^ L X ^ AnalyficalTechnoiogies, Inc

SFUND RECORDS CTR

88015256 SFUNO RECORDS CTR

0222-00703

GCMS - RESULTS

REAGENT BLANK

7717^ y / u A

AR055S

TEST : VOLATILE ORGANICS (EPA 624)

CLIENT : MONTGOMERY & ASSOCIATES PROJECT # : 661D PROJECT NAME : HASSAYAMPA CLIENT I.D. : REAGENT BLANK

ATI I.D. DATE EXTRACTED DATE ANALYZED UNITS DILUTION FACTOR

806130 06/29/88 06/29/88 UG/L N/A

COMPOUNDS RESULTS

CHLOROMETHANE BROMOMETHANE VINYL CHLORIDE CHLOROETHANE METHYLENE CHLORIDE ACETONE CARBON DISULFIDE 1,1-DICHLOROETHENE 1,1-DICHLOROETHANE 1,2-DICHLOROETHENE (TOTAL) CHLOROFORM 1,2-DICHLOROETHANE, 2-BUTANONE (MEK) 1,1,1-TRICHLOROETHANE CARBON TETRACHLORIDE VINYL ACETATE BROMODICHLOROMETHANE 1,1,2,2-TETRACHLOROETHANE 1,2-DICHLOROPROPANE TRANS-1,3-DICHLOROPROPENE TRICHLOROETHENE DIBROMOCHLOROMETHANE 1,1,2-TRICHLOROETHANE BENZENE CIS-1,3-DICHLOROPROPENE 2-CHLOROETHYLVINYLETHER BROMOFORM 2-HEXANONE (MBK) 4~METHYL-2-PENTANONE (MIBK) TETRACHLOROETHENE TOLUENE CHLOROBENZENE ETHYL BENZENE STYRENE TOTAL XYLENES

<10 <10 <1 <1 TR TR <1 <1 <1 <1 <1 <1 <10 <1 . <1 <10 <1 <1 <1 <1 <1 <1 <1 <1 <1 <10 <5 <10 <10 <1 <1 <1 <1 <1 <1

1 ^ - ' . • - ' • C - . \ , I r : J o/ti,»;;j

SURROGATE PERCENT RECOVERIES

1,2-DICHLOROETHANE-D4 BFB (%) T0LUENE-D8 (%)

(%) 97 111 98

{oT-'H >>90 - ' / 77^

DHTH: Bb23 iil CALI: 8629 #2

RIC ^z2S/yi?i 12:34:06 SAMPLE: REAGENT BLANK SML CONDS.: C ^ RAHGE: G 1.. 1200 LABEL: N O. 4 . 8 QUAN: A

lOO.y-i

c o

o

n

Z CD - ' CG G V. X 0-

r\i r- V

a . I <

-- c Z UJ — X Li. cn

I—»

V 2 '_' •— i~ U

RIC

71

'6\Zl

IS i ^A •"'=

384

JiiJLs / 435

t-Or"

J L.

SCAN JC 1 TO 1200

0 J 0 BASE: U 28.. 3

753

, I

I I ^ ^ J SnK

153784.

2tIH 4L1L1

13:20 b'JL'' . '1: f-t r-l 26:40

1000 33:20

—I 1209 SCAN 40:08 TIME

PROCEDURE DATA F I L E REFERENCE NAME L I S T

REPORT

TCA DIAGNOSTIC REPORT B629 B629 VQN INITIALIZATION OPTION; 2 VQSTDS

6 / 2 9 / 8 8 13; 1 '3; 11

PROCESSING OPTION;

: STANDARDS X PLUS UNKNOWNS PROC USED POSS RMS PROC USED POSS

6 6 1 44 18 7 1 6 6 1 44 18 6 1 6 6 1 44 18 6 1

-— ><: - L I S T NAMES - : RMS STANDARD/UNKNOWN

56 VQSTDS/VQl 44 VQSTDS/VQ2 44 VQSTDS/VQ3

42 COMPOUNDS PROCESSED, 7 FOUND

COMPOUND >^ MO L I B ENTRY

1 VQ 1 2 VQ 2 3 VQ 3 4 VQ 4 5 VQ 5 6 VQ 6 7 VQ 7 8 VQ 8 9 VQ 9

10 VQ 10 11 VQ 11 12 VQ 12 13 VQ 13 ' 4 VQ 14

j VQ 15 16 VQ 16 17 VQ 17 18 VQ 18 19 VQ 19 20 VQ 2 0 21 VQ 21 22 VQ 2 2 23 VQ 23 24 VQ 24 25 VQ 25 26 VQ 26 27 VQ 27 28 VQ 28 29 VQ 29 30 VQ 30 31 VQ 31 32 VQ 32 33 VQ 33 34 VQ 34 35 VQ 35 36 VQ 36 37 VQ 37 38 VQ 38 39 VQ 39

1 VQ 40 rl VQ 41 42 VQ 42

REF - 3 0 0 - 6 0 8 - 7 5 8 - 3 8 2 - 7 2 1 - 9 0 2

- 5 4 - 8 5

- 1 0 7 - 1 3 7 - 2 0 3 - 2 2 2 - 2 5 2 - 2 8 6 - 3 2 6 - 3 4 6 - 3 6 3 - 3 8 5 - 3 8 2 - 4 2 4 - 4 3 6 - 4 3 8 - 4 5 0 - 6 8 6 - 4 9 1 - 4 9 9 - 5 1 5 - 5 3 4 - 5 3 7 - 5 3 1 - 5 3 7 - 5 7 0 - 6 1 6 - 6 3 1 - 6 7 8 - 6 8 7 - 7 2 7 - 7 6 2 - 8 2 4 - 9 4 7 - 9 8 7 - 9 5 6

PRED 3 0 2 6 1 0 7 5 9 3 8 4 7 2 2 9 0 3

5 8 8 9

1 1 1 1 4 1 2 0 6 2 2 5 2 5 5 2 8 9 3 2 9 3 4 9 3 6 6 3 8 8 3 8 4 4 2 6 4 3 8 4 4 0 4 5 2 6 8 7 4 9 3 5 0 1 5 1 7 5 3 6 5 3 9 5 3 3 5 3 9 5 7 2 6 1 7 6 3 2 6 7 9 6 8 8 7 2 8 7 6 3 8 2 5 9 4 7 9 8 7 9 5 6

- SEARCH -SEL DELTA PEAKS F I T 303 1 1 97£ 609 - 1 1 92C 759 1 995 3 8 4 7 2 2 9 0 3

2o: 7

1 997 1 9 4 t 1 97C

I 3

'

I 893

>< SAT >< PEAKS M/Z

1 2 8 1 1 4

, . 1 1 7 6 5

) 98 3 95

5 0 9 4 6 2 6 4 8 4 4 3 7 6 9 6 6 3 9 6 8 3 6 2 7 2 9 7

1 1 7 4 3 8 3 8 3 6 3 7 5

1 3 0 1 2 9

9 7 7 8 7 5 6 3

1 7 3 1 7 3

4 3 1 6 4

9 2 1 1 2 1 0 6 1 0 4 1 0 6 1 0 6

— CHRO — TOP DELTA 302 - 1 6 0 9 7 5 9 3 8 4 7 2 2 9 0 3

206 - ] 2 2 5

5 3 3

6 7 9

7 2 7

7 6 2

— —. PEAKS

L 1 1

1

Cl .

1 1

Q i j a n t i t a t i on Repor t F i l e ; B629

D.-!ta'; B629, TI OA/29/88 12;34;00

pie: REAGENT BLANK SML Conds, ; GC4 Formula; Instrument; 1050 Weight; 0.004 Submitted by: Analyst: MGB Acct. No. ;

AMOUNT=AREA * REF AMNT/<REF AREA * RESP FACT) Resp. fac. from Library Entry

No Name 1 ISl BROMOCHLOROMETHANE 2 IS2 1,4-DIFLUOROBENZENE 3 IS3 CHL0R0BENZENE-D5 4 SSI DICHL0R0ETNANE-D4 5 SS2 TOLUENE-DS 6 SS3 BROMOFLUOROBENZENE 7 45V CHLOROMETHANE 8 46V BROMOMETHANE 9 88V VINYL CHLORIDE 10 16V CHLOROETHANE 11 44V METHYLENE CHLORIDE 12 13H ACETONE 13 15H CARBON DISULFIDE 14 29V 1, l-DICHLOROETHENE 15 13V 1,1-DICHLOROETHANE 16 30V TRANS-1<2-DICHLOROETHENE •7 23V CHLOROFORM i IOV 1,2-DICHLOROETHANE

19 14H 2-BUTAANONE 20 IIV 1,1.1-TRICHLOROETHANE 21 6V CARBON TETRACHLORIDE 22 19H VINYL ACETATE 23 48V BROMODICHLOROMETHANE 24 15V 1,1,2,2-TETRACHLaROETHANE 25 32V 1,2-DICHLOROPROPANE 26 33VT TRANS-1, 3-DICHLOROPROPANE 27 87V TRICHLOROETHENE 38 51V DIBROMOCHLOROMETHANE 29 14V 1,1,2-TRICHLOROETHANE 30 4V BENZENE 31 33VC CI3-1,3-DICHLORQPROPENE 32 19V 2-CHLOROETHYL VINYL ETHER 33 47V BROMOFORM 34 4-METHYL-2-PENTAN0NE 35 16H 2-HEXANONE 36 85V TETRACHLOROETHENE 37 86V TOLUENE 38 7V CHLOROBENZENE 39 38V ETHYLBENZENE 40 18H STYRENE 41 20H TOTAL XYLENES 42 XYLENES

Nrj

1 2 "i

4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 ^9 ?

30 31 32 33 34 35 36 37 38 39 40 41 42

m/ z 128 114 117 65 98 95

NOT NOT NOT NOT 84 43

NOT NOT NOT NOT NOT NOT NOT NOT NOT NOT NOT NOT NOT NOT NOT NOT NOT 78

NOT NOT NOT NOT 43

NOT 92 112 NOT NOT NOT NOT

Scan 302 609 759 384 722 903

FOUND FOUND FOUND FOUND

206 225

FOUND FOUND FOUND FOUND FOUND FOUND FOUND FOUND FOUND FOUND FOUND FOUND FOUND FOUND FOUND FOUND FOUND

533 FOUND FOUND FOUND FOUND

679 FOUND

727 762

FOUND FOUND FOUND FOUND

Time 10: 04 20: 18 25: 18 12; 48 24: 04 30: 06

6: 52 7: 30

17; 46

22:38

24: 14 25; 24

Ref 1 2 3 1 3 3

RRT 1. 000 1. 000 1. 000 1. 272 0. 951 1, 190

Meth A BB

Area(Hght) Amount XTot

A A A A A

BB BB BB BQ QB

0. 682 A BB 0, 745 A BB

0. 875 A BB

3 0. 895 A*VV

3 0. 958 A BQ 3 1, 004 A BQ

56196, 346341. 268720. 103712. 360490, 223139,

865.

50, 000 50, 000 50, 000 97. 015 98, 203 111. 114

UG/L UG/L UG/L 7. 7. y.

10. 10, 10, 20, 21.

70 70 70 75 01

23, 77

3799, 3658,

2, 100 UG/L 7. 892 UG/L

0. 45 1. 69

/ y

0. 141 UG/L 0. 03

804,

260. 1801.

0,

0, 0,

624

064 341

UG/L

UG/L UG/L

0,

0. 0,

13

01 07

/ \ AnalyticalTechnologies, Inc GCMS - RESULTS

77/TV-^U A

TEST : VOLATILE ORGANICS (EPA 624)

ATI I.D. : 80613002

CLIENT PROJECT # PROJECT NAME CLIENT I.D.

MONTGOMERY & ASSOCIATES 661D HASSAYAMPA TRIP BLANK

SAMPLE MATRIX : AQUEOUS

DATE SAMPLED DATE RECEIVED DATE EXTRACTED DATE ANALYZED UNITS DILUTION FACTOR

06/22/88 06/23/88 N/A 06/29/88 UG/L

1

COMPOUNDS RESULTS

CHLOROMETHANE BROMOMETHANE VINYL CHLORIDE CHLOROETHANE METHYLENE CHLORIDE ACETONE CARBON DISULFIDE 1,1-DICHLOROETHENE 1,1-DICHLOROETHANE 1,2-DICHLOROETHENE (TOTAL) CHLOROFORM 1,2-DICHLOROETHANE 2-BUTANONE (MEK) 1,1,1-TRICHLOROETHANE CARBON TETRACHDDRIDE VINYL ACETATE BROMODICHLOROMETHANE 1,1,2,2-TETRACHLOROETHANE 1,2-DICHLOROPROPANE TRANS-1,3-DICHLOROPROPENE TRICHLOROETHENE DIBROMOCHLOROMETHANE 1,1,2-TRICHLOROETHANE BENZENE CIS-1,3-DICHLOROPROPENE 2-CHLOROETHYLVINYLETHER BROMOFORM 2-HEXANONE (MBK) 4-METHYL-2-PENTANONE (MIBK) TETRACHLOROETHENE TOLUENE CHLOROBENZENE ETHYL BENZENE STYRENE TOTAL XYLENES

<10 <10 <1 <1 12 B <10 <1 <1 <1 <1 <1 <1 <10 <1 <1 <10 <1 <1 <1 <1 <1 <1 <1 <1 <1 <10 <5 <10 <10. <1 <1 <1 <1 <1 <1

y

SURROGATE PERCENT RECOVERIES

l,2-DICHLOROETHANE-D4 (%) BFB (%) T0LUENE-D8 (%)

y y

100 104 y 103

D INDICATES ANALYTE ALSO FOUND IN REAGENT DLANK,

CsX-^- ynuj--7uA

kit DAIH: :50S1302 «1 Qiili=LiiLJS:3o:00 CALl: S0bl302 #2 SAMPLE: .iOF A0K!:-:0-2 TRIP BLANK 5ML CONDS. :_iLL-RANGE: G 1.1200 LPBEL: N O- 4.0 QU-r*: n 0- :.0 J

lyO. 0 1

^CANS 1 TO 1200

•J r-H-.c: • • 1 ,

118312,

\

RIC

:r c: CJ L i -

pv.

• - >

u X cr, — ":» >— ^

I )

(—

V

O Oi V

-0

1—

< Q U I Ul

'_,' W . 4

L

64

203

161,1

500

IJ\-.'J 531 ,^

301

U —-O'/;K _J L.^JlZ2..J033

V. JOU 6:40

4v30 13:20

t.yu •'0:00 - - . c . I \',

^ i Z - . •^ V

1 OOG 33:20

1209 SCAN 40:08 TIME

PROCEDURE DATA FILE REFERENCE NAME LIST

REPORT

TCA 8061302 8061302 VQN INITIALIZATION VQSTDS

DIAGNOSTIC REPORT 6/29/88 19;18;48

OPTION: 2 PROCESSING OPTION: 3

: STANDARDS — PROC USED POSS

6 6 1 6 6 1 6 6 1

X PLUS UNKNOWNS RMS PROC USED POSS 57 18 7 1 57 18 6 1 57 18 6 1

-— >< - LIST NAMES - Z RMS STANDARD/UNKNOWN 52 VQSTDS/VQl 57 VQSTDS/VQ2 57 VQSTDS/VQ3

COMPOUNDS PROCESSED, 7 FOUND

COMPOUND > NO LIB ENTRY 1 VQ 1 2 VQ 2 3 VQ 3 4 VQ - 4 5 VQ 5 6 VQ 6 7 VQ 7 8 VQ 8 9 VQ 9 10 VQ 10 11 VQ 11 12 VQ 12 13 VQ 13 14 VQ 14 15 VQ 15 16 VQ 16 17 VQ 17 18 VQ 18 19 VQ 19 20 VQ 20 21 VQ 21 22 VQ 22 23 VQ 23 24 VQ 24 25 VQ 25 26 VQ 26 27 VQ 27 28 VQ 28 29 VQ 29 30 VQ 30 31 VQ 31 32 VQ 32 33 VQ 33 34 VQ 34 35 VQ 35 36 VQ 36 37 VQ 37 38 VQ 38 39 VQ 39 40 VQ 40 41 VQ 41 42 VQ 42

REF -300 -608 -758 -382 -721 -902 -54 -85

-107 -137 -203 -222 -252 -286 -326 -346 -363 -385 -382 -424 -436 -438 -450 -686 -491 -499 -515 -534 -537 -531 -537 -570 -616 -631 -678 -687 -727 -762 -824 -947 -987 -956

PRED 300 608 758 382 721 902 54 85 107 137 203 222 252 286 326 346 363 385 382 424 436 438 450 686 491 499 515 534 537 531 537 570 616 631 678 687 727 762 824 947 987 956

— SEARCH >< SAT >< SEL DELTA PEAKS FIT PEAKS M/Z 300 608 758 381 -1 721 901 -1

203

I 97 i I 92; I 99; I 99E I 99-I 97

1 99"

3 . 1 2 8 3 114 ^ 117 3 65 7 98 I 95

50 94 62 64

7 B4 43 76 96 63 96 83 62 72 97 117 43 83 83 63 75 130 129-97 78 75 63 173 173 43 164 92 112 106 104 106 106

CHRO TOP DELTA PEAKS 299 -] 608 758 381 721 902

203 221

53 1

/

L 1

I 1

1 1

1

Quantitation Report File; 8061302

Data; 8061302. TI 06/29/88 18:38:00

mple: JOB 806130-2 -nds. ; GC4

Formula: Submitted by;

TRIP BLANK SML

Instrument; 1050 Analyst: MGB

Weight; Acct, No,

0. 004

AMOUNT=AREA * REF AMNT/(REF AREA » RESP FACT) Resp, fac. from Library Entry

No 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 3

19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42

Name ISl IS2 IS3 SSI SS2 SS3 45V 46V 88V 16V 44V 13H 15H 29V 13V 30V 23V IOV 14H IIV 6V 19H 48V 15V 32V 33VT 87V 51V 14V 4V

33VC 19V 47V

BROMOCHLOROMETHANE 1, 4-DIFLUOROBENZENE CHL0R0BENZENE-D5 DICHL0R0ETNANE-D4 TOLUENE-DS BROMOFLUOROBENZENE CHLOROMETHANE BROMOMETHANE VINYL CHLORIDE CHLOROETHANE METHYLENE CHLORIDE ACETONE CARBON DISULFIDE 1,1-DICHLOROETHENE 1.1-DICHLOROETHANE TRANS-1,2-DICHLOROETHENE CHLOROFORM 1,2-DICHLOROETHANE 2-BUTAANONE 1,1,1-TRICHLOROETHANE CARBON TETRACHLORIDE VINYL ACETATE BROMODICHLOROMETHANE 1.1.2,2-TETRACHLOROETHANE 1,2-DICHLOROPROPANE TRANS-1, 3-DICHLOROPROPANE TRICHLOROETHENE DIBROMOCHLOROMETHANE 1,1,2-TRICHLOROETHANE BENZENE CIS-1,S-DICHLOROPROPENE 2-CHLOROETHYL VINYL ETHER BROMOFORM

4-METHYL-2-PENTAN0NE 16H 85V a6V 7V

38V 18H 20H

2-HEXANONE TETRACHLOROETHENE TOLUENE CHLOROBENZENE ETHYLBENZENE STYRENE TOTAL XYLENES

XYLENES

A ^ -

No m / z S c a n T i m e R e f RRT M e t h A r e a ( H g h t ) A m o u n t / . T o t 1 128 299 9:58 1 1.000 A BB 46021, 50.000 UG/L 10,46 2 114 608 20 :16 2 1.000 A BB 224472 50.000 UG/L 10.46 1 117 758 25:16 3 1.000 A BB 152827, 50.000 UG/L 10,46 4 65 381 12:42 1 1.274 A BB 87586. 100.044 '/. 20 .92 , 5 98 721 24:02 3 0.951 A BB 215238. 103.098 7. 2 1 . 5 6 ^ 6 95 902 30:04 3 1.190 A BB 119282. 104.440 /. 2 i . Q A y 7 NOT FOUND 8 NOT FOUND 9 NOT FOUND

10 NOT FOUND 11 84 203 6:46 1 0,679 A BB 17783, 12.002 UG/L 2.51 12 43 221 7:22 1 0,739 A BB 3252, 8.568 UG/L 1 79 13 NOT FOUND 14 NOT FOUND 15 NOT FOUND 16 NOT FOUND 17 NOT FOUND 18 NOT FOUND 19 NOT FOUND 20 NOT FOUND 21 NOT FOUND 22 NOT FOUND 23 NOT FOUND 24 NOT FOUND 25 NOT FOUND 26 NOT FOUND 27 NOT FOUND ''8 NOT FOUND ? NOT FOUND

30 78 531 17:42 2 0.873 A QB 476. 0.120 UG/L 0.03/,.. 31 NOT FOUND 32 NOT FOUND 33 NOT FOUND 34 NOT FOUND 35 NOT FOUND 36 NOT FOUND 37 NOT FOUND 38 NOT FOUND 39 NOT FOUND 40 NOT FOUND 41 NOT FOUND 42 NOT FOUND

.,Z

7 ^ AnalyticalTechnologies, Inc

GCMS - RESULTS

REAGENT BLANK

TEST : SEMI-VOLATILE ORGANICS (EPA 625)

CLIENT : MONTGOMERY & ASSOCIATES PROJECT # : 661D PROJECT NAME : HASSAYAMPA CLIENT I.D. : REAGENT BLANK

Th/u-'AUA

ATI I.D. DATE EXTRACTED DATE ANALYZED UNITS DILUTION FACTOR

806130 06/29/88 08/01/88 UG/L N/A

COMPOUNDS RESULTS

N-NITROSODIMETHYLAMINE PHENOL ANILINE BIS(2-CHLOROETHYL)ETHER 2-CHLOROPHENOL 1,3-DICHLOROBENZENE 1,4-DICHLOROBENZENE BENZYL ALCOHOL 1,2-DICHLOROBENZENE 2-METHYLPHENOL BIS(2-CHLOROISOPROPYL)ETHER 4-METHYLPHENOL N-NITROSO-DI-N-PROPYLAMINE HEXACHLOROETHANE NITROBENZENE ISOPHORONE 2-NITROPHENOL 2,4-DIMETHYLPHENOL BENZOIC ACID BIS(2-CHLOROETHOXY)METHANE 2,4-DICHLOROPHENOL 1,2,4-TRICHLOROBENZENE NAPHTHALENE 4-CHLOROANILINE HEXACHLOROBUTADIENE 4-CHLORO-3-METHYLPHENOL 2-METHYLNAPHTHALENE HEXACHLOROCYCLOPENTADIENE 2,4,6-TRICHLOROPHENOL 2,4,5-TRICHLOROPHENOL 2-CH LORONAPHTHALENE 2-NITROANILINE DIMETHYLPHTHALATE ACENAPHTHYLENE 3-NITROANILINE ACENAPHTHENE 2,4-DINITROPHENOL 4-NITROPHENOL DIBENZOFURAN 2,4-DINITROTOLUENE 2,6-DINITROTOLUENE DIETHY LPHTHALATE 4-CHLOROPHENYL-PHENYLETHER

<10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <50 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <50 <10 <50 <10 <10 <50 <10 <50 <50 <10 <10 <10 <10 <10

(CONTINUED NEXT PAGE)

/ \ AnalyticalTechnologies, Inc GCMS - RESULTS

REAGENT BLANK ATI I.D.

'- 77UA''7/ A^

806130

TEST : SEMI-VOLATILE ORGANICS (EPA 625)

COMPOUNDS RESULTS

FLUORENE 4-NITROANILINE 4,6-DINITRO-2-METHYLPHENOL N-NITROSODIPHENYLAMINE 4-BROMOPHENYL-PHENYLETHER HEXACHLOROBENZENE PENTACHLOROPHENOL PHENANTHRENE ANTHRACENE DI-N-BUTYLPHTHALATE FLUORANTHENE BENZIDINE PYRENE BUTYLBENZYLPHTHALATE 3,3'-DICHLOROBENZIDINE BENZO(a)ANTHRACENE BIS(2-ETHYLHEXYL)PHTHALATE CHRYSENE DI-N-ETHYLPHTHALATE BENZO(b)FLUORANTHENE BENZO(k)FLUORANTHENE BENZO(a)PYRENE INDENO(1,2,3-cd)PYRENE DIBENZO(a,h)ANTHRACENE BENZO(g,h,i)PERYLENE

<10 <50 <50 <10 <10 <10 <50 <10 <10 10 <10 <100 <10 <10 <20 <10 TR <10 <10 <10 <10 <10 <10 <10 <10

SURROGATE PERCENT RECOVERIES

NITR0BENZENE-D5 (%) 2-FLUOROBIPHENYL (%) TERPHENYL (%) PHEN0L-D5 (%) 2-FLUOROPHENOL (%) 2,4,6-TRIBROMOPHENOL (%)

77 84 82 85 98 108

^M b^^

RIC 08/01/88 0:25:00 , . ^ A SAiiPi:Er"^o^/:n5'^ \7/7kl CO»DS.! IUL lL->2XiriL RANGE: G 1,2600 LABEL: N 0,

'S07s\ 3o

An/jJ-^u/ i DATA: 88I13B2495 #2213 SCANS 300 TO 2600 CALI: 88M3B2495 «2

4.0 QUAN: A 0, 1.0 J 0 BASE: U 20, 3

100.0-1 162048.

RIC

L^N^ jLk.

1000 r-1500 7^'.m

"• I'' \ J-. .<•»»«'

I 2000 33:20

— I 2500 41:40

SCAN TIME

PROCEDURE DATA FILE REFERENCE NAME LIST

REPORT

y r^^-

<. — — — PROC

2 2 2 2 2

. 2 2 2 1

TCA 88M3B2495 aaM3B2493

DIAGNOSTIC

> f^/ff '1 Kl INITIALIZATION XI

a 1 n i -*uryr^ua USED POSS

2 1 2 1 2 1 2 1 2 1 2 1 2 1 2 1 4 0

^ . M V,rf^

— ^% RMS

0 0 0 0 0 0 0 0 0

r \

C^aj OPTION:

1 if^ 1 ikii

REPORT 8/0

2 PROCESSING OPTION: 3

— P L w a ui''(rM'<ij¥iii' a PROC

11 9 9 9 12 12 11 10 7

USED 2 4 2 3 2 4 3 4 0

POSS I 3 1 2 1 1 1 1 1

_ ^ ^ V >- 1 T C ^ klAhtf^f? _ — >>v. — uxai •''"nc.a — RMS

0 838

0 230

0 317 182 243

0

STANDARD/UNKNOWN Xl/Zl Xl/ZA X2/Z2 X2/ZB X3/Z3 X3/ZC X4/Z4 XS/Z3 X6/Z6

1:09: 29

ao COMPOUNDS PROCESSED. 14 FOUND

< COMPOUND >< NO LIB ENTRY REF 1 SV 1 -644 2 SV 2 -866 3 SV 14 -239 4 SV 13 -613 3 SV 16 -600 6 SV 17 -617 7 SV 18 -613 8 SV 19 -637 9 SV 20 -647 10 SV 21 -680 11 SV 22 -677 12 SV 7 -611 13 SV 8 -449 14 SV 23 -710 15 SV 24 -710 16 SV 25 -737 17 SV 26 -734 18 SV 27 -729 19 SV 3 -1189 20 SV 28 -748 21 SV 29 -793 22 SV 30 -303 23 SV 31 -828 24 SV 32 -867 25 SV 33 -343 26 SV 34 -849 27 SV 9 -743 28 SV 33 -361 29 SV 36 -869 30 SV 37 -902 31 SV 38 -910 32 SV 39 -988 33 SV 40 -996 34 SV 4 -1461 35 SV 41 -1041 36 SV 42 -1037 37 SV 43 -1063 38 SV 44 -1083 39 SV 45 -1114 40 SV 46 -1164 41 SV 47 -1158 42 SV 48 -1114 43 SV 49 -1195

PRED 641 863 236 610 397 614 612 634 644 677 674 617 462 713 713 739 736 731 1186 743 790 802 823 864 840 846 743 860 868 901 909 986 994 1439 1037 1034 1060 lOBO llll 1161 1133 llll 1192

— SEARCH X SAT >< SEL DELTA PEAKS FIT PEAKS M/Z 641 863

626 9 461 -1

1186

746 1

1439

I 988 I 913

1 996 3 932

, , . .

1 996

, , . , .

2 987 , , . , .

, , 1 941 , ,

,

.

, ,

132 136 42 94 93 93 128 146 146 108 146 99 112 108 43 108 70 117 164 77 82 139 122 122 93 162 82 180 128 127 223 107 142 188 237 196 196 162 63 163 132 138 153

CHRO TOP DELTA PEAKS 641 1 863 1

• • >

624 -2 1 461 1

• • • • • • • • •

• .

1186 1 • • • • •

• B •

• • • • • • • * • • • • • >

746 1 •

• • • • - . • • .

• • • .

• • 1460 1 1

• •

• •

• .

•

. • *

.

V4 \-5' \ 6 \ 7 \Q \ 9 30 51 52 53 54 55 56 57 58 59 60 61 62 63 64 65 66 67 68 69 70 71 72 73 74 75 76 77 78 79 80

SV SV SV SV SV SV SV SV SV SV SV SV SV SV

sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv

50 -1210 10 -1073 11 -1337 51 -1235 52 -1225 53 -1241 54 -1171 35 -1299 36 -1298 57 -1289 58 -1310 5 -1962

59 -1315 60 -1323 61 -1387 62 -1407 63 -1444 64 -1465 65 -1474 66 -1609 67 -1689 6 -2211 12 -1776 68 -1776 69 -1728 70 -1887 71 -1967 72 -1959 73 -2010 74 -1967 75 -2121 76 -2151 77 -2155 78 -2202 79 -2393 80 -2401 81 -2443

1207 1072 1336 1234 1224 1240 1170 1298 1297 1268 1309 1961 1312 1320 1384 1404 1441 1462 1471 1606 1687 2213 1773 1773 1725 1885 1966 1957 2009 1966 2121 2151 2155 2202 2393 2401 2443

.

1072 1340 ^

1961

1605 ,

2213 1774

, , , .

2006 .

, , , , , .

1 996 \ 1 973

• •

< . •

•

1 919

. ,

, , , , , , ,

1 1 993 ,

1 930 1 1 983

,

t • •

, , ,

, . •

3 1 990 .

• • •

• • • • •

• •

> • •

184 172 330 139 168 89 165 149 204 166 138 240 198 169 248 284 266 178 178 149 202 264 244 184 202 149 252 228 149 228 149 252 232 232 276 278 276

1072 1339 -]

. , ,

, ,

, , , , ,

1961 , , , , , , ,

1605 ,

2213 1774

, , , . .

2006 , , , , , , , ,

.

1 L 1

1

1 ,

1 1

1

•

l u a n t i t a t i o n R e p a r t File: 88M3B2493

l a t a : a0M3B2495. TI ) 8 / 0 1 / a 8 0 : 2 5 : 0 0 ^ ^ Jatnple: ^ T - l ^ ^ - f C A 6 J ;onds. : IUL 1L->2X1ML i t a n d a r d ID: 2-BNA-7-1A J e n s i t i v i t y ID: 2491

I n s t r u i n e n t : 5100 A n a l y s t : RJT I n s t C a l i :

>MOUNT=AREA • REF AMNT/(REF AREA • RESP FACT) Jesp. f a c . f rom L i b r a r y E n t r y NO 1 2 3 4 3 6 7. 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24

No 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24

NAME ISl IS2 I S3 IS4 ISS IS6 SS2 SSI SS3 SS4 SSS SS6 688 66B

1. 4-DICHL0R0BENZENE-D4 NAPHTHALENE--D8 (SV#2) ACENAPHTHENE-DIC PHENANTHRENE-DIC

(SV#1)

\ (SV#3) > (SV#4)

CHRYSENE-D12 (SV#3) PERYLENE-D12 (SV#6> PHENOL-DS (SV#73 1

2-FLUaROPHENaL (SV#8) NITROBENZENE-DS (SV#9) /

2-FLUOROBIPHENYL (SV#10) 2.4. 6-TRIBROMOPHENOL (SV#11) TERPHENYL-D14 (SV#12) DI-N -BUTYL PHTHALATE (SV#66) BIS(2-ETHYLHeXYL)PHTHALATE (SV#73)

CYCLOHEXENE UNKNOWN PHENOL, 2-UNKNOWN D4-1

FLUORO-

.4-DICHLOROBENZENE (INT. D8-NAPHTHALENE (INT. STD. ) DIO-DIO-D12-D12-

m/z 152 136 164 188 240 264 99 112 82 172 330 244 149 149 RIC RIC RIC RIC RIC RIC RIC RIC RIC RIC

ACENAPTHENE (INT. STD. ) PHENANTHRENE ' CHRYSENE (INT. PERYLENE (INT.

Scan 641 863 1186 1460 1961 2213 624 461 746 1072 1339 1774 1605 2006 174 393 446 2169 641 863 1186 1460 1961 2213

Time 10:41 14:23 19:46 24: 20 32:41 36: S3 10:24 7:41 12:26 17: 32 22: 19 29: 34 26:43 33:26 2: 54 6: 33 7: 26

36:09 10: 41 14: 23 19: 46 24: 20 32:41 36; 53

(INT. STD. STD.

Ref

d) 3 4 3 6 1

^ 3 3 5 4 5

22 22 22 22 19 20 21 22 23 24

STD. ) ) )

RRT 1. 000 1. 000 1. 000 1, OOO 1. 000 1. 000 0.973 0.719 0. 864 0. 904 1. 129 0. 903 1.099 1. 023 0. 119 0. 269 0, 303 1, 486 1. 000 1. 000 1. 000 1. 000 1. 000 1. 000

STD. )

M« A A A A A A A A A A A A A A A A A A A A A A A A

• th BB BB BB BB BB BB BV VB BB BB BB BB BB BB BB BB BB BB VB BB BV BB BB BB

A r e a ( H g h t ) 29659. 124200. _ '97338. 202101. 149890. 116543. 10530. 2186.

33123^

mos4. 16661.

147977. 29849. 14489.

293242. 32632. 36352. 7761.

204303. 246476. 412322. 513708. 433213. 330115.

Ainount 40. 40. 40. 40. 40. 40. 14. 6.

39. 31. 33. 31. 3. 4.

000 000 000 000 000 000 122 564 761 175 880 662 178 114

NG/UL NG/UL NG/UL NG/UL NG/UL NG/UL NO/UL NO/UL NG/UL NO/UL NO/UL NO/UL NO/UL NO/UL

36. 962^ 6. 7. 1.

40. 40. 40. 40. 40. 40.

328 049 505 000 000 000 000 000 000

UO/L UO/L UG/L UG/L UO/L UG/L

7.Tot 4. 4. 4. 4. 4. 4. 1. 0. 4. 5. 6. 6. 0. 0. 6. 0. 0. 0. 4. 4. 4. 4. 4. 4.

66 66 66 66 66 66 64 76 63 96 27 01 60 48 62 74 82 18 66 66 66 66 66 66

A / j , ! ^ AnalyticalTechnologies, Inc

GAS CHROMATOGRAPHY - RESULTS

REAGENT BLANK

TEST : ORGANOCHLORINE PESTICIDES AND PCB'S (EPA 608)

777 TJ-777 7

CLIENT PROJECT # PROJECT NAME CLIENT I.D.

MONTGOMERY & ASSOCIATES 661D HASSAYAMPA REAGENT BLANK

ATI I.D. : DATE EXTRACTED : DATE ANALYZED UNITS DILUTION FACTOR

806130 06/30/88 07/13/88 UG/L

: N/A

COMPOUNDS RESULTS

ALDRIN ALPHA BHC BETA BHC GAMMA BHC (LINDANE) DELTA BHC CHLORDANE 4,4'-DDD 4,4'-DDE 4,4'-DDT DIELDRIN ENDOSULFAN I ENDOSULFAN II ENDOSULFAN SULFATE ENDRIN JNDRIN ALDEHYDE HEPTACHLOR HEPTACHLOR EPOXIDE METHOXYCHLOR TOXAPHENE AROCLOR 1016 AROCLOR 1221 AROCLOR 1232 AROCLOR 124 2 AROCLOR 1248 AROCLOR 1254 AROCLOR 1260

< 0 . 0 5 < 0 . 0 5 < 0 . 0 5 < 0 . 0 5 < 0 . 0 5 < 0 . 5 < 0 . 1 < 0 . 1 < 0 . 1 < 0 . 1 < 0 . 0 5 < 0 . 1 < 0 . 1 < 0 . 1 < 0 . 1 < 0 . 0 5 < 0 . 0 5 < 0 . 5 < 1 . 0 < 0 . 5 < 0 . 5 < 0 . 5 < 0 . 5 < 0 . 5 < 1 . 0 < 1 . 0

SURROGATE PERCENT RECOVERIES

ISODRIN % 99

DE':: "CCitlF I RMATORY COLUMN

CHART SPEED 0.6 CM/MIN ATTEN: 16 ZERO: 10% 1 MIN/TICK

-STAT~T INJECT

0. 903

'2.171 2.627

= ^ ^ ^

~^R:OFF

3.474

8. 890 -A BHCT 9.66 1

, B BKec. 1 1 . 258 11.694

ATTEN: 32 ZERO: 5% 1 MIN/TICK

'- - R E P I ^ P X M . 9 4 4 ^ 1 5 . 4 8 3

' ENDe-Zl 1 6 . 0 7 0 -DDE:^ 16.858

17.721 , 18.214

^ _IiDD=} 18. 686

! _D.DT—i^ 19.607 ' END0-B04 20.306

' METHej«;Y 22.401 )

~" 24.285 24.922

— —I 25.802

^ - ^ . 2 1 2

=• 14.539

TITLE: P E S T I C I D E S - ^ ^ ^ G./50

CHANNEL NO: 2 SAMPLE: 9

20:21 13 JUL 88

METHOD: DB608

>\^^J-*1UA

TITLE

CHANh

PEAK NO

1 2 3 4 5 6 7 8 9 10 1 1 12 13 14 15 16 17 18 19 20 1 2

23 24 25 26 27 28 29

: PESTICIDES

EL NO: 2

PEAK NAME

A BHC LINDANE B BHC

HEPTACHLO D-BHC

ALDRIN ISODRIN HEPT EPX

ENDO I DDE DIELDRIN

ENDRIN DDD ENDO I I DDT ENDRIN AL ENDO S04 METHOXY END KETON

TOTALS:

g / < ^ Use

SAMPLE: 9

RESULT UG/ML 0 . 0000 0.0000 0.0017 0.0022 0.001 1 0,0000 0.0012 0,0019 0 . 0000 0.0000 0.0029 /

98.8270 "• 0.0026 0.0000 0.00 1 0 0,0014 0.0018 0,0000 0,0000 0,0030 0,0006 0,00 1 0 0,0017 0,0021 0,0015 0,0061 0,0020 0,0000 0,0000

98,8628

TIME CMIN) 7,835 8. 185 9.661 10.992 1 1 ,258 1 1 .694 12.029 12.471 12,899 13.123 13.196 14.539 14.944 15.483 16.070 16.858 17.068 17.721 18.136 18.214 18.686 18.864 19.607 19.910 20.306 22.401 22.699 24.285 24.922

20:

METHOD

TIME OFFSET

-0,069 -0,068 -0,062

-0,071 -0,069

0.016 -0,121 -0,096

-0,090 -0,082 -0,082

-0,106 -0,064 -0,056 -0.083 -0.080 -0.064 -0.079 -0,091

-1,417

21 13

: DB608

AREA COUNTS

686 808

3340 4130 1770 5290 1968 3505 1755 5325 5251

349212 3808 3887 1512 2053 2657 3156 2444 1406 668 1372 1790 2746 2226 1406 2968 574

9106

426819

JUL 88

SEP CODE BV VB BB BV VV VV VB BB BV VV VB BV VV VV VB BV VB BV VV VV VV VB BV VV VB BV VB BV VB

&'*

?

? ?

?

? ? ? ? ?

? ?

Wl/2 CSEC) 7,65 6,10 6,75 7.05 6, 45 7.65 7.35 6,05 7,20 10,40 2.65 7,80

10, 15 9,70 7, 00 7,55 7. 80 8. 60

13, 60

14. 00 9, 90 7, 90 8, 10 1 1 .20 6.70 7.55 13.60 41 ,65

DETECTED PKS: 55 REJECTED PKS: 26

DIVISOR: 1,00000 MULTIPLIER: 1,00000

NOISE: 8.5 OFFSET: 19

RACK: 16 VIAL: 1 INJ: 1

NOTES: DB608 PRIMARY COLUMN

TITLE: PESTICIDE CONFIRMATORY

CHANNEL NO: 1 SAMPLE: SAME

PEAK PEAK NO NAME

RESULT UG/ML

20:21 13 JUL 88

METHOD: DBS

TIME CMIN)

TIME OFFSET

AREA COUNTS

SEP CODE

Wl/2 CSEC)

TITLE : PESTICIDE

CHANNEL NO: 1

PEAK NO

1

2 3 4 5 6 7 8

PEAK NAME

LINDANE D-BHC

ALDRIN

TOTALS:

CONFIRMATORY

SAMPLE:

RESULT UG/ML J _ Q-yc i i ^

1 .7247 2.5303 2.0686 1.8830 3.4014 3.4640

82.9491

100.0000

SAME

TIME CMIN) O .ttr 1

10,659 1 1 ,356 12.094 12,720 13.109 14,075 14,999

20:

METHOD

TIME OFFSET

0.116 0, 174

-0.225

0,065

21 13

: DBS

AREA COUNTS

7175 6253 9174 7500 6827 12332 12559

300741

362561

JUL 88

SEP CODE BS BB BB BB BV VB BB BB

Wl/2 CSEC) 6. 25 5,65 6,80 7,35

? 6,05 6.75 7.50 9,80

REJECTED PKS; DETECTED PKS: 26

MULTIPLIER: 1,00000

NOISE: 71.6 OFFSET: -20

RACK: 16 VIAL: 1 INJ: 1

NOTES: DBS CONFIRMATORY COLUMN

18

CHART SPEED 0,6 CM/MIN (ATTEN: 16 ZERO: \e% 1 MIN/TICK

-STAT" INJECT

==?^ ^7.'\^7 -zAzz---'-= C : 3.697 ^ ^ ^ . - A . 266

— -—1^ 4,938 __ =? 5,5-;7i SR:OFF

7. 845

DAhfE 1 1 . 004 11.717

1 14

ezzB. ALDR^M" 13.

" — ' — L 4 ,

0,918

ATTEN: 32 ZERO: 5% 1 MIN/TICK

_ISODR:

' 1 5 , 4 8 8 PENDe-Zl 1 5 . 9 2 2

" 1 4 , 5 5 2 .

~ S R : O K T '

r

3 . 2 2 5

1 5 . 0 0 9