Shetland Islands Scotland Product Guide - EPC-UK · Product Guide - Explosives and Accessories - 2017/18. EPC-UK safety data sheets are designed to give ‘at a glance’ information

Product GuideExplosives and Accessories 2017/18

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Product Guide - Explosives and Accessories - 2017/18

EPC-UK safety data sheets are designed to give ‘at a glance’ information and product profile.

Terms and Conditions

“The products and services that we supply to you are sold subject to our standard Terms and Conditions of Supply and any other Special Conditions that we notify to you. Copies of these conditions are available on request.”

The information contained in this booklet is given without warranty and cannot cover all conditions of use. Users should undertake their own tests to ensure the suitability of the products for their own particular application.

The EPC Groupe is one of the world’s leaders in explosives manufacture, storage and distribution and in particular drilling and blasting. For over 120 years, the EPC Groupe has enjoyed a reputation for effective solutions, technological innovation and high-quality customer service.

Our motto, CONCENTRATED ENERGY®, is the very essence of modern industrial explosives, which require precision, care and the highest standards of quality and safety. EPC-UK is an established full service provider, through its unrivaled capability, depth of experience and professionalism, as well as offering a full range of products and support services including consultancy, training and integrated on site blasting.

Safety FirstSafety is at the forefront of everything we do. EPC-UK has introduced the DuPont Safety programme, which was originally initiated by the EPC Groupe. The DuPont programme is focused on reducing the risk of accidents by monitoring behaviour patterns and improving the safety culture within an organisation.

Delivering ProfessionalismOur ethos is simple. We work in some of the most demanding fields in the world, and we understand that our customers require solutions that are not only effective but safe, secure and ethical. With EPC Groupe, you can be assured of the highest standards of safety, professionalism and care.

YOUR SAFETY IS OUR CONCERN

SAFETYEVERYDAY

Contents

1. Ammonium Nitrate

2. ANFO

3. Black Powder

4. Boosters

5. Bulk Emulsions

6. Detonating Cord

7. Electric Detonators

8. Electronic Detonators

9. Non - Electric Detonators

10. Emulsion Primers

11. Authorised Nitroglycerine Explosives

12. Packaged Explosives

13. Blasting Accessories

14. Blasting and Support Services

Ammonium Nitrate

Ammonium Nitrate is a white crystalline, dry prill with the chemical formula NH4NO3. It is made by reacting nitric acid with anhydrous ammonia under very carefully controlled conditions.

The resulting material is further processed to form granular prills.

Pure Ammonium Nitrate is water soluble. Conditioning agents are added to Ammonium Nitrate so a typical analysis is 34.5% Nitrogen by weight.

Ammonium Nitrate (oxidiser) is used extensively in the mining industry and is intentionally made very porous to allow for the rapid uptake of liquid fuel oil (fuel). This ANFO mixture then becomes an explosive product.

A range of explosive grade porous prill Ammonium Nitrates are sold by EPC-UK Explosives. Ammonium Nitrate can be supplied in either 25kg bags or 1 tonne bags depending on the grade supplied.

1

Ammonium Nitrate Data

PRODUCT AND COMPANY IDENTIFICATION

Product Identifier Ammonium Nitrate, porous grade.

Use of the Product Porous Ammonium Nitrate for the on-site manufacture of ANFO explosives.

Manufacturer / Supplier EPC-UK EXPLOSIVES

Address ROUGH CLOSE WORKS CARNFIELD HILL SOUTH NORMANTON ALFRETON DERBYSHIRE, DE55 2BE

Telephone Number 01773 832253

Contact e-mail [email protected]

Emergency Telephone Number

01773 832253

HAZARD IDENTIFICATION

Classification of Mixture Ox sol 3 H272 May intensify fire; oxidizer.

Eye irrit. 2 H319 Causes serious eye irritation.

Hazard Pictogram

Signal Word Warning

Hazard statements H272 May intensify fire; oxidizer. H319 Causes serious eye irritation.

Precautionary statements - Prevention

Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. Take any precaution to avoid mixing with combustibles. Wear eye protection.

Label elements

Safety data sheet according to the REACH regulations as amended by EC Regulation 2015/0830


HAZARD IDENTIFICATION Continued...

Precautionary statements - Intervention

IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: get medical attention. In case of fire: Use flooding quantities of water to extinguish.

Substance meets the criteria for PBT Substance meets the criteria for vPvB Other hazards which do affect the classification

Not applicable. Not applicable. Product forms slippery surface when combined with water.

COMPOSITION/INFORMATION ON THE INGREDIENTS

Mixtures

Other Hazards

Dangerous substance

Concentration range

REACHregistration

EC Number

CASNumber

CLP Classification

Ammonium Nitrate

>90% 01-211949 0981-27

229-347-8

6484-52-2

Ox. Sol. 3; H272,Eye Irrit. 2; H319.

FIRST AID MEASURES

General

First Aid – Eyes Rinse with plenty of running water. Check for and remove any contact lenses. If irritation persists, get medical attention.

First Aid – Skin Wash with soap and water. Get medical attention if irritation develops.

First Aid – Ingestion Wash out mouth with water. If material has been swallowed and the exposed person is conscious, give small quantities of water to drink. Do not induce vomiting unless directed to do so by medical personnel.

Description of First Aid Measures

FIRST AID MEASURES Continued

First Aid – Inhalation If inhaled, remove to fresh air. In case of inhalation of decomposition products in a fire, symptoms may be delayed. The exposed person may need to be kept under medical surveillance for 48 hours.

First Aider Self-Protection No action shall be taken involving any personal risk or without suitable training. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation.

Eye contact Causes serious eye irritation.

Skin contact No known significant effects or critical hazards.

Inhalation Exposure to decomposition products may cause a health hazard. Serious effects may be delayed following exposure.

Ingestion Irritating to mouth, throat and stomach.

Eye contact Adverse symptoms may include the following: pain or irritation watering redness

Skin contact No specific data.

Inhalation No specific data.

Ingestion No specific data.

Notes to physicians Treat symptomatically. Contact poison treatment specialist immediately if large quantities have been ingested or inhaled. In case of inhalation of decomposition products in a fire, symptoms may be delayed. The exposed person may need to be kept under medical surveillance for 48 hours.

Specific treatments No Specific treatment.

Most Important Symptoms and Effects, Both Acute and Delayed

Indication of Any Immediate Medical Attention and Special Treatment Needed

Potential Acute Health Effects

Over-exposure signs/symptoms


FIRE FIGHTING MEASURES

Extinguishing Media Appropriate: Use flooding quantities of water to extinguish. Inappropriate: Do NOT use chemical extinguisher or foam or attempt to smother the fire with steam or sand.

Special Hazards Arising from Product

Oxidizing material. May intensify fire. The product itself is not combustible but it can support combustion, even in absence of air. On heating it melts and further heating can cause decomposition, releasing toxic fumes containing nitrogen oxides and ammonia. It has high resistance to detonation. Heating under strong confinement can lead to explosive behaviour.

Hazardous thermal decomposition products

Decomposition products may include the following materials: nitrogen oxides, ammonia. Avoid breathing dusts, vapours or fumes from burning materials. In case of inhalation of decomposition products in a fire, symptoms may be delayed.

Advice for Firefighters Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training. Move containers from fire area if this can be done without risk. Use water spray to keep fire-exposed containers cool. Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode. Clothing for fire-fighters (including helmets, protective boots and gloves) conforming to European standard EN 469 will provide a basic level of protection for chemical incidents. The product itself is not combustible but it can support combustion, even in absence of air. On heating it melts and further heating can cause decomposition, releasing toxic fumes containing nitrogen oxides. It has high resistance to detonation. Heating under strong confinement can lead to explosive behaviour.

ACCIDENTAL RELEASE MEASURES

Personal precautions, protective equipment and emergency procedures

For non-emergency personnelNo action shall be taken involving any personal risk or without suitable training. Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. Do not touch or walk through spilled material. Shut off all ignition sources. No flares, smoking or flames in hazard area. Provide adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put on appropriate personal.For emergency respondersIf specialized clothing is required to deal with the spillage, take note of any information in Exposure Control/Personal Protection on suitable and unsuitable materials. See also the information in “For non-emergency personnel”.

Environmental Precautions Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air).

Methods and material for containment and cleaning up

Small spill Move containers from spill area. Use spark-proof tools and explosion-proof equipment. Avoid dust generation. Using a vacuum with HEPA filter will reduce dust dispersal. Place spilled material in a designated, labelled waste container. Dispose of via a licensed waste disposal contractor. Large spill Move containers from spill area. Use spark-proof tools and explosion-proof equipment. Approach release from upwind. Prevent entry into sewers, water courses, basements or confined areas. Avoid dust generation. Do not dry sweep. Vacuum dust with equipment fitted with a HEPA filter and place in a closed, labelled waste container. Dispose of via a licensed waste disposal contractor.

Reference to other sections See Product and Company Identification for emergency contact information. See Exposure Control/Personal Protection for information on appropriate personal protective equipment. See Disposal Considerations for additional waste treatment information.


HANDLING AND STORAGE

Precautions for Safe Handling

Protective measuresPut on appropriate personal protective equipment (see Exposure Control/Personal Protection). Do not ingest. Avoid contact with eyes, skin and clothing. Keep in the original container or an approved alternative made from a compatible material, kept tightly closed when not in use. Keep away from clothing, incompatible materials and combustible materials. Keep away from heat. Empty containers retain product residue and can be hazardous. Do not reuse container. Advice on general occupational hygiene.Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Workers should wash hands and face before eating, drinking and smoking. Remove contaminated clothing and protective equipment before entering eating areas. See also Exposure Control/Personal Protection for additional information on hygiene measures.

Conditions for safe storage, including any incompatibilities

Store in accordance with local regulations. Store in original container protected from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see Stability and Reactivity) and food and drink. Separate from reducing agents and combustible materials. Keep container tightly closed and sealed until ready for use. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabelled containers. Use appropriate containment to avoid environmental contamination. Keep away from: organic materials, oil and grease.

Specific end use(s) Used for site mixing of ANFO.

Seveso Directive - Reporting thresholds

Category Notification and MAPP threshold

Safety report threshold

Ammonium nitrate 350 t 2,500 t

EXPOSURE CONTROL / PERSONAL PROTECTION

Control Parameter Occupational Exposure Limit

No exposure limit value known.

Product / ingredient name

Type Exposure Value Population Effects

Ammonium nitrate DNEL Long term Dermal

21.3 mg/kg bw/day

Workers Systemic

Ammonium nitrate DNEL Long term Inhalation

37.6 mg/m³ Workers Systemic

Product / ingredient name Type Compartment Detail

Value Method Detail

Ammonium nitrate PNEC Fresh water 0.45 mg/l Assessment Factors

Ammonium nitrate PNEC Marine water 0.045 mg/l Assessment Factors

Ammonium nitrate PNEC Intermittent release

4.5 mg/l Assessment Factors

Ammonium nitrate PNEC Sewage Treatment Plant

18 mg/l Assessment Factors

DNELs/DMELs

PNECs

Engineering measures Good general ventilation should be sufficient to control worker exposure to airborne contaminants.

Hygiene measures A washing facility or water for eye and skin cleaning purposes should be present.

Eye/face protection Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid exposure to liquid splashes, mists, gases or dusts. Recommended: Tightly-fitting goggles CEN: EN166.

Exposure controls

Individual protection/ PPE


EXPOSURE CONTROL / PERSONAL PROTECTION Continued

Hand protection Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary. > 8 hours (breakthrough time): Protective gloves should be worn under normal conditions of use.

Body protection Personal protective equipment for the body should be selected based on the task being performed and the risks involved.

Other skin protection Appropriate footwear and any additional skin protection measures should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product.

Respiratory protection In case of inadequate ventilation wear respiratory protection. Recommended: Filter P2 (EN 143)

Environmental exposure controls

Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation. In some cases, fume scrubbers, filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels.

Skin protection

PHYSICAL AND CHEMICAL PROPERTIES

Appearance/ colour Solid white prills.

Odour Odourless.

Odour threshold Not determined.

pH > 4.5 [Conc. (% w/w): 100 g/l]

Melting point 169.6°C

Initial boiling point and boiling range

Not determined.

Flash point Not determined.

Basic physical and chemical properties

PHYSICAL AND CHEMICAL PROPERTIES Continued

Evaporation Rate Not determined.

Flammability Non-flammable.

Upper / lower flammability or explosive limits

Not determined.

Vapour pressure Not available.

Vapour density Not available.

Density Ca 800 kg/m3

Solubility(ies) > 100 g/l in water @ 20 °C

Partition coefficient (n-octanol / water)

<1

Auto-ignition temperature Not determined.

Decomposition temperature >210°C

Viscosity Not determined.

Explosive properties None.

Oxiding properties Oxidiser.

Other information No additional information.

STABILITY AND REACTIVITY

Reactivity No specific test data related to reactivity available for this product or its ingredients.

Chemical Stability The product is stable.

Possibility of hazardous reactions

Hazardous reactions or instability may occur under certain conditions of storage or use. Conditions may include the following: contact with combustible materials. Reactions may include the following: risk of causing or intensifying fire.

Conditions to avoid Avoid contamination by any source including metals, dust and organic materials.

Incompatible materials Reactive or incompatible with the following materials: alkalis combustible materials reducing materials organic materials acids

Hazardous Decomposition Products

Under normal conditions of storage and use, hazardous decomposition products should not be produced.


TOXICOLOGICAL INFORMATION

Information on toxicological effects

Acute toxicity

Skin corrosion / irritation

Conclusion/Summary: No known significant effects or critical hazards.


Result Species Dose Exposure References

Ammonium nitrate

LD50 Oral Rat 2,950 mg/kg OECD 401

- IUCLID 5

LD50 Dermal

Rat > 5,000 mg/kg OECD 402

- IUCLID 5


Result Species Score Exposure Observation References

Ammonium nitrate

Eyes - Irritant OECD 405

Rabbit - IUCLID 5

Skin No known significant effects or critical hazards.

Eyes Causes serious eye irritation.

Respiratory No known significant effects or critical hazards.

Skin No known significant effects or critical hazards.

Respiratory No known significant effects or critical hazards.

Mutagenicity Conclusion/Summary

No known significant effects or critical hazards.

Carcinogenicity Conclusion/Summary


Conclusion/Summary

Sensitisation Conclusion/ Summary

TOXICOLOGICAL INFORMATION Continued

Conclusion/Summary No known significant effects or critical hazards.

Information on the likely routes of exposure


Inhalation Exposure to decomposition products may cause a health hazard. Serious.

Ingestion Irritating to mouth, throat and stomach.

Skin contact No known significant effects or critical hazards.

Eye contact Causes serious eye irritation.

Inhalation No specific data.

Ingestion No specific data.

Skin contact No specific data.

Eye contact Adverse symptoms may include the following: pain or irritation watering redness.

Potential immediate effects No known significant effects or critical hazards.

Potential delayed effects No known significant effects or critical hazards.

Teratogenicity

Potential acute health effects

Symptoms related to the physical, chemical and toxicological characteristics

Delayed and immediate effects and also chronic effects from short and long term exposure Short term exposure

Reproductive Toxicity


Maternal toxicity

Fertility Development toxin

Species Dose Exposure References

Ammonium nitrate

- Negative Negative Rat Oral : > 1500 mg/kg bw/day

28 days IUCLID 5




Potential immediate effects No known significant effects or critical hazards.

Potential delayed effects No known significant effects or critical hazards.

Conclusion/Summary No known significant effects or critical hazards.

General No known significant effects or critical hazards.

Carcinogenicity No known significant effects or critical hazards.

Mutagenicity No known significant effects or critical hazards.

Teratogenicity No known significant effects or critical hazards.

Developmental effects No known significant effects or critical hazards.

Fertility effects No known significant effects or critical hazards.

Long term exposure

Potential Chronic Health Effects


Result Species Dose Exposure References

Ammonium nitrate

Chronic NOAEL Oral

Rat 256 mg/kg OECD 422

28 days IUCLID 5

Sub-acute No-observable-effect-concentration Dusts and mists Inhalation

Rat > 185 mg/kg OECD 412

2 weeks 5 hours per day

IUCLID 5

ECOLOGICAL INFORMATION

Persistence and Degradability

Determination methods not applicable.

Soil/water partition coefficient (KOC)

Not available.

Mobility Not available.

PBT Assessment Not applicable.

vPvB Assessment Not applicable.

Other Adverse Effects No known significant effects or critical hazards.

Toxicity

Bioaccumulation potential:

Mobility in soil

Result of PBT and vPvB Assessment


Result Species Exposure References

Ammonium nitrate

Acute LC50 447 mg/l Fresh water

Fish - Fish 48 h IUCLID 5

Acute EC50 490 mg/l Fresh water

Aquatic invertebrates. Daphnia

48 h IUCLID 5

Acute EC50 1,700 mg/l Salt water

Aquatic plants - Algae

10 d IUCLID 5


LogPow BCF Potential References

Ammonium nitrate porous prills 34.5

< 1 - low




DISPOSAL CONSIDERATIONS

Product disposal The generation of waste should be avoided or minimized wherever possible. Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Waste should not be disposed of untreated to the sewer unless fully compliant with the requirements of all authorities with jurisdiction.

Waste treatment methods

European Waste catalogue

Waste code Waste designation

06 10 02* Wastes containing dangerous substances

Container Disposal The generation of waste should be avoided or minimized wherever possible. Waste packaging should be recycled. Incineration or landfill should only be considered when recycling is not feasible. Empty the bag by shaking to remove as much as possible of its contents. Empty bags may be disposed of as non-hazardous material or returned for recycling.

Special precautions This material and its container must be disposed of in a safe way. Care should be taken when handling emptied containers that have not been cleaned or rinsed out. Empty containers or liners may retain some product residues. Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers.

TRANSPORT INFORMATION

UN Number UN1942

UN Proper Shipping Name Ammonium nitrate

Transport Hazard Classes 5.1

Packing Group PGIII

Environmental Hazards No

Additional information Hazard Identification Number: 50 Emergency Action Code number: 1Z Tunnel Code (E)

UN Number UN1942



Packing Group PGIII


Additional information Danger Code Not applicable

UN Number UN1942



Packing Group PGIII


Additional information Marine Pollutant: No IMDG Code Segregation Group: SG02 Emergency Schedules F-H, S-Q

Regulations: ADR/RID/Carriage of Dangerous Goods

Regulations: ADN

Regulations: IMDG


TRANSPORT INFORMATION Continued

UN Number UN1942.

UN Proper Shipping Name Ammonium nitrate.


Packing Group PGIII

Environmental Hazards Not a marine pollutant.

Additional information Marine Pollutant: No This product, classified as UN1942 Ammonium nitrate, is not liable to self-heating sufficient to initiate decomposition, ref. IMDG SP900.

Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code

Not applicable.

Bulk cargo shipping name Ammonium nitrate UN 1942.

Class Class 5/.1 Oxidising Material.

Group B

Marpol V Non-HME.

Regulations: IATA

IMSBC

REGULATORY INFORMATION

UK Legislation Carriage of Dangerous Goods Regulations 2009, as amended – implementing ADR Classification (Hazard Information and Packaging for Supply) Regs 2009, as amended. Control of Substances Hazardous to Health regs 2002, as amended Control of Major Accident Hazard Regulations 2015. Qualifying quantities Lower Tier 350 tonnes, Upper Tier 2500 tonnes The Ammonium nitrate Materials (High Nitrogen Content) Safety Regulations 2003.

Safety, health and environmental regulations/legislation specific for the substance or mixture

REGULATORY INFORMATION Continued

EC Regulations Registration, Evaluation, Authorisation and Restriction of Chemicals Regulations 2006, as amended. Ammonium nitrate listed in Annexe XVII Restrictions The Classification Labelling and Packaging Regulations 2008 as amended.

Chemical Safety Assessment

This product contains substances for which Chemical Safety Assessments are still required.

OTHER INFORMATION

MSDS first issued: 03/96

ChangesIssue Issue Date Changes6 06/2012 General minor updates7 19/12/2016 Completely re-written to complying with suppliers MSDS

Abbreviations and acronymsATE = Acute Toxicity Estimate. CLP = Classification, Labelling and Packaging Regulation [Regulation (EC) No. 1272/2008]. DNEL = Derived No Effect Level.DMEL = Derived Minimal Effect Level. EUH statement = CLP-specific Hazard statement PNEC = Predicted No Effect Concentration. RRN = REACH Registration Number. PBT = Persistent, Bioaccumulative and Toxic. vPvB = Very Persistent and Very Bioaccumulative. bw = Body weight.

Key literature references and sources for data EU REACH IUCLID5 CSR. National Institute for Occupational Safety and Health, U.S. Dept. of Health, Education, and Welfare, Reports and Memoranda Registry of Toxic Effects of Chemical Substances. IHS, 4777 Levy Street, St Laurent, Quebec HAR 2P9, Canada. Regulation (EC) No 1272/2008 Annex VI.

Procedures used to derive the classification.

Classification Justification

Ox. Sol. 3, H272 Expert judgment

Eye Dam./Irrit. 2, H319 Calculation method


OTHER INFORMATION Continued

Relevant hazard Statements and Precautionary statements

H272 May intensify fire; oxidizer.

H319 Causes serious eye irritation.

P210: Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.

P221: Take any precaution to avoid mixing with combustibles.

P280: Wear eye protection.

P305+P351+P337+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical attention.

P370+P378 In case of fire: Use flooding quantities of water to extinguish.

Advice on training

Notice: FOR FURTHER INFORMATION CONTACT: EPC-UK EXPLOSIVES EXPLOSIVE ENGINEERING DEPARTMENT ON 01773 832253

ANFO

ANFO explosives are supplied either in cartridge or bulk form and are suitable for use in dry borehole conditions. EPC-UK’s range of ANFO explosives includes Ammospex and Ammoblast.

Ammospex and ammoblast are oxygen balanced, free flowing mixture of ammonium nitrate prills and fuel oil. The lack of water resistance and low bulk strength of ANFO have to be recognised when designing blasts using these product.

Bulk ANFO may be delivered in a variety of approved containers and weights. Standard packaging available in the UK;

Ammospex – 2.5Kg cartridges, 10 cartridges per box

Ammoblast – 25Kg bags, 1 bag per box.

Other sizes and weights are available on request.

2

ANFO DataAmmospex / Ammoblast

PRODUCT SPECIFICATION

Product Type ANFO

Product Name Ammospex Ammoblast

Weight Strength (% ANFO) 100

Bulk Strength (% ANFO) 100

Density (g/ml) 0.8

VOD (m/s) 3000-4000

Gas Volume (l/kg) 970

CO2 Volume (l/kg) 85

Water Resistance Poor

Fume Characteristics Fair

Detonator Sensitive No

Temperature Range (use) oC -20/+40

Shelf Life 1 year

UN Number UN0082

UN Description Explosive, Blasting, Type B

UN Class/Compatibility Group

1.1D

CE Mark ENB/B/0063/12

PACKAGING DETAILS

Product Packaging

Cartridge Diameter (mm)

Cartridge Length (mm)

Cartridge Weight (kg)

Cartridges/box

Box Weight (kg)

Polythene film

85

570

2.5

10

25

Polythene bag in box

Bulk

Bulk

25

1 bag/box

25

*may depend on loading method



Product Identifier AMMOSPEX / AMMOBLASTANFO

Use of the Product The product is an explosive used as a column charge in blasting and similar explosive usage.






01773 832253


Classification According to EC Regulation 1272/2008

Eye Irrit. 2 H319 Causes serious eye irritation.

Expl. 1.1 H201 Explosive; mass explosion hazard.

According to EC Regulation 1272/2008

Hazard Pictograms

Signal Word Danger.

Hazard statements H319 Causes serious eye irritation. H201 Explosive; mass explosion hazard.


P210 Keep away from heat/ sparks/open flames/hot surfaces. — No smoking. P280 Wear protective gloves/protective clothing/eye protection/ face protection.

Classification of Substance / Mixture

Label elements



P372 Explosion risk in case of fire.P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses if present and easy to do – continue rinsing.

Precautionary statements - Storage

P401 Store in a safe and suitable place in accordance with legal requirements.

Precautionary statements - Disposal

P501 Dispose of contents/container. Dispose of the product/container in accordance with local regulations on the disposal of explosive and contaminated waste.

Other Hazards May cause explosion or fire if handled improperly


Substances Not applicable.

Mixtures

Dangerous substance

Concentration range

EC Number

CASNumber

Classification

Ammonium Nitrate

92.5-95.0% 229-347-8

6484-52-2

Eye Irrit. 2 H319Oxid. Solid 3 H272

Fuels, diesel 5.0-7.5% 269-822-7

68334-30-5

Flam. Liq. 3; H226 Asp Tox 1; H304 Skin Irrit. 2; H315 Acute Tox. 4 H332 Carc. 2 H351 STOT RE 2; H373 (Thymus, liver, bone marrow) Aquatic Chronic 2; H411


FIRST AID MEASURES

General Call a doctor/physician if you feel unwell.

First Aid – Eyes Rinse thoroughly with water for at least 15 minutes. Remove contact lenses if present and easy to do – continue rinsing. If eye irritation persists, consult an ophthalmologist.

First Aid – Skin Wash the affected areas thoroughly with soap and plenty of water. If skin irritation persists: Get medical advice/attention.

First Aid – Ingestion DO NOT INDUCE VOMITING. If conscious, give some water. Get medical attention if persistent.

First Aid – Inhalation Remove victim to fresh air and keep at rest in a position comfortable for breathing. Perform artificial respiration if breathing has stopped. Get medical attention.

Eye contact After eye contact, a serious eye irritation is likely to occur.

Skin contact After skin contact, skin and mucous membranes’ irritation may occur. A continuous contact with skin may lead to sensitisation.

Ingestion ANFO can be toxic if ingested. The symptoms can be headache, nausea and sleep disorders.

Inhalation Remove to well ventilated area. If problems persist, seek medical advice. A person suffering from inhalation of after detonation fumes must be removed to fresh air, receive medical attention and stay under medical observation for at least 48 hours. The person should lie down until the doctor arrives.



Indication of Any Immediate Medical Attention and Special Treatment Needed - Treat symptomatically.


Extinguishing Media Appropriate: Large quantities of water must be used to cool and protect exposed material.

Inappropriate: not determined.


If the product is enveloped in flames, there is an immediate risk of explosion, so evacuate as quickly as possible, to at least 300 metres from the flames, and a greater distance may be required depending on the quantity of explosives If possible seek shelter behind a natural or artificial barrier. Product combustion generates toxic fumes and gases, mainly carbon monoxide and nitrous fumes.

Advice for Firefighters If the flames do not involve the product directly, extinguish them using the media recommended for the specific type of fire. Move the product away from the fire if possible. If the fire directly involves the product, evacuate the area immediately to an upwind position to avoid breathing the fumes. There is an explosion risk in case of fire so DO NOT fight fire when it reaches explosives. Only if possible, fight the fire from a protected position, wearing self-contained breathing apparatus and using large quantities of water.



Personal Protective Equipment must be worn. Gather the dispersed product using anti-sparking tools and equipment (wood, plastic…). Eliminate all potential sources of ignition and avoid any action that could cause an impact, friction, sparking or a sudden rise in temperature.


ACCIDENTAL RELEASE MEASURES Continued

Environmental Precautions Do not let the product get into the soil and water. Call the fire brigade if soil or water is contaminated.


Place the product in a suitable container, preferably a cardboard box or canister that can be sealed after removal of the product. Never use tools that generate sparks. Keep anyone not involved in the operation well away from the danger area and inform them of the risk of explosion. Contamination may increase the explosive’s sensitivity to impact and friction.

Reference to other sections Refer to Handling and Storage, Exposure Control/Personal Protection and Disposal Considerations.



Handle with care, bearing in mind the potential hazards.Earth all electrical equipment present and any conductive item.Keep the product well away from heat, direct sunlight and other sources of ignition, including combustible materials.When handling the product, avoid ingesting or inhaling any solid particles that are formed. Do not eat, drink or smoke when handling the product. Wear disposable plastic, latex or rubber gloves to prevent contact with the skin.Wash your hands thoroughly after handling the product.Remove contaminated clothes and PPE before entering areas where food and drink are consumed.

HANDLING AND STORAGE Continued


Store only in authorized areas that are suitable for the purpose and are licenced under the Explosives Regulations 2014.Take measures to avoid the generation and accumulation of electrostatic charges.Keep the storage areas closed.Do not store in damp or humid conditions. Avoid thermal cycling. Keep boxes closed prior to use.The shelf life of the explosive is 12 months when stored under recommended conditions.All explosives and explosive items are chemically incompatible with acids, alkalis and highly reactive materials such as reducing agents and highly oxidizing agents (avoid chlorates and perchlorates).

Specific end use(s) The product is supplied for use, testing and analysis by qualified personnel who have been fully trained to handle explosives.


Control Parameter None

Exposure controls

Appropriate engineering controls

Personal protective equipment

Provide appropriate exhaust ventilation at places where dust is formed.

Eye/face protection: safety goggles are required in the presence of large amounts of powder during handling.

Hand protection: wear plastic, rubber or latex gloves. Disposable gloves are recommended to minimise cross-contamination with the explosive.

Body protection: the entire skin must be covered by suitable clothing. Any powder contaminating the skin must be removed immediately by washing in plenty of water. Work clothes must be antistatic, made of cotton for instance, and flame retardant.




Respiratory protection: not required during normal handling.Hygiene measures: Do not eat, drink or smoke when using this product. Wash thoroughly after handling. Avoid contact with eyes, skin and clothing. Wash contaminated clothes before reuse. Other: use appropriate anti-static footwear.Not available.


Appearance/ colour Homogeneous prilled granules (Ammospex contained in a polyethylene cartridge, Ammoblast in bulk), off white /pink.

Odour Characteristic of fuel oil /diesel.

Odour threshold Not available.

pH Not available. 10% solution of the AN in water will have a ph of 4.5-7.

Melting point / Freezing Point

Not available.

Initial Boiling point and boiling range

Not available.

Flash point >100C

Evaporation Rate Not available.

Flammability Not available.


Not available.



Relative Density 750-850 kg/m3, tapped density.

Solubility(ies) Ammonium nitrate very soluble in water.


Not available.

Auto-ignition temperature Not available.



Decomposition temperature >150 C

Viscosity Not available.

Explosive properties Detonation rate: 3000-4000 m/s.Ignition sensitivity: A primer cartridge is recommended.

Oxiding properties Not available.

Other information Not available.



Reactivity Impact, friction, electrostatic discharge, excessive temperature rise, naked flames and other causes of ignition can cause explosion.

Fire can lead to explosion.

Chemical Stability Stable under the recommended storage and use conditions and at moderately elevated temperatures and pressures. German assay at 120°C with methyl violet. No variation after 2h 30’.

Possibility of hazardous Reactions

When the product is exposed to heat, there is a risk for explosion at temperatures well below the auto-ignition temperature.

Conditions to avoid Keep away from heat, sparks, naked flames and hot surfaces. Do not smoke. Avoid scratching, impact, shock and friction.

Incompatible materials Copper and its alloys, bromates, chlorates, chlorites, hypochlorites, nitrites, perchlorates, permanganates, powdered metals, acids and bases. Highly reactive materials such as reducing agents and highly oxidizing agents.


Some Nitrogen Oxides, Oxides of Carbon, including Carbon Monoxide may be produced when the product is detonated. However the amount of toxic gases produced will depend on many variables such as method of initiation, rock type, humidity etc. In the event of a fire, larger quantities of Nitrous fumes and carbon monoxide may be released.



Acute toxicity ANFO is toxic when inhaled or ingested. Exposure to the product by ingestion or inhalation can generate acute or chronic symptoms such as headache, nausea and sleep disorders.

Skin corrosion / irritation Prolonged and repeated contacts can irritate the skin.

Serious eye damage / irritation

Powder in the eyes can cause considerable discomfort and lacrimation. Can cause sleep disorder, irritation, sensitisation and epileptic convulsions.May persist for several days.

Respiratory or skin sensitisation

Inhalation and continuous skin contact may lead to sensitisation.

Germ Cell Mutagenicity Not available.

Carcinogenicity Not available.

Reproduction toxicity Not available.

STOT – single exposure Not available.

STOT –repeated exposure Not available.

Aspiration hazard Not available.

Other Information Respiratory irritation

The powder irritates the airways and can cause sneezing and coughing. Large quantities can cause headache, lack of appetite, malaise, vomiting, dizziness, fluctuations in blood pressure and fainting.



Toxicity

Environmental dispersion causes severe ecological impacts because the product contains ammonium nitrate, which is highly soluble in water, leading to eutrophication of algae.

Result Species Exposure

LC50 650 mg/L Fish 24 hours

LC50 340 mg/L Daphnia 24 hours

LC50 2.5 mg/L Algae 5 days

ECOLOGICAL INFORMATION Continued


Not available.

Bioaccumulation potential Not available.

Mobility in soil Not available.


Not available.

Other Adverse Effects Not available.


Waste treatment methods Considering the potential risk associated with the kind of product, it must only be disposed by personnel specifically trained for the purpose.

Product disposal Avoid or reduce the generation of waste to a minimum.Collect waste in appropriate containers in accordance with the applicable regulations, ready for disposal using approved methods.The buildings where containers of waste are kept must be properly equipped and authorised by the competent authorities.Waste must never be discharged into the drains or waterways.Under the supervision of a trained competent person the product may be disposed of by detonation in a shot hole or by burning on an approved burning ground. For further guidance see the HSE /CBI Explosives Industry Group, “Guidance for the Safe Management of the Disposal of Explosives”.

Container Disposal The accepted method for destroying empty boxes is burning.



UN Number UN 0082.

UN Proper Shipping Name EXPLOSIVE, BLASTING, TYPE B.

Transport Hazard Classes 1.1D

Packing Group Not assigned, but treat as PG II.

Environmental Hazards -

Special Precautions for User Not available.


Not available.

OTHER INFORMATION


UK Legislation Carriage of Dangerous Goods Regulations 2009, as amended – implementing ADRControl of Substances Hazardous to Health Regs 2002, as amendedControl of Major Accident Hazard Regulations 2015Explosives Regulations 2014, as amended.

EC Regulations Registration Evaluation, Authorisation and Restriction of Chemicals Regulations 2006, as amendedClassification Labelling and Packaging Regulations 2008, as amended.

Chemical Safety Assessment Not available.



ChangesIssue Issue Date Changes7 05/2012 Minor changes8 10/11/2016 Completely re-written complying EC Reg 2015/0830

Abbreviations and acronymsPBT: Persistent, Bioaccumulative, ToxicvPvB: very Persistent and very Bioaccumulative


References - “Guidance for the Safe Management of the Disposal of Explosives,

January 2007”.- ADR “European Agreement regarding the International Carriage of

Dangerous Goods by Road”.- RID “European Agreement regarding the International Carriage of

Dangerous Goods by Rail”.- IMO/IMDG “International Maritime Transport of Dangerous Goods”.- ADN “European Agreement concerning the International Carriage of

Dangerous Goods by Inland Waterways”.- Registration files available on the ECHA website. CAS# 6484-52-2.

Evaluation method for mixtures - Not applicable.

Relevant hazard Statements and Precautionary statementsH201 Explosive; mass explosion hazard.H226 Flammable liquid and vapour.H228 Flammable solid.H261 In contact with water releases flammable gas.H272 May intensify fire; oxidiser.H304 May be fatal if swallowed and enters airways.H315 Causes skin irritation.H319 Causes serious eye irritation.H332 Harmful if inhaled.H351 Suspected of causing cancer.H373 May cause damage to organs through prolonged or repeated exposure.H411 Toxic to aquatic life with long-lasting effects.

P210 Keep away from heat/ sparks/open flames/hot surfaces. — No smoking.P280 Wear protective gloves/protective clothing/eye protection/ face protection.P372 Explosion risk in case of fire.P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses if present and easy to do – continue rinsing.P401 Store in a safe and suitable place in accordance with legal requirements.P501 Dispose of contents/container. Dispose of the product/ container in accordance with local regulations on the disposal of explosive and contaminated waste.

Advice on training - Not available.


3

Black Powder

Black Powder is a low explosive powder made from a combination of Sulphur (10%), charcoal (15%) and potassium nitrate (75%).

Black Powder deflagrates rather than explodes (i.e. has a velocity of Detonation <1000m/s) when confined and as such is suited for use in ‘gentle’ blasting applications such as dimension stone production, primarily to limit the formation of excessive cracks in the deposit being worked.

For speci ng applications EPC-UK stocks as standa PMG medium grained black powder ( e approx. 0.8mm – 4mm), other gra ailable on request.

alist blastird Wano Nparticle sizdes are av

Black Powder DataWano NPMG Black Powder


Product Type Black Powder

Product Name Wano NPMG Black Powder

Weight Strength (% ANFO) N/A

Bulk Strength (% ANFO) N/A

Density (g/ml) 1.7

VOD (m/s) 300-600


Water Resistance None

Fume Characteristics Poor

Detonator Sensitive Yes (0.6g PETN or Equivalent)

Temperature Range (use) °C -20/+50

Shelf Life 10 yrs (if stored unopened)

UN Number UN0027

UN Description Black Powder (Gun Powder)

UN Class/Compatibility Group 1.1D

CE Mark 0589.EXP.0086/98

PACKAGING DETAILS

Product Packaging Plastic Bag/Fibreboard Box

Cartridge Diameter Bulk

Cartridge Length Bulk

Cartridge Weight Bulk

Cartridges/box Bulk

Box Weight (kg) 25


Product Identifier Black Powder IncludingBlasting powder, fireworks powder, golden glitter powder, musket powder, fuse powder, black powder according to TL 1376-05xx, black powder according to MIL-P-223-C, black powder according to INT. DEF. STAN. 13-167/1, black powder according to BOFORS standard W9-33.

Use of the Product Blasting, Pyrotechnics, Propellant.






01773 832253


Classification of Mixture Expl. 1.1 .H201 Explosive, mass explosion hazard.

Hazard Pictogram GHS01

Signal Word Danger.

Hazard Statement Warning H201 Explosive, mass explosion hazard.

Label elements




Precautionary Statements P210: Keep away from heat/sparks/open flames/hot surfaces. No smoking.P250: Do not subject to grinding / shock / friction.P370+380: In case of fire, evacuate area.P372: Explosion risk in case of fire. P373: DO NOT fight fire when fire reaches explosives.P501 Dispose of contents/container. Dispose of the product/container in accordance with local regulations on the disposal of explosive and contaminated waste.

Other Hazards Result of PBT vPvB assessment: No assessment established up to now.


Mixtures

Name Potassium nitrate Sulphur Charcoal

CAS-Nr. 7757-79-1 7704-34-9 16291-96-6

EC-Nr. 231-818-8 231-722-6 240-383-3

Registration-Nr.

01-2119488244-35-xxxx-

01-2119487295-27-xxxx

01-2119560590-41-xxxx

Concentration 40-85 6-27 5-52

Signal word Warning Warning

Classification H272 May intensify fire oxidizer

H315 causes skin irritation

FIRST AID MEASURES

First Aid – Inhalation After inhalation of detonation gases, remove victim to fresh air. If nauseous consult doctor.

First Aid – Skin Wash the affected areas thoroughly with soap and plenty of water.

First Aid – Eyes Rinse thoroughly with water for at least 15 minutes. Remove contact lenses if present and easy to do – continue rinsing. If eye irritation persists, consult a doctor.

First Aid – Ingestion Rinse mouth with water. Consult doctor.

Inhalation Combustion gas can damage the central nervous system, metabolism and the digestive system. Prolonged exposure can cause pulmonary oedema.


Treat symptomatically.




Extinguishing Media Appropriate: Large quantities of water must be used to cool and protect exposed material.

Inappropriate: not determined.

- DO NOT ATTEMPT TO EXTINGUISH THE BURNING EXPLOSIVES! RISK OF EXPLOSION.

Try to remain calm and extinguish the fire before it reaches the product. In case of the risk of an explosion, do not attempt to extinguish the fire. Evacuate to a shelter located at least 300m away, before the fire reaches the explosive. Secure the site against unauthorized access.


FIRE FIGHTING MEASURES Continued


If the product is enveloped in flames, there is an immediate risk of explosion, so evacuate as quickly as possible, to at least 300 metres from the flames, and if possible seek shelter behind a natural or artificial barrier. Product combustion generates toxic fumes and gases, carbon monoxide and hydrogen sulphide.

Advice for Firefighters If the flames do not involve the product directly, extinguish them using the media recommended for the specific type of fire. Move the product away from the fire if possible.If the fire directly involves the product, evacuate the area immediately to an upwind position to avoid breathing the fumes. There is an explosion risk in case of fire, so DO NOT fight fire when it reaches explosives. Only if possible, fight the fire from a protected position, wearing self-contained breathing apparatus and using large quantities of water.



Remove all potential sources of ignition and avoid any action that could cause an impact, friction, sparking or a sudden rise in temperature. Wash hands in case of contact with the product. Keep unauthorized persons away.

Environmental Precautions Do not let the product get into sewage or waters. After penetration of waters, immediately notify authorities.


Pick up by hand using shovels made of wood or aluminium. And only fill into clean and marked containers which can be covered. Avoid impact and friction. Do not use sparking tools. After as much as possible has been removed, down the area with water. In case of rain cover the product with a tarpaulin.




Protect from fire and direct solar radiation. Open and handle containers with care. Avoid formation of dust. Keep away ignition sources. Do not smoke. Avoid impact and friction.


In general storage must be licensed as required by the Explosives regulations.

Store in a cool dry place in original packaging.

Shelf life, when stored in good conditions in unopened packaging, is 10 years.

Do not exceed the authorized amounts for the store.

Do not store with other dangerous goods.

Only store with other compatible explosives.

Storage limits for which COMAH applies for Explosives:

10 tonnes Lower Tier 50 tonnes Upper Tier

Specific end use(s) The product is supplied for use, testing and analysis by qualified personnel who have been fully trained to handle explosives.Do not use beyond the shelf life.


Control Parameter Contains no substances with threshold limit valuesdust general (EH40)inhalable dust 10 mg.m-3

respirable dust 4 mg.m-3

After detonation gasesCarbon Monoxide (EH40)

8 hr TWA 35 mgm-3

STEL 232 mgm-3

Hydrogen Sulphide (EH40)8 hr TWA 7 mgm-3

STEL 14 mgm-3




Install effective earthing at the workplace. Do not use sparking tools.

Personal protective equipment Hand protection

Not necessary if handled correctly but gloves are recommended.

Eye protection Not necessary if handled correctly but safety glasses are recommended.

Body protection Work clothes must be antistatic, made of cotton for instance, and flame retardant.

Respiratory protection If dust present, wear dust mask.

Industrial hygiene Do not eat, drink or smoke when using this product. Wash thoroughly after handling, especially before breaks and after finishing work. Avoid contact with eyes.

Other Use appropriate anti-static footwear.


Not available.

Exposure controls


Appearance/ colour Granular/meal. Black.

Odour Odourless.

Odour threshold Not applicable.

pH 10% dilution neutral to litmus.

Melting point / Freezing point

Not available.


Not applicable.

Flash point Not applicable.




Not available.





Relative density 1.1-1.9 g/cm3

Apparent Density 0.5-1.2 g/cm3

Solubility(ies) Water: 320g/dm3 (ref to KNO3)


Not available.


Decomposition temperature 290-360°C

Viscosity Not available.

Explosive properties Mass explosion hazardImpact sensitivity ≥7.5JImpact sensitivity >360 N

Oxidising properties Not available.



Reactivity Avoid impact and friction.

Chemical Stability When heating – danger of explosion. Product is slightly hygroscopic. Keep locked and dry. The recommended shelf life is 10 years.


When heating – danger of explosion.

Conditions to avoid Keep away from heat, sparks, naked flames and hot surfaces. Do not smoke. Avoid impact, shock and friction.

Incompatible materials Strong oxidizing and reducing agents.


Carbon monoxide and hydrogen sulphide.




Other informationInhalation of the dust should be avoided as even inert dusts may impair respiratory organ functions.

Potassium Nitrate Sulphur Charcoal

Acute toxicity LD50 (oral, rat) = 3015 mg/kgData not available on acute skin and inhalation toxicity

LD50 (oral, rat) = >5,000 mg/kgInhalation LC50 rat 9.23 mg/l 4 hDermal: LD rabbit .2,000mg/kg

Quantitative data on the toxicity of this material are not available.The product manufacturer’s experience has provided no indication of any hazardous potential.

Skin corrosion / irritation

Data not available Causes skin irritation


Slight irritation Slight irritation


Data not available No sensitizing effect

Genotoxicity in vitro

Ames test: negative

Ames test: negative

STOT – single exposure

Not classified as such


STOT – repeated exposure



Aspiration hazard Not classified as such



Toxicity


Toxicity to fish LC50 Poecilla teticulata 191 mg/l 96hr

LC50 Danio rereo191 mg/l 96hr

Quantitative data on the toxicity of this material are not available.

Toxicity to daphnia LC50 Daphnia Magna 490 mg/l 48 hr

LC50 Daphnia Magna >1,000 mg/l 48 hr

Toxicity to bacteria No data available No data available



Bioaccumulation potential

Mobility in soil



No data available No data available No data available






PBT and vPvB assessment

Not available Not available Not available

Other Adverse Effects Not available


Product and Container disposal

Do not put waste in general waste or landfill; destroy in licensed facilities.

Contaminated packaging with traces of explosives must be carefully reviewed to ensure they are empty and put flat. They can be burned on the place of use, if the property is authorized. See the CBI/EIG “Guidance for the Safe Management and Disposal of Explosives”




UN Number UN 0027.

UN Proper Shipping Name BLACK POWDER


Packing Group Not assigned.

Environmental Hazards Not a marine pollutant under IMDG code.

Special Precautions for User As an explosive, the product is a high consequence dangerous good and adequate transport precautions must be taken for its security. Transport by air is forbidden under ICOA/IATA codesIMDG code EmS F-B, S-Y.


Not available.

Label


UK Legislation Carriage of Dangerous Goods Regulations 2009, as amended – implementing ADR.Control of Substances Hazardous to Health Regs 2002, as amended.Explosives Regulations 2014Control of Major Accident Hazard Regulations 2015.

EC Regulations Registration Evaluation, Authorisation and Restriction of Chemicals Regulations 2006, as amended.Classification Labelling and Packaging Regulations 2008, as amended.



Abbreviations and acronymsADN/ADNR: Regulations concerning the transport of dangerous substances in barges on inland waterways. ADR/RID: European Agreement concerns the International Carriage of Dangerous Goods by Road/ Regulations concerning the international carriage of dangerous goods by rail. ANSI: American National Standards Institute.CAS No.: Chemical Abstract Service Number.CLP: Classification, Labelling and Packaging. EC No.: European Commission Number. IATA: International Air Transport Associations. IMDG: International Maritime Dangerous Goods code.NFPA: National Fire Protection Association.PBT: Persistent, Bioaccumulative, Toxic.RCRA: The Resource Conservation and Recovery Act.UN No.: United Nations Number.vPvB: very Persistent and very Bioaccumulative.

References“Guidance for the Safe Management and Disposal of Explosives” HSE/CBI-EIG, 2007.“ EH40/2005 Workplace exposure limits” HSE.

Evaluation method for mixturesNot applicable.

Relevant hazard Statements and Precautionary statementsMeanings of Hazard Phrases H271 May cause fire or explosion; strong oxidizer.H272 May intensify fire; oxidizer.H315 Causes skin irritation.

Advice on training


OTHER INFORMATION


Changes

Issue Issue Date Changes

7 28/02/2017 Completely updated based on suppliers’ MSDS

Boosters

Boosters are available from EPC-UK in a variety of sizes.

Due to their high density and velocity of detonation, boosters supplied by EPC-UK offer the best priming characteristics for use with slurries, emulsions and bulk emulsion/ANFO blends.

The velocity of detonation is greater than 7500m/s resulting in a detonation pressure of more than 25GPa, enabling them to be used in the most arduous of conditions encountered in quarries or surface mines. Smaller boosters have a single detonator pocket to accommodate a single detonator, whilst the larger, 410g boosters have two pockets. Initiation can be achieved using a single No 8 strength detonator or by 12g detonating cord.

Sizes available include: 150g, 250g and 410g. Other sizes may be available on request.

4

Boosters DataEPC Boost A


Product Type Boosters

Product Name EPC Boost A

Weight Strength (% ANFO) N/A

Bulk Strength (% ANFO) N/A

Density (g/ml) 1.32

VOD (m/s) 7500

Gas Volume N/A

Water Resistance Very Good



Shelf Life 5 years

UN Number UN0042

UN Description Cast booster without any detonator


1.1D

CE Mark 0080.EXP.08.0038/0080.EXP.11.003

PACKAGING DETAILS

Product Packaging Plastic Case




Cartridges/box (kg)

53

171

0.25

40

63

163

0.41

30/15/10

Boosters EPC Boost A Data


Product Identifier EPCBoost A

Use of the Product Boosters for firing explosivesThese detonator sensitive Boosters are designed to initiate other, generally less sensitive, explosives.Other uses are not recommended unless an evaluation is conducted before starting use.






01773 832253


Classification of Mixture Explosive, div. 1.1; H201: Explosive, mass explosion hazard.


Signal Word Danger

Hazard Statement Warning H201: Explosive, mass explosion hazard.

Precautionary Statements P210: Keep away from heat/sparks/open flames/hot surfaces. No smokingP240: Ground/bond container and receiving equipment.

Label elements


HAZARD IDENTIFICATION Continued

Precautionary Statements P250: Do not subject to grinding/shock/impact.P370+P380: In case of fire, evacuate the area. Due to explosion hazard, fight fire from a reasonable distance. P372: Explosion risk in case of fire P373: DO NOT fight fire when fire reaches explosives.P401: Store in a safe and suitable place in accordance with legal local/regional/national andinternational requirements.P501: Dispose of the product/container in accordance with local regulations.

Other Hazards vPvB substances: noneSubstances PBT: noneThe health hazards associated with the Booster are due to the presence of the explosive RDX, which is sealed inside the Booster. Hence the possibility of accidental contact of the explosive and operators is very unlikely and can only be associated with accidents involving significant breakage of the product.


Substances N/A

Mixtures

Additional information: for the full text of hazard H, see Other Information section.

Name Composition(%)

CAS No EINECS Classification

Hexogen ( RDX )

98-99 121-82-4 204-500-1 Expl. 1.1: H201 Acute Tox. 3 H301,STOT SE 1 H370STOT RE 2 H373


FIRST AID MEASURES

General Untrained and uninstructed persons shall not handle this material nor its packaging.

First Aid – Inhalation Does not occur under normal handling conditions.In the event of fire:· Remove the victim from the contaminated area and allow him to rest in a ventilated room or in the open air.· Perform artificial respiration if breathing has stopped.· Seek medical attention in any case.

First Aid – Skin Does not occur under normal handling conditions.If the container breaks and product comes into contact with the skin:· Remove contaminated clothing immediately.· Wash the affected areas thoroughly with water.· Seek medical advice.

First Aid – Eyes Does not occur under normal handling conditions.If the container breaks and product comes into contact with the eyes:· Immediately rinse thoroughly with water.· Consult an ophthalmologist.

First Aid – Ingestion Does not occur under normal handling conditions.If the container breaks and product comes into contact with the eyes:· Immediately rinse thoroughly with water.· Rinse the mouth with water, but only if the victim is fully conscious.· Never induce vomiting.· Summon a doctor, who will assess the need for a stomach pump.



General Does not occur under normal handling conditions.Points below are if the RDX comes into contact with a person:Limited information is available on RDX. Convulsion and loss of consciousness may occur following overexposure to RDX in powder form.If the components are absorbed by the human body, this may lead to the formation of metahaemoglobin and cause cyanosis.

Eye contact Irritation of the eye.

Skin contact RDX is easily absorbed through the skin and it can irritate skin and mucous membranes. Continuous contact with the skin leads to sensitisation.

Inhalation RDX is moderately toxic if inhaled. It can irritate mucous membranes.

Ingestion RDX is moderately toxic if ingested.


No specific treatment required. Please follow the instructions in section 4.1 above.



Extinguishing Media Large quantities of water.


Try to remain calm and extinguish the fire before it reaches the product. Burning explosives cannot be extinguished with any fire-fighting equipment. In case of the risk of an explosion, do not attempt to extinguish the fire. Evacuate to a shelter located at least 300 m away. Secure the site against unauthorized access.


FIRE FIGHTING MEASURES Continued


If one or more products are enveloped in flames, there is an immediate risk of explosion, so evacuate as quickly as possible to at least 300 metres from the flames and, if possible, seek shelter behind a natural or artificial barrier. Product combustion generates toxic fumes and gases, mainly carbon monoxide and nitrous fumes.

Advice for Firefighters If the flames do not involve the product directly, extinguish them using the media recommended for the specific type of fire.Move the product away from the fire area if possible.If the fire directly involves the product:· Do not attempt to put the fire out as an explosion is likely.· Evacuate the area immediately, to an upwind position to avoid breathing in the fumes.· Only if possible, fight the fire from a protection position using large quantities of water.



The following measures should be taken in the unlikely event of the container breaking, and the explosive being dispersed.For non-emergency personnel• Don suitable clothing, see Exposure Controls.• Eliminate any potential sources of ignition nearby.For emergency personnel• Don appropriate PPE and gather the dispersed product using anti-sparking tools and equipment (wood, plastic).• Remove all potential sources of ignition and avoid any action that could cause any impact, friction, sparking or a sudden rise in temperature.

Environmental Precautions Avoid contaminating the soil and water at all costs.Call the fire brigade if soil or water is contaminated.Refer to Disposal Considerations for product disposal instructions.



Place the product in a suitable container, preferably a cardboard box or canister that can be sealed after removal of the product.Never use tools that generate sparks.Keep anyone not involved in the operation well away from the danger area and inform them of the risk of explosion.Contamination of the spilt RDX with materials such as powder, sand, moisture or metal particles may increase the explosive’s sensitivity to impact or friction.

Reference to other sections Also see Handling and Storage, Exposure Control/Personal Protection and Disposal Considerations.



Precautionary measures:• Handle with care, bearing in mind the potential hazards.• Earth all electrical equipment present and any conductive item.• Keep the product well away from heat, direct sunlight and other sources of ignition, including combustible materials.User information:• Risk of explosion due to impact, friction, fire or other sources of ignition.• Handle with care.• Do not smoke.Occupational health and safety:• When handling the product, avoid ingesting or inhaling any solid particles that are formed.• If the product comes into contact with the skin, due for example to container breakage, wash the area thoroughly with soap and water.• Do not eat, drink or smoke when handling the product.• Wash your hands thoroughly after handling the product.• Remove contaminated clothes and PPE before entering areas where food and drink are consumed.



Conditions for safe storage , including any incompatibilities

Precautionary measures:• Store only in authorised areas that are suitable for the purpose. Take measures to avoid the generation / accumulation of static charges.• Keep the storage areas closed.• Do not smoke or do anything else that can lead to impact, friction or a sudden rise in temperature.Incompatible materials:Store in a warehouse suitable for explosives and only with other explosives of a compatible category. Storage must be licensed as required by the Explosives regulations.Storage limits for which COMAH applies for Explosives: 10 tonnes Lower Tier; 50 tonnes Upper Tier

Specific end use(s) The product is supplied for use, testing and analysis by qualified personnel who have been fully trained to handle explosives.


Control Parameter RDX

Occupational exposure limits: Not applicable under normal handling conditions.Information about the main substances in the explosive:Hexhydro-1,3,5-trinitro-1,3,5-triazine: CAS: 121-82-4, EC: 204-500-1 (RDX)TLV TWA(8h): 1.5 mg/m3 – TLV STEL(15min): 3 mg/m3 - NIOSH (skin).Biological limit values:Does not contain materials with a known current value for biological limits.Limit values for occupational exposure and/or biological limit values for atmospheric contaminants:No contaminants are produced under normal handling conditions.If the product is enveloped by fire and starts to combust, beware of the fumes released, mainly NOx and CO, which can cause hazardous consequences if they are inhaled or come into contact with the eyes.DNEL exposure limit values NA.PNEC exposure limit values NA.


Technical measures The generation and accumulation of electrostatic charge on people and equipment must be avoided by means of effective earthing.Provide good ventilation.

Occupational health and safety

Do not eat, drink or smoke when handling the product.When handling the product, avoid ingesting or inhaling any solid particles that are formed. Always wash hands before breaks and at end of work.

Hand protection Not required during normal handling.It is advisable to use appropriate work gloves anyway, even with sealed products.

Respiratory protection Not required during normal handling.

Eye protection Not required during normal handling.

Skin protection Not required during normal handling. Work clothes must be antistatic, made of cotton for instance, and flame retardant.

Other Use appropriate anti-static safety footwear.

Environmental exposure monitoring

Not required during normal handling.

Exposure controls


Appearance/ colour External appearance is that of the yellow plastic shell, cylindrical container.

Odour No characteristic odour.


pH Not applicable.


Not available.





Not available.

Flash point Not available.




Not available.



Relative Density EPCBOOST A booster = 1.7 g/cm3EPCBOOST A 250 booster = 1.0 g/cm3EPCBOOST A 150 booster = 1.5 g/cm3

Solubility(ies) Not available.


Not available.


Decomposition temperature Not available.

Viscosity Not applicable - solid.

Explosive properties Explosive.


Mixability Not available.

Conductivity Not available.


Other information Information on ingredients


Reactivity Impact, friction, electrostatic discharge, excessive temperature rise, naked flames and other causes of ignition can cause explosion.

Fire can lead to explosion.

Chemical Stability The product is chemically stable under normal conditions.

STABILITY AND REACTIVITY Continued


When the product is exposed to heat, there is a risk of explosion at temperatures well below the auto-ignition temperature.

Conditions to avoid Keep away from heat, sparks, naked flames and hot surfaces. Do not smoke.Avoid scratching, impact, shock and friction.

Incompatible materials All explosives and explosive devices are chemically incompatible with acids, alkalis and highly reactive materials such as reducing agents and highly oxidising agents. Explosives and explosive devices are physically incompatible with nitrophenols and materials that can sensitize the explosive and lead to an uncontrollable reaction.Combinations with phosphorous, ammonium, amines, metal powders, chlorates, mercury, and organic compounds or solvents must be avoided.


Nitrous fumes and carbon monoxide during combustion.


Acute toxicity Under normal conditions, the explosive is enclosed in a special container. If the container breaks, the toxicity of the contents is similar to that of the component present in the highest percentage, namely RDX. RDX:LD50 (oral, rat): 71 mg/kgLD50 (oral, mouse): 59 mg/kgNot classifiable based on the information available.RDX is moderately toxic when inhaled or ingested.It is easily absorbed through the skin and can irritate the eyes, skin and mucous membranes. The substance is inextricably bonded in the product and does not contribute to create health hazards.




Skin corrosion / irritation Not available.


Slight irritationPossible loss of consciousness due to excessive exposure to RDX.


Data not available.

Germ Cell Mutagenicity Data not available.

Carcinogenicity Data not available.

Reproduction toxicity Data not available.

STOT – single exposure Not classifiable based on the information available.RDX:The substance is inextricably bonded into the product and does not contribute to create health hazards.

STOT – repeated exposure Not classifiable based on the information available.RDX:The substance is inextricably bonded into the product and does not contribute to create health hazards.



Toxicity Eco-toxicological information relating to the explosive mixture:

The results of tests on acute toxicity indicate that the LC50 value is generally higher than 3 mg/l for RDX.

Acute static toxicity tests have shown that RDX does not display toxicity for 4 species of algae and 4 species of invertebrates, and the LC50 value calculated for all species of fish is in the range 4.1-6.0 mg/l. A comparison of the toxicity of RDX observed in static and in current tests has shown that RDX essentially displays no difference for fish and invertebrates.


Toxicity The results of 14C-RDX bioaccumulation studies have revealed an apparent lack of a perceptible accumulation in the tissues and in edible and non-edible organs of all the species tested. Effects on growth and critical life stages of fathead minnows have been observed at 5.8 mg/l, and for survival from 4.9 to 6.3 mg/l during chronic exposure of fathead minnows in several life cycles. Midges exposed chronically to RDX appear to be unaffected even at a concentration of 21 mg/l, whereas in water-fleas chronic exposure increases the number of young produced by parthenogenesis from females to concentrations greater than 4.8 mg/l.

A water quality criterion of 0.35 mg/l of RDX has been proposed for the protection of freshwater life with an adequate safety margin.

Eco-toxicological information relating to the main substances contained in the explosive mixture:

RDX

LC50 (Pimephales promelas, 96 hours): 11.1-15.0 mg/l

NOEC (Pimephales promelas, 28g): 1.4 mg/l

EC50 (Ceriodaphnia dubia, 48 hours): >17 mg/l

NOEC (Ceriodaphnia dubia, 7g): 3.64 mg/l

NOEC (Pseudokirchnerella subcapitata): 0.5 mg/l




BOD7 = 0.02 g/g - COD = 0.35 g/g - BOD7/COD7 = 0.057Hydrolysis is not expected to significantly influence the environmental fate of RDX. The primary physical mechanism of RDX degradation in aqueous solution is photolysis. RDX is expected to persist at length in clear illuminated surface water. Formaldehyde and nitrosamines have been identified as photoproducts. Nitrosamines could be of primaryimportance for the environment due to their mutagenic/carcinogenic potential. In these products, however, conversion only occurs in a limited portion if the product itself is photoreactive. Biodegradation of RDX occurs in water and soil, mainly in anaerobic conditions.

Bioaccumulation potential Based on a low LogKow and low BCF values of between 1.2 and 5.9, RDX has a low potential of bioconcentration in aquatic organisms.

Mobility in soil RDX has a Koc value of 70, which indicates low mobility in the soil.


The product does not meet the classification criteria for PBT.The product does not meet the classification criteria for vPvB.

Other Adverse Effects None known.


Waste treatment methods Considering the potential risk associated with the kind of product, it must only be disposed of by personnel specifically trained for the purpose.

DISPOSAL CONSIDERATIONS Continued


Contaminated packages:Avoid or reduce the generation of waste to a minimum.Collect waste in appropriate containers in accordance with the applicable regulations, ready for disposal using approved methods.The buildings where containers of waste are kept must be properly equipped and authorised by the competent authorities.Waste must never be discharged into the drains or waterways.Packaging:Packaging must be destroyed or recycled at an authorised waste treatment centre, in accordance with the applicable regulations.

See the HSE/CB-EIG document “Guidance for the Safe management of the Disposal of Explosives”.


UN Number UN 0042.

UN Proper Shipping Name BOOSTERS without detonator.



Environmental Hazards Not classified.

Special Precautions for User As an explosive, the product is a high consequence dangerous good and adequate transport precaution must be taken for its security. Transportation, including loading and unloading, must be carried out by persons who have received the necessary training required by the modal regulations concerning the transport of dangerous goodsIMDG Code EmS: F-B, S-XTransport by air is prohibited by ICAO/IATA codes.


Not applicable.



UK Legislation Carriage of Dangerous Goods Regulations 2009, as amended – implementing ADRControl of Substances Hazardous to Health regs 2002, as amendedExplosives Regulations 2014Control of Major Accident Hazard Regulations 2015.


Chemical Safety Assessment Not envisaged for an article.


Material Safety Data Sheet according to:- EC Regulation no. 1907/2006 (REACH) as amended- EC Regulation no. 1272/2008 (CLP) as amended.Abbreviations and acronymsADR: European Agreement concerning the International Carriage of Dangerous Goods by Road.CAS: Chemical Abstracts Service (divisione della American Chemical Society).CLP: Classification, Labelling, Packaging.DNEL: Derived No Effect Level.GHS: Globally Harmonized System of Classification and Labelling of Chemicals.IATA: International Air Transport AssociationIATA-DGR: Dangerous Goods Regulation by the “International Air Transport Association” (IATA).ICAO: International Civil Aviation Organization.ICAO T.I.: International Civil Aviation Organization Technical Instructions.

OTHER INFORMATION

MSDS first issued:

Changes


1 04/2012 New Issue

2 24/02/17

IC50: Inhibition Concentration for 50 percent of the test population.IMDG: International Maritime Dangerous Goods Code.LC50: Lethal Concentration for 50 percent of the test population.LD50: Lethal Doses for 50 percent of the test population.MARPOL 73/78: International Convention for the Prevention of Pollution From Ships, 1973 as modified by the Protocol of 1978.NIOSH-REL: National Institute for Occupational Safety and Health (USA) – Recommended Exposure Limits.NOEC: No Observed Effect Concentration.OSHA-PEL: Occupational Safety & Health Administration (USA) - Permissible Exposure Limits.PNEC: Predicted No-Effect Concentration.RID: Regulations concerning the International Carriage of Dangerous Goods by Rail.STEL: Short-Term Exposure LevelSTOT: Specific Target Organ Toxicity.TLV: Threshold Level Value.TLV-TWA: Threshold Level Value for the average time weighted over 8 hours.VLEP: Occupational exposure limit values.

ReferencesHSE/CB-EIG document “Guidance for the Safe Management of the Disposal of Explosives” 2007.ADR European Agreement concerning the International Carriage of Dangerous Goods by Road.- International Maritime Dangerous Goods Code (IMDG Code).- International Air Transport Association (IATA).- ECDIN - Environmental Chemicals Data and Information Network - Joint Research Centre, Commission of the European Communities- SAX’s DANGEROUS PROPERTIES OF INDUSTRIAL MATERIALS - Eight Edition - Van Nostrand ReinoldNational Institute of Health – National Chemicals Inventory

Evaluation method for mixturesN/A

Relevant Hazard Statements and Precautionary StatementsMeanings of Hazard Phrases H201: Explosive; danger of mass explosion.H301: Toxic if swallowed.H370: Causes damage to organs.H373: May cause damage to organs in the event of prolonged or repeated exposure.

Advice on training Handling of this product should only be allowed by qualified persons.


OTHER INFORMATION

Bulk Emulsions

Bulk emulsions are an emulsified Ammonium Nitrate solution incorporating a fuel phase. Classified as an oxidizing agent for transportation purposes the composition does not become explosive until mixed with gassing agents and sensitized at the point of delivery to the borehole.

EPC-UK supplies the Multiblend range, a pumpable high energy chemically sensitised bulk emulsion explosive manufactured in the UK. The multiblend range is specifically designed for large scale quarrying, mining and civil engineering blasting works. The waterproof product is mixed on site by bespoke trucks and suitable for use in both wet and dry holes. Multiblend is available in a range of blends incorporating various quantities of undissolved ammonium nitrate dependent on specific energy and heave requirements of the customer.

5

Bulk Emulsions DataBlendex


Product Type Bulk Emulsion

Product Name Blendex 70 Blendex 80 Blendex 100

Weight Strength (% ANFO)

81 79 70

Bulk Strength (% ANFO)

112 - 134 109 - 130 96 - 111

Density (g/ml) 1.15 - 1.32 1.14 - 1.31 1.10 - 1.27

VOD (m/s) 5100 5100 5000

Gas Volume (l/kg)

1010 1010 1035

Water Resistance Excellent

Fume Characteristics

Good

Detonator Sensitive

No

Temperature Range (use) °C

-10/+50

Shelf Life Should not be stored, bulk loaded at point of use

UN Number UN0241

UN Description Explosive, Blasting, Type E


1.1D

CE Mark ENB/B/085/14



Product Identifier Blendex 70, Blendex 85, Blendex 100(Note: The number after Blendex indicates the approximate percentage of emulsion matrix in the product).

Use of the Product Blendex explosives are mixed on-site and intended for immediate use as a general explosive column charge. The products are suitable for use in diameters greater than or equal to 85 mm, depending on primer/use conditions. Other products are available for use in small diameters. The explosives listed here are all pumpable products.






01773 832253



Explosive 1.1 H201 Explosive; mass explosion hazard.

Eye irrit. 2 H319 Causes serious eye irritation.

Hazard Pictogram

Label elements


Mixtures

Dangerous substance

Concentration range

EC Number

CASNumber

CLP Classification

Ammonium Nitrate

75-85% 229-347-8

6484-52-2

Ox. Sol. 3; H272,Eye Irrit. 2; H319.

Hydrocarbons, C16-C20, n-alkanes, isoalkanes, cyclics, aromatics (2-30%)

4.0-7.0% 919-006-8

64742-80-9

Asp. Tox. 1 - H304Aquatic Chronic 4 - H413

Sodium nitrite

<0.2% 231-555-9

7632-00-0

Ox Sol 3 H272Acute Tox 3 H301Eye irrit 2 H319Acute Aquatic 1 H400

Acetic acid <0.4% 200-580-7

64-19-7 Flam Liq 3 H226Skin Corr 1A H314


Signal Word Danger.

Hazard statements H201 Explosive mass Explosion Hazard .


P210 Keep away from heat/ sparks/open flames/hot surfaces. — No smoking. P280: Wear protective gloves/protective clothing/eye protection.


P370+372+380: Explosion risk in case of fire: Evacuate area. P373: DO NOT fight fire when fire reaches explosives. P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses if present and easy to do – continue rinsing. P337+P313 If eye irritation persists: Get medical advice/attention.

Other Hazards Excessive skin contact may cause dermatitis.

Label elements


FIRST AID MEASURES

General

First Aid – Eyes IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses if present and easy to do – continue rinsing. If eye irritation persists get medical advice/attention.

First Aid – Skin Wash thoroughly with soap and water.

First Aid – Ingestion Immediately drink plenty of water and seek medical advice.

First Aid – Inhalation Remove person to fresh air. If symptoms persist seek medical advice. A person suffering from inhalation of after detonation fumes must be removed to fresh air, receive medical attention and stay under medical observation for at least 48 hours. The person should lie down until the doctor arrives.

Eye contact Irritation of the eye, redness.

Skin contact After skin contact, a skin and mucous membranes’ irritation may occur (irritating, redness). Long term effects may include dermatitis.

Inhalation or ingestion Mild cases of methaemoglobinaemia will lead to cyanosis and in more severe cases may produce unconsciousness.

Eyes – Continue irrigation treatment as for chemical burns. Ingestion – Treat methaemoglobinaemia.





Extinguishing Media Appropriate: Use water based extinguishers to prevent fire reaching the Blendex. Tyre fires / fires in the engine compartment of the Multiblend vehicle may be fought with the vehicle fire extinguishers, if it is safe to do so. Inappropriate: Not determined.


This material is explosive and may burn to detonation. If the fire looks likely to reach the Blendex retire to a safe distance of at least 300 m and cordon off the area. Toxic and irritating gasses may be produced in a fire. Evacuate the area. DO NOT fight fire when fire reaches the product.

Advice for Firefighters If the flames do not involve the product directly, extinguish them using the media recommended for the specific type of fire. Note: If the fire involves the Multiblend truck, the materials on board should be treated as explosive as well. If the fire directly involves the product or materials on the truck, evacuate the area immediately to an upwind position to avoid breathing the fumes. There is an explosion risk in case of extended fire so DO NOT fight fire if it reaches the product.



Wash your hands thoroughly after handling. Wear eye protection and protective gloves.Eliminate all potential sources of ignition and avoid any action that could cause an impact, friction, sparking or a sudden rise in temperature.In the event of an emergency stop the production of Blendex.



Environmental Precautions Avoid spilling on the ground other than pumping into approved shot holes. Do not allow to enter a water course.


Spillages at the point of use should be scooped up, e.g. with a plastic shovel and included with the explosives in a borehole. Other disposal methods are referred to in Disposal Considerations.




Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. Do not subject to grinding, shock or friction.Keep product clean and free from contamination.Avoid spills and keep away from drains.Do not to eat, drink or smoke in work areas; Remove contaminated clothing and protective equipment before entering eating areas. Wash hands thoroughly after handling.


Not intended to be stored. - bulk loaded at point of use. If loaded holes are left overnight, a sentry should be placed. Any storage of product samples in a container or package would need to comply with the Explosives Regulations 2014.


Specific end use(s) Material is mixed on site and produced by trained operators using a Multiblend truck, to produce a product of the desired composition and density. The product is pumped directly into the shot holes for blasting according to the blast design.


Ammonium Nitrate DNEL/DMEL (Workers) Long-term - systemic effects, dermal 21.3 mg/kg bodyweight/day Long-term - systemic effects, inhalation 37.6 mg/m³ DNEL/DMEL (General population)Long-term - systemic effects, oral 12.8 mg/kg bodyweight/day Long-term - systemic effects, inhalation 11.1 mg/m³ Long-term - systemic effects, dermal 12.8 mg/kg bodyweight/day PNEC (Water) PNEC aqua (freshwater) 0.45 mg/l PNEC aqua (freshwater) intermittent 4.5 mg/l PNEC aqua (marine water) 0.045 mg/l PNEC Sewage Treatment Plant 18 mg/l

Sodium Nitrite DNEL (Workers) Long-term - systemic effects, inhalation 2 mg/m³ Short term systemic effects, inhalation 2 mg/m³ PNEC (Water) PNEC aqua (freshwater) 0.0054 mg/l PNEC aqua (marine water) 0.000616 mg/l PNEC sediment (freshwater) 0.0195 mg/kg PNEC sediment (marine water) 0.0223 mg/kg PNEC Soil 0.000733 mg/kg PNEC Sewage Treatment Plant 21 mg/l

Control Parameter



Oil There were no effects at the maximum attainable vapour concentrations, limit doses, or at other limits imposed by safety considerations. As no effects were demonstrated, the data are not appropriate for DNEL derivation. As the substances are demonstrably not hazardous for effects which are quantifiable, human health exposure assessments have not been conducted.

Acetic acid DNEL (Workers) Long-term - local effects, inhalation 25 mg/m³ Acute local effects, inhalation 25 mg/m³ DNEL/DMEL (General population) Acute - local effects, inhalation 25 mg/m³ Long-term - local effects, inhalation 25 mg/m³ PNEC (Water) PNEC aqua (freshwater) 3.058 mg/l PNEC aqua (marine water) 0.3058 mg/l PNEC Intermittent releases 30.58 mg/l PNEC sediment (freshwater) 11.36 mg/kg PNEC sediment (marine water) 1.136 mg/kg PNEC Soil 0.478 mg/kg PNEC Sewage Treatment Plant 85 mg/l

Engineering measures For normal use operators are in open air providing adequate ventilation. Product is mainly enclosed in hose and shothole. Exposure is from outside of hose and sampling.

PPE Safety glasses Impact resistance F or B, or goggles; Gloves to European standard EN374. They can include : Nitrile, Neoprene, Fluor-elastomer or PVC e.g. Ansell Alphatec; Overalls to EN 471 Class 2 or greater.

Exposure controls


Appearance/ colour Viscous fluid, containing varying amounts of suspended solids. (ammonium nitrate prills- none for Blendex 100). Light brown/white in colour.

Odour Slightly oily/diesel smell. May also smell of vinegar.


pH Not available.


Not available.


Not available.

Flash point Not available.


Flammability None of the ingredients are classed as flammable.


Not available.



Relative Density Ca 1000-1200 when gassed in density pot. May compress to higher densities in the borehole.

Solubility(ies) Essentially insoluble in water, though it will leach ammonium nitrate out of the Blendex over time.


Not available.


Decomposition temperature >150°C

Viscosity The emulsion component has a viscosity in excess of 14,000 cP.

Explosive properties Blendex is a UN Class 1.1 explosive.

Oxiding properties Not available.

Other information




Acute toxicity Product: Not acute toxic by calculation Components Sodium nitrite, oral, 180 mg/kg Ammonium Nitrate LD50, Oral rat, >5,000 mg/kg Ammonium Nitrate LD50, dermal rat, 2,980 mg/kg Oil LD50, Oral, rat, 4,150 mg/kg Oil LD50, Dermal, rat, 1,700 mg/kg Oil LC50, Inhalation, rat, 5.28 mg/l Acetic acid LD50 Oral rat, 3,310 mg/kg Acetic acid LC50 Inhalation, rat, 4h, >40 mg/l

Skin corrosion / irritation Product not classified as skin corrosive Components Oil: Well defined erythema, No oedema Acetic acid: very corrosive



Reactivity Explosive: may detonate if subjected to fire / naked flame, impact, friction and sparks.

Chemical Stability The product is stable under normal ambient conditions (-20 to +40°C). It is intended for immediate use on site when mixed. If stored for several days there may be some loss of gas which will reduce sensitivity. On storage for long periods the ammonium nitrate in the emulsion may start to crystallise out.


Avoid strong acids and bases.

Conditions to avoid Avoid fire, impact, friction and static electricity.

Incompatible materials Strong acids and alkalis. Chromates, Copper. Copper alloys. Chlorates.


The after detonation fume may will include carbon dioxide and nitrogen and may include some quantities of Carbon monoxide and oxides of nitrogen.



Product causes severe eye irritation.Components20% Sodium nitrite solution irritating to eyes.Ammonium nitrate: Causes serious eye irritation.Acetic acid: very corrosive.


Components do not cause sensitisation or not classified.

Germ Cell Mutagenicity Oil: This substance has no evidence of mutagenic properties.Acetic acid: In vivo tests did not show mutagenic effects.

Carcinogenicity Oil: NOAEL Oral, rat, 750 mg/kg. No evidence it can cause cancer. Acetic acid: Animal testing did not show any carcinogenic effects.

Reproduction toxicity Fertility Oil: NOAEL Oral, rat, >3,000 mg/kg. No evidence of toxicity to reproduction. Development – Maternal toxicity Oil: NOAEC Oral, rat, 500 mg/kg. No evidence of toxicity to reproduction. Acetic acid not toxic for foetal development nor teratogenic for the mother animal;

STOT – single exposure Ammonium Nitrate: NOAEL Oral, rat>1500 mg/kg Acetic acid: not classified as specific target organ toxicant.

STOT – repeated exposure Ammonium Nitrate: NOAEL Oral, rat, 90 days, >256 mg/kg Oil: NOAEL Oral, rat, >1056 mg/kg Acetic acid: not classified as specific target organ toxicant, repeated exposure.

Aspiration hazard Product has too high a viscosity to be classed as an aspiration hazard.




ToxicityAcute Toxicity

Component Result Species Exposure

Ammonium Nitrate

LC50 1 447 mg/l Fish 48h

LC50 1 490 mg/l Other aquatic organisms

EC50 1700 mg/l Algae 72h

Sodium Nitrite

LC50 0.54-26.3 mg/l

Fish (Oncorhynchus mykiss)

96h

LC50 4.93 mg/l Crustaceans 96h

EC50 15.4 mg/l Daphnia magna (Water flea)

48 h

EC50 > 100 mg/l Algae (Scenedesmus subspicatus)

72 h

EC10 210 mg/l Bacteria - activated sludge

3 h

EC50 421 mg/l Bacteria Protozoa 48 h

Oil

LC0 > 1000 mg/l Fish (Oncorhynchus mykiss)

96 hours

EC0 > 1000 mg/l Daphnia magna (Water flea)

48 h

EC50 1000 mg/l Selenastrum capricornutum

72 h

EC0 > 1000 mg/l Bacteria - activated sludge

5 m


Chronic Toxicity

Component Result Species Exposure

Oil

5,000 mg/l Fish early life stage Brachydanio rerio (Zebra Fish)

21 days

EC50 5,000 mg/l Invertebrates Daphnia magna (Water flea)

21 days

Acetic acid

LC50 75 mg/l Fish Lepomis macrochirus

96 h

LC50 88 mg/l Fish Pimephales promelas

96 h

EC50 95 mg/l Daphnia magna (Water flea)

24 h

EC10 1000 mg/l Bacteria Pseudomonas putida

0.5 h

EC50 > 300.82 mg/l Algae Skeletonema costatum

72 h



Ammonium Nitrate: Determination methods not applicable. Sodium nitrite: Determination methods not applicable. Inorganic product which is not removable from water by biological processes. Oil: The product is readily biodegradable. Acetic acid: Readily biodegradable.

Bioaccumulation potential Ammonium Nitrite, sodium nitrite and Acetic acid: Bio-accumulation not expected. Oil is a hydrocarbon UVCB Standard tests not applicable.



Product disposal The product is an explosive and must be treated as such. Under the supervision of an expert, the product may be destroyed by detonation in a borehole or by burning at an approved site. For more guidance see the HSE/CBI Explosives Industry Group publication: “Guidance for the Safe Management of the Disposal of Explosives”, January 2007.

Container Disposal Product is normally mixed on site and pumped into the shot hole for immediate use – no packaging.



Mobility in soil Ammonium Nitrate. Sodium nitrite, acetic acid: Components are mobile in a water environment, but may need to be leached out of the emulsion. Oil is a hydrocarbon UVCB. Standard tests not applicable.


Ammonium nitrate: No further information available. Sodium nitrite: This substance is not considered to be persistent, bioaccumulating nor toxic (PBT). This substance is not considered to be very persistent nor very bioaccumulating (vPvB). Oil: This substance is not classified as PBT or vPvB according to current EU criteria. Acetic acid: This substance is not considered to be persistent, bioaccumulating nor toxic (PBT). This substance is not considered to be very persistent and very bioaccumulating (vPvB).

Other Adverse Effects Sodium nitrite: Very toxic to aquatic organisms. Do not flush into surface water or sanitary sewer system. Avoid subsoil penetration. Note: sodium nitrite is destroyed in the gassing of the Blendex.


Note: The product is produced by mixing on site for immediate use, so it would not normally be transported, as such.

UN Number UN0241.

UN Proper Shipping Name Explosive, Blasting, Type E.


Packing Group Not applied to explosives but generally taken to be PGII.

Environmental Hazards Not a marine pollutant.

Special Precautions for User If the product is to be transported, then it must be checked that the product in its packaging has been classified by the HSE, as the product is not normally transported.


The product is not intended to be transported by sea in bulk/IBCs.


UK Legislation Carriage of Dangerous Goods Regulations 2009, as amended – implementing ADR.Classification (Hazard Information and Packaging for Supply) Regs 2009, as amended.Control of Substances Hazardous to Health Regs 2002, as amended.Control of Major Accident Hazard Regulations 2015 would not normally apply as the product is not stored.The Explosive Regulations 2014, as amended.

EC Regulations Registration Evaluation, Authorisation and Restriction of Chemicals Regulations 2006, as amended.

Chemical Safety Assessment No Chemical Safety Assessment has been carried out for this substance/mixture by the supplier. Chemical safety assessments exist for Ammonium nitrate, sodium nitrite, the oil and acetic acid.


Relevant hazard Statements and Precautionary statementsH201 Explosive mass Explosion Hazard.H226 Flammable liquid and vapour.H272 May intensify fire; oxidizer.H301 Toxic if swallowed.H304 May be fatal if swallowed and enters airways.H314 Causes severe skin burns and eye damage.H319 Causes serious eye irritation.H400 Very toxic to aquatic life.H413 May cause long lasting harmful effects to aquatic life.

P210: Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.P264: Wash hands thoroughly after handling.P280: Wear protective gloves/protective clothing/eye protection/face protection.P370+380: In case of fire: Evacuate area.P372: Explosion risk in case of fire.P373: DO NOT fight fire when fire reaches explosives.P305+351+338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses if present and easy to do – continue rinsing.P337+313: If eye irritation persists get medical advice/attention Advice on training.



OTHER INFORMATION


Changes


11

12 24/11/2016 Completely re-written to comply with CLP requirements

Abbreviations and acronymsUVCB Substances of unknown or variable composition, complex reaction products or biological materials.ReferencesEvaluation method for mixtures

Detonating Cord

Detonating Cord is a linear explosive consisting of a PETN powder wrapped in a flexible plastic outer coating. Manufactured in the EU EPC-UK is able to supply a comprehensive range of cord weights for a variety of applications.

Detonating cord has a variety of uses in quarrying, mining, civil engineering and other specialist applications. Low strength detonating cords are typically used for the initiation of shock tube in both quarrying and demolition. Higher strength cord is typically used in pre-splitting applications or as a main charge in demolition.

The multilayer construction of the cord ensures a high resistance to tension and abrasion whilst in use.

6

Detonating Cord DataDaveycord


Product Type Detonating Cord

Product Name Daveycord 12g Daveycord 20g

Cord Colour Green

Core Loading (g/m) 12 20

VOD (m/s) 7000

Tensile Strength (N) >784

Outer Diameter (mm) 5.2 6.2

Length/reel (m) 125 100

Reels/box 4

Water Resistant Yes (if cut end sealed)

Detonator Sensitive Yes (0.6g of Equivalent PETN)

Temperature Range (use) oC

-30/+50

Shelf Life 4 years

UN Number UN0065

UN Description Cord, Detonating, Flexible

UN Class/ Compatibility Group

1.1D

CE Mark 0080EXP970086 0080EXP970088


Product Type Detonating Cord

Product Name Daveycord 40g SEICord 100g

Cord Colour Green Peach

Core Loading (g/m) 40 100

VOD (m/s) 6500 >7000

Tensile Strength (N) >784 >2647

Outer Diameter (mm) 8.3 12.5

Length/reel (m) 100 50

Reels/box 4 1

Water Resistant Yes (if cut end sealed)

Detonator Sensitive Yes (0.6g of Equivalent PETN)

Temperature Range (use) oC

-30/+50

Shelf Life 4 years 5 years

UN Number UN0065

UN Description Cord, Detonating, Flexible


1.1D

CE Mark 0080EXP970090 0080EXP030037



Product Identifier Detonating cord, Daveycord, Seicord.Types supplied: Daveycord 5. Daveycord 10, Daveycord 20, Daveycord 40, Daveycord 70, Seicord 100.The number indicates the PETN content of the cord in g/m

Use of the Product Recommended use: the product is generally used in excavation and demolition work and in the mining industry.It can also be used as a linear charge explosive whenever allowed by the current state of the art, for example to produce isolated blocks of rock, for controlled demolitions, for contour and preliminary cutting, and detonation transmission.Never use in the presence of firedamp.Not recommended use: the intended use is specified above. Other uses are not recommended unless an evaluation is conducted before starting use, which provides evidence that the associated risks are being monitored.

Manufacturer / Supplier EPC-UK plc





01773 832253


Explosive Div 1.1 H201: Explosive, mass explosion hazard.


Signal Word Danger.

Warning H201: Explosive, mass explosion hazard.

Other Hazards vPvB substances: noneSubstances PBT: noneOTHER HAZARDS. If used improperly, it can explode and cause fires.

Classification of the Substance or Mixture

Label elements


Mixtures

The detonating fuse consists of an explosive core (dry PETN with the addition of up to 0.5% graphite) containing two fibres in the centre made of polyester or other synthetic material. The explosive is contained in a tube formed of tapes made of polypropylene or other synthetic material wrapped in fabric made of polypropylene or other synthetic material and covered with a PVC or polyethylene sheath. In addition to containing the explosive, the tube gives the fuse impermeability and tensile strength.

PETN: pure PETN can be added with up to 0.5% graphite.

Polyethylene and/or Polypropylene and/or PVC plastic componentsAll the synthetic materials are treated with additives that make them antistatic.The components are perfectly contained in a suitable casing.

Hazardous components within the meaning of CLP regulations:

Name CAS No EINECS Classification

PETN 78-11-5 201-084-3 Unst Exp H200

Additional information: for the full text of hazard H, see Other Information Section.


FIRST AID MEASURES

General Call first aid in the event of an accidental detonation. Protect yourself and move the victim to safety.Untrained and uninstructed persons shall not handle this material nor its packaging. In the event of contact with PETN held in the cord:

First Aid – Inhalation • Remove the victim from the contaminated area and allow him to rest in a ventilated room or in the open air. If symptoms persist, such as coughing, consult a physician.• Perform artificial respiration if breathing has stopped and summon a doctor.

First Aid – Skin Does not occur under normal handling conditions.If the container breaks and product comes into contact with the skin:• Remove contaminated clothing immediately.• Wash the affected areas thoroughly with water.• Seek medical advice.

First Aid – Eyes Does not occur under normal handling conditions.In case of contact of the product with eyes:• Immediately flush eyes with running water for 15 minutes, keeping the eyelids open.• Consult an ophthalmologist.

First Aid – Ingestion Does not occur under normal handling conditions.If the container breaks and product comes into contact with the eyes:• Rinse the mouth with water, but only if the victim is fully conscious.• Never induce vomiting• Summon a doctor, who will assess the need for a stomach lavage.



Eye contact PETN causes slight irritation to the eyes.

Skin contact PETN causes slight irritation to skin and continuous contact with the skin leads to sensitisation. Information on PETN is limited. Headache.

Inhalation PETN causes slight irritation to mucous membranes. It is moderately toxic by inhalation, causes irritation in respiratory tracts, coughing, breathing difficulties, sensations of burning, possible pulmonary oedema, possible obstruction of upper respiratory tracts, and may affect breathing. May cause headaches and dizziness. Inhaling dust/vapours may also affect the central nervous system, cardiovascular system, and urinary system

Ingestion May cause irritation in the gastrointestinal tracts, causing nausea, vomiting, and diarrhoea. May cause headaches and dizziness. May affect the liver, blood, and eyes.

General PETN is a vasodilator. Prolonged or repeated exposure may cause symptoms similar to acute exposure and may affect hearing and the endocrine system.


Treat symptomatically. Please follow the instructions in description of First Aid Measures section above.


Effects do not occur under normal handling conditions. Effects refer to coming into contact with the PETN content of the cord. Nausea and vomiting are reported following excessive exposure to PETN powder.Before giving aid, take care to wear personal protection equipment.



Extinguishing Media Large quantities of water.Do not fight fire when fire reaches explosives: explosion risk! Fire of explosives cannot be extinguished with any fire-fighting equipment.DO NOT ATTEMPT TO EXTINGUISH THE BURNING EXPLOSIVES! RISK OF EXPLOSION.Try to remain calm and extinguish the fire before it reaches the product. In case of the risk of an explosion, do not attempt to extinguish the fire. Evacuate to a shelter located at least 300m away. Secure the site against unauthorized access.


If one or more products are enveloped in flames, there is an immediate risk of a mass explosion, so evacuate as quickly as possible to at least 300 metres from the flames and, if possible, seek shelter behind a natural or artificial barrier.Product combustion generates toxic fumes and gases, mainly carbon monoxide and nitrous fumes.After the fire has been extinguished, the site where it took place may only be entered after ascertaining that the entire area has completely cooled. Damaged live detonators may be present in the area.

Advice for Firefighters If the flames do not involve the product directly, extinguish them using the media recommended for the specific type of fire (water, dry chemicals or CO2, sand, etc.).Move the product away from the fire area if possible.If the fire cannot be extinguished immediately and it directly involves the product:• Do not attempt to put the fire out as an explosion is likely.• Evacuate the area immediately.• Take shelter and alert local authorities.• Only if possible, fight the fire from a protected position using large quantities of water.



For non-emergency personnel• Don suitable clothing, see Exposure Controls.• Eliminate any potential sources of ignition nearby.For emergency personnel• Don appropriate PPE and gather the dispersed product using rigorously anti-sparking tools and equipment (wood, plastic).• Remove all potential sources of ignition and avoid any action that could cause an impact, friction, sparking or a sudden raise in temperature

Environmental Precautions Avoid contaminating the soil and water.Call the fire brigade if soil or water is contaminated.Please refer to Disposal Considerations for product disposal instructions.


Place the product in a suitable container, preferably a cardboard box or canister that can be sealed after removal of the product.Avoid any impact, friction, or anything that may lead to a spark or electrostatic discharge.Never use tools that generate sparks.Keep anyone not involved in the operation well away from the danger area and inform them of the risk of explosion.Contamination of the spilled product with materials such as powder, sand or metal particles may increase the explosive’s sensitivity to impact or friction. Keep away from incompatible chemicals.

Reference to other sections Also see Handling and Storage, Exposure Control/Personal Protection and Disposal Considerations.

The following measures should be taken in the unlikely event that the containing cord breaks or the explosive inside is dispersed and/or fallen on the ground.




Precautionary measures:• Handle with care, bearing in mind the potential hazards.• Earth all electrical equipment present and any conductive item.• Keep the product well away from heat, direct sunlight and other sources of ignition, including combustible materials.User information:• The boxes must be handled with care and opened using tools that do no produce sparks and do not damage the contents.• DO NOT SMOKE (including electronic cigarettes) and do not use naked flame during handling.• Risk of explosion due to impact, friction, fire or other sources of ignition.Occupational health and safety:• When handling the product, avoid ingesting or inhaling any solid particles that are formed.• If the product comes into contact with the skin, due for example to container breakage, wash the area thoroughly with soap and water.• Do not eat, drink or smoke when handling the product.• Wash your hands thoroughly after handling the product.• Remove contaminated clothes and PPE before entering areas where food and drink are consumed.


Precautionary measures:• Store only in licensed stores that are suitable for the purpose, in accordance with the Explosive Regulation.• Take measures to avoid the generation and accumulation of electrostatic charges.• Keep the storage areas closed.• Do not smoke or do anything else that can lead to impact, friction or a sudden rise in temperature.Storage temperature -30°C to +50°CStorage limits for which COMAH applies for Explosives: 10 tonnes Lower Tier; 50 tonnes Upper TierIncompatible materials:Store in a magazine suitable for explosives and only with other explosives of a compatible category.


Specific end use(s) The PETN detonating cord is supplied for use, testing and analysis in civil work excavation, demolition and in the mining industry by qualified personnel who have been fully trained to handle explosives.


Control Parameter Occupational exposure limits:Not applicable under normal handling conditions.Information about the main explosive substance (PETN):Not Available.Biological limit values:Does not contain materials with a known current value for biological limits.Limit values for occupational exposure and/or biological limit values for atmospheric contaminants:No contaminants are produced under normal handling conditions.If the product is enveloped by fire and starts to combust, beware of the fumes released, mainly NOx and CO, which can cause hazardous consequences if they are inhaled or come into contact with the eyes.DNEL exposure limit valuesNot Available.

Technical measures The generation and accumulation of electrostatic charge on people and equipment must be avoided by means of effective earthing. Provide good ventilation.

Industrial hygiene Do not eat, drink or smoke when handling the product. Do not swallow or inhale any solid particles that have formed when handling the product.

Respiratory protection Not required during normal handling. Do not breathe fumes after detonation.

Exposure controls



Eye protection Not required during normal handling, but recommended.

Skin protection Not required during normal handling.Work clothes must be antistatic, made of cotton for instance, and flame retardant.

Hand protection Not required during normal handling.It is advisable to use appropriate work gloves anyway, even with sealed products.

Other Use appropriate anti-static safety footwear.

Environmental exposure monitoring

Not required during normal handling.

Exposure controls


Appearance/ colour Plasticised cord of different colour, diameter and length, wound up around a suitable reel. The plastic coating has a characteristic colour and varies depending on the type of approved fuse.

Odour No characteristic odour.


pH Not applicable.


Not applicable to cord. PETN: 141.3°C


No data available for cord. PETN: 190°C


Evaporation Rate Not applicable.

Flammability No data available.


Not applicable.



Vapour pressure Not applicable.

Vapour density Not applicable.

Relative Density At least 1.1 kg/dm. PETN is 1.773

Solubility(ies) Water solubility: Not applicable. PETN not solubleLipid solubility: PETN is soluble in the main organic solvents (e.g. 20g/100 ml of acetone); the remaining components are dissolved by specific solvents.


Not available.

Auto-ignition temperature Ca 200°C

Decomposition temperature Not applicable.

Viscosity Not applicable.

Explosive properties Detonation speed: ≥ 6000 m/sExplosion heat: 6402 kJ/kgSensitivity to impacts 3 NmSensitivity to friction: 60 N

Oxidising properties Not applicable.

Mixability Not applicable.

Conductivity Not applicable.


Other information


Reactivity Impact, friction, electrostatic discharge, excessive temperature rise, naked flames and other causes of ignition can cause explosion.Fire can lead to explosion.

Chemical Stability Stable within the storage temperatures recommended in Handling and Storage and within the item's usage limitations (expiration date).


When the product is exposed to heat, there is a risk for the product inside to explode at temperatures well below the auto-ignition temperature. Explosion in the event of shock, pressure, impact, friction, fire, sparks, electrostatic discharges, or other sources of ignition.




Incompatible materials All explosives and explosive devices are chemically incompatible with acids, alkalis and highly reactive materials such as reducing agents and highly oxidising agents.Explosives and explosive devices are physically incompatible with nitrophenols and materials that can sensitize the explosive and lead to an uncontrollable reaction.Combinations with phosphorous, ammonium, amines, metal powders, chlorates, mercury, and organic compounds or solvents must be avoided.


Nitrous fumes and carbon monoxide during combustion.


Acute toxicity PETN:LD50 (oral, rat): 1660 mg/kg, Not classifiable based on the information available. PETN is moderately harmful by inhalation or ingestion.Can cause slight irritation to the mucous membranes.PETN powder is a vasodilator, hence in case of inhalation causes effects similar to those of nitroglycerine, i.e. headache, fatigue, decrease in blood pressure, nausea.

Skin corrosion / irritation PETN: Skin irritation.


PETN: Slight irritation.


No data available.

Information on toxicological effectsUnder normal conditions, the explosive is enclosed in special wrapping. If the wrapping breaks, the toxicity of the contents is similar to that of the component present in the highest percentage, namely PETN.


Germ Cell Mutagenicity No data available.

Carcinogenicity No data available.

Reproduction toxicity No data available.

STOT – single exposure Not applicable.

STOT – repeated exposure Not applicable.

Aspiration hazard Not applicable.

Acute toxicity Not applicable.

Skin corrosion / irritation Not applicable.


Not applicable.


Not applicable.

Germ Cell Mutagenicity Not applicable.

Carcinogenicity Not applicable.

Reproduction toxicity Not applicable.

STOT – single exposure Not applicable.

STOT – repeated exposure Not applicable.


In relation to the product


Toxicity Under normal conditions, the explosive is enclosed in a special wrapping.

If the wrapping breaks, refer to the following eco-toxicological properties of PETN.

Eco-toxicological information relating to the main substances contained in the explosive mixture:

Pentaerythritol tetra nitrate (P.E.T.N.) - CAS: 78-11-5, EC: 201-084-3

LC50 (Fish, Pimephales promelas, 96 hours): 27000 mg/l

LC50 (Daphnia magna, 48 hours): 8500 mg/l




Hydrolysis is not expected to significantly affect the environmental fate of PETN. The primary physical degradation mechanism of PETN in aqueous solution is photolysis. PETN is expected to persist at length in clear illuminated surface water. Formaldehyde and nitrosamines have been identified as photoproducts. Nitrosamines could be of primary importance for the environment due to their mutagenic/carcinogenic potential. In these products, however, conversion only occurs in a limited portion if the product itself is photoreactive. Biodegradation of PETN occurs in water and soil, mainly in anaerobic conditions.

Bioaccumulation potential Data not available.

Mobility in soil Data not available.


The product does not meet the classification criteria for PBT.The product does not meet the classification criteria for vPvB.

Other Adverse Effects Toxicity for water (referring to the PETN content and not the finished product): harmful to aquatic organisms. It can lead to long-term, harmful effects under water.


Product Considering the potential risk associated with the kind of product, it must only be disposed by personnel specifically trained for the purpose.Avoid or reduce the generation of waste to a minimum.Collect waste in appropriate containers in accordance with the applicable regulations, ready for disposal using approved methods.The buildings where containers of waste are kept must be properly equipped and authorised by the competent authorities.Waste must never be discharged into the drains, waterways or general waste.See the CBI/EIG “Guidance for the Safe Management and Disposal of Explosives”.


DISPOSAL CONSIDERATIONS Continued

Product Packaging Packaging must be destroyed in accordance with the applicable regulations. Always check packaging for residual explosives before burning.



UN Number UN 0065.

UN Proper Shipping Name Detonating cord, flexible.


Packing Group Not applicable.

Environmental Hazards Not classified.

Special Precautions for User As an explosive, the product is a high consequence dangerous good and adequate transport precaution must be taken for its security.For IMDG code EmS: F-B, S-XTransport by air under ICAO/IATA is forbidden.


Not applicable.





Not envisaged for one article, pursuant to EC Regulation no. 1906/2007.



OTHER INFORMATION


ChangesIssue Issue Date Changes11 26/02/2017 Completely re-written

Abbreviations and acronyms

ADR: European Agreement concerning the International Carriage of Dangerous Goods by Road.

CAS: Chemical Abstracts Service (American Chemical Society).

CLP: Classification, Labelling, Packaging.

DNEL: Derived No Effect Level.

GHS: Globally Harmonized System of Classification and Labelling of Chemicals.

IATA: International Air Transport Association.

IATA-DGR: Dangerous Goods Regulation by the "International Air Transport Association" (IATA).

ICAO: International Civil Aviation Organization.

ICAO T.I.: International Civil Aviation Organization Technical Instructions.

IC50 : Inhibition Concentration for 50 percent of the test population.

IMDG: International Maritime Dangerous Goods Code.

LC50: Lethal Concentration for 50 percent of the test population.

LD50: Lethal Doses for 50 percent of the test population.

MARPOL 73/78: International Convention for the Prevention of Pollution From Ships, 1973 as modified by the Protocol of 1978.

NIOSH-REL: National Institute for Occupational Safety and Health (USA) – Recommended Exposure Limits.

NOEC: No Observed Effect Concentration.

OSHA-PEL: Occupational Safety & Health Administration (USA) - Permissible Exposure Limits.

PNEC: Predicted No-Effect Concentration.

RID: Regulations concerning the International Carriage of Dangerous Goods by Rail.

STEL: Short-Term Exposure Level

STOT: Specific Target Organ Toxicity.

TLV: Threshold Level Value.

TLV-TWA: Threshold Level Value for the average time weighted over 8 hours.

VLEP: Occupational exposure limit values

OTHER INFORMATION

References

ADR

IMDG

IATA

Guidance for the Safe Management and Disposal of Explosives, 2007.

ECDIN - Environmental Chemicals Data and Information Network - Joint Research Centre, Commission of the European Communities.

SAX's DANGEROUS PROPERTIES OF INDUSTRIAL MATERIALS - Eighth Edition - Van Nostrand Reinold.

National Institute of Health – National Chemicals Inventor

Relevant hazard Statements and Precautionary statements

Meanings of Hazard Phrases

H200 Unstable explosive.

H201 Explosive; mass explosive hazard.

Advice on training

Handling of this product should only be allowed by qualified persons.


Electric Detonators

EPC-UK supply standard electric detonators manufactured by Davey Bickford in France.

The Daveydet Short Delay range consists of 21 delay numbers with a time interval of 25ms between successive numbers in the range to give better breakage and controlled vibration.

The Daveydet Half-Second range consists of 13 delay numbers with a time interval of 0.5 seconds between successive numbers in the range.

Daveydet Medium Intensity detonators are suitable for general blasting operations. For situations where a higher degree of protection from electrical sources such as radios, mobile phones etc. is required, the Daveydet High Intensity detonators are more suitable. The High Intensity detonator requires the use of a high output exploder.

7

Electric Detonators Data

Common features for standard electric detonatorsThe detonator shell is made of Aluminium. The base of the detonator tube is stamped with a letter Y to identify the manufacturer. The delay period number Is printed on the side of the detonator. Instantaneous detonators have no markings on the base of the aluminium tube. The initiating power of these detonators is equivalent to no. 10 strength as a result of the compression of the 0.8g base charge.

Triple crimping of the detonator shell ensures excellent water resistant characteristics:

2 days at 25 bars

8 days at 10 bars

28 days at 5 bars.

The twinned copper wires can support a tensile strength of 10daN without internal disturbance of the fusehead assembly. The resistance per unit length of twinned wires is 0.14W/m for 0.56mm diameter copper wire and 0.095W/m for 0.7mm diameter copper wire.

The lead wires of the detonator are copper and have colour-coded insulation.

The wire coating is formed from PVC, which offers a good resistance to abrasion.

Delayed action Daveydet detonators are available in the following delay numbers:

• Short Delay series 1 to 20 inclusive – delay interval 25 milliseconds

• Half Second series 1 to 10 inclusive – delay interval 500 milliseconds.


The detonators have a plastic tag on one of the wires that indicates the delay number of the detonator.

The fuseheads in Daveydet detonators have the following electrical characteristics:

The fuseheads in Daveydet detonators have the following electrical characteristics:

Detonator Type Wire Colours

High Intensity Instantaneous Detonators

White White

Medium Intensity Instantaneous Detonators

Yellow White

Medium Intensity Short Delay Detonators

Pink Green

Medium Intensity Half Second Detonators

Red Yellow

Medium Intensity

High Intensity

Fusehead Resistance 0.45 ohms 0.05 ohms

Guaranteed no fire current

0.65 amps 4.2 amps

Guaranteed all fire current for one detonator

1.0 amps 7.0 amps

Recommended series firing current

1.7 amps 13 amps

Maximum no fire energy

8mj/W 500mj/W

Minimum operating energy

15mj/W 1000mj/W

• Short circuited lead wires and shell

11kV with 2000pF

25kV with 3000pF

• One lead wire and the shell

6kV with 2000pF

25kV with 3000pF

• Two ends of the detonator lead wires

5kV with 2000pF

25kV with 3000pF

Behaviour to static electric discharge between:

Each fusehead is protected by an insulating anti-static sleeve.EPC-UK also supply the Daveydet P instantaneous and short delay range of detonators. These are approved for use in coal and other safety lamp mines. The half second permitted range of detonators is approved for use in certain circumstances underground in coal and other safety lamp mines. The electrical characteristics of these detonators are different to Medium Intensity Detonators.

For Seismic prospecting EPC-UK supply the Daveydet SR range of detonators. These detonators have unique electrical characteristics and cannot be fired in the same circuit as other detonators.

Classification and Labelling

Electric detonators with lead wire lengths between 2m and 12m are presented as twinned folded wires.

These detonators are classified 1.1B. The UN No. for transportation is UN.0030.

Upon request detonators can also be packaged as 1.4B and the UN No. for transportation is UN.0459.

Plain Detonators

Herica plain detonators for use with safety fuse can be supplied by EPC-UK.

For further details on these products please contact the Explosive Engineering Department department of EPC-UK.



Product Identifier SERIES 4000 ELECTRIC DETONATORDaveydet MI (medium intensity), delay, short delay and instantaneous; Daveydet HI (high intensity) instantaneous; and Daveydet SR (seismic) detonators.

Use of the Product Explosive initiation - industrial useThese detonators are not suitable for use in gassy mines. Daveydet P detonators should be used in those conditions.






01773 832253


Classification of Mixture Classification According to EC Regulation 1272/2008 Detonators are explosive articles.Without packaging electric detonators are classified H201 (explosive : mass explosion hazard).


Hazard Pictogram

Signal Word Danger.

Hazard Statement Warning H201 : explosive : mass explosion hazard.

Label elements


Precautionary Statements P210 : keep away from heat /sparks / open flames / hot surfaces - no smoking.P250 : do not subject to grinding / shock / friction.P372 : explosion risk in case of fire.P401 : store at a temperature. between -10 and 50°C.P501 : dispose of contents / container according to the rules relating to the explosives.

Other Hazards Not applicable: the explosive material is not accessible in normal use.


Substances Metal casing enclosing:- Primary explosive ≤ 0.2g- And/or Secondary explosive ≤ 0.8g- And/or Delay composition- And a priming cap coated with a pyrotechnic pasteA plastic plug is crimped on to the open end of the casing used for passing the electrical wires through.Pyrotechnical substance TNT mass equivalent: 1g equivalent TNT per detonator.

FIRST AID MEASURES

General Protect yourself, notify emergency responders and take the victim to safety.


Not applicable.


For injuries due to splinters, provide first aid then request medical advice if necessary.For explosions nearby, check hearing.Treat symptoms in all cases.




Extinguishing Media None.


Set up a safety perimeter.Do not personally intervene to stop a pyrotechnics fire.Whenever possible, measures should be taken to prevent the fire from spreading.After the fire has been extinguished, the site where it took place may only be entered after ascertaining that the entire area has cooled completely.

Advice for Firefighters When intervening, wear special fire prevention equipment (respiratory device, helmet, etc.).



Pyrotechnic materials spilled accidentally must be collected by authorised personnel, so that they can be disposed of and if necessary, destroyed (see waste handling, Disposal Considerations). Avoid any impacts, friction, or anything that may lead to a spark or electrostatic discharge.

Keep away from incompatible chemicals.

If there is broken packaging around pyrotechnic items, transfer the items into a wood or cardboard container, taking care to avoid damaging them (impact, spark, heat, etc.).

Environmental Precautions Not applicable.


Not applicable.

Reference to other sections Not applicable.



Handle with care, avoiding impacts, friction and exposure to heat, naked lights, electromagnetic radiation (including mobile phones), electrostatic charges, etc.Any use not covered in the technical instructions or by untrained personnel is prohibited.No smoking.


Storage temperature: -10 °C to +50°C

Protect from humidity. Generally storage of detonators must be licenced in accordance with the Explosives Regulations 2014.

COMAH storage limits for Explosives depends on the classification:

Class 1.1 Class 1.4Lower Tier 10 tonnes; 50 tonnesUpper Tier 50 tonnes; 200 tonnes

Specific end use(s) Not applicable


Control Parameter Not affected

Exposure controls Respiratory protection: Do not inhale the smoke after a fire has started.- Hand protection: wearing gloves recommended.- Eye protection: wearing goggles recommended.- Hearing protection: close to an explosion, wearing hearing protection appropriate for the distance recommended.



Not applicable - article.

Explosive properties Maximum no fire currentMedium intensity detonators 0.65 AmpsHigh intensity detonator 4.2 Amps

Other information Not applicable.



Reactivity Not applicable.

Chemical Stability Stable within the storage temperatures recommended in Handling and Storage and within the item’s usage limitations (expiration date).


Not applicable.

Conditions to avoid Avoid any exposure to high temperatures, impacts, friction, electrostatic discharges or stray currents.

Incompatible materials Acids and alkalis.


Fumes contain lead.Possible release of oxides of carbon and nitrogen.


Toxicity No hazards identified for the item.


No hazards identified for the item.

Bioaccumulation potential No hazards identified for the item.

Mobility in soil No hazards identified for the item.


No hazards identified for the item.

Other Adverse Effects No hazards identified for the item.



No hazards identified for the item

Acute toxicity Skin corrosion / irritation Serious eye damage / irritation Respiratory or skin sensitisation Germ Cell Mutagenicity Carcinogenicity Reproduction toxicity STOT – single exposure STOT – repeated exposure Aspiration hazard


Product disposal Do not place in waste bins, drains, or landfill.Processing and destruction require specific procedures and must be covered in a special study that takes into account the product’s condition and treatment of the waste after destruction. This operation must be carried out by trained, authorised personnel in approved areas. All materials contaminated by pyrotechnic materials from the item should also be considered pyrotechnic waste. See the HSE/CBI-EIG Guidance.

Container Disposal While packaging may often be destroyed by burning, great care must be taken to ensure there are no detonators remaining inside.



UN Number UN 0030 UN 0255 UN 0456

UN Proper Shipping Name

Detonators, Electric, for Blasting



Transport Hazard Classes

1.1B 1.4B 1.4S

Packing Group Not applicable Not applicable Not applicable

Environmental Hazards

Not applicable Not applicable Not applicable

Special Precautions for UserADR Specifics (road)IATA specifics (Air)IMDG specifics (sea)

NoneForbiddenNone

NoneCargo aircraft onlyNone

NoneNoneNone


Not applicable Not applicable Not applicable



UK Legislation Carriage of Dangerous Goods Regulations 2009, as amended – implementing ADRClassification (Hazard Information and Packaging for Supply) Regs 2009, as amended.Control of Substances Hazardous to Health regs 2002, as amendedThe Explosives regulation 2014, as amendedControl of Major Accident Hazard Regulations 2015.


Chemical Safety Assessment Not applicable.



ReferencesHSE/CBI EIG publication “Guidance for the Safe management of the Disposal of Explosives”, January 2007.

Evaluation method for mixtures: Not applicable.

Meaning of Hazard Phrases and Precautionary statementsMeanings of Hazard PhrasesH201 : explosive : mass explosion hazard.Meanings of Precautionary StatementsP210 : keep away from heat /sparks / open flames / hot surfaces - no smoking.P250 : do not subject to grinding / shock / friction.P372 : explosion risk in case of fire.P401 : store at a temperature between -10 and 50°C.P501 : dispose of contents / container according to the rules relating to the explosives.

Advice on trainingUsers of detonators and other explosives should undergo suitable training, e.g.shot firer’s course. Contact EPC-UK for availability of courses.


OTHER INFORMATION

Changes


7 06/02/2017 Re-written

Electronic Detonators

Electronic Detonators form a modern fully programmable high strength detonators. Each detonator contains a circuit board that can be programmed to initiate at a precise time within a firing sequence. Detonators are individually programmed via the use of a handheld tagger and initiated via a bespoke blasting box.

EPC-UK supplies the DigiShot electronic detonator to the UK market. Electronic detonators can be used in a variety of applications including quarrying, mining, demolition and other specialist areas. the high strength detonator is suitable for initiating most priming charges. Complex firing patterns can be easily transferred to the detonators through the use of computer based software, when implemented properly the highly accurate initiation timings offer benefits in vibration control, fragmentation and general blast optimisation.

The digital firing system used for initiation means each firing circuit and individual detonator is tested and a record retained in the software prior to firing. The circuit can only be initiated by specialist firing equipment offering benefit in safety and security over traditional systems. The DigiShot system can be fired in a remote configuration offering improved control over the blast danger zone.

8

Electronic Detonators DataDigiShot

Maximum Lead-in wire plus surface harness should not exceed 2500m

*Up to 900 detonators can be fired in synchronisation mode


Product Type Electronic Detonators

Product Name DigiShot

Detonator Shell Copper

Length (mm) 93.75 - 94.25

Diameter (mm) 7.49 - 7.54

Base Charge PETN

Net Explosive Quantity (g) 1

Strength No.8D

Lead Colour Red

Tensile Strength >550N

Temperature Range (use) °C -40/+80

Shelf Life 3 years

UN Number UN00456

UN Descritption 1.4S


Detonators, Electric for Blasting

CE MARK ENB/D/93/16

PACKAGING DETAILS

Product Packaging

Lead Length* 10 15 20 25 30

Units Per Box 42 36 30 24 24

* Other lead lengths are available on request



Product Identifier Digishot Electronic Detonators

Use of the Product A precision initiation system for explosive charges used in commercial mining.






01773 832253


Other Hazards After detonation, dust and fumes may be harmful by inhalation on repeated exposure by inhalation (lead poisoning).

Classification

Electric detonators are designed to explode with a substantial release of energy and should therefore be handled with care. Detonators must not be subjected to impact, friction, or exposed to heat or flame. There is a danger of high velocity penetrating shrapnel within a radius of ±10 m around a detonator. Detonators are explosive articles. Without packaging electronic detonators are classified Exp 1.1 H201 (explosive: mass explosion hazard).

As packaged for transport Digishot detonators may be Class 1.1B or Class 1.4S


Ingredients

Explosive Ingredients Other Ingredients

Lead Azide, PETN, Fusehead compositionGlass, Quartz, phosphor bronze, PVC, Nitrile, ink, resin, silicon, tantalum, ceramic, copper, aluminium, gold, tin, Santoprene, Arnite, polycarbonate, polyethylene, nickel, chromium, iron.

COMPOSITION/INFORMATION ON THE INGREDIENTS Continued

Ingredients

Chemical Name

CAS no. (%) EC number Classification

Lead Compounds

7439-92-1 <1 231-100-4 Repr 1A H360FDAcute Tox. 4 H302, H332STOT RE 2 H373Aquatic Acute 1 H400Aquatic Chronic 1 H410

Lead Azide 13424-46-9 <1 236-542-1 Unst. Expl. H200Acute Tox. 4 H302, H332STOT RE 2 H373Aquatic Acute 1 H400Aquatic Chronic 1 H410Repr 1A H360Df

PETN 78-11-5 <2 201-084-3 Unst Exp H200

Lead Azide is included in the ECHA list of substances of very high concern.

FIRST AID MEASURES

First Aid – Eyes Unlikely unless detonator is fired. Obtain medical attention ASAP.

First Aid – Skin Not harmful unless detonator is fired. Treat for high velocity trauma, stop bleeding and obtain medical attention ASAP.

First Aid – Ingestion Not normal route of entry, but seek medical advice ASAP. Make physician aware of explosive properties of ingested material.

First Aid – Inhalation Unlikely unless detonator is fired. Remove patient from NO2 exposure to clean air and obtain medical attention. Administer oxygen if possible.


Trauma due to high velocity shrapnel.






Extinguishing Media Do not fight the fire if it has reached, or if it will reach the detonators.

If fire may be prevented from reaching the explosives, water, carbon dioxide, extinguishing powders or alcohol resistant foams may be used as appropriate. Don’t use water if electrical equipment is involved.


Try to remain calm and extinguish the fire before it reaches the product. In case of the risk of an explosion, do not attempt to extinguish the fire. Evacuate to a shelter located at least 300m away. Secure the site against unauthorized access.


Evolves toxic fumes (hydrogen chloride and phosgene) from the PVC when heated to the decomposition temperature.

Advice for Firefighters Set up a safety perimeter.Do not personally intervene to stop a pyrotechnics fire.Whenever possible, measures should be taken to prevent the fire from spreading.After the fire has been extinguished, the site where it took place may only be entered after ascertaining that the entire area has cooled completely. Be aware of unexploded detonators in area. When intervening, wear special fire prevention equipment (respiratory device, helmet, etc.).



Damaged or cracked detonators may be very sensitive to sources of ignition. Do not pick up or move damaged detonators. Shut off all possible sources of ignition. Evacuate the area and then inform the relevant authorities or responsible person immediately. In case of a transport accident, notify the local authorities / police, the transport company and supplier.

Environmental Precautions Not applicable.


While undamaged detonators may be picked up, freed of loose contamination and carefully packed in suitable, preferably original, packaging. (Note any change of packing may affect the transport classification). Pyrotechnic materials spilled accidentally must be collected by authorised personnel, so that they can be disposed of and, if necessary, destroyed (see waste handling, Disposal Considerations).

Reference to other sections See Exposure Control/Personal Protection and Disposal Considerations.



Handle with great care. Impact, heat, or flame may cause an explosion.


In well ventilated magazine, licenced in accordance with the Explosives Regulations 2014. The product has a 3 year shelf life from the date of manufacture when stored in accordance with the relevant regulatory requirements. COMAH storage limits for Explosives depends on the classification:

Class 1.1 Class 1.4Lower Tier 10 tonnes; 50 tonnesUpper Tier 50 tonnes; 200 tonnes

Specific end use(s) Not available.



Control Parameter Hazardous materials are encapsulated. No exposure during normal handling is therefore expected.Exposure limits for contents:Lead and lead inorganic compounds.TWA 0.15 mg/m3 (8 hours)Exposure through the skin may be significant.Lead Azide is listed in the ECHA list of substances of very high concern.

Exposure controls Keep materials in their original packaging to prevent exposure. Provide adequate ventilation and where possible ear protection when firing.Where possible wear safety spectacles and non-static producing clothing when handling the detonators.


Appearance A copper tube of 7.5 mm OD and 94.0±0.25 mm or 88.9±0.25 mm in length and may have the words DANGEROUS – BLASTING CAP EXPLOSIVE or DANGER – DETONATEUR – EXPLOSIF printed on the tube. A red coloured cable is secured in the tube by means of a pliable / elastic PVC crimp plug.

Odour Not available.


pH Not applicable.


Not applicable.


Not applicable.



Flammability Not applicable.


Not available.





Relative density Not applicable.

Solubility(ies) Not applicable.


Not applicable.

Auto-ignition temperature 100°C

Decomposition temperature 100°C


Explosive properties Explosive Article (1.1B or 1.4S depending on packaging).


Other information Not applicable.


Reactivity Contains explosive material. Do not expose to temperatures greater than 100°C

Chemical Stability Stable within the storage temperatures recommended in Handling and Storage. Impact heat or flame may cause an explosion.


Not applicable.

Conditions to avoid Avoid any exposure to high temperatures, impacts, friction, electrostatic discharges or stray currents.



Carbon dioxide, Carbon monoxide, lead compounds and oxides of nitrogen.



Acute toxicity Hazardous materials are encapsulated. No exposure during normal handling is therefore expected.Fumes from firing may cause irritation to the gastrointestinal tract. Keep under observation for lead poisoning.Properties of material enclosed inside the detonator.Lead and lead compoundsLDLo: 160 mg/kg, Oral, PigeonPETNLD50: 1,660 mg/g, Oral. ratLDLo: 7,000 mg/kg, Oral, mouse

Skin corrosion / irritation When explosion occurs, treat for high velocity trauma, stop bleeding and obtain medical attention as soon as possible.


Fumes from firing may cause eye irritation.

Reproduction toxicity Lead and lead compounds can cause developmental toxicity impair fertility.

STOT – single exposure No data available.

STOT – repeated exposure Bio-accumulative potential (lead) May cause damage to organs through prolonged or repeated exposure.




Toxicity

Items as supplied and undamaged present no ecological problems to the environment, provided they are disposed of correctly. Components inside the detonator are explosive and toxic to aquatic life.

Ingredient name Species Period Result

Lead and Lead Inorganic compounds

Trout (LC50) 96 hrs 0.14 ppm

Shrimp (LC50) 48 hrs 375 ppm

PETN Pimephales promelas (LC50) 96 hrs 27,000 ppm


Persistence and DegradabilityNot readily bio-degradable

May be harmful to the environment if released in large amounts.

Ingredient name

Lead and Lead Inorganic compounds

Not readily 92,000 high

PETN <28 days 74 low

Persistence/degradability Bio-accumulative potentialLog POW BCE PotentialBOD5 COD

PhotolysisTHOD Aquatic half life

biodegradability

Bioaccumulation potential Possible.



Product disposal Do not place in waste bins, drains, or landfill.Processing and destruction require specific procedures and must also take into account the product’s condition and treatment of the waste after destruction. This operation must be carried out by trained, authorised personnel in approved areas. All materials contaminated by pyrotechnic materials from the item should also be considered pyrotechnic waste. See the HSE/CBI-EIG Guidance.

Container Disposal While packaging may often be destroyed by burning, great care must be taken to ensure there are no detonators remaining inside.




UN Number

UN Proper Shipping Name

Transport Hazard Classes

Packing Group

Environmental Hazards

Special Precautions for UserADR Specifics (road)IATA specifics (Air)IMDG specifics (sea)


UN 0030

Detonators, Electric, for

Blasting

1.1B

Not applicable

Not applicable

None Forbidden

None

Not applicable

UN 0456

Detonators, Electric, for

Blasting

1.4S

Not applicable

Not applicable

None None None

Not applicable


UK Legislation Carriage of Dangerous Goods Regulations 2009, as amended – implementing ADRClassification (Hazard Information and Packaging for Supply) Regs 2009, as amended.Control of Substances Hazardous to Health regs 2002, as amendedThe Explosives regulation 2014, as amendedControl of Major Accident Hazard Regulations 2015.


Chemical Safety Assessment Not applicable.


Abbreviations and acronymsECHA: European Chemical Agency

ReferencesHSE/CBI EIG publication “Guidance for the Safe Management of the Disposal of Explosives”, January 2007.

Evaluation method for mixtures: Not applicable.

Meaning of Hazard Phrases and Precautionary statementsMeanings of Hazard Phrases H201 explosive : mass explosion hazard.H302 Harmful if swallowed.H332 Harmful if inhaled.H360DF May damage the unborn child. Suspected of damaging fertility.H360FD May damage fertility. May damage the unborn child.H373 May cause damage to organs through prolonged or repeated exposure.H400 Very toxic to aquatic life.H410 Very toxic to aquatic life with long-lasting effects.

Advice on training Users of detonators and other explosives should undergo suitable training, e.g.shot firer’s course. Contact EPC-UK for availability of courses.


OTHER INFORMATION

Changes


1 06/02/2017 New issue based on manufacturer’s SDS

Non - Electric Detonators

Minexplo supplies non-electric detonator systems for initiation of surface blasts & long delay tunnel detonators for underground and demolition blasting.

The surface blasting system consists of a set of detonators with three available in-hole delay times of 450ms, 475ms and 500ms together with a range of delayed action surface connectors.

By using combinations of downhole detonators and the various surface delayed action connectors, the simplest to most complicated blast designs can be achieved.

The tunnel series of non-electric detonators has delay intervals suitable for use in tunnelling, underground mining and demolition applications. There are up to 26 delay numbers in the tunnel range from 0 to 7000 milliseconds.

9

Non - Electric Detonators DataEuronel 2


Product Type Non-electric Detonators

Product Name

Detonator Shell

Length (mm)

Diameter (mm)

Base Charge

Net Explosive Quantity (g)

Strength

Lead Colour

Tensile Strength (N)


Shelf Life

UN Number

UN Descritption


CE Mark ENB/D/152/16

Aluminium

7.5

PETN

>196

-20/+50

2 years

UN0360

1.1B

Detonator Assemblies, Non-Electric for Blasting

Euronel 2 In-Hole

89 - 93

0.8

No.8D

Yellow

51.5

0.24

No.4D

Red

Euronel 2 Connector

Nominal Delay in ms

Colour of block

0 Green

17 Yellow

25 Red

33 Purple

42 White

67 Blue

109 Grey

Surface connectors are available in time delays as follows:


Product Type Non-electric Detonators

Product Name

Detonator Shell

Length (mm)

Diameter (mm)

Base Charge

Net Explosive Quantity (g)

Strength

Lead Colour

Tensile Strength


Shelf Life

UN Number

UN Descritption


CE Mark ENB/D/152/16

Aluminium

7.5

PETN

Yellow

>196N

-20/+50

2 years

UN0360

1.1B

Detonator Assemblies, Non-Electric for Blasting

Euronel 2 Tunnel

91-95

0.8

No.8D

83 - 99

0.8 / 0.24

No. 8D / No. 4D

Euronel 2 Duo


Tube length in metres

1.1B Packaging

Qty/per bag Qty/box

4.8 10 100

6.0 10 80

7.8 10 70

9.0 10 60

Connector Detonators

Euronel 2 Range & Packaging


1.1B Packaging

Qty/per bag Qty/box

6.0 10 100

7.8 10 100

10.2 10 70

12.0 10 50

15.0 10 50

18.0 5 40

21.0 5 30

24.0 5 25

27.0 5 25

In-hole Detonators


1.1B Packaging

Qty/per bag Qty/box

30 4 20

50 2 10

100 1 5

Starter lines


1.1B Packaging

Qty/per bag Qty/box

4.8 10 100

6.0 10 100

7.8 10 100

10.2 10 70

12 10 70

Tunnel Detonators


1.1B Packaging

Qty/per bag Qty/box

4.8 10 90

6.0 10 80

7.8 10 70

9.0 10 50

10.2 10 50

12.0 10 50

Duo Detonators

Other lead lengths can be supplied by special request.



Product Identifier Euronel 2 non-electric detonator assemblies:Euronel 2 connector.Euronel 2 starter line.Euronel 2 in-hole detonators.Euronel 2 Tunnel detonators.Euronel 2 Duo detonators.

Use of the Product Connector – A surface initiation system for explosive charges, particularly in open cast, open pit mining, quarry blasting and underground mining applications underground mining applications.Starter line – A connector detonator with a longer length of shock-tubing to act as a lead-in line.In-Hole – A down-hole initiation system for explosive charges, particularly in open cast, open pit mining and quarry blasting.Tunnel – An in-hole initiation system for explosive charges, particularly in development tunnelling in underground mining.Duo – A combined down-hole and surface initiation system for explosive charges used in open pit/cast mining, quarry blasting and underground applications.

Euronel 2 detonators are not suitable for use in underground mines where there is a risk of methane gas and/or coal dust explosion.

Manufacturer / Supplier EPC-UK EXPLOSIVES / MINING EXPLOSIVES LTD





01773 832253


Classification According to EC Regulation 1272/2008

Explosive Class 1.1B.


H201 Mass explosion HazardP210 Keep away from heat/sparks/open flames/hot surfaces. – No smoking.P250 Do not subject to shock impact or friction.P280 Wear protective gloves/protective/clothing/eye protection.P234 Keep in original containerP370/P380/P372 Explosion risk in case of fire: evacuate area.P373 DO NOT fight fire when fire reaches explosives.P401 Store in accordance with the Explosives Regulations 2014.P501 Dispose of contents/container to in accordance with local/regional/national/international regulations.

Danger

Other Hazards The detonator assemblies may explode if exposed to fire, releasing toxic gas, including CO, NOx and lead vapours. Fire may also occur as a secondary effect of explosion.

Label elements




Dangerous substance

Pentaerythritol tetranitrate (PETN)

Quantity Connector and starter line: 0.14g / assembly.In-hole and tunnel: 0.7g / assemblyDuo detonator: 0.84g/ assembly

EINECS / EC Number

201-084-3

CAS Number 78-11-5

CLP Classification

Unst. Expl: H200

DANGER

ECHA Registration

05-2114281184-50-0000EURENCO Bofors AB, SWEDEN

Dangerous substance

Lead (II) Azide

Quantity Duo 160-200 mg / assemblyOthers 80-100 mg / assembly

EINECS / EC Number

236-542-1

CAS Number 13424-46-9

CLP Classification

Unst. Expl.: H200Repr.1A: H360DfAcute Tox. 4: H332Acute Tox. 4: H302STOT RE 2: H373 Aquatic Acute 1: H400Aquatic Chronic 1: H410

DANGER

ECHA Registration

05-2114121064-67-0000


Dangerous substance

Lead (II) (IV) Oxide

Quantity

EINECS / EC Number

215-235-6


CLP Classification

Repr. 1A: H360DfAcute Tox. 4: H302Acute Tox. 4: H332STOT RE 2: H373Aquatic Acute 1: H400Aquatic Chronic 1: H410

DANGER

ECHA Registration

05-2117100997-39-0000

Dangerous substance

HMX (Octogen; Octahydro-1,3,5,7-tetranitro-1,3,5,7-tetrazocine)

Quantity Contains ca 10-20mg of HMX per metre of shock tube

EINECS / EC Number

220-260-0


CLP Classification

Expl. 1.1; H201Acute Tox. 4:H302Acute Tox. 3: H311

DANGER

ECHA Registration


FIRST AID MEASURES

General Components are contained in a shell: User cannot be in direct contact during normal handling.In case of accidental initiation when nearby:- For any injury due to splinters proceed with first- aid treatment and evacuate to hospital.- Have ears and hearing checked (hearing test) by a specialist.

First Aid – Eyes In the event of substances contained within the article coming in contact with the eye wash with water.

First Aid – Skin In the event of substances contained within the article coming in contact with the skin wash with soap and water.

First Aid – Ingestion In the event of substances contained within the article, seek medical advice.

First Aid – Inhalation Pre-use: Hazardous materials are encapsulated, no exposure during normal handling is therefore expected. Post use: Toxic gases are released. Minimal exposure is expected as quantities of hazardous components used are small, and operator is at a safe distance.

Eye contact Not applicable.

Skin contact Not applicable.

Inhalation or ingestion If affected by fumes, remove to fresh air.

If affected by fumes or feel unwell seek medical attention.





Extinguishing Media Do not fight the fire if it has reached, or if it will reach, the detonator assemblies.

If fire may be prevented from reaching the explosives, water, carbon dioxide, extinguishing powders or alcohol resistant foams may be used. Don’t use water if electrical equipment is involved.


Product will detonate in a fire. May produce toxic gasses containing carbon monoxide and oxides of nitrogen.

Advice for Firefighters Evacuate to a safe distance.Wear positive pressure self-contained breathing apparatus (SCBA) and full turnout gear. Fire-fighters’ protective clothing will provide limited protection DO NOT FIGHT FIRE WHEN IT REACHES MATERIAL. Withdraw from fire and let it burn. Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. First move people out of line of the sight of the scene away from windows.



Evacuate surrounding areas. Prevent access to the area by unauthorised persons. Extinguish any sources of ignition. Protect from any shock or impact.

If detonators have been damaged, particularly if they have been broken open, do not touch, seek specialist advice.

Environmental Precautions Prevent the product from entering sewage systems and surface waters.


Undamaged detonators may be carefully picked up and put in packaging similar to the original. Remove any loose grit before packing.

Reference to other sections Refer to Disposal Considerations for disposal information.




Take necessary precaution measures when handling the product: don’t smoke, drink or eat in work areas. If ingested, seek medical advice immediately and show the container or the label.

Keep away from heat / naked flames. Keep away from sources of ignition. Avoid mechanical shocks. Wear suitable protective clothing.

The control and handling of detonators must be carried out by authorised staff

Conditions for safe storage , including any incompatibilities

Store in a segregated, approved and labelled area, complying with the legal requirements. Keep container in a cool, well ventilated area. Keep container tightly closed and sealed until ready for use. Avoid all possible sources of ignition (spark or flame). Earth all stores containing detonators. Do not store with hazardous goods of classes other than Class 1, nor with incompatible goods of Class 1.Storage temperatures: from 0°C to + 45°C. Under these conditions storage life up to 12 months. See Regulatory Information for specific regulations.

Specific end use(s) Not applicable.


Control Parameter The hazardous substances are contained within the detonator. There is no exposure during normal handling.

Exposure controls Not applicable.


Appearance/ colour Explosive article, consisting of an aluminium shell containing initiating and secondary explosives, crimped to a length of shock tube. The shock tube is red (for connector detonators) or yellow (other detonators).

Odour None.


pH Not applicable.


Not applicable. Solid item, will detonate if heated sufficiently.


Not applicable.

Flash point Not applicable, explosive article.


Flammability Not applicable.


Not applicable.



Relative density Not applicable.

Solubility(ies) Casing/tubing not soluble in water. Casing may be dissolved by acids / strong bases.


Not applicable.

Auto-ignition temperature Auto-ignition temperature of PETN is 190°C. Heated detonators may explode at significantly lower temperatures.

Decomposition temperature

Viscosity Not applicable, solid.

Explosive properties Explosives article, detonation possible by open flames, sparks, static discharge or shocks.





Reactivity Explosive article, detonation possible by flames, sparks, static discharge, impact.

Chemical Stability Stable under normal handling conditions.


Explodes if initiated.

Conditions to avoid Avoid any exposure to high temperature, to impact, friction and electrostatic discharges or stray currents.



Carbon oxides (CO, CO2) nitrogen oxides (NO, NO2), Lead fume.


Acute toxicity PETN: Acute Toxicity 4;Lead Azide and Lead Oxide: Acute Toxicity 4 May be harmful if swallowed, May be harmful if inhaled.HMX Acute Toxicity 4; May be harmful if swallowed, Acute Toxicity 3. Toxic in contact with the skin.

Skin corrosion / irritation PETN: Not irritating; Lead Azide: study not technically feasible. Lead Oxide: non-irritant.


PETN no data: Lead Azide: study not technically feasible; Lead Oxide non-irritant.


PETN not skin sensitising; Lead Azide: study not technically feasible. Lead oxide is not a skin sensitiser.

Germ Cell Mutagenicity Lead Azide and Lead Oxide: Repr 1A May damage fertility or the unborn child.

Carcinogenicity

Information on toxicological effectsThe hazardous substances are contained within the article and there is no exposure under normal circumstances;Toxicological information on the contents of the article is as follows.


Reproduction toxicity Lead Azide may damage the unborn child suspected damaging to fertility.

STOT – single exposure Lead Azide: No data.

STOT – repeated exposure Lead Azide and Lead Oxide: STOT RE 2. May cause damage to organs through prolonged or repeated exposure.



Toxicity Not Applicable.


Not Applicable.

Bioaccumulation potential Not Applicable.

Mobility in soil Not Applicable.


Not Applicable.

Other Adverse Effects Negligible impact of the fumes on the environment following the initiation of the detonator.



Product and Packaging disposal

Waste must be disposed of in accordance with national and local control regulations. Disposal of this product should only be done by trained personnel.

The HSE and the CBI EIG have issued “Guidance for the Safe Management of the Disposal of Explosives”.

Preferred methods of disposal include destruction by detonation for the detonators and burning of the packaging. A thorough examination of the packaging before burning is required to ensure no detonators are present.

Detonators must not be disposed of by landfill or via the sewage disposal system.



UN Number UN0360.

UN Proper Shipping Name DETONATOR ASSEMBIES, NON ELECTRIC, for blasting.

Transport Hazard Classes 1.1B

Packing Group Not applicable.

Environmental Hazards Detonator assemblies are not an environmentally hazardous substance and they are not classed as a marine pollutant in the IMDG code.

Special Precautions for User User must comply with the requirements for the control and traceability of explosives.

Transport in bulk, etc. Not applicable.

OTHER INFORMATION


UK Legislation Explosive Regulations 2014 (see also guidance to the regulations)Carriage of Dangerous Goods Regs 2009, as amended – implementing ADRClassification (Hazard Information and Packaging for Supply) Regs 2009, as amended.Control of Substances Hazardous to Health Regs 2002, as amendedControl of Lead at work RegulationsControl of Major Accident Hazard Regulations 2015.

EC Regulations Registration Evaluation, Authorisation and Restriction of Chemicals Regulations 2006, as amendedClassification Labelling and Packaging Regulations 2008, as amended


MSDS first issued: 17/06/15

ChangesIssue Issue Date Changes1 17/06/15 New Issue

OTHER INFORMATION

Abbreviations and acronyms Expl. 1.1 explosive material, subclass 1.1. Unst. Expl. unstable explosive material. Repro.Cat.3 fertility hazard, category 3. Repr.1A fertility hazard, category 1A. Acute Tox. 4 acute toxicity, cat. 4.STOT RE 2 specific target organ toxicity repeated exposure, cat. 2.Aquatic Acute 1 acute toxicity for aquatic environment, cat.1.Aquatic Chronic 1 chronic toxicity for aquatic environment, cat.1.IMDG International Maritime Dangerous Goods.ADR European Agreement concerning the International

Carriage of Dangerous Goods by Road.

ReferencesGuidance L150: Explosive Regulation 2014, Safety provisions.Guidance L151: Explosive Regulation 2014, Security provisions.

Evaluation method for mixturesRelevant hazard Statements and Precautionary statementsH200 Unstable explosive. H201 Mass explosion Hazard.H360Df May damage fertility or the unborn child.H302 May be harmful if swallowed.H311 Toxic in contact with skin.H332 Harmful if inhaled.H373 May cause damage to organs through prolonged or repeated exposure.H400 Very toxic to aquatic life.H410 Very toxic to aquatic life with long lasting effects.P210 Keep away from heat/sparks/open flames/hot surfaces. – No smoking.P250 Do not subject to shock impact or friction.P280 Wear protective gloves/protective clothing/eye protection.P234 Keep in original container.P370/P380/P372 Explosion risk in case of fire: evacuate area.P373 DO NOT fight fire when fire reaches explosives.P401 Store in accordance with the Explosives Regulations 2014P501 Dispose of contents/container to in accordance with local/ regional/national/international regulations.

Advice on training Training for Shotfirers and Explosive Supervisors is available. Please contact the EPC-UK Explosives Engineering Department.


Emulsion Primers

EPC-UK supply Explus TSR primers in 50mm and 35mm diameter cartridges. This explosive is suitable for use as a primer for initiating Ammonium Nitrate based explosives in shallow large diameter holes as experienced in opencast coal sites.

Packaged emulsions contain water in oil compositions, i.e. where the water solution of oxidisers is dispersed evenly between the oil phase. A surfactant (emulsifier) is used to ensure that the oxidiser remains dispersed in the fuel. A density reducing agent is added to make the product detonator sensitive.

As a result of the intimate blend of the oxidiser and fuel and the fine particle size, emulsions have a relatively high velocity of detonation in comparison to other products. These products have excellent water resistant properties.

10

Emulsion Primers DataExplus TSR


Product Type Emulsion Primers

Product Name Explus TSR



Density (g/ml) 1.27

VOD (m/s) 5500





Shelf Life 1 year

UN Number UN0241



CE Mark 0080.EXP.08.0020

PACKAGING DETAILS

Product Packaging Plastic Laminate

Cartridge Diameter (mm) 50

Cartridge Length (mm) 250

Cartridge Weight (kg) 0.5

Cartridges/box (kg) 50

Emulsion Primers Explus TSR Data


Product Identifier Cartridged Emulsion Explosives:Explus TSR

Use of the Product Explosive mainly used in quarries, mines and public construction work.






01773 832253



Classification of Mixture Expl. 1.1 H201 Explosive, mass explosion hazard.



Signal Word Danger.

Hazard Statement Warning H201 Explosive, mass explosion hazard. H319 Causes serious eye irritation.

Precautionary Statements - Prevention

P210 Keep away from heat/sparks/open flames/hot surfaces. No smoking.P280 Wear protective gloves/protective clothing/eye protection/face protection.

Label elements


Intervention P372 Explosion risk in case of fireP305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses if present and easy to do – continue rinsing.

Storage P401 Store in a safe and suitable place in accordance with legal requirements.

Disposal P501 Dispose of contents/container. Dispose of the product/container in accordance with local regulations on the disposal of explosive and contaminated waste.

Other Hazards During transport, storage and handling: danger of explosion when exposed to extreme heat, an important shock, a high friction and severe electric shock. Immediate propagation of detonation in the whole mass and possibility of transmission to other neighbouring explosives.Detonation in case of excessive heating during a combustion in heap.Projection of solids present next to the exploding charge.

Name Ammonium nitrate Sodium nitrate Sodium perchlorate

CAS-Nr. 6484-52-2 7631-99-4 7601-89-0

EC-Nr. 229-347-8 231-554-3 231-511-9

Registration-Nr. 01-2119490981-27 01-2119488221-41 01-2119540521-50

Concentration 30-70 5-20 <10

CLP Classification Eye Irrit. 2 H319Ox. Liq 3 H272

Eye Irrit. 2 H319Ox. Liq 2 H272

Ox.sol.1 H271; Acute tox.4 H302Eye Irrit. 2 H319STOT RE 2H373

Specific concentration limits

- - -


Mixtures


FIRST AID MEASURES

General Untrained and uninstructed persons shall not handle this material nor its packaging. Call a doctor/physician if you feel unwell.


First Aid – Skin Wash the affected areas thoroughly with soap and plenty of water or decontaminate with acetone or 10% of sodium sulfate. If skin irritation persists: Get medical advice/attention.




Skin contact A skin irritation can occur when there is a prolonged contact with the product if leaked.

Inhalation Poisoning by inhalation of fumes produced during combustion or detonation.






Extinguishing Media Appropriate: Large quantities of water must be used to cool and protect exposed material. A versatile powder can be used in case of aluminum combustion.

Inappropriate: not determined.- DO NOT ATTEMPT TO EXTINGUISH THE BURNING EXPLOSIVES! RISK OF EXPLOSION.



If the product is enveloped in flames, there is an immediate risk of explosion, so evacuate as quickly as possible, to at least 300 metres from the flames, and if possible seek shelter behind a natural or artificial barrier. Product combustion generates toxic fumes and gases, mainly carbon monoxide and nitrous fumes.

Advice for Firefighters If the flames do not involve the product directly, extinguish them using the media recommended for the specific type of fire. Move the product away from the fire if possible.

If the fire directly involves the product, evacuate the area immediately to an upwind position to avoid breathing the fumes. There is an explosion risk in case of fire so DO NOT fight fire when it reaches explosives. Only if possible, fight the fire from a protected position, wearing self-contained breathing apparatus and using large quantities of water.




Eliminate all potential sources of ignition and avoid any action that could cause an impact, friction, sparking or a sudden rise in temperature. Keep away from other flammable materials. Wash hands in case of contact with the product.

Environmental Precautions Do not let the product get into the soil and water. Do not dispose of with normal waste.


Pick up cartridges using rubber gloves, remove any contamination and put the waste in plastic bags without mixing with other material. After closing bags by adhesive or plastic ligation, place them in cardboard boxes ready for disposal.




Handle with care, bearing in mind the potential hazards.Earth all electrical equipment present and any conductive item.

Keep the product well away from heat, direct sunlight and other sources of ignition, including combustible materials. Do not smoke near the product.

When handling the product, avoid ingesting or inhaling any solid particles that are formed. Do not eat, drink or smoke when handling the product. Wear disposable plastic, latex or rubber gloves to prevent contact with the skin.

Wash your hands thoroughly after handling the product.

Remove contaminated clothes and PPE before entering areas where food and drink are consumed.



In general storage must be licensed as required by the Explosives regulations Do not exceed the authorized amounts for the store. Do not store with other dangerous goodsOnly store with other compatible explosives.Store in a well-ventilated area where the average temperature does not exceed 35 to 40°C. Until A TEMPERATURE OF 65°C, the storage is safe; the product can only harden. Do not smoke or manipulate fire in the storage area.Storage rooms shall comply with the fire-fighting and rescue and controlled access requirements. Store in closed packages in cool dry place. Keep locked. Access allowed only to experts.

Storage limits for which COMAH applies for Explosives: 10 tonnes Lower Tier 50 tonnes Upper Tier

Specific end use(s) The product is supplied for use, testing and analysis by qualified personnel who have been fully trained to handle explosives.Do not use beyond the shelf life. Do not cut cartridges.


Control Parameter None.



Personal protective equipmentHand protection

Wear plastic, rubber or latex gloves. Disposable gloves are recommended to minimize cross-contamination with the explosive.

Eye protection It is strongly recommended to use protection glasses to avoid potential projections in the eyes in case of the cartridge rupture.

Exposure controls



Body protection The entire skin must be covered by suitable clothing.Work clothes must be antistatic, made of cotton for instance, and flame retardant.


Industrial hygiene Do not eat, drink or smoke when using this product. Wash thoroughly after handling. Avoid contact with eyes, skin and clothing. Wash contaminated clothes before reuse.



Not available.


Appearance/ colour White/gray plastic emulsion, Immediate colour will be the colour of the plastic film of the cartridge.

Odour No odour.


pH 5.8 (10% dilution).


Not applicable.


Not applicable.





Not available.



Relative Density 1.13-1.35



Solubility(ies) Water: insolubleOther: not available.


Not available.



Viscosity >3,000,000 cP

Explosive properties Impact sensitivity: no reaction at 50 J (Dried Explosive: reaction at 28.6 J) Sensitivity to friction: no reaction to 353 N (Dried Explosive: no response to 353 N)





Reactivity Sensitivity to shock and friction is increased in the presence of hard material (dust, sand …) Explosion risk in case of strong shock, or violent friction on the material to the confined state.Danger of explosion due to a sudden increase in temperature (fire).Risk of an instant transmission of the explosion to all of the explosive mass. Sensitivity of the dried product is higher than the original product’s sensitivity.

Chemical Stability Stable under the recommended storage and use conditions and at moderately elevated temperatures and pressures. The recommended shelf life is one year. Beyond one year, the product is not more dangerous, but its reliability is no longer guaranteed. Field climate recommended: -10°C to + 60°C.






Incompatible materials Avoid contact with alkalis, amines, strong acids, alkali metals, copper, and zinc. Do not store with products of the class 1.1B.


The fumes from combustion or explosion contain COx and NOx.


Acute toxicity Ammonium NitrateLD50 (oral, rat) = 2950 mg/KgLD50 (skin, rat) > 5.000 mg/KgSodium nitrateLD50 (oral, rat) = 3430 mg/KgLD50 (Skin, rat) > 5000 mg/Kg

Skin corrosion / irritation A skin irritation can occur.


Ammonium nitrate is irritating to rabbit eyes. The product can induce a severe eye irritation.


Inhalation and continuous skin contact may lead to sensitisation.





STOT – repeated exposure Not available.


Respiratory irritation The explosive irritates the airways and can cause sneezing and coughing. Large quantities can cause headache, lack of appetite, malaise, vomiting, dizziness, fluctuations in blood pressure and fainting.


Other information


Toxicity

Aquatic toxicity of Sodium nitrate

Fish LC50 48h 447 mg/L

Daphnia CE50 48h 447 mg/L

Algae CE50 10j 1.700 mg/L

Aquatic toxicity of Ammonium nitrate

Oncorhynchus LC50 96h 7950 mg/L

Tschawytscha Daphnia

CE50 24h 8609 mg/L

Microorganism CE10 3h 180 mg/L


Not available.




Ammonium nitrate and sodium nitrate : not concerned by PBT nor vPvB.




The use of the emulsion does not produce any waste other than the cardboard boxes and the polyethylene bags that must be destroyed according to the appropriate regulations. Do not put waste in general waste or landfill; destroy in licensed facilities.Contaminated packaging with traces of explosives must be carefully reviewed to ensure they are empty and put flat. They can be burned on the place of use, if the property is authorized. See the CBI/EIG “Guidance for the Safe Management and Disposal of Explosives”




UN Number UN 0241.

UN Proper Shipping Name EXPLOSIVE, BLASTING, TYPE E.




Special Precautions for User As an explosive, the product is a high consequence dangerous good and adequate transport precautions must be taken for its security. Transport by air is forbidden under ICOA/IATA codes.


Not available.

Label






Abbreviations and acronymsADN/ADNR: Regulations concerning the transport of dangerous substances in barges on inland waterways. ADR/RID: European Agreement concerns the International Carriage of Dangerous Goods by Road/ Regulations concerning the international carriage of dangerous goods by rail. ANSI: American National Standards Institute.CAS No.: Chemical Abstract Service Number.CFR: Code of Federal Regulations.CLP: Classification, Labelling and Packaging. EC No.: European Commission Number. IATA: International Air Transport Associations. IMDG: International Maritime Dangerous Goods code.NFPA: National Fire Protection Association.PBT: Persistent, Bioaccumulative, Toxic.RCRA: The Resource Conservation and Recovery Act.UN No.: United Nations Number.UVCB: Substances of Unknown or Variable composition, Complex reaction products or Biological materials. vPvB: very Persistent and very Bioaccumulative.WHMIS: Workplace Hazardous Materials Information System.

ReferencesGuidance for the Safe Management and Disposal of Explosives, HSE/CBI-EIG, 2007.

Evaluation method for mixturesNot applicable.

Relevant hazard Statements and Precautionary statementsMeanings of Hazard Phrases H271 May cause fire or explosion; strong oxidizer.H272 May intensify fire; oxidizer.H302 Harmful if swallowed.H373 May cause damage to organs through prolonged or repeated exposure.

Advice on training Unavailable.


OTHER INFORMATION


Changes


10 26/02/2017 Completely updated. Includes Exem 55 and 100 as well as Explus TSR

AuthorisedNitroglycerineExplosives

EPC-UK supply a nitroglycerine based explosive in a range of diameters suitable for use in the civil engineering, demolition, tunnelling and quarrying industries. The product currently supplied is Perunit E.

Nitroglycerine explosives generally have good water resistant characteristics, depending on their application and exposure to water.

Reliable initiation can be provided with standard detonating cord, electric, non-electric or electronic detonators.

As a group, the nitroglycerine explosives are one of the most sensitive commercial products used today (excluding detonators). 11

Authorised Nitroglycerine DataPerunit E


Product Type Authorised Nitroglycerine

Product Name Perunit E



Density (g/ml) 1.30

VOD (m/s) 6000





Shelf Life 9 months

UN Number UN0081

UN Description Explosives Blasting, Type A


1.1D

CE Mark 0589.EXP.0556/07

PACKAGING DETAILS

Product Packaging Waxed Paper




Cartridges/box kg)

28

220

0.2

125

38

320

0.5

78



Product Identifier Product name: PERUNIT E – underground explosive.

Use of the Product Explosive for blasting operations. Do not use for other purposes.






01773 832253


Classification According to EC Regulation (EC) 1272/2008

Expl. 1.1 H201 Acute Tox. 1 H310 Acute Tox. 2 H300+H330 Eye Irrit. 2 H319 STOT RE 2 H373 Aquatic Chronic 3 H412

According to EC Regulation 1272/2008 Hazard Pictogram

Signal Word Danger.

Hazard statement H201: Explosive, mass explosion hazard.

Other Hazards The product does not meet the criteria for PBT, vPvB.


Label elements

Regulation 1272/2008 stipulates in Annex 1, Art. 1.3.5 that explosives placed on the market with a view to obtaining an explosive or pyrotechnic effect can be labelled and packaged in accordance with the requirements for explosives only.


MixturesMixture of ammonium nitrate, ethyleneglycol dinitrate, glycerol trinitrate, monoethyleneglycol, nitrocellulose and other components not classified as dangerous.

Dangerous substance

Concentration range

EC Number

CAS Number

Classification

Ammonium Nitrate ca 60.0 229-347-8

6484-52-2

Ox. Sol. 3; H272 Eye Irrit. 2; H319

Ethyleneglycol dinitrate

ca 20.0 211-063-0

628-96-6

Unst. Expl.; H200 Acute Tox. 1, H310 Acute Tox. 2, H300+H330 STOT RE 2; H373

Glycerol trinitrate ca 10.0 200-240-8

55-63-0 Unst. Expl., H200 Acute Tox. 1, H310 Acute Tox. 2, H300+H330 STOT RE 2, H373 Aquatic Chronic 2, H411

Monoethyleneglycol ca 2.5 203-473-3

107-21-1 Acute Tox. 4; H302 STOT RE 2, H373

Nitrocellulose ca 1.2 9004-70-0

Expl. 1.1; H201

FIRST AID MEASURES

General In all cases keep the victim at physical and psychic rest and keep warm. Never give anything to an unconscious person. In heavy cases, always after contact with eyes and if swallowed, seek medical advice.

First Aid – Eyes Rinse with water for at least 15 minutes. Move to the physician, while continuing to rinse.



FIRST AID MEASURES

First Aid – Skin Remove contaminated clothing. Wash affected area with soap and water and use skin protective cream.

First Aid – Ingestion Rinse mouth with fresh water. Seek medical advice.

First Aid – Inhalation Break off the exposition. Move the victim to fresh air (not in the sun). If not breathing, give artificial respiration.


The mixture causes headaches, pain in abdomen, dizziness, nausea.


No data.


Extinguishing Media Suitable extinguishing media: water spray. Adapt extinguishing media to the kind of fire.

Unsuitable extinguishing media: powders.


In case of fire there is an extreme danger of explosion. Try to prevent the spread of fire. If the fire is going to reach the product do not attempt to extinguish. Warn surroundings of danger of explosion and evacuate immediately to a safe distance. In case of fire, toxic and irritant gases are formed.

Advice for Firefighters Self-contained breathing apparatus and protective clothing conforming to EN 469. Do not approach a fire which has reached or is near the explosives.



Avoid the free movement of persons in contaminated area. Wear personal protective equipment. Avoid spreading of the product. Avoid contact of spilled material with open fire, electric sparks and aggressive chemical compounds.

Environmental Precautions Avoid discharge to surface- and groundwater. If it is not possible, inform police and fire-fighters.


Sweep up spilled material and place in impermeable packages. Flush spill area with plenty of water. Dispose by explosion only in a place approved for disposal of explosives in accordance with national regulations relating to explosives.

Reference to other sections For more see Disposal Considerations and Exposure Control/Personal Protection.



Handle in accordance with regulations relating to explosives. Keep away from open flame, heat, do not eat, drink or smoke. Maximum care should be taken during handling (lifting, transferring, opening of containers) and transportation. Keep away from combustible material. Take precautionary measures against static discharges. Observe personal hygiene measures. Wear suitable protective clothing and gloves. Wash thoroughly with soap and water after handling. Ensure drinking water is available for first-aid.


Store according to national regulations relating to explosives.

Maximum relative humidity 75 %. Recommended storage temperature -10 to +25 °C.

Specific end use(s) Blasting operations. Observe safety regulations for processing of explosives. To be used within 9 months after manufacturing.



Control Parameters Occupational exposure limit values:

Exposures to Glycerol trinitrate and Ethyleneglycol dinitrate should be kept as low as is reasonably practical and certainly to below 0.2 ppm.

Ammonium nitrate CAS 6484-52-2 DNEL

PNEC

Users Route of study

Effects Time of exposure

Value

Workers Inhalation Systemic effects

Long-term 37.6 mg/m3

Workers Dermal Systemic effects

Long-term 21.3 mg/kg/den

General population

Inhalation Systemic effects

Long-term 11.1 mg/m3

General population

Dermal Systemic effects


General population

Oral Systemic effects


Fresh water Marine water Intermittent releases STP

0.45 mg/l 0.045 mg/l 4.5 mg/l 18 mg/l

Sediment (fresh water)

Sediment (marine water)

Soil Secondary poisoning

Not available Not available Not available No potential

Glycerol trinitrate CAS 55-63-0 DNEL



Value


Long-term 0.5 mg/kg/day


Acute/short term

2.5 mg/kg/day

General population

Oral Systemic effects

Long-term 0.5 mg/kg/day


Glycerol trinitrate CAS 55-63-0

Ethyleneglycol CAS 107-21-1 DNEL

PNEC

PNEC



Value

Workers Inhalation Systemic effects

Long-term 35 mg/m3


Long-term 106 mg/kg/day

General population

Inhalation Systemic effects

Long-term 7 mg/m3

General population

Dermal Systemic effects

Long-term 53 mg/kg/den


0.0198 mg/l Not available 0.0198 mg/l Not available


10 mg/l l 1 mg/l 10 mg/l 199.5 mg/l



Soil Secondary poisoning

Not available Not available Not available No potential



Air Soil Secondary poisoning

37 mg/kg 3.7 mg/kg No potential

1.53 mg/kg No potential




Process enclosures, local exhaust, general ventilation.

Personal protective equipment

Protective clothing shall be selected specifically for the working place, depending on concentration and quantity of the hazardous substances handled. All used personal protective equipment should conform to directive 89/686/EEC. Eye and face protection - chemical goggles; Skin protection - protective gloves depending on operation conforming EN 374, protective clothing, boots, cap; Respiratory protection – In cases of fume discharge use respiratory protection mask with filter A2 conforming EN 133.


Avoid release to the environment. If it is impossible, substance should be removed safely from the place of leakage. In case of leakage of substance to air or water sources, soil or sewer system, inform relevant authorities about leakage.

Exposure controls


Appearance/ colour Plastic material of red colour.

Odour Characteristic odour of nitroesters.


pH Not available.


Not applicable.


Not applicable.

Flash point > 190 °C


Flammability Not applicable – explosive.


Not applicable.





Relative density Bulk density: 1.30 g/cm3

Solubility(ies) Insoluble in water.


Not available.

Auto-ignition temperature Not applicable – explosive.

Decomposition temperature Not applicable.


Explosive properties Expl. 1.1

Oxidising properties Not applicable – explosive.

Other information Impact sensitivity: min. 5 J. Lower sensitivity to friction, electric spark, high detonation initiation sensitivity. Soluble in acetone, ethyl acetate, partly soluble in benzene and toluene.


Reactivity Explosive.

Chemical Stability Stable under normal conditions.


Unknown.

Conditions to avoid Temperatures above 50°C, strong impact, friction, direct sunlight.

Incompatible materials Strong acids and alkalis.


Oxides of nitrogen and carbon.



Acute toxicity Fatal if swallowed (category 2), in contact with skin (category 1) or if inhaled (category 2). Ammonium nitrate LD50: 2950 mg.kg-1, oral, rat. Glycerol trinitrate LD50: 685 mg.kg–1, rat, oral. Glycerol trinitrate LD50: >9 mg.kg–1, rat, dermal.Ethyleneglycol dinitrate LD50: 616 mg.kg–1, rat, oral. Monoethyleneglycol LD50: 7.712 mg.kg–1, rat, oral. Monoethyleneglycol LD50: > 2.5 mg.l–1, rat, inhalation. Nitrocellulose LD50: >5000 mg.kg–1, rat, oral.

Skin corrosion / irritation Does not contain these substances (or less than classification limit).


Causes serious eye irritation. (Eye Irrit. 2; H319) Ammonium nitrate – irritating, rabbit, Hansen E.


Does not contain these substances (or less than classification limit).

Germ Cell Mutagenicity Does not contain these substances (or less than classification limit).

Carcinogenicity Does not contain these substances (or less than classification limit).

Reproduction toxicity Does not contain these substances (or less than classification limit).

STOT – single exposure Does not contain these substances (or less than classification limit).

STOT – repeated exposure May cause damage to organs through prolonged or repeated exposure. STOT RE 2; H373.

Aspiration hazard Does not contain these substances (or less than classification limit).


Likely routes of exposure

Through inhalation, skin exposure and ingestion.


ToxicityHarmful to aquatic life with long lasting effects.

Result Species Exposure

Ammonium nitrate LC50 Fish 447 mg.l-1 (48 h)

Glycerol trinitrate LC50 Fish 3.48 mg.l-1

Glycerol trinitrate LC50 Invertebrates 17.83 mg.l-1 (48 h)

Glycerol trinitrate EC50 Algae 1.15 mg.l-1 (96 h)

Ethyleneglycol dinitrate LC50 Fish 1.9 mg.l-1

Monoethyleneglycol LC50 Fish 72860 mg.l-1 (96 h)

Monoethyleneglycol EC50 Invertebrates 100 mg.l-1 (48 h)

Monoethyleneglycol EC50 Algae 6500 - 13000 mg.l-1 (96 h)

Persistence and Degradability Not established.

Bioaccumulation potential Not established.

Mobility in soil Solubility of ethyleneglycol dinitrate and glycerol trinitrate in water is relatively low (5 – 6.8 g/l and 1.4 g/l respectively). Nitrocellulose is practically insoluble in water.


Assessment was not carried out.

Other Adverse Effects Lack of data.


Waste treatment methods Product disposal: Sweep up spilled material carefully and place in impermeable packages. Flush spill area with plenty of water. Under the supervision of an expert, the product may be destroyed by detonation or by burning at an approved site. For more guidance see the HSE/CBI Explosives Industry Group publication: “Guidance for the Safe Management of the Disposal of Explosives”, January 2007.Container Disposal: The accepted method for disposing of the empty boxes is burning on site. Double check that the boxes are empty.

Waste codes / waste designations according to EWC

16 04 03 N Other waste explosives.



UN Number UN0081.

UN Proper Shipping Name EXPLOSIVE, BLASTING, TYPE A.

Transport Hazard Classes 1

Packing Group

Environmental Hazards No.

Special Precautions for User No.


Not applicable.

Other applicable information for ADR/RID Classification code: 1.1D Label: 1 for IMDG EmS F-B, S-Y for IATA Air transport is forbidden


UK Legislation Carriage of Dangerous Goods Regulations 2009, as amended – implementing ADRClassification (Hazard Information and Packaging for Supply) Regs 2009, as amended.Control of Substances Hazardous to Health regs 2002, as amendedControl of Major Accident Hazard Regulations 2015.



REGULATORY INFORMATION Continued

EU Regulations Regulation (EC) No 1907/2006 concerning the Registration, Evaluation, Authorisation and Restriction of Chemicals (REACH), in the wording of later regulations Regulation (EC) No 1272/2008 on classification, labelling and packaging of substances and mixtures (CLP), in the wording of later regulations. Dangerous Substances Directive 67/548/EHS. Dangerous Preparations Directive 1999/45/ES. European Waste Catalogue (EWC).


Assessment was not carried out.


CAS Chemical Abstracts Service.

EN European standard.

EWC The European Waste Catalogue.

CLP Regulation No. 1272/2008/EC.

REACH Regulation No. 1907/2006/EC.

PBT Persistent, bioaccumulative and toxic.

vPvB very persistent and very bioaccumulative.

ADR The European Agreement concerning the International Carriage of Dangerous Goods by Road.

RID Regulations concerning the International Transport of Dangerous Goods by Rail.

IMDG The International Maritime Dangerous Goods. IATA The International Air Transport Association.

OTHER INFORMATION

MSDS first issued:

Changes


2 23/02/17 Completely rewritten to include latest supplier’s information


Abbreviations and acronymsAcute Tox. 1 Acute toxicity, Category 1. Acute Tox. 2 Acute toxicity, Category 2. Acute Tox. 4 Acute toxicity, Category 4. Aquatic Chronic 2 Hazardous to the aquatic environment chronic, Category 2. Aquatic Chronic 3 Hazardous to the aquatic environment chronic, Category 3. Expl. 1.1 Explosive, Division 1.1. Eye Irrit. 2 Serious eye damage/eye irritation, Category 2. Ox. Sol. 3 Oxidising solid, Category 3. STOT RE 2 Specific target organ toxicity — repeated exposure, Category 2.

Relevant Hazard Statements and Precautionary statementsUnst. Expl. Unstable Explosive. H200 Unstable explosives. H201 Explosive; mass explosion hazard. H272 May intensify fire; oxidiser. H302 Harmful if swallowed. H310 Fatal in contact with skin. H319 Causes serious eye irritation. H373 May cause damage to organs. H300 + H330 Fatal if swallowed or if inhaled H411 Toxic to aquatic life with long lasting effects.

Advice on trainingHandling of this product should only be allowed by qualified persons.



Packaged Explosives

EXEM emulsion cartridges manufactured by EPC Groupe in Europe are water in oil emulsions, that is, oxidiser salts dispersed as microscopically fine droplets, surrounded by a continuous fuel phase.

The emulsion is stabilised against liquid separation by an emulsifier (or surfactant). A density modifying agent is added to provide sensitivity. Using the groupes advanced Emulsion technology Exem is suitable for a wide range of applications across surface mining and quarrying operations. The product provides the optimum combination of safety, efficiency reliability and consistency and is available in a range of cartridge sizes.

Key Features;

• High water resistance• High Velocity of Detonation• Good oxygen balance with low post blast fumes• Good handling characteristics• Available in two compositions (Exem 55 & Exem 100)

EPC-UK recommends the use of a booster for safe and efficient priming when firing these compositions.

12

Packaged Explosives DataExem


Product Type Packaged Emulsion

Product Name Exem 55 Emulsion



Density (g/ml) 1.21

VOD (m/s) 5500



Fume Characteristics Excellent

Detonator Sensitive Yes*

Temperature Range (use) °C - 10/60

Shelf Life 1 year

UN Number UN0241



CE Mark 0080.EXP.10.0020

PACKAGING DETAILS

Product Packaging Plastic laminate




Cartridges/box

* For safe and efficient priming a 410g booster is recommended

80

485

2.8

9

90

460

3.15

8

100

480

4.17

6


* For safe and efficient priming a 410g booster is recommended


Product Type Packaged Emulsion

Product Name Exem 100 Emulsion



Density (g/ml) 1.27

VOD (m/s) 5500



Fume Characteristics Excellent

Detonator Sensitive Yes*

Temperature Range (use) °C - 10/60

Shelf Life 1 year

UN Number UN0241



CE Mark 0080.EXP.10.0018

PACKAGING DETAILS

Product Packaging Plastic laminate




Cartridges/box

80

470

2.8

9

90

450

3.15

8

100

470

4.17

6


Product Identifier Cartridged Emulsion Explosives:Exem 55, Exem 100.

Use of the Product Explosive mainly used in quarries, mines and public construction work.






01773 832253



Classification of Mixture Expl. 1.1 H201: Explosive, mass explosion hazard.



Signal Word Danger.

Hazard Statement Warning H201 Explosive, mass explosion hazard. H319 Causes serious eye irritation.

Precautionary Statements - Prevention

P210 Keep away from heat/sparks/open flames/hot surfaces. No smoking.P280 Wear protective gloves/protective clothing/eye protection/face protection.

Label elements



Intervention P372 Explosion risk in case of fireP305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses if present and easy to do – continue rinsing.

Storage P401 Store in a safe and suitable place in accordance with legal requirements.

Disposal P501 Dispose of contents/container Dispose of the product/container in accordance with local regulations on the disposal of explosive and contaminated waste.

Other Hazards During transport, storage and handling: danger of explosion when exposed to extreme heat, an important shock, a high friction and severe electric shock. Immediate propagation of detonation in the whole mass and possibility of transmission to other neighbouring explosives.Detonation in case of excessive heating during a combustion in heap.Projection of solids present next to the exploding charge.

Name Ammonium nitrate Sodium nitrate Sodium perchlorate

CAS-Nr. 6484-52-2 7631-99-4 7601-89-0

EC-Nr. 229-347-8 231-554-3 231-511-9

Registration-Nr. 01-2119490981-27 01-2119488221-41 01-2119540521-50

Concentration 30-70 5-20 <10

CLP Classification Eye Irrit. 2 H319Ox. Liq 3 H272

Eye Irrit. 2 H319Ox. Liq 2 H272

Ox.sol.1 H271; Acute tox.4 H302Eye Irrit. 2 H319STOT RE 2H373

Specific concentration limits

- - -


Mixtures

FIRST AID MEASURES

General Untrained and uninstructed persons shall not handle this material nor its packaging. Call a doctor/physician if you feel unwell.


First Aid – Skin Wash the affected areas thoroughly with soap and plenty of water or decontaminate with acetone or 10% of sodium sulfate. If skin irritation persists: Get medical advice/attention.




Skin contact A skin irritation can occur when there is a prolonged contact with the product if leaked.

Inhalation Poisoning by inhalation of fumes produced during combustion or detonation.







Extinguishing Media Appropriate: Large quantities of water must be used to cool and protect exposed material. A versatile powder can be used in case of aluminum combustion.

Inappropriate: not determined.- DO NOT ATTEMPT TO EXTINGUISH THE BURNING EXPLOSIVES! RISK OF EXPLOSION.



If the product is enveloped in flames, there is an immediate risk of explosion, so evacuate as quickly as possible, to at least 300 metres from the flames, and if possible seek shelter behind a natural or artificial barrier. Product combustion generates toxic fumes and gases, mainly carbon monoxide and nitrous fumes.

Advice for Firefighters If the flames do not involve the product directly, extinguish them using the media recommended for the specific type of fire. Move the product away from the fire if possible.

If the fire directly involves the product, evacuate the area immediately to an upwind position to avoid breathing the fumes. There is an explosion risk in case of fire so DO NOT fight fire when it reaches explosives. Only if possible, fight the fire from a protected position, wearing self-contained breathing apparatus and using large quantities of water.



Eliminate all potential sources of ignition and avoid any action that could cause an impact, friction, sparking or a sudden rise in temperature. Keep away from other flammable materials. Wash hands in case of contact with the product.

Environmental Precautions Do not let the product get into the soil and water. Do not dispose of with normal waste.


Pick up cartridges using rubber gloves, remove any contamination and put the waste in plastic bags without mixing with other material. After closing bags by adhesive or plastic ligation, place them in cardboard boxes ready for disposal.




Handle with care, bearing in mind the potential hazards.Earth all electrical equipment present and any conductive item.

Keep the product well away from heat, direct sunlight and other sources of ignition, including combustible materials. Do not smoke near the product.

When handling the product, avoid ingesting or inhaling any solid particles that are formed. Do not eat, drink or smoke when handling the product. Wear disposable plastic, latex or rubber gloves to prevent contact with the skin.

Wash your hands thoroughly after handling the product.

Remove contaminated clothes and PPE before entering areas where food and drink are consumed.




In general storage must be licensed as required by the Explosives regulations Do not exceed the authorized amounts for the store. Do not store with other dangerous goodsOnly store with other compatible explosives.Store in a well-ventilated area where the average temperature does not exceed 35 to 40°C. Until A TEMPERATURE OF 65°C, the storage is safe; the product can only harden. Do not smoke or manipulate fire in the storage area.Storage rooms shall comply with the fire-fighting and rescue and controlled access requirements. Store in closed packages in cool dry place. Keep locked. Access allowed only to experts.

Storage limits for which COMAH applies for Explosives: 10 tonnes Lower Tier; 50 tonnes Upper Tier

Specific end use(s) The product is supplied for use, testing and analysis by qualified personnel who have been fully trained to handle explosives.Do not use beyond the shelf life. Do not cut cartridges.


Control Parameter None.



Personal protective equipmentHand protection

Wear plastic, rubber or latex gloves. Disposable gloves are recommended to minimize cross-contamination with the explosive.

Eye protection It is strongly recommended to use protection glasses to avoid potential projections in the eyes in case of the cartridge rupture.

Exposure controls


Body protection The entire skin must be covered by suitable clothing.Work clothes must be antistatic, made of cotton for instance, and flame retardant.


Industrial hygiene Do not eat, drink or smoke when using this product. Wash thoroughly after handling. Avoid contact with eyes, skin and clothing. Wash contaminated clothes before reuse.



Not available.


Appearance/ colour White/gray plastic emulsion, Immediate colour will be the colour of the plastic film of the cartridge.

Odour No odour.


pH 5.8 (10% dilution).


Not applicable.


Not applicable.





Not available.



Relative Density 1.13-1.35.




Solubility(ies) Water: insolubleOther: not available


Not available.



Viscosity >3,000,000 cP.

Explosive properties Impact sensitivity: no reaction at 50 J (Dried Explosive: reaction at 28.6 J) Sensitivity to friction: no reaction to 353 N (Dried Explosive: no response to 353 N)





Reactivity Sensitivity to shock and friction is increased in the presence of hard material ( dust, sand …) Explosion risk in case of strong shock, or violent friction on the material to the confined state.Danger of explosion due to a sudden increase in temperature (fire).Risk of an instant transmission of the explosion to all of the explosive mass. Sensitivity of the dried product is higher than the original product’s sensitivity.

Chemical Stability Stable under the recommended storage and use conditions and at moderately elevated temperatures and pressures. The recommended shelf life is one year. Beyond one year, the product is not more dangerous, but its reliability is no longer guaranteed. Field climate recommended: -10°C to + 60°C.





Incompatible materials Avoid contact with alkalis, amines, strong acids, alkali metals, copper, and zinc. Do not store with products of the class 1.1B.


The fumes from combustion or explosion contain COx and NOx.


Acute toxicity Ammonium NitrateLD50 (oral, rat) = 2950 mg/KgLD50 (skin, rat) > 5.000 mg/KgSodium nitrateLD50 (oral, rat) = 3430 mg/KgLD50 (skin, rat) > 5000 mg/Kg

Skin corrosion / irritation A skin irritation can occur.


Ammonium nitrate is irritating to rabbit eyes. The product can induce a severe eye irritation.


Inhalation and continuous skin contact may lead to sensitization.





STOT – repeated exposure Not available.


Respiratory irritation The explosive irritates the airways and can cause sneezing and coughing. Large quantities can cause headache, lack of appetite, malaise, vomiting, dizziness, fluctuations in blood pressure and fainting.


Other information



Toxicity

Aquatic toxicity of Sodium nitrate

Fish LC50 48h 447 mg/L

Daphnia CE50 48h 447 mg/L

Algae CE50 10j 1.700 mg/L

Aquatic toxicity of Ammonium nitrate

Oncorhynchus LC50 96h 7950 mg/L

Tschawytscha Daphnia

CE50 24h 8609 mg/L

Microorganism CE10 3h 180 mg/L


Not available.




Ammonium nitrate and sodium nitrate : not concerned by PBT nor vPvB.




The use of the emulsion does not produce any waste other than the cardboard boxes and the polyethylene bags that must be destroyed according to the appropriate regulations. Do not put waste in general waste or landfill; destroy in licensed facilities.Contaminated packaging with traces of explosives must be carefully reviewed to ensure they are empty and put flat. They can be burned on the place of use, if the property is authorized. See the CBI/EIG “Guidance for the Safe Management and Disposal of Explosives”.



UN Number UN 0241.

UN Proper Shipping Name EXPLOSIVE, BLASTING, TYPE E.




Special Precautions for User As an explosive, the product is a high consequence dangerous good and adequate transport precautions must be taken for its security. Transport by air is forbidden under ICOA/IATA codes.


Not available.

Label







Abbreviations and acronymsADN/ADNR: Regulations concerning the transport of dangerous substances in barges on inland waterways. ADR/RID: European Agreement concerns the International Carriage of Dangerous Goods by Road/ Regulations concerning the international carriage of dangerous goods by rail. ANSI: American National Standards Institute.CAS No.: Chemical Abstract Service Number.CFR: Code of Federal Regulations.CLP: Classification, Labelling and Packaging. EC No.: European Commission Number. IATA: International Air Transport Associations. IMDG: International Maritime Dangerous Goods code.NFPA: National Fire Protection Association.PBT: Persistent, Bioaccumulative, Toxic.RCRA: The Resource Conservation and Recovery Act.UN No.: United Nations Number.UVCB: Substances of Unknown or Variable composition, Complex reaction products or Biological materials. vPvB: very Persistent and very Bioaccumulative.WHMIS: Workplace Hazardous Materials Information System.

ReferencesGuidance for the Safe Management and Disposal of Explosives, HSE/CBI-EIG, 2007.

Evaluation method for mixturesNot applicable

Relevant hazard Statements and Precautionary statementsMeanings of Hazard Phrases H271 May cause fire or explosion; strong oxidizer.H272 May intensify fire; oxidizer.H302 Harmful if swallowed.H373 May cause damage to organs through prolonged or repeated exposure.

Advice on training Unavailable.


OTHER INFORMATION


Changes


10 26/02/2017 Completely updated. Includes Exem 55 and 100 as well as Explus TSR

13

Blasting Accessories

Blasting Accessories Data

EPC-UK supply a complete range of complementary blasting accessories including;

• Stemming Rods

• Shock Tube Initiators

• ‘ROBIS’ Remote Shock Tube Initiator

• Seismographs

• Cartridge Pricker

• Copper Connecting Wire

• Shotfiring Cable

• Ohmmeter

• “Plystem” Clay Stemming

• Layflat Tubing

Cornwall

Whatley

South Wales

Bramble Island

Alfreton

Settle

Scotland

Shetland Islands

Nationwide Distribution

EPC-UK offers a comprehensive network of depots throughout the UK

Blasting and Support Services

EPC-UK offer a range of services;

Complete Blasting Solutions

Explosives Engineering Consultancy

On-line blast monitoring service

EPC-UK App

14

Complete Blasting Solutions

EPC-UK operates highly competent blasting service teams across the UK

Working with many of the leading brands in the UK quarrying and mining industry our service team drill and blast in excess of 35m tonnes of rock per annum through ‘Rock on Ground’ contracts.

EPC-UK operates one of the largest drill rig fleets in the country, our four year replacement cycle ensures we are able to service contracts with the most modern and efficient of rigs supplied by leading manufacturers.

Supported by our in house explosive engineering team EPC-UK utilises cutting edge technology to drive improvements in blast performance.

Our blasting teams are able to offer expertise not only in the quarry sector but in a range of environments from large scale mining operations to complex civil engineering projects.

• Quarrying

• Mining

• Civil Engineering Projects; Wind Farms, Road Cuttings, Shaft Sinking & Tunnelling

• Specialist Blasting

• OHSAS 18001 acreddited

• Achilles and Avetta Accredited

• NVQ/QCF Qualified Drillers, Profilers, Shotfirers and Explosive Supervisors

• IOSH Qualified Supervisors

• NEBOSH Qualified Managers

Explosives Engineering Consultancy

EPC-UK employs a team of Explosive Engineers, experts in their field they are able to offer advice, support and consultancy on a range of blasting matters;

• Vibration prediction, control and management

• Regression Line Analysis

• Signature Hole Analysis and Linear Superposition Modelling

• Tailored Blast Optimisation Projects

• Product support

TrainingA range of training courses can be delivered at EPC-UK’s Learning and Development Centre, Alfreton, Derbyshire, including;

• Industry Standard Courses; Shot Firing, Explosive supervisor

• Specialist Courses; Miscellaneous Mines

• Bespoke Courses

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On-line blast monitoring service

EPC Metrics provides a comprehensive service for the remote assessment of vibration and air over-pressure. State of the art, remote stations provide automated logging with instant transmission of data.

Using our web based data management platform, results can be viewed immediately after a blast with options for automated alerts.

The benefits of EPC Metrics:

• Fixed stations

• Instant availability of results

• Consistent monitoring

• Set-up of custom alerts, including email & text message notification

In addition to remote monitoring, EPC Metrics can also assist with your seismograph hire and purchase requirements.

EPC METRICS

EPC-UK App

The EPC-UK App provides free safety information and a range of interactive tools for those working in the commercial explosives and blasting industry, in a simple to use format with many key features available offline, enabling access to information whenever and wherever you need it.

Key features and advantages include:

Safety information – Sharing best practice; access the latest industry safety bulletins and follow our Esprit d’Equipe campaign

CPD – Record and save your own CPD events with the ability to email records direct

Innovation – Get all the latest news and updates direct to your mobile device

Reports – submit a report or near miss immediately no paper no fuss

Product information – explore product specifications, images and first aid information

Blast calculations – complex calculations made easy no pen and paper required

EPC-UK safety data sheets are designed to give ‘at a glance’ information and product profile.

Terms and Conditions

“The products and services that we supply to you are sold subject to our standard Terms and Conditions of Supply and any other Special Conditions that we notify to you. Copies of these conditions are available on request.”

The information contained in this booklet is given without warranty and cannot cover all conditions of use. Users should undertake their own tests to ensure the suitability of the products for their own particular application.

Product GuideExplosives and Accessories 2017/18


Head OfficeUnit 1, Venture Crescent, Alfreton, Derbyshire DE55 7RATelephone: 01773 832253

Rough Close WorksCarnfield Hill, South Normanton, Alfreton, Derbyshire DE55 2BETelephone: 01773 832253

Scotland DepotPortcullis Estate, Milton Of Campsie, Glasgow G66 8AQTelephone: 0141 776 7196

Cornwall

Whatley

South Wales

Bramble Island

Alfreton

Settle

Scotland

Shetland Islands


Product Guide - Explosives and Accessories - 2017/18

Documents

Shetland Islands Scotland Product Guide - EPC-UK · Product Guide - Explosives and Accessories - 2017/18. EPC-UK safety data sheets are designed to give ‘at a glance’ information