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SPREADSHEET AND GRAPHING WITH EXCEL Table of contents Introduction 2 Layout of spreadsheet 2 Selecting a group of cells 3 Formatting of Cells and Cell Contents 3 Number format and alignment format 4 Font and border 5 Pattern 6 Type of data entry 6 Number 6 Text, labels, and formulas 7 Statistical analysis and other functions 12 Graphing in excel 13 Printing charts and graphs 28 Conclusion 30

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SPREADSHEET AND GRAPHING WITH EXCEL

Table of contents

Introduction 2

Layout of spreadsheet 2

Selecting a group of cells 3

Formatting of Cells and Cell Contents 3

Number format and alignment format 4

Font and border 5

Pattern 6

Type of data entry 6

Number 6

Text, labels, and formulas 7

Statistical analysis and other functions 12

Graphing in excel 13

Printing charts and graphs 28

Conclusion 30

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SPREADSHEET AND GRAPHING WITH EXCEL

In the general chemistry curriculum at Norco College, the Excel program is used to record and

manipulate data, perform error analysis, and construct graphs. Although many students may be

quite familiar with Excel already, the following tutorial is written to provide a basic introduction

to Excel and to provide a review of commonly used functions in the course.

There are free tutorials available for Excel 2010 and can be accessed at

https://www.norcocollege.edu/lynda/Pages/Set-Up.aspx . You will need to first set up an

account by following the directions at this website. Refer to the following websites for the

tutorials:

Basics:

https://www.lynda.com/Excel-tutorials/Excel-2010-Essential-Training/61219-

2.html?srchtrk=index%3a3%0alinktypeid%3a2%0aq%3atutorial+excel%0apage%3a1%0as%3ar

elevance%0asa%3atrue%0aproducttypeid%3a2

Shortcuts:

https://www.lynda.com/Excel-2010-tutorials/power-shortcuts/69522-2.html

Charts:

https://www.lynda.com/Excel-2010-tutorials/Charts-in-Depth/81263-2.html

Advanced Formatting:

https://www.lynda.com/Excel-2010-tutorials/advanced-formatting-techniques/74462-2.html

For Excel 2003, the following screenshots and directions are helpful but may vary depending on

if your computer is a Mac or PC.

Layout of the Spreadsheet

Once you have opened the Excel program, choose Normal under View in the main menu bar

located at the top of the screen. You will be presented with a basic format of a spreadsheet.

Main Menu Bar for Excel (varies depending on the version of Excel and Mac or PC)

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The spreadsheet is made up of a series of columns (labeled A, B, C, etc.) and rows (labeled 1, 2,

3, etc.). When you click on any box in the spreadsheet, the column and row will be highlighted

(darker shade as compared to the other rows or columns). In addition, the cell that is selected

will be highlighted around the edges to alert you that this is the active cell (the cell you selected)

and its location is referred to as B6.

Selecting a Group of Cells

To select cells A3 through D14, click on cell A3 and hold and drag the cursor to cell D14. The

group of cells will be highlighted as shown in the figure below.

Formatting of Cells and Cell Contents

The Format option in the main menu bar allows you to do many things with the look of the

cells as well as the contents of the cells. Click on Format, then Cells…, and you should see the

following:

Column “B” Row 6 Cell B6

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SPREADSHEET AND GRAPHING WITH EXCEL

• Number Format

o Changes the way values are written ($, scientific notation, etc.) and the number of

decimal places desired (click on Number and it gives an option to identify the

number of decimal places)

• Alignment Format

o Changes the way the contents are aligned in the cells

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• Font

o Allows you to change the type, size and style (superscript, etc.) of font.

• Border

o Allows you to change the border of the cells or a group of cells and the style of

border.

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• Pattern

o Allows you to change the color of the cell and its contents

Types of Data Entry

• Numbers (e.g. 352)

o Highlight the cell and type in the number and hit the Enter or Return key.

o Changing Formatting (scientific notation, decimals, number of digits or

placeholders, etc.)

▪ Select the cell(s) to be formatted

▪ Select Format on the main menu bar

▪ Select Cells…You should see the following screen:

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▪ From here, the most common selection under the Number menu item in

the category section is Number or Scientific. You may choose the

number of decimal places here too. This is useful when ensuring that you

report numbers to the correct number of significant figures.

▪ In addition to number formatting, you may also choose to change the

alignment, font, size, etc.

• Text or labels (e.g. concentration)

o Changing Formatting (font, size, style, etc.)

▪ Process is the same as for formatting numbers. Select Format under the

main menu bar, then select Cells… and then choose the type of

formatting you want (font, size, etc.).

• Formulas (e.g. =C1+D1)

o Excel makes performing mathematical operations on a series of data very easy.

You can add columns of numbers or do any other type of operation.

o Formula always starts with an “=” sign

o Mathematical symbols in order of operation include

▪ Parentheses ( ) or brackets [ ] to group expressions

▪ Exponents (a caret symbol, ^)

▪ Division (a forward slash, /)

▪ Multiplication (an asterisk, *)

▪ Addition (a plus symbol, +)

▪ Subtraction (a minus symbol, -)

For example, make a spreadsheet that contains the following information:

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Next, change the 3 in cm3 to a superscript. Highlight the 3 and then go to Format,

Cells…, and check the Superscript box (see below). Then hit OK to make the change.

Now, let’s change the format of the cells so that the contents of all cells in the table are

aligned in the center. First, click and drag to highlight the table, then go to Format,

Cells…, and Alignment.

Next, choose Center, and then hit OK. Your spreadsheet should look as follows:

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To calculate the volume of the block (L x W x H) using the formula function in Excel for

trial 1, first click on cell E7. Then type in the equal sign, “=” (all formulas begin with an

equal sign), and click on each of the three cells that contain the desired data with the

multiplication sign in between: B7 * C7 * D7.

After pushing the Return key, the screen looks like the following:

You have now calculated the volume by multiplying the length times the width times the

height. Instead of calculating the volume by hand, we did it by using Excel by entering a

formula. If you double click again on cell E7, it will show you the formula that was

used. Next, let’s copy the formula in cell E7 and paste it in the remaining two cells in

order to calculate the volume for trials 2 and 3. First copy the formula in cell E7 by

clicking on the cell, then by pushing the Control and c button at the same time. You can

do this another way by going under Edit in the main menu bar and clicking on Copy.

Next click and drag to highlight cells E8 and E9. The cells should be highlighted as

follows:

Notice the location of the formula that was copied has a dashed line around it and the

location of where the formula will be pasted is highlighted around the cell’s perimeter

and shaded.

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SPREADSHEET AND GRAPHING WITH EXCEL

Next, hit the two buttons Control and p (for paste) and hit return. The volumes will be

now calculated for Trials 2 and 3.

The number of significant figures for volume should be 3 so the format for the cells E7-

E9 needs to be changed to reflect this. Make sure that these cells are highlighted. Then

go to Format in the main menu bar, then Cells… then Number.

Click on 1 decimal place and hit OK and now the results are shown with three significant

figures.

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Double click on each cell going from E7 to E9. Notice the formula will appear in each

cell and that the cell number only changes. By copying the cell in E7 we essentially

copied the “relative” cell. In other words by pasting the formula in the next two cells

below this, the relative location is kept (column B) but the row number changes. This

allows you to copy and paste formulas for a large amount of data which makes your life

MUCH easier!

You can further customize your table by making borders, colors, etc. For example, let’s

place a border around the entire table and around each cell. Click and drag to select cells

of the table and then click Format, Cells…, and then Border. From here, choose the

Outside, Inside borders and increase the Line thickness for the border. Play around with

the options to get more familiar with these features.

The result is as follows:

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Statistical Analysis and Other Functions

Functions can be used to calculate the average, standard deviation, etc. on a large set of data.

Below is a list of some common functions:

• Average: =average(cell range)

• Standard deviation: =stdev(cell range)

• Other functions: (see your Excel help section)

If we wanted to calculate the average volume and standard deviation (an indication to the level of

precision of the measurements), then it is easiest to use functions. Type “avg volume:” and “std

dev” below the “Height” column.

Then click on cell E11. Enter “=average(and then click on cell E7 and drag to cell E9 and enter

a closed parenthesis)”. Select Return.

The average value of volume is calculated for you and is shown in cell E11.

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You can also calculate the standard deviation of the volume by selecting first the cell where the

data is to be located, E12, and then by entering “=stdev(and choose the cell range by clicking

and dragging on cells E7..E9)”.

Select Return to show the value of the standard deviation.

At this point, you should change the number of significant figures in the standard deviation by

changing the format.

Graphing in Excel

Make a spreadsheet with the following information (be sure to also do all necessary formatting

changes).

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You may have to change the column width so that all information can be seen.

You can do this two ways. The first way is to move your cursor over the vertical line between

the B and C column heading. Your cursor should change. Then click on this spot and move

your cursor to expand (or shrink) the column width.

You may also do this by going to Format, Column, then Width to adjust the column width.

You can change the column width on a single column or a block of columns.

Next, in order to graph the data to make a plot of Concentration versus Absorbance data (this is

sometimes called a Beer’s plot or a calibration curve), you need to click on Insert, and then

Chart.

This will bring you to the following choices:

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The first thing to do is choose the type of chart you want. The most common chart to select is

XY (Scatter). You generally do not want lines to go from each point on your plot (like a dot-to-

dot picture). Therefore, select the chart with only points by clicking on the correct picture icon

under Chart sub-type (see above). Click Next to finish the graph.

You next come across the Data Range screen. You may either enter the data range by hand,

B6:C9 (the two dots between the cell addresses means to use all cells including and in between

these cells) or you may choose to use your cursor to click and drag over the data you want

plotted.

If you used your cursor to select the data range, your screen will look like the following:

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At this point it is CRITICAL to make sure you plotted the correct data for the graph. In other

words, make sure that concentration values are on the x-axis and absorbance values are on the y-

axis (check a couple of data points to verify that Excel is plotting what you intended). This

happened automatically in this example because the table of data listed the x data in the first

column and the y data in the next column.

If you did not plot the correct data you will need to go to the Series option and reselect the

correct data to plot (see below).

Note that the y data points are considered series data. If you have more than one set of y data

(several series of data), you can add more to the existing plot by selecting Add. Next, click and

drag or type in the correct data range for a particular series in the Y box. You can toggle

between the different series by clicking on the series of interest in the Series box (not the Series

tab!). You can also delete a series of data by first clicking on the series of interest in the Series

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box and clicking on Remove. However, this plot has only one series of data (one set of y

values).

Click the Next button and continue with the graph. The next screen looks like the following:

Fill in the table for your Chart title and Axes labels (see below), and then click on Next.

You have other choices in this screen as well. Click on Axes to see your options here.

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Click on Gridlines to see your options on placing horizontal and/or vertical lines on your graph.

Uncheck the Major gridlines box (and any other box) so that no gridlines appear on your graph.

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Click on Legend to see your options here.

The legend shows what series were plotted. The legend is most useful if more than one series is

plotted (i.e. more than one set of y values are plotted on the same graph which then requires a

legend to distinguish between the data sets). Since there is only one set of y values plotted,

deselect the Show legend box so that no legend appears on the graph.

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The Data labels option in this menu allows you to show the x and y values for each data point.

This is not commonly used on graphs. Select Finish to finish the graph.

You will then be asked to save the graph as part of the worksheet (As object in) or as a separate

worksheet (As a new sheet). It is easiest to save the graph as part of the worksheet since it

makes printing data and the graph together much easier. Select As object in. The screen should

look as follows:

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If you want to manipulate anything on the graph to further modify it, click once anywhere on the

graph. You will notice that the graph is outlined now and that there is a new menu that appears

at the top for graphing. Your computer may not show a new menu automatically. If not, go to

View, Toolbars, and then Graph to add a new menu bar. Notice also that there are other menu

bars that you can select to be shown instead of having to scroll through all of the choices on the

main menu bar. The spreadsheet now has two parts, a data part (where the cells are located) and

a graph part. If you want to alter anything on the data part of your spreadsheet, just click any cell

and the main menu bar changes so to reflect that you are working on the data part of the

spreadsheet (gives you menu options for changing the data part of the spreadsheet).

If you click anywhere on the graph part, the main menu bar changes to reflect that you are

working on the graph (gives you menu options for changing the graph).

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You can continue to customize your graph by double-clicking on any portion. For example if

you double click (or right click for PC users) on an axis, you can make changes to the axis

(change the scale, etc.).

For now, let’s make the 2+ in the Chart title a superscript. Highlight the 2+ with your cursor,

then go to Format and then Selected Chart Title.

The next screen should look like the following:

Check the Superscript box and then OK. The 2+ should now be a superscript.

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Let’s now alter the axes information and its format. Let’s explore this first by double-clicking on

the y-axis. You will get a screen that looks like the following:

In this screen, you can alter the cross or tick marks on your scale and the line thickness. Under

the Major tick mark type (tick marks besides the numbers on the scale), select Cross. Under

Minor Tick Mark type (tick marks between the major tick marks) select None. There are many

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styles to choose from here but it is recommended to choose a major tick mark and possibly a

minor tick mark. Click on OK to finish.

Now you have tick marks on the y-axis. Notice the absorbance values on the y-axis have either

one or two decimal places while the data in the spreadsheet has 3 significant figures. One way to

address this discrepancy is to change the number of decimal places to reflect the number of

decimal places you know for certain. The estimated digit in your measurements should be

determined by interpolating between the tick marks on your graph.

You will need to change the decimal places to two. To do this, first be sure your y axis is

selected (double-click) and choose the Number option in the Format Axis menu screen.

Choose Number and 2 decimal places and then click OK. Your graph on your spreadsheet

should look like the following:

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You can now estimate to the thousandth’s place for the absorbance values on the y axis which is

consistent with the measured absorbance values which is estimated to the thousandth’s place.

You should also check the x axis values to make sure the concentrations can be read to the

proper number of significant figures adjusting the tick marks on the x axis accordingly.

If you measured the absorbance of an unknown, you could then determine the concentration of

the unknown using the plot above after making the best-fit line through all of the data. Another

way to determine the concentration of an unknown is to determine the slope of the best-fit line,

which would give the Beer’s constant. The Beer’s constant is useful so that when you measure

the absorbance of an unknown Fe(SCN)2+ solution, you could determine its concentration by

using Beer’s Law: A = bC where A is absorbance, C is concentration and b is Beer’s constant.

This equation works if the y-intercept is equal to zero, i.e. the best-fit line passes through (0, 0)

on your graph. You could determine the slope of the line graphically (change of y over change

of x) or by doing a linear regression of the data since the relationship between absorbance and

concentration is linear. In either case, a best-fit line is needed which requires a linear regression

of the data. To do the linear regression, click on anywhere on your graph so that the graph main

menu bar appears at the top of your screen. Click on Chart, then on Add Trendline.

Next, select Linear.

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You can format the trend line and display the equation and the coefficient of determination (R2)

on the chart by selection Options and selecting the appropriate boxes. Checking the Set

intercept to zero box (you should discuss this with your professor first as to whether this should

be done for your specific graph) will force the line through zero. Checking the next two boxes

“Display equation on chart and Display R-squared value on chart” will display the equation

and the R2 value on the chart. The equation of the line (y = mx + b) gives two pieces of

important information, namely the slope (m) and the y-intercept (b). The R2 value gives you an

indication as to the degree that the data best fits a line (generally the closer the data fit a straight

line, the higher the R2 value. The maximum value for R2 is 1).

Click OK after selecting all three boxes.

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The displayed equation and the R2 value can be moved around on the chart if needed so that it is

not on the line by clicking on the text box and dragging it to another spot on the chart. Your

graph should look like the following:

There may be a time when you need to increase the number of significant figures on the slope

and/or y-intercept in your regression output (some programs round it to 1 significant figure and

this introduces a lot of rounding error in any subsequent calculations using this data). You can

estimate the number of significant figures that should be in your value of the slope by doing a

quick calculation by hand of the slope by choosing two data points on the line and estimating

these points to the proper number of significant figures. Use the correct rules for significant

figures when doing the calculation to determine the number of significant figures that should be

in your final slope value. Then, adjust the number of decimal places in the output of the

regression data to have a few more digits than required in order to minimize rounding errors in

subsequent calculations that require the use of the slope value.

Double-click on the regression data in your graph. Then select Number in the Format Data

Labels screen, then choose Number and 3 decimal places and then click OK.

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Your regression data should now show 3 decimal places in the slope of the line on your graph.

You now could either use the value of the slope to determine the concentration of an unknown if

the absorbance of an unknown is known using Beer’s Law or you could calculate the

concentration of the unknown using the graph only by finding the absorbance of your unknown

on your graph and moving over to where it intersects the line and then by reading the

concentration at that point.

Printing charts and graphs

Unless color is needed, it is best to change the color of the plot area of the chart to white. Click

on the chart so that it is selected. Under Format, choose Selected Plot Area. In the Colors and

Lines tab, under Fill, change the color by selecting No Fill. Click OK. This will change the

background of the plot area to white.

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If both the data table and chart are to be graphed on the same page, select both by clicking and

dragging the mouse over the entire area. Notice that selected area has dashed lines around it and

is highlighted. Under File, select Print Area, then Set Print Area. Then choose Print under

File. If on the other hand, only the graph is to be graph, click on the chart so that it is highlighted

and then click File and then Print.

The graph or the data table and graph can be printed in one of two styles: Portrait (vertical) or

Landscape (horizontal). Choose the appropriate style under File, Page Set Up. It is always a

good idea to do a Print Preview so that any mistakes can be fixed before the actual printing.

Doing so will save you time and paper.

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SPREADSHEET AND GRAPHING WITH EXCEL

There are a variety of short cuts and icons that can be used to make working in Excel easier that

are not covered in this tutorial. Although the format of the spreadsheet might change depending

on the version of Excel or Mac/PC, the basic guidelines will remain fairly the same. For

additional help with items not covered in this tutorial or on more advanced Excel features, see

your professor.