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HEAT EXCHANGER ALUMINUM
2 www.aleris.com
YOUR PARTNER IN ALUMINUM SOLUTIONS
We believe that it’s a win-win to enable our customers’ progress. Quality. Accountability. Integrity. These things are non-negotiable. When we collaborate with customers to find solutions, we’re contributing to their success and creating a better world.
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With Aleris heat exchanger aluminum, Aleris provides customers with the people, the tools and the resources that they need to realize the value that aluminum offers.
THINK BEYOND
At Aleris, aluminum isn’t just our work — it’s our passion. It represents opportunity, innovation and game-changing solutions to create a better world.
GLOBAL REACH becomes more important in business every minute of every day. Aleris is helping our customers meet international demand through global assets such as our newly built world-class rolling mill in China, which allows us to serve fast-growing Asian markets.
SUSTAINABILITY is important to us. With a safety-focused culture, Aleris looks after the environment the same way that we look after our people.
TECHNICAL PROWESS is what drives our people. We’re not satisfied with today’s solutions. By always striving to develop new and innovative aluminum products for our customers, we ensure that we’re providing them the best materials to meet tomorrow’s challenges today.
CONSISTENCY in our quality, reliability and creativity come together to make Aleris the preferred choice for our customers, and as a result, a leading global producer of commercial aluminum plate.
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HEAT EXCHANGER ALUMINUM FROM ALERIS
Aleris is among the world´s leading suppliers of high-quality aluminum products for the manufacture of heat exchangers, and has over 65 years of experience as a principal supplier to many world-class industries.
Aluminum is the preferred material for the increasingly diverse and demanding fi eld of heat exchanger manufacture, and is used around the world in many industries, including the automotive sector, for a variety of heat exchanger designs.
Aluminum provides a unique combination of advantages, e.g. its cost, strength, corrosion life, weight reduction capabilities, processing and machining characteristics, and the ability to alloy special material properties to specifi c customer applications.
Our products are being continually developed and improved. As a result, Aleris can offer an extensive range of products, covering a wide range of alloys, tempers, dimensions and properties.
If you need further data or more urgent assistance, please contact us using the information provided at the back of the brochure or simply visit our website at www.aleris.com
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TECHNICAL CAPABILITIES FOR CLAD AND CORE MATERIAL
Customer specifi c brazing coils and sheets can be delivered in a large variety of alloy combinations, clad ratios, thicknesses & widths, and coil diameters. Our customers are supported by world class logistics and strict quality controls (during all steps of our production). An overview of our production capabilities is provided opposite.
We can advise you further on process steps and tempers, if required.
Typical technical capabilities Clad material %
One side clad / clad ratio 4 - 20
Both sides clad / clad ratio 4 - 15 per side
Clad material mm in
Thickness 0.095 - 3.175 0.004 - 0.125
Coil width 25 - 1,280 0.98 - 50.39
Coil inner diameter 250 - 600 9.80 - 23.60
Coil outer diameter (max.) 1,770 69.68
Unclad material mm in
Thickness 0.095 - 6.4 0.004 - 0.252
Coil width 15 - 1,650 0.59 - 64.96
Coil inner diameter 152 - 609 6 - 24
Coil outer diameter (max.) 1,676 65.98
Other dimensions, coils and sheets on request
Clad thickness depending on alloy combination and thickness
clad
core
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Clad chemical composition [all data on weight -%]Alloy Specifi cation Chemical elements each total Approx. Aleris melting range designation Si Fe Cu Mn Mg Cr Zn Ti Zr 0.05 0.15 °C °F
For brazing in controlled atmosphere with / without fl ux
4343 AA; EN 573-3 Min. 6.8 - - - - - - - - - - 577 1071
Max. 8.2 0.8 0.25 0.10 - - 0.20 - - 0.05 0.15 613 1135
Hogal 4433 4433 Min. 8.2 - - - - - - - - - - 577 1071
Max. 8.9 0.8 0.25 0.10 0.035 - 0.2 - - 0.05 0.15 600 1112
4045 AA; EN 573-3 Min. 9.0 - - - - - - - - - - 577 1071
Max. 11.0 0.8 0.30 0.05 0.05 - 0.10 0.20 - 0.05 0.15 591 1096
For vacuum brazing
4004 AA; EN 573-3 Min. 9.0 - - - 1.0 - - - - - - 554 1029
Max. 10.5 0.8 0.25 0.1 2.0 - 0.20 - - 0.05 0.15 596 1105
4104 1) AA; EN 573-3 Min. 9.0 - - - 1.0 - - - - - - 554 1029
Max. 10.5 0.8 0.25 0.10 2.0 - 0.20 - - 0.05 0.15 596 1105
4004 mod. 4403 Min. 9.0 - - - 0.45 - - - - - - 554 1029
Max. 10.5 0.8 0.25 0.10 0.75 - 0.20 - - 0.05 0.15 596 1105
4104 mod.1) 4411 Min. 9.0 - - - 0.60 - - - - - - 554 1029
Max. 10.5 0.80 0.25 0.10 0.80 - 0.20 - - 0.05 0.15 596 1105
Hogal 4450 2) 4450 Min. 9.0 - - - 0.16 - - - - - - 577 1071
Max. 11.0 0.30 0.30 0.05 0.25 - 0.10 0.20 - 0.05 0.15 591 1096
Hogal 4470 3) 4470 Min. 11.0 - - - 0.15 - - - - - - 577 1071
Max. 14.0 0.30 0.30 0.15 0.25 - 0.20 - - 0.05 0.15 582 1080
Zn containing 6)
Hogal 4437 4) 4437 Min. 6.8 - - - - - 0.9 - - - - 577 1071
Max. 8.2 0.8 0.25 0.10 - - 1.1 - - 0.05 0.15 605 1121
Hogal 4453 5) 4453 Min. 9.0 - - - - - 0.9 - - - - 577 1071
Max. 11.0 0.8 0.30 0.05 0.05 - 1.1 0.2 - 0.05 0.15 591 1096
For corrosion protection 7)
1145 AA Min. - - - - - - - - - - - 646 1195
Max. Si + Fe max. 0.55 0.05 0.05 0.05 - 0.05 0.03 - 0.05 0.15 657 1215
7072 AA Min. - - - - - 0.8 - - - - 645 1193
Max. Si + Fe max. 0.7 0.10 0.10 0.10 - 1.3 - - 0.05 0.15 657 1215
1) Bi 0.02 - 0.20%2) Hogal 4450 is similar to AA4045 + max. 0.25% Mg3) Hogal 4470 is similar to AA4047 + max. 0.25% Mg4) Hogal 4437 is similar to AA4343 + 1% Zn5) Hogal 4453 is similar to AA4045 + 1% Zn6) Higher Zn concentrations are available on request7) 3xxx series alloys are also available for corrosion protection on request
Further options on request
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Core chemical composition for tubes, side supports, headers [all data on weight -%]Alloy Specifi cation Chemical elements each total Approx. Aleris melting range designation Si Fe Cu Mn Mg Cr Zn Ti Zr 0.05 0.15 °C °F
3003 AA; EN 573 - 3 Min. - - 0.05 1.0 - - - - - - - 643 1189
Max. 0.6 0.7 0.20 1.5 - - 0.10 - - 0.05 0.15 655 1211
3005 AA; EN 573 - 3 Min. - - - 1.0 0.20 - - - - - - 629 1164
Max. 0.6 0.7 0.30 1.5 0.6 0.10 0.25 0.10 - 0.05 0.15 654 1209
3103 AA; EN 573 - 3 Min. - - - 0.9 - - - - - - - 640 1184
Max. 0.50 0.7 0.10 1.5 0.30 0.10 0.20 0.10 - 0.05 0.15 655 1211
Hogal 3190 3190 Min. - - 0.2 1.0 0.40 - - - - - - 629 1164
Max. 0.4 0.70 0.5 1.5 0.70 0.10 0.25 - - 0.05 0.15 654 1209
Hogal 3527 3527 Min. 0.45 0.34 0.6 0.9 - 0.05 - - - - - 643 1189
Max. 0.65 0.44 1.0 1.5 0.1 0.15 0.1 0.1 0.05 0.05 0.15 655 1211
Hogal 3529 3529 Min. 0.45 0.34 0.6 0.9 - 0.05 - - - - - 643 1189
Max. 0.65 0.44 1.0 1.5 0.03 0.15 0.1 0.1 0.05 0.05 0.15 655 1211
Hogal 3532 3532 Min. - - 0.5 0.65 0.1 - - 0.08 - - - 643 1189
Max. 0.3 0.5 0.7 1.00 0.3 - 0.10 0.10 - 0.05 0.15 655 1211
Hogal 3534 3534 Min. - - 0.5 0.65 - - - 0.08 - - - 643 1189
Max. 0.3 0.5 0.7 1.00 0.02 - 0.10 0.10 - 0.05 0.15 655 1211
Corus 3536 3536 Min. - - 0.80 0.75 0.15 - - - 0.05 - -
Max. 0.3 0.5 1.00 1.00 0.24 0.05 - 0.10 0.15 0.05 0.15 on request
Corus 3537 3537 Min. 0.45 0.34 0.90 1.10 - 0.10 - - 0.05 - -
Max. 0.65 0.44 1.10 1.3 0.1 0.25 0.10 0.05 0.15 0,05 0.15 on request
Hogal 3542 3542 Min. - - 0.40 0.90 0.20 - - 0.08 - - - 643 1189
Max. 0.10 0.25 0.60 1.2 0.30 0.05 0.05 0.10 - 0.05 0.15 655 1211
Hogal 3551 3551 Min. 0.5 - 0.1 0.5 - 0.05 - - 0.05 - -
Max 1.25 0.5 0.6 1.25 0.25 0.20 0.25 0.20 0.20 0.05 0.15 on request
Hogal 3570 3570 Min. 0.45 0.40 0.40 0.70 0.30 - - - - - - 616 1141
Max. 0.65 0.60 0.60 0.90 0.40 0.10 0.20 0.20 - 0.05 0.15 654 1209
Hogal 3572 3572 Min. 0.30 - 0.60 1.00 0.27 - - - - - - 616 1141
Max. 0.70 0.40 0.90 1.40 0.32 - 0.15 0.05 - 0.05 0.15 654 1209
6060 EN 573 - 3 Min. 0.30 0.10 - - 0.35 - - - - - - 616 1141
Max. 0.6 0.30 0.10 0.10 0.6 0.05 0.15 0.05 - 0.05 0.15 654 1209
6063 AA; EN 573 - 3 Min. 0.20 - - - 0.45 - - - - - - 616 1141
Max. 0.6 0.35 0.10 0.10 0.9 0.10 0.10 0.10 - 0.05 0.15 652 1206
Some alloys requires a minimum order tonnage for quotationFurther options on request
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Properties pre and post braze (typical values) Core alloy Temper 1) Gauge Pre braze tensile property Post braze tensile property 2) Sagging Electrical (Comments) ASTM B557 ASTM B557 resistance 3) conductivity Yield Tensile Elongation Yield Tensile Free strength strength strength strength Corr. Pot. Rp0.2 Rm A50 Rp0.2 Rm (SCE) ASTM G69 mm MPa MPa % MPa MPa mV mm % IACS
Fin stock
AA3003 H14 0.1 Min. - 140 - 35 100 -710 - -
0.3 Max. >115 180 >1 45 120 -740 - 40.45
3103 H14 0.1 Min. - 140 - 35 100 -710 - -
(low Mg) 0.3 Max. >115 180 >1 45 120 -740 - 40.45
3003 + 1.5% Zn H14 0.1 Min. - 140 - 35 100 -850 - 4) -
0.3 Max. >115 180 >1 45 120 -880 - 4) 40.45
Corus 3555 H16 0.1 Min. - 185 - 50 125 -725 <15 -
(high strength 1.5% Zn) 0.3 Max. >160 220 >0.5 55 145 -745 - 40.4
AA6063 H16 0.1 Min. - 140 - - - -740 - 4) - 4)
0.3 Max. >130 175 >1 70+ 100+ -770 - 4) - 4)
AA6063 H26 0.1 Min. - 130 - - - -740 - 4) - 4)
0.3 Max. >100 175 >6 70+ 100+ -770 - 4) - 4)
1) Other tempers available2) Braze cycle: 600°C / 3 min.3) 50 mm overhang. gauge 0.1 mm4) Available on request
Core chemical composition for bare and clad fi n stock [all data on weight -%]Alloy Specifi cation Chemical elements each total Approx. Aleris melting range designation Si Fe Cu Mn Mg Cr Zn Ti Zr 0.05 0.15 °C °F
Zn free
3003 AA; EN 573 - 3 Min. - - 0.05 1.0 - - - - - - - 643 1184
Max. 0.6 0.7 0.20 1.5 - - 0.10 - - 0.05 0.15 655 1211
Zn containing
3003 + 1.5% Zn - Min. - - 0.05 1.0 - - 1.3 - - - - 640 1184
Max. 0.60 0.7 0.20 1.5 - - 1.5 - - 0.05 0.15 657 1215
Non heat-treatable - high strength
Corus 3555 3555 Min. 0.7 - - 0.7 - - 1.3 - - - - 611 1132
Max. 1.2 0.7 0.5 1.2 0.15 0.1 1.7 0.2 - 0.05 0.15 654 1209
Some alloys requires a minimum order tonnage for quotationFurther options on request
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Properties pre and post braze (typical values) Core Temper 1) Gauge Pre braze tensile property Post braze tensile propertyalloy ASTM B557 ASTM B557 Yield Tensile Elongation Yield Tensile Free strength strength strength strength corrosion Rp0.2 Rm A50 Rp0.2 Rm potential (SCE) 0 days 10 days 20 days 40 days 0 days 10 days 20days 40days ASTM G69 mm MPa MPa % MPa MPa MPa MPa mV
Formed components
AA3003 O - Min. - - - 35 not applicable - not applicable -710
- Max. >35 >125 28 37 115 -740
Hogal 3527 O 1 Min. - - - 50 not applicable 150 not applicable -680
2 Max. >35 >145 >17 60 160 -700
Hogal 3532 O 0.3 Min. - 117 - - not applicable 130 not applicable -680
3 Max. >45 165 >18 50 170 -710
Hogal 3534 O 0.3 Min. - 117 - - not applicable 130 not applicable -680
3 Max. >45 165 >18 48 140 -710
Corus 3537 O 1 Min. - 150 - 50 not applicable 150 not applicable -670
3 Max. >50 190 >17 65 165 -720
Hogal 3542 O 0.3 Min. - 117 - - not applicable 130 not applicable -685
3 Max. >45 165 >18 50 170 -710
Corus 3547 O 1 Min. - 150 - 50 not applicable 150 not applicable -670
3 Max. >50 190 >17 65 165 -720
Corus 3547 H22 1 Min. - 175 - 50 not applicable 150 not applicable -670
3 Max. >155 235 >8 65 165 -720
Corus 3536 O 0.3 Min. - 140 - 55 60 60 60 150 155 160 160 -670
3 Max. >50 180 >18 60 65 65 65 155 160 165 165 -720
Hogal 3551 O 0.5 Min. - 120 - 45 50 60 65 155 160 165 175 -710
3 Max. >35 160 >18 50 60 65 70 160 165 175 185 -740
Hogal 3572 O 1 Min. - 150 - 55 60 65 70 155 160 175 190 -710
3 Max. >50 175 >18 60 65 70 80 160 170 185 200 -740
Hogal 3572 H22 1 Min. - 175 - 55 60 65 70 155 160 175 190 -710
3 Max. >140 235 >8 60 65 70 80 160 170 185 200 -740
Tube stock
AA3003 H14 - Min. - <200 - 35 not applicable 115 not applicable -710
- Max. >120 - >1 37 - -740
Hogal 3190 H24 0.3 Min. - 180 - 55 not applicable 130 not applicable -690
1.0 Max. >145 235 >5 - 180 -720
Hogal 3527 H24 0.2 Min. - 190 - 55 not applicable 155 not applicable -680
0.3 Max. >165 265 >5 60 165 -700
Hogal 3532 H24 0.25 Min. - 165 - 50 not applicable 120 not applicable -680
1 Max. >145 235 >3 - 170 -710
Hogal 3534 H24 0.25 Min. - 165 - 48 not applicable 130 not applicable -680
1 Max. >145 235 >3 - 140 -710
Hogal 3542 H24 0.3 Min. - 165 - 50 not applicable 120 not applicable -685
1 Max. >145 235 >3 - 170 -710
Corus 3537 H24 0.25 Min. - 180 - 60 not applicable 160 not applicable -670
1 Max. >165 265 >5 70 180 -720
Corus 3536 H24 0.25 Min. - 185 - 60 65 70 75 155 165 175 180 -670
1 Max. >165 265 >3 65 70 75 85 165 175 180 190 -720
Hogal 3572 H24 0.25 Min. - 200 - 70 90 100 105 190 215 225 235 -710
1.0 Max. >165 265 >3 80 95 105 110 200 225 235 240 -740
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Aluminum heat exchangers are subject to a wide range of severe environmental conditions, e.g. de-icing road salt, grit, acid exhaust fumes, etc. The heat exchanger can be protected against aggressive external and internal corrosion attacks using the principle of galvanic protection for critical compo-nents and through suitable alloy selection.
A less noble (anodic) alloy will corrode preferentially to a noble (cathodic) alloy when in contact via a corrosive medium. This principle can be applied to the individual components of a heat exchanger (e.g. tubes, headers, tanks, etc.), and it can also be applied to the heat exchanger alloy system itself.
WE CAN ADVISE YOU FURTHER ON ALLOY SELECTION AND COMPATIBILTIY, IF REQUIRED.
Corrosion potential [mV]
-680
-690
-700
-710
-720
-730
0 50 100 150
depth [µm]
clad
length
core
Hogal 3532
Hogal 3190
In addition to the galvanic protection principle, the micro-structure of Aleris’ brazing alloys have been engineered to improve their corrosion life. This alloy development process is ongoing through our continuous R&D activities, and has to date produced a series of “Long-Life” alloys, and more recently multiclad materials.
CORROSION PROTECTION
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1ST GENERATION LONG-LIFE ALLOYS
The special chemical compositions and thermo-mechanical processing of these alloys (e.g. Hogal 3190, 3532, 3534, 3542), have been designed by Aleris to give both high corrosion performance and high strength. On brazing Si diffuses from the clad into the core, where small particles of α-Al(MnFe)Si precipitate along the clad / core interface, this band has a corrosion potential lower than the core and acts to sacrifi cially protect it against external corrosion penetrating through the material depth. In H24 temper these alloys have elongated grains after brazing, which are also advantageous for corrosion, as they create longer grain boundaries compared to other material tempers.
2ND GENERATION AGE HARDENING / HIGH STRENGTH
The use of Cu in these alloys (e.g. Hogal 3572, 3536) creates an additional corrosion protection mechanism in these material, after brazing a Cu depleted band, which is less noble compared to the core material also protects against external corrosion penetrating through the material.
3RD GENERATION “ECO” ALLOYS
Our latest generation of alloys (e.g. Hogal 3551 and 3527) have been designed to provide an economically optimized solution between the performance of the 2nd generation alloys and the cost of the 1st generation alloys. This has been achieved by enhancing the chemistry of these materials to make them both more cost effective and environmentally friendly, as they can require less primary (pure) aluminum in their initial processing.
Figure 1: Standard alloy AA3003, clad AA4104, cross section [x100].
Figure 4: Microstructure: band of dense α-Al(MnFe)Si precipitates, [x500].
Figure 3: Grain structure of Long-Life alloy 3190, grain size ASTM 4 [x100].
Long-Life
alloy
Long-Life
alloy
Long-Life
alloy
Figure 2: Long-Life alloy 3190, clad AA4104, cross section [x100].
Plant KoblenzAleris Rolled Products Germany GmbHCarl-Spaeter-Straße 1056070 Koblenz · GermanyT +49 261 891 7479
Plant DuffelAleris Aluminum Duffel BVBAA. Stocletlaan 872570 Duffel · BelgiumT +32 15 30 2111
Global HeadquartersAleris International, Inc.25825 Science Park DriveCleveland, Ohio 44122 · USAT +1 216 910 [email protected]
European Head offi ce Aleris Switzerland GmbHBalz Zimmermann-Straße 78058 Zürich Airport · SwitzerlandT +41 44 828 [email protected]
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© 2014, Aleris CorporationIssue 5/14 · 1st release
Pictures used by courtesy of Behr GmbH & Co. KG, Haugg Kühlerfabrik GmbH and Modine Manufacturing Company.