s e r v e d . A t t h e T L V t h e T i 0 2 m a n u f a c t u r e r c o n c l u d e s t h a ts i g n i f i c a n t h a z a r d f o r m a n .

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_____522020______6_2______________________________________________________DATE 11/07/96

I_________SECTION IV - FIRST AID AND EMERGENCY PROCEDURES; (CONTINUED)__________'

SWALLOWINGe m e r g e n c y r o o m o r p h y s i c i a n i m m e d i a t e l y .

INHALATIONS e m o v e t o f r e s h a i r i m m e d i a t e l y . I f b r e a t h i n g h a s s t o p p e d , g i v e a r t i f i -c i a l r e s p i r a t i o n . K e e p w a r m a n d q u i e t . G e t m e d i c a l a t t e n t i o n i m m e d i a t e l y .c I u s h w i t h l a r g e a m o u n t s of w a t e r , l i f t i n g u p p e r n n a l o w e r l i d s o c c a s i o n a l -. y . C o n t i n u e f o r a t l e a s t 1 5 m i n u t e s . G e t m e d i c a i a t t e n t i o n .

SKINR e m o v e c o n t a m i n a t e d r . o t h i n g . W a s h a f f e c t e d . i r e a w i t h s o a p a n d w a t e r .O b t a i n m e d i c a l a t t e n t i o n • f i r r i t a t i o n p e r s i s t s

NOTES TO PHYSICIANA n y t r e a t m e n t t n a t - n i g h t b e r e q u i r e d f o r o v e r c x p o s u r e s h o u l d b e

_ _ _ _ _ d i r e c t e d at the c o n t r c i of s y m p t o m s and th e c . i n i c at c o n g i t • o n s . ___

j______________________SECTION V - PHYSICAL DATA_________________________________BOILING RANGE 165 D E G . F . ( 74 D E G . C . ) TO 414 D E G . F . ( 212 O E G . C . )

FREEZING POINT: 50 D E C . = . ( - 4 5 D E C . C.)

VAPOR PRESSURE: 5 mm Hg 3 68 D E C . F . ( 2 0 O E G . :.)

VAPOR DENSITY H e a v i e r t h a n a i r . % VOLATILE BY VOLUME 51

EVAPORATION RATE VOC 3 . 3 5 Ib/gal less water & NPRS* - 0 2 g/1 lesa waterC A LS l o w e r t h a n d i e t h y l e t h e r .

WEIGHT LB. /GAL. 7.8 VOC 6 . 9 6 lb/gal solids 835 g/1 solids C A L C U L A T E DS P E C I F I C G R A V I T Y C . 9

APPEARANCE & ODOR: L i q u i d , S o l v e n t o d o r SOLUBILITY: S l i g h t i n w a t e r

VISCOSITY: N o i n f o r m a t i o n f o u n d P H : - . - 7 ( 5 * 0 U N I T S )

All Physical data determined at 68 DEG. F. (20 DEG. C.) 760 mm Hg• Negligibly Photochemically Reactive MaterialsVOC values reported here are verified by ASTM method D-3960_______________________________

| _____________SECTION VI - FIRE AND EXPLOSION DATA__________________________NFPA FLAMMABILITY CLASSIFICATION F L A M M A B L E L I Q U I D C L A S S ; C

FLAMMABLE LIMITS 1.0 t. - 7 . 0 •,;

SHPOINT 8 0 D E G . F , ( 2 7 D E G . C , ) C A L C U L A T E D

. . .OIGNITION 5 7 2 D E G . F . ( 3 0 0 C E G . C . ) DECOMPOSITION TEMP ' 3 3 2 D E G . F . ( 1 0 0 0 D E G . C . )



EXTINGUISHING MEDIAU s e N F P A C l a s s B F i r e e x t i n g u i s h e r * ( c a r b o n d i o x i d e a l l p u r p o s e d r y c h e m i -c a l 3 r a l c o h o l f o a m ) d e s i g n e d t o e x t i n g u i s h ' l a m m a b l e l i q u i d f i r e s . P o l y -T i e r • o a m i s p r e f e r r e d f o r l a r g e f i r e s .

UNUSUAL FIRE AND EXPLOSION HAZARDSD u r i n g e m e r g e n c y c o n d i t i o n s , o v e r e x p o s u r c t o d e c o m p o s t i o n p r o d u c t s m a yc a u s e a h e a l t h h a z a r d . S y m p t o m s m a y n o t b e i m m e d i a t e l y a p p a r e n t . O b t a i nm e d i c a l a t t e n t i o n .W A R N I N G ' F L A M M A B L E .

SPECIAL FIRE FIGHTING PROCEDURESu a t e r m a y b e i n e f f e c t i v e , b u t m a y b e u s e d t o c o o l e x p o s e d c o n t a i n e r s t op r e v e n t p r e s s u r e b u i l d - u p a n d p o s s i b l e a u t o - i g n i t i o n o r e x p l o s i o n w h e ne x p o s e d t o e x t r e m e h e a t . I f u a t e r i s u s e d , ' o g n o z z l e s a r e p r e f e r a b l e .

SECTION VII - REACTIVITY DATA.CTIVITYNEUTRALIZING AGENT N o i n f o r m a t i o n f o u n d


CONDITIONS TO AVOIDA v o i d e x c e s s i v e h e a t ( > 1 1 5 F ( 4 6 C ) a n d s o u r c e s o f i g n i t i o n .


HAZARDOUS DECOMPOSITION PRODUCTSB u r n i n g , i n c l u d i n g w h e n h e a t e d b y w e l d i n g o r c u t t i n g , w i l l p r o d u c e s m o k ec a r b o n m o n o x i d e a n d c a r b o n d i o x i d e .

HAZARDOUS POLYMERIZATIONW i l l n o t o c c u r

CONDITIONS TO AVOIDN o n e k n o w n_________________________________ __

[ _______________SECTION VIII - ENVIRONMENTAL INFORMATION_____________________->S TO BE TAKEN IF MATERIAL IS RELEASED OR SPILLED

K e e p s p e c t a t o r s a w a y . E l i m i n a t e a l l i g n i t i o n s o u r c e s ( f l a m e s , h o t

522020 62

i SECTION VIII - ENVIRONMENTAL INFORMATION;

PAGEDATE

(CONTINUED)

11/07 /96

STEPS TO BE TAKEN IF MATERIAL ISi u r t a c e s , a n d s o u r c e s oD i k e a n d c o n t a i n s p

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RCRA CLASSIFICATIONT h i s p r o d u c t ,D a s e d on its i3 e q . f . ( 6 0 d e g

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P r o p e r s e l e c t i o ni n c l u d i n g d u r a t ie x p o s u r e t o o r g an o t r e q u i r e t h ea r e a s . I n r e s t r ir e s p i r a t o r r n a y bm e c h a n i c a l p r e f iM S H A a p p r o v e d aia r e e x c e e d e d u s ea p p r o p r i a t e p r o tP r o t e c t i o n " i a n dI n d u s t r i a l x y g i e

VENTILATIONP - o v i d e g e n e r a la n d c a t t e r n t o KS e c t ' o n i ; b e l o wp r o d u c t s t h a t a rc o a t e d w i t h t h i sR e c o m m e n d e d P r a c

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s t a t e d . R e m o v e d e c o m p o s i t i o nc u t t i n g , o r b r a z i n g o b i e c t sr ' a i v ' e n t ' l a t i o n A M a n u a l o f

HAND PROTECTION• • e a r a p p r o

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y s p e c t a c l e s .EQUIPMENT

t o b e n e e d e d .

SECTION X - SPECIAL PRECAUTIONS.̂ .CAUTIONS TO BE TAKEN IN HANDLING AND STORAGE

D

OTHERDECDS

o n o t s t o r e a b o v e 1 1 5 d e g . F ( 4 6 d e 9 . C ) s to m p l i a n c e w i t h O S H A 2 9 C F R 1 9 1 0 . 1 0 6 .PRECAUTIONSo n o t t a K e i n t e r n a l l y . C l o s e c o n t a i n e r a f tm p t y c o n t a i n e r s m u s t n o t b e w a s h e d a n d r e -o n t a i n e r s s h o u l d b e g r o u n d e d a n d b o n d e d t oo n o t w e l d , b r a z e o r c u t o n e m p t y t o n t a i n ee v e r u s e p r e s s u r e t o e m p t y . D r u m i s n o t a

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1 0 N

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C O N T A I N E R C N L Y U S E D F O R ' C O M P O N E N T O F

PAGE 4522020 62 ___ DATE 11/07/96


, S ; S T G C E R T I F Y T H A T ' H I S I T E M I S H A Z A R D O U S A N D I N F O R M A T I O N S T A T E D I S , T OH E b E S ; : F C U R K N O W L E D G E , C O R R E C T .


T * E I N F O R M A T I O N C O N T A I N E D H E R E I N I S B A S E D O S D A T A C O N S I D E R E D T O B EA C C U R A T E . W H I L E T H E I N F O R M A T I O N I S B E L I E V E D T O B E R E L I A B L E , N O W A R R A N T Y I SE X P R E S S E D O R I M P L I E D R E G A R D I N G T H E A C C U R A C Y C F T H I S D A T A O R T H E R E S U L T S T OB E O B T A I N E D F R O M T H E U S E T H E R E O F . S I N C E T H E U S E O F T H I S I N F O R M A T I O N A N D T H EC O N D I T I O N S A N D U S E O F T H I S P R O D U C T A R E C O N T R O L L E D B Y T H E U S E R , I T I S T H E„ S E R ' S O B L I G A T I O N T O D E T E R M I N E T H E C O N D I T I O N S O F S A F E U S E O F T H E P R O D U C T .

T h e C o r p o r a t e S a f e t y a n d E n v i r o n m e n t a l A f f a i r s D e p a r t m e n t i sr e s p o n s i D l e ' o r T i e p r e p a r a t i o n o f t h i s M a t e r i a l S a f e t y D a t a S h e e t .

PRATT & LAMBERT 316-733-1361Industrial Coatings Div.101 ProBpect AvenueCleveland, OH 44115

DOT EMERGENCY CHEMTEL (800)255-3924 (24hr«)INFORMATION PHONE NO. 216-566-2902 (M-F 8 AM-5 PM CT)


These ratings should be used only,is oart cf ful ly implemented H .M. I .S . program.



SECTION i;PRODUCT CLASS A L K Y D , M E D I U M - L O N G

TRADE NAME . .* . H I G H S O L I D S * * * * P H l i l I P S G R A Y A / D E N L

MANUFACTURER CODE I.D. 5 2 1 0 2 2 12

REVISED ON 1 / 0 7 / 9 6

8 0 1 0 -M A N U F A C T U R E R C A G E * 6 1 1 9 6 C O N T R A C T

SECTION ii - HAZARDOUS! INGREDIENTSINGREDIENT % BY

WGTCAS NO./NIOSH#


SARA313

VPmm Hg 9

20 DEG.CPPM MG/CU.M.

NAPTHA (PETROLEUM)HEAVY A L K Y L A T ECARBON BLACKT I T A N I U M D I O X I D E

PETROLEUM H Y D R O -CARBON M I X T U R E

p i N E c: L

SOLVENT

PI GHENT

6 4 7 4 1 - 6 5 - 7 M F R 100


13463-67-7 T L V - T U APIGMENT XR2275000 OSHA-PEL

8032-32-4 T L V - T U A016180000 C S M A - P E L

100100

525

3 .503 . 5 0

525525

S O L V E N T8000-< .1 - 7 NONE E S T A B L I S H E D

MPPCF SKIN

S K I N S K I N A B S O R P T I O N M U S TC E I L I N G = A L L O W . E X P O S U R E L E V E L S H O U L D9 = M A N U F A C T U R E R R E C O M M E N D E D E X P O S U R E; L = S H O R T ' E R M E X P O S U R E L I M I TS A R A 3 ' 3 = C H E M I C A L I S S U B J E C T T O R E P O R T I

o f T I T L E : i i O F S . A . R . A . 4 0 C F R P A R T 3 7 2N I O S H * = N I O S H R E G I S T R Y O F T O X I C E F F E C T S O F

E C O N S I D E R E D A S A R O U T E O F E X P O S U R EN O T B EL I M I T

E X C E E D E D F O R A N Y T I M E P E R I O D

N G R E Q U I R E M E N T S O F S E C T I O N 3 1 3

C H E M I C A L S U B S T A N C E S N U M B E R .


SWALLOWINGC a n c a u s e g a s t r o i n t e s t i n a l i r r i t a t i o n , n a u s e a , j n d v o m i t i n g . A• T i a t e r i . i i n t o l u n g may c a u s e c n e m l c a 1 p n e u m o n i t i s w h i c h cjn DC

INHALATIONMay < _ d u b e ~ o s e or t h r e a t ' r r i t a t I o n . H i g h c o n c e n t r a t i o n s nay cc e n t r a l - e r v o u s s y s t e m d e p r e s s i o n c h a r a c t e r i z e d b y h c a a a c n e s ," a u s e a ana c o n t u s t c n .

EYE

SKINMay c a u s e d e f a t t i no and • r r i t a t i o n of the s k i n .

EFFECTS OF REPEATED OVEREXPOSURER e p o r t s n a v e a s s o c i a t e d p r o l o n g e d a n d r e p e a t e d o c c u p a t i o n a l o vm i s u s e D y d e l i b e r a t e l y c o n c e n t r a t i n g a n d i n h a l i n g t h e c o n t e n t sh a r m f u l o r f a t a l

SIGNIFICANT LABORATORY DATA WITH POSSIBLE RBLKVAKCB TO HUMAN HEALTH.T i t a n i u m d i o x i d e I S N O T l i s t e d a s a p o t e n t i a l c a r c i n o g e n b y t hT o x i c o l o g y P r o g r a m , t h e i n t e r n a t i o n a l A g e n c y f o r R e s e a r c h o n Co r A . C . G . I . H . T i t a n i u m d i o x i d e i n a 2 4 - m o n t h i n h a l a t i o n s t u d yr e v e a l e d a s i g n i f i c a n t i n c r e a s e i n b e n i g n a n d m a l i g n a n t l u n g tg r o u p e x p o s e d t o 2 5 0 m g / M 3 r e s p i r a b l e T i 0 2 d u s t . A t l o w e r e x p o st h i s s i g n i f i c a n t e f f e c t w a s n o t o b s e r v e d . T h e n o r m a l c l e a r a n c eof the l u n g s may h a v e b e e n o v e r w h e l m e d at the 2 5 0 m g / M 3 e x D o s u rt h i s m a y n a v e c o n t r i b u t e d t o t h e t u m o r f o r m a t i o n . T h e s e r e s u l tb e d i r e c t l y r e l e v a n t t o t h e w o r k p l a c e w h e r e o c c u p a t i o n a l e x p o sa r e o b s e r v e d . A t t h e T L V t h e T i 0 2 m a n u f a c t u r e r c o n c l u d e s t n a ts i g n i f i c a n t h a z a r d f o r m a n .

SECTION IV - FIRST AID AND EMERGENCY PROCEDURES

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SWALLOWING.OWINGI f s w a l l o w e d d o n o t i n d u c e v o m i t i n g . C a l l p o i s o n c o n t r o le m e r g e n c y r o o m o r p h y s i c i a n i m m e d i a t e l y .ATIONALATIONR e m o v e t o f r e s h a i r i m m e d i a t e l y I f b r e a t h i n g h a s

c e n t e r , h o s p i t a l

s t o p p e d , g i v e a r t i f i -

P AG E 2521022 32 DATE 11/07/96

SECTION IV - FIRST AID AND EMERGENCY PROCEDURES; (CONTINUED)

INHALATIONc i a l r e s p i r a t i o n . K e e p w a r m and q u i e t . Get 11 e d i c a I a t t e n t i o n i m m e d i a t e l y .

EYEf l U S t l W i t h l a r g e a m o u n t s o f w a t e r , l i f t i n g u p p e r a_nd l o w e r . i d s o c c a s i o n a l -y . Co

1 t h l a r g e a m o u n t s o f w a t e r , l i f t i n g u p p e r a _ n d l o w e r . i dn t i n u c f o r a t l e a s t 1 5 m i n u t e s . G e t m e d i c a l a t t e n t i o n .

R e m o v e c o n t a m i n a t e d c l o t h i n g . W a s h a f f e c t e d a r e a w i t h s o a p a n d w a t e r .O b t a i n m e d i c a l a t t e n t i o n i f i r r i t a t i o n p e r s i s t s .

NOTES TO PHYSICIANA n y t r e a t m e n t t h a t m i g h t b e r e q u i r e d f o r o v e r e x p o s u r e s h o u l d b ed i r e c t e d a t t h e c o n t r c l c t s y m p t 0 m s a n d t h e c l i n i c a l c o n d i t i o n s .

SECTION V - PHYSICAL DATABOILING RANGE 1 6 5 O E G . F . ( 7 4 O E G . C . ) T O 4 1 4 D E G . F . ( 2 1 2 D E G . C . )

FREEZING POINT: - 5 0 D E G . F . t - 4 5 D E C . C . )

VAPOR PRESSURE: 1 m m H g a 6 8 D E G . F . ( 2 0 D E C . C . )

VAPOR DENSITY H e a v i e r t h a n a i r . % VOLATILE BY VOLUME 51

EVAPORATION RATE VOC 3 . 3 1 Xh/g*l less water & NPRS* 397 g/1 less watarc A LS l o w e r than d i e t h y l e t h e r .

WEIGHT LB. /GAL. 8.2 VOC 6 . 8 0 Ifa/gal solids 816 g/1 solids C A L C U L A T E DS P E C I F I C G R A V I T Y 1 . 0

APPEARANCE & ODOR: L i q u i d , S o l v e n t o d o r SOLUBILITY: S l i g h t i n w a t e r

VISCOSITY: N o i n f o r m a t i o n f o u n d P H : 4 - 7 ( S T O U N I T S )

All Physical data determined at 68 DEG. F. (20 DEG. C.) 760 mm Hg• Negligibly Photochemically Reactive MaterialsVOC values reported here are verified by ASTM aathod D-3960_________________________________

SECTION VI - FIRE AND EXPLOSION DATANFPA FLAMMABILITY CLASSIFICATION F L A M N » B L E L I Q U I D - C L A S S 1C

FLASHPOINT 9 3 D E G . F , ( 3 4 D E G . C , ) C A L C U L A T E D

AUTOIGNITION 5 7 2 D E G . F . ( J 0 0 D E G . C . ) DECOMPOSITION TEMP 1 8 3 2 D E G . F . ( 1 0 0 0 D E G . C . )

" ^ROSION RATE N o t a p p l i c a b l e MAGNETISM N o t a p p l i c a b l e

EXPLOSIVE WGT . N o t a p p l i c a b l e

EXTINGUISHING MEDIAU s e N F P A C l a s s B F i r e e x t i n g u i s h e r s ( c a r b o n d i o x i d e . a l l p u r p o s e d r y c h e m i -c a l o r a l c o h o l f o a m ) d e s i g n e d t o e x t i n g u i s h f l a m m a b l e l i q u i d f i r e s . P o l y -m e r f o a m i s p r e f e r r e d f o r l a r g e f i r e s .

UNUSUAL FIRE AND EXPLOSION HAZARDSD u r i n g e m e r g e n c y c o n d i t i o n s , o v e r e x p o s u r e t o d e c o m p o s t i o n p r o d u c t s m a yc a u s e a h e a l t h h a z a r d . S y m p t o m s m a y n o t b e i m m e d i a t e l y a p p a r e n t . O b t a i nm e d i c a l a t t e n t i o n .W A R N I N G * F L A M M A B L E .

SPECIAL FIRE FIGHTING PROCEDURESw a t e r m a y b e i n e f f e c t i v e , b u t m a y b e u s e d t o c s o l e x p o s e d c o n t a i n e r s t op r e v e n t p r e s s u r e b u i l d - u o a n d p o s s i b l e a u t o - i g n i t i o n o r e x p l o s i o n w h e ne x p o s e d t o e x t r e m e h e a t . I f w a t e r i s u s e d , ' o q n o z z l e s a r c p r e f e r a b l e .

SECTION VII - REACTiviTY DATANEUTRALIZING AGENT No i n f o r m a t i o n f o u n d


CONDITIONS TO AVOIDA v o i d e x c e s s i v e h e a t ( > 1 1 5 F ( 4 6 C ) a n d s o u r c e s o f i g n i t i o n .


HAZARDOUS DECOMPOSITION PRODUCTSB u r n i n g , i n c l u d i n g w h e n h e a t e d b y w e l d i n g o r c u t t i n g , w i l l p r o d u c e s m o k ec a r b o n m o n o x i d e a n d c a r b o n d i o x i d e .




K e e p s p e c t a t o r s a w a y . E l i m i n a t e a l l i g n i t i o n s o u r c e s ( f l a m e s , h o ts u r f a c e s , a n d s o u r c e s o f e l e c t r i c a l , s t a t i c o r f r i c t i o n a l s p a r k s ) .D i k e a n d c o n t a i n s p i l l w i t h i n e r t m a t e r i a l ( e . g . s a n d , e a r t h ) . T r a n s f e rl i q u i d s t o c o v e r e d m e t a l c o n t a i n e r s f o r r e c o v e r y o r d i s p o s a l , o r r e m o v ew i t h i n e r t a b s o r b e n t . U s e o n l y n o n - s p a r k i n g t o o l s . P l a c e a b s o r b e n t d i k i n g

^ PAGE J______521022_______3_2__________________________________________________________DATE 11/07/96

I____________SECTION VIII - ENVIRONMENTAL INFORMATION; (CONTINUED)____________

STEPS TO BE TAKEN IF MATERIAL IS RELEASED OR SPILLEDm a t e r i a l s i n c o v e r e d m e t a l c o n t a i n e r s f o r d i s p o s a l . P r e v e n t c o n t a m i n a t i o no f s e w e r s , b t r e a m s , a n a g r o u n d w a t e r w i t h s p i l l e d m a t e r i a l o r u s e da o s o r b e n t .

•E DISPOSALD i s p o s e i n a c c o r d a n c e w i t h f e d e r a l , s t a t e a n a l o c a l r e g u l a t i o n s .

..Jl CLASSIFICATIONT h i s p r o d u c t , i f d i s c a r d e d d i r e c t l y , y o u l d b e c l a s s i f i e d a h a z a r d o u s w a s tb a s e d o n i t s i g n i t a b i l i t y c h a r a c t e r i s t i c , i . e . h a s a f l a s h p o i n t o f 1 4 0d e g . - . ( 6 0 d e g . C ) o r l e s s . T h e p r o p e r R C R A c l a s s i f i c a t i o n w o u l d b e D 0 0 1 .

ENVIRONMENTAL HAZARDSN o n e k n o w n


P r o p e r s e l e c t i o n o f r e s p i r a t o r y p r o t e c t i o n d e p e n d s u p o n m a n yi n c l u d i n g d u r a t i o n / l e v e l o f e x p o s u r e a n d c o n d i t i o n s o f u s e . Ie x p o s u r e t o o r g a n i c c h e m i c a l s s u c h a s t h o s e c o n t a i n e d i n t h i sn o t r e q u i r e t h e u s e o f r e s p i r a t o r y p r o t e c t i o n i f u s e d i n w e l la r e a s . I n r e s t r i c t e d v e n t i l a t i o n a r e a s a N I 0 S H a p p r o v e d c h e m i

m e c h a n i c a l p r e f i l t e r m a y a l s o b e r e q u i r e d . ; n c o n f i n e d a r e a sM S H A a p p r o v e d a i r s u p p l i e d r e s p i r a t o r . I f t h e T L V ' s l i s t e d i na r e e x c e e d e d u s e a p r o p e r l y f i t t e d M 1 0 S H / M S H A a p p r o v e d r e s p i ra p p r o p r i a t e p r o t e c t i o n f a c t o r . R e f e r t o O S H A 2 9 C F R 1 9 1 0 . 1 5 4P r o t e c t i o n " , a n d " R e s p i r a t o r y P r o t e c t i o n A M a n u a l A n d G u i d e l iI n d u s t r i a l H y g i e n e A s s o c . "

VENTILATIONP r o v i d e g e n e r a l d i l u t i o n a n d l o c a l e x h a u s t v e n t i l a t i o n i n s u fa n a p a t t e r n t o k e e p c o n c e n t r a t i o n s o f h a z a r d o u s i n g r e d i e n t s IS e c t i o n I I b e l o w t h e l o w e s t e x p o s u r e l i m i t s t a t e d . R e m o v e d e ca r o d u c t s t h a t a r e g e n e r a t e d w h e n w e l d i n g , c u t t i n g , o r b r a z i n g: o a t e a w i t h t h i s p r o d u c t . R e f e r t o " I n d u s t r i a l V e n t i l a t i o n

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HAND PROTECTIONS o l v e n t i m p e r m e a b l e g l o v e s a r e r e q u i r e d f o r r e p e a t e d o r p r o l o n g e d c o n t a c t

EYE PROTECTIONW e a r s a f e t y s p e c t a c l e s .

OTHER PROTECTIVE EQUIPMENTN o t l i k e l y t o b e n e e d e d .

SECTION x - SPECIAL! PRECAUTIONSPRECAUTIONS TO BE

3 o n o t s t o rc o m o l i a n c e

.£R PRECAUTIONSD o n o t t a k eE m p t y c o n t aC o n t a i n e r sD o n o t w e l dN e v e r u s e p

TAKENe a b ow i t h

i n t ei n e r ss h o u I, brar e s s u

IN HANDLING AND STORAGIv e 1 1 5 d e g . F ( 4 6 d e g . C ) s t o r e IO S M A 2 9 C F R 1 9 1 0 . 1 0 6 .

r n a l l y . C l o s e c o n t a i n e r a f t e r e am u s t n o t b e w a s h e d a n d r e - u s e d

d b e g r o u n d e d a n d b o n d e d t o t h ez e o r c u t o n e m p t y c o n t a i n e r ,r e t o e m p t y . D r u m i s n o t a p r e s

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q u a n t i t i e s i n

s e .a n y p u r p o s e ,i v i n g c o n t a i n e r .

v e s s e l .

SECTION XI - OTHERiINFORMATION

SECTION XII - TRANSPORTATION DATA» R 0 P

D 0 T

D 0 T

D 0 T

P R E C

L I M ID . 0 .

E R S "1 I P P

: . A s s i F iL A B E L

P L A C A R D

A U T I 0 N S

TED 0 U A NT . I . D .

I N G

C A T

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1 0

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N

T A K E N I N

N 0R UN 1 2 6 3

L E ) P A I N T

F L A M M A B L § L I Q U I DF L A M M A B L E .F L A M M A B L E .

T R A N S P O R T A T I O N

A E R O S O L P R O P E LR . Q . NO.

D O T M A R

E M E R G E N

& P R 0 C E

L E N T :U . S .

K 1

C Y

D U

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A C C

R E S

N 0 t0 S T A

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yN 11 _£Qs i *i!JiE ?i2iii y_M1 P I N T M E T A L 2 N 1 N 11 Q U A R T M E T A L 2 N 1 M 11 G A L L O N M E T A L 2 N 1 N 15 G A L L O N M E T A L 1 7 C 1A1

1 7 K 1 A 25 5 G A L L O N M E T A L 1 7 C 1 A 1

1 7K 1A2F I B E R B O A R D B O X 1 2 B 4 C( N O P L A S T I C C O N T A I N E R S W I L L B E A U N I T C O N T A I N E R O N L Y U S E D F O R 1 C O M P O N E N T O FA K I T U N I T C O N T A I N E R ) .

"GOVERNMENT SPEC.521022 32 DATE 11/07A91


T H I S I S T O C E R T I F Y T H A T T H I S I T E M I S H A Z A R D O U S A N D I N F O R M A T I O N S T A T E D I S , T OT H E B E S T C F Q u R K N O W L E D G E , C O R R E C T .


' H E I N F O R M A T I O N C O N T A I N E D H E R E I N I S B A S E D O N D A T A C O N S I D E R E D T O B EA C C U R A T E . W H I L E T H E I N F O R M A T I O N I S B E L I E V E D T O B E R E L I A B L E , N O W A R R A N T Y I SE X P R E S S E D C R I M P L I E D R E G A R D I N G T H E A C C U R A C Y O F T H I S D A T A O R T H E R E S U L T S T OB E O B T A I N E D F R O M T H E U S E T H E R E O F . S I N C E T H E U S E O F T H I S I N F O R M A T I O N A N D T H EC O N D I T I O N S A N D U S E O F T H I S P R O D U C T A R E C O N T R O L L E D B Y T H E U S E R , I T I S T H EU S E R ' S O B L I G A T I O N T O D E T E R M I N E T H E C O N D I T I O N S O F S A F E U S E O F T H E P R O D U C T .

T h e C o r p o r a t e S a f e t y a n d E n v i r o n m e n t a l A f f a i r s D e p a r t m e n t i sr e s p o n s i b l e f o r t h e p r e p a r a t i o n o f t h i s M a t e r i a l S a f e t y D a t a S h e e t .


H . M . I . S .HEALTH 2FLAMMABILITY 3REACTIVITY 0

"hese rat ings should be used onlyas part ot f u l l y ' no I emen t ca H . M . I . S . program.



SECTION i


TRADE NAME .... H I G H S O L I D S • • • • A M O C O B L U E

MANUFACTURER CODE I . D . i 2 2 C 1 5 4 2

REVISED ON 1 1 / 0 7 / 9 6


A / D

C O N T R A C T


INGREDIENT % BYWGT

CAS NO., NIOSH*


SARA313

VPmm Ha @

20 DEG.C

N A P ! H A ( F E T R O L E J M )i E A V Y A L K Y L A T E

• : TAN : ^ M . : ; G X I D E

? E T R 0 . t: ̂ u " " C R 0 -,; A R B o s M : x • „ R E

M I N E R A L ic I R I T S

6 4 7 4 1 - 6 5 - 7 M F RS O L V E N T

13463-67 :P I G M E N T AR2275303

- L V - T U A: SHA-PEL

3 3 3 2 - 3 2 - - L V - T U A3 I 6 1 8 0 3 0 C C S H A - P E L

8 0 0 0 - 4 1 - 7S O L V E N T

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100 525

100 525100 525


64742-68-7 T L V - T U A 100 525OSHA-PEL 100 525

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M A B I L I T Y L I M I T P E R C E N TM A B I L I T Y L I M I T P E R C E N TP T I O N M U S T B E C O N S I D E R E D A S A R O U T E O F E X P O SE X P O S U R E L E V E L S H O U L D N O T B E E X C E E D E D - O R A

R R E C O M M E N D E D E X P O S U R E L I M I TE X P O S U R E L I M I T

I C A L I S S U B J E C T T O R E P O R T I N G R E Q U I R E M E N T S O F. A . R . A . . . 0 C F R P A R T 3 7 2G I S T R Y O F T O X I C E F F E C T S O F C H E M I C A L S U B S T A N C

U R EN Y T I M E P E R

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I 0 D

3


SWALLOWING~ j n c a u s e q a s t r c i n t c s t ' ^ a t ' r r i t a t I C n , n a u s e a , : n a v . . n i t ' ° q . A

INHALATIONMay c a u s e ° o s e or t h r o a t • r r i t a t ) o n . H i g h c o n c e n t r a t i o n s nay cc e n t r a l n e r v o u s s y s t e m d e p r e s s i o n c h a r a c t e r i z e d b y h e a d a c h e s ,n a u s e a a n d c o n f u s i o n .


SKINM a y c a u s e d e t a i l i n g a n d i r r i t a t i o n o f t h e s i c i n .

EFFECTS OF REPEATED OVEREXPOSURER e p o r t s h a v e a s s o c i a t e d p r o l o n g e d a n d r e p e a t e d o c c u p a t i o n a l o v

m i s u s e b y d e l i b e r a t e l y c o n c e n t r a t i n g a n d i n h a l i n g t h e c o n t e n t sh a r m f u l o r f a t a l

SIGNIFICANT LABORATORY DATA WITH POSSIBLE RELEVANCE TO HUMAN HEALTH.* i t a n i u m d i o x i d e I S N O T m i s t e d a s a p o t e n t i a l c a r c i n o g e n b y t h' o x i c o i o g y P r o g r a m , t h e I n t e r n a t i o n a l A g e n c y f o r R e s e a r c h o n Co r A . C . G . I . H . T i t a n i u m d i o x i d e i n a 2 4 - m o n t h i n h a l a t i o n s t u d yr e v e a l e d a s i g n i f i c a n t i n c r e a s e i n b e n i g n a n d m a l i g n a n t l u n g tg r o u p e x p o s e d t o 2 5 0 m g / M 3 r e s p i r a b l e T i 0 2 d u s t . A t l o w e r e x p o st h i s s i g n i f i c a n t e f f e c t w a s n o t o b s e r v e d . " h e n o r m a l c l e a r a n c eo f t h e l u n g s m a y h a v e b e e n o v e r w h e l m e d a t t h e 2 5 0 r a g / M 3 e x p o s u rT h i s m a y h a v e c o n t r i b u t e d t o t h e t u n o r f o r m a t i o n . T h e s e r e s u l to e d i r e c t l y r e l e v a n t t o t h e w o r k p l a c e w h e r e o c c u p a t i o n a l e x p o sa r e o b s e r v e d . A t t h e T L V t h e T i O Z m a n u f a c t u r e r c o n c l u d e s t h a ts i g n i f i c a n t h a z a r d f o r m a n .

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SECTION IV - FIRST AID AND EMERGENCY PROCEDURES.LOWING

I f s w a l l o w e d d o n o t i n d u c e v o m i t i n g . C a l l p o i s o n c o n t r o l c e n t e r , h o s p i t a l

—————^————————— PAGE 2______522015_____4_2__________________________________________DATE 11/07/96

I__________SECTION IV - FIRST AID AND EMERGENCY PROCEDURES; (CONTINUED)_______

SWALLOWINGo m e r q e n c v " o o m c r p h y s i c ' a n i m m e d i a t e l y

INHALATION"a e m o v e t o f r e s h a i r i m m e d i a t e l y . I f b r e a t h i n g n a b s t o p p e d , g i v e a r t i f i -c i a l r e s p i r a t i o n . K e e p w a r m a n d q u i e t . G e t n e a i c a l a t t e n t i o n i m m e d i a t e l y .

F l u s h w i t h , a r g e a m o u n t s of w a t e r , l i f t i n g „ D p e r ,1 n a l o w e r '. i a s o c c a s i o n a l -l y . C o n t i n u e f o r , 1 t l e a s t 1 5 m i n u t e s . G e t r ^ e a i c a i a t t e n t i o n .

SKINS e m o v e c o n t a m i n a t e d c l o t h i n g . W a s h e f f e c t e d a r e a w i t h s o a p a n d w a t e r .0 b t a ' n m e d i c a l a t t e n t i o n i f i r r i t a t i o n p e r s i s t s

NOTES TO PHYSICIANA n y t r e a t m e n t t h a t T i i g h t b e r e q u i r e d f o r o v e r c x p o s u r e s h o u l d b ed i r e c t e d a t t h e c o n t r o l o f s y m p t o m s a n d t h e c . i n i c a l c o n d i t i o n s .

SECTION V - PHYSICAL DATABOILING RANGE ' 6 5 D E G . F . ( 7 4 O E G . C . ) T O 4 1 4 D E G . F . ( 2 1 2 D E G . C . )

FREEZING POINT: 5 0 D E C . F . ( - 4 5 D E C . C . )

VAPOR PRESSURE : 2 m m H g a 6 8 D E C . F . ( 2 D D E C . C . )

VAPOR DENSITY l e a v i e r t h a n a i r . % VOLATILE BY VOLUME 53

EVAPORATION RATE VOC 3 . 4 8 Ib/gal less voter i NPRS* .18 g/1 less watarC A iS l o w e r t h a n d i e t h y l e t h e r .

E ! CA V I » 1 0 8 9 6 g / 1 """** : A L C U L A T E D

APPEARANCE & ODOR : L i q u i d , S o l v e n t o d o r SOLUBILITY : S l i g h t • n w a t e r

VISCOSITY: N o i n f o r m a t i o n f o u n d P H : . . - 7 ( S T D U N I T S )

All Physical data determined at 68 DEC. F. (20 DEG. C.) 760 mm Ha• Negligibly Photochemically Reactive Material*VOC values reported here are verified by ASTM method D-3960

SECTION VI - FIRE AND EXPLOSION DATANFPA FLAMMABILITY CLASSIFICATION F L A M M A B L E L I Q U I D C L A S S 1 C

FLAMMABLE LIMITS ' . 0 % - 7 . 0 '/.

-HPOINT 9 3 D E G . F , ( 3 4 O E G . C , } C A L C U L A T E D

JIGNITION 5 7 2 D E G . F . ( 3 0 0 D E G . C . ) DECOMPOSITION TEMP " 3 3 2 D E G . f . ( T O G O O E G . C . )



EXTINGUISHING MEDIAu s e N F P A C l a s s B F i r e e x t i n g u i s h e r s ( c a r b o n d i o x i d e , j l l p u r p o s e d r y c h e m i -c a l o r a l c o h o l f o a m ) d e s i g n e d t o e x t i n g u i s h f l a m m a b l e l i q u i d f i r e s . P o l y -m e r ' o a m i s p r e f e r r e d f o r t a r q e f i r e s

UNUSUAL FIRE AND EXPLOSION HAZARDSD u r i n g e m e r g e n c y c o n d i t i o n s , o v e r e x p o s u r e t o d e c o m p o s t i o n p r o d u c t s m a yc a u s e j h e a l t h h a z a r d . S y m p t o m s m a y n o t b e i m m e d i a t e l y a p p a r e n t O b t a i nT i e d t c a i a t t e n t i o n .W A R N I N G 1 C L A M M A B L E .

SPECIAL FIRE FIGHTING PROCEDURESw a t e r m a y b e i n e f f e c t i v e , b u t m a y b e u s e d t o c o o l e x p o s e d c o n t a i n e r s t op r e v e n t p r e s s u r e b u i l d - u p a n d p o s s i b l e a u t o - i g n i t i o n o r e x p l o s i o n w h e n

_ e x p o s e d t o e x t r e m e h e a t . I f w a t e r i s _ u s e d , * o q n o z z l e s a r e p r e f e r a b 1 e .______



CONDITIONS tO AVOIDA v o i d e x c e s s i v e h e a t ( > 1 1 5 F ( 4 6 C ) a n d s o u r c e s o f i g n i t i o n .


HAZARDOUS DECOMPOSITION PRODUCTSB u r n i n g , n c i u d i n g w h e n h e a t e d b y w e l d i n g o r c u t t i n g , w i l l p r o d u c e s m o k ec a r b o n m o n o x i d e a n d c a r b o n d i o x i d e .


CONDITIONS TO AVOIDN o n e Known______________________________ __ __

[_ _______________SECTION VIII - ENVIRONMENTAL INFORMATION_________________'S TO BE TAKEN IF MATERIAL IS RELEASED OR SPILLED

K e e p s p e c t a t o r s a w a y . E l i m i n a t e a l l i g n i t i o n s o u r c e s ( f l a m e s , h o t

522015 42

| SECTIONVIII - ENVIRONMENTAL INFORMATION;

PAGEDATE

(CONTINUED)

11/07 /96

STEPS TO BE TAKEN IF MATERIAL IS RELEASED OR SPILLEDu r a c e s

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ENVIRONMENTAL HAZARDSS o n e K n o w n


• r o p e r s e l e c t i o n c t ' e s p ' r a t o r y p r o t e c t i o n d e p e n d s u p o n n a n y' n c i u d i n g d u r a t i o n / l e v e l o f e x p o s u r e a n d c o n d i t i o n s o * u s e .e x p o s u r e t o o r g a n i c c h e m i c a l s s u c h a s t h o s e c o n t a i n e d i n t h i•• o t ' e q u i " e the use o* ' e s p i r a t o r y p r o t e c t i o n i * u s e d in wel

e s p i ' a t c " may be ^ r q u i • e a . J n d e r c e r t a i n r e n d i t i o n s , s u c h am e c h a n i c a l p r e f i I t e r r a y a l s o b e r e q u i r e d . i n c o n f i n e d a r e a s" S H A a p p r o v e d air s u p p i • e a ' e s p i r a t o r . If the ' . J ' ; , - s t e da r e e x c e e d e d u s e a p r o p e - l y f i t t e d M I O S H / M S H A a p p r o v e d r e s p ia p p r o p r i a t e p r o t e c t i o n - a c t o r . R e f e r t o O S H A 2 9 C F R 1 9 ' 0 . 1 3 4f ' r o t e c t ' 0 i " , and " R e s p i r a t o r y P r o t e c t i o n A M a n u a . And G „ i d e iI n d u s t r i a l ^ y g i e n e A s s o c . "

VENTILATIONp r o v i d e g e n e r a l d i l u t i o n and l o c a l e x h a u s t •. e n t • . a t i o n • n sui n d p a t t e r n t o n e e p c o n c e n t r a t i o n s o t h a z a r d o u s - " g r e d i e n t s

.-> e c t • o n I! b e l o w the * o w e s t e x p o s u r e l i m i t s t a t e d . R e m o v e dep r o d u c t s t h a t a r e g e n e r a t e d w h e n w e l d i n g , c u t t i n g , o r b r a z i n. o a t e d w i t h t h i s p r o d u c t . R e f e r t o " I n d u s t r i a l v e n t i l a t i o nR e c o m m e n d e d P r a c t ' c c " A C G I H

HAND PROTECTIONS o l v e n t i m p e r m e a D l e g l c v e s a r e r e q u i r e d f o r ' e p e a t e d o r p r o i

EYE PROTECTIONw e a r •• a t e t y s p e c t a c l e s .

OTHER PROTECTIVE EQUIPMENTsot i ' ic e t y to be n e e d e d .

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SECTION X - SPECIAL PRECAUTIONSrKECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE

D o n o t s t o r e a b o v e ' 1 5 d e g . F ( 4 6 d g g . C )c o m p l i a n c e w i t h O S H A 2 9 C F R 1 9 1 0 . 1 0 6 .

OTHER PRECAUTIONS; ; o n o t t a * e ' i t e r n a l le m p t y c o n t a i n e r s m u s tJ o n t a i n e r s s h o u l d b e3 o n o t w e l d , b r a z e o r c u t o n e m p t ys e v e r ^ s e p r e s s u r e t o e m p t y . D r u m

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PAGE522015______42__________________________________________________________DATE 11/07/96


C L R T I f " T H A T T r l I S I T E M I S H A Z A R D O U S A N D I N F O R M A T I O N S ' A T E D I S , T OC „ R K N O W L E D G E . , C O R R E C T .


T H E I N F O R M A T I O N C O N T A I N E D H E R E I N I S B A S E D O N D A T A C O N S I D E R E D T O B EA C C U R A T E . W H I L E T H E I N F O R M A T I O N I S B E L I E V E D T O B E R E L I A B L E , N O W A R R A N T Y I SE X P R E S S E D O R I M P L I E D R E G A R D I N G T H E A C C U R A C Y O F T H I S D A T A O R T H E R E S U L T S T OB E O B T A I N E D F R O M T H E U S E T H E R E O F . S I N C E T H E U S E C F T H I S I N F O R M A T I O N A N D T HC O N D I T I O N S A N D U S E O F T H I S P R O D U C T A R E C O N T R O L L E D B Y T H E J S E R , I T I S T H EU S E R ' S O B L I G A T I O N " 0 D E T E R M I N E T H E C O N D I T I O N S O F S A F E U S E C F T H E P R O D U C T .

T h e C o r p o r a t e S a f e t y a n d E n v i r o n m e n t a l A f f a i r s D e p a r t m e n t ' sr e s p o n s i b l e f o r t h e p r e p a r a t i o n o f t h i s M a t e r i a l S a f e t y D a t a S h e e t .


H . M . I . S .HEALTH 1FLAMMABILITY 3REACTIVITY 0

"hese rat inqs should bo used oniy. is port or » u . i y imoiemented n . M . l . S . program.

r^"PORATE CONTACT 216-566-2917 (M-F 8 AM-5 PM CT)


SECTION I

PRODUCT CLASS A i < Y D , M E D I U M - L O N G

TRADE NAME .... H I G H S O L I D S • • • • M O B I L R E D A / 0 D R E N L

MANUFACTURER CODE I . D . 5 2 6 0 1 0 4 2

REVISED ON

8 0 1 0 -M A N U F A C T U R E R C A G E 6 1 1 9 6 C O N T R A C T

1 1 / 0 7 / 9 6

SECTION II

INGREDIENT % BY CAS NO.WGT /NIOSH8

S A P T H 4 ( P E T R O L E U M ) 6 4 7 4 : - 6 5 - 7- E A V Y A L K Y L A T E S O L V E N T

» Y L E N E - 5 ' 3 3 0 - 2 0 - 7S O L V E N T 7 E 2 ' 0 0 0 0 0

P E T R O L E U M H Y D R O - 8 0 3 2 - 3 2 - wC A R B O N M I X T U R E 0 1 6 1 8 0 0 0 0

- HAZARDOUS INGREDIENTS

Mf R

" L V- TWA• . V - S T E LO S H A - P E LO S H A - S T E LFL ' .0

T LV- TUAO S H A - P E L

PPM

100

100150100150

100100

ALLOWABLE SARA VPEXPOSURE LEVEL 313 mm Hq ®

20 DEG.CMG/CU.M. MPPCF SKIN

5 2 5

-35 x 5S 5 5

UF L " . C

5 2 55 2 5

P I N E O I LS O L V E N T

8 0 0 0 - 4 1 - 7 NONE E S T A B L I S H E D

E X P O S U R Ef 0 R ANY

. F L ^ L O W E R F L A M M A B I L I T Y L I M I T P E R C E N T' L - U P P E R F . A M M A B 1 L I T * L I M I T P E R C E N T

I N = S K I N A B S O R P T I O N M U S T B E C O N S I D E R E D A S A R O U T E O FC E 1 L ! N G = A i L O U . E X P O S U R E L E V E L S H O U L D N O T B E E X C E E D E DR = M A N U F A C T U R E R R E C O M M E N D E D E X P O S U R E L I M I T

S T E L = S H O R T T E R M E X P O S U R E L I M I TX - S A R A 3 1 3 = C H E M I C A L I S S U B J E C T T O R E P O R T I N G R E Q U I R E M E N T SO F ' ! T L E i i l O F S . A . R . A . i 0 C F R P A R T 3 7 2N I 0 S H » = N I O S H R E G I S T R Y O F T O X I C E F F E C T S O F C H E M I C A L S U B S T A N C E S

I M E P E R I O D

O F S E C T I O N 3 1 3

N U M B E R .


^ a n c a u s e g a s t r o i n t e s t i n a l i r r i t a t i o n , n a u s e a , : n d v ~ n ' t ; n g . A s p i r a t i o n ofm a t e r • a , nto i ^ n g - n a y c a u s e C h e m i c a l p n e u m o n i t ' s w n • r h ,an be ' .1 t a I .

INHALATIONH a v c a u s e n o s e o r t h r e a t i r r i t a t i o n . H i g h c o n c e n t r a t i o n s m a y c a u s e a c u t ec e n t r a l " c r v o u s s y s t e n d e p r e s s i o n c h a r a c t e ' - ' j e d K v l e a a a c h c s , d i z z i n e s s ,n a u s e a j n a c o n f u s i o n .


SKINM a y c a u s e d e f a t t i n q a n d i r r i t a t i o n o f t h e s k i n .

EFFECTS OF REPEATED OVEREXPOSUREJ v e r e x p o s u r e t o x y i e n e m a y c a u s e i n j u r y t o t h e l i v e r , k i d n e y s , a n db l o o d .R e p o r t s h a v e a s s o c i a t e d p r o l o n g e d a n d r e p e a t e d o c c u p a t i o n a l o v e r e x p o s u r e: o s o l v e n t s w i t h p e r m a n e n t b r a i n a n d n e r v o u s s y s t e m d a m a g e . i n t e n t i o n a lT i s u s e b y d e l i b e r a t e , y c o n c e n t r a t i n g a n d i n h a l i n g t h e c o n t e n t s m a y b ei a r m r u I cr t a t a l .

SIGNIFICANT LABORATORY DATA WITH POSSIBLE RELEVANCE TO HUMAN HEALTH.N o n e c u r r e n t l y k n o w n

I ______________ SECTION IV - FIRST AID AMD EMERGENCY PROCEDURES _______________SWALLOWING

I t s w a l l o w e d d o n o t ' n d u c e v o m i t i n g . C a l l p o i s o n c o n t r o l c e n t e r , h o s p i t a le m e r g e n c y r o o m o r p h y s i c i a n i m m e d i a t e l y .

INHALATIONR e m o v e t c f r e s h a i r ' m m e d i a t e l y . I f b r e a t h i n g h a s s t o p p e d , g i v e a r t i f i -c i a l " e s p i r a t i o n . K e e p w a r m a n d q u i e t . G e t m e d i c a l a t t e n t i o n i m m e d i a t e l y

FVEc l u s h w i t i l a r g e a m o u n t s o f w a t e r , l i f t i n g u p p e r a n d l o w e r l i d s o c c a s i o n a l. y . C o n t i n u e f o r a t . e a s t 1 5 m i n u t e s . G e t m e d i c a l a t t e n t i o n .

R e m o v e c o n t a m i n a t e d c l o t h i n g . W a s h a f f e c t e d a r e a w i t h s o a p a n d w a t e r .

526010PAGEDATE 11/07/96


SKINC D t a i n m e d i c a l a t t e n t i o n : f i r r i t a t i o n p e r s i s t s .

NOTES TO PHYSICIANa n y T r e a t m e n t t h a t n i g h t b e r e q u i r e d f o r o v e r e x p o s u r e s h o u l d b ej ' r e c t c d a t t h e c o n t r o l o f s y m p t o m s a n d t h e c l i n i c a l c o n d i t i o n s .


FREEZING POINT:

VAPOR PRESSURE:

VAPOR DENSITY


' 65 D E G . ; . ( 74 D E G . C . ) TO - 14 D E G . F . ( 212 D E G . C . )

• 5 0 D E G . F . ( • 4 5 D E C . C . )

5 m m H g £ 6 8 D E G . F . ( 2 0 D E C . : . )

M e a v i e r t h a n a i r . % VOLATILE B Y VOLUME

VOC 3 . 4 9 Ib/gal lees water & NEKS* - ' 9 g/1 less waterC A L

VOC 7 . 6 0 Ib/gal solids 912 g/1 anliAt C A L C U L A T E DWEIGHT LB./GAL. 7 . 9S P E C I F I C G R A V I T Y 0 . 9

APPEARANCE & ODOR: L i q u i d , S o l v e n t o d o r


SOLUBILITY:

PH:


4-7 ( S T O U N I T * )

All Physical data determined at 68 DEG. F. (20 DEG. C.) 760 nun Hg* Negligibly Photochemically Reactive MaterialsVOC values reported here are verif ied by ASTM method D-3960______

SECTION VI - FIRE AND EXPLOSION DATANFPA FLAMMABILITY CLASSIFICATION F L A M M A B L E

FLAMMABLE LIMITS

FLASHPOINT

. 0 . 0

80 D E G . F C E G . C C A L C U L A T E D

AUTOIGNITION 5 7 2 D E G . F . ; 3 0 0 D E G . C . )

CORROSION RATE S o t a p p l i c a b l e

NET EXPLOSIVE W G T . N o t a p p , ' : a b I e

DECOMPOSITION TEMP

MAGNETISM

' 3 3 2 D E G . F . ( 1 0 0 0 D E G . C . )


"•""•INGUISHING MEDIAJse S F P A C L a s s B F i r e e x t i n g u i s h e r s ( c a r b o n J i o x i d ec a i o r a l c o h o l f o a m ) d e s i g n e d t o e x t i n g u i s h ' . a m m a b

r e f e r r e d f o r l a r g e f i r e s .

. i . l p u r p o s e d r y c h e t n i• q u i d f i ' e s . P o l y -

mer * " : a m ' s p r e f e r r e d forUNUSUAL FIRE AND EXPLOSION HAZARDS

D u r i n g e m e r g e n c y c o n d i t i o n s , o v e r e x p o s u r e t o d e c o m p o s i t i o n p r o d u c t s m a yc a u s e a h e a l t h h a j a r d . S y m p t o m s m a y n o t b e i m m e d i a t e l y a p p a r e n t . O b t a i n• n e d i c a l a t t e n t i o n .W A R N I N G 1 F L A M M A B L E .

SPECIAL FIRE FIGHTING PROCEDURESw a t e r m a y b e i n e f f e c t i v e , b u t ( nay b e u s e d t o c o o l e x p o s e d c o n t a i n e r s t op r e v e n t p r e s s u r e b u i l d - u p a n d p o s s i b l e a u t o - ' g n i t i o n o r e x p l o s i o n w h e ne x p o s e d t o e x t r e m e h e a t . I f w a t e r i s u s e d , ' o q n o z z l e s a r e p r e f e r a b l e .





HAZARDOUS DECOMPOSITION PRODUCTSS u r n i n g , i n c l u d i n g w h e n h e a t e d b y w e l d i n gc a r b o n m o n o x i d e a n d c a r b o n d i o x i d e .

HAZARDOUS POLYMERIZATION« i l l n o t o c c u r

CONDITIONS TO AVOIDN o n e K n o w n

F ( 4 6 C ) a n d s o u r c e s o f i g n i t i o n .

c u t t i n g , i l l p r o d u c e s m o k e


* . e e p s p e c t a t o r s a w a y . E l i m i n a t e a l l i g n i t i o n s o u r c e s ( f l a m e s , h o ts u r f a c e s , a n d s o u r c e s o f e l e c t r i c a l , s t a t i c c r t r i c t i o n a l s p a r i c s ) .D i K e a n d c o n t a i n s p i l l w i t h i n e r t m a t e r i a l ( e . g . s a n d , e a r t h ) . T r a n s f e r. i q u i a s t o c o v e r e d m e t a l c o n t a i n e r s f o r r e c o v e r y c r d i s p o s a l , o r r e m o v e» i t h i n e r t a b s o r b e n t . u s e o n l y n o n - s p a r k i n g t o o l s . P l a c e a b s o r b e n t d i k i n gm a t e r i a l s 1 1 c o v e r e d m e t a l c o n t a i n e r s f o r d i s p o s a l . P r e v e n t c o n t a m i n a t i o n3 t s e w e r s , s t r e a m s , j n d g r o u n d w a t e r w i t h s p i i . o d m a t e r i a l o r u s e da b s o r b e n t .:E DISPOSALD i s p o s e i n a c c o r d a n c e w i t h f e d e r a l , s t a t e a n d l o c a l r e g u l a t i o n s .

526010 4 2PAGEDATE 11/07/96

RCRA CLASSIFICATION" h i s p r o d u c t , i f d i s c a r d e d d i r e c t l y , w o u l d fc<? r . a s s i f i o d ao a s e a o n i t s i g n i t a b i i i t y c h a r a c t e r i s t i c , i . e . r a s a f i a s nd e g . F . ( 6 0 d e q . C ) o r l e s s . " h e p r o p e r R C R A c . a s s i f i c a t i o n

'RONMENTAL HAZARDSN o n e k n o w n

j SECTION IX - PERSONAL PROTECTION INFORMATIONRESPIRATORY PROTECTION

' r o p e r s e l e c t i o n o ' r c s p i i a t o r y p r o t e c t ' c n c e D e n a s u D o n man c l u d i n g a u r a t i o n / i e v e i j f e x p o s u r e a n d c o n d i t i o n s o f u s e

e x p o s u r e T o o r g a n i c c h e m i c a l s s u c h a s t h o s e c o n t a i n e d i n t• - O T r e a u •. - e The use o* r e s p i r a t o r y p r o t e c t ' c n •' u s e d in wa r e a s . I n r e s t r i c t e d v e n t ' i a t i o n a r e a s a N I C S H a p p r o v e d c h• e s p i r a t o r - n a y De r c q u < r c a . U n d e r c e r t a i n c o n d i t i o n s , s u c h• n e c n a n i c a l p r e f ' l t e r .-nay a ; s o b e r e q u i r e d . I n c o n f i n e d a r eM S H A a p p r o v e d a i r s u p p l i e d r e s p i r a t o r . I f t i e " L V ' s . i s t e da r e e x c e e d e d u s e a p r o p e r t y f i t t e d N I O S H / M S H A a p p r o v e d r e sa p p r o p r i a t e p r o t e c t i o n f a c t o r . R e f e r t o O S H A 2 9 C F R 1 9 1 0 . 'P r o t e c t i o n " , a n d " R e s p i r a t o r y P r o t e c t i o n A M a n u a l A n d G u i d' n d u s t r i a l h y g i e n e A s s o c . "

VENTILATIONP r o v i d e g e n e r a l d i l u t i o n a n d l o c a l e x h a u s t v e n t i l a t i o n i na n d p a t t e r n t o k e e p c o n c e n t r a t i o n s o f h a z a r d o u s i n g r e d i e n tS e c t ' o n I I b e l o w t h e l o w e s t e x p o s u r e l i m i t • t a t e d . R e m o v ep r o d u c t s t h a t a r e g e n e r a t e d w h e n w e l d i n g , c u t t i n g , c r b r a zc o a t e d w i t h t h i s p r o d u c t . R e f e r t o " I n d u s t r i a , V e n t i . a t i o nS e c o n m e n d e d P r a c t i c e " A C G I M

HAND PROTECTION- e a r a p p r o p r i a t e i - n p e r - i e a D l e g l o v e s ( N o r t h S i l v e r S h i e l d )

EYE PROTECTIONj e a r s a f e t y s p e c t a c i o s .

w

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0 f

OTHER PROTECTIVE EQUIPMENTb e n e e d e d .

SECTION X - SPECIAL PRECAUTIONSPRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE

2 o n o t s t o r e a b o v e- o m p i ' a n c e w i t h 0 S H

OTHER PRECAUTIONSL- 'o n o t t a k e i n t e r n at m p t y c o n t a i n e r s muC o n t a i n e r s s h o u l d bCo no t w e l d , p r a z es e v e r u s e p r e s s u r e

A

Isect

• ' 52 9

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9 rc

o e

d e g . F ( 4 6 d e g . C )C F R 1 9 1 0 . 1 0 6 .

C l o s e c o n t a i n e r ao t b e w a s h e d a n do u n d e d a n d b o n d e du t o n e m p t y e o n t a im p t y . D r u m i s n o t

s t

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A M M A B L E ^ I 0 U I D E M E R G E N C Y A C C I D E N T P R E C A U T I O N S

A M M A B L E % P R O C E D U R E S S E E A B O V E

A M M A B L E

0 R T A T 1 0 N

A E R O S O L P R O P E L L E N T : N o t a p p l i c a b l eN O . U . S . P O S T A L F O R B I D D E N

N

N 1N 1N 1A 1A 2A 1A 2G

U N I T C O N T A I N E R O N L Y ' J S E D F O R ' C O M P O N E N T O F

526010

miDATE

SECTION

T •> S : S T O C E R T5 E S T C > C U R

; F Y •< N 0 U

XII

H A TL E D G

- TRANSPORTATION JDATA ; (CONTINUED)

T H I S : T E M I S H A Z A R D O U S A N D I N F O R M A T I O N S T A T E D I SE , C O R R E C T .

T 0

R E G U L A ' Q R Y F G R M A T I 0 N S E R V I C E S

• H E I N F O R M A T I O N C O N T A I N E D H E R E I N I SS C C ' J R A T E . J HE X P R E S S E D J Ra E O B T A I N E DIC O N D I T I O N SU S E R ' S O B L

T h e C or e s p o n s i b l e

1 L E THEI M P L I E D

F R O M T H EA N D U S E O F

C A T I O N • 0 D E

N F 0 R M A T I 0 NR E G A R DJ S E " H

I A S E D ONI S B E L I E V E D

I N G T H E A C C U R A C YE R E 0 F . S I N C E THE

A T A C O N S I D E R E D T O B EB E R E L I A B L E

S EI S

0 FH I S P R O D U C T A R E C O N T R O L L E D B YE R M I N E T H E C O N D I T I O N S C F S A F E

A T AT H I S !

T H EU S E

N O W A R R A N T Y I SC R T H E R E S U L T S T O^ F O R M A T I O N A N D T H EU S E R ,OF T H

p o r a t etor t

S a f e t y a n d E n v i r o n m e n t a l A f f a i r s D e p a r t m e n te p r e p a r a t i o n o f t h i s M a t e r i a l S a f e t y D a t a

I T I S T H EE P R O D U C T .i s

S h e e t .

PRATT & LAMBERT 316-733-1361Industrial Coatings Div.101 Prospect AvenueCleveland, OH 44115


-"PORATE CONTACT 216-566-2917 (M-F 8 AM-5 PM CT)

H.M.I.S.HEALTH 1 •FLAMMABILITY 3REACTIVITY 0

Tviese ratings should be used only. is part ct v j l l y irroiementPd H . M . I . S . program.


SECTION I


TRADE NAME . . . . H I G H S O L I D S *

MANUFACTURER CODE I . D . 5 2 6 0 3 0

REVISED ON 1 1 / 0 7 / 9 6

T O T A L R E D A / D D R E N L

068 C 1 0M A N U F A C T U R E R C A G E 6 1 1 9 6 C O N T R A C T


INGREDIENT % BYWGT

CAS NO./NIOSH*


SARA313

VPmm Ho 6

20 DEG.CPPM MG/CU.M.

N A P T " A ( ? E T R O L E U M )H E A V Y AL <Y LAT EX" L ENE

. U M f Y D R O -:ARBON M I X T U R EP I G M E N T GRANGE 34

C R Y S T A L L I S E S : L C A

SOLVENT64741-65-7 M F R 100 525

P I G M E N T

SOLVENT

•330-2C- ̂ZE210000G

8032-32 -4016180000

•5793-73--

14808-60 - 7W7330000

TL V- TUA• L V - S T E L3SHA-PELO S H A - STEL

- FL 1

T LV- TUAC SHA-PEL

100150100150

.0100100

UF L

NONE E S T A B L 1

* L V - TUAO S H A - P E L

3 .0 .

-35655-35655

525525

SHED

10001000

8000 • N O N E E S T A B L I S H E D

MPPCF SKIN

E X P O S U R EF O R A N Y : M E P E R I O D

O F S E C T I O N 3 1 3

L F L = L O U E R F L A M M A B I L I T Y L I M I T P E R C E N TU F L - U P P E R F i A M M A B I L I T " L I M I T P E R C E N TS K I S - S K I M A B S O R P T I O N M U S T B E C O N S I D E R E D A S A R O U T E C FC - C E I - '. N G = A L L O W . E X P O S U R E L E V E L S H O U L D NOT BE E X C E E D E DM F R = M A N U F A C T U R E R R E C O M M E N D E D E X P O S U R E L I M I TS T E L = S H O R T T E R M E X P O S U R E L I M I TX - S A R A 3 1 3 = C H E M I C A L I S S U B J E C T T O R E P O R T I N G R E Q U I R E M E N T SOF : : • L E '. : : OF S . A . R . A . 40 CFR P A R T 372s : c s f » - N : o s H R E G I S - R Y OF -o xic E E F E c Ts OF C H E M I C A L S U B S T A N C E S NUMBER._______

1________________________SECTION III - HEALTH INFORMATION_________________________EFFECTS OF SHORT TERM OVEREXPOSURE

SWALLOWINGC a n c a u s e g a s t r o i n t e s t i n a l i r r i t a t i o n , n a u s e a , ^ n d v o m i t i n g . A s p i r a t i o n o fm a t e r i a l ' n t o l u n g m a y c a u s e c h e m i c a l p n e u m o n i t ^ s w h i c h c a n o e f a t a l .



SKINMay c a u s e d e f a t t i n q nnd • r r i t a t i o n of the s n i nEFFECTS OF REPEATED OVEREXPOSURE

R e p e a t e d a n d p r o l o n g e d o c c u p a t i o n a l o v e r e x p o s u r e t c c ' y s t a i l i n e b i l i c a m a yc a u s e s i i i c o s i s , a p r o g r e s s i v e l y d i s a b l i n g l u n g d i s e a s e .O v e r e x p o s u r e t o x y l e n e m a y c a u s e i n j u r y t o t h e l i v e r , n i d n e y s , a n db l o o d .» r e x i s t i n q r e s p i r a t o r y c o n d i t i o n s * » y b e a g g r a v a t e d D y e x p o s u r e ; oc r y s t a l l i n e s i l i c a .R e p o r t s h a v e a s s o c i a t e d p r o l o n g e d a n d r e p e a t e d o c c u p a t i o n a l o v e r e x p o s u r et o s o l v e n t s w i t h p e r m a n e n t b r a i n a n d n e r v o u s s y s t e m d a m a g e . I n t e n t i o n a lm i s u s e b y d e l i b e r a t e l y c o n c e n t r a t i n g a n d i n n a l i n g t h e c o n t e n t s m a y b e

SIGNIFICANT"LABORATORY3 DATA WITH POSSIBLE RELBVANCE TO HUMAN HEALTH.T h e i n t e r n a t i o n a l A g e n c y f o r R e s e a r c h o n C a n c e r c o n s i d e r s c r y s t a l l i n e

• • - - - • - >.,... i , m i t « . r i n v i r l p n e e o f c a r c i n o q e n i c i t y i n h u m a n s a n d s u f f i c i e n t

526030 06 PAGE 2DATE 11/07/96


SWALLOWINGe m e r g e n c y

INHALATIONR e m o v e t o f r e s hc i a i r e s p ' r a t i o n

f l u s h w i t h . a r g ei y . C o n t ' n u e f o

SKINR e m o v e c o n t a m i n aO b t a i n m e d i c a l a

NOTES TO PHYSICIANA n y t r e a t m e n t t hd i r e c t e d a t t h e

o o m o r p h y s i c i a n i m m e d i a t e l ya i r i m m e d i a t e l y . I f b r e a t h i n g h a s s t o

K e e p w a r m a n d q u i e t . G e t m e d i c a l a t

a m o u n t s c f w a t e r , l i f t i n g u p p e r a n a I cr a t . e a s t " 5 m i n u t e s . G e t m e d i c a l a t t

t e d c . o t h i n g . W a s h a f f e c t e d a r e a w i t ht t e n t i o n : ' i r r i t a t i o n p e r s i s t s .

a t m i g h t b e r e q u i r e d f o r o v e r e x p o s u r ec o n t r o t o f s y m p t o m s a n d t h e c l i n i c a l c o

p p e d , g i v e a r t i f i -t e n t i o n i m m e d i a t e l y

w e r . ' d s o c c a s i o n a le n t i on.

o a p a n a w a t e r .

h o u l d b en d i t ' o n s .

SECTION V - PHYSICAL DATABOILING RANGE 165 D E G . F . (

FREEZING POINT: - 5 0 0 E G . f . t

VAPOR PRESSURE: 5 mm Hg £

VAPOR DENSITY - e a v i e r t h a n a - i


WEIGHT LB./GAL. 3 . 2S P E C I F I C G R A V I T v

APPEARANCE & ODOR: . i g

VISCOSITY: NO

7 4 D E G . C . ) T O 4 1 4 D E G . F . C

4 5 D E G . C . )

6 8 D E G . F . ( 2 0 D E G . : . )

% VOLATILE BY VOLUME .9

VOC 3 . 2 1 Ib/gal lees water & NPRS* I 8

2 1 2 D E G . C . )

VOC• . 0

u i d , S o l v e n t o d o r

i n f o r m a t i o n f o u n d

6.39 Ib/gal solids 7 6

5 g/1 less waterC A L

7 g /1 nollds C A L C U L A T E D

SOLUBILITY:

PH:h t • i w a t e r

( S T D „ N I T S )

All Physical data determined at 68 DEC. F. (20 DEG. C.) 760 mm Hg• Negligibly Photochemically Reactive MaterialsVOC values reported here are verif ied by ASTM method D - 3 9 6 0


FT M4MABLE LIMITS ' . 0 % • 7 . 0f L A M M A B L E L I Q U I D C L A S S

3HPOINT

AUTOIGNITION

CORROSION RATE

80 D E G . f .

5 7 2 D E G . F . ( 3 0 0 D E G . C . )


( 2 7 D E G . C , )

DECOMPOSITION TEMP " 3 3 2

MAGNETISM no tN E T EXPLOSIVE W G T . N o t a p p l i c a b l e

EXTINGUISHING MEDIAU s e N F P A C l a s s 8 F i r e e x t i n g u i s h e r s ( c a r b o n d i o x i d e , a Ica l c r a l c o h o l f o a m ) d e s i g n e d t o e x t i n g u i s h ' ; a m m a b ! eT i e r * o a m • s p r e f e r r e d f o r . a r g e f i r e s .

UNUSUAL FIRE AND EXPLOSION HAZARDSD u r i n g e - n e r g e n c y c o n a • t • o n s , o v e r e x p o s u r e t c do com p o s t ;c a u s e a h e a l t h h a z a r a . S y m p t o m s m a y n o t b e ' T m e d i a t c . y• n e d i c a l a t t e n t i o n .J A R N t N G ' - L A M M A B L E .

SPECIAL FIRE FIGHTING PROCEDURESW a t e r m a y b e i n e f f e c t ' v e , b u t m * y b e u s e d t o c o o l e x p o sp r e v e n t p r e s s u r e b u i l d - u p a n d p o s s i b l e a u t o - i g n i t i o n o re x p o s e d t o e x t r e m e h e a t . I f w a t e r i s u s e d , ' o g n o z z l e s

C A L C U L A T E D

C E G . F . ( 1 0 0 0 D E G . C . )

a p p I i c a b I e

I p u r p o s e d r y c h e m i• q u i d f i r e s . P o I y -

o n c - o d u c t s m a ya p p a r e n t . O b t a i n

e d c o n t a i n e r s t oe x p l o s i o n w h e n

a r e p r e f e r a b l e .


STABILITY

' TOCONDITIONS tO AVOIDA v o i d e x c e s s i v e h e a t ( > 1 1 5 F ( 4 6 C ) a n d s o u r c e s o f

INCOMPATABILITY (MATERIALS TO AVOID)S t r o n g a c i d s o r a l k a l i n e m a t e r i a l s

HAZARDOUS DECOMPOSITION PRODUCTSB u r n i n g , - n c l u d i n g w h e n h e a t e d b y w e l d i n g o r c u t t i n g wc a r b o n m o n o x i d e a n d c a r b o n d i o x i d e . 'P i g m e n t s u s e d i n t h i s p r o d u c t m • y b e g i n t o d e c o m p o s e a t3 9 2 a e g . : ( 2 0 0 C ) t o p r o d u c e m o n o a z o d y e s , a n d a t e v e nt o p r o d u c e 3 3 ' - d i c h i o r o P e n z i d i n e . a s u s p e c t h u m a n c a r e

HAZARDOUS POLYMERIZATION H >- iW i l l n o t o c c u r

CONDITIONS TO AVOIDN o n e u n o w n

n i t i o n .

i l l p r o d u c e s m o k e ,

t e m p e r a t u r e o v e rh i g h e r t e m p e r a t u r e s

i n o g e n .

"L SECTION VIII - ENVIRONMENTAL INFORMATIONSTEPS TO BE TAKEN IF MATERIAL IS RELEASED OR SPILLED

5 2 6 0 3 0 0 6

SECTii(!i!.lllBLiIllSTEPS TO BE TAKEN IF MATERIAL IS RELEASED OR SPILLED

s u r f a c e s , a n a s o u r c e s c ' e l e c t r i c a l , s t a t i c o r f r • c tD i k e a n a c o n t a i n s p i l l w i t h i n e r t m a t e r i a l ( e . g . s a n. i q u i a s t o c o v e r e d m e t a l c o n t a i n e r s f o r r e c o v e r y o r* i t h i n e r t a b s o r b e n t . Use o n l y n o n - s p a r k i n g ; o a i s .n a t c r i a t s i n c o v e r e d m e t a l c o n t a i n e r s f o r d i s p o s a l .o f s e w e r s , s t r e a m s , , i nd g ^ o u n d w a t e r w i t h s p i l l e d m a ta b s o r b e n t .

WASTE DISPOSALJ ' s o o s e • • a c c o r d a n c e w i t h f e d e r a l , s t a t e d n a j c a i

RCRA CLASSIFICATION' h i s p r o d u c t , i * d i s c a r d e d d i r e c t l y , w o u l d b e c l a s sD a s e d e n i t s i g n i t a b i l ' t y c h a r a c t e r i s t i c , i . e . h a s < ia e q . ; . ( 6 0 d e g . C ) o r l e s s . The p r o p e r R C R A r . a s s • f ' c

ENVIRONMENTAL HAZARDSs o n e « ; n o w . n

PAGE 3DATE 11 /07 /96

mil': o n a i sa , e a r :d i s p o s aP l a c e aP r e v e n te r i a I c

r e 9 u i a t

f i e d af l a s h

a t i o n M

p a r k s ) .h ) . T r a n s f e rI , o r r e m o v eo s o r b e n t d i k i n g

c o n t a m i n a t i o nr u s e d

i o n s .

h a z a r d o u s u 3 § t fp o i n t o f 1 4 0o u l d b e 0 0 0 1 .

iSECTION IX - PERSONAL PROTECTION INFORMATION

RESPIRATORY PROTECTIONP r O P C r s e l e c t i o n o f r e s p i r a t o r y p r o t e c t i o n d e p e n d s u p o n m a n• n c i u a i n g d u r a t i o n / l e v e l o f e x p o s u r e and c o n d i t i o n s of u s e .e x p o s u r e t o o r g a n i c c h e m i c a l s s u c h a s t h o s e c o n t a i n e d i " . t hr o t r e q u i r e t h e u s e o f r e s p i r a t o r y p r o t e c t i o n i f u s e d i n w ea r e a s . ! n r e s t r i c t e d v e n t i l a t i o n a r e a s a N I 0 S H a p p r o v e d c h er e s p i r a t o r m a y b e r e q u i r e d . U n d e r c e r t a i n c o n d t i o n s , s u c hm e c n a n i c a l p r e f i l t e r m a y a i s o b e r e q u i r e d . I n c o n f i n e d a r e aM S M A a p p r o v e d a i r s u p p l i e d r e s p i r a t o r . I f t h e T L V ' s l i s t e da r e e x c e e d e d u s e a p r o p e r l y f i t t e d N I O S M / M S H A a p p r o v e d • e s pa p p r o p r - a t e p r o t e c t ' 0 - f a c t o r . R e f e r t o C S M A £ 9 C F R ' 9 l C . ' 3P r o t e c t i o n " , a n d " < ? e s p ' r n t o r y P r o t e c t i o n A M a n u a i A n d ' - j j i d e: " d u s t ' • a . H y g i e n e A s s c c . "

VENTILATION:- r o v i a e g e n e r a l d i l u t i o n ana * o c a 1 e x h a u s t . e n t i . d t i o n • r, si ~ a i: a t t e - n : o < e e D , c " c c n : ' . i T i o n s of h a z a - d o u s i n g r e d i e n t s

S e c : • o n ; ; c e i c » t ie . . w e s t e n o o s u r e l i m i t •. t a t e a . R e m o v e c^ ' c d o c t s : - i a t a r e g e n e r a t e d r , n e n w e l d i n g , c u t t i n g , o r o r a z i. o a t e d » i t n t h i s p r o d u c t . 3 e t e - t o " I n d u s t r i a l v e n t i . a t i o nR e c o m m e n d e d P r a c t i c e " H C G l H

HAND PROTECTION- e a r a o o r c p r i a t e i m p e r t r e a o l c g l o v e s ( N o r t i - S ' l v e r S h i e l d ! .

EYE PROTECTION. . e a r •. a • e t v s n e c . J C ; c s

OTHER PROTECTIVE EQUIPMENTS o t I ' n e l y t o b e n e e d e d .

y f a c t o r sI n g e n e r a l

i s p r o d u c t m a y1 1 v e n t i l a t e dm i c a l c a r t r i d g ea s s p r a y i n g , as u s e a N I O S H /i n S e c t i o n 1 1i r a t o r w i t h a n• i " R e s p i r a t o r yl i n e , A m e r i c a n

u f f • c i e n t v o l u m e- ' s t C d in

e c c m p o s i t i o nn g o b j e c t s

A M a n u a l o f

SECTION X - SPECIAI* PRECAUTIONSPRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGB

D o n o t s t o r e a b o v e ' 1 5 d e g . F ( 4 6 d e g . C ) s t o r e l a r g e q u a n t 1

c o m o i i a n c e w i t h O S H A J 9 C F R 1 9 1 0 . 1 0 6 .OTHER PRECAUTIONS

; c n o t t a k e - n t e r n a l l y . C l o s e c o n t a i n e r a f t e r e a c h u s e .J o r o t b ' e a t h e s a n d i n g d u s t ,t m o t y c o n t a i n e r s n u s t " o t b e w a s h e d a n d r e - u s e d ' o r o n y p u rC o n t a i n e r s s n o u l d b e g r o u n d e d a n d b o n d e d t o t h e r e c e i v i n g c7 3 n 0 t « e l d , D r a z e o r c u t o n e m p t y c o n t a i n e r .^ f v e r ^ s e p r e s s u r e t o e m o t v . D r u m i s n o t a p r e s s u r e v e s s e l

t i e s i n

p o s e .o n t a i n e r .


SBCTION XII - TRANSPORTATION DATAP R O P E R S H I P P I N G M A M E ( A R T I C L E ) P A t M T D O T M A R K I N G T H

C O T C L A S S I F I C A T I O N F L » M M » B L | L I Q U I D E M E R G E N C Y A C C I

O O T . A 8 E L F L A M M A B l , ^ & P R O C E

C O T ^ L A C A R C F L A M M A B L EP R E C A J T ; O N S * c B E T A K E N I N ' R A N S P O R T A T I O N. ; H I T E D ^ U A N T I ' V : > < o A E R O S O L P R O P E L L E N T - .D . 0 . ' . : . 3 . N U M B E R J N 1 2 6 3 R . Q . N O . u . S

J N I T : C N T A : N E R o . o . - . U N1 P 1 N T M E T A L 2 N 1 N 1l O U A R T M E T A L 2 N 1 N 1

G A L L C N M E T A L 2 N 1 N 1• i G A L L O N M E T A L 1 / C 1 A 1

1 7 k - 1 4 7

D U R E S

S 0 t^ O S T A l

I S S I D E U P

D E N T P R E C A U T I O N S

S E E A B O V E

a p p l i c a b l eF O R B I D D E N

3H101si

' i 33Mi

• 1 a a i4 s e i e c A i o j c $ icS L 1U3U.1JCO03 SJIC

Q 0 H d 3 H 1 JC 3SH 3 J V S )si i: ' a 3 s n 3Hi A a c 3 ̂

ONV

j o 1 e w siyj jo uoijcjcao^d,- 'C1U3UUOJIAJ3 puc A ; o j rSNOIilQNOD 3 H J. 3NIW>^130

_ j j o , D • a iojejodjc^ a

N D I 1 V C I 1 8 C3SP. ONV SNOONC:

3 h i 33NIS3SnQllldWI

Q3NI»1BO 3E0 C3SS3«dX3

OIIWWSOJN: SIHI jo ssn3M 3H1 JjC W1WO SIHi j C A3W8n33V 3HIMVn ON '318VI13a 38 C. 0 3 A 3 I 1 3 8 SI NOIlVHdOJN! 3Hi STIHr '31VM39 01 Q3H3QISNC2 V1VG NC Q3SV8 S! NI3nn a3MVH23 N 0 1 I V W N 0 J N !

S33IAS3S N o : i v w s o j

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c :S

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PRATT i LAMBERT 316-733-1361Industrial Coatings Div.101 Prospect AvenueCleveland, OH 44115



"hese ratings snould be used onlyas part of f u l l y implemented H . M . I . S . program.

"ORATE CONTACT 216-566-2917 (M-F 8 AM-5 PM CT)


SECTION I

PRODUCT CLASS A ^ K Y D , M E D I U M - L O N G

TRADE NAME .... H I G H S O L I D S * * * * H A R B O R B L U E

MANUFACTURER CODE I . D . ;; 2 2 C 2 8 25


REVISED ON

A / D D R U M E N L

1 1 / 0 7 / 9 6

| SECTION II - HAZARDOUS INGREDIENTS

INGREDIENT % BYWGT

CAS NO./NIOSH*


SARA313

VPram Hg ®

20 DEC.C

> , * P T HA ( P E T R O L E U M )h E A V Y A ^ Y t A T E

C I C X I D E• ; TAN i

P E T R O L E U M MCARSON M I X T U R EP I N E o:.

S O L V E N Ti 741 •65 - 7 MFR

PPM MG/CU.M.

100 525

• 3463-67-7 ; L V - T U AP I G M E N T XR227503G O S H A - P E L

8032-32-i T L V - T U AS O L V E N T 0 1 6 1 8 0 0 0 0 O S H A - P E L

100100

5 2 5525

S O L V E N T8000- ' . 1 NONE E S T A B L I S H E D

MPPCF SKIN

s <~ -M F« T

ICRES

0

NE

LA-S

;

R;H

;M

iAT LS

SNAS3E

K I N A B S O R P T I O N M U S T B E C O N S I D E R E D A S A R O U T E C F E X P O S U R EG = A L L O W . E X P O S U R E - E V E L S H O U L D NOT 8E E X C E E D E D FOR ANY T IN U F A C T U R E R R E C O M M E N D E D E X P O S U R E L I M I TH O R T T E R M E X P O S U R E L I M I T1 3 - C H E M I C A L I S S U B J E C T T O R E P O R T I N G R E Q U I R E M E N T S O F S E C T

1 ! I O F S . A . R . A . - 0 C F R P A R T 3 7 2• J I O S H R E G I S T R Y O F T O X I C E F F E C T S O F C H E M I C A L S U B S T A N C E S N U

M

I

M

E

0 N

B E

P E R

3 1

R .

I

3

0 D

SECTION III - HEALTH INFORMATIONEFFECTS OF SHORT TERM OVERKXPOSURE

SWALLOWINGC a n c a u s e g a s t r o i n t e s t i n a l i r r i t a t i o n , n a u s e a , .ind v o m i t i n g . A sT a t e r i . i l ' " . t o I j n g r a y c a u s e c h e m i c a l p n e u m o n i t i s w h i c h c a n b e

P*ia

rtaa

tI

i 0 n 0 f

INHALATION" a y c a u s e n o s e o r t h r o a t i r r i t a t i o n . H i g h c o n c e n t r a t i o n s m a y c ac e n t r a l ^ e r v o u s s y s t c T I a e p r e s s i o n c h a r a c t e r i z e d b y h e a a a c n e s , Jn a u s e a . i n a c o n t u s i o n .

uis e a c u t

se*

EYEway . a u b e eye ' r r i t a t i c n .

SKINM a y c a u s e d e f a t t i n g a n a ' r r i t a t i o n o f t h e s k i n .

EFFECTS OF REPEATED OVEREXPOSURER e p o r t s h a v e a s s o c i a t e d p r o l o n g e d a n d r e p e a t e d o c c u p a t i o n a l o v eT 3 s o l v e n t s w i t h p e r m a n e n t b r a i n a n d n e r v o u s s y s t e m d a m a g e . ! n t- n i s u s e b y d e l i b e r a t e l y c o n c e n t r a t i n g a n d i n h a l i n g t h e c o n t e n t sl a r m f u l o r f a t a l .

rem

ena

XtyPio0b

sneuarIe

SIGNIFICANT LABORATORY DATA WITH POSSIBLE RELEVANCE TO HUMAN HEALTH.' i t a n i u m d i o x i d e I S N O T l i s t e d a s a p o t e n t i a l c a r c i n o g e n b y t h eT o x i c o l o g y P r o g r a m , t h e I n t e r n a t i o n a l A g e n c y f o r R e s e a r c h o n C ao r A . C . G . I . H . T i t a n i u m d i o x i d e i n a 2 4 - m o n t h i n h a l a t i o n s t u d y w' e v e a I e d a s i g n i f i c a n t • n c r e a s e in b e n i g n and m a l i g n a n t l u n g tug r o u p e x p o s e d t o 2 5 0 m g / M 3 r e s p i r a b l e T i 0 2 d u s t . A t l o w e r e x p o s ut i i s s i g n i f i c a n t e f f e c t w a s n o t o b s e r v e d . T h e n o r m a l c l e a r a n c e: i t h e i u n g s m a y h a v e D e e n o v e r w h e l m e d a t t h e 2 5 0 m g / M 3 e x p o s u r et h i s m a y h a v e c o n t r i b u t e d t o t h e t u m o r f o r m a t i o n . T h e s e r e s u l t sb e d i r e c t l y r e l e v a n t t o t h e w o r k p l a c e w h e r e o c c u p a t i o n a l e x p o s u• i r e o o s e r v e d . A t t h e T L V t h e T i 0 2 m a n u f a c t u r e r c o n c l u d e s t h a t ts i g n i f i c a n t h a z a r d f o r m a n .

nimrm

rh

NCt0eeImee

aehr

cea

r

tr

sIhVre

i

r

eae

i

o

aiVnInmi

n0tnei,ois

aSsIstt

IH A

t hs ,m sa nsn o

e

d

SECTION IV - FIRST AID AHt> EMERGENCY PROCEDURESSWALLOWING

! f s w a l l o w e d d o n o t i n d u c e v o m i t i n g . C a l l p o i s o n c o n t r o l c e n t e re m e r g e n c y r o o m o r p h y s i c i a n i m m e d i a t e l y .

n o s p i t a I'"HALATION

R e m o v e t o f r e s h a i r i m m e d i a t e l y . I f b r e a t h i n g h a s s t o p p e d , g i v e a r t i f i -c i a l r e s p i r a t i o n . K e e p w a r m a n d q u i e t . G e t m e d i c a i a t t e n t i o n i m m e d i a t e l y

.EF l u s h w i t h l a r g e a m o u n t s o f w a t e r , l i f t i n g u p p e r a n d l o w e r l i d s o c c a s i o n a l

522028 25PAGE 2DATE 11/07/96


EYEi y C o n t i n u e f o r a t i c a s t m i n u t e s . e t - i c a i e a i a t t e n t

R e m o v e c o n t a m i n a t e d c l o t h i n g . W a s h a f f e c t e d a r e a w i t h s o a p0 b t a • ̂ m e d i c a l a t t e n t i o n i f i r r i t a t i o n p e r s i s t s .

iS TO PHYSICIANA n y t r e a t m e n t t h a t i r i g h t t c r e q u i r e d f o r o v e r e x p o s u r e s h o u l d b ed ' r c c t c a a t t h e c o n t r o l o f s y m p t o m s » n d t h e c l i n i c a l c o n d i t i o n s .

o n .

a n d w a t e r .


FREEZING POINT:

VAPOR PRESSURE :

VAPOR DENSITYEVAPORATION RATE

S l o w e r t h a n d i c t h y l e t h e r .

' 6 5 D E G . f . ( 7 4 D E G . C . ) 1 0 4 1 4 D E G . F . C 2 1 2 D E G . C . )

- <> 0 D E G . F . ( - 4 5 D E C . C.)

1 mm Hg a 68 D E G . F . ( 2 0 O E G . C.)

H e a v i e r t h a n a i r . % VOLATILE BY VOLUME 53

VOC 3.44 lb/gal less water & MSB* - 1 3 g/1 less water C A L

WEIGHT LB . /GAL . 8.1 VOCS P E C I F I C G R A V I T Y 1 . 0

APPEARANCE & ODOR : . i q u i a , S o l v e n t o d o r

VISCOSITY : N o i n f o r m a t i o n f o u n d

7 . 3 6 lb/gal solids

SOLUBILITY :

PH:

8 8 3 g / 1 solids C A L C U L A T E D


4 - 7 C S T D U N I T S )

All Physical data determined at 68 DEG. F. (20 DEG. C.) 760 nun Hg* Negligibly Photochemical ly Reactive MaterialsVOC values reported here are verified by ASTM method D-3960

SECTION VI - FIRE AND EXPLOSION DATANFPA FLAMMABILITY CLASSIFICATION F L A M M A B L E L I Q U I D C L A S S ; C

FLASHPOINT 9 3 0 E G . F , ( 3 4 D E G . C , ) C A L C U L A T E D

AUTOIGNITION 5 7 2 D E G . F . ( 3 0 0 D E G . C . )

CORROSION RATE S o t a p p l i c a b l e

V - EXPLOSIVE W G T . N o t a p p l i c a b l e

DECOMPOSITION TEMP

MAGNETISM' 8 3 2 C E G . F . M O O O D E G . C . )


.NGUISHING MEDIAj se s F P A C . a s s B F i r e e x t i n g u i s h e r s ( c a r b o n d i o x i d e .c a l o r a l c o h o l f o a m ) d e s i g n e d t o e x t i n g u i s h f , a m m a D i c

f o a m i s p r e f e r r e d f o r l a r g e f i r e s .

i l l n u r o o s e d r y c h e m i. i q u i u f i r e s . P o l y -

m e r f o a m i s p r e f e r r e d f o rUNUSUAL FIRE AND EXPLOSION HAZARDS

D u r i n g e m e r g e n c y c o n d i t i o n s , o v e r e x p o s u r e t o d e c o m p o s t i o n p r o d u c t sc a u s e a h e a l t h h a z a r d .

m a yS y m p t o m s m a y n o t b e i m m e d i a t e l y a p p a r e n t . O b t a i n

m e d i c a l a t t e n t i o n .W A R N I N G ' F L A M M A B L E .SPECIAL FIRE FIGHTING PROCEDURESw a t e r m a y b e i n e f f e c t i v e , b u t m a y b e u s e d t o c o o l e x p o s e d c o n t a i n e r s t op r e v e n t p r e s s u r e b u i l d - u p a n d p o s s i b l e a u t o - i g n i t i o n o r e x p l o s i o n w h e ne x p o s e d t o e x t r e m e h e a t . I f w a t e r i s u s e d , ' o g n o z z l e s a r c p r e f e r a b l e .





HAZARDOUS DECOMPOSITION PRODUCTSB u r n i n g , i n c l u d i n g w h e n h e a t e d b y w e l d i n gc a r b o n m o n o x i d e a n d c a r b o n d i o x i d e .



( 4 6 C ) a n d s o u r c e s o f i g n i t i o n .

c u t t i n g , i l l p r o d u c e s m o k e ,


K e e p s p e c t a t o r s a w a y . E l i m i n a t e a l l i g n i t i o n s o u r c e s ( f l a m e s , h o ts u r f a c e s , a n d s o u r c e s o f e l e c t r i c a l , s t a t i c o r f r i c t i o n a l s p a r k s ) .D i k e a n d c o n t a i n s p i l l w i t h i n e r t t i a t e r i a l ( e . g . s a n d , e a r t h ) . T r a n s f e r. i q u i d s t o c o v e r e d m e t a l c o n t a i n e r s f o r r e c o v e r y o r d i s p o s a l , o r r e m o v e* i t n ' ri e r t a b s o r b e n t . Use o n l y n o n - s p a r k i n g t o o i s . P l a c e a o s o r b e n t d i k i n gm a t e r i a l s i n c o v e r e d m e t a l c o n t a i n e r s f o r d i s p o s a l . P r e v e n t c o n t a m i n a t i o no f s e w e r s , s t r e a m s , a n d g r o u n d w a t e r w i t h s p i l l e d m a t e r i a l o r u s e da b s o r b e n t .

522028 25

SECTION VIII - ENVIRONMENTAL INFORMATION;

PAGE 3DXTfi Il/u")j9£

(CONTINUED)WASTE DISPOSAL

D i s p o s e ' " a c c o r d a n c e w i t h f e d e r a l , s t a t e a n a l o c a l r e g u l a t i o n s .RCRA CLASSIFICATION

T i i s p r o d u c t , i f d i s c a r d e d d i r e c t l y , w o u l d b e c l a s s i f i e d a h a z a r d o u s w a s t eb a s e d o n i t s i g n i t a c i l i t y c h a r a c t e r i s t i c , i . e . h a s a f l a s h p o i n t o f 1 i 0a e q . f . ( 6 0 d e g . C ) or l e s s . The p r o p e r R C R A c l a s s i f i c a t i o n w o u l d be 0 0 0 1 .

.RONMENTAL HAZARDSS o n e k n o w n


P r o p e r s e l e c t i o n o • " e s p i r a t o r y p r o t e c t i o n d e p e n d s u p o n m a n y f a c t o r s- D e l u d i n g d u r a t i o n / l e v e l o f e x p o s u r e a n d c o n d i t i o n s o f u s e . I n g e n e r a le x p o s u r e t c o r g a n i c c h e m i c a l s s u c h a s t h o s e c o n t a i n e d i n t h i s p r o d u c t m a y- a t - e q u i r e t h e u s e o f r e s p i r a t o r y p r o t e c t i o n i f u s e d i n w e l l v e n t i l a t e du r e a s . :n r e s t r i c t e d v e n t i . a t i o n a r e a s a N I 0 S H a p p r o v e d c n e m i c a I c a r t r i d g e- e s p i r o t o r T i a y b e ~ e a u i r e a . U n d e r c e r t a i n c o n d i t i o n s , s u c h a s s p r a y i n g , an e c n a n i c a l p r e f i l t e r iiay a i s o b e r e q u i r e d . I n c o n f i n e d a r e a s u s e a N I 0 S H /H S H A a p p r o v e d a i r s u p p l i e d r e s p i r a t o r . I f t h e 7 L V ' s l i s t e d i n S e c t i o n 1 1a r e e x c e e d e d u s e a p r o p e r l y f i t t e d N I O S H / M S H A a p p r o v e d r e s p i r a t o r w i t h a na p p r o p r i a t e p r o t e c t i o n f a c t o r . R e f e r t o O S H A 2 9 C F R 1 9 1 0 . ' 3 4 " R e s p i r a t o r ys r o t e c t i o r i " , a n d " R e s p i r a t o r y P r o t e c t i o n A M a n u a l A n d G u i d e l i n e , A m e r i c a nI n d u s t r i a l H y g i e n e A s s o c . "

VENTILATIONP r o v i d e g e n e r a l d i l u t i o n a n d l o c a l e x h a u s t v o n t ' l a t i o n I P s u f f i c i e n t v o l u m ea n d p a t t e r n t o k e e p c o n c e n t r a t i o n s o f h a z a r d o u s i n g r e d i e n t s . i s t e d i nS e c t i o n ! ' . b e l o w t h e l o w e s t e x p o s u r e l i m i t s t a t e d . R e m o v e d e c o m p o s i t i o np r o d u c t s t h a t a r e g e n e r a t e d w h e n w e l d i n g , c u t t i n g , o r b r a z i n g o b j e c t sc o a t e d « i t h t h i s p r o d u c t . R e f e r t o " I n d u s t r i a l V e n t i l a t i o n - A M a n u a l o fS e c c n m e r d e d P r a c t i c e " A C G I H

HAND PROTECTION: o i v e n t I T ; p e r m e a b l e 3 , e v e s a ' e r e q u i r e d > : > r r e p e a t e d o r p r o l o n g e d c o n t a c t .

EYE PROTECTION. e a r • . a t e t v s p e c t a c l e s .

OTHER PROTECTIVE EQUIPMENTsot . •. K e i y to be needed._________ _

| SECTION X - SPECIAL PRECAUTIONSPRECAUTIONS

C 0->

n o tm o t i

TO BEs t o r

a n c e

TAKENew 1

at

bh

0IN HANDLING AND STORAGEv e '15O S H A 2 9 C

d e gF R 1

. F ( 4 6 d e g . C ) s t o r e9 1 0 . 1 0 6 .

I a r g e q u a n t i t i e s i n

OTHER PRECAUTIONS3 0r mI aD o•j e

n o tP t yn t a i

v e r

! a K ec o n t an e r s

„ s e D

1i ns h

r e

neobs

tru

s

esI

u

r n a I I y .m u s t n o

d DC g r o

re • o en

SECTION

C I 0t bu n d

P t y

XI

s e c o n t a i n e r a f t e r ee w a s h e d a n d r e - u s e de d a n d b o n d e d t o t h e

D r u m i s n o t a p r e

- OTHER INFORMATION

a cfr

s s

h u s e .o r a n y p u r p o s e .e c e i v i n g c o n t a i n e r .

u r e v e s s e l .

SECTION XII - TRANSPORTATION DATAP R 0 P t

C O T -

: c TDO' ;

R S

A S

A B E

. A C

H I P P I N G N A M E ( A R T I C L E )

S ! F I C A T I C N

L

A R 0

P A I N T

• L A H M A 8 L E L I Q U I D

F L A M M A B L EF L A M M A B L E

DOT M

' M E R G

.-. C R 0

A R

E N

C E

K I N

C Y

C U R

G

A

f

T H I S

C C I D E

S i L

S I D

N T P

E A B

E UP

R E C A U T

0 V E

I O N S

D

U

111",

5

F

I M 1 T E D Q U A N T I T Y :.0.'. i . D . N U M B E R

N I T C O N T A I N E R

P I N T M E T A LQ U A R T M E T A LG A L L O N M E T A LG A L L O N M E T A t

5 G A L L O N M E T A L

: B E R B O A R O B O X

N 0J N '263

0 . 0 . T .

2 N2 N2 N1 7 C1 7 K1 7 C1 7 K: 2 a

A E R O S O L P R O P E L L E N T :R . 0 . N 0 . U . S .

U N

1 N 11 N 11 N 11 A 11 A 21 A 11 A24 G

N o t a p p l i c a b l eP O S T A L F O R B I D D E N

( x o P L A S T I C C O N T A I N E R S W I L L B E A U N I T C O N T A I N E R O N L Y U S E D F O R i C O M P O N E N T o fA K I T U N I T C O N T A I N E R ) .

GOVERNMENT SPEC. PRODUCTS /GSA PAGE 4522028______2_5______________________________________________________DATE 11/07/96


H I S ; S T C C E R T I F Y T H A T ' H I S I T E M I S H A Z A R D O U S A N D I N F O R M A T I O N S T A T E D I S T OB E S T O F O U R K N O W L E D G E , C O R R E C T .

R E G U L A T O R Y : >, F 0 R M A T I 0 N S E R V I C E S

• H E I N F O R M A T I O N C O N T A I N E D H E R E I N i s B A S E D O N D A T A C O N S I D E R E D T O B EA C C U R A T E . W H I L E T H E I N F O R M A T I O N I S B E L I E V E D ' C B E R E L I A B L E , N O W A R R A N T Y I SE X P R E S S E D O R I M P L I E D R E G A R D I N G T H E A C C U R A C Y O F T H I S D A T A O R T H E R E S U L T S T O3 E O B T A I N E D F R O M T - E U S E T H E R E O F . S I N C E * H E o S E O F T H I S I N F O R M A T I O N A N D T MC O N D I T I O N S A N D U S E C F T H I S P R O D U C T A R E C O N T R O L L E D B Y T H E U S E R , I T I S T H E- S E R ' S O B L I G A T I O N ' 0 D E T E R M I N E T H E C O N D I T I O N S C F S A F E U S E O F T H E P R O D U C T .

" h e C o r p o r a t e S a f e t y a n d E n v i r o n m e n t a l A f f a i r s D e p a r t m e n t i sr e s p o n s i b l e f o r t i e p r e p a r a t i o n o f t h i s M a t c r i a l S a f e t y D a t a S h e e t .

PRATT & LAMBERT 316-733-1361Industrial Coatings Div.101 Prospect AvenueCleveland, OH 44115DOT EMERGENCY CHEMTEL (800)255-3924 (24hrs)INFORMATION PHONE NO. 216-566-2902 (M-F 8 AM-5 PM CT)CORPORATE CONTACT 216-566-2917 (M-F 8 AM-5 PM CT)

H.M.I.S.HEALTH 2*FLAMMABILITY 3REACTIVITY 0

These r a t i n g s snould be used only. i s part o f f u l l y implemented H . M . I . S . program.


SECTION

PRODUCT CLASS A L K Y D , S H O R T B L E N DTRADE NAME 3 . 5 V O C . S X J M . B L U E D R U M E N A M E L

MANUFACTURER CODE I .D. 5 0 2 5 1 8 63

REVISED O N 1 1 / 0 7 / 9 6

T R I C H L O R O E T H A N E

8 0 1 0 -H A N J F A C T ' J R E R C A G E * 6 1 1 9 6 C O N T R A C T

SECTION II

INGREDIENT % BYWGT

i S O B U T Y L A L C O H O LS O L V E N T

A L I P H A T I C" Y D R O C A R B O N S O L V E N T

• Y I E S E 5S O L V E N T

E T H Y L B E N Z E N E < 5S O L V E N T

; E N T S A P T H A , H E A V Y, j«AT I C S O L V E N T

T I T A N IUM D I O X I D EP I G M E N T

M E T H Y L N • P R O P Y LK E T O N E S O L V E N T

S - B U - Y : A C E T A T ES O L V E N T

' , 1 , 1 T R I C H L O R O - JOE T H A N E S O L V E N T

D I E T H Y L E N E E T H E R < 1S O L V E N T

CAS NO., NIOSH*

7 8 - 8 3 - 1NP9625000

6 4 7 4 2 - 8 9 - 8N / A

' 3 3 0 - 2 C - 7Z E 2 1 G O C O O

1 0 0 - 4 1 - 4: A Q 7 C C C C C

6 4 7 4 2 - 9 4 - 5

1 3 4 6 3 - 6 7 - 7XR2275000

1 0 7 - 8 7 - 9SA7875000

• 2 3 - 8 6 - 4A F 7 3 5 2 0 0 0

7 1 - 5 5 - 6

1 2 3 - 9 1 - 1

- HAZARDOUS INGREDIENTSALLOWABLE SARA VP

EXPOSURE LEVEL 313 mm Hg 920 DEG.C

PPM MG/CU.M. MPPCF SKIN


.FL 1.0

M F R

T L V - T W AT L V - S T E LO S H A - P E LO S H A - S T E L

LFL 1 .0

T L V- TUAT L V - S T E LO S H A - P E LO S H A - S T E L

LFL 1 .0

NONE

T L V - T W AO S H A - P E L


L F L 1 . 5

T . V - T U AT . V - S T E LO S H A - P E LO S H A - S T E L

L F L 1 . 7


LFL 8 .0


LFL 2 .0

5050

U F L

400

100150100150

U F L

100125100125

U F L

E S T A B L I

200250200250

U F L

150200150200

U F L

350450J50450

UFL

2525

UFL

150150

• • .0

4 3 56 5 5435655

7. 0

4 3 55 4 54355 4 5

6. 7

S H E D

1010

700875700875

3 . 2

7 ' 0950710950

' .6

19002 4 5 019002450

1 1 . 0

9090

2 2 . 2

10

12

x 5

X 1

S K I N

27

10

X 100

S K I N X 40SKI N

. F L = L O W E R F L A M M A B 1 L I T Y L I M I T P E R C E N TU F L = U P P E R F L A M M A B I L I T T L I M I T P E R C E N TS K I N = S K I N A B S O R P T I O N M U S T B E C O N S I D E R E D A S A R O U T E O F E X P O S U R E: - C E I L I N G = A L L O W . E X P O S U R E L E V E L S H O U L D N O T B E E X C E E D E D F O R A N Y T I M E P E R I O D« F R = M A N U F A C T U R E R R E C O M M E N D E D E X P O S U R E L I M I TS T E L = S H O R T T E R M E X P O S U R E L I M I T< - S A R A 3 ' 3 - C H E M I C A L I S S U B J E C T T O R E P O R T I N G R E Q U I R E M E N T S O F S E C T I O N 3 1 3O F - : T L E i i i O F S . A . R . A . 4 0 C F R P A R T 3 7 2> • I 0 S H » = N 1 0 S H R E G I S T R Y O F T O X I C E F F E C T S O F C H E M I C A L S U B S T A N C E S N U M B E R .

SECTION III - HEALTH INFORMATIONECTS OF SHORT TERM OVKREXPOSUREFALLOWING

C a n c a u s e g a s t r o i n t e s t i n a l i r r i t a t i o n , n a u s e a a n d v o m i t i n g . A s p i r a t i o n o f

502518 63PAGE 2DATE 11/07/96

SECTION III - HEALTH INFORMATION; (CONTINUED)iRMA-J

SWALLOWINGm a t e r i a

•••NHALATION1 1 1 - T r i

i n t o l u n g n a y c a u s e

a ti

.11 ay o c c u ri n c o o r d i n a tc a u s e a n e s t h e sM a y c a u s e n o s e

c h l o r o e t h a n e m a yc o n c e n t r a t

o n . c o n f u s

c a u s e

c h e m i c a l p n e u m o n i t i s w h i c h

i r r i t a t i o n o f t h e n o s e a n d t h

c a n b e f a t a l .

c e n t r an a u s e a

EYEM a y

SKINM a y c

EFFECTS OF0 v e r eb l o o dR e p o rt o s o

n e r v o u sand c o n f

r t h r o as y s t e ms i o n .

c a u s e i r r i t a t i o n o f t h e n o s e a n d t hi o n s a b o v e 1 0 0 0 p p m . S y m p t o m s w o u l d io n a n d d r o w s i n e s s . V e r y h i g h c o n c e n t

t i r r i t a t i o n . H i g h c o n c e n t r a t i o n s m ad e p r e s s i o n c h a r a c t e r i z e d b y h e a d a c h e

r o a t . N a r c o s i sn c I u a er a t i o n s m a y

y c a u s e a c u t es , d i z z i n e s s .

c a u s e s e v e r e e y e

a u s e d e f a t t i n g a n dREPEATED OVEREXPOSURE

i t a t i o n .

i r r i t a t i o n o f t h e s k i n .

p o s u r e t o x y l e n e n a y c a u s e i n j u r y t o t h e n i a n e y s a n dt s h a v e a s s o c i a t e dI v e n t s w i t h p e r m a n

m i s u s e b y d e l i b e r a t e l yh a r m f u l o r f a t a l .

SIGNIFICANT LABORATORY DATA WITHT i t a n i u m d i o x i d e I ST o x i c o l o g yc r A . C . Gr e v e a l e d

P r o gH . TS

a mN O T• h e

i t a n i u mg n i

g r o u p e x p o s e d t ot h i s s i g n i f i c a n t

t h e l u n g s m a yo ft hb e3 r

s t3 1t h

i c a n t2 5 0 m g /e f f e c th a v e D

p r o l o n g e d a n d r e p e a t e d o c c u p a t i o n a le n t b r a i n a n d n e r v o u s s y s t e m d a m a g e ,c o n c e n t r a t i n g a n d i n h a l i n g t h e c o n t e

POSSIBLE RELEVANCE TO HUMAN HEALTH,i i s t e dI n t e r n a

d i o x i d ei n c r e a s e

a p o t e n t i a l> n • I A g e n c y f

3 r e s p iw a s n o t

c o n t r i b u t e di s m a y i a vd i r e c t l y r e l e v a n t t o

e o p s e r v e d . A t t h eg n i f • c a n t l a z a r d fore s u p p l i e r o f t h e ' , 'o a ' e s did not p r o d u c ee t h y i e n e E t h e r ( ' , 4 , De i n t e r n a t i o n a l A g e n c

t h. V t

t hw o r

T i

e v i n d e n c eN a t i o n a l o x i

h u m a n sc o I o g y

sP r

h ea n .' - T r i c he v i d e n co x a n e )

o r R ec i e n t

a st i oi n a 2 4 - m o n t hi n b e n i g n a n d

r a b l e T i 0 2 d u s to b s e r v e d . " h e

w h e l m e d a t t h ee t u » o r ' o r m a tk pi a C e w h e r e oO f m a n u f a c t u r e

c a r c i n o g e n b yor R e s e a r c h on n a I a t i o n stun a l i g n a n t . a n

A t l o w e r e xn o r m a l c l e a r a2 5 0 m g / M 3 e x p o

i o n . T h e s e r e sc c u p a t i o n a l e xr c o n c l u d e s t h

o v e r e x p o s u r eI n t e n t i o n a l

n t s m a y b e

t h e N a t i o n a ln C a n c e r , O S H A ,d y w i t h r a t sg t u m o r s i n t h ep o s u r e l e v e l s ,n e e m e c h a n i s m s

v e l , a n du I

r et s

p o s u rat t h

I em aee r

Y notl i m i t

i ssn o

f

( M a y b e r e a s o n a b l y a n t ih r a m (NTc i p a t e d

l o r o e t h a n e ^ o D o r t s t h a t , o n ge of c a r c i n o g e n i c i t y or m u t ah a s b e e n l i s t e d a s a p o t e n t is e a r c h o n C a n c e r C I A R C G r o u pe v i d e n c e i n e x p e r i m e n t a l a n

P) l i s t s 1 , 4 - D i o x a n e as a Grt o b « a c a r c i n o g e n ) .

m It e r m a n Ig e n i c i t y .a 1 c a r c i n o g e n by2 8 - I n s u f f i c i e n t

i m a I s . Theoup 2 s u b s t a n c e

SECTIOK IV - FIRST AID A^D EMERGENCY PROCEDURESSWALLOWING

I f s w a l l o w e d d o n o t i n d u c e v o m i t i n g . C a l l p o i s o n c o n t r o l c e n t e r , h o s p i t a le m e r g e n c y r o o m o r p h y s i c i a n i m m e d i a t e l y .

iLATIONR e m o v e t c f r e s h a i r i m m e d i a t e l y . I f b r e a t h i n g h a s s t o p p e d , g i v e a r t i f i -c i a l r e s p i r a t i o n . < e e p w a r m a n d q u i e t . G e t r a d i c a l a t t e n t i o n i m m e d i a t e l y .

EYEF l u s h w i t h l a r g e a m o u n t s o f w a t e r , l i f t i n g u p p e r a n d l o w e r l i d s o c c a s i o n a l -l y . C o n t i n u e f o r a t l e a s t 1 5 m i n u t e s . G e t m e d i c a l a t t e n t i o n .

SKINR e m o v e c o n t a m i n a t e d c l o t h i n g . W a s h a f f e c t e d a r e a w i t h s o a p a n d w a t e r .O b t a i n m e d i c a l a t t e n t i o n i f i r r i t a t i o n p e r s i s t s .

NOTES TO PHYSICIANE p i n e p h r i n e a n d o t h e r d r u g s w i t h s i m i l a r a c t i v i t y o n t h e h e a r t m a y p r o d u c es e r i o u s a r r h y t h m i a s a n d s h o u l d n e v e r b e g i v e n t o p e r s o n s o v e r c o m e w i t h a n yc h l o r i n a t e d h y d r o c a r b o n , p a r t i c u l a r l y w h e n t h e r e ' s c o e x i s t e n t a n o x i a .

SECTIONBOILING RANGE

FREEZING POINT:

VAPOR PRESSURE:VAPOR DENSITY

; 4- 5

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D E G . C . )

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205 D E G . C . )

EVAPORATION RATES l o w e r t h a n o i e t h y l e t h e r .

WEIGHT LB. /GAL. 9 . 2S P E C I F I C G R A V I T Y 1 . 1

VOC 3 . 2 4 Ib/gal less water & KKS* 389 g/1 less water C A L

VOC 5 . 9 6 Ib/gal fnlirfa

APPEARANCE fc ODOR:VISCOSITY:

L i q u i d , S o l v e n t o d o r

N o i n f o r m a t i o n f o u n d

SOLUBILITY:PH:

7 1 5 g/1 Bnlitte C A L C U L A T E D


4 - 7 ( S T D U N I T S )

All Physical data determined at 68 DEG. F. (20 DEG. C.) 760 mm Kg* Negligibly Photochemically Reactive Material!VOC values reported here are verified by ASTM method D - 3 9 6 0

SECTION VI - FIRE AND 1EXPLOSION DATAA FLAMMABILITY CLASSIFICATION

-AMMABLE LIMITS 1 . 0 r . - 2 2 . 2F L A M M A B L E L I Q U I D C L A S S I B

502518 63

i SECTION VI - FIRE AND EXPLOS]:ON DATA; (CONTINUED)

PAGEDATE ll/

307 796

FLASHPOINT

Arr> IGNITION4 5 D E G . E G . C , ) C A L C U L A T E D

572 D E G . [ . ( 3 0 0 0 E G . C . ) DECOMPOSITION TEMP '332 D E C . F. (1000 O E G . C . )O S I O N RATE N o t a p p l i c a b l e

EXPLOSIVE W G T . N o t a p p I - c o b l eMAGNETISM

EXTINGUISHING MEDIAUse N F P A C l a s sc a i o r a l c o h o l

f o a mm e r f o a m i s p r e f e r r e d ' o rUNUSUAL FIRE AND EXPLOSION HAZARDS

i e r g e n c yi e a I t h h

B F i r e e x t i n g u i s h e r s ( c a r o o nf o a m ) a e s i g n e a t o e x t i n g u i s h

r e f e r r e d ' o r l a r g e f i r e s .


d i o x i d e , - i l l p u r p o s e d r y c h e m if l a m m a b l e l i q u i d f i r e s . P o l y -

u r i n g e m e r g e n c y c o n d ih e a l t h h a z a r d .

o n s , o v e r e x p o s u r e t o a e c o m p o s t ' c n p r o d u c t s m a yS y m p t o m s m a y n o t b e i m m e d i a t e l y a p p a r e n t . O b t a i n

c o n t a c t w i t h a l u m i n u m

c a u s e am e d i c a l a t t e n t i o nT h i s p r o d u c t c o n t a i n s h a l o g e n a t e d h y d r o c a r b o n s ;m a y c a u s e v i o l e n t r e a c t i o n a n d o r e x p l o s i o n .W A R N I N G ' F L A M M A B L E .

SPECIAL FIRE FIGHTING PROCEDURESF i r e f i g h t e r s s h o u l d w e a r s e l f - c o n t a i n e d b r e a t h i n g a p p a r a t u s .w a t e r m a y b e i n e f f e c t i v e , b u t m a y b e u s e d t o c o o l e x p o s e d c o n t a i n e r s t op r e v e n t p r e s s u r e b u i l d - u p a n d p o s s i b l e a u t o - i g n i t i o n o r e x p l o s i o n w h e ne x p o s e d t o e x t r e m e h e a t . I f w a t e r i s u s e d , f o g n o z z l e s a r e p r e f e r a b l e .



CONDITIONS TO AVOIDf t v o i d e x c e s s i v e h e a t ( > i i 5 ; ( 4 6 C ) a n d s o u r c e

INCOMPATABILITY (MATERIALS TO AVOID)S t r o n g a c i d s o r a l k a l i n e m a t e r i a l s .0 x i a i z ' n g m a t e r i a l s .j a t e r - , o n g t e r m c o n t a c t c a n d e p l e t e s t a b i l i z el y d r o 1 , y s i s p r o d u c ' n g c o r r o s i v e a c i d . A v o i d p r os t o r a g e ' " , a l u m i n u m c - ' t s ' a l l o y s . M e t a l l i cs h o u i d b e a v o i d e d .T h i s p r o d u c t c o n t a i n s r a i o g e n a t e d h y d r o c a r b o n sa l u m i n i u m . A v o i d c c n t a c : w i t h a l u m i n i u m i n s i t• n a y b e e l e v a t e d o r i n w n i c h r e a c t i o n s m a y b e ee q u i p m e n t s y s t e m s c o n t a ' " i n g a l u m i n i u m p a r t s .

HAZARDOUS DECOMPOSITION PRODUCTSB u r n i n g , n c i u d i n g w h e n l e a t e d b y w e l d i n g o r cc a r b o n m o n o x i d e a n d c a r p o n d i o x i d e . I n a d d i t i o n

" i a v Pe g e n e r a t e d ..ÂRDOUS POLYMERIZATION

U i l l n o t o c c u rCONDITIONS TO AVOID

" n i s p r o d u c t c o n t a i n s r - a l o g e n a t e d h y d r o c a r b o n s' o r m h y d r o g e n c h l o r i d e , c h l o r i n e , a n d p h o s g e n e, u r f a c e s , o p e n f l a m e s , a n d U . V . r a d i a t i o n . D ow e l d i n g o p e r a t i o n s .H o t s u r f a c e s .

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j SECTION VIII - EHVIROHMENTAL INFORMATIONSTEPS TO BE TAKEN IF MATERIAL IS RELEASED OR SPILLED

e e p s p e c t a t o r s a H l i m i n a t e a l l i g n i t o n s o u r c e s ( f l a m e s . l o ts u r f a c e s , a n d s o u r c e s o f e l e c t r i c a l , s t a t i c o r f r i c t i o n a l s p a r k s ) .D i n e a n a c o n t a i n s p i l l « i t h i n e r t m a t e r i a l ( e . g . s a n d , e a r t h ) . " r a n s f e rl i q u i d s t o c o v e r e d m e t a l c o n t a i n e r s f o r r e c o v e r y o r d i s p o s a l , o r r e m o v ew i t h i n e r t a b s o r b e n t . u s e o n l y n o n - s p a r k i n g t o o l s . P l a c e a b s o r b e n t d i k i n gm a t e r i a l s i n c o v e r e d m e t a l c o n t a i n e r s f o r d i s p o s a l . P r e v e n t c o n t a m i n a t i o no f s e w e r s , s t r e a m s , a n a g r o u n d w a t e r w i t h s p i l l e d m a t e r i a l o r u s e da b s o r b e n t .

WASTE DISPOSALD i s p o s e i n a c c o r d a n c e w i t h f e d e r a l , s t a t e a n d l o c a l r e g u l a t i o n s .CLASSIFICATIONh i s p r o d u c t , i f d i s c a r d e d d i r e c t l y , w o u l d b e c l a s s i f i e d a h a z a r d o u s w a s t e

c h a r a c t e r i s t i c , i . e . h a s a f l a s h p o i n t o f 1 4 0T h e p r o p e r R C R A C l a s s i f i c a t i o n w o u l d b e D 0 0 1 .

1 - T r i c h l o r o e t h a n e w n i c n m a y o r m a y n o t b ew a s t e , (see 4 0 C F R 2 6 1 . 3 3 ) .

RCRA

b a s e d o n i t s i g n i t a b i l ' t yd e g . F . C 6 0 d e g . C ) o r l e s sT I I S p r o d u c t c o n t a i n s 1 , 1c l a s s i f i e d a s a h a z a r d o u s

ENVIRONMENTAL HAZARDSN o n e i c n o w n


P r o p e r s e l e c t i o n o f r e s p i r a t o r y p r o t e c t i o n d e p e n d s u p o n m a n yi n c l u d i n g d u r a t i o n / l e v e l o f e x p o s u r e a n d c o n d i t i o n s o f u s e .e x p o s u r e t o o r g a n i c c h e m i c a l s s u c h a s t h o s e c o n t a i n e d i n t h i" . o t r e q u i r e t h e u s e o f r e s p i r a t o r y p r o t e c t i o n • , • u s e d i n w e la r e a s . ; n r e s t r i c t e d v e n t i l a t i o n a r e a s a N I O S H a p p r o v e d c h e mr e s p i r a t o r m a y b e r e q u i r e d . U n d e r c e r t a i n c o n d i t i o n s , s u c h am e c h a n i c a l p r e f i l t e r m a y a l s o b e r e q u i r e d . ! n c o n f i n e d a r e a sM S H A a p p r o v e d a i r s u p p l i e d r e s p i r a t o r . I f t h e T L V ' s l i s t e d i

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502518PAGE 4DATE 11/07/96

SECTION IX - PERSONAL PROTECTION INFORMATION; (CONTINUED)

RESPIRATORY PROTECTIONj r e e x c e e d e d u s e a p r o p e r l y f i t t e d N I O S H / M S H A a p p r o v e d r e s p i r a t o r w i t h a na p p r o p r i a t e p r o t e c t i o n f a c t o r . R e f e r t o O S H A 2 9 C F R 1 9 1 0 . 1 3 4 " R e s p i r a t o r yP r o t e c t i o n " , a n d " R e s p i r a t o r y P r o t e c t i o n A M a n u a l A n d G u i d e l i n e , A m e r i c a ni n d u s t r i a l H y g i e n e A s s o c . "

.PILATIONP r o v i d e g e n e r a l d i l u t i o n a n d l o c a l e x h a u s t v e n t i l a t i o n i n s u f f i c i e n t v o l u m ea n d p a t t e r n t o k e e p c o n c e n t r a t i o n s o f h a z a r d o u s i n g r e d i e n t s l i s t e d i nS e c t i o n : ; b e l o w t h e . o w e s t e x p o s u r e l i m i t s t a t e d . R e m o v e d e c o m p o s i t i o no r o d u c t s t h a t a r e g e n e r a t e d w h e n w e l d i n g , c u t t i n g , o r b r a z i n g o b j e c t sc o a t e d w i t h t h i s p r o d u c t . R e f e r t o " I n d u s t r i a l V e n t i l a t i o n - A M a n u a l o fR e c o m m e n d e d P r a c t i c e " A C G I H

HAND PROTECTIONW e a r a o p r c o r i a t e i m p e r m e a b l e g l o v e s ( N o r t h

EYE PROTECTIONW e a r s a f e t y s p e c t a c l e s .

OTHER PROTECTIVE EQUIPMENT

S i l v e r S h i e l d ) .

s o t i i k e i v t o b e n e e d e d .

1 SECTION X - SPECIAL 1 PRECAUTIONSPRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE

C o n o t s t o r e a b o v e ' ' 5 d e g . F ( l . 6 d e g . C ) s t o r e l a r g e q u a n t i t i e sc o m p l i a n c e w i t h O S M A 2 9 C F R 1 9 1 0 . 1 0 6 .

i n

OTHER PRECAUTIONSC o n o t t a k e i n t e r n a l l y . C l o s e c o n t a i n e r a f t e r e a c h u s e .C o n t a c t o f v a p o r s w i t h h o t s u r f a c e s a n d i n h a l i n g v a p o r s t h r o u g h a c i g a r e t t ec a n c r e a t e n y d r o g e n c h l o r i d e a n d / o r p h o s g e n e g a s .E m p t y c o n t a i n e r s m u s t " o t b e w a s h e d a n d r e - u s e d f o r a n y p u r p o s e .C o n t a i n e r s s h o u l d b e g r o u n d e d a n d b o n d e d t o t h e r e c e i v i n g c o n t a i n e r .C o n o t » e i d , b r a z e o r c u t o n e m p t y c o n t a i n e r .N e v e r u s e p r e s s u r e t o e m p t y . D r u m i s n o t a p r e s s u r e v e s s e l .


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A N M A B L E i. P R O C E D U R E S SEE A B O V E

A M M A B L E

0 R T A T ION

A E R O S O L P R O P E L L E N T : N o t a p p l i c a b l e. N O . U . S . P O S T A L F O R B I D D E N

N

N 1N 1N 1A 1A 2A 1A 2G

; T. A S T ! C C O N T A I N E R S W I L LU N I T C O N T A I N E R ) .

B E A U N I T C O N T A I N E R O N L Y U S E D F O R C O M P O N E N T O F

T H I S1 H E

I S T O C E R T I F Y T H A T T H I S I T E M I SE S T O F C U R K N O W L E D G E , C O R R E C T .

H A Z A R D O U S A N D I N F O R M A T I O N S T A T E D I S T 0


T H E I N F O R M A T I O N C O N T A I N E D H E R E I N I S B A S E D O N D A T AA C C U R A T E . W H I L E T H E I N F O R M A T I O N I S B E L I E V E D T O B EE X P R E S S E D C R I M P L I E D R E G A R D I N G T H E A C C U R A C Y O F T HS E O B T A I N E D F R O M T H E U S E T H E R E O F . S I N C EC O N D I T I O N S A N D U S E O F T H I S P R O D U C T A R EU S E R ' S O B L I G A T I O N T O D E T E R M I N E T H E

T H E U S E O FC O N T R O L L E D

C O N D I T I O N S O F S A F E

C O N S I D E R E D T O B ER E L I A B L E , N O W A R R A N T YS D A T A O R T H E R E S U L T S

T h e C o r p o r a t e S a f e t y a n d E n v i r o n m e n t a l A f f

T H I S I N F O R M A T I O N A N DB Y T H E U S E R , I T I S T H E

U S E O F T H E P R O D U C T .D e p a r t m e n t

r e s p o n s i b l e f o r t h e p r e p a r a t i o n o f t h i s M a t e r i a l S a f e t y D a t a S h e e t

I ST 0T H E

PRATT & LAMBERT 316-733-1361Industrial Coatings Div.101 Prospect AvenueCleveland, OH 44115DOT EMERGENCY CHEMTEL (800)255-3924 (24hrs)INFORMATION PHONE NO. 216-566-2902 (M-F 8 AM-5 PM CT!CORPORATE CONTACT 216-566-2917 (M-F 8 AM-5 PM CT)

H . M . I . 13 .HEALTH 1FLAMMABILITY 3REACTIVITY 0

These ratings snould be used onlyas part of fu l ly implemented M . M . l . S . program.


SECTION I

PRODUCT CLASS A L K Y D . M E D I U M - L O N G

TRADE NAME .... H I G H S O L I D S « « • •


J A C A M B R O U N

REVISED ON 1 1 / 0 7 / 9 6

A / 0 O R E N L



INGREDIENT % BYWOT

CAS NO./NIOSH*


SARA313

VPznxn Ho

20 DBG.®C

K A P T H A ( P E T R O L E U M )r - E A V Y A L K Y L A T E

x Y L E N E

M A N G A N E S E D I O X I D E

P E T R O L E U M H Y D R O -CARBON M I X T U R EM I N E R A L S P I R I T S

E O I L

S O L V E N T6 4 7 4 1 - 6 5 - 7 M f R

PPM M G / C U . M .

100 525

5 1 3 3 0 - 2 0 - 7 T L V - T U AS O L V E N T Z E 2 1 0 0 0 0 0 U V - S T E L

O S H A - P E LOSMA-STEL

L F L 1 .0

S O L V E N T

7439-96-5 T L V - T U AO S H A - C E 1 L

8032-32-4 T L V - T W A016180000 OSHA-PEL

64742-88-7 TLV-TUAOSHA-PEL

LFL 1

8000-4 1 • 7

100150100150

100100

100100

435655-35

U F L '.0

UFL

55

525525

525525

'.0


MPPCF SKIN


L F L = L O W E R F L A M M A B I L I T Y L I M I T P E R C E N TU F L = U P P E R F L A M M A B I L I T Y L I M I T P E R C E N TS K I N = S K I N A B S O R P T I O N M U S T B E C O N S I D E R E D A S AC - C E I L I N G = A L L O U . E X P O S U R E L E V E L S H O U L D N O T B EM F R = M A N U F A C T U R E R R E C O M M E N D E D E X P O S U R E L I M I TS T E L = S H O R T T E R M E X P O S U R E L I M I TX - S A R A 3 1 3 = C H E M I C A L I S S U B J E C T T O R E P O R T I N GO F T : T L E i i l O F S . A . R . A . - 0 C F R P A R T 3 7 2K I C S H X = > J [ O S H R E G I S T R Y C F T O X I C E F F E C T S O F C H E M I C A L


R E Q U I R E M E N T S O F S E C T I O N 3 1 3

S U B S T A N C E S N U M B E R

SECTION III - HEALTH INFORMATIONEFFECTS OF SHORT TERM OVEREXPOSORESWALLOWING

C a n c a u s e g a s t r o i n t e s t i n a l i r r i t a t i o n , n a u s e a , a n d v o m i t i n g . A s p i r a t i o n o fm a t e r i a l i n t o I j n g m a y c a u s e c h e m i c a l p n e u m o n i t i s w h i c h c a n b e f a t a l .



SKINM a y c a u s e d e t a i l i n g a n d i r r i t a t i o n o f t h e s k i n .

EFFECTS OF REPEATED OVERBXPOSUREO v e r e x p o s u r e t o x y l e n e m a y c a u s e i n j u r y t o t h e l i v e r , k i d n e y s , a n db l o o d .R e p o r t s h a v e a s s o c i a t e d p r o l o n g e d a n d r e p e a t e d o c c u p a t i o n a l o v e r e x p o s u r et o s o l v e n t s w i t h p e r m a n e n t b r a i n a n d n e r v o u s s y s t e m d a m a g e . I n t e n t i o n a lm i s u s e b y d e l i b e r a t e l y c o n c e n t r a t i n g a n d i n h a l i n g t h e c o n t e n t s m a y b e

SIGNIFICANT" LABORATORY*DATA WITH POSSIBLE RELEVANCE TO HUMAN HEALTH.N o n e c u r r e n t l y k n o w n

SECTION IV - FIRST AID AND EMERGENCY PROCEDURES•'ALLOWING

i f s w a l l o w e d d o n o t i n d u c e v o m i t i n g . C a l l p o i s o n c o n t r o l c e n t e re m e r g e n c y r o o m o r p h y s i c i a n i m m e d i a t e l y .

h o s p i t a L

527007 02PAGE 2DATE 11/07/96

SECTION IV - FIRST AID AND EMERGENCY PROCEDURES; (CONTINUED)INHALATION

R e m o v e t o f r e s h a i r i m m e d i a t e l y . I f b r e a t h i n g h a s s t o p p e d , g i v e a r t i f i -c i a l - e s p i r a t i o n . < e e p w a r m a n d q u i e t . G e t m e a i c a l a t t e n t i o n i m m e d i a t e l y

EYEF l u s h w i t h l a ri y . Co

i t h l a r g e a m o u n t s o f w a t e r , l i f t i n g u p p e r a n d l o w e r l i d s o c cn t i n u e t o r a t l e a s t 1 5 m i n u t e s . G e t m e d i c a l a t t e n t i o n .

s i o n a I

R e m o v e c o n t a m i n a t e d c l o t h i n g . W a s h a f f e c t e d a r e a w i t h s o a p a n d w a t e r .O b t a i n m e d i c a l a t t e n t i o n i f i r r i t a t i o n p e r s i s t s .



FREEZING POINT:VAPOR PRESSURE:

VAPOR DENSITY

T 0 414 D E G . F C


' 6 5 D E G . F . ( 7 4 D E G . C . )

- 5 0 D E C . F . ( • 4 5 D E C . C . )

5 m m H g 2 6 8 D E C . F . ( 2 0 D E G . C . )

h e a v i e r t h a n a i r . % VOLATILE BY VOLUME 5 2

VOC 3 . 3 7 Ib/gal less veter & NPRS*

212 D E G . C . }

WEIGHT LB./GAL. 7 . 9S P E C I F I C G R A V I T Y 0 . 9

APPEARANCE & ODOR:

VISCOSITY:

VOC

S o l v e n tL i q u i d ,

N o i n f o r m a t i o n

7 . 0 6 Ib/gal aoLids

o d o r SOLUBILITY:f o u n d P H :

-04 g/1 less waterc A L

8 4 7 g / 1 Bnlifte C A L C U L A T E D


4 - 7 ( S T D U N I T S )

All Physical data determined at 68 DEG. F. (20 DEG. C.) 760 mm Hg• Negligibly Photochemically Reactive MaterialsVOC values reported here are verified by ASTM method D-3960______

SECTION VI - FIRE AND EXPLOSION DATANFPA FLAMMABILITY CLASSIFICATIONFLAMMABLE LIMITS ' . 0 X - 7 . 0 X

F L A M M A B L E L I Q U I D C L A S S I

FLASHPOINT 8 0 D E G . F ,

5 7 2 D E G . F . ( 3 0 0 D E G . C . )

( 2 7 D E G . C , ) C A L C U L A T E D


N o t a p p l i c a b l etOSION RATE Not a p p l i c a b l e MAGNETISM

NET EXPLOSIVE WGT . N o t a p p l i c a b l e

EXTINGUISHING MEDIAU s e N F P A C l a s s B F i r e e x t i n g u i s h e r s ( c a r b o n d i o x i d e a l l p u r p o s e d r y c h e m ic a l o r a l c o h o l f o a m ) d e s i g n e d t o e x t i n g u i s h f l a m m a b l e l i q u i d f i r e s . P o l y -m e r f o a m i s p r e f e r r e d f o r l a r g e f i r e s .

UNUSUAL FIRE AND EXPLOSION HAZARDSD u r i n g e m e r g e n c y c o n d i t i o n s , o v e r e x p o s u r e t o d e c o m p o s t i o n p r o d u c t s m a yc a u s e a h e a l t h h a z a r d . S y m p t o m s m a y n o t b e i m m e d i a t e l y a p p a r e n t . O b t a i n•n e d i c a i a t t e n t i o n .j A R s i N G ' F L A M M A B L E .

SPECIAL FIRE FIGHTING PROCEDURESw a t e r m a y b e i n e f f e c t i v e , b u t m a y b e u s e d t o c o o l e x p o s e d c o n t a i n e r s t op r e v e n t p r e s s u r e D u i l d - u p a n d p o s s i b l e a u t o - i g n i t i o n o r e x p l o s i o n w h e ne x p o s e d t o e x t r e m e h e a t . I f w a t e r i s u s e d , f o g n o z z l e s a r e p r e f e r a b l e .


STABILITY

CONDITIONS lo AVOIDA v o i d e x c e s s i v e h e a t ( > 1 1 5 F ( 4 6 C ) a n d s o u r c e s o f i g n i t i o n .


HAZARDOUS DECOMPOSITION PRODUCTSB u r n i n g , i n c l u d i n g w h e n h e a t e d b y M e l d i n gc a r b o n m o n o x i d e a n d c a r b o n d i o x i d e .



c u t t i n g , w i l l p r o d u c e s m o k e


K e e p s p e c t a t o r s a w a y . E l i m i n a t e a l l i g n i t i o n s o u r c e s ( f l a m e s , h o ts u r f a c e s , a n d s o u r c e s o f e l e c t r i c a l , s t a t i c o r f r i c t i o n a l s p a r k s ) .D i k e a n d c o n t a i n s p i l l w i t h i n e r t m a t e r i a l (e.g. s a n d , e a r t h ) . T r a n s f e r

527007 02 DATE 11/07/96

SECTION VIII - ENVIRONMENTAL INFORMATION; (CONTINUED)

IF MATERIAL ISc o v e r e d m e t aa p s o b e n tn c o v e r e as t r e a m s .

STEPS TO BE TAKEN. d U I O S tOw i t h i n e r t•n a I e r i a i sof s e w e r s ,a b s o r b e n t .

. ..oTE DISPOSALD i s p o s e i n a c c o r d a n c e

RCRA CLASSIFICATION" h i s p r o d u c t , i f d i s cb a s e d on its i g n i t a b ideq. F . ( 6 0 d e g . C )

ENVIRONMENTAL HAZARDSN o n e « n o w n

RELEASED OR SPILLEDc o n t a i n e r s f o r

J s e o n l y n o n - s p am e t a l c o n t a i n e r s

r r e c o v e r y or ar k i n g t o o l s . Pf o r d i s p o s a l . P

a n d g r o u n d w a t e r w i t h s p i l l e d m a t e r i a l

i s p o s a i , o r r e m o v el a c e a b s o r b e n t d i k i n ge v e n t c o n t a m i n a t i o n

o r u s e d

w i t h f e d e r a l s t a t e a n a l o c a l e g u l a t i o n s

o r

a r d e dI i t y cl e s s .

d i r e e t I y ,h a r a c t e r iThe p r o p e

w o u l d b e c l a s s i f i e d a h a z a rs t i c , i . e . h a s a f l a s h p o i n tr R C R A c l a s s i f i c a t i o n w o u l d

d o u s wasof 140

be 0001.

t e

SECTION IX - PERSONAL PROTECTION INFORMATIONPROTECTION

l e c t i o n ofd u r a t i o n /

t o o r g a n i cr e t h e u s e

r e s tm a y

RESPIRATORYP r o p e r s e• n c I u d i n ge x p o s u r enot r e q u ii r e a s . Inr e s p i r a t o- l e c n a n i c a l p r e f i l tM S H A a p p r o v e d a i ra r e e x c e e d e d u s e aa p p r o p r i a t e p r o t e cP r o t e c t i o n " , a n d "I n d u s t r i a l H y g i e n e

r e s p i r a t o r y p r o t e c t i o n d e p e ne v e l o f e x p o s u r e a n d c o n d i t ic h e m i c aof r e s p

i c t e d v e n t ib e r e q u i r e d

s s u c ha t o r y

• s t h o s e c o n tp r o t e c t i o n i '

e r may as u p p I ledp r o p e r I

t i o n f a c t o rR e s p i r a t o r yA s s o c . "

a t i o n a r e a s a N 1 0 S H aU n d e r c e r t a i n c o n d i t

I s o b e r e q u i r e d . I n c or e s p i r a t o r . I f t h e

y f i t t e d N I O S H / M S H A aR e f e r t o O S H A 2 9

P r o t e c t i o n A M a n u

VENTILATIONP r o v i d e g e n e r a lu n a p a t t eS e c t • a n

d i l u t i o n a n d l o c a l

p r o d u c t s T h a t; o a t e d w • t h tR e c o m m e n d e d P

HAND PROTECTION

e x h a u s tr. t o k e e p c c n c e n t r a t i o n s o f h a z ab e l o w t h e l o w e s t e x p o s u r e l i m i t

a r e g e n e r a t e d w h e n w e l d i n g ,i s p r o d u c t

r a c t • c e A C G I MR e f e r t o I n d u s t r

a so na i

uP P1 0n fV 'P rC FI

I ai nd .9 ,e n

usn es er on s1 nS0 VRA n

t ig r

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p o0 tddv e,e dI •.e d1 9d

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nu

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m as e

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c hc hr ee de s. 1i d

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i

IIe I

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i n

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P rv ea Is ps eS et 0R ee ,

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a Ita tt rn gI 0nt ha tr i

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m a ye di d 9 e, aS H /1 I

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n

0 f

. e a r a p p r o p r i a t e m p e r m e a b l e g l o v e s ( N o r t h

v e n td o u ss t a t e du t ti a i

S i l v e r S h i e l d ) .

EYE PROTECTION. e a r • , a t e t v s p e c t a c l e s .

OTHER PROTECTIVE EQUIPMENTN o t i i i c e l y t o b e n e e d e d

SECTION X - SPECIAL PRECAUTIONS-PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE

0 o n o t s t o r e a b o v e 1 1 5 d e g . F ( 4 6 d e gc o m p l i a n c e w i t h O S H A 2 9 C F R 1 9 1 0 . 1 0 6 .

OTHER PRECAUTIONS

C ) s t o r e l a r g e q u a n t i t i e s

D oE m pC o nC 0N e v

nttne

0 tya i0 tr

tC 0n e

M

:i S

anree

KtSI

ea is

d ,D r

i n t e r n a l l y . C l o s e c o n t a i n e r a f t e r e a c h u s e .n e r s m u s t n o t b e w a s h e d a n d r e - u s e d f o r a n y p u r ph o u l d b e g r o u n d e d a n d b o n d e d t o t h e r e c e i v i n g c ob r a z e o r c u t o n e m p t y c o n t a i n e r .

e s s u r e to e m p t y . D r u • is not a p r e s s u r e v e s s e l .

onste .a i n e r .



D 0

D 0

0 0

P R

D .

U N

1

S

S S

; i

O P E R S H I P P 1

T C L A S S I F I C

T . A B E L

T P L A C A R DE C A U T 1 0 N S T

M I T E 3 Q U A N T0 . ' . 1 . 0 . N

IT C 0 N T A I N E

P I N T M E T A LQ U A R T M E T A LG A L L O N M E T AG A L L O N M E T A

G A L L O N M E T

B E R B O A R D B O

N O P L A S T I CK I T U N I T C

N G N A M E

A T 1 0 N

Q B E T A

I T Y :U M B E R J

R

LL

A L

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C O N T A I N0 N T A 1 N E

( A R T

KEN 1

N 0N 126

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T D O T M A R K I N G T H I S S I D E U P

E L I Q U I D E M E R G E N C Y A C C I D E N T P R E C A U T I O N

E & P R O C E D U R E S S E E A B O V E

E

0 N

L P R O P E L L E N T : N o t a p p l i c a b l eU . S . P O S T A L F O R B I D D E N

C O N T A I N E R O N L Y U S E D F O R 1 C O M P O N E N T O F

5~ * i * r n / - \ - i - - - — - . - , . . — — - — - — ,-w.r,, PACK 4______27007_______0_2________________t___________________________________DATE 11/07/96

I__________SECTION XII - TRANSPORTATION DATA; (CONTINUED)__________________

T H I S I S T O C E R T I F Y T H A T T H I S I T E M I S H A Z A R D O U S A N D I N F O R M A T I O N S T A T E D I S , T O• J E B E S T 3 c O U R K N O W L E D G E , C O R R E C T .


T H E I N F O R M A T I O N C O N T A I N E D H E R E I N I S B A S E D C N D A T A C O N S I D E R E D T O B EA C C U R A T E . - M I L E T H E I N F O R M A T I O N I S B E L I E V E D T O B E R E L I A B L E , N O W A R R A N T Y I SE X P R E S S E D C R I M P L I E D R E G A R D I N G T H E A C C U R A C Y C F T H I S D A T A O R T H E R E S U L T S T O3 E O B T A I N E D F R O M T H E U S E T H E R E O F . S I N C E T H E U S E O F T H I S I N F O R M A T I O N A N D T H EC O N D I T I O N S A N D U S E O F T H I S P R O D U C T A R E C O N T R O L L E D B Y T H E U S E R , I T I S T H EU S E R ' S O B L I G A T I O N T O D E T E R M I N E T H E C O N D I T I O N S O F S A F E U S E O F T H E P R O D U C T .

T h e C o r p o r a t e S a f e t y a n d E n v i r o n m e n t a l A f f a i r s D e p a r t m e n t i sr e s p o n s i b l e f o r t h e p r e p a r a t i o n o f t h i s M a t e r i a l S a f e t y D a t a S h e e t .

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