A /j}^ AnolylicolTechnologies, Inc/^ -ZU7) A /j} ^ AnolylicolTechnologies, Inc GCMS - RESULTS REAGENT BLANK TEST : VOLATILE ORGANICS tr'i i^7H SFUND RECORDS CTR 0222-00710 AR0565 CLIENT

^ / ^ -ZU7)

A / j } ^ AnolylicolTechnologies, Inc

GCMS - RESULTS

REAGENT BLANK

TEST : VOLATILE ORGANICS tr'i i 7H

SFUND RECORDS CTR

0222-00710 AR0565

CLIENT PROJECT \ PROJECT NAME CLIENT I.D.

MONTGOMERY & ASSOCIATES 661-D HASSAYAMPA REAGENT BLANK

SFUND RECORDS CTR

88015263

ATI I.D. DATE EXTRACTED DATE ANALYZED UNITS DILUTION FACTOR

806047 06/15/88 06/15/88 UG/L N/A

COMPOUNDS RESULTS

CHLOROMETHANE BROMOMETHANE VINYL CHLORIDE CHLOROETHANE METHYLENE CHLORIDE ACETONE CARBON DISULFIDE 1,1-DICHLOROETHENE 1,1-DICHLOROETHANE TRANS-1,2-DICHLOROETHENE CHLOROFORM 1,2-DICHLOROETHANE 2-BUTANONE (MEK) 1,1,1-TRICHLOROETHANE CARBON TETRACHLORIDE VINYL ACETATE BROMODICHLOROMETHANE 1,1,2,2-TETRACHLOROETHANE 1,2-DICHLOROPROPANE TRANS-1,3-DICHLOROPROPENE TRICHLOROETHENE DIBROMOCHLOROMETHANE 1,1,2-TRICHLORETHANE BENZENE CIS-1,3-DICHLOROPROPENE 2-CHLOROETHYLVINYLETHER BROMOFORM 2-HEXANONE (MBK) 4-METHYL-2-PENTANONE (MIBK) TETRACHLOROETHENE TOLUENE CHLOROBENZENE ETHYL BENZENE STYRENE TOTAL XYLENES

SURROGATE PERCENT RECOVERIES

l,2-DICHLOROETHANE-D4 (%) BFB (%) T0LUENE-D8 (%)

<10 <10 <1 <1 5 15 <1 <1 <1 <1 <1 <1 <10 <1 <1 <10 <1 <1 <1 <1 <1 <1 <1 <1 <1 <10 <5 <10 <10 <1 <1 <1 <1 <1 <1

92 106 103

'.Oyx^ti.'-s~0 V- Z r i G . ' i ^ '^ '^ r / i

-^dt--ir^tU-:^.iî-A 7.0i'-l'.17.^1}

l"> l i S S ' s

2-J Cn)ro-ft-.oJTto a.rQ,.'v\s

'''7 VZs cZ/fii:.. -O-nr VAZ)

9 > Z i - /n/xj-TL/y.^

DHTH: BSl5 *1 CHLI: B615 #2

iLHHb

--.^;!;I^: 1.1400 LhBEL: N 0. 4.0 QUAH: H 9, 1.9 J 8 BH5E: U 20..

100.?-

1200

801792.

"0

n

i I : f

J i

Q ru z u o LL

O « - i

a

00 00 >^ tti r - t

" V

<l . .

u \-X cn i « «

z t - t

ML

<

Q U r in » - l

< Z o 1-4

H- LL

11

l!

11

\"\

n 1 1

i i

j j t

V -"Vl

131 --AJ T 200 G:4fi

644

41? .1

LJ \ 453 551

400 13:20

600 20:30

758

38

J ^ l yye

2b: 40

SSi

972

1034 I

1000 33:20

1168 — I 1288 SCA1>I 40:80 TIME

No

6 7

8 i ' t

lO 11 12 13 14 15 16 17 13 19 20 21 22 23 24 25 26 27

r-! 30 31 32 33 34 35 36 37 38 39 40 il 42

m/z

128 114 !. :i 7

t 'O

98 9S

NOT NOT NOT NOT 84 43

NOT NOT NOT NOT NOT NOT NOT NOT NOT NOT NOT NOT NOT NOT 130 NOT NOT 78

NOT NOT NOT NOT NOT NOT NOT NOT NOT 104 NOT NOT

Scan

334 64^ 793 A 1 7 700-<V72

FOUND FOUND FOUND FOUND

239 254

FOUND FOUND FOUND FOUND FOUND' FOUND FOUND FOUND FOUND FOUND FOUND FOUND FOUND FOUND

551 FOUND FOUND

568 FOUND

FOUND FOUND FOUND; FOUND FOUND FOUND FOUND FOUND 1030

FOUND FOUND

Time

11: 08 28 36 OA 16 2 A

21 2 h VO -~\ c--: r-J. -w'

32

7: 58 8:28

18: 56

't

m: oôt

Ref

1 1 2 J 3 1

34: 20

i

3 3

0 1,

RRT

000 000 OOC' . - . - ; ' 1 '•>'

7:>0 ;i'U3

0. 716 0, 760

Meth A BB

RB Bl'?

Ul-; BI3

M

A

A

A A

BB BV

18: 22 2 0. 856 A BB

2 0. 882 A BB

A BB

Area(Hqht)

il33PS.

bOC

64,?.'..; 2924/ J

Amount

50, 000 SO. 000

1.02 ('"'V OS. ^ A 2

UG/L 1 0 0 / [ . 1

7.Tot

0. 58 O "••.;-;

25504,

13887. 5. 098

IS, 465 UG/L UG/L

.i. o e 3. 2 7 y

3866.

1984.

0.831 UG/L

0,164 UG/L

0 18

0 03

A Cz

13 13, O: 139 UG/L 0 nn J ^

Ouantitation Report F i l e : B 6 1 5

D a t a : B 6 1 5 , T I ; : v . / . I S / 8 8 2 0 ; ' 4 9 ; 0 0

U i l e ; RfAQENT BLANK WATFT r-ML ••„•'.I');,i";; G C 4 r (.' r (Tl i.l 1 a ;

:-:(.ibmi t t e d b y ; I n Si tT-ume fit lOS*.' A n a l q s t ; MGB

We;iyf A crt.

; ) ( " ) • •

No.

A.MCnNT=AREA *. REF AMNT/<REF AREA * RESP FACT) Rebp. fac. from Library Entry

No 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 7

.3 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42

Name ISl IS2 133 SSI SS2 333 4SV 46V BBV 16V 44V 13H 15H 29V 13V BOV 23V IOV 14H IIV 6V 19H 48V 15V 32V 33VT 87V 51V 14V 4V

33VC 19V 47V 17H 16H 85V 86V 7V BBV IBH 20H

BROMOCHLOROMETHANE 1, 4-DIFLUOROBENZENE CHL0R0BENZENE-D5 DICHL0R0ETNANE-D4 TOLUENE-DS BROMOFLUOROBENZENE CHLOROMETHANE BROMOMETHANE VINYL CHLORIDE CHLOROETHANE METHYLENE CHLORIDE ACETONE CARBON DISULFIDE 1,1-DICHLOROETHENE 1,1-DICHLOROETHANE TRANS-1, 2-DICHLOROETHENE CHLOROFORM 1,2-DICHLOROETHANE 2-BUTAANONE 1, 1, 1-TRICHLOROETHANE CARBON TETRACHLORIDE VINYL ACETATE BROMODICHLOROMETHANE 1,1,2, 2-TETRACHLOROETHANE 1,2-DICHLOROPROPANE TRANS-1,3-DICHLQRaPRQPANE TRICHLOROETHENE DIBROMOCHLOROMETHANE 1,1,2-TRICHLOROETHANE BENZENE CIS-1.3-DICHLOROPROPENE 2-CHLOROETHYL VINYL ETHER BROMOFORM 4-METHYL-2-PENTANaNE 2-HEXANONE TETRACHLOROETHENE TOLUENE CHLOROBENZENE ETHYLBENZENE STYRENE TOTAL XYLENES

XYLENES

PROCEDURE DATA FILE REFERENCE NMME LIST

TCA B615 B615 VQN

ftFI'OPT. VGGTUS

- SIANDARDS --PROC USED POSS

6 6 1 6 b 1

6 6 1

DIAGNOSTIC REPORT

I NIT IAL. I ZATION OPTION; 2

•;;• :

RMS 86 86 86

: Pi..US UNKNfJWIvjS PROC USED P0S3

IB B 1 13 7 1 IB 7 2

FRLif'T

;-.

RHS 94 78

239

6/15/32

SSJHQ OPT.! ON; 3

2 - Li:f-;T Nr M!-::; - >. STANDARD/UNKNOWN VQSTDS/VQl VQSTDS/VQ2 VQSTDS/VQ3

21; 2-b: 33

42 COMPOUNDS PROCESSED, 10 FOUND

COMPOUND > NO LIB 1 VQ 2 VQ 3 VQ 4 VQ 5 VQ 6 VQ 7 VQ 8 VQ 9 VQ 10 VQ 11 VQ 12 VQ 13 VQ M VQ 5 VQ 16 VQ 17 VQ 18 VQ 19 VQ 20 VQ 21 VQ 22 VQ 23 VQ 24 VQ 25 VQ 26 VQ 2.7 VQ

28 VQ 29 VQ 30 VQ 31 VQ 32 VQ 33 VQ 34 .VQ 35 VQ 36 VQ 37 VQ 38 VQ 39 VQ 0 VQ

41 VQ 42 VQ

ENTRY 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 IB 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42

< REF

-336 -647 -801 -419 -761 -978 -65

-105 -131 -167 -238 -255 -287 -322 -362 -382 -400 -422 -419 -463 -475 -475 -489 -726 -531 -538 --554 -574 -576 -570 -576 -561 -656 -671 -718 -726 -767 -806 -880

-1034 -1086 -1046

PRED 334 644 797 417 757 973 66 106 132 167 238 255 287 321 361 381 399 421 417 461 473 473 487 722 528 535 551 571 573 , 567 574 559 654 669 715 723 764 803 877 1030 1082 1042

-- SEARCH • X SAT >< SEL DELTA PEAKS FIT PEAKS M/Z 334 644 793 417 758 972

,

239 255

551

720

I

1 I

1

5

I 952 I 926 ) 993 I 995 1 999 1 992

1 990 1 913

1 991

1

2 925

'

128 114 117 65 98 95 50 94 62 64 34 43 76 96 63 96 83 62 72 97

, 117 43 83 83 63 7S 130 129 97 78 75 63 173 43 43 164 92 112 106 104 106

. • 106

- — CHRO -TOP DELTA rEAK,3 334 644 793 417 753 972

239 254

0 \ j l

568

1030

1 1

1 1

/ \ AnolyticalTechnologies, Inc

GCMS - RESULTS

TEST : VOLATILE ORGANICS Bf otH

'7r)u/-zu7\

ATI I.D. : 80604703

CLIENT PROJECT # PROJECT NAME CLIENT I.D. SAMPLE MATRIX

MONTGOMERY & ASSOCIATES 661-D HASSAYAMPA TRIP BLANK AQUEOUS

DATE SAMPLED DATE RECEIVED DATE EXTRACTED DATE ANALYZED UNITS DILUTION FACTOR

06/09/88 06/10/88 N/A 06/15/88 UG/L

1

COMPOUNDS RESULTS

CHLOROMETHANE BROMOMETHANE VINYL CHLORIDE CHLOROETHANE METHYLENE CHLORIDE ACETONE CARBON DISULFIDE 1,1-DICHLOROETHENE 1,1-DICHLOROETHANE TRANS-1,2-DICHLOROETHENE CHLOROFORM 1,2-DICHLOROETHANE 2-BUTANONE (MEK) 1,1,1-TRICHLOROETHANE CARBON TETRACHLORIDE VINYL ACETATE BROMODICHLOROMETHANE 1,1,2,2-TETRACHLOROETHANE 1,2-DICHLOROPROPANE TRANS-1,3-DICHLOROPROPENE TRICHLOROETHENE DIBROMOCHLOROMETHANE 1,1,2-TRICHLORETHANE BENZENE CIS-1,3-DICHLOROPROPENE 2-CHLOROETHYLVINYLETHER BROMOFORM 2-HEXANONE (MBK) 4-METHYL-2-PENTANONE (MIBK) TETRACHLOROETHENE TOLUENE CHLOROBENZENE ETHYL BENZENE STYRENE TOTAL XYLENES


<10 <10 <1 <1 13 B <10 <1 <1 <1 <1 <1 <1 <10 <1 <1 <10 <1 <1 <1 <1 <1 <1 <1 <1 <1 <10 <5 •<io

<10 <1 <1 <1 <1 <1 <1

l,2-DICHLOROETHANE-D4 (%) BFB (%) T0LUENE-D8 (%)

99 ' 105 105

^^v 7??^ -TluA

\oiz.

tti

sO

n

c\i 01

Q Z 00 3 00 O \ U. tti

r t CD N .

Q . . UJ H X < cn l-l Q

Z Ul u. to < Z O l-H V- u .

Rll

Df iTA: 80G047TB ttl CALI: 80S047TB #2

l'-l'- -^ _ . .__

.'r".--I'-'R;-. 21:43:00-''^ " '--. LHHF'LE:"JOB"805047 TRIP BLANK 5ML CONDS,: !A4 " = -•--'• ^^r•iGE: G 1.. 1400 LABEL: N O. 4.8 QUAH: A 0.. 1.9 J 0 BASE: U 20.

758

1 T'O 1200

R2

644

237

1

J • -

416

\ i il_i53__ 567 -. f

241408.

738

J73

U 859 922 I 1083 1168

200 6:40

400 13:20

600 20:00

860 26:40

1000 33:20

1200 SCAH 40:00 TIME

No 1 5

• ) '

-i c

6 7 0 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 ^S -9 30 31 32 33 34 35 36 37 38 39 40 41 42

m/z 128 1 14 1 17 65 98 95

NOT NOT NOT NOT 84 43

NOT NQT NOT NOT NOT NOT NOT NOT NOT NOT NOT NOT NOT NOT NOT NOT NOT 78

NOT NOT NOT NOT NOT NOT NOT NOT NOT NOT NOT NOT

Scan 334 644 798 416 758 973

FOUND FOUND FOUND FOUND

237 254

FOUND FOUND FOUND FOUND FOUND FOUND FOUND FOUND FOUND FOUND FOUND FOUND FOUND FOUND FOUND FOUND FOUND

567 FOUND FOUND FOUND FOUND FOUND FOUND FOUND FOUND FOUND FOUND FOUND FOUND

Time 11 21 26 13 25 32

7 8

18

08 28 36 S2 16 26

54 28

: 54

Ref 1 2 3 ]

3 3

1 1

,

2

1. 1

1 . 1. 0. 1,

0. 0.

0

RRT 000 000 000 246 950 219

710 760

880

Meth A A

A A A

A A

A

BB DB BJ] HB BP BB

BB BB

BB

Area(Hght) 116627. 627 S 30. 52 ' i 032 . 2370-• 3. 644959. 286334.

63622. 7120.

1279.

Amount 50 boo SO. 000 ;;iO. 000 93.; 923 104. 763 104. 649

12. 903 8. 045

0. 101

UG/L UG/I. UG/L •;_ y. y.

UG/L UG/L

UG/L

XTot 10. 43 10 A3 }. 0 . -12 : ^ . - ' , ,••; i l

2 -i. 36 21. 83

^ 2. 69 1. 68

/•

0, 02

y

^

Quantitation Report File: 806047TB

Data: 806047TB. TI OA/15/88 21;43:00

.p.le: JUB 306047 TRIP BLANK SML C and s. ; QC4 Formula; Instrument; lOSO Weight; 0.0-03 Submitted by; Analyst; MG.U Acct. No. ;

AMOUNT=AREA «• REF AMNT/(REF AREA * RESP FACT) Resp. fac. from Library Entry

BROMOCHLOROMETHANE 1, 4-DIFLUOROBENZENE CHL0R0BENZENE-D5 DICHL0R0ETNANE-D4 T0LUENE-D8 BROMOFLUOROBENZENE CHLOROMETHANE BROMOMETHANE VINYL CHLORIDE CHLOROETHANE METHYLENE CHLORIDE ACETONE CARBON DISULFIDE 1,1-DICHLOROETHENE 1,1-DICHLOROETHANE TRANS-1;2-DICHLOROETHENE CHLOROFORM 1,2-DICHLOROETHANE 2-BUTAANONE 1,1,1-TRICHLOROETHANE CARBON TETRACHLORIDE VINYL ACETATE BROMODICHLOROMETHANE 1,1,2,2-TETRACHLOROETHANE 1,2-DICHLOROPROPANE TRANB-1,3-DICHLOROPROPANE TRICHLOROETHENE DIBROMOCHLOROMETHANE 1,1,2-TRICHLOROETHANE BENZENE CIS-1,3-DICHLOROPROPENE 2-CHLOROETHYL ViNYL ETHER BROMOFORM 4-METHYL-2-PENTAN0NE 2-HEXANONE TETRACHLOROETHENE TOLUENE CHLOROBENZENE ETHYLBENZENE STYRENE TOTAL XYLENES

42 XYLENES

'<-:'-'nz,.-.

No 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 7 a 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 3Q 39 40 41

Name ISl 182 ISB SSI SS2 SSB 45V 46V 88V 16V 44V 13H 15H 29V 13V BOV 23V IOV 14H 11V 6V 19H 48V 15V 32V 33VT B7V 51V 14V 4V

33VC 19V 47V 17H 16H 85V 86V 7V

3av 18H 20H

PROCEDURE: DATA FILE: REFERENCE: WAME LIST:

REPORT;

TCA DIAGNOSTIC REPORT a06047TD 806047TB VQN INITIALIZATION OPTION: 2 VQSTDS

6/15/88 22:31:OS

PROCESSING OPTION;

STANDARDS >-c: PLUS UNKNOWNS PROC USED POSS RMS PROC USED POSS

6 6 6

6 6 6

1 1 1

65 65 65

18 18 18

7 6 7

1 1 2

-— :-C - LIST NAMES - : RMS STANDARD/UNKNOWN 64 VQSTDS/VQl 65 VQ3TDS/VQ2

635 VQSTDS/VQ3

42 COMPOUNDS PROCESSED, 8 FOUND

: COMPOUND X NO LIB ENTRY REF 1 VQ 1 -336 2 VQ 2 -647 3 VQ 3 -801 4 VQ 4 -419 5 VQ 5 -761 6 VQ 6 -978 7 VQ 7 -65 8 VQ 8 -105 9 VQ 9 -131 10 VQ 10 -167 11 VQ 11 -238 12 VQ 12 -255 13 VQ 13 -287 4 VQ 14 -322 5 VQ 15 -362

16 VQ 16 -382 17 VQ 17 -400 18 VQ 18 -422 19 VQ 19 -419 20 VQ 20 -463 21 VQ 21 -475 22 VQ 22 -475 23 VQ 23 -489 24 VQ 24 -726 25 VQ . 25 -531 26 VQ 26 -538 27 VQ 27 -554 28 VQ 28 -574 29 VQ 29 -576 . 30 VQ 30 -570 31 VQ 31 -576 32 VQ 32 -561 33 VQ 33 -656 34 VQ 34 -671 35 VQ 35 -718 36 VQ 36 -726 37 VQ 37 -767 38 VQ 38 -806 39 VQ V 39 -880 i) VQ vf 40 -1034

41 VQ /A/Til -1086 ;; 7'427'WQ7!7774277i04ii.

PRED 334 644 797 417 757 974 64 104 130 166 237 253 285 320 360 380 398 420 417 460 472 472 486'^ 723 528 535 551 571 •573^ 567 575-560 655 670 717 725 766 805 879;

1 0 3 3 ; 1083 i045;

- SEARCH SEL DELTA PEAKS 334 1 644 1 798 1 1 416 -1 1 758 1 1 973 -1 1

237

730 13

W:

':A '•'••// 77779:/:,:?:,-^:^/. '77'i/o::~90:'-i7Z'f/,î.;'/^:i7''''/7Z/r/..-•'•'', '•'••'-z\777/i;J7j7777j2,^^:A77J7J{

— >< SAT >--: FIT PEAKS M/Z 951 128 922 114 998 117 99S 65 996 98 979 95

50 94 62 64

992 84 43 76 96 63 96

V . 83 62

;••'./ 7 2

97 117

.. . ; 43 83 83

: 63 75

. 1 3 0 129 97 78

. . 75 63 173 43

896 . 43 . - ; 164

92 112

• •. " " 7 ' ' ^ 7 / ' z ' ^ 1 0 6 ••

104 , . , ...-. 106

2 / o Z z z ' : _ ' - •;•';•;;•;,..;., i o 6

-- CHRO TOP DELTA PEAKS 334 1 644 1 798 1 416 1 758 1 973 1

•

. 237 1 254 1

.

• . • ; • • . - • . - - -

' .

. . ' . • .

567 1

. • • • ' • . .

. . " ' ' - Z : • 2 ' ' - ' ' ' ' - . O z ..'••.

. ' . • .

.• • " z . . '•'• • ' : ' .

/o. ' - ' / • ' ' • ' .

A /yi/v-z/AA

/ J S ^ AnolylicolTechnologies, Inc

GCMS - RESULTS

REAGENT BLANK

TEST : SEMI-VOLATILE ORGANICS grq o-zs'

CLIENT : MONTGOMERY & ASSOCIATES

PROJECT # : 661-D PROJECT NAME : HASSAYAMPA CLIENT I.D. : REAGENT BLANK

ATI I.D. DATE EXTRACTED DATE ANALYZED UNITS DILUTION FACTOR

806047 06/13/88 06/21/88 UG/L N/A

COMPOUNDS RESULTS

N-NITROSODIMETHYLAMINE PHENOL ANILINE BIS(2-CHLOROETHYL)ETHER 2-CHLOROPHENOL 1,3-DICHLOROBENZENE 1,4-DICHLOROBENZENE BENZYL ALCOHOL 1,2-DICHLOROBENZENE 2-METHYLPHENOL BIS(2-CHLOROISOPROPYL)ETHER 4-METHYLPHENOL N-NITROSO-DI-N-PROPYLAMINE HEXACHLOROETHANE NITROBENZENE ISOPHORONE 2-NITROPHENOL 2,4-DIMETHYLPHENOL BENZOIC ACID BIS(2-CHLOROETHOXY)METHANE 2,4-DICHLOROPHENOL 1,2,4-TRICHLOROBENZENE NAPHTHALENE 4-CHLOROANILINE HEXACHLOROBUTADIENE 4-CHLORO-3-METHYLPHENOL 2-METHYLNAPHTHALENE HEXACHLOROCYCLOPENTADIENE 2,4,6-TRICHLOROPHENOL 2,4,5-TRICHLOROPHENOL 2-CHLORONAPHTHALENE 2-NITROANILINE DIMETHYL PHTHALATE ACENAPHTHYLENE 3-NITROANILINE ACENAPHTHENE 2,4-DINITROPHENOL 4-NITROPHENOL DIBENZOFURAN 2,4-DINITROTOLUENE 2,6-DINITROTOLUENE DIETHYL PHTHALATE 4-CHLOROPHENYL-PHENYLETHER

<10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <50 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <50 <10 <50 <10 <10 <50 <10 <50 <50 <10 <10 <10 <10 <10

/ ^ AnolyticolTechnologies, Inc

GCMS - RESULTS ^

REAGENT BLANK ATI I.D. 806047

TEST : SEMI-VOLATILE ORGANICS E'' i l'-

COMPOUNDS RESULTS

FLUORENE 4-NITROANILINE 4,6-DINITRO-2-METHYLPHENOL N-NITROSODIPHENYLAMINE(1) 4-BROMOPHENYL-PHENYLETHER HEXACHLOROBENZENE PENTACHLOROPHENOL PHENANTHRENE ANTHRACENE DI-N-BUTYLPHTHALATE FLUORANTHENE BENZIDINE PYRENE BUTYLBENZYLPHTHALATE 3,3'-DICHLOROBENZIDINE BENZO(a)ANTHRACENE BIS(2-ETHYLHEXYL)PHTHALATE CHRYSENE DI-N-OCTYL PHTHALATE BENZO(b)FLUORANTHENE BENZO(k)FLUORANTHENE BENZO(a)PYRENE INDENO(1,2,3-cd)PYRENE DIBENZO(a,h)ANTHRACENE BENZO(g,h,i)PERYLENE

<10 <50 <50 <10 <10 <10 <50 <10 <10 TR'^ <10 <100 <10 <10 <20 <10 TR <10 <10 <10 <10 <10 <10 <10 <10


NITROBENZENE-DS (%) 2-FLUOROBIPHENYL (%) TERPHENYL (%) PHEN0L-D5 (%) 2-FLUOROPHENOL (%) 2,4,6-TRIBROMOPHENOL (%)

116 79 109 88 94 73

i,X5- - >)/V-7UA

SCANS RIC / DATA: B621 ftl .06/21/88 S*45^08..^ CALI: B621 #2 'SAMPLE! .-{gACFHT RLAE K BN/A 6/13/88 CONDS.: ec RAHGE: G ^1.2380 LABEL: H 8. 4.8 QUAH: A 0. 1.8 J 8 BASE: U 28. 3

1 TO 2300

100.0-1

CD ni ai o

z Z i CD O 00

u. \ n ru

o •• Ui K 3: < Cl) KH o z UJ HH X U . CO

»-• <c z r j l-H H- U.

RIC

. ^ l " * ^ ^

311295.

^ T J

• 'ZZ^- '—'î.

r • I

500 8:20

1000 16:40

1500 25:00

2000 SCAN TTI-1F

PROCEDURE DATA FILE REFERENCE NAME LIST - REPORT

! . - tt-T-

TCA B621 B621

DIA(

Kl INITIALIZATION XI

• O 1 MIVL^niTWO

PROC USE 2 2 2 2 2 2 2 2 1 •

;D POSS 2 1 2 1 2 1 2 1 2 1 2 1 2 1 2 1 3 0

— - . " i y — ->s. RMS

0 0 0 0 0 0 0 0 0

80 COMPOUNDS PROCESSEDi

y /.riMOni i t . t r \ - ^ y : <. CUnrUUr NO 1 2 3 4 5 6 7 8

.'•• 7

J .0

11 12 13 14 15 16 17 18 19 20 21 22 23 24 23 26 27 28 29 30 31 32 33

7 36 37 38 39 40 41

MJ^ ••S.

LIB ENTRY REF SV i SV SV SV SV SV SV SV SV SV SV ,,-SV SV SV ' SV sv sv sv SV sv SV sv sv sv , sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv

1 -424 2 -607 14 -263 13 -412 16-641 1 7 - 4 0 2 1 8 - 4 0 7 1 9 - 4 1 7 ;20i i 426-21 -459

,.^722.7^50 ' ''7'-? 4i0 , . 8 ,)-278„ 23 C-490 24 ' -479

.25 -514 26 -500 27 -493 3 -871

28 -510 29 -549 30 -557 31 -584 32 -623 33 -590 34 -606 9 -508

33 -603 36 -609 37 -644 38 -642 39 -724 40 -713 4 -1090

41 -750 42 -769 43 -784 44^,-784 43 :>-816 .46, .'-853 47' - -845

PRED 426 611 263 414 645

.404 : 409 419 428 461

. 432 411

v 277 493 482 517 503 496 878 513 552 560 588

, 629 594 610 511 607 613 648 646 729 718 1098 756 776 791 791 823 860

• 852,

Mt •* 1

PROC 11 9 9 9 12 12 11 10 7

13 1

3N0STIC REPORT 6/21/88 16: 31:02

OPTION: .2 PROCESSING OPTION: 3

'LUS UNKNOWNS • USED

2 4 2 3 2 4 3 3 0

-OUND

Ot.nr\un

POSS 1 2

SEL DELTA PEAKS 426 611

;

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41 27

87

51

1091

* 5 -i

3

1

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1 1 ,

3 2 2 1

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1

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>< - LIST NAMES - > RMS STANDARD/UNKNOWN

0 Xl/Zl 242 Xl/ZA

0 X2/Z2 7 X2/ZB 0 X3/Z3

28 X3/ZC 41 X4/Z4 76 X5/Z5 0' X6/Z6 •' J /z7j7772j ' " ' / ' ' " '

-^y C A T "S * _ _ _ _ _ _ /ÛIDn :_ y-^ aA 1 y-<. _ _ _ _ _ _ i MKCJ —

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FIT PEAKS M/Z TOP DELTA PEAKS 983 152 426 972 -1 136 611

42 . .

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996 1 971 ';

931

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1 112 275 1 108

45 . 108 70 117 f . 164 878 77 82 : 139 122 122 93 . 162 82 Sll 180 128 127 225 107

, 142 ; 188 1098 237 196 . 196 . .

• 162 65 . 163 152

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51 52 53 54 55 56 57 58 59 60 61 62 63 64 65 66 67 68 69 70 71 72 73 74 ^5 . 6 77 78 79 80

-.-''/ SV SV sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv • sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv

M.V 50 10 11 51 52 53 54 55 36 57 58 5

59 60 61 62 63

- 64 65 66 67 6 12 68 69 70 71 72 73 74 75 76 77 78 79 80 81

- ' d l -.2

-896 -777 -993

-1267 -899 -839 -916 -961 -959 -951

-1349 -1491 -976 -981

-1031 -1045 -1081 -1093 -1099 -1209 -1271 -1698 -1342 -1763 -1302 -1431 -2007 -1488 -1530 -1494 -1620 -1648 -1648 -1688 -1893 -1903 -1952

ttb-rJ

903 784 784 1001 1001 1276 906 866 923 969 967 959 1358 1504 1504 983 988 1039 1033 1089 1101 1107 1219 1219 1281 1716 1716 1333 1333 1782 1312 1443 2031 1502 1544 1508 1620 1648 1648 1688 1893 1903 1952

1 992 1 984

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1 941

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• . • ' • •

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1 884

1 949 1 863

iS3 184 172 330 139 168 89 165 149 204 166 "138 240 198 169 248 284 266 178 : ^178 149 202 264 244 184 202 149 252 228 149 228 149 252 232 252 276 278 276

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Quantitation Report File: B621

Data: B621. TI 06/21/83 16:12:00 , =?mple: REAGENT BLANK BN/A 6/13/88 ' nds. : GCS Formula: Instrument: 1050 Weight; 50.000 Submitted by: Analyst: MGB Acct. No. :

•

AMOUNT=AREA <* REF AMNT/(REF AREA * RESP FACT) Resp. fac. from Library Entry ' '-7.. 777'7 777'

1,4-DICHL0R0BENZENE-D4 <SV#1) NAPHTHALENE-DS (SV#2) N-NITROSODIMETHYLAMINE (SV#14) PHENOL <SV#13y '.':''z2--..--,:: •'- -O;,'.:,:-':-'/ 2 - , ANILINE (SV#16) ,' -v;;,. BIS<2-CHLOROETHYL)ETHER (SV#17) 2-CHLOROPHENOL <SVttlS) 1,3-DICHLOROBENZENE (SV#19) 1,4-DICHLOROBENZENE (SV#20) BENZYL ALCOHOL (SVtt21) 1,2-DICHLaRQBENZENE (SV#22) PHEN0L-D3 <SV#7> 2-FLUOROPHENOL (SV#8) 2-METHYLPHENOL (SV#23) BIS(2-CHL0R0IS0PR0PYL)ETHER (SV#24) 4-METHYLPHENaL (SV#23) N-NITROSO-DI-N-PROPYLAMINE (SV#26) HEXACHLOROETHANE (SV#27) ACENAPHTHENE-DIO (SV#3) NITROBENZENE (SV#28) ISOPHORONE (SV#29) 2-NITROPHENOL (SV#30) 2,4-DIMETHYLPHENOL (SV#31) BENZOIC ACID <SV#32) BIS(2-CHLOROETHOXY)METHANE (SV#33) 2,4-DICHLOROPHENOL (SV#34) NITR0BENZENE-D5 (SV#9) 1,2,4-TRICHLOROBENZENE (SV#33) NAPHTHALENE (SV#36> 4-CHLOROANILINE (SV#37) HEXACHLOROBUTADIENE (SV#38) 4-CHL0R0-3-METHYLPHENaL <SV#39) 2-METHYLNAPHTHALENE (SV#40) PHENANTHRENE-DIO (SV#4) HEXACHLOROCYCLOPENTADIENE (SVtt41) 2,4,6-TRICHLOROPHENOL <SV#42) 2,4,3-TRICHLOROPHENOL <SV#43) 2-CHLORONAPHTHALENE (SV#44) 2-NITROANILINE (SV#43) DIMETHYL PHTHALATE (SV#46) ACENAPHTHYLENE (SV#47) S-NITROANILINE <SV#48) ACENAPHTHENE (SV#49) 2,4-DINITROPHENOL (SVttSO) 2-FLUOROBIPHENYL (SVttlO) 2,4,6-TRIBROMOPHENOL (SVttll) 4-NITROPHENOL (SVttSl)

No 1 2 3 4 3 6 7 8 9 10 11 12 13 14 13 16 17 •8 *9 20 21 22 23 24 23 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 4

45 46 47

Name ISl IS2 61B 63A 3H 18B 24A 26B 27B 6H 25B S52 SSI 2H 42D 4H 63B 12B 133 .363 34B 57A 34A IH 43B BIA SS3 SB 55B 7H 52B 22A 9H IS4 33B 21A 4H 20B lOH 71B 77B IIH IB 59A SS4 SSS SBA

No Name 43 8H DIBENZOFURAN (SVtt52) 49 35B 2,4-DINITROTOLUENE (SVtt53)

ZÔ 36B 2,6-DINITROTOLUENE (SVtt54)

No 1 2 3 4 5 6 7 8 9 10 11 12 13 14 13 16 17 18 19 20 21 22 23 ' 1

— j

26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49

m/z Scan 132 426 136 611 NOT FOUND NOT FOUND NOT FOUND NOT FOUND NOT FOUND NOT FOUND NOT FOUND

-NOT FOUND ^NOT FOUND

99 414 112 275 NOT FOUND NOT FOUND NOT FOUND NOT FOUND NOT FOUND 164 878 NOT FOUND NOT FOUND NOT FOUND NOT FOUND NOT FOUND NOT FOUND NOT FOUND 82 311

NOT FOUND ,-NOT FOUND NOT FOUND NOT FOUND NOT FOUND NOT FOUND 188 1098 NOT FOUND NOT FOUND NOT FOUND NOT FOUND NOT FOUND NOT FOUND NOT FOUND NOT FOUND NOT FOUND NOT FOUND 172 784 330 1001 NOT FOUND NOT FOUND NOT FOUND NOT FOUND

Time 7:06 10: 11

. . • - ; .

6:34 4:35

14:38

' 8:31 . W •

18: 18

13:04 16: 41

Ref 1 2

1 1

19

2

34

19 19

1. 1.

0. 0.

1.

0.

1.

0. 1.

RRT 000 000

972 646

000

836

000

893 140

Meth A BB A BB

A BV A BB

A BB

A BQ

A BQ

A BB A QD

Area(Hght) 112860. 309990.

33928. 35239.

'

176202.

42323.

243404.

77540. 8428,

Amount 100. 000 100. 000 ,

43. 867 46. 789

'

100. 000

; • •

57. 858

1 1

(

100. 000

39. 327 36. 277

NG/UL NG/UL

' ! . ; • -

' ' • ; . •

.

NG/UL NG/UL

NG/UL

NG/UL

NG/UL

NO/UL NG/UL

y.Tot 11. 77 11.77

--.

3. 16 3. 51-

11. 77 m

6. 81

11. 77

4. 63 4. 27-

- ^ r ^

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Cûantitation Report File: D621

Data: B621. TI 06/21/88 16:12:00 P' mple: REAGENT BLANK BN/A 6/13/88 nds. : GC5

Formula: Instrument: 1050 Submitted by: Analyst: MGB

AMOUNT=AREA * REF AMNT/(REF AREA » RESP FACT) Resp. fac. from Library Entry

Weight: 30.000 Acct. No. :

No 51 52 53 54 55 56 57 58 59 60 61 62 63 64 65 66 67 3 ^9 70 71 72 73 74 73 76 77 78 77 80

Name 70B DIETHYL PHTHALATE (SVtt55) 40B 4-CHLOROPHENYLPHENYL ETHER (SVtt56) SOB FLUORENE <SV#37) 12H 4-NITROANIHNE (SVttSS) 133 CHRYSENE-D12 (SVttS) 60A 2-METHYL-4,6-DINITROPHENOL (SVtt59) 62B N-NITROSODIPHENYLAMINE (SVtt60) 41B 4-BROMOPHENYLPHENYL ETHER (SVtt61) 9B HEXACHLOROBENZENE (SVtt62) 64A PENTACHLOROPHENOL (SVtt63) 81B PHENANTHRENE (SVtt64) 78B ANTHRACENE (SVtt65) 68B DI-N-BUTYL PHTHALATE (SVtt66) 39B FLUORANTHENE <SVtt67) IS6 PERYLENE-D12 (SVtt6) SS6 :.TERPHENYL-D14 (SVtt12) 3D BENZIDINE (SVtt68) 84B PYRENE (SVtt69) 67D DUTYL DENZYL PHTHALATE (SVtt70) 28B 3,3'-DICHLOROBENZIDINE (SVtt71) 72B BEN20(A)ANTHRACENE (SVtt72) 66B BIS(2-ETHYLHEXYL)PHTHALATE (SVtt73) 76B CHRYSENE (SVtt74) 69B DI-N-OCTYL PHTHALATE (SVtt73) 74B BENZO(B)FLUORANTHENE (SVtt76) 74B BENZO(K)FLUORANTHENE (SVtt77) 73D BENZO(A)PYRENE (SVtt78) 83B INDENOd, 2, 3-CD)PYRENE (SVtt79) 82B DIBENZO(A,H)ANTHRACENE (SVttSO) 79B BEN20(G,H. DPERYLENE (SVttBl)

. - 1 . . . --I.' •

No m/z Scan 51 NOT FOUND 32 NOT FOUND 53 NOT FOUND 54 NOT FOUND 55 240 1304 56 NOT FOUND 57 NOT FOUND 58 NOT FOUND 59 NOT FOUND 60 NOT FOUND Al NOT FOUND 2 NOT FOUND

63 149 1219

Time Ref RRT Meth Area(Hght) Amount XTot

04 35 1. 000 A DD 130112. 100. 000 NG/UL 11. 77

20: 19 34 1. 110 A BD 3190. 1. 413 NO/UL 0. 17 u ^

No 64 65 '-6 7

68 69 70 71 72 73 74 75 76 77 78 79 80

m/z Scan NOT FOUND 264 1716 244 1333 NOT FOUND NOT FOUND NOT FOUND NOT FOUND NOT FOUND 149 1544 NOT FOUND NOT FOUND NOT FOUND NOT FOUND NOT-FOUNDC NOT FOUND •NOT FOUND NOT FOUND

Time

28:36 22:33

23:44

' ^ '

•'*T:;'ji'^'.- •*•

Ref

65 1. 33 0.

53 1.

'

RRT

000 900

027

Meth

A QB A QB

A QQ

Z Z ' • ' . ; .

Area(H

147222 83467

879

Amount 7.Tot

100. 000 NG/UL 11. 77 54. 573 NG/UL 6. 42

0. 974 NG/UL 0. 11

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GAS CHROMATOGRAPHY - RESULTS

REAGENT BLANK

TEST : ORGANOCHLORINE PESTICIDES AND PCB'S (EPA 608)

CLIENT PROJECT # PROJECT NAME CLIENT I.D.

MONTGOMERY & ASSOCIATES 661-D HASSAYAMPA REAGENT BLANK

ATI I.D. DATE EXTRACTED DATE ANALYZED - UNITS DILUTION FACTOR

806047 06/13/88 06/29/88 UG/L N/A

COMPOUNDS RESULTS

ALDRIN ALPHA BHC BETA BHC GAMMA BHC (LINDANE) DELTA BHC CHLORDANE 4,4'-DDD 4,4'-DDE 4,4'-DDT DIELDRIN ENDOSULFAN I ENDOSULFAN II ENDOSULFAN SULFATE ENDRIN ENDRIN ALDEHYDE HEPTACHLOR HEPTACHLOR EPOXIDE METHOXYCHLOR TOXAPHENE AROCLOR 1016 AROCLOR 1221 AROCLOR 1232 AROCLOR 1242 AROCLOR 1248 AROCLOR 1254 AROCLOR 1260

<0.05 <0.05 <0.05 <0.05 <0.05 <0.5 <0.1 <0.1 <0.1 <0.1 <0.05 <0.1 <0.1 <0.1 <0.1 <0.05 <0.05 <0.5 <1.0 <0.5 <0.5 <0.5 <0.5 <0.5 <1.0 <1.0


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2 2 4 5 6 7 y 9 10 " 11 ; 12 13 14 15 16 ' •'•• 1

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3.82 4.86 6.51 6. 65 6.77 7. 22 7.44 7.77, 7.91 3.03 8.18 8.67 8.77 9.Q6 9. 86

10.13 10.77 11.13 11.4 11. 61 11.77 11.93 12.32 12.44 12.59 12. 74 13.19 13.77

. 13. 36 14.22 14. 61 14.84 15.63 15. 73 16. 57 17. 09

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1045, 02 132 03 93 01 312 01 157 02 38 03 257 01 133 01 326 02 196 03 1679 01 1022 01

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Documents

A /j}^ AnolylicolTechnologies, Inc/^ -ZU7) A /j} ^ AnolylicolTechnologies, Inc GCMS - RESULTS REAGENT BLANK TEST : VOLATILE ORGANICS tr'i i^7H SFUND RECORDS CTR 0222-00710 AR0565 CLIENT