MRPL QC LABORATORY - Welcome to Mangalore Refinery … Specification - 2018.pdf · No CHARACTERISTIC UNIT REQUIREMENT TEST METHOD 1 ... percent v/v b) percent evaporated at 100°C

Page 1 of 16

एमआरपीएलएमआरपीएलएमआरपीएलएमआरपीएल

गुणव ा िनयं�ण �योगशालागुणव ा िनयं�ण �योगशालागुणव ा िनयं�ण �योगशालागुणव ा िनयं�ण �योगशाला

आईआईआईआई....एसएसएसएस....उ पादन �विश��उ पादन �विश��उ पादन �विश��उ पादन �विश��:२०१२०१२०१२०१८८८८

MRPL

QC LABORATORY IS PRODUCTS SPECIFICATION:2018

Page 2 of 16

INDIAN STANDARD (IS)

SPECIFICATION FOR DOMESTIC PRODUCTS: 2018

S. No Product Name Specification Number

1 Liquefied Petroleum Gases (LPG) IS 4576: 1999-Second Revision, Reaffirmed 2014,

Amendment 1,2003

2 Motor Gasoline – MG 91 BS IV IS 2796:2017- 6th

Revision

3 Aviation Turbine Fuels, (ATF)

Kerosene Type, JET A-1

IS 1571:2017, 9th

revision, and Defence Standard

91-091, Issue 9,dated 03.10.2016 & JIG(AFQRJOS)

Issue 29,October 2016

4 Kerosene-SKO IS 1459: 2016, 3rd

Revision, Amendment 1

5 Automotive Diesel Fuel (HSD)-

BS IV

IS 1460: 2017,6th

Revision

6 Diesel Fuels (High Flash) IS 1460:2000-4th

Revision

7 Fuel Oil- MV2 Grade IS 1593: 1982, Reaffirmed 2014, Second Revision,

Amendment 1 & 2

8 Paving Bitumen -VG 30 IS 73: 2013, 4th

Revision


Revision


Revision

11

12

13

14

15

Page 3 of 16

SPECIFICATION FOR LIQUEFIED PETROLEUM GAS

(Commercial Butane-Propane Mixture) IS 4576 – 1999

S. No CHARACTERISTIC UNIT REQUIREMENT TEST METHOD

1 Density@ 15°C g/ml Report ASTM D 2598

2 Vapour pressure at 40°C kPa 1050 Max. ASTM D 1267

3 Composition, Liquid - ASTM D 2163

i. C2 Hydrocarbons (Ethane) Vol% Report -

ii. C3 Hydrocarbons (Propane) Vol% Report -

iii. C4 Hydrocarbons (Iso- Butane) Vol% Report -

iv. C4 Hydrocarbons (n- Butane) Vol% Report -

v. C5 Hydrocarbons & Heavier Vol% Max 2.5 -

vi. Unsaturated Hydrocarbons Vol% Report -

OR - -

4 Volatility evaporation

temperature in °C for 95 % by vol.

at 760 mm Hg pressure

°C Max +2 ASTM D 1837

5 Total Volatile Sulphur ppm Max 150.0 ASTM D 3246

6 Copper Corrosion @ 38°C, for 1

hour.

Not worse

than No. 1

ASTM D 1838

7 Hydrogen Sulfide Pass ASTM D 2420

8 Free water Content None VISUAL

Page 4 of 16

SPECIFICATION FOR MOTOR GASOLINE

(REGULAR)MG 91 BHARAT STAGE IV

IS 2796 – 2017 S.NO CHARACTERISTIC TEST

METHOD

LIMIT REQUIREMENT TEST RESULTS

1 Appearance Visual - Clear and bright, Free

from un-dissolved

water, foreign matter

and other impurities.

Clear and bright, Free

from un-dissolved

water, foreign matter

and other impurities.

2 Colour Visual - Orange

3 Density at 15°,kg/m3 ASTM D

4052

- 720 to 775

4 Distillation

a) percent evaporated

at 70°C (E 70°C),

percent v/v

b) percent evaporated

at 100°C (E 100°C),

percent v/v

c) percent evaporated

at 150°C (E 150°C),

percent v/v

d) Final boiling point,°C

e) Residue, percent by

volume

ASTM D 86

-

-

Min

Max

Max

10-45

40-70

75

210

2.0

5 Research octane

number (RON)

IS 1448

P:27

Min 91

6 Motor octane number

(MON)

IS 1448

P:26

Min

81

7 Gum content (Solvent

washed),g/m3

IS 1448

P:29

Max 40

8 Total sulphur, mg/kg ASTM D

5453/P:153

Max 50

9 Lead content (as Pb), g/l IP 224 # Max 0.005

10 Reid vapour pressure

(RVP) at 38°C, kPa

IS 1448

P: 39

Max 60

11 Vapour lock index (VLI)

VLI= 10 RVP+7E 70°C

Calculation Max 750 Summer

950 Other months

12 Benzene content

percent by volume

ASTM D

3606

Max 1.0

13 Copper strip corrosion

for 3 h at 50°C

IS 1448

P:15

- Not worse than

No.1

14 Water tolerance of

motor gasoline-alcohol

blends, temperature for

phase separation

IS

2796:2017

Annex-B #

Max 0°C Winter

10°C Other months

Page 5 of 16

15 Engine intake system

cleanliness

- - Report MFA used

16 Olefin content, percent

by volume

ASTM D

1319/IS

1448 P:23

Max 21

17 Oxidation stability,

minutes

IS 1448

P:28

Min 360

18 Aromatics content,

percent by volume

ASTM D

1319/IS

1448 P:23

Max 35

19 Oxygen content,

percent by mass

ASTM D

6839 #

Max 3.7

20 Ethanol content,

percent by volume

ASTM D

4815 #

Max 5.0 NA

21 Oxygenates percent by

volume

a) Ethers containing 5 or

more ‘C’ atoms per

molecules such as

MTBE,ETBE or TAME

b) Any other oxygenates

ASTM D

4815-

Annex C #

Max

-

15

Not permitted

Remarks:

Notes:

1. The Quality Certificate shall not be reproduced except in full, without written approval of the

Laboratory.

2. Reported results are pertaining to the sample received at laboratory.

3. MRPL Motor Gasoline does not contain any oxygenates.

4. NA : Not Applicable

5. Summer shall be the period from April to July months.

6. # Not under the scope of NABL Accreditation.

Page 6 of 16

SPECIFICATION FOR AVIATION TURBINE FUEL JET A-1

IS 1571-2017 -DOMESTIC Def Stan 91-091 Issue 9 and AFQRJOS issue 29, dated 03.10.2016

S.NO CHARACTERISTIC TEST

METHOD


1 Appearance:

a) Visual appearance Visual - Clear, bright and free

from solid matter and

un-dissolved water at

ambient fuel

temperature.

Clear, bright and free

from solid matter and

un-dissolved water at

ambient fuel

temperature.

b) Colour ASTM D

6045

- Report

c) Particulate

contamination at point

of manufacture.mg/l

ASTMD

5452

Max 1.0

d) Particulate, at point of

manufacture,

cumulative channel

particle counts,

1) ≥ 4 µm(c)

2) ≥ 6 µm(c)

3) ≥ 14 µm(c)

4) ≥ 21 µm(c)

5) ≥ 25 µm(c)

6) ≥ 30 µm(c)

IP 565 - ISO code

Channel counts

Report

Report

Report

Report

Report

Report

2 Composition:

a) Total acidity, mg KOH/g IS 1448

P:113

Max 0.015

b) Aromatics, percent by

volume

IS 1448

P:23

Max 25.0 (22.0 Defence

Max)

c) Total sulphur, percent

by mass

ASTM D

4294


Max)

d) Sulphur mercaptan ,

percent (m/m)

IS 1448

P:109


Max)

e) Doctor Test IS 1448

P:19

- Negative

f)

Refining components, at

the point of manufacture

1) Non-hydro processed

components, percent (v/v)

- - Report

2) Severely Hydro

processed components,

percent (v/v)

- - Report

3) Mildly hydro processed

components, percent (v/v)

- - Report

4) Synthetic components,

percent (v/v)

- - Report

Page 7 of 16

3 Volatility:

a) Distillation:

1) Initial boiling point,°C

2) 10 percent recovery

°C (v/v)


°C (v/v)


°C (v/v)

5)Final boiling point,°C

6) Residue,percent(v/v)

7) Loss ,percent (v/v)

ASTM D

86

Max

Max

Max

Max

Report

205.0

Report

Report

300.0

1.5

1.5

b) Flash point (Abel),°C IP 170 Min 38.0

c) Density at 15°C,kg/m3 ASTM D

4052

- 775.0 to 840.0

4 Fluidity:

a) Freezing point,°C ASTM D

5972

Max Minus 47

b) Kinematic viscosity at

minus 20°C, mm2/s

IS 1448

P:25

Max 8.000

5 Combustion:

a) Specific energy MJ/kg

or

Product of API gravity

and aniline point.

ASTM D

3338

IS 1448

P:3

Min 42.80

4800

b) Smoke point, mm or

1) Smoke point, mm

2) Naphthalenes,

percent (v/v)

IP 598

IS 1448

P:118

Min

Min

Max

25.0

19.0

3.00

-

6 Corrosion:

a) Copper strip corrosion

for 2 h at 100°C

IS 1448

P:15

- Not worse than No.1

b) Silver strip corrosion

Classification for 4 h at

50°C

IP 227 - “0” at Refinery point

“1” at Delivery point

7 Thermal stability at control Temperature

of 260°C.

a)

b)

Filter pressure

differential, mm Hg

Tube rating, visual

IS 1448

P:97

Max

25

Less than 3,No

‘Peacock’ (P) or

‘Abnormal’ (A)

8 Contaminants:

a) Existent gum, mg/100ml

or

IS 1448

P:29

Max 7 -

b) Existent gum with air,

mg/100 ml

7

9 Water Separation Characteristic:

a) Water reaction:

Interface rating

IS 1448

P:42

Max 1b

b) Micro separometer

rating at the point of

IS 1448

P:142

Page 8 of 16

manufacture:

1) MSEP without SDA

2) MSEP with SDA

Min

Min

85

70

-

10 Conductivity

Electrical conductivity,

pS/m (at the point,time &

temperature of delivery)

ISO 6297 Min

Max

50

600

11 Lubricity:

Wear scar diameter,mm ASTM D

5001

Max 0.85(0.65 Defence

Max)

12 Additives:

a) Static dissipater

additive (SDA, mg/l) Qualification ref no: RDE/A/621

b) Antioxidant (for

Hydro processed Qty)

,mg/l Qualification ref no: RDE/A/607

- Max

-

3.0

17 to 24

Remarks:

Notes:

1. Latest methods of IS 1448 used for testing unless specified otherwise.


Laboratory.

3. No additive is added other than the ones mentioned in S. No: 12.

4. Both number of particles and number of particles as a scale number as defined under Table of ISO

4406:1999 are reported.

5. FAME Content- Not measured-Risk assessed in accordance with JIG Bulletin 75.

`

Page 9 of 16

SPECIFICATION FOR KEROSENE

IS 1459 -2016 S.NO CHARECTERISTIC TEST

METHODS

LIMIT REQUIREMENT TEST RESULT

1 Acidity,inorganic ASTM D

974

- Nil

2 Burning quality

a) Char value,mg/kg of

oil consumed.

IS 1448 P:5 Max

20

b) Bloom on glass

chimney

- Not darker than

grey

3 Colour

a) Saybolt (in case of

undyed kerosene)

ASTMD 156 Min 10

b) Visual (in case of

dyed kerosene)

Visual

Annex A

- Blue NA


for 3 h at 50°C

IS 1448

P:15

- Not worse than

No.1


4052

- Not limited ,but to

be reported

6 Distillation,

a) Percent recovered

upto 200°C,percent

(v/v)

b) Final boiling point ,°C

ASTM D 86 Min

Max

20

300

7 Flash point (Abel),°C IP 170 Min 35

8 Smoke point, mm IS 1448

P:31

Min 18

9 Total sulphur content,

percent, m/m

ASTM D

4294

Max 0.20

Remarks:

Notes: 1. The Quality Certificate shall not be reproduced except in full, without written approval of the

Laboratory.

2. Only latest version is used for all test methods.


4. Test in serial no. 2, is done at refinery end only.

5. The material is free from visible water, sediment and suspended matter and not doped with blue

dye.

Page 10 of 16

SPECIFICATION FOR AUTOMOTIVE DIESEL FUEL (BHARAT STAGE IV)

IS 1460 – 2017 S.NO CHARACTERISTIC TEST

METHOD


1 Appearance Visual - Clear, bright and free

from sediments,

suspended matter and

undissolved water at

normal ambient fuel

temperature

Clear, bright and free

from sediments,

suspended matter

and undissolved

water at normal

ambient fuel

temperature

2 Acidity,inorganic,mg of

KOH/g

ASTM D

974

- Nil

3 Acidity,total,mg of

KOH/g

ASTMD

974

Max 0.20

4 Ash,percent by mass IS 1448

P:4

Max 0.01

5 Carbon

residue(Ramsbottom or

micro) on 10 percent

residue,percent by mass

ASTM D

4530

Max 0.30

6 Cetane number IS 1448

P: 9

Min 51

7 Cetane index IP 380 Min 46

8 Pour point ASTM D

5950

Max 3 °C Winter

15 °C Summer


for 3 h at 50°C

IS 1448

P:15

- Not worse than No.1

10 Distillation,95 percent

v/v, recovery, °C

ASTM D

86

Max 360

11 Flash point,

a) Abel, °C IP 170 Min 35

b)PMCC,°C ASTM D

93A

Min 66

12 Kinematic viscosity, cSt,

at 40°C

IS 1448

P:25

- 2.0 to 4.5

13 Total contamination,

mg/kg

IP 440 Max 24


4052

- 815 to 845

Page 11 of 16

15 Total sulphur, mg/kg ASTM D

5453/D

4294

Max 50

16 Water content, mg/kg ISO 12937 Max 200

17 Cold Filter Plugging

Point (CFPP)

ASTM D

6371

- 6°C Winter

18°C Summer

18 Oxidation stability,g/m3 IS 1448

P:154

Max 25

19 Polycyclic Aromatic

Hydrocarbon

(PAH),percent by mass

IP 391 Max 8

20 Lubricity corrected wear

scar diameter (wsd 1.4)

at 60°C,microns

ISO

12156/P:

149

Max 460

21 FAME content,% v/v ASTM D

7371#

Max 7.0 - *

Remarks:

Notes:


Laboratory.


3. MRPL Diesel fuel does not contain any residuum oil and ignition improver additives.

4. Whenever Abel Flash point exceeds 66°C, PMCC flash point value will be reported.

5. Winter months are from November to February, rest of the months of the year shall be called as

summer.

6. # Not under the scope of NABL Accreditation.

7. * MRPL Automotive Diesel Fuel does not contain any FAME/Biodiesel, so FAME analysis is not

applicable.

Page 12 of 16

SPECIFICATION FOR DIESEL FUEL (HIGH FLASH) IS 1460 – 2000


1 Acidity ,Inorganic mg KOH/gm Nil IS 1448, P: 2

2 Acidity ,Total mg KOH/gm Max 0.20 IS 1448, P: 2

3 Ash % Mass Max 0.01 IS 1448, P: 4

4 Carbon residue (Ramsbottom) On

10% Residue

% Mass Max 0.30 IS 1448, P: 8

5

Cetane Number OR Min 48.0 IS 1448, P: 9

6 Cetane Index Min 46 .0 ASTM D 4737

7

Pour Point °C Max 12°C, for

winter

IS 1448, P: 10

°C Max 18°C, for

summer

8 Copper strip Corrosion for 3 hours

@ 100 deg. C

Not worse

than No.1

IS 1448, P: 15

9 Distillation, % v/v, recovered:

at 350°C

at 370°C

% Vol

Min 85.0

Min 95.0

IS 1448, P: 18

10 Flash Point (PMCC) °C Min 66.0 IS 1448, P: 21

11 Kinematic Viscosity @ 40 deg. C cSt Range 2.0 to

5.0

IS 1448, P: 25

12 Sediment % Mass Max 0.05 IS 1448 ,P:30

13 Density @ 15 deg. C kg/m3 Range 820-860 IS 1448 ,P:16

14 Total Sulphur % Mass Max 0.25 ASTM D 4294

15 Water content % Vol Max 0.05 IS 1448 ,P:40

16 Cold Filter Plugging Point (CFPP) °C Max 6°C for

winter

IP 309

°C Max 18°C for

Summer

17 Total Sediments mg/100ml Max 1.5 ASTM D 2274

Page 13 of 16

SPECIFICATION FOR FURNACE OIL MV2 Grade

IS 1593 – 1982

Note: Tests indicated in Sl. No. 11-14 is as per customer requirements.


1 Acidity, Inorganic Mg KOH/gm Nil IS 1448, P: 2

2 Ash % Mass Max 0.1 IS 1448, P: 4

3 Gross Calorific Value Cal/gm Report IS 1448, P: 7

4 Relative Density @ 15/15°C - Report IS 1448, P: 32

5 Flash Point (PMC) °C Min 66.0 IS 1448, P: 21

6 Kinematic Viscosity at 50 ° C cSt Max 180 IS 1448, P: 25

7 Sediment % Mass Max 0.25 IS 1448, P: 30

8 Total Sulphur % Mass Max 4.0 ASTM D 4294 IS

1448,P:33

9 Water content % Vol Max 1 0 IS 1448, P: 40

10 Pour Point °C Report ASTM D 97

11 Cleanliness Number Report ASTM D 4740

12 Micro Carbon Residue % Mass Report ASTM D 4530

13 Asphaltenes % Mass Report IP 143

14 Net calorific value Cal/gm Report IS 1448 P:6

Page 14 of 16

SPECIFICATION FOR PAVING BITUMEN (VG 30) IS 73 - 2013


1 Specific Gravity/Density

at 27°C/27°C

- Report IS 1202

2 Absolute Viscosity at

60°C

poises Range 2400-3600 IS 1206(Part 2)

3 Kinematic viscosity at

135°C

cSt Min 350 IS 1206(Part 3)

4 Flash Point (COC) °C Min 220 IS 1448 P:69

5 Solubility in

Trichloroethylene

% Min 99.0 IS : 1216

6 Penetration at 25 ° C,100

g,5 sec

0.1 mm Min 45 I S: 1203

7 Softening Point (R&B) °C Min 47 I S: 1205

8 Tests on Residue from

thin film oven tests/

RTFOT

i) Viscosity ratio at 60°C Calculation Max 4.0 IS 1206(Part 2)

ii) Ductility at 25°C, cm,

after Rotating thin film

oven test

cm Min 40 IS 1208

Page 15 of 16



1 Specific Gravity/Density at

27°C/27°C

- Report IS 1202

2 Absolute Viscosity at 60°C poises Range 800-1200 IS 1206(Part 2)


135°C


4 Flash Point (COC) °C Min 220 IS 1448, P:69

5 Solubility in

Trichloroethylene

% Min 99.0 IS : 1216

6 Penetration at 25 °C,100

g,5 sec

0.1 mm Min 80 I S: 1203




RTFOT


ii) Ductility at 25°C, cm, after

Rotating thin film oven

test

cm Min 75 IS 1208

Page 16 of 16



1 Specific Gravity/Density

at 27°C/27°C

- Report IS 1202

2 Absolute Viscosity at

60°C

poises Range 3200-4800 IS 1206(Part 2)


135°C


4 Flash Point (COC) °C Min 220 IS 1448 P:69

5 Solubility in

Trichloroethylene

% Min 99.0 IS : 1216

6 Penetration at 25 ° C,100

g,5 sec

0.1 mm Min 35 I S: 1203




RTFOT


ii) Ductility at 25°C, cm,

after Rotating thin film

oven test

cm Min 25 IS 1208

Documents

MRPL QC LABORATORY - Welcome to Mangalore Refinery … Specification - 2018.pdf · No CHARACTERISTIC UNIT REQUIREMENT TEST METHOD 1 ... percent v/v b) percent evaporated at 100°C