Ácido FosfóricopH [H] ka1 ka2 ka3 α0 α1 α2

0 0 7.11E-03 6.32E-08 4.50E-13 0 0 00.5 0.3162 7.11E-03 6.32E-08 4.50E-13 0.97800872 0.0219912776 3.60298E-09

1 0.1 7.11E-03 6.32E-08 4.50E-13 0.9336196 0.0663803539 5.49252E-091.5 0.03162 7.11E-03 6.32E-08 4.50E-13 0.81642108 0.1835785539 1.98754E-09

2 0.01 7.11E-03 6.32E-08 4.50E-13 0.584452 0.4155453727 6.31842E-102.5 3.16E-03 7.11E-03 6.32E-08 4.50E-13 0.30768805 0.6922981066 1.99707E-10

3 1.00E-03 7.11E-03 6.32E-08 4.50E-13 0.12329773 0.8766468652 6.31994E-113.5 3.16E-04 7.11E-03 6.32E-08 4.50E-13 0.04254504 0.9572635027 1.9971E-11

4 1.00E-04 7.11E-03 6.32E-08 4.50E-13 0.01386099 0.9855161669 6.31994E-124.5 3.16E-05 7.11E-03 6.32E-08 4.50E-13 0.00441599 0.9935968205 1.9971E-12

5 1.00E-05 7.11E-03 6.32E-08 4.50E-13 0.00139569 0.9923327706 6.31994E-135.5 3.16E-06 7.11E-03 6.32E-08 4.50E-13 0.00043554 0.9799651541 1.9971E-13

6 1.00E-06 7.11E-03 6.32E-08 4.50E-13 0.00013227 0.940432378 6.31994E-146.5 3.16E-07 7.11E-03 6.32E-08 4.50E-13 3.70357E-05 0.8333022725 1.9971E-14

7 1.00E-07 7.11E-03 6.32E-08 4.50E-13 8.61799E-06 0.6127387496 6.31994E-157.5 3.16E-08 7.11E-03 6.32E-08 4.50E-13 1.48147E-06 0.333329675 1.9971E-15

8 1.00E-08 7.11E-03 6.32E-08 4.50E-13 1.92133E-07 0.1366066881 6.31994E-168.5 3.16E-09 7.11E-03 6.32E-08 4.50E-13 2.11612E-08 0.0476125892 1.9971E-16

9 1.00E-09 7.11E-03 6.32E-08 4.50E-13 2.18979E-09 0.0155694268 6.31994E-179.5 3.16E-10 7.11E-03 6.32E-08 4.50E-13 2.20804E-10 0.0049680848 1.9971E-1710 1.00E-10 7.11E-03 6.32E-08 4.50E-13 2.21197E-11 0.0015727128 6.31994E-18

10.5 3.16E-11 7.11E-03 6.32E-08 4.50E-13 2.18994E-12 0.0004927368 1.9971E-1811 1.00E-11 7.11E-03 6.32E-08 4.50E-13 2.12927E-13 0.0001513913 6.31994E-19

11.5 3.16E-12 7.11E-03 6.32E-08 4.50E-13 1.94513E-14 4.37654E-05 1.9971E-1912 1.00E-12 7.11E-03 6.32E-08 4.50E-13 1.53476E-15 1.091215E-05 6.31994E-20

12.5 3.16E-13 7.11E-03 6.32E-08 4.50E-13 9.16737E-17 2.062659E-06 1.9971E-2013 1.00E-13 7.11E-03 6.32E-08 4.50E-13 4.04623E-18 2.876869E-07 6.31994E-21

13.5 3.16E-14 7.11E-03 6.32E-08 4.50E-13 1.4581E-19 3.280731E-08 1.9971E-2114 1.00E-14 7.11E-03 6.32E-08 4.50E-13 4.83788E-21 3.439736E-09 6.31994E-22

0 2 4 6 8 10 12 14 160

0.2

0.4

0.6

0.8

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Ácido Fosfórico

α0α1α2α3

pH

∆α

0 2 4 6 8 10 12 14 160

0.2

0.4

0.6

0.8

1

1.2

Ácido Fosfórico

α0α1α2α3

pH

∆α

Ácido Fosfórico Ácido Cítricoα3 pH [H] ka1 ka2 ka3 α0 α12.843975E-20 0 0 8.40E-04 1.80E-05 4.00E-06 0 05.127588E-21 0.5 0.3162 8.40E-04 1.80E-05 4.00E-06 0.99735034 0.002649512.471634E-20 1 0.1 8.40E-04 1.80E-05 4.00E-06 0.99166849 0.00833002

2.82857E-20 1.5 0.03162 8.40E-04 1.80E-05 4.00E-06 0.97410764 0.025877622.84329E-20 2 0.01 8.40E-04 1.80E-05 4.00E-06 0.92238052 0.07747996

2.843934E-20 2.5 3.16E-03 8.40E-04 1.80E-05 4.00E-06 0.78905494 0.209748782.843971E-20 3 1.00E-03 8.40E-04 1.80E-05 4.00E-06 0.53903111 0.452786142.843974E-20 3.5 3.16E-04 8.40E-04 1.80E-05 4.00E-06 0.26235959 0.697411572.843975E-20 4 1.00E-04 8.40E-04 1.80E-05 4.00E-06 0.0911371 0.765551632.843975E-20 4.5 3.16E-05 8.40E-04 1.80E-05 4.00E-06 0.02240105 0.595470922.843975E-20 5 1.00E-05 8.40E-04 1.80E-05 4.00E-06 0.00337064 0.283133342.843975E-20 5.5 3.16E-06 8.40E-04 1.80E-05 4.00E-06 0.00027044 0.071888932.843975E-20 6 1.00E-06 8.40E-04 1.80E-05 4.00E-06 1.3082E-05 0.010988872.843975E-20 6.5 3.16E-07 8.40E-04 1.80E-05 4.00E-06 4.82914E-07 0.00128372.843975E-20 7 1.00E-07 8.40E-04 1.80E-05 4.00E-06 1.61289E-08 0.000135482.843975E-20 7.5 3.16E-08 8.40E-04 1.80E-05 4.00E-06 5.17638E-10 1.376E-052.843975E-20 8 1.00E-08 8.40E-04 1.80E-05 4.00E-06 1.64931E-11 1.38542E-062.843975E-20 8.5 3.16E-09 8.40E-04 1.80E-05 4.00E-06 5.21322E-13 1.38579E-072.843975E-20 9 1.00E-09 8.40E-04 1.80E-05 4.00E-06 1.65303E-14 1.38854E-082.843975E-20 9.5 3.16E-10 8.40E-04 1.80E-05 4.00E-06 5.21693E-16 1.38678E-092.843975E-20 10 1.00E-10 8.40E-04 1.80E-05 4.00E-06 1.6534E-17 1.38885E-102.843975E-20 10.5 3.16E-11 8.40E-04 1.80E-05 4.00E-06 5.2173E-19 1.38688E-112.843975E-20 11 1.00E-11 8.40E-04 1.80E-05 4.00E-06 1.65344E-20 1.38889E-122.843975E-20 11.5 3.16E-12 8.40E-04 1.80E-05 4.00E-06 5.21734E-22 1.38689E-132.843975E-20 12 1.00E-12 8.40E-04 1.80E-05 4.00E-06 1.65344E-23 1.38889E-142.843975E-20 12.5 3.16E-13 8.40E-04 1.80E-05 4.00E-06 5.21734E-25 1.38689E-152.843975E-20 13 1.00E-13 8.40E-04 1.80E-05 4.00E-06 1.65344E-26 1.38889E-162.843975E-20 13.5 3.16E-14 8.40E-04 1.80E-05 4.00E-06 5.21734E-28 1.38689E-172.843975E-20 14 1.00E-14 8.40E-04 1.80E-05 4.00E-06 1.65344E-29 1.38889E-18

0 2 4 6 8 10 12 14 160

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Ácido Cítrico

α0α1α2α3

pH

∆α

0 2 4 6 8 10 12 14 160

0.2

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0.8

1

1.2

Ácido Cítrico

α0α1α2α3

pH

∆α

Ácido Cítrico Ácido Cítricoα2 α3 pH [H] ka1 ka2 α0 α1

0 7.01624E-11 0 0 5.60E-02 5.42E-05 0 01.46833E-07 1.85747E-12 0.5 0.3162 5.60E-02 5.42E-05 0.84952135 0.150452868.08383E-07 3.23353E-11 1 0.1 5.60E-02 5.42E-05 0.64090094 0.358904535.34509E-07 6.76166E-11 1.5 0.03162 5.60E-02 5.42E-05 0.3604816 0.638424081.75186E-07 7.00743E-11 2 0.01 5.60E-02 5.42E-05 0.15082156 0.844600715.54257E-08 7.01592E-11 2.5 3.16E-03 5.60E-02 5.42E-05 0.0525611 0.931462551.75406E-08 7.01623E-11 3 1.00E-03 5.60E-02 5.42E-05 0.01665689 0.93278615.54283E-09 7.01624E-11 3.5 3.16E-04 5.60E-02 5.42E-05 0.00479361 0.849500861.75406E-09 7.01624E-11 4 1.00E-04 5.60E-02 5.42E-05 0.00115671 0.647758295.54283E-10 7.01624E-11 4.5 3.16E-05 5.60E-02 5.42E-05 0.00020778 0.368221841.75406E-10 7.01624E-11 5 1.00E-05 5.60E-02 5.42E-05 2.78141E-05 0.155758915.54283E-11 7.01624E-11 5.5 3.16E-06 5.60E-02 5.42E-05 3.10868E-06 0.055090481.75406E-11 7.01624E-11 6 1.00E-06 5.60E-02 5.42E-05 3.23499E-07 0.018115945.54283E-12 7.01624E-11 6.5 3.16E-07 5.60E-02 5.42E-05 3.27086E-08 0.005796461.75406E-12 7.01624E-11 7 1.00E-07 5.60E-02 5.42E-05 3.28861E-09 0.001841625.54283E-13 7.01624E-11 7.5 3.16E-08 5.60E-02 5.42E-05 3.28801E-10 0.000582691.75406E-13 7.01624E-11 8 1.00E-08 5.60E-02 5.42E-05 3.29407E-11 0.000184475.54283E-14 7.01624E-11 8.5 3.16E-09 5.60E-02 5.42E-05 3.28974E-12 5.82992E-051.75406E-14 7.01624E-11 9 1.00E-09 5.60E-02 5.42E-05 3.29462E-13 1.84498E-055.54283E-15 7.01624E-11 9.5 3.16E-10 5.60E-02 5.42E-05 3.28991E-14 5.83022E-061.75406E-15 7.01624E-11 10 1.00E-10 5.60E-02 5.42E-05 3.29467E-15 1.84502E-065.54283E-16 7.01624E-11 10.5 3.16E-11 5.60E-02 5.42E-05 3.28993E-16 5.83025E-071.75406E-16 7.01624E-11 11 1.00E-11 5.60E-02 5.42E-05 3.29468E-17 1.84502E-075.54283E-17 7.01624E-11 11.5 3.16E-12 5.60E-02 5.42E-05 3.28993E-18 5.83026E-081.75406E-17 7.01624E-11 12 1.00E-12 5.60E-02 5.42E-05 3.29468E-19 1.84502E-085.54283E-18 7.01624E-11 12.5 3.16E-13 5.60E-02 5.42E-05 3.28993E-20 5.83026E-091.75406E-18 7.01624E-11 13 1.00E-13 5.60E-02 5.42E-05 3.29468E-21 1.84502E-095.54283E-19 7.01624E-11 13.5 3.16E-14 5.60E-02 5.42E-05 3.28993E-22 5.83026E-101.75406E-19 7.01624E-11 14 1.00E-14 5.60E-02 5.42E-05 3.29468E-23 1.84502E-10

0 2 4 6 8 10 12 14 160

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Ácido Cítrico

α0α1α2α3

pH

∆α

0 2 4 6 8 10 12 14 160

0.2

0.4

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0.8

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1.2

Ácido Oxálico

α0α1α2

pH

∆α

0 2 4 6 8 10 12 14 160

0.2

0.4

0.6

0.8

1

1.2

Ácido Cítrico

α0α1α2α3

pH

∆α

0 2 4 6 8 10 12 14 160

0.2

0.4

0.6

0.8

1

1.2

Ácido Oxálico

α0α1α2

pH

∆α

Ácido Cítrico Ácido Súlfuricoα2 pH [H] ka1 ka2 α0 α1 α2

1 0 0 0.00E+00 1.02E-02 1 0 02.57892E-05 0.5 0.3162 0.00E+00 1.02E-02 1 0 00.00019453 1 0.1 0.00E+00 1.02E-02 1 0 00.00109433 1.5 0.03162 0.00E+00 1.02E-02 1 0 00.00457774 2 0.01 0.00E+00 1.02E-02 1 0 00.01597635 2.5 3.16E-03 0.00E+00 1.02E-02 1 0 00.05055701 3 1.00E-03 0.00E+00 1.02E-02 1 0 00.14570553 3.5 3.16E-04 0.00E+00 1.02E-02 1 0 0

0.351085 4 1.00E-04 0.00E+00 1.02E-02 1 0 00.63157038 4.5 3.16E-05 0.00E+00 1.02E-02 1 0 00.84421328 5 1.00E-05 0.00E+00 1.02E-02 1 0 00.94490641 5.5 3.16E-06 0.00E+00 1.02E-02 1 0 00.98188374 6 1.00E-06 0.00E+00 1.02E-02 1 0 0

0.9942035 6.5 3.16E-07 0.00E+00 1.02E-02 1 0 00.99815838 7 1.00E-07 0.00E+00 1.02E-02 1 0 00.99941731 7.5 3.16E-08 0.00E+00 1.02E-02 1 0 00.99981553 8 1.00E-08 0.00E+00 1.02E-02 1 0 0

0.9999417 8.5 3.16E-09 0.00E+00 1.02E-02 1 0 00.99998155 9 1.00E-09 0.00E+00 1.02E-02 1 0 00.99999417 9.5 3.16E-10 0.00E+00 1.02E-02 1 0 00.99999815 10 1.00E-10 0.00E+00 1.02E-02 1 0 00.99999942 10.5 3.16E-11 0.00E+00 1.02E-02 1 0 00.99999982 11 1.00E-11 0.00E+00 1.02E-02 1 0 00.99999994 11.5 3.16E-12 0.00E+00 1.02E-02 1 0 00.99999998 12 1.00E-12 0.00E+00 1.02E-02 1 0 00.99999999 12.5 3.16E-13 0.00E+00 1.02E-02 1 0 0

1 13 1.00E-13 0.00E+00 1.02E-02 1 0 01 13.5 3.16E-14 0.00E+00 1.02E-02 1 0 01 14 1.00E-14 0.00E+00 1.02E-02 1 0 0

0 2 4 6 8 10 12 14 160

0.2

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Ácido Oxálico

α0α1α2

pH

∆α

0 2 4 6 8 10 12 14 160

0.2

0.4

0.6

0.8

1

1.2

Chart Title

α0α1α2

Axis Title

Axis Title

0 2 4 6 8 10 12 14 160

0.2

0.4

0.6

0.8

1

1.2

Ácido Oxálico

α0α1α2

pH

∆α

0 2 4 6 8 10 12 14 160

0.2

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1.2

Chart Title

α0α1α2

Axis Title

Axis Title

α0 α1 ka1#DIV/0! 0.995 1.99

0.03225806 0.495 1.990.102 -0.005 1.99

0.32258065 -0.505 1.991.02 -1.005 1.99

3.2278481 -1.505 1.9910.2 -2.005 1.99

32.278481 -2.505 1.99102 -3.005 1.99

322.78481 -3.505 1.991020 -4.005 1.99

3227.8481 -4.505 1.9910200 -5.005 1.99

32278.481 -5.505 1.99102000 -6.005 1.99

322784.81 -6.505 1.991020000 -7.005 1.99

3227848.1 -7.505 1.9910200000 -8.005 1.9932278481 -8.505 1.99

102000000 -9.005 1.99322784810 -9.505 1.99

1020000000 -10.005 1.993227848101 -10.505 1.99

1.02E+10 -11.005 1.993.2278E+10 -11.505 1.99

1.02E+11 -12.005 1.993.2278E+11 -12.505 1.99

1.02E+12 -13.005 1.99